#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2203562.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2203562_Fobs loop_ _publ_author_name 'Liu, Ji-Wei' 'Gao, Shan' 'Huo, Li-Hua' 'Zhao, Hui' 'Ng, Seik Weng' _publ_section_title ; Hexaaquamanganese(II) benzene-1,4-dioxyacetate ; _journal_issue 5 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m517 _journal_page_last m518 _journal_volume 60 _journal_year 2004 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 101.809 _cell_angle_beta 96.159 _cell_angle_gamma 106.986 _cell_length_a 5.6556 _cell_length_b 6.3747 _cell_length_c 11.6370 _exptl_crystal_F_000 201.00 _reflns_d_resolution_high 0.7700 _[local]_cod_data_source_file ci6356Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' CI6356R C10 H20 MN O12' _shelx_refln_list_code 4 _shelx_f_calc_maximum 81.37 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 161.48 153.25 4.50 o 2 0 0 1.94 2.03 0.18 o 3 0 0 512.85 471.22 2.00 o 4 0 0 44.99 112.99 1.59 o 5 0 0 45.20 45.12 0.58 o 6 0 0 39.14 37.23 1.85 o -7 1 0 53.31 59.93 1.69 o -6 1 0 4.74 4.63 0.42 o -5 1 0 5.32 4.47 0.46 o -4 1 0 444.59 431.97 2.41 o -3 1 0 431.82 392.01 5.09 o -2 1 0 269.47 261.12 1.95 o -1 1 0 420.87 460.08 37.47 o 0 1 0 156.36 146.83 1.95 o 1 1 0 83.52 75.61 11.31 o 2 1 0 88.10 64.54 0.55 o 3 1 0 55.23 56.42 6.92 o 4 1 0 66.17 70.50 2.09 o 5 1 0 76.30 68.63 1.72 o 6 1 0 69.68 69.34 0.85 o -7 2 0 20.07 24.78 1.60 o -6 2 0 132.95 130.92 7.15 o -5 2 0 4.11 5.21 0.51 o -4 2 0 282.46 265.25 0.68 o -3 2 0 894.28 993.80 19.55 o -2 2 0 403.48 399.17 5.11 o -1 2 0 970.58 965.31 10.85 o 0 2 0 219.67 249.89 0.71 o 1 2 0 826.23 819.00 28.30 o 2 2 0 68.25 61.89 0.56 o 3 2 0 17.47 42.75 2.26 o 4 2 0 152.00 142.14 1.00 o 5 2 0 4.65 4.79 0.59 o 6 2 0 19.71 17.02 1.18 o -7 3 0 3.73 5.78 1.40 o -5 3 0 3.93 11.01 8.02 o -4 3 0 3.71 3.00 0.22 o -3 3 0 321.40 380.24 2.60 o -2 3 0 685.33 681.56 1.17 o -1 3 0 573.50 637.72 3.71 o 0 3 0 294.66 291.69 4.01 o 1 3 0 82.71 81.11 1.15 o 2 3 0 24.08 18.92 0.66 o 3 3 0 172.44 214.18 2.46 o 4 3 0 109.15 113.51 1.32 o 5 3 0 24.28 25.01 0.84 o -5 4 0 473.14 457.64 4.91 o -4 4 0 127.56 135.57 2.41 o -3 4 0 64.18 56.83 1.93 o -2 4 0 401.24 381.95 7.32 o -1 4 0 139.23 182.93 1.30 o 0 4 0 115.30 105.97 1.48 o 1 4 0 204.84 193.29 3.95 o 2 4 0 3.45 17.08 8.97 o 3 4 0 10.57 16.84 1.76 o 4 4 0 24.33 25.91 0.94 o -5 5 0 39.80 38.93 2.46 o -4 5 0 5.66 5.36 0.27 o -3 5 0 440.66 387.91 5.02 o -2 5 0 5.28 22.82 4.36 o -1 5 0 3.25 9.63 0.78 o 0 5 0 292.79 275.24 1.10 o 1 5 0 18.30 14.38 0.50 o 2 5 0 84.20 86.70 1.25 o 3 5 0 27.90 31.24 1.23 o -6 6 0 0.89 5.27 1.22 o -5 6 0 16.41 14.78 1.04 o -4 6 0 7.38 5.96 0.36 o -3 6 0 25.79 21.18 0.82 o -2 6 0 41.69 60.25 14.35 o -1 6 0 40.96 35.16 1.06 o 0 6 0 2.87 1.86 2.08 o 1 6 0 53.81 49.64 1.87 o 2 6 0 62.04 68.52 1.19 o -5 7 0 34.90 28.30 1.19 o -4 7 0 25.19 22.07 0.67 o -3 7 0 0.85 1.22 0.39 o -2 7 0 171.98 159.57 1.67 o -1 7 0 78.60 84.68 1.51 o 0 7 0 0.24 1.47 1.10 o 1 7 0 40.53 44.89 3.02 o -3 8 0 3.37 2.48 0.60 o -2 8 0 5.79 5.55 2.10 o 1 -8 1 37.58 39.67 1.49 o 2 -8 1 17.60 18.42 1.08 o 3 -8 1 14.62 10.72 0.69 o -1 -7 1 0.23 0.47 1.30 o 0 -7 1 7.92 7.24 1.18 o 1 -7 1 85.92 99.69 1.63 o 2 -7 1 2.47 2.15 0.62 o 3 -7 1 1.98 1.23 0.40 o 4 -7 1 37.72 27.83 0.50 o 5 -7 1 2.18 4.38 0.95 o -3 -6 1 15.75 20.96 1.50 o -2 -6 1 10.06 11.41 1.23 o -1 -6 1 43.08 45.33 1.35 o 0 -6 1 36.96 37.06 1.19 o 1 -6 1 69.29 66.49 1.19 o 2 -6 1 156.14 136.40 10.97 o 3 -6 1 13.86 10.18 0.38 o 4 -6 1 61.45 55.37 0.55 o 5 -6 1 26.83 23.02 1.97 o 6 -6 1 33.38 38.72 1.41 o -4 -5 1 0.17 1.57 1.25 o -3 -5 1 30.81 29.61 1.14 o -2 -5 1 34.18 32.06 2.93 o -1 -5 1 74.96 80.34 1.36 o 0 -5 1 28.02 23.04 0.91 o 1 -5 1 78.48 74.95 1.01 o 2 -5 1 6.49 6.81 0.31 o 3 -5 1 108.42 110.35 3.07 o 4 -5 1 277.05 265.80 0.87 o 5 -5 1 78.16 79.86 0.69 o -4 -4 1 64.15 70.08 1.11 o -3 -4 1 51.83 55.76 1.25 o -2 -4 1 53.51 52.87 0.76 o -1 -4 1 419.94 407.53 5.87 o 0 -4 1 268.38 259.69 25.44 o 1 -4 1 200.16 293.02 0.98 o 2 -4 1 106.53 106.54 1.92 o 3 -4 1 3.57 4.47 0.28 o 4 -4 1 6.22 12.93 7.16 o 5 -4 1 136.69 138.84 8.76 o 7 -4 1 20.34 20.53 1.63 o -5 -3 1 28.84 24.39 0.95 o -4 -3 1 73.28 79.27 1.68 o -3 -3 1 24.73 32.64 2.03 o -2 -3 1 330.76 341.60 3.93 o -1 -3 1 102.22 102.94 0.88 o 0 -3 1 68.51 71.58 2.59 o 1 -3 1 12.88 10.52 0.67 o 2 -3 1 1788.73 2082.73 100.71 o 3 -3 1 2.77 1.96 0.24 o 4 -3 1 124.71 122.79 1.52 o 5 -3 1 843.07 806.63 3.76 o 6 -3 1 7.94 6.97 0.42 o 7 -3 1 26.65 30.09 1.63 o -6 -2 1 5.65 5.02 0.53 o -5 -2 1 157.19 153.21 1.17 o -4 -2 1 45.09 51.01 3.74 o -3 -2 1 69.06 108.91 3.23 o -2 -2 1 841.98 820.84 6.01 o -1 -2 1 552.34 590.96 9.54 o 0 -2 1 93.12 113.11 0.74 o 1 -2 1 734.04 673.20 2.03 o 2 -2 1 458.33 435.86 19.61 o 3 -2 1 1125.88 1165.76 5.75 o 4 -2 1 180.21 169.87 3.26 o 5 -2 1 8.10 8.98 0.30 o 6 -2 1 45.83 44.78 2.86 o 7 -2 1 5.03 7.59 1.47 o -6 -1 1 49.62 49.39 1.42 o -5 -1 1 15.98 17.30 0.64 o -4 -1 1 77.16 78.17 1.51 o -3 -1 1 9.41 8.29 0.36 o -2 -1 1 166.37 151.65 0.76 o -1 -1 1 6620.52 6599.05 31.34 o 1 -1 1 649.78 666.28 4.32 o 2 -1 1 513.46 483.36 9.53 o 3 -1 1 280.91 248.41 2.40 o 4 -1 1 156.48 160.68 2.61 o 5 -1 1 2.79 2.86 0.65 o 6 -1 1 67.29 61.86 3.44 o 7 -1 1 0.36 2.23 1.21 o -6 0 1 112.34 109.45 1.99 o -5 0 1 90.36 82.72 2.12 o -4 0 1 158.89 188.02 3.34 o -3 0 1 169.43 150.48 0.54 o -2 0 1 794.81 852.54 17.13 o -1 0 1 575.78 655.11 1.77 o 1 0 1 100.27 80.85 1.92 o 2 0 1 1346.40 1371.96 6.10 o 3 0 1 193.46 189.29 2.80 o 4 0 1 43.55 63.41 1.94 o 5 0 1 142.74 136.61 4.90 o 6 0 1 17.35 16.05 1.48 o -7 1 1 74.03 91.78 1.90 o -6 1 1 25.52 18.80 0.89 o -5 1 1 64.92 61.47 1.25 o -4 1 1 226.86 235.18 3.47 o -3 1 1 53.19 37.68 0.37 o -2 1 1 36.89 28.92 1.81 o -1 1 1 415.05 502.01 7.21 o 0 1 1 5026.16 4383.23 17.02 o 1 1 1 296.17 245.99 2.41 o 2 1 1 677.74 643.07 1.41 o 3 1 1 138.87 130.56 2.02 o 4 1 1 69.52 73.27 1.58 o 5 1 1 58.26 56.64 0.80 o 6 1 1 16.44 13.23 2.52 o -7 2 1 65.72 77.44 1.85 o -6 2 1 73.30 59.12 10.59 o -5 2 1 1.39 0.90 0.22 o -4 2 1 246.40 263.72 1.60 o -3 2 1 0.96 48.63 0.80 o -2 2 1 2773.84 3161.48 23.94 o -1 2 1 2307.02 2415.33 20.54 o 0 2 1 6.03 70.05 3.61 o 1 2 1 240.09 211.13 1.43 o 2 2 1 459.07 441.36 12.03 o 3 2 1 37.63 34.83 0.58 o 4 2 1 83.47 80.55 0.85 o 5 2 1 17.32 14.76 1.26 o -6 3 1 143.30 164.14 1.96 o -5 3 1 159.95 169.09 1.69 o -4 3 1 21.11 31.06 0.86 o -3 3 1 500.28 527.69 13.50 o -2 3 1 79.07 70.71 1.60 o -1 3 1 204.22 227.05 9.41 o 0 3 1 423.72 391.17 8.22 o 1 3 1 1.66 1.81 0.38 o 2 3 1 35.91 42.37 1.11 o 3 3 1 62.85 69.43 3.00 o 4 3 1 70.36 72.13 5.67 o 5 3 1 5.57 6.00 0.99 o -6 4 1 38.09 44.42 1.37 o -5 4 1 4.02 17.60 1.05 o -4 4 1 239.83 223.07 5.52 o -3 4 1 279.70 283.04 8.21 o -2 4 1 1.08 1.22 0.64 o -1 4 1 325.63 358.74 2.76 o 0 4 1 343.17 355.16 5.63 o 1 4 1 56.74 61.60 3.34 o 2 4 1 6.52 11.58 2.45 o 3 4 1 131.19 140.32 1.43 o 4 4 1 28.38 26.03 1.23 o -5 5 1 1.39 5.23 1.02 o -4 5 1 223.32 206.63 4.23 o -3 5 1 100.25 97.63 0.67 o -2 5 1 0.94 2.40 0.79 o -1 5 1 21.34 44.84 1.54 o 0 5 1 53.29 47.56 1.86 o 1 5 1 89.38 86.03 3.18 o 2 5 1 72.11 73.66 1.09 o 3 5 1 10.04 13.95 0.91 o -6 6 1 51.72 55.84 1.57 o -5 6 1 10.22 11.14 1.04 o -4 6 1 42.46 39.35 0.73 o -3 6 1 258.19 225.90 2.04 o -2 6 1 43.51 46.64 0.97 o -1 6 1 14.17 12.97 1.00 o 0 6 1 60.87 54.24 2.42 o 1 6 1 8.52 12.05 1.78 o 2 6 1 17.38 19.96 1.70 o -5 7 1 56.85 48.76 1.42 o -4 7 1 0.63 1.16 0.35 o -3 7 1 0.26 0.91 0.64 o -2 7 1 43.93 51.64 1.18 o -1 7 1 2.09 12.66 1.16 o 0 7 1 21.02 19.17 1.30 o 1 7 1 44.25 51.86 1.73 o 1 -8 2 1.30 2.15 0.87 o 2 -8 2 14.24 16.78 3.22 o 3 -8 2 3.67 2.48 0.63 o -1 -7 2 1.92 3.55 1.23 o 0 -7 2 27.86 33.79 1.40 o 1 -7 2 119.33 120.12 1.69 o 2 -7 2 9.51 17.33 1.75 o 3 -7 2 85.39 80.98 1.08 o 4 -7 2 33.20 26.49 0.62 o 5 -7 2 16.29 14.10 1.03 o -3 -6 2 10.82 13.79 1.32 o -2 -6 2 28.02 32.67 1.44 o -1 -6 2 0.83 0.87 1.02 o 0 -6 2 92.23 95.27 1.50 o 1 -6 2 31.51 33.76 1.01 o 2 -6 2 21.25 20.50 1.17 o 3 -6 2 389.27 362.39 11.48 o 4 -6 2 46.50 42.26 1.27 o 5 -6 2 1.20 1.26 0.56 o 6 -6 2 2.42 6.21 1.16 o -4 -5 2 14.39 13.50 1.41 o -3 -5 2 27.43 23.93 1.20 o -2 -5 2 23.43 26.96 1.13 o -1 -5 2 197.47 204.51 1.79 o 0 -5 2 468.27 459.42 2.23 o 1 -5 2 3.65 2.90 0.68 o 2 -5 2 40.56 38.94 1.22 o 3 -5 2 3.95 3.46 0.29 o 4 -5 2 0.76 0.88 0.29 o 5 -5 2 64.02 59.89 2.56 o 6 -5 2 23.87 23.18 1.42 o -5 -4 2 3.36 3.33 1.13 o -4 -4 2 13.37 10.25 1.32 o -3 -4 2 33.33 35.45 1.28 o -2 -4 2 55.26 54.41 3.03 o -1 -4 2 127.48 118.92 1.23 o 0 -4 2 50.95 43.25 0.80 o 1 -4 2 873.69 942.68 5.80 o 2 -4 2 1.58 0.32 0.24 o 3 -4 2 2.47 5.97 2.52 o 4 -4 2 973.07 1039.72 2.03 o 5 -4 2 46.15 59.91 0.63 o 7 -4 2 28.66 29.82 1.71 o -5 -3 2 10.05 8.17 0.55 o -4 -3 2 54.06 49.91 1.24 o -3 -3 2 175.53 206.35 2.40 o -2 -3 2 24.74 19.96 0.26 o -1 -3 2 188.29 171.24 1.17 o 0 -3 2 53.64 56.53 1.20 o 1 -3 2 815.94 943.29 41.68 o 2 -3 2 204.47 196.84 1.33 o 3 -3 2 6.83 5.63 0.29 o 4 -3 2 84.28 78.02 2.15 o 5 -3 2 27.39 28.86 2.04 o 6 -3 2 29.61 26.28 2.60 o 7 -3 2 79.46 89.40 1.98 o -6 -2 2 1.47 1.75 0.61 o -5 -2 2 36.64 37.72 0.58 o -4 -2 2 5.81 7.61 1.29 o -3 -2 2 483.48 517.19 13.78 o -2 -2 2 2439.66 2668.37 8.30 o -1 -2 2 8.28 5.95 0.15 o 1 -2 2 38.84 154.64 85.54 o 2 -2 2 3.76 1.10 0.21 o 3 -2 2 526.75 476.98 2.93 o 4 -2 2 147.58 143.77 0.67 o 5 -2 2 253.14 246.51 0.97 o 6 -2 2 0.21 -0.05 0.35 o 7 -2 2 12.06 12.82 1.39 o -6 -1 2 41.30 42.41 1.57 o -5 -1 2 159.53 151.95 2.21 o -4 -1 2 67.94 71.30 0.87 o -3 -1 2 92.92 79.43 1.21 o -2 -1 2 294.52 293.63 3.28 o -1 -1 2 1869.65 2108.88 25.84 o 0 -1 2 409.02 670.13 214.20 o 1 -1 2 145.47 158.43 1.38 o 2 -1 2 16.81 13.69 0.27 o 3 -1 2 1663.74 1643.74 4.37 o 4 -1 2 375.41 391.05 1.98 o 5 -1 2 61.03 57.04 0.69 o 6 -1 2 51.90 47.77 1.39 o -7 0 2 34.30 33.29 1.37 o -6 0 2 84.59 87.37 1.68 o -5 0 2 44.26 43.06 2.62 o -4 0 2 355.78 342.84 4.73 o -3 0 2 7.41 5.15 0.31 o -2 0 2 213.61 214.36 4.57 o -1 0 2 4476.46 4361.46 7.12 o 0 0 2 157.76 177.16 1.58 o 1 0 2 885.48 864.31 2.63 o 2 0 2 2069.89 2038.86 2.68 o 3 0 2 146.11 136.46 1.37 o 4 0 2 78.41 90.75 0.73 o 5 0 2 71.27 70.18 2.67 o 6 0 2 5.79 3.87 0.73 o -6 1 2 16.42 12.79 1.74 o -5 1 2 119.89 108.34 8.76 o -4 1 2 42.20 63.03 14.49 o -3 1 2 286.35 299.35 1.91 o -2 1 2 498.42 460.24 12.29 o -1 1 2 211.31 214.73 3.36 o 0 1 2 55.61 107.88 57.91 o 1 1 2 3543.69 3269.38 37.54 o 2 1 2 1086.51 1013.50 10.82 o 3 1 2 5.16 6.79 0.42 o 4 1 2 67.12 70.11 2.89 o 5 1 2 9.02 8.90 0.61 o 6 1 2 6.19 6.26 0.67 o -7 2 2 71.34 79.41 1.80 o -6 2 2 91.11 95.93 1.64 o -5 2 2 114.02 114.79 2.25 o -4 2 2 16.85 32.16 0.81 o -3 2 2 5.58 16.74 0.64 o -2 2 2 966.45 1054.69 14.05 o -1 2 2 234.16 258.63 4.54 o 0 2 2 8.15 18.07 9.31 o 1 2 2 263.90 243.55 1.28 o 2 2 2 35.03 31.02 0.56 o 3 2 2 106.92 96.24 2.29 o 4 2 2 19.02 19.63 0.68 o 5 2 2 30.03 30.03 2.31 o -6 3 2 1.84 6.36 1.10 o -5 3 2 74.71 156.29 1.62 o -4 3 2 21.70 25.76 0.83 o -3 3 2 2.57 2.20 0.26 o -2 3 2 1211.35 1358.26 3.46 o -1 3 2 978.76 1130.83 8.19 o 0 3 2 382.05 361.41 7.33 o 1 3 2 36.47 31.55 0.52 o 2 3 2 167.91 171.12 2.39 o 3 3 2 63.20 65.07 2.39 o 4 3 2 11.25 11.53 0.94 o 5 3 2 19.82 17.26 0.89 o -7 4 2 1.22 -1.35 1.35 o -6 4 2 14.89 15.10 1.19 o -5 4 2 135.47 137.77 2.60 o -4 4 2 27.07 26.25 0.86 o -3 4 2 147.33 135.19 2.26 o -2 4 2 24.12 22.86 0.29 o -1 4 2 70.25 117.69 1.65 o 0 4 2 597.63 573.35 7.69 o 1 4 2 5.17 4.43 0.37 o 2 4 2 21.40 20.12 0.74 o 3 4 2 23.36 30.25 0.83 o 4 4 2 0.82 0.34 0.84 o -6 5 2 1.09 3.81 1.18 o -5 5 2 30.96 40.61 1.23 o -4 5 2 511.67 434.93 9.45 o -3 5 2 51.26 48.42 0.55 o -2 5 2 25.90 21.99 0.53 o -1 5 2 276.96 279.89 1.51 o 0 5 2 50.97 58.64 2.42 o 1 5 2 13.90 14.35 0.87 o 2 5 2 43.76 41.30 0.96 o 3 5 2 7.33 7.23 1.00 o -6 6 2 18.31 15.51 1.39 o -5 6 2 3.59 3.91 1.04 o -4 6 2 31.97 26.88 0.48 o -3 6 2 6.17 7.54 0.48 o -2 6 2 20.56 26.77 5.24 o -1 6 2 105.96 102.54 2.30 o 0 6 2 3.23 2.83 0.50 o 1 6 2 91.81 82.77 2.37 o 2 6 2 45.69 47.91 3.11 o -5 7 2 14.43 12.73 1.20 o -4 7 2 5.46 3.10 0.36 o -3 7 2 30.19 24.11 0.93 o -2 7 2 37.29 42.33 1.16 o -1 7 2 9.84 10.99 3.87 o 0 7 2 48.75 45.12 2.17 o 1 -8 3 29.69 32.66 1.06 o 2 -8 3 29.16 32.23 1.67 o 3 -8 3 3.85 3.85 0.70 o -1 -7 3 3.98 5.76 1.26 o 0 -7 3 18.83 19.46 1.30 o 1 -7 3 6.73 8.78 0.79 o 2 -7 3 131.56 105.20 16.19 o 3 -7 3 70.91 75.05 1.11 o 4 -7 3 0.15 0.18 0.39 o 5 -7 3 0.29 0.92 0.82 o -3 -6 3 22.83 22.91 1.43 o -2 -6 3 16.60 14.66 1.26 o -1 -6 3 101.13 94.07 1.68 o 0 -6 3 16.51 15.63 1.06 o 1 -6 3 9.73 13.03 0.81 o 2 -6 3 50.26 50.34 1.68 o 3 -6 3 36.35 33.62 0.97 o 4 -6 3 27.10 24.17 1.00 o 5 -6 3 14.79 13.95 0.60 o 6 -6 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