#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2201434.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2201434_Fobs loop_ _publ_author_name 'Lynch, Daniel E.' 'McClenaghan, Ian' _publ_section_title ; Ethyl 4-phenyl-2-(N-pyrrolyl)-1,3-thiazole-5-carboxylate ; _journal_issue 7 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o745 _journal_page_last o746 _journal_volume 58 _journal_year 2002 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 91.979 _cell_angle_gamma 90.000 _cell_length_a 10.2375 _cell_length_b 3.9460 _cell_length_c 35.0750 _exptl_crystal_F_000 624.00 _reflns_d_resolution_high 0.8409 _[local]_cod_data_source_file cv6119Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title 'Ethyl 4-phenyl-2-(N-pyrrole)-1,3-thiazole-5-carboxylate' _shelx_refln_list_code 4 _shelx_f_calc_maximum 175.78 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 5296.27 6523.85 476.71 o 3 0 0 711.12 857.56 63.59 o 4 0 0 53.51 74.47 9.07 o 5 0 0 7928.38 10951.94 441.33 o 6 0 0 1800.86 2506.36 160.07 o 7 0 0 927.31 1156.18 58.55 o 8 0 0 2621.60 2994.31 337.26 o 9 0 0 130.02 148.69 28.74 o 10 0 0 95.50 67.37 30.13 o 11 0 0 20.26 28.67 43.00 o 12 0 0 439.53 389.30 52.09 o 1 1 0 1.98 -0.89 3.04 o 2 1 0 23.58 20.50 4.56 o 3 1 0 126.59 136.74 10.72 o 4 1 0 333.53 358.14 57.87 o 5 1 0 334.60 327.74 54.14 o 6 1 0 172.04 209.21 17.16 o 7 1 0 41.78 53.38 16.98 o 8 1 0 326.99 347.00 25.99 o 9 1 0 376.26 387.10 39.47 o 10 1 0 53.13 81.40 30.37 o 11 1 0 467.86 432.64 57.39 o 0 2 0 1139.58 1098.73 70.55 o 1 2 0 987.10 789.63 67.16 o 2 2 0 106.84 122.59 12.11 o 3 2 0 257.47 248.69 13.00 o 4 2 0 196.62 210.40 17.83 o 5 2 0 781.26 815.70 31.09 o 6 2 0 6.74 -7.93 13.49 o 7 2 0 38.92 42.96 12.99 o 8 2 0 100.08 105.00 23.54 o 9 2 0 119.10 125.96 23.46 o 10 2 0 62.29 42.10 26.43 o 11 2 0 70.46 85.76 45.29 o 1 3 0 134.05 131.83 14.19 o 2 3 0 16.26 9.33 9.88 o 3 3 0 367.73 388.34 39.78 o 4 3 0 332.91 357.05 39.80 o 5 3 0 6.01 -12.34 24.43 o 6 3 0 7.59 -42.74 28.50 o 7 3 0 34.53 51.29 51.51 o 8 3 0 7.61 14.55 50.80 o 9 3 0 37.16 -10.11 43.88 o 0 4 0 37.21 82.84 23.63 o 1 4 0 7.23 -12.12 16.75 o 2 4 0 91.93 132.14 23.72 o 3 4 0 55.80 116.04 23.59 o 4 4 0 1.71 -7.36 20.54 o 5 4 0 37.19 13.51 27.20 o 6 4 0 2.00 3.00 50.38 o -11 1 1 38.38 23.55 39.67 o -10 1 1 65.61 34.98 22.87 o -9 1 1 523.20 503.11 33.42 o -8 1 1 64.93 47.18 16.39 o -7 1 1 110.50 96.92 12.33 o -6 1 1 57.89 57.13 13.43 o -5 1 1 2081.46 2204.24 85.54 o -4 1 1 517.24 539.58 51.26 o -3 1 1 414.57 330.51 28.68 o -2 1 1 880.89 799.34 70.37 o -1 1 1 3065.44 2282.16 149.05 o 0 1 1 5561.19 4022.57 329.22 o 1 1 1 10919.08 8002.44 579.27 o 2 1 1 0.14 7.29 4.19 o 3 1 1 147.91 147.83 16.37 o 4 1 1 623.23 641.63 32.78 o 5 1 1 475.34 461.29 31.03 o 6 1 1 954.43 971.73 55.62 o 7 1 1 121.04 110.05 16.03 o 8 1 1 75.91 86.45 29.83 o 9 1 1 237.64 160.33 27.54 o 10 1 1 6.60 25.30 24.35 o 11 1 1 0.01 32.04 24.96 o -11 2 1 166.83 129.77 37.05 o -10 2 1 24.97 20.23 21.70 o -9 2 1 388.18 342.46 35.62 o -8 2 1 150.41 153.26 22.72 o -7 2 1 535.58 456.42 53.78 o -6 2 1 3.60 -7.63 14.92 o -5 2 1 173.87 169.39 28.86 o -4 2 1 394.39 367.56 23.22 o -3 2 1 252.83 231.34 24.63 o -2 2 1 0.57 2.68 7.29 o -1 2 1 47.91 37.00 7.32 o 0 2 1 387.49 252.94 59.30 o 1 2 1 629.18 488.85 48.02 o 2 2 1 300.69 244.05 20.26 o 3 2 1 208.02 204.20 19.40 o 4 2 1 365.20 349.78 33.75 o 5 2 1 53.15 57.19 11.34 o 6 2 1 77.70 85.53 15.82 o 7 2 1 88.26 109.22 21.82 o 8 2 1 667.61 605.29 39.79 o 9 2 1 78.77 64.73 25.43 o 10 2 1 79.35 61.85 31.91 o -9 3 1 476.62 468.92 45.45 o -8 3 1 90.19 83.89 45.67 o -7 3 1 185.15 190.85 50.87 o -6 3 1 411.66 420.44 28.04 o -5 3 1 0.06 19.75 24.46 o -4 3 1 93.43 125.17 27.38 o -3 3 1 574.71 526.32 58.07 o -2 3 1 3.45 6.74 10.28 o -1 3 1 203.55 160.57 17.97 o 0 3 1 515.58 432.32 58.92 o 1 3 1 21.67 10.07 11.13 o 2 3 1 471.50 443.53 59.17 o 3 3 1 6.11 1.12 12.45 o 4 3 1 897.82 943.84 72.84 o 5 3 1 408.97 415.58 42.90 o 6 3 1 97.22 80.96 32.25 o 7 3 1 543.41 591.30 46.55 o 8 3 1 97.92 135.98 59.48 o 9 3 1 501.92 464.80 59.17 o -6 4 1 1.26 -53.18 41.04 o -5 4 1 128.69 188.62 42.13 o -4 4 1 472.07 518.99 36.47 o -3 4 1 0.05 20.51 22.56 o -2 4 1 269.68 262.19 23.70 o -1 4 1 150.77 165.89 25.12 o 0 4 1 3.44 4.77 15.92 o 1 4 1 71.23 90.98 29.42 o 2 4 1 187.42 189.69 67.73 o 3 4 1 288.47 292.63 27.48 o 4 4 1 34.97 43.68 23.82 o 5 4 1 180.09 175.57 29.34 o 6 4 1 404.96 409.67 53.18 o -12 0 2 155.31 98.88 33.06 o -11 0 2 209.99 116.45 54.56 o -10 0 2 70.53 69.59 28.20 o -9 0 2 5426.00 5872.05 468.06 o -8 0 2 1922.64 2275.57 190.39 o -7 0 2 1542.90 2017.02 171.70 o -6 0 2 96.11 94.12 13.67 o -5 0 2 3644.60 5297.52 318.11 o -4 0 2 505.24 558.98 29.88 o -3 0 2 395.93 548.85 28.09 o 2 0 2 5010.52 5952.07 270.40 o 3 0 2 749.33 1036.75 66.76 o 4 0 2 838.90 979.58 49.80 o 5 0 2 4319.61 5991.28 465.04 o 6 0 2 114.67 142.69 14.60 o 7 0 2 1794.83 2326.36 128.10 o 8 0 2 7.00 28.28 20.90 o 9 0 2 15.10 8.88 15.63 o 10 0 2 523.26 559.06 40.25 o 11 0 2 255.67 217.87 34.11 o 12 0 2 120.14 62.22 48.63 o -11 1 2 18.77 -18.77 37.32 o -10 1 2 370.56 316.84 31.40 o -9 1 2 122.43 127.21 21.19 o -8 1 2 4.18 12.86 14.38 o -7 1 2 52.06 86.51 16.08 o -6 1 2 58.92 86.36 17.42 o -5 1 2 0.70 5.27 8.69 o -4 1 2 67.29 99.97 8.51 o -3 1 2 727.91 762.15 26.70 o -2 1 2 619.52 582.97 39.71 o -1 1 2 6112.61 5745.91 504.23 o 0 1 2 435.62 338.77 23.12 o 1 1 2 584.37 596.46 45.85 o 2 1 2 1274.74 1306.39 120.26 o 3 1 2 27.55 23.30 5.92 o 4 1 2 2176.47 2943.22 127.19 o 5 1 2 2576.69 2808.83 262.07 o 6 1 2 693.61 844.34 42.60 o 7 1 2 192.70 207.53 18.56 o 8 1 2 361.42 354.18 22.37 o 9 1 2 654.74 617.52 34.83 o 10 1 2 2387.94 2218.42 148.75 o 11 1 2 122.52 127.25 31.04 o -11 2 2 122.51 166.01 41.58 o -10 2 2 125.55 177.06 22.72 o -9 2 2 872.88 826.20 72.38 o -8 2 2 714.38 615.95 69.83 o -7 2 2 23.43 30.94 12.84 o -6 2 2 175.00 191.36 21.04 o -5 2 2 276.35 320.14 21.35 o -4 2 2 1774.23 1998.85 166.97 o -3 2 2 803.38 876.71 71.54 o -2 2 2 303.47 302.87 27.05 o -1 2 2 1221.25 1053.68 92.45 o 0 2 2 10.39 9.14 4.99 o 1 2 2 31.08 27.24 5.32 o 2 2 2 371.44 345.43 28.13 o 3 2 2 44.89 26.75 8.73 o 4 2 2 983.08 1033.14 85.70 o 5 2 2 102.90 83.98 12.08 o 6 2 2 82.78 95.33 17.76 o 7 2 2 4.05 -5.32 16.25 o 8 2 2 58.38 47.39 22.91 o 9 2 2 31.80 9.84 23.97 o 10 2 2 8.97 -9.68 35.05 o -9 3 2 718.40 757.69 66.40 o -8 3 2 63.05 38.98 39.29 o -7 3 2 2.85 29.50 25.20 o -6 3 2 37.32 12.88 38.86 o -5 3 2 204.69 300.08 67.11 o -4 3 2 0.02 0.75 13.61 o -3 3 2 22.88 41.78 12.14 o -2 3 2 3.43 -6.65 9.20 o -1 3 2 124.09 131.31 12.91 o 0 3 2 96.23 76.84 22.20 o 1 3 2 130.34 110.35 16.36 o 2 3 2 7.36 23.79 13.17 o 3 3 2 248.17 263.41 30.36 o 4 3 2 23.05 13.10 13.87 o 5 3 2 65.16 48.06 20.42 o 6 3 2 248.42 200.31 27.50 o 7 3 2 610.71 711.97 58.22 o 8 3 2 269.93 261.08 27.53 o 9 3 2 220.55 197.99 45.51 o -6 4 2 336.56 392.95 42.34 o -5 4 2 17.35 12.16 31.56 o -4 4 2 23.90 36.72 17.69 o -3 4 2 3.02 31.32 21.30 o -2 4 2 0.14 8.76 18.63 o -1 4 2 51.63 76.01 17.83 o 0 4 2 10.53 15.71 12.08 o 1 4 2 9.38 -6.87 15.92 o 2 4 2 41.97 33.38 16.99 o 3 4 2 14.91 12.61 18.77 o 4 4 2 194.29 228.38 29.74 o 5 4 2 213.63 274.78 28.86 o 6 4 2 85.12 61.38 35.45 o -11 1 3 0.03 14.50 31.68 o -10 1 3 85.28 81.64 23.40 o -9 1 3 11.93 14.81 28.55 o -8 1 3 16.27 19.13 17.30 o -7 1 3 1542.21 1684.62 75.51 o -6 1 3 407.49 397.40 33.55 o -5 1 3 1227.20 1254.65 65.93 o -4 1 3 137.51 124.22 10.04 o -3 1 3 1.08 -8.39 5.88 o -2 1 3 2773.38 2194.05 191.16 o -1 1 3 392.05 326.68 28.88 o 0 1 3 1852.54 1347.04 106.69 o 1 1 3 516.77 410.13 57.18 o 2 1 3 1152.34 1130.48 116.77 o 3 1 3 52.47 53.64 7.54 o 4 1 3 1272.16 1270.79 237.83 o 5 1 3 13.33 24.74 13.63 o 6 1 3 15.63 -4.30 9.74 o 7 1 3 180.30 184.45 19.15 o 8 1 3 239.09 214.17 20.29 o 9 1 3 102.78 54.06 20.45 o 10 1 3 77.50 56.94 26.17 o 11 1 3 17.87 47.16 38.22 o -11 2 3 85.73 91.87 28.15 o -10 2 3 166.82 88.57 25.89 o -9 2 3 43.84 46.08 26.19 o -8 2 3 364.54 378.27 28.73 o -7 2 3 349.31 312.45 45.87 o -6 2 3 45.17 54.30 13.40 o -5 2 3 687.81 548.11 56.24 o -4 2 3 25.74 27.58 10.99 o -3 2 3 174.08 137.99 11.14 o -2 2 3 413.21 356.21 36.70 o -1 2 3 426.96 311.72 32.43 o 0 2 3 1.26 4.21 5.28 o 1 2 3 61.25 47.77 7.84 o 2 2 3 779.52 620.23 56.89 o 3 2 3 19.33 25.63 7.90 o 4 2 3 1614.36 1562.48 75.69 o 5 2 3 69.19 77.25 11.66 o 6 2 3 111.81 125.26 19.31 o 7 2 3 58.33 54.32 17.14 o 8 2 3 48.35 47.37 33.19 o 9 2 3 94.27 42.44 40.30 o 10 2 3 394.52 369.42 40.55 o -9 3 3 181.85 179.88 37.00 o -8 3 3 44.84 85.75 34.39 o -7 3 3 277.87 333.29 39.35 o -6 3 3 244.95 261.37 33.46 o -5 3 3 783.30 646.41 149.92 o -4 3 3 1076.42 1058.34 340.56 o -3 3 3 4.00 -19.34 12.90 o -2 3 3 869.23 842.86 98.39 o -1 3 3 882.27 744.56 91.78 o 0 3 3 292.33 297.39 27.75 o 1 3 3 389.85 360.80 28.88 o 2 3 3 7.82 -11.93 11.86 o 3 3 3 240.72 237.28 28.09 o 4 3 3 78.96 39.08 22.97 o 5 3 3 44.49 51.03 18.42 o 6 3 3 519.51 525.19 33.19 o 7 3 3 0.09 0.35 27.21 o 8 3 3 197.88 178.98 31.73 o 9 3 3 162.48 142.46 47.42 o -6 4 3 183.74 198.84 48.78 o -5 4 3 1.67 -14.28 58.71 o -4 4 3 137.68 155.08 25.97 o -3 4 3 277.91 310.72 29.49 o -2 4 3 17.07 25.54 20.87 o -1 4 3 199.00 217.55 20.54 o 0 4 3 101.39 66.96 17.94 o 1 4 3 300.81 354.85 27.99 o 2 4 3 12.85 32.89 19.17 o 3 4 3 2.14 10.05 18.42 o 4 4 3 65.39 111.58 24.76 o 5 4 3 12.34 5.06 27.10 o 6 4 3 123.97 43.31 45.33 o -12 0 4 726.15 444.64 93.46 o -11 0 4 647.43 527.24 88.57 o -10 0 4 574.88 572.80 43.00 o -9 0 4 478.08 456.22 53.30 o -8 0 4 620.82 689.00 42.84 o -7 0 4 739.64 1012.02 66.47 o -6 0 4 2196.85 3118.12 200.27 o -5 0 4 3146.20 4123.83 168.48 o -4 0 4 4892.23 6564.75 397.86 o -3 0 4 214.13 259.49 24.63 o -2 0 4 581.84 699.10 40.48 o -1 0 4 2866.54 3761.86 140.65 o 1 0 4 1.15 2.73 1.41 o 2 0 4 2339.63 2615.58 259.17 o 3 0 4 1749.00 2299.91 151.64 o 4 0 4 1308.77 1512.82 74.13 o 5 0 4 4057.37 6180.94 466.24 o 6 0 4 72.67 125.96 35.45 o 7 0 4 22.12 33.73 13.22 o 8 0 4 0.58 -12.01 19.00 o 9 0 4 34.27 44.61 15.82 o 10 0 4 62.69 80.68 30.08 o 11 0 4 139.12 98.36 46.20 o 12 0 4 656.59 503.65 89.35 o -11 1 4 310.86 284.60 36.25 o -10 1 4 0.04 -37.11 24.74 o -9 1 4 214.00 212.51 24.15 o -8 1 4 42.68 19.04 17.68 o -7 1 4 35.19 41.27 15.89 o -6 1 4 124.67 145.96 12.94 o -5 1 4 1162.95 1493.62 66.99 o -4 1 4 4243.83 5456.55 290.81 o -3 1 4 248.89 246.43 15.15 o -2 1 4 437.30 508.43 36.40 o -1 1 4 796.93 674.47 51.79 o 0 1 4 4613.83 532.26 1496.39 o 2 1 4 3203.82 2988.87 352.03 o 3 1 4 440.25 501.07 33.06 o 4 1 4 3294.29 3811.39 699.99 o 5 1 4 74.38 90.32 13.12 o 6 1 4 2226.91 2391.96 147.99 o 7 1 4 268.09 266.45 16.66 o 8 1 4 2220.02 2417.78 110.58 o 9 1 4 658.77 670.05 57.44 o 10 1 4 0.19 22.64 25.32 o 11 1 4 290.76 273.90 39.12 o -10 2 4 471.01 399.60 47.90 o -9 2 4 464.30 444.24 40.44 o -8 2 4 2.23 17.70 19.08 o -7 2 4 1.02 6.44 16.09 o -6 2 4 92.20 110.50 15.83 o -5 2 4 276.65 283.82 21.63 o -4 2 4 353.39 332.39 24.60 o -3 2 4 156.83 204.15 14.97 o -2 2 4 116.72 112.74 14.51 o -1 2 4 1026.25 953.62 93.84 o 0 2 4 37.59 27.26 4.92 o 1 2 4 252.07 245.09 25.79 o 2 2 4 424.54 396.98 33.14 o 3 2 4 114.48 131.59 10.61 o 4 2 4 1004.44 1016.48 129.12 o 5 2 4 394.97 452.10 49.83 o 6 2 4 261.66 261.00 20.16 o 7 2 4 97.89 136.17 18.14 o 8 2 4 182.17 175.58 19.68 o 9 2 4 107.06 89.34 26.16 o 10 2 4 69.61 49.59 30.64 o -9 3 4 77.60 86.54 30.31 o -8 3 4 194.84 193.62 42.16 o -7 3 4 127.98 106.38 34.63 o -6 3 4 359.51 390.19 56.76 o -5 3 4 38.63 35.98 27.86 o -4 3 4 258.89 188.47 37.55 o -3 3 4 188.80 222.57 17.13 o -2 3 4 47.22 60.14 11.04 o -1 3 4 101.30 106.34 16.35 o 0 3 4 165.99 121.19 13.19 o 1 3 4 473.38 394.27 24.85 o 2 3 4 290.99 233.33 16.80 o 3 3 4 2.05 5.86 12.68 o 4 3 4 9.52 0.17 16.13 o 5 3 4 0.07 1.19 14.71 o 6 3 4 13.05 17.73 19.74 o 7 3 4 2.41 -10.04 26.91 o 8 3 4 263.27 382.18 47.27 o 9 3 4 4.18 -28.79 30.12 o -6 4 4 169.14 178.11 34.09 o -5 4 4 8.39 17.63 27.00 o -4 4 4 119.23 116.57 27.99 o -3 4 4 47.51 92.46 26.12 o -2 4 4 86.19 113.89 19.08 o -1 4 4 45.43 76.45 19.08 o 0 4 4 2.68 6.47 16.18 o 1 4 4 19.10 19.83 17.15 o 2 4 4 3.50 5.84 19.50 o 3 4 4 1.25 20.30 19.50 o 4 4 4 228.85 291.02 26.42 o 5 4 4 7.26 3.84 25.20 o 6 4 4 34.33 10.50 85.13 o -11 1 5 38.80 15.97 43.81 o -10 1 5 183.31 153.86 25.06 o -9 1 5 244.41 228.15 28.84 o -8 1 5 2080.18 1897.80 98.13 o -7 1 5 192.10 168.94 18.63 o -6 1 5 254.82 247.34 17.26 o -5 1 5 0.43 15.60 8.01 o -4 1 5 29.77 38.64 9.92 o -3 1 5 72.33 51.47 7.03 o -2 1 5 2800.09 2376.77 172.12 o -1 1 5 725.58 585.46 32.79 o 0 1 5 30898.58 458.72 100.56 o 1 1 5 91.41 107.65 14.24 o 2 1 5 72.90 63.63 7.97 o 3 1 5 0.28 -5.93 6.56 o 4 1 5 49.11 46.77 9.51 o 5 1 5 1355.23 1227.59 201.50 o 6 1 5 454.55 480.57 27.66 o 7 1 5 37.41 37.28 14.78 o 8 1 5 327.36 299.76 27.75 o 9 1 5 0.02 -30.24 20.16 o 10 1 5 11.55 10.12 27.34 o 11 1 5 69.72 14.75 28.77 o -10 2 5 105.71 70.39 44.50 o -9 2 5 3.14 9.96 45.13 o -8 2 5 222.25 253.98 28.94 o -7 2 5 646.09 694.83 53.51 o -6 2 5 47.95 58.12 13.65 o -5 2 5 599.90 571.96 29.73 o -4 2 5 1382.59 1359.42 88.97 o -3 2 5 95.95 90.64 10.37 o -2 2 5 5.49 9.67 7.47 o -1 2 5 1085.35 994.91 97.92 o 0 2 5 17.73 13.07 4.04 o 1 2 5 899.69 679.82 72.62 o 2 2 5 147.28 144.49 18.74 o 3 2 5 289.56 269.70 29.63 o 4 2 5 365.31 369.25 28.92 o 5 2 5 505.53 441.86 47.62 o 6 2 5 416.04 407.17 24.78 o 7 2 5 0.03 -20.60 17.82 o 8 2 5 1613.80 1587.89 123.78 o 9 2 5 1155.73 1126.06 60.53 o 10 2 5 32.58 2.40 32.79 o -9 3 5 115.99 132.31 53.37 o -8 3 5 419.29 382.33 43.30 o -7 3 5 18.04 -28.88 54.18 o -6 3 5 304.07 331.83 60.89 o -5 3 5 1.82 -22.14 15.04 o -4 3 5 164.51 177.58 40.23 o -3 3 5 1395.67 1585.84 130.43 o -2 3 5 2.09 -12.23 14.96 o -1 3 5 197.86 182.07 18.02 o 0 3 5 162.44 172.82 13.12 o 1 3 5 10.50 13.08 10.22 o 2 3 5 165.95 155.64 20.27 o 3 3 5 3.18 -7.44 16.44 o 4 3 5 437.15 445.17 36.51 o 5 3 5 218.58 227.47 19.41 o 6 3 5 92.87 73.96 22.46 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