#------------------------------------------------------------------------------
#$Date: 2016-06-17 04:48:19 +0300 (Fri, 17 Jun 2016) $
#$Revision: 183630 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/75/2107500.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2107500
loop_
_publ_author_name
'Davarcı, Derya'
'Gür, Rüştü'
'Beşli, Serap'
'Şenkuytu, Elif'
'Zorlu, Yunus'
_publ_section_title
;
 Silver(I) coordination polymers assembled from flexible
 cyclotriphosphazene ligand: structures, topologies and investigation of
 the counteranion effects
;
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              344
_journal_page_last               356
_journal_paper_doi               10.1107/S2052520616002663
_journal_volume                  72
_journal_year                    2016
_chemical_formula_moiety         'C32 H27 Ag2 N10 O6 P3, 2(BF4)'
_chemical_formula_sum            'C32 H27 Ag2 B2 F8 N10 O6 P3'
_chemical_formula_weight         1129.90
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           'APEX2 v2014.11-0'
_cell_angle_alpha                99.386(5)
_cell_angle_beta                 99.515(5)
_cell_angle_gamma                103.137(5)
_cell_formula_units_Z            1
_cell_length_a                   8.1432(8)
_cell_length_b                   9.8790(10)
_cell_length_c                   13.5670(15)
_cell_measurement_temperature    300.(2)
_cell_volume                     1025.10(19)
_computing_cell_refinement       'APEX2 (Bruker AXS)'
_computing_data_collection       'APEX2 (Bruker AXS)'
_computing_data_reduction        'SAINT (Bruker AXS)'
_computing_molecular_graphics    'MERCURY (Macrae et al., 2006)'
_computing_publication_material
'PLATON V1.16 (Spek, 2009), SHELXTL V6.14 (Bruker AXS)'
_computing_structure_refinement  'SHELXTL V6.14 (Bruker AXS)'
_computing_structure_solution    'SHELXTL V6.14 (Bruker AXS)'
_diffrn_ambient_temperature      300.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type
'Bruker APEX II QUAZAR three-circle diffractometer'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'multilayer QUAZAR mirrors'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0546
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12958
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         2.92
_exptl_absorpt_coefficient_mu    1.166
_exptl_absorpt_correction_T_max  0.85
_exptl_absorpt_correction_T_min  0.60
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker AXS)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.830
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             558
_exptl_crystal_size_max          0.493
_exptl_crystal_size_mid          0.471
_exptl_crystal_size_min          0.145
_refine_diff_density_max         1.742
_refine_diff_density_min         -1.131
_refine_ls_abs_structure_details
;
Flack x determined using 2307 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.12(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     569
_refine_ls_number_reflns         6792
_refine_ls_number_restraints     69
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0796
_refine_ls_R_factor_gt           0.0748
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1602P)²+0.0722P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2109
_refine_ls_wR_factor_ref         0.2174
_reflns_number_gt                6089
_reflns_number_total             6792
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            xk5028sup1.cif
_cod_data_source_block           CCDC1422435
_cod_depositor_comments
'Adding full bibliography for 2107497--2107503.cif.'
_cod_database_code               2107500
_cod_database_fobs_code          2107500
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Ag Ag1 0.84901(13) 1.17851(9) 0.91032(8) 0.0609(4) Uani d 1
Ag Ag2 0.43723(15) 0.02437(13) 0.39677(10) 0.0689(5) Uani d 1
B B1 0.415(8) 0.833(6) 0.121(4) 0.145(4) Uani d 1
B B2 0.438(6) 0.231(6) 0.701(4) 0.140(4) Uani d 1
C C1 0.1463(16) 0.1677(13) 0.4267(9) 0.038(3) Uani d 1
H H1 0.2156 0.1997 0.492 0.045 Uiso calc 1
C C2 0.0011(15) 0.2145(10) 0.4036(9) 0.030(2) Uani d 1
C C3 -0.0980(19) 0.1763(14) 0.3077(11) 0.046(3) Uani d 1
H H3 -0.1936 0.2113 0.2913 0.055 Uiso calc 1
C C4 -0.0539(18) 0.0847(15) 0.2354(11) 0.047(3) Uani d 1
H H4 -0.1217 0.0546 0.1697 0.056 Uiso calc 1
C C5 0.089(2) 0.0382(15) 0.2603(11) 0.047(3) Uani d 1
H H5 0.1197 -0.0218 0.2104 0.056 Uiso calc 1
C C6 -0.0820(19) 0.4125(13) 0.1175(10) 0.041(3) Uani d 1
H H6 -0.0059 0.3624 0.142 0.05 Uiso calc 1
C C7 -0.0714(17) 0.5448(13) 0.1736(9) 0.036(3) Uani d 1
C C8 -0.177(2) 0.6212(17) 0.1404(10) 0.051(3) Uani d 1
H H8 -0.1673 0.7129 0.1752 0.061 Uiso calc 1
C C9 -0.307(3) 0.556(2) 0.0493(11) 0.069(5) Uani d 1
H H9 -0.3864 0.6036 0.025 0.082 Uiso calc 1
C C10 -0.311(2) 0.4236(18) -0.0014(11) 0.055(4) Uani d 1
H H10 -0.3959 0.3804 -0.0598 0.066 Uiso calc 1
C C11 -0.2626(15) 0.8759(10) 0.3971(9) 0.031(2) Uani d 1
H H11 -0.3188 0.8396 0.3292 0.038 Uiso calc 1
C C12 -0.1134(14) 0.8434(10) 0.4318(8) 0.026(2) Uani d 1
C C13 -0.0257(19) 0.8979(15) 0.5312(10) 0.045(3) Uani d 1
H H13 0.079 0.8797 0.5556 0.054 Uiso calc 1
C C14 -0.1001(19) 0.9812(14) 0.5939(9) 0.040(3) Uani d 1
H H14 -0.0506 1.0181 0.6628 0.048 Uiso calc 1
C C15 -0.2520(19) 1.0056(13) 0.5476(12) 0.043(3) Uani d 1
H H15 -0.3001 1.0638 0.5886 0.052 Uiso calc 1
C C16 0.5385(16) 0.3876(13) 0.4220(11) 0.039(3) Uani d 1
H H16 0.5766 0.3837 0.4897 0.047 Uiso calc 1
C C17 0.4947(14) 0.5102(12) 0.4023(9) 0.031(2) Uani d 1
C C18 0.4464(19) 0.5253(16) 0.3040(11) 0.046(3) Uani d 1
H H18 0.4192 0.6072 0.2891 0.055 Uiso calc 1
C C19 0.441(2) 0.4115(18) 0.2286(12) 0.056(4) Uani d 1
H H19 0.4078 0.4152 0.1604 0.067 Uiso calc 1
C C20 0.483(2) 0.2930(16) 0.2533(12) 0.053(3) Uani d 1
H H20 0.4798 0.2188 0.2006 0.064 Uiso calc 1
C C21 0.6070(18) 0.9191(13) 0.7552(10) 0.042(3) Uani d 1
H H21 0.5654 0.9934 0.7364 0.051 Uiso calc 1
C C22 0.5405(15) 0.7823(12) 0.6951(9) 0.034(2) Uani d 1
C C23 0.597(2) 0.6709(13) 0.7238(10) 0.049(3) Uani d 1
H H23 0.5517 0.5789 0.6851 0.058 Uiso calc 1
C C24 0.724(3) 0.6989(17) 0.8126(11) 0.067(5) Uani d 1
H H24 0.7649 0.6262 0.8348 0.08 Uiso calc 1
C C25 0.788(2) 0.8387(18) 0.8669(10) 0.058(4) Uani d 1
H H25 0.8744 0.8581 0.9251 0.07 Uiso calc 1
C C26 -0.0679(18) 0.3762(14) 0.7330(10) 0.043(3) Uani d 1
H H26 -0.1563 0.3044 0.689 0.051 Uiso calc 1
C C27 0.0011(16) 0.4936(14) 0.6978(10) 0.040(3) Uani d 1
C C28 0.130(2) 0.6009(16) 0.7591(12) 0.062(4) Uani d 1
H H28 0.1751 0.6834 0.7374 0.074 Uiso calc 1
C C29 0.190(2) 0.581(2) 0.8557(12) 0.070(5) Uani d 1
H H29 0.2811 0.6504 0.9002 0.084 Uiso calc 1
C C30 0.117(2) 0.4616(19) 0.8854(11) 0.058(4) Uani d 1
H H30 0.1618 0.4494 0.9501 0.07 Uiso calc 1
C C31 1.228(4) 1.115(3) 0.972(2) 0.098(4) Uani d 1
C C32 1.347(4) 1.053(3) 0.924(2) 0.100(4) Uani d 1
H H32A 1.455 1.073 0.9713 0.149 Uiso calc 1
H H32B 1.3651 1.0932 0.8652 0.149 Uiso calc 1
H H32C 1.2999 0.9521 0.9022 0.149 Uiso calc 1
F F1 0.430(4) 0.866(3) 0.2156(16) 0.149(4) Uani d 1
F F2 0.375(3) 0.676(3) 0.1255(17) 0.148(4) Uani d 1
F F3 0.251(3) 0.840(2) 0.0780(15) 0.142(4) Uani d 1
F F4 0.510(4) 0.836(3) 0.0528(17) 0.145(4) Uani d 1
F F5 0.330(3) 0.309(3) 0.7099(16) 0.143(4) Uani d 1
F F6 0.555(2) 0.227(2) 0.7739(14) 0.134(4) Uani d 1
F F7 0.310(3) 0.099(2) 0.6773(15) 0.142(4) Uani d 1
F F8 0.486(3) 0.236(3) 0.6149(16) 0.142(4) Uani d 1
N N1 0.2257(12) 0.5139(10) 0.5418(7) 0.031(2) Uani d 1
N N2 0.2432(12) 0.7223(9) 0.4317(7) 0.0293(19) Uani d 1
N N3 -0.0585(13) 0.5277(10) 0.4136(8) 0.034(2) Uani d 1
N N4 -0.1942(18) 0.3532(13) 0.0308(8) 0.047(3) Uani d 1
N N5 -0.3319(13) 0.9588(10) 0.4576(8) 0.036(2) Uani d 1
N N6 -0.0154(19) 0.3600(14) 0.8259(9) 0.056(3) Uani d 1
N N7 0.1907(13) 0.0777(10) 0.3583(9) 0.039(2) Uani d 1
N N8 0.7310(16) 0.9450(11) 0.8403(8) 0.044(3) Uani d 1
N N9 0.5295(15) 0.2785(12) 0.3517(10) 0.048(3) Uani d 1
N N10 1.140(3) 1.159(3) 1.0065(18) 0.098(4) Uani d 1
O O1 -0.0450(10) 0.2999(8) 0.4833(7) 0.0354(18) Uani d 1
O O2 -0.0684(12) 0.5048(9) 0.5992(7) 0.0392(19) Uani d 1
O O3 0.4154(12) 0.7744(9) 0.6111(7) 0.043(2) Uani d 1
O O4 0.5083(10) 0.6218(8) 0.4842(7) 0.0342(17) Uani d 1
O O5 0.0627(11) 0.5996(9) 0.2582(6) 0.0380(18) Uani d 1
O O6 -0.0502(11) 0.7663(8) 0.3562(6) 0.0329(17) Uani d 1
P P1 0.0212(3) 0.4678(3) 0.5051(2) 0.0278(6) Uani d 1
P P2 0.0503(3) 0.6496(2) 0.3728(2) 0.0266(6) Uani d 1
P P3 0.3360(3) 0.6502(3) 0.5132(2) 0.0279(6) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N8 Ag1 N4 . 1_666 138.6(5)
N8 Ag1 N6 . 1_665 126.8(4)
N4 Ag1 N6 1_666 1_665 89.8(5)
N8 Ag1 N10 . . 98.2(6)
N4 Ag1 N10 1_666 . 98.3(6)
N6 Ag1 N10 1_665 . 93.2(7)
N7 Ag2 N5 . 1_645 170.2(4)
F1 B1 F4 . . 140.(6)
F1 B1 F3 . . 107.(4)
F4 B1 F3 . . 109.(4)
F1 B1 F2 . . 91.(3)
F4 B1 F2 . . 101.(3)
F3 B1 F2 . . 99.(4)
F6 B2 F8 . . 115.(4)
F6 B2 F5 . . 124.(5)
F8 B2 F5 . . 109.(4)
F6 B2 F7 . . 108.(4)
F8 B2 F7 . . 102.(4)
F5 B2 F7 . . 95.(3)
N7 C1 C2 . . 121.8(11)
N7 C1 H1 . . 119.1
C2 C1 H1 . . 119.1
C3 C2 C1 . . 120.8(11)
C3 C2 O1 . . 121.1(11)
C1 C2 O1 . . 118.1(10)
C2 C3 C4 . . 118.5(12)
C2 C3 H3 . . 120.8
C4 C3 H3 . . 120.8
C5 C4 C3 . . 119.7(13)
C5 C4 H4 . . 120.1
C3 C4 H4 . . 120.1
C4 C5 N7 . . 121.8(13)
C4 C5 H5 . . 119.1
N7 C5 H5 . . 119.1
N4 C6 C7 . . 123.5(13)
N4 C6 H6 . . 118.3
C7 C6 H6 . . 118.3
C8 C7 C6 . . 120.2(13)
C8 C7 O5 . . 122.2(12)
C6 C7 O5 . . 117.3(12)
C7 C8 C9 . . 117.5(14)
C7 C8 H8 . . 121.2
C9 C8 H8 . . 121.2
C10 C9 C8 . . 118.7(13)
C10 C9 H9 . . 120.6
C8 C9 H9 . . 120.6
N4 C10 C9 . . 122.1(14)
N4 C10 H10 . . 119.0
C9 C10 H10 . . 119.0
N5 C11 C12 . . 122.2(11)
N5 C11 H11 . . 118.9
C12 C11 H11 . . 118.9
C11 C12 C13 . . 120.2(11)
C11 C12 O6 . . 114.9(9)
C13 C12 O6 . . 124.5(11)
C12 C13 C14 . . 117.3(12)
C12 C13 H13 . . 121.3
C14 C13 H13 . . 121.3
C15 C14 C13 . . 115.9(12)
C15 C14 H14 . . 122.1
C13 C14 H14 . . 122.1
N5 C15 C14 . . 127.7(13)
N5 C15 H15 . . 116.2
C14 C15 H15 . . 116.2
N9 C16 C17 . . 124.0(13)
N9 C16 H16 . . 118.0
C17 C16 H16 . . 118.0
C18 C17 C16 . . 120.7(12)
C18 C17 O4 . . 119.9(11)
C16 C17 O4 . . 119.4(10)
C17 C18 C19 . . 115.8(14)
C17 C18 H18 . . 122.1
C19 C18 H18 . . 122.1
C20 C19 C18 . . 120.6(15)
C20 C19 H19 . . 119.7
C18 C19 H19 . . 119.7
N9 C20 C19 . . 123.2(14)
N9 C20 H20 . . 118.4
C19 C20 H20 . . 118.4
N8 C21 C22 . . 120.9(12)
N8 C21 H21 . . 119.6
C22 C21 H21 . . 119.6
C23 C22 O3 . . 126.4(11)
C23 C22 C21 . . 120.1(12)
O3 C22 C21 . . 113.5(10)
C22 C23 C24 . . 118.4(12)
C22 C23 H23 . . 120.8
C24 C23 H23 . . 120.8
C25 C24 C23 . . 118.2(13)
C25 C24 H24 . . 120.9
C23 C24 H24 . . 120.9
N8 C25 C24 . . 123.4(13)
N8 C25 H25 . . 118.3
C24 C25 H25 . . 118.3
N6 C26 C27 . . 123.0(12)
N6 C26 H26 . . 118.5
C27 C26 H26 . . 118.5
C28 C27 C26 . . 120.6(14)
C28 C27 O2 . . 120.3(13)
C26 C27 O2 . . 119.1(12)
C27 C28 C29 . . 116.4(15)
C27 C28 H28 . . 121.8
C29 C28 H28 . . 121.8
C30 C29 C28 . . 119.9(14)
C30 C29 H29 . . 120.0
C28 C29 H29 . . 120.0
N6 C30 C29 . . 122.9(15)
N6 C30 H30 . . 118.6
C29 C30 H30 . . 118.6
N10 C31 C32 . . 179.(3)
C31 C32 H32A . . 109.5
C31 C32 H32B . . 109.5
H32A C32 H32B . . 109.5
C31 C32 H32C . . 109.5
H32A C32 H32C . . 109.5
H32B C32 H32C . . 109.5
P3 N1 P1 . . 120.1(6)
P2 N2 P3 . . 120.2(5)
P2 N3 P1 . . 122.1(6)
C6 N4 C10 . . 117.8(13)
C6 N4 Ag1 . 1_444 122.5(11)
C10 N4 Ag1 . 1_444 116.9(9)
C15 N5 C11 . . 116.8(11)
C15 N5 Ag2 . 1_465 121.4(9)
C11 N5 Ag2 . 1_465 121.5(8)
C26 N6 C30 . . 117.0(13)
C26 N6 Ag1 . 1_445 127.4(10)
C30 N6 Ag1 . 1_445 115.2(10)
C1 N7 C5 . . 117.3(11)
C1 N7 Ag2 . . 119.4(8)
C5 N7 Ag2 . . 122.6(9)
C25 N8 C21 . . 119.0(12)
C25 N8 Ag1 . . 126.0(10)
C21 N8 Ag1 . . 114.3(8)
C16 N9 C20 . . 115.7(12)
C31 N10 Ag1 . . 125.(2)
C2 O1 P1 . . 120.7(7)
C27 O2 P1 . . 121.6(8)
C22 O3 P3 . . 129.3(8)
C17 O4 P3 . . 118.6(7)
C7 O5 P2 . . 127.8(8)
C12 O6 P2 . . 125.6(6)
N3 P1 O1 . . 110.9(5)
N3 P1 N1 . . 117.3(5)
O1 P1 N1 . . 109.3(5)
N3 P1 O2 . . 108.7(5)
O1 P1 O2 . . 98.6(5)
N1 P1 O2 . . 110.5(5)
N3 P2 O5 . . 112.0(5)
N3 P2 O6 . . 111.0(5)
O5 P2 O6 . . 98.1(4)
N3 P2 N2 . . 118.4(5)
O5 P2 N2 . . 104.8(5)
O6 P2 N2 . . 110.4(5)
N1 P3 O3 . . 111.0(5)
N1 P3 N2 . . 118.4(5)
O3 P3 N2 . . 104.4(5)
N1 P3 O4 . . 110.5(5)
O3 P3 O4 . . 100.0(5)
N2 P3 O4 . . 110.8(5)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ag1 N8 . 2.264(11)
Ag1 N4 1_666 2.307(13)
Ag1 N6 1_665 2.436(12)
Ag1 N10 . 2.57(2)
Ag2 N7 . 2.192(10)
Ag2 N5 1_645 2.203(11)
B1 F1 . 1.24(5)
B1 F4 . 1.31(6)
B1 F3 . 1.39(6)
B1 F2 . 1.52(6)
B2 F6 . 1.27(4)
B2 F8 . 1.29(5)
B2 F5 . 1.30(6)
B2 F7 . 1.43(5)
C1 N7 . 1.330(17)
C1 C2 . 1.373(18)
C1 H1 . 0.93
C2 C3 . 1.357(18)
C2 O1 . 1.414(14)
C3 C4 . 1.37(2)
C3 H3 . 0.93
C4 C5 . 1.36(2)
C4 H4 . 0.93
C5 N7 . 1.387(19)
C5 H5 . 0.93
C6 N4 . 1.318(18)
C6 C7 . 1.378(19)
C6 H6 . 0.93
C7 C8 . 1.340(19)
C7 O5 . 1.385(15)
C8 C9 . 1.43(2)
C8 H8 . 0.93
C9 C10 . 1.37(2)
C9 H9 . 0.93
C10 N4 . 1.35(2)
C10 H10 . 0.93
C11 N5 . 1.344(16)
C11 C12 . 1.355(16)
C11 H11 . 0.93
C12 C13 . 1.375(17)
C12 O6 . 1.412(14)
C13 C14 . 1.39(2)
C13 H13 . 0.93
C14 C15 . 1.38(2)
C14 H14 . 0.93
C15 N5 . 1.243(19)
C15 H15 . 0.93
C16 N9 . 1.297(19)
C16 C17 . 1.392(17)
C16 H16 . 0.93
C17 C18 . 1.368(19)
C17 O4 . 1.402(14)
C18 C19 . 1.38(2)
C18 H18 . 0.93
C19 C20 . 1.37(2)
C19 H19 . 0.93
C20 N9 . 1.37(2)
C20 H20 . 0.93
C21 N8 . 1.348(17)
C21 C22 . 1.395(17)
C21 H21 . 0.93
C22 C23 . 1.374(17)
C22 O3 . 1.376(14)
C23 C24 . 1.39(2)
C23 H23 . 0.93
C24 C25 . 1.39(2)
C24 H24 . 0.93
C25 N8 . 1.316(19)
C25 H25 . 0.93
C26 N6 . 1.309(19)
C26 C27 . 1.365(19)
C26 H26 . 0.93
C27 C28 . 1.35(2)
C27 O2 . 1.396(17)
C28 C29 . 1.38(3)
C28 H28 . 0.93
C29 C30 . 1.35(3)
C29 H29 . 0.93
C30 N6 . 1.33(2)
C30 H30 . 0.93
C31 N10 . 1.05(3)
C31 C32 . 1.45(4)
C32 H32A . 0.96
C32 H32B . 0.96
C32 H32C . 0.96
N1 P3 . 1.583(9)
N1 P1 . 1.592(10)
N2 P2 . 1.583(9)
N2 P3 . 1.589(9)
N3 P2 . 1.561(10)
N3 P1 . 1.569(10)
N4 Ag1 1_444 2.307(13)
N5 Ag2 1_465 2.203(11)
N6 Ag1 1_445 2.436(12)
O1 P1 . 1.585(7)
O2 P1 . 1.604(9)
O3 P3 . 1.584(8)
O4 P3 . 1.590(8)
O5 P2 . 1.580(9)
O6 P2 . 1.582(8)
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C1 H1 F8 . 0.93 2.45 3.30(2) 152.2
C5 H5 F3 1_545 0.93 2.59 3.52(3) 171.1
C8 H8 O6 . 0.93 2.41 2.942(16) 116.5
C9 H9 F4 1_455 0.93 2.61 3.42(3) 145.9
C10 H10 F6 1_454 0.93 2.42 3.20(3) 141.8
C11 H11 F1 1_455 0.93 2.44 3.18(3) 136.4
C13 H13 F7 1_565 0.93 2.62 3.13(2) 114.5
C16 H16 F8 . 0.93 2.51 3.26(3) 138.2
C18 H18 F2 . 0.93 2.42 3.09(3) 128.5
C21 H21 F6 1_565 0.93 2.30 3.14(3) 149.4
C21 H21 F7 1_565 0.93 2.60 3.44(3) 150.7
C32 H32B F6 1_665 0.96 2.43 3.30(4) 150.6
C32 H32B F7 1_665 0.96 2.53 3.42(4) 154.5
