#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/26/2202671.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2202671
loop_
_publ_author_name
'Sakai, Ken'
'Kurashima, Mai'
_publ_section_title
;
 [μ-2,3,5,6-Tetrakis(2-pyridyl)pyrazine]bis[chloroplatinum(II)]
 bis[trichloro(dimethyl sulfoxide-κS)platinate(II)]
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m411
_journal_page_last               m413
_journal_paper_doi               10.1107/S1600536803011541
_journal_volume                  59
_journal_year                    2003
_chemical_formula_iupac
'[Pt2 Cl2 (C24 H16 N6)] [Pt Cl3 (C2 H6 O1 S1)]2'
_chemical_formula_moiety         'C24 H16 Cl2 N6 Pt2 2+, 2C2 H6 Cl3 O Pt S 1-'
_chemical_formula_sum            'C28 H28 Cl8 N6 O2 Pt4 S2'
_chemical_formula_weight         1608.64
_chemical_name_systematic
;
[μ-2,3,5,6-Tetrakis(2-pyridyl)pyrazine]bis[chloroplatinum(II)]
bis[trichloro(dimethylsulfoxide-\kS)platinate(II)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                94.085(2)
_cell_angle_beta                 105.321(2)
_cell_angle_gamma                100.954(2)
_cell_formula_units_Z            2
_cell_length_a                   10.0868(11)
_cell_length_b                   12.9476(14)
_cell_length_c                   16.5057(19)
_cell_measurement_reflns_used    818
_cell_measurement_temperature    296.0(10)
_cell_measurement_theta_max      19.06
_cell_measurement_theta_min      2.52
_cell_volume                     2024.3(4)
_computing_cell_refinement       'SAINT (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'KENX (Sakai, 2002)'
_computing_publication_material
;
SHELXL97, TEXSAN (Molecular Structure Corporation, 1999),
KENX and ORTEPII (Johnson, 1976)
;
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      296.0(10)
_diffrn_detector_area_resol_mean 8.366
_diffrn_measured_fraction_theta_full 0.966
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measurement_device       'Bruker SMART APEX CCD-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0880
_diffrn_reflns_av_sigmaI/netI    0.1994
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9820
_diffrn_reflns_theta_full        23.27
_diffrn_reflns_theta_max         23.27
_diffrn_reflns_theta_min         1.29
_diffrn_standards_decay_%        'no decay, variation 0'
_diffrn_standards_interval_time  120
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    14.446
_exptl_absorpt_correction_T_max  0.86810
_exptl_absorpt_correction_T_min  0.51126
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   '(XPREP in SAINT; Bruker, 2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.639
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1468
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.548
_refine_diff_density_min         -1.145
_refine_ls_extinction_coef       not_refined
_refine_ls_extinction_expression not_refined
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.913
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     455
_refine_ls_number_reflns         5638
_refine_ls_number_restraints     516
_refine_ls_restrained_S_all      0.879
_refine_ls_R_factor_all          0.1510
_refine_ls_R_factor_gt           0.0785
_refine_ls_shift/su_max          <0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'calc w = 1/[σ²(Fo²)]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0979
_refine_ls_wR_factor_ref         0.1171
_reflns_number_gt                3198
_reflns_number_total             5638
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            lh6065.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               2202671
_cod_database_fobs_code          2202671
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Pt1 -0.07386(12) 0.65039(8) 0.44332(7) 0.0288(3) Uani d U 1 . . Pt
Pt2 -0.25499(12) 0.53161(9) 0.03547(7) 0.0334(3) Uani d U 1 . . Pt
Pt3 0.05194(13) 0.85989(9) 0.25251(8) 0.0382(3) Uani d U 1 . . Pt
Pt4 -0.49029(12) 0.25699(9) 0.25938(7) 0.0322(3) Uani d U 1 . . Pt
Cl1 -0.0098(8) 0.6901(5) 0.5869(4) 0.045(2) Uani d U 1 . . Cl
Cl2 -0.3209(8) 0.4879(6) -0.1071(4) 0.056(2) Uani d U 1 . . Cl
Cl3 -0.0695(8) 0.8785(7) 0.1172(5) 0.062(3) Uani d U 1 . . Cl
Cl4 0.1616(8) 0.7434(6) 0.1950(5) 0.053(2) Uani d U 1 . . Cl
Cl5 0.1785(9) 0.8377(6) 0.3852(5) 0.059(2) Uani d U 1 . . Cl
Cl6 -0.6873(9) 0.2354(6) 0.3081(6) 0.066(3) Uani d U 1 . . Cl
Cl7 -0.4423(9) 0.4365(6) 0.2991(5) 0.058(2) Uani d U 1 . . Cl
Cl8 -0.2887(7) 0.2848(6) 0.2190(5) 0.050(2) Uani d U 1 . . Cl
S1 -0.0597(8) 0.9645(5) 0.3081(5) 0.043(2) Uani d U 1 . . S
S2 -0.5377(10) 0.0878(7) 0.2138(7) 0.071(3) Uani d U 1 . . S
O1 -0.184(2) 0.9102(14) 0.3277(13) 0.062(6) Uani d U 1 . . O
O2 -0.453(2) 0.0460(16) 0.1631(16) 0.084(7) Uani d U 1 . . O
N1 -0.124(2) 0.6167(15) 0.3204(13) 0.023(4) Uani d U 1 . . N
N2 -0.201(2) 0.5659(15) 0.1562(13) 0.023(5) Uani d U 1 . . N
N3 -0.252(2) 0.7057(14) 0.4175(13) 0.025(5) Uani d U 1 . . N
N4 -0.372(2) 0.6385(16) 0.0414(14) 0.040(5) Uani d U 1 . . N
N5 -0.120(2) 0.4377(16) 0.0674(14) 0.037(5) Uani d U 1 . . N
N6 0.092(2) 0.5901(15) 0.4349(13) 0.026(5) Uani d U 1 . . N
C1 -0.316(3) 0.7424(18) 0.4695(16) 0.030(5) Uani d U 1 . . C
H1 -0.2704 0.7535 0.5273 0.036 Uiso calc R 1 . . H
C2 -0.446(3) 0.7649(19) 0.4414(17) 0.036(6) Uani d U 1 . . C
H2 -0.4863 0.7924 0.4804 0.043 Uiso calc R 1 . . H
C3 -0.516(3) 0.749(2) 0.3603(18) 0.042(6) Uani d U 1 . . C
H3 -0.6043 0.7650 0.3426 0.050 Uiso calc R 1 . . H
C4 -0.458(3) 0.7067(19) 0.3010(18) 0.036(6) Uani d U 1 . . C
H4 -0.5072 0.6890 0.2440 0.044 Uiso calc R 1 . . H
C5 -0.317(3) 0.6929(19) 0.3338(17) 0.032(5) Uani d U 1 . . C
C6 -0.235(3) 0.6468(18) 0.2775(16) 0.025(5) Uani d U 1 . . C
C7 -0.265(3) 0.6354(18) 0.1881(17) 0.029(5) Uani d U 1 . . C
C8 -0.352(3) 0.685(2) 0.1205(17) 0.032(5) Uani d U 1 . . C
C9 -0.400(3) 0.7773(19) 0.1339(17) 0.036(6) Uani d U 1 . . C
H9 -0.3788 0.8109 0.1889 0.043 Uiso calc R 1 . . H
C10 -0.477(3) 0.820(2) 0.0688(18) 0.043(6) Uani d U 1 . . C
H10 -0.5089 0.8815 0.0785 0.051 Uiso calc R 1 . . H
C11 -0.507(3) 0.767(2) -0.0129(19) 0.051(7) Uani d U 1 . . C
H11 -0.5647 0.7895 -0.0591 0.061 Uiso calc R 1 . . H
C12 -0.447(3) 0.682(2) -0.0228(18) 0.044(6) Uani d U 1 . . C
H12 -0.4592 0.6519 -0.0779 0.052 Uiso calc R 1 . . H
C13 -0.097(3) 0.369(2) 0.014(2) 0.053(7) Uani d U 1 . . C
H13 -0.1319 0.3697 -0.0438 0.064 Uiso calc R 1 . . H
C14 -0.018(3) 0.292(2) 0.0439(18) 0.044(6) Uani d U 1 . . C
H14 -0.0014 0.2432 0.0058 0.053 Uiso calc R 1 . . H
C15 0.032(3) 0.292(2) 0.1270(18) 0.041(6) Uani d U 1 . . C
H15 0.0821 0.2408 0.1471 0.049 Uiso calc R 1 . . H
C16 0.011(3) 0.3649(19) 0.1822(18) 0.038(6) Uani d U 1 . . C
H16 0.0472 0.3657 0.2403 0.046 Uiso calc R 1 . . H
C17 -0.066(3) 0.4385(19) 0.1512(17) 0.030(5) Uani d U 1 . . C
C18 -0.101(3) 0.5257(19) 0.2015(17) 0.029(5) Uani d U 1 . . C
C19 -0.045(3) 0.5659(19) 0.2905(17) 0.029(5) Uani d U 1 . . C
C20 0.086(3) 0.552(2) 0.3533(18) 0.035(5) Uani d U 1 . . C
C21 0.204(3) 0.5319(19) 0.3366(18) 0.038(6) Uani d U 1 . . C
H21 0.2069 0.5200 0.2809 0.045 Uiso calc R 1 . . H
C22 0.318(3) 0.529(2) 0.4010(19) 0.043(6) Uani d U 1 . . C
H22 0.3953 0.5085 0.3893 0.052 Uiso calc R 1 . . H
C23 0.321(3) 0.555(2) 0.4825(19) 0.043(6) Uani d U 1 . . C
H23 0.3991 0.5542 0.5272 0.052 Uiso calc R 1 . . H
C24 0.207(3) 0.5835(19) 0.4963(17) 0.034(6) Uani d U 1 . . C
H24 0.2076 0.5995 0.5522 0.040 Uiso calc R 1 . . H
C25 0.049(3) 1.041(2) 0.403(2) 0.082(11) Uani d U 1 . . C
H25A 0.0024 1.0924 0.4208 0.122 Uiso calc R 1 . . H
H25B 0.1359 1.0766 0.3939 0.122 Uiso calc R 1 . . H
H25C 0.0696 0.9954 0.4460 0.122 Uiso calc R 1 . . H
C26 -0.098(3) 1.069(2) 0.248(2) 0.066(10) Uani d U 1 . . C
H26A -0.1883 1.0460 0.2064 0.099 Uiso calc R 1 . . H
H26B -0.0269 1.0891 0.2196 0.099 Uiso calc R 1 . . H
H26C -0.1000 1.1294 0.2847 0.099 Uiso calc R 1 . . H
C27 -0.717(3) 0.040(3) 0.148(2) 0.084(11) Uani d U 1 . . C
H27A -0.7412 0.0899 0.1090 0.125 Uiso calc R 1 . . H
H27B -0.7797 0.0330 0.1831 0.125 Uiso calc R 1 . . H
H27C -0.7255 -0.0274 0.1169 0.125 Uiso calc R 1 . . H
C28 -0.549(5) 0.017(3) 0.297(3) 0.147(18) Uani d U 1 . . C
H28A -0.6187 0.0372 0.3212 0.221 Uiso calc R 1 . . H
H28B -0.4595 0.0324 0.3389 0.221 Uiso calc R 1 . . H
H28C -0.5761 -0.0572 0.2767 0.221 Uiso calc R 1 . . H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
1 0 8
3 1 5
0 3 -6
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 Pt1 N6 . 81.2(8) yes
N1 Pt1 N3 . 83.4(8) yes
N6 Pt1 N3 . 164.6(8) yes
N1 Pt1 Cl1 . 178.6(6) yes
N6 Pt1 Cl1 . 97.6(6) yes
N3 Pt1 Cl1 . 97.8(6) yes
N1 Pt1 Pt1 2_566 106.0(6) ?
N6 Pt1 Pt1 2_566 50.9(6) ?
N3 Pt1 Pt1 2_566 136.5(5) ?
Cl1 Pt1 Pt1 2_566 73.60(17) ?
N2 Pt2 N5 . 80.5(9) yes
N2 Pt2 N4 . 82.1(9) yes
N5 Pt2 N4 . 162.5(9) yes
N2 Pt2 Cl2 . 179.0(6) yes
N5 Pt2 Cl2 . 99.1(7) yes
N4 Pt2 Cl2 . 98.4(7) yes
N2 Pt2 Pt2 2_465 102.7(6) ?
N5 Pt2 Pt2 2_465 132.4(6) ?
N4 Pt2 Pt2 2_465 53.2(6) ?
Cl2 Pt2 Pt2 2_465 76.8(2) ?
S1 Pt3 Cl5 . 90.6(3) yes
S1 Pt3 Cl3 . 91.6(3) yes
Cl5 Pt3 Cl3 . 177.7(3) yes
S1 Pt3 Cl4 . 177.3(3) yes
Cl5 Pt3 Cl4 . 89.0(3) yes
Cl3 Pt3 Cl4 . 88.7(3) yes
S2 Pt4 Cl8 . 91.7(3) yes
S2 Pt4 Cl7 . 176.6(4) yes
Cl8 Pt4 Cl7 . 87.0(3) yes
S2 Pt4 Cl6 . 90.9(3) yes
Cl8 Pt4 Cl6 . 176.5(3) yes
Cl7 Pt4 Cl6 . 90.6(3) yes
O1 S1 C25 . 106.2(14) ?
O1 S1 C26 . 110.3(13) ?
C25 S1 C26 . 98.9(15) ?
O1 S1 Pt3 . 114.9(8) ?
C25 S1 Pt3 . 111.9(11) ?
C26 S1 Pt3 . 113.2(11) ?
O2 S2 C28 . 111.9(18) ?
O2 S2 C27 . 103.5(16) ?
C28 S2 C27 . 98.0(18) ?
O2 S2 Pt4 . 119.8(10) ?
C28 S2 Pt4 . 108.8(15) ?
C27 S2 Pt4 . 112.6(11) ?
C19 N1 C6 . 127(2) ?
C19 N1 Pt1 . 116.8(18) ?
C6 N1 Pt1 . 116.2(16) ?
C18 N2 C7 . 125(2) ?
C18 N2 Pt2 . 118.4(17) ?
C7 N2 Pt2 . 116.9(17) ?
C1 N3 C5 . 118(2) ?
C1 N3 Pt1 . 129.5(18) ?
C5 N3 Pt1 . 111.8(16) ?
C8 N4 C12 . 117(2) ?
C8 N4 Pt2 . 113.7(18) ?
C12 N4 Pt2 . 128.7(19) ?
C13 N5 C17 . 120(2) ?
C13 N5 Pt2 . 124(2) ?
C17 N5 Pt2 . 114.8(17) ?
C24 N6 C20 . 116(2) ?
C24 N6 Pt1 . 129.5(17) ?
C20 N6 Pt1 . 114.1(17) ?
N3 C1 C2 . 122(3) ?
C3 C2 C1 . 121(3) ?
C2 C3 C4 . 120(3) ?
C3 C4 C5 . 116(3) ?
N3 C5 C4 . 122(2) ?
N3 C5 C6 . 114(2) ?
C4 C5 C6 . 123(2) ?
N1 C6 C7 . 118(2) ?
N1 C6 C5 . 114(2) ?
C7 C6 C5 . 128(2) ?
N2 C7 C6 . 114(2) ?
N2 C7 C8 . 112(2) ?
C6 C7 C8 . 134(2) ?
N4 C8 C9 . 121(2) ?
N4 C8 C7 . 114(2) ?
C9 C8 C7 . 125(3) ?
C10 C9 C8 . 122(3) ?
C9 C10 C11 . 117(3) ?
C12 C11 C10 . 118(3) ?
N4 C12 C11 . 125(3) ?
N5 C13 C14 . 121(3) ?
C15 C14 C13 . 119(3) ?
C14 C15 C16 . 120(3) ?
C15 C16 C17 . 119(3) ?
N5 C17 C16 . 121(2) ?
N5 C17 C18 . 112(2) ?
C16 C17 C18 . 127(3) ?
N2 C18 C19 . 118(2) ?
N2 C18 C17 . 112(2) ?
C19 C18 C17 . 130(2) ?
N1 C19 C18 . 114(2) ?
N1 C19 C20 . 116(2) ?
C18 C19 C20 . 130(2) ?
C21 C20 N6 . 119(3) ?
C21 C20 C19 . 127(3) ?
N6 C20 C19 . 111(2) ?
C22 C21 C20 . 120(3) ?
C21 C22 C23 . 121(3) ?
C24 C23 C22 . 118(3) ?
C23 C24 N6 . 125(3) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pt1 N1 . 1.95(2) yes
Pt1 N6 . 2.008(18) yes
Pt1 N3 . 2.017(19) yes
Pt1 Cl1 . 2.278(7) yes
Pt2 N2 . 1.92(2) yes
Pt2 N5 . 1.99(2) yes
Pt2 N4 . 1.99(2) yes
Pt2 Cl2 . 2.268(7) yes
Pt3 S1 . 2.212(7) yes
Pt3 Cl5 . 2.294(8) yes
Pt3 Cl3 . 2.300(8) yes
Pt3 Cl4 . 2.320(7) yes
Pt4 S2 . 2.184(8) yes
Pt4 Cl8 . 2.276(7) yes
Pt4 Cl7 . 2.292(7) yes
Pt4 Cl6 . 2.310(8) yes
Pt1 Pt2 . 6.4792(17) yes
Pt1 Pt3 . 4.5726(16) yes
Pt2 Pt2 2_465 4.662(2) yes
Pt1 Pt1 2_566 4.760(2) yes
Pt2 Pt3 . 5.2396(16) yes
Pt2 Pt2 2_565 5.758(2) yes
Pt2 Pt4 . 5.9359(16) yes
Pt1 Pt4 . 5.9778(16) yes
Pt1 C24 2_566 3.40(3) yes
S1 O1 . 1.445(18) ?
S1 C25 . 1.76(3) ?
S1 C26 . 1.78(3) ?
S2 O2 . 1.49(2) ?
S2 C28 . 1.72(4) ?
S2 C27 . 1.81(3) ?
N1 C19 . 1.29(3) ?
N1 C6 . 1.30(3) ?
N2 C18 . 1.31(3) ?
N2 C7 . 1.36(3) ?
N3 C1 . 1.31(3) ?
N3 C5 . 1.35(3) ?
N4 C8 . 1.35(3) ?
N4 C12 . 1.36(3) ?
N5 C13 . 1.30(3) ?
N5 C17 . 1.34(3) ?
N6 C24 . 1.35(3) ?
N6 C20 . 1.38(3) ?
C1 C2 . 1.37(3) ?
C2 C3 . 1.32(3) ?
C3 C4 . 1.39(3) ?
C4 C5 . 1.43(3) ?
C5 C6 . 1.56(3) ?
C6 C7 . 1.42(3) ?
C7 C8 . 1.49(3) ?
C8 C9 . 1.40(3) ?
C9 C10 . 1.37(3) ?
C10 C11 . 1.40(4) ?
C11 C12 . 1.37(3) ?
C13 C14 . 1.42(3) ?
C14 C15 . 1.33(3) ?
C15 C16 . 1.36(3) ?
C16 C17 . 1.38(3) ?
C17 C18 . 1.50(3) ?
C18 C19 . 1.45(3) ?
C19 C20 . 1.50(3) ?
C20 C21 . 1.36(3) ?
C21 C22 . 1.35(3) ?
C22 C23 . 1.36(3) ?
C23 C24 . 1.33(3) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
Cl5 Pt3 S1 O1 . -87.0(11)
Cl3 Pt3 S1 O1 . 93.3(11)
Cl5 Pt3 S1 C25 . 34.2(12)
Cl3 Pt3 S1 C25 . -145.6(12)
Cl5 Pt3 S1 C26 . 144.9(12)
Cl3 Pt3 S1 C26 . -34.8(12)
Cl8 Pt4 S2 O2 . -9.2(13)
Cl6 Pt4 S2 O2 . 173.2(13)
Cl8 Pt4 S2 C28 . 121.2(16)
Cl6 Pt4 S2 C28 . -56.3(16)
Cl8 Pt4 S2 C27 . -131.3(14)
Cl6 Pt4 S2 C27 . 51.2(14)
N6 Pt1 N1 C19 . 6.1(18)
N3 Pt1 N1 C19 . -175.4(19)
Pt1 Pt1 N1 C19 2_566 -38.8(19)
N6 Pt1 N1 C6 . -174.7(18)
N3 Pt1 N1 C6 . 3.8(17)
Pt1 Pt1 N1 C6 2_566 140.4(16)
N5 Pt2 N2 C18 . 5.8(18)
N4 Pt2 N2 C18 . -173.3(19)
Pt2 Pt2 N2 C18 2_465 137.4(17)
N5 Pt2 N2 C7 . -177.5(18)
N4 Pt2 N2 C7 . 3.3(17)
Pt2 Pt2 N2 C7 2_465 -46.0(17)
N1 Pt1 N3 C1 . 175(2)
N6 Pt1 N3 C1 . -180(3)
Cl1 Pt1 N3 C1 . -6(2)
Pt1 Pt1 N3 C1 2_566 68(2)
N1 Pt1 N3 C5 . 0.5(17)
N6 Pt1 N3 C5 . 6(4)
Cl1 Pt1 N3 C5 . 179.9(16)
Pt1 Pt1 N3 C5 2_566 -105.8(16)
N2 Pt2 N4 C8 . 3.4(18)
N5 Pt2 N4 C8 . 1(4)
Cl2 Pt2 N4 C8 . -177.6(17)
Pt2 Pt2 N4 C8 2_465 115.9(19)
N2 Pt2 N4 C12 . 171(2)
N5 Pt2 N4 C12 . 169(2)
Cl2 Pt2 N4 C12 . -10(2)
Pt2 Pt2 N4 C12 2_465 -76(2)
N2 Pt2 N5 C13 . 174(2)
N4 Pt2 N5 C13 . 177(2)
Cl2 Pt2 N5 C13 . -5(2)
Pt2 Pt2 N5 C13 2_465 76(2)
N2 Pt2 N5 C17 . 3.5(17)
N4 Pt2 N5 C17 . 6(4)
Cl2 Pt2 N5 C17 . -175.5(17)
Pt2 Pt2 N5 C17 2_465 -95.1(18)
N1 Pt1 N6 C24 . 176(2)
N3 Pt1 N6 C24 . 170(2)
Cl1 Pt1 N6 C24 . -4(2)
Pt1 Pt1 N6 C24 2_566 -65(2)
N1 Pt1 N6 C20 . -3.0(17)
N3 Pt1 N6 C20 . -9(4)
Cl1 Pt1 N6 C20 . 177.7(16)
Pt1 Pt1 N6 C20 2_566 116.0(19)
C5 N3 C1 C2 . 2(4)
Pt1 N3 C1 C2 . -171.8(18)
N3 C1 C2 C3 . 1(4)
C1 C2 C3 C4 . 0(4)
C2 C3 C4 C5 . -5(4)
C1 N3 C5 C4 . -7(4)
Pt1 N3 C5 C4 . 167.6(19)
C1 N3 C5 C6 . -179(2)
Pt1 N3 C5 C6 . -4(3)
C3 C4 C5 N3 . 9(4)
C3 C4 C5 C6 . 180(2)
C19 N1 C6 C7 . -8(4)
Pt1 N1 C6 C7 . 172.6(16)
C19 N1 C6 C5 . 172(2)
Pt1 N1 C6 C5 . -7(3)
N3 C5 C6 N1 . 7(3)
C4 C5 C6 N1 . -164(2)
N3 C5 C6 C7 . -172(2)
C4 C5 C6 C7 . 16(4)
C18 N2 C7 C6 . -11(3)
Pt2 N2 C7 C6 . 172.1(15)
C18 N2 C7 C8 . 168(2)
Pt2 N2 C7 C8 . -9(3)
N1 C6 C7 N2 . 19(3)
C5 C6 C7 N2 . -162(2)
N1 C6 C7 C8 . -160(3)
C5 C6 C7 C8 . 19(4)
C12 N4 C8 C9 . -4(4)
Pt2 N4 C8 C9 . 165.2(19)
C12 N4 C8 C7 . -178(2)
Pt2 N4 C8 C7 . -9(3)
N2 C7 C8 N4 . 11(3)
C6 C7 C8 N4 . -170(3)
N2 C7 C8 C9 . -162(2)
C6 C7 C8 C9 . 17(4)
N4 C8 C9 C10 . 5(4)
C7 C8 C9 C10 . 179(2)
C8 C9 C10 C11 . 0(4)
C9 C10 C11 C12 . -5(4)
C8 N4 C12 C11 . -1(4)
Pt2 N4 C12 C11 . -169(2)
C10 C11 C12 N4 . 6(4)
C17 N5 C13 C14 . 2(4)
Pt2 N5 C13 C14 . -168.7(18)
N5 C13 C14 C15 . 0(4)
C13 C14 C15 C16 . -2(4)
C14 C15 C16 C17 . 1(4)
C13 N5 C17 C16 . -2(4)
Pt2 N5 C17 C16 . 169.5(18)
C13 N5 C17 C18 . 178(2)
Pt2 N5 C17 C18 . -11(3)
C15 C16 C17 N5 . 0(4)
C15 C16 C17 C18 . -180(2)
C7 N2 C18 C19 . -7(4)
Pt2 N2 C18 C19 . 169.9(16)
C7 N2 C18 C17 . 171(2)
Pt2 N2 C18 C17 . -13(3)
N5 C17 C18 N2 . 15(3)
C16 C17 C18 N2 . -165(2)
N5 C17 C18 C19 . -168(2)
C16 C17 C18 C19 . 12(4)
C6 N1 C19 C18 . -10(4)
Pt1 N1 C19 C18 . 169.0(16)
C6 N1 C19 C20 . 173(2)
Pt1 N1 C19 C20 . -8(3)
N2 C18 C19 N1 . 17(3)
C17 C18 C19 N1 . -159(2)
N2 C18 C19 C20 . -166(2)
C17 C18 C19 C20 . 17(4)
C24 N6 C20 C21 . -13(4)
Pt1 N6 C20 C21 . 165.2(19)
C24 N6 C20 C19 . -179(2)
Pt1 N6 C20 C19 . 0(3)
N1 C19 C20 C21 . -159(3)
C18 C19 C20 C21 . 25(4)
N1 C19 C20 N6 . 5(3)
C18 C19 C20 N6 . -171(2)
N6 C20 C21 C22 . 13(4)
C19 C20 C21 C22 . 175(2)
C20 C21 C22 C23 . -6(4)
C21 C22 C23 C24 . 1(4)
C22 C23 C24 N6 . -2(4)
C20 N6 C24 C23 . 8(4)
Pt1 N6 C24 C23 . -170(2)
