#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2200469.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2200469_Fobs loop_ _publ_author_name 'Hill, Nicholas J.' 'Levason, William' 'Reid, Gillian' 'Webster, Michael' _publ_section_title ; 1,2-Bis(diphenylarsino)ethane ; _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o700 _journal_page_last o701 _journal_volume 57 _journal_year 2001 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 100.341 _cell_angle_gamma 90.000 _cell_length_a 9.0780 _cell_length_b 5.7610 _cell_length_c 21.3720 _exptl_crystal_F_000 492.00 _reflns_d_resolution_high 0.8419 _[local]_cod_data_source_file cv6037Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' Ph2AsCH2CH2AsPh2' _shelx_refln_list_code 4 _shelx_f_calc_maximum 221.00 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' 'x+1/2, -y+1/2, z+1/2' '-x, -y, -z' '-x-1/2, y-1/2, -z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 46.62 48.28 3.13 o 4 0 0 109.92 77.66 4.25 o 6 0 0 357.03 413.18 18.91 o 8 0 0 647.54 605.69 27.68 o 10 0 0 1081.38 1073.87 41.50 o 1 1 0 217.16 236.29 7.21 o 2 1 0 5015.54 5050.96 41.37 o 3 1 0 1245.03 1296.67 22.48 o 4 1 0 5307.82 5461.28 54.66 o 5 1 0 10.97 2.42 7.91 o 6 1 0 3731.03 3765.14 54.40 o 7 1 0 197.89 182.48 11.40 o 8 1 0 612.44 618.93 28.22 o 9 1 0 13.74 4.37 15.67 o 10 1 0 207.18 194.46 12.11 o 0 2 0 7356.27 6714.84 53.60 o 1 2 0 1223.96 1224.60 21.36 o 2 2 0 3470.53 3368.29 38.87 o 3 2 0 1438.07 1473.98 27.34 o 4 2 0 2767.76 2975.94 42.73 o 5 2 0 116.88 183.44 9.45 o 6 2 0 264.20 288.61 17.12 o 7 2 0 38.98 11.31 14.05 o 8 2 0 670.95 646.22 31.08 o 9 2 0 88.78 84.64 8.63 o 10 2 0 575.18 578.68 34.26 o 1 3 0 130.89 164.50 10.89 o 2 3 0 1656.73 1668.70 31.66 o 3 3 0 833.63 876.71 24.73 o 4 3 0 3090.05 3144.83 49.25 o 5 3 0 958.01 975.27 29.91 o 6 3 0 1262.71 1286.95 36.29 o 7 3 0 354.56 395.91 22.49 o 8 3 0 742.19 752.67 32.99 o 9 3 0 152.87 147.16 10.13 o 0 4 0 2466.99 2385.92 43.33 o 1 4 0 2223.01 2122.73 40.60 o 2 4 0 1774.83 1682.23 37.24 o 3 4 0 618.99 664.84 24.87 o 4 4 0 7.49 -3.33 9.98 o 5 4 0 13.95 16.55 9.53 o 6 4 0 0.66 -6.61 11.95 o 7 4 0 171.06 183.48 11.53 o 8 4 0 232.76 234.87 15.45 o 1 5 0 998.25 1002.90 33.17 o 2 5 0 89.49 89.75 6.79 o 3 5 0 855.08 839.05 32.49 o 4 5 0 1307.05 1327.81 40.88 o 5 5 0 835.00 815.90 35.01 o 6 5 0 224.28 275.65 16.59 o 7 5 0 256.54 263.76 14.65 o 0 6 0 97.30 125.23 8.60 o 1 6 0 1363.10 1264.92 43.39 o 2 6 0 127.59 134.87 9.36 o 3 6 0 182.76 192.15 12.59 o 4 6 0 23.82 34.58 7.19 o 5 6 0 6.62 6.17 15.35 o -9 0 1 134.12 123.25 8.65 o -7 0 1 1975.19 1852.06 40.55 o -5 0 1 6110.34 6066.61 62.18 o -3 0 1 2730.65 2719.83 30.98 o -1 0 1 5503.35 5021.35 69.96 o 1 0 1 3139.81 3048.49 22.51 o 3 0 1 8150.27 8341.68 61.20 o 5 0 1 4246.36 4117.26 51.01 o 7 0 1 2383.40 2330.93 46.31 o 9 0 1 554.60 520.01 28.73 o -10 1 1 90.04 107.64 8.85 o -9 1 1 1041.61 1068.50 37.60 o -8 1 1 1.35 -1.36 10.22 o -7 1 1 1568.25 1609.74 38.18 o -6 1 1 59.25 68.40 5.45 o -5 1 1 485.88 524.71 18.38 o -4 1 1 1880.51 2179.53 33.04 o -3 1 1 1662.38 1643.55 25.29 o -2 1 1 640.70 690.95 14.16 o -1 1 1 3910.37 3725.83 30.44 o 0 1 1 10017.08 8750.13 83.31 o 1 1 1 31823.27 24913.24 227.24 o 2 1 1 4119.10 4167.48 37.51 o 3 1 1 4181.49 4130.76 42.23 o 4 1 1 2.33 7.34 5.92 o 5 1 1 960.23 963.52 24.96 o 6 1 1 1.44 7.34 9.13 o 7 1 1 112.81 122.82 7.07 o 8 1 1 66.66 70.29 6.28 o 9 1 1 627.76 638.51 30.65 o 10 1 1 37.43 46.72 7.98 o -10 2 1 8.05 11.10 15.77 o -9 2 1 262.28 236.40 12.84 o -8 2 1 210.54 220.60 14.21 o -7 2 1 406.63 405.28 22.28 o -6 2 1 295.30 269.08 17.00 o -5 2 1 4046.50 4093.96 55.11 o -4 2 1 253.42 236.78 12.69 o -3 2 1 9265.98 9209.34 74.13 o -2 2 1 865.98 840.33 19.01 o -1 2 1 169.76 136.67 7.96 o 0 2 1 126.16 131.46 6.99 o 1 2 1 263.22 291.30 10.67 o 2 2 1 5.63 6.82 4.58 o 3 2 1 2261.61 2310.32 34.74 o 4 2 1 951.40 1008.98 24.97 o 5 2 1 2917.41 2913.73 46.58 o 6 2 1 398.15 404.74 20.89 o 7 2 1 1771.36 1798.18 43.06 o 8 2 1 12.05 8.57 12.02 o 9 2 1 519.13 464.18 29.79 o 10 2 1 71.99 65.80 9.16 o -9 3 1 704.05 652.01 32.95 o -8 3 1 159.29 184.29 11.01 o -7 3 1 577.37 621.56 28.59 o -6 3 1 336.44 369.51 21.13 o -5 3 1 1.47 6.31 8.40 o -4 3 1 46.15 45.97 4.58 o -3 3 1 22.85 26.38 3.80 o -2 3 1 1122.33 1119.08 26.03 o -1 3 1 3593.53 3280.12 43.62 o 0 3 1 2259.86 2203.45 24.92 o 1 3 1 5302.41 5071.67 55.31 o 2 3 1 1250.71 1160.68 26.57 o 3 3 1 2881.47 2814.38 43.66 o 4 3 1 942.49 974.95 27.96 o 5 3 1 149.42 148.26 8.23 o 6 3 1 19.12 14.84 10.75 o 7 3 1 47.71 41.61 6.27 o 8 3 1 53.30 69.05 7.56 o 9 3 1 222.34 244.30 13.53 o -8 4 1 404.42 460.95 27.58 o -7 4 1 294.53 292.39 15.85 o -6 4 1 415.55 397.24 24.04 o -5 4 1 485.42 456.47 24.18 o -4 4 1 1407.07 1444.03 37.37 o -3 4 1 2001.41 1969.30 41.88 o -2 4 1 1251.85 1265.33 32.36 o -1 4 1 1573.75 1544.25 34.91 o 0 4 1 377.78 364.40 12.62 o 1 4 1 44.73 44.87 4.50 o 2 4 1 1100.60 1047.65 29.86 o 3 4 1 1041.06 1056.21 30.70 o 4 4 1 22.77 18.89 9.99 o 5 4 1 1531.57 1622.39 42.06 o 6 4 1 1036.47 1009.41 35.48 o 7 4 1 477.72 536.67 28.09 o 8 4 1 436.29 493.40 28.86 o -7 5 1 107.58 107.09 9.86 o -6 5 1 98.34 82.42 8.88 o -5 5 1 15.89 25.33 13.02 o -4 5 1 39.93 36.98 6.50 o -3 5 1 6.12 -0.22 11.56 o -2 5 1 70.65 72.42 6.54 o -1 5 1 659.21 684.81 27.03 o 0 5 1 2525.03 2403.50 47.69 o 1 5 1 831.70 773.54 28.39 o 2 5 1 1873.39 1833.15 44.25 o 3 5 1 280.75 304.51 19.96 o 4 5 1 317.19 306.28 16.07 o 5 5 1 81.05 73.94 9.02 o 6 5 1 9.22 23.28 13.42 o 7 5 1 8.43 4.59 16.97 o -5 6 1 265.25 262.12 17.22 o -4 6 1 1022.12 1015.24 41.22 o -3 6 1 129.95 132.55 9.22 o -2 6 1 300.07 314.44 17.03 o -1 6 1 29.61 33.67 6.69 o 0 6 1 668.75 667.18 27.64 o 1 6 1 19.19 33.30 6.83 o 2 6 1 185.62 190.24 11.12 o 3 6 1 1.01 20.84 12.72 o 4 6 1 576.39 606.70 30.99 o 5 6 1 126.49 127.95 10.17 o -10 0 2 811.18 736.69 34.73 o -8 0 2 2016.02 2048.76 46.18 o -6 0 2 556.02 515.17 19.70 o -4 0 2 3749.10 4057.15 44.35 o -2 0 2 398.51 446.40 10.43 o 2 0 2 36149.45 29468.68 272.92 o 4 0 2 4718.23 4542.39 48.94 o 6 0 2 2845.71 2774.75 46.40 o 8 0 2 1023.81 1000.90 33.03 o 10 0 2 351.58 338.50 19.39 o -10 1 2 237.69 233.85 13.42 o -9 1 2 21.34 25.32 13.76 o -8 1 2 685.09 716.61 28.46 o -7 1 2 412.75 424.80 20.86 o -6 1 2 824.51 805.64 24.55 o -5 1 2 286.03 299.06 14.25 o -4 1 2 9022.92 8938.83 72.40 o -3 1 2 265.32 308.44 11.69 o -2 1 2 3755.11 3691.18 34.60 o -1 1 2 388.30 378.19 9.31 o 0 1 2 9554.94 8933.45 211.00 o 1 1 2 272.74 308.16 9.08 o 2 1 2 0.49 4.03 4.11 o 3 1 2 5.09 -8.85 8.85 o 4 1 2 2170.32 2240.58 34.68 o 5 1 2 399.57 406.81 17.56 o 6 1 2 4163.42 4191.57 58.55 o 7 1 2 3.49 7.57 9.66 o 8 1 2 825.60 840.02 31.92 o 9 1 2 52.13 55.66 7.48 o 10 1 2 395.79 379.23 19.24 o -10 2 2 567.04 593.98 32.80 o -9 2 2 47.58 43.63 8.01 o -8 2 2 2185.29 2267.26 51.30 o -7 2 2 396.96 472.23 22.18 o -6 2 2 1397.93 1420.31 35.23 o -5 2 2 223.26 210.53 13.78 o -4 2 2 379.03 397.83 16.42 o -3 2 2 27.46 38.79 3.65 o -2 2 2 1110.05 1080.30 21.53 o -1 2 2 1782.23 1775.78 26.33 o 0 2 2 7041.06 6642.45 38.95 o 1 2 2 50.97 36.07 2.88 o 2 2 2 9388.46 9224.54 71.10 o 3 2 2 4329.48 4448.88 49.68 o 4 2 2 1688.66 1663.67 32.26 o 5 2 2 30.79 17.95 9.16 o 6 2 2 360.22 401.31 19.69 o 7 2 2 144.74 142.05 7.87 o 8 2 2 0.33 -6.41 13.20 o 9 2 2 65.87 53.52 8.26 o -9 3 2 16.15 -16.21 16.87 o -8 3 2 53.81 71.75 7.43 o -7 3 2 105.87 117.58 7.79 o -6 3 2 416.11 435.52 22.65 o -5 3 2 921.96 897.22 28.95 o -4 3 2 3099.25 3161.87 49.10 o -3 3 2 2279.45 2311.51 39.34 o -2 3 2 7032.60 6906.45 67.95 o -1 3 2 499.47 494.50 17.68 o 0 3 2 393.00 372.00 15.13 o 1 3 2 125.67 141.26 7.80 o 2 3 2 40.03 52.82 4.03 o 3 3 2 306.18 282.56 15.89 o 4 3 2 647.51 669.56 22.88 o 5 3 2 327.00 317.94 13.75 o 6 3 2 1133.73 1182.68 35.82 o 7 3 2 173.95 176.07 10.18 o 8 3 2 1085.23 1077.97 39.54 o 9 3 2 285.47 250.10 14.76 o -8 4 2 595.71 601.06 32.76 o -7 4 2 346.95 368.32 18.18 o -6 4 2 324.97 308.36 15.90 o -5 4 2 64.98 71.23 6.27 o -4 4 2 10.41 -12.46 12.46 o -3 4 2 12.65 16.14 4.45 o -2 4 2 13.31 12.50 4.13 o -1 4 2 285.33 285.07 16.37 o 0 4 2 1470.45 1418.32 23.69 o 1 4 2 2658.00 2526.65 44.94 o 2 4 2 1851.76 1815.36 39.48 o 3 4 2 2548.97 2560.07 47.87 o 4 4 2 1381.86 1393.79 37.33 o 5 4 2 106.08 117.20 7.52 o 6 4 2 43.17 50.34 6.74 o 7 4 2 56.83 77.85 8.02 o 8 4 2 10.28 -4.25 15.63 o -7 5 2 197.64 212.77 13.15 o -6 5 2 152.59 159.25 10.20 o -5 5 2 475.36 479.08 26.01 o -4 5 2 454.74 458.94 25.14 o -3 5 2 972.63 948.91 33.89 o -2 5 2 432.12 441.64 23.10 o -1 5 2 878.86 884.80 30.76 o 0 5 2 417.41 410.47 16.27 o 1 5 2 1149.89 1187.84 35.92 o 2 5 2 307.92 330.21 21.00 o 3 5 2 318.73 306.71 14.90 o 4 5 2 825.92 831.86 33.28 o 5 5 2 409.01 405.21 26.86 o 6 5 2 299.27 302.49 17.31 o 7 5 2 805.05 866.26 38.75 o -5 6 2 191.19 191.21 11.55 o -4 6 2 12.96 27.00 14.88 o -3 6 2 40.21 36.38 7.55 o -2 6 2 30.02 38.87 7.46 o -1 6 2 149.14 164.08 9.67 o 0 6 2 197.42 181.93 7.81 o 1 6 2 1020.96 942.17 37.08 o 2 6 2 210.72 214.16 11.63 o 3 6 2 1051.83 1036.57 40.38 o 4 6 2 3.73 -16.42 16.42 o -9 0 3 290.08 276.56 15.96 o -7 0 3 390.24 353.46 19.44 o -5 0 3 3493.17 3365.25 45.16 o -3 0 3 9191.09 8922.71 63.55 o -1 0 3 5109.82 5007.02 34.42 o 1 0 3 7361.49 7056.07 116.13 o 3 0 3 1.73 23.05 2.70 o 5 0 3 1059.27 1051.87 26.80 o 7 0 3 1684.19 1593.39 41.10 o 9 0 3 1414.10 1342.81 43.56 o -10 1 3 31.22 14.69 14.94 o -9 1 3 490.41 534.54 26.84 o -8 1 3 57.76 58.82 6.65 o -7 1 3 4529.81 4597.35 65.67 o -6 1 3 13.09 15.06 4.29 o -5 1 3 1400.86 1377.36 28.91 o -4 1 3 256.86 273.19 12.43 o -3 1 3 1575.31 1638.54 25.40 o -2 1 3 194.14 220.64 8.89 o -1 1 3 256.46 266.50 8.40 o 0 1 3 57.32 49.53 2.07 o 1 1 3 3899.07 3766.81 34.21 o 2 1 3 2518.70 2725.80 31.57 o 3 1 3 19062.50 18271.25 110.88 o 4 1 3 3225.92 3410.58 44.11 o 5 1 3 1938.62 1889.69 35.97 o 6 1 3 750.05 746.60 26.22 o 7 1 3 1396.02 1340.48 36.71 o 8 1 3 86.12 68.90 7.91 o 9 1 3 133.67 129.10 9.61 o 10 1 3 57.29 56.48 8.93 o -10 2 3 191.24 174.00 10.69 o -9 2 3 190.82 178.91 11.28 o -8 2 3 168.08 176.57 10.58 o -7 2 3 17.39 17.01 5.60 o -6 2 3 320.00 332.86 18.00 o -5 2 3 1627.55 1630.81 33.98 o -4 2 3 327.33 326.11 15.12 o -3 2 3 5579.47 5639.74 56.16 o -2 2 3 471.79 447.57 14.79 o -1 2 3 8006.01 7704.02 61.13 o 0 2 3 958.90 960.08 17.21 o 1 2 3 3622.75 3609.43 39.81 o 2 2 3 303.28 335.56 12.91 o 3 2 3 227.47 258.24 12.98 o 4 2 3 9.48 7.52 6.64 o 5 2 3 2697.25 2828.55 46.61 o 6 2 3 887.61 923.24 29.18 o 7 2 3 824.39 894.88 31.62 o 8 2 3 6.71 7.89 9.30 o 9 2 3 794.74 876.70 36.82 o -9 3 3 1034.94 959.60 40.84 o -8 3 3 734.93 794.18 33.46 o -7 3 3 1532.45 1529.56 43.06 o -6 3 3 255.75 248.28 12.52 o -5 3 3 315.75 361.53 18.64 o -4 3 3 704.71 712.40 23.77 o -3 3 3 888.09 932.39 25.72 o -2 3 3 97.17 130.52 7.30 o -1 3 3 51.62 43.48 3.74 o 0 3 3 669.19 695.23 14.44 o 1 3 3 4091.21 4127.55 50.35 o 2 3 3 2229.77 2226.64 37.81 o 3 3 3 3526.84 3586.29 50.73 o 4 3 3 1621.72 1697.35 37.03 o 5 3 3 1530.26 1559.38 37.93 o 6 3 3 40.88 52.34 6.20 o 7 3 3 108.12 112.25 8.01 o 8 3 3 49.46 57.93 7.89 o 9 3 3 19.05 23.88 7.70 o -8 4 3 0.32 7.74 13.85 o -7 4 3 48.00 53.69 7.74 o -6 4 3 130.72 116.29 9.06 o -5 4 3 222.16 289.42 18.93 o -4 4 3 1048.89 1086.56 33.16 o -3 4 3 1136.89 1135.36 32.18 o -2 4 3 2697.20 2697.25 47.29 o -1 4 3 2006.54 1879.03 39.04 o 0 4 3 721.14 698.16 19.33 o 1 4 3 514.65 502.35 21.30 o 2 4 3 207.77 205.11 10.59 o 3 4 3 725.79 738.46 27.13 o 4 4 3 8.08 16.62 9.03 o 5 4 3 601.74 649.05 28.53 o 6 4 3 367.64 396.76 24.41 o 7 4 3 814.72 773.53 35.46 o 8 4 3 376.89 412.99 19.89 o -7 5 3 266.92 278.51 17.87 o -6 5 3 254.44 260.47 16.82 o -5 5 3 528.27 538.91 28.21 o -4 5 3 364.63 393.83 23.06 o -3 5 3 0.98 -1.11 9.96 o -2 5 3 64.69 79.83 6.54 o -1 5 3 75.04 63.83 7.64 o 0 5 3 100.87 112.14 5.50 o 1 5 3 290.39 284.94 18.50 o 2 5 3 1548.52 1561.84 42.01 o 3 5 3 407.92 396.46 24.24 o 4 5 3 1091.00 1126.70 39.83 o 5 5 3 503.42 513.05 29.37 o 6 5 3 479.77 506.31 29.34 o -5 6 3 1.13 4.95 13.27 o -4 6 3 470.23 495.34 29.10 o -3 6 3 376.76 337.81 17.97 o -2 6 3 607.58 641.20 31.67 o -1 6 3 188.59 222.35 11.99 o 0 6 3 792.02 773.51 23.98 o 1 6 3 116.10 120.01 8.84 o 2 6 3 548.67 502.62 30.05 o 3 6 3 43.68 48.19 8.12 o 4 6 3 131.46 155.97 10.16 o -10 0 4 396.39 353.40 17.92 o -8 0 4 2042.45 1941.78 44.70 o -6 0 4 3213.35 3246.99 48.97 o -4 0 4 3639.82 3659.90 42.64 o -2 0 4 223.27 211.08 8.11 o 0 0 4 131.15 162.88 5.18 o 2 0 4 262.82 235.37 9.79 o 4 0 4 7948.45 8180.08 72.50 o 6 0 4 6931.15 6794.01 77.28 o 8 0 4 381.34 356.58 17.27 o 10 0 4 92.92 83.45 9.34 o -10 1 4 1110.81 982.44 39.86 o -9 1 4 46.52 42.60 7.14 o -8 1 4 275.41 297.11 19.18 o -7 1 4 53.81 46.78 5.79 o -6 1 4 159.81 175.65 9.99 o -5 1 4 71.24 71.58 4.64 o -4 1 4 3154.78 3143.29 40.67 o -3 1 4 30.93 30.09 2.81 o -2 1 4 13357.22 11846.20 189.15 o -1 1 4 6448.41 6413.50 47.96 o 0 1 4 2298.43 2289.13 19.65 o 1 1 4 1529.60 1696.64 23.69 o 2 1 4 9766.41 9597.02 69.04 o 3 1 4 128.78 166.97 9.93 o 4 1 4 64.61 64.00 4.54 o 5 1 4 305.22 356.68 17.27 o 6 1 4 1446.94 1473.60 36.18 o 7 1 4 18.21 18.23 5.83 o 8 1 4 990.36 948.31 35.29 o 9 1 4 94.97 93.97 8.63 o 10 1 4 594.45 585.34 34.21 o -10 2 4 32.68 13.29 18.78 o -9 2 4 2.97 11.49 11.97 o -8 2 4 1300.43 1329.97 40.61 o -7 2 4 716.06 729.71 28.18 o -6 2 4 3764.64 3789.11 56.96 o -5 2 4 434.86 427.60 18.19 o -4 2 4 2021.65 1922.80 34.21 o -3 2 4 28.97 15.31 3.22 o -2 2 4 2187.88 2249.93 32.47 o -1 2 4 892.86 983.34 20.60 o 0 2 4 38.53 25.83 2.13 o 1 2 4 691.18 704.93 17.90 o 2 2 4 8413.78 8450.13 70.38 o 3 2 4 228.63 207.42 12.61 o 4 2 4 5952.79 5947.94 65.38 o 5 2 4 1791.71 1730.70 36.93 o 6 2 4 912.31 927.52 30.24 o 7 2 4 61.59 65.66 6.58 o 8 2 4 209.67 197.70 11.77 o 9 2 4 80.56 105.78 9.06 o -9 3 4 191.63 195.14 12.50 o -8 3 4 435.10 441.34 26.53 o -7 3 4 102.10 100.06 7.84 o -6 3 4 0.67 -1.29 11.12 o -5 3 4 1269.50 1207.45 32.58 o -4 3 4 985.24 981.44 27.81 o -3 3 4 166.09 145.56 8.25 o -2 3 4 3990.78 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