#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2203163.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2203163_Fobs loop_ _publ_author_name 'Rybakov, Victor B.' 'Bush, Alexander A.' 'Babaev, Eugene V.' 'Aslanov, Leonid A.' _publ_section_title ; 4,6-Dimethyl-5-nitro-1H-pyridin-2-one ; _journal_issue 2 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o201 _journal_page_last o203 _journal_volume 60 _journal_year 2004 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 100.760 _cell_angle_gamma 90.000 _cell_length_a 9.7677 _cell_length_b 5.8751 _cell_length_c 13.7295 _exptl_crystal_F_000 352.00 _reflns_d_resolution_high 0.8208 _[local]_cod_data_source_file ci63202sup2.hkl _[local]_cod_data_source_block 2 #BEGIN Tags that were not found in dictionaries: _shelx_title ' bush2 in P 21/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 136.49 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 5.32 8.38 1.39 o 4 0 0 146.63 144.60 5.89 o 6 0 0 11.59 13.61 2.46 o 8 0 0 6.22 9.15 4.42 o 10 0 0 18.22 18.50 2.46 o 1 1 0 241.38 269.60 11.78 o 2 1 0 4.87 6.59 1.47 o 3 1 0 1271.96 1201.45 21.61 o 4 1 0 133.33 115.04 3.93 o 5 1 0 0.04 1.47 1.47 o 6 1 0 152.62 156.28 5.89 o 7 1 0 33.51 34.62 2.95 o 8 1 0 0.02 -0.20 1.63 o 9 1 0 39.57 41.04 3.44 o 10 1 0 0.46 -0.49 2.46 o 11 1 0 14.61 15.39 4.42 o 0 2 0 537.44 483.17 5.89 o 1 2 0 627.55 686.07 8.35 o 2 2 0 443.39 448.65 12.28 o 3 2 0 760.67 781.81 34.86 o 4 2 0 151.41 150.62 11.29 o 5 2 0 41.55 43.94 2.36 o 6 2 0 408.51 397.85 6.87 o 7 2 0 98.34 97.23 3.47 o 8 2 0 1.06 -0.39 2.95 o 9 2 0 19.83 20.43 2.46 o 10 2 0 12.64 14.38 2.95 o 11 2 0 2.55 2.67 1.47 o 1 3 0 59.74 56.47 2.08 o 2 3 0 1339.78 1362.89 8.66 o 3 3 0 71.03 77.35 4.42 o 4 3 0 4.29 -1.47 3.44 o 5 3 0 1.27 -1.47 4.42 o 6 3 0 0.20 -0.49 3.44 o 7 3 0 18.28 16.75 2.78 o 8 3 0 4.72 6.38 2.46 o 9 3 0 0.21 0.49 2.46 o 10 3 0 14.25 15.24 1.39 o 0 4 0 2.93 5.89 2.95 o 1 4 0 315.48 326.80 9.33 o 2 4 0 132.37 129.70 3.47 o 3 4 0 95.21 87.94 6.87 o 4 4 0 101.17 95.42 3.93 o 5 4 0 56.28 59.07 3.47 o 6 4 0 57.22 55.07 3.47 o 7 4 0 26.14 28.88 4.42 o 8 4 0 10.16 7.37 2.08 o 9 4 0 2.52 3.44 2.46 o 1 5 0 7.61 9.33 2.78 o 2 5 0 54.85 52.96 6.87 o 3 5 0 1.19 -2.78 2.78 o 4 5 0 9.18 8.84 2.36 o 5 5 0 37.73 40.26 2.78 o 6 5 0 3.70 2.95 2.08 o 7 5 0 0.06 2.16 1.63 o 8 5 0 12.93 15.65 5.89 o 0 6 0 363.60 332.92 8.84 o 1 6 0 16.85 16.58 2.78 o 2 6 0 6.54 8.76 5.40 o 3 6 0 18.62 17.45 2.36 o 4 6 0 0.79 2.62 1.76 o 5 6 0 14.31 14.00 5.89 o 6 6 0 0.33 1.37 2.95 o 1 7 0 3.40 0.39 1.96 o 2 7 0 0.30 -0.39 2.95 o -11 0 1 5.92 5.89 1.96 o -9 0 1 228.70 248.46 7.86 o -7 0 1 0.00 0.00 2.95 o -5 0 1 8.41 10.80 1.96 o -3 0 1 869.17 782.70 6.87 o -1 0 1 126.68 145.35 1.96 o 1 0 1 10839.65 10447.17 101.15 o 3 0 1 1708.95 1638.08 10.80 o 5 0 1 109.15 111.96 4.91 o 7 0 1 57.40 66.78 3.93 o 9 0 1 13.70 13.75 2.95 o 11 0 1 0.00 -0.98 0.98 o -11 1 1 4.79 3.93 1.96 o -10 1 1 6.08 5.89 1.96 o -9 1 1 275.69 277.92 7.86 o -8 1 1 236.98 245.52 6.87 o -7 1 1 8.40 6.87 1.96 o -6 1 1 230.35 231.77 5.89 o -5 1 1 465.51 413.45 6.87 o -4 1 1 0.74 -1.96 1.96 o -3 1 1 527.46 537.19 5.89 o -2 1 1 168.93 173.82 3.93 o -1 1 1 35.50 35.35 1.96 o 0 1 1 996.55 1085.18 6.87 o 1 1 1 806.14 853.41 5.89 o 2 1 1 6.58 5.89 1.96 o 3 1 1 402.23 397.74 5.89 o 4 1 1 11.06 12.77 1.96 o 5 1 1 519.51 485.14 7.86 o 6 1 1 0.04 0.00 1.96 o 7 1 1 127.59 118.83 4.91 o 8 1 1 38.96 35.35 3.93 o 9 1 1 37.30 35.35 2.95 o 10 1 1 10.41 8.84 1.96 o 11 1 1 1.83 0.00 0.98 o -11 2 1 11.21 13.75 1.96 o -10 2 1 11.65 13.75 1.96 o -9 2 1 21.35 16.70 2.95 o -8 2 1 60.11 63.83 3.93 o -7 2 1 0.80 0.98 2.95 o -6 2 1 285.15 304.44 6.87 o -5 2 1 6.42 5.89 2.95 o -4 2 1 0.07 0.00 1.96 o -3 2 1 689.36 766.99 7.86 o -2 2 1 8.79 7.86 1.96 o -1 2 1 91.27 99.19 3.93 o 0 2 1 251.75 219.98 3.93 o 1 2 1 5.92 4.91 1.96 o 2 2 1 897.72 807.25 7.86 o 3 2 1 465.91 486.12 6.87 o 4 2 1 197.29 199.36 4.91 o 5 2 1 58.82 57.94 3.93 o 6 2 1 1.19 1.96 2.95 o 7 2 1 724.32 698.25 11.78 o 8 2 1 197.87 188.56 5.89 o 9 2 1 25.94 24.55 1.96 o 10 2 1 2.32 1.96 0.98 o 11 2 1 1.99 1.96 0.98 o -10 3 1 14.56 17.68 1.96 o -9 3 1 1.11 -1.96 1.96 o -8 3 1 7.21 4.91 2.95 o -7 3 1 45.23 41.25 3.93 o -6 3 1 49.89 49.10 4.91 o -5 3 1 8.55 7.86 2.95 o -4 3 1 1.76 0.98 2.95 o -3 3 1 305.45 315.24 6.87 o -2 3 1 7.35 6.87 2.95 o -1 3 1 40.00 42.23 2.95 o 0 3 1 156.83 155.17 3.93 o 1 3 1 2.07 7.86 2.95 o 2 3 1 538.34 525.40 7.86 o 3 3 1 331.29 312.30 6.87 o 4 3 1 68.82 60.89 3.93 o 5 3 1 101.42 105.08 4.91 o 6 3 1 10.36 12.77 3.93 o 7 3 1 4.31 2.95 2.95 o 8 3 1 0.85 2.95 2.95 o 9 3 1 0.62 0.98 0.98 o 10 3 1 0.99 1.96 0.98 o -9 4 1 0.00 0.00 1.96 o -8 4 1 13.43 15.71 2.95 o -7 4 1 4.73 3.93 2.95 o -6 4 1 14.88 8.84 3.93 o -5 4 1 25.87 25.53 3.93 o -4 4 1 1.32 1.96 2.95 o -3 4 1 24.12 30.44 3.93 o -2 4 1 37.96 40.26 3.93 o -1 4 1 0.24 -0.98 2.95 o 0 4 1 106.39 96.24 4.91 o 1 4 1 126.55 119.81 4.91 o 2 4 1 36.52 37.32 3.93 o 3 4 1 34.22 38.30 3.93 o 4 4 1 128.93 125.70 5.89 o 5 4 1 0.38 -0.98 2.95 o 6 4 1 29.83 30.44 3.93 o 7 4 1 90.49 91.33 5.89 o 8 4 1 3.92 6.87 1.96 o 9 4 1 0.40 0.00 1.96 o -8 5 1 73.85 74.64 4.91 o -7 5 1 13.60 8.84 2.95 o -6 5 1 42.73 46.16 3.93 o -5 5 1 16.39 14.73 3.93 o -4 5 1 17.56 14.73 3.93 o -3 5 1 29.42 35.35 4.91 o -2 5 1 0.62 -0.98 3.93 o -1 5 1 133.23 124.72 5.89 o 0 5 1 3.64 4.91 3.93 o 1 5 1 4.88 0.00 3.93 o 2 5 1 10.58 14.73 3.93 o 3 5 1 8.35 3.93 3.93 o 4 5 1 2.08 3.93 2.95 o 5 5 1 33.60 33.39 3.93 o 6 5 1 0.80 3.93 2.95 o 7 5 1 5.68 5.89 1.96 o 8 5 1 0.91 2.95 1.96 o -6 6 1 0.21 -2.95 2.95 o -5 6 1 5.47 6.87 3.93 o -4 6 1 0.04 2.95 3.93 o -3 6 1 0.32 4.91 3.93 o -2 6 1 10.35 3.93 3.93 o -1 6 1 22.30 23.57 3.93 o 0 6 1 114.33 111.96 5.89 o 1 6 1 158.49 155.17 5.89 o 2 6 1 33.28 29.46 3.93 o 3 6 1 74.92 68.74 3.93 o 4 6 1 9.87 8.84 2.95 o 5 6 1 0.01 1.96 1.96 o 6 6 1 5.50 8.84 1.96 o -2 7 1 9.19 12.77 2.95 o -1 7 1 41.84 41.25 3.93 o 0 7 1 0.15 0.98 2.95 o 1 7 1 2.04 0.00 1.96 o 2 7 1 1.25 -1.96 1.96 o -10 0 2 1.68 1.96 1.96 o -8 0 2 89.00 84.46 4.91 o -6 0 2 689.78 642.27 9.82 o -4 0 2 4.59 5.89 1.96 o -2 0 2 545.00 519.51 4.91 o 0 0 2 1.23 4.91 1.96 o 2 0 2 2251.75 2336.33 12.77 o 4 0 2 3070.72 3154.38 18.66 o 6 0 2 352.51 332.92 7.86 o 8 0 2 87.98 89.37 4.91 o 10 0 2 14.61 14.73 1.96 o -11 1 2 0.33 0.98 0.98 o -10 1 2 27.75 35.35 2.95 o -9 1 2 220.47 214.09 6.87 o -8 1 2 325.69 310.33 7.86 o -7 1 2 4.69 8.84 1.96 o -6 1 2 5.35 5.89 1.96 o -5 1 2 723.31 722.80 8.84 o -4 1 2 31.24 37.32 2.95 o -3 1 2 1421.03 1370.96 9.82 o -2 1 2 5901.22 5698.91 17.68 o -1 1 2 2935.85 3239.82 12.77 o 0 1 2 0.06 -1.96 1.96 o 1 1 2 126.26 123.74 2.95 o 2 1 2 1486.34 1472.11 10.80 o 3 1 2 304.55 295.60 5.89 o 4 1 2 326.27 324.08 5.89 o 5 1 2 445.39 437.02 7.86 o 6 1 2 0.37 1.96 1.96 o 7 1 2 4.23 2.95 1.96 o 8 1 2 91.09 82.49 4.91 o 9 1 2 67.38 59.91 2.95 o 10 1 2 12.87 12.77 1.96 o 11 1 2 0.29 0.00 0.98 o -11 2 2 6.26 7.86 1.96 o -10 2 2 4.08 5.89 1.96 o -9 2 2 0.01 0.98 1.96 o -8 2 2 0.18 3.93 2.95 o -7 2 2 22.38 26.52 2.95 o -6 2 2 10.91 9.82 2.95 o -5 2 2 3.07 3.93 2.95 o -4 2 2 133.17 124.72 3.93 o -3 2 2 1.60 1.96 1.96 o -2 2 2 742.98 778.78 7.86 o -1 2 2 1036.50 1127.41 9.82 o 0 2 2 148.93 136.51 3.93 o 1 2 2 259.00 295.60 4.91 o 2 2 2 37.62 34.37 2.95 o 3 2 2 259.64 241.59 4.91 o 4 2 2 35.77 37.32 2.95 o 5 2 2 64.23 70.71 3.93 o 6 2 2 112.49 103.12 4.91 o 7 2 2 218.61 211.14 6.87 o 8 2 2 67.17 70.71 3.93 o 9 2 2 11.17 12.77 1.96 o 10 2 2 3.62 1.96 0.98 o -10 3 2 0.66 -0.98 1.96 o -9 3 2 3.88 1.96 2.95 o -8 3 2 120.12 117.85 5.89 o -7 3 2 18.77 12.77 3.93 o -5 3 2 0.37 0.00 2.95 o -4 3 2 160.82 157.13 4.91 o -3 3 2 2.34 -1.96 2.95 o -2 3 2 155.77 164.99 4.91 o -1 3 2 200.78 182.66 4.91 o 0 3 2 38.48 39.28 2.95 o 1 3 2 10.61 10.80 1.96 o 2 3 2 267.16 253.37 5.89 o 3 3 2 9.25 6.87 1.96 o 4 3 2 45.47 51.07 3.93 o 5 3 2 0.17 0.98 2.95 o 6 3 2 38.13 39.28 3.93 o 7 3 2 1.07 -1.96 2.95 o 8 3 2 4.48 5.89 1.96 o 9 3 2 1.87 1.96 1.96 o 10 3 2 3.07 4.91 0.98 o -9 4 2 0.69 0.98 1.96 o -8 4 2 2.44 4.91 2.95 o -7 4 2 97.64 113.92 5.89 o -6 4 2 26.08 25.53 3.93 o -5 4 2 33.64 41.25 4.91 o -4 4 2 77.45 74.64 4.91 o -3 4 2 97.57 90.35 4.91 o -2 4 2 27.34 29.46 3.93 o -1 4 2 80.20 73.65 4.91 o 0 4 2 1.43 0.98 2.95 o 1 4 2 190.19 180.70 5.89 o 2 4 2 97.28 93.30 4.91 o 3 4 2 2.48 2.95 2.95 o 4 4 2 0.45 -3.93 3.93 o 5 4 2 51.65 48.12 4.91 o 6 4 2 167.65 192.48 6.87 o 7 4 2 219.62 239.62 7.86 o 8 4 2 11.14 15.71 2.95 o 9 4 2 16.13 16.70 1.96 o -8 5 2 7.99 10.80 2.95 o -7 5 2 0.08 -0.98 2.95 o -6 5 2 1.23 0.00 2.95 o -5 5 2 139.41 134.54 6.87 o -4 5 2 34.21 42.23 4.91 o -3 5 2 0.26 0.00 2.95 o -2 5 2 154.51 139.45 6.87 o -1 5 2 23.97 26.52 3.93 o 0 5 2 5.55 10.80 3.93 o 1 5 2 15.13 10.80 3.93 o 2 5 2 16.54 19.64 3.93 o 3 5 2 1.08 5.89 3.93 o 4 5 2 35.76 31.43 3.93 o 5 5 2 13.64 17.68 2.95 o 6 5 2 24.83 29.46 2.95 o 7 5 2 19.54 18.66 2.95 o -6 6 2 0.23 -1.96 2.95 o -5 6 2 3.33 8.84 3.93 o -4 6 2 1.24 0.98 3.93 o -3 6 2 1.69 -1.96 3.93 o -2 6 2 11.70 12.77 3.93 o -1 6 2 47.53 41.25 4.91 o 0 6 2 4.16 5.89 3.93 o 1 6 2 2.40 -0.98 3.93 o 2 6 2 9.98 7.86 2.95 o 3 6 2 0.25 3.93 2.95 o 4 6 2 38.06 33.39 3.93 o 5 6 2 0.03 0.00 1.96 o -2 7 2 24.59 25.53 3.93 o -1 7 2 22.05 22.59 2.95 o 0 7 2 23.52 17.68 2.95 o 1 7 2 2.44 0.00 1.96 o -11 0 3 41.72 41.25 2.95 o -9 0 3 3.61 5.89 1.96 o -7 0 3 168.75 167.93 5.89 o -5 0 3 409.37 394.79 6.87 o -3 0 3 244.54 246.50 4.91 o -1 0 3 2100.34 2354.98 11.78 o 1 0 3 77.67 70.71 2.95 o 3 0 3 582.71 592.18 7.86 o 5 0 3 248.67 269.08 6.87 o 7 0 3 8.40 9.82 2.95 o 9 0 3 6.37 4.91 1.96 o 11 0 3 4.56 4.91 0.98 o -11 1 3 10.37 10.80 1.96 o -10 1 3 39.67 43.21 2.95 o -9 1 3 0.00 -1.96 1.96 o -8 1 3 117.82 113.92 4.91 o -7 1 3 0.11 -0.98 1.96 o -6 1 3 84.69 82.49 3.93 o -5 1 3 171.43 182.66 4.91 o -4 1 3 646.84 632.45 7.86 o -3 1 3 133.37 129.63 3.93 o -2 1 3 5810.89 5888.44 19.64 o -1 1 3 18629.29 18366.52 168.91 o 0 1 3 48.00 43.21 2.95 o 1 1 3 156.36 138.47 3.93 o 2 1 3 0.18 3.93 1.96 o 3 1 3 215.53 239.62 4.91 o 4 1 3 33.59 36.34 2.95 o 5 1 3 123.75 132.58 4.91 o 6 1 3 2.96 6.87 1.96 o 7 1 3 2.44 2.95 1.96 o 8 1 3 5.70 6.87 1.96 o 9 1 3 6.92 2.95 1.96 o 10 1 3 0.56 1.96 0.98 o -11 2 3 3.82 4.91 1.96 o -10 2 3 0.21 -1.96 1.96 o -9 2 3 0.21 0.00 2.95 o -8 2 3 2.34 1.96 2.95 o -7 2 3 111.36 111.96 4.91 o -6 2 3 4.03 5.89 1.96 o -5 2 3 1.19 0.98 1.96 o -4 2 3 1393.45 1434.79 12.77 o -3 2 3 238.07 240.61 4.91 o -2 2 3 0.72 0.00 1.96 o -1 2 3 416.73 461.57 6.87 o 0 2 3 778.95 776.81 7.86 o 1 2 3 2336.76 2268.56 13.75 o 2 2 3 106.12 103.12 3.93 o 3 2 3 1.88 2.95 1.96 o 4 2 3 4.81 3.93 1.96 o 5 2 3 21.53 19.64 2.95 o 6 2 3 35.65 32.41 3.93 o 7 2 3 11.62 11.78 2.95 o 8 2 3 64.51 61.87 3.93 o 9 2 3 30.00 27.50 2.95 o 10 2 3 24.22 21.61 1.96 o -10 3 3 7.53 6.87 1.96 o -9 3 3 0.28 1.96 1.96 o -8 3 3 8.14 4.91 2.95 o -7 3 3 226.61 217.04 6.87 o -6 3 3 4.13 4.91 2.95 o -5 3 3 12.89 10.80 2.95 o -4 3 3 30.33 36.34 3.93 o -3 3 3 238.39 209.18 5.89 o -2 3 3 128.50 122.76 4.91 o -1 3 3 61.04 57.94 2.95 o 0 3 3 0.78 0.98 1.96 o 1 3 3 673.90 672.71 8.84 o 2 3 3 7.91 5.89 2.95 o 3 3 3 128.54 138.47 4.91 o 4 3 3 67.44 75.62 4.91 o 5 3 3 263.60 292.65 7.86 o 6 3 3 204.36 202.30 7.86 o 7 3 3 1.06 1.96 2.95 o 8 3 3 0.57 0.00 1.96 o 9 3 3 16.62 20.62 1.96 o 10 3 3 0.69 0.98 0.98 o -9 4 3 0.28 1.96 1.96 o -8 4 3 9.44 7.86 2.95 o -7 4 3 7.57 9.82 3.93 o -6 4 3 36.76 37.32 4.91 o -5 4 3 0.52 1.96 3.93 o -4 4 3 114.76 114.90 5.89 o -3 4 3 3.62 0.00 2.95 o -2 4 3 35.07 31.43 3.93 o -1 4 3 3.70 9.82 2.95 o 0 4 3 1.92 -2.95 2.95 o 1 4 3 71.94 61.87 4.91 o 2 4 3 39.13 45.17 3.93 o 3 4 3 9.68 14.73 2.95 o 4 4 3 0.01 -2.95 2.95 o 5 4 3 1.98 -2.95 2.95 o 6 4 3 10.88 11.78 2.95 o 7 4 3 60.24 71.69 4.91 o 8 4 3 35.82 36.34 2.95 o 9 4 3 1.17 1.96 1.96 o -8 5 3 0.34 2.95 2.95 o -7 5 3 1.79 -2.95 2.95 o -6 5 3 29.02 29.46 3.93 o -5 5 3 11.06 10.80 3.93 o -4 5 3 53.85 47.14 4.91 o -3 5 3 30.23 22.59 4.91 o -2 5 3 453.23 408.54 9.82 o -1 5 3 324.99 319.17 8.84 o 0 5 3 13.51 17.68 3.93 o 1 5 3 0.31 6.87 3.93 o 2 5 3 18.09 19.64 3.93 o 3 5 3 26.78 25.53 3.93 o 4 5 3 23.16 30.44 3.93 o 5 5 3 15.88 16.70 2.95 o 6 5 3 1.73 0.98 2.95 o 7 5 3 6.60 7.86 1.96 o -6 6 3 1.54 5.89 2.95 o -5 6 3 5.44 0.98 3.93 o -4 6 3 4.71 7.86 2.95 o -3 6 3 13.18 13.75 3.93 o -2 6 3 8.76 12.77 3.93 o -1 6 3 30.43 29.46 3.93 o 0 6 3 0.83 0.98 2.95 o 1 6 3 2.02 4.91 3.93 o 2 6 3 11.29 13.75 2.95 o 3 6 3 1.13 1.96 2.95 o 4 6 3 19.90 18.66 2.95 o 5 6 3 0.34 -0.98 1.96 o -1 7 3 23.82 24.55 2.95 o 0 7 3 0.65 -2.95 2.95 o -10 0 4 609.80 632.45 10.80 o -8 0 4 40.03 43.21 3.93 o -6 0 4 32.57 31.43 2.95 o -4 0 4 201.14 225.87 4.91 o -2 0 4 378.01 373.18 5.89 o 0 0 4 2980.00 3181.88 15.71 o 2 0 4 1279.51 1127.41 9.82 o 4 0 4 691.22 657.00 8.84 o 6 0 4 62.21 72.67 3.93 o 8 0 4 261.69 238.64 6.87 o 10 0 4 4.26 3.93 0.98 o -11 1 4 7.13 6.87 1.96 o -10 1 4 42.42 39.28 2.95 o -9 1 4 67.62 68.74 3.93 o -8 1 4 0.02 2.95 1.96 o -7 1 4 12.83 16.70 2.95 o 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