#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:06:22 +0300 (Sun, 03 Apr 2016) $ #$Revision: 180961 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/41/2204199.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2204199_Fobs loop_ _publ_author_name 'Stibrany, Robert T.' 'Schugar, Harvey J.' 'Potenza, Joseph A.' _publ_section_title ; Hydrogen bonding in 1H-naphth[2,3-d]imidazole ; _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1648 _journal_page_last o1651 _journal_volume 60 _journal_year 2004 _space_group_IT_number 9 _symmetry_space_group_name_Hall 'I -2ya' _symmetry_space_group_name_H-M 'I 1 a 1' _cell_angle_alpha 90.000 _cell_angle_beta 110.502 _cell_angle_gamma 90.000 _cell_length_a 9.4503 _cell_length_b 16.3882 _cell_length_c 11.4770 _exptl_crystal_F_000 704.00 _reflns_d_resolution_high 0.8381 _cod_data_source_file lh6257Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' npk5m in Ia' _shelx_refln_list_code 4 _shelx_f_calc_maximum 203.84 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' 'x+1/2, -y, z' 'x+1/2, y+1/2, z+1/2' 'x+1, -y+1/2, z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 221.80 214.27 17.17 o 4 0 0 2278.63 2637.14 50.56 o 6 0 0 175.21 181.75 14.18 o 8 0 0 152.01 178.64 25.52 o 10 0 0 181.08 158.43 24.39 o 3 1 0 11.63 21.47 10.75 o 5 1 0 1010.66 1038.45 16.27 o 7 1 0 124.89 122.49 13.48 o 9 1 0 188.01 193.97 15.17 o 4 2 0 63.53 54.61 8.49 o 6 2 0 592.62 580.72 14.97 o 8 2 0 7.03 12.75 8.62 o 10 2 0 22.36 12.79 14.66 o 1 3 0 3397.55 3425.08 49.54 o 3 3 0 246.52 258.40 21.31 o 5 3 0 301.29 295.97 9.30 o 7 3 0 14.55 14.95 7.97 o 9 3 0 87.46 115.00 17.19 o 0 4 0 7106.13 7166.50 135.76 o 2 4 0 969.10 946.03 22.10 o 4 4 0 558.70 584.63 14.37 o 6 4 0 33.03 26.69 6.55 o 8 4 0 185.68 189.30 13.63 o 10 4 0 5.55 16.33 17.35 o 1 5 0 1153.91 1188.15 59.32 o 3 5 0 69.32 70.02 8.14 o 5 5 0 187.18 184.18 9.34 o 7 5 0 136.95 138.35 11.52 o 9 5 0 2.34 -2.05 24.11 o 0 6 0 147.47 165.31 7.83 o 2 6 0 2214.45 2429.18 30.49 o 4 6 0 11.32 13.23 6.03 o 6 6 0 405.41 384.74 19.33 o 8 6 0 187.30 201.23 22.15 o 10 6 0 2.56 -22.45 22.45 o 1 7 0 546.09 594.92 11.97 o 3 7 0 79.71 99.32 9.10 o 5 7 0 21.19 16.09 7.14 o 7 7 0 80.31 78.16 11.01 o 9 7 0 43.77 66.45 19.57 o 0 8 0 507.41 470.15 15.03 o 2 8 0 2703.80 2940.64 33.83 o 4 8 0 389.03 386.03 24.40 o 6 8 0 445.08 405.72 14.88 o 8 8 0 106.95 127.74 36.64 o 1 9 0 1228.93 1240.38 23.01 o 3 9 0 83.96 88.04 19.09 o 5 9 0 780.81 757.63 18.86 o 7 9 0 30.37 49.79 12.06 o 9 9 0 59.57 60.49 21.10 o 0 10 0 2071.58 2090.24 69.54 o 2 10 0 140.79 137.60 8.83 o 4 10 0 199.97 193.02 13.71 o 6 10 0 26.47 29.56 11.84 o 8 10 0 6.78 8.07 19.27 o 1 11 0 293.78 315.85 11.85 o 3 11 0 358.96 370.13 32.24 o 5 11 0 331.26 305.62 17.65 o 7 11 0 18.03 39.69 13.78 o 0 12 0 56.68 61.37 13.16 o 2 12 0 65.92 75.14 8.41 o 4 12 0 51.65 53.37 11.84 o 6 12 0 91.59 92.34 16.77 o 8 12 0 29.00 2.67 17.20 o 1 13 0 0.37 -0.87 7.79 o 3 13 0 81.09 65.01 10.61 o 5 13 0 486.18 399.59 41.28 o 7 13 0 29.25 53.06 18.34 o 0 14 0 1183.26 1163.73 38.06 o 2 14 0 233.25 226.45 15.72 o 4 14 0 235.65 225.96 17.42 o 6 14 0 88.29 70.84 18.11 o 1 15 0 235.77 247.42 14.72 o 3 15 0 12.77 31.85 10.31 o 5 15 0 24.52 42.93 33.93 o 0 16 0 50.43 70.81 15.47 o 2 16 0 2.09 23.92 10.62 o 4 16 0 184.80 167.23 21.51 o 6 16 0 7.24 3.73 23.41 o 1 17 0 1.72 8.16 19.93 o 3 17 0 85.50 70.72 17.94 o 5 17 0 26.69 70.87 19.97 o 0 18 0 43.65 66.71 17.69 o 2 18 0 2.97 1.93 13.32 o 4 18 0 53.43 48.65 20.07 o 1 19 0 30.37 35.07 14.71 o -10 1 1 150.37 200.71 24.71 o -8 1 1 84.91 82.77 9.88 o -6 1 1 1134.39 1216.67 20.64 o -4 1 1 50.59 60.62 11.26 o -2 1 1 573.21 545.17 15.67 o 2 1 1 371.92 378.94 15.31 o 4 1 1 2885.91 2966.26 35.13 o 6 1 1 147.32 153.73 9.95 o 8 1 1 161.87 170.21 12.71 o 10 1 1 47.61 59.09 13.60 o -9 2 1 125.99 133.89 15.56 o -7 2 1 82.74 97.01 9.28 o -5 2 1 881.29 896.00 15.93 o -3 2 1 2570.79 2453.57 45.85 o 1 2 1 24028.66 25165.49 327.33 o 3 2 1 152.15 154.12 10.42 o 5 2 1 1737.04 1743.18 20.73 o 7 2 1 39.29 42.10 8.65 o 9 2 1 84.96 81.50 12.89 o -10 3 1 51.60 44.63 36.57 o -8 3 1 3.30 6.56 9.21 o -6 3 1 221.78 228.79 10.24 o -4 3 1 72.49 75.06 9.97 o -2 3 1 768.35 721.51 25.00 o 0 3 1 22081.71 21911.03 233.52 o 2 3 1 971.36 967.89 23.92 o 4 3 1 201.76 197.23 8.73 o 6 3 1 70.58 78.37 10.02 o 8 3 1 76.00 93.34 18.06 o 10 3 1 81.55 81.05 14.54 o -9 4 1 63.97 66.01 17.73 o -7 4 1 194.11 194.81 10.87 o -5 4 1 1438.89 1530.62 23.54 o -3 4 1 493.33 539.19 33.75 o -1 4 1 1197.67 1113.44 20.61 o 1 4 1 7663.41 8101.51 111.20 o 3 4 1 1467.33 1587.20 22.19 o 5 4 1 214.88 196.54 9.18 o 7 4 1 178.20 177.71 11.20 o 9 4 1 0.50 10.88 15.54 o -10 5 1 22.82 29.68 19.71 o -8 5 1 475.17 468.39 20.44 o -6 5 1 148.76 146.73 12.93 o -4 5 1 131.06 123.55 8.22 o -2 5 1 1150.16 1028.03 22.57 o 0 5 1 3475.55 3626.37 76.28 o 2 5 1 1423.62 1545.67 22.62 o 4 5 1 454.44 464.87 11.00 o 6 5 1 833.26 800.56 19.81 o 8 5 1 23.71 45.89 13.80 o -9 6 1 179.78 199.46 23.34 o -7 6 1 33.87 34.68 15.14 o -5 6 1 87.59 84.71 7.44 o -3 6 1 219.97 228.79 9.88 o -1 6 1 0.44 1.57 4.66 o 1 6 1 3953.88 4168.41 50.61 o 3 6 1 112.70 110.63 9.36 o 5 6 1 317.11 313.94 19.32 o 7 6 1 58.91 48.16 9.99 o 9 6 1 1.46 -1.41 13.75 o -10 7 1 37.46 60.09 22.39 o -8 7 1 889.92 847.26 36.68 o -6 7 1 77.77 76.30 10.26 o -4 7 1 100.09 112.44 10.04 o -2 7 1 267.14 292.68 13.89 o 0 7 1 2068.06 2125.28 25.09 o 2 7 1 3073.17 3426.46 42.56 o 4 7 1 409.04 384.44 12.74 o 6 7 1 2028.40 2161.49 34.43 o 8 7 1 15.20 47.96 13.64 o -9 8 1 102.02 117.70 36.68 o -7 8 1 33.68 55.10 10.92 o -5 8 1 51.69 65.99 8.13 o -3 8 1 15.42 28.01 7.58 o -1 8 1 33.55 31.02 7.39 o 1 8 1 108.25 128.02 11.01 o 3 8 1 236.89 236.11 13.83 o 5 8 1 112.71 109.14 9.61 o 7 8 1 39.35 44.81 10.30 o 9 8 1 10.63 10.81 19.64 o -8 9 1 149.24 139.14 20.30 o -6 9 1 124.08 121.68 11.81 o -4 9 1 5.24 -1.38 7.08 o -2 9 1 748.77 749.10 15.48 o 0 9 1 1325.54 1323.92 23.43 o 2 9 1 70.87 86.58 11.07 o 4 9 1 127.15 115.42 10.49 o 6 9 1 76.13 85.64 10.52 o 8 9 1 4.16 25.48 13.80 o -9 10 1 122.85 157.24 25.53 o -7 10 1 21.66 33.28 15.14 o -5 10 1 637.59 618.01 22.29 o -3 10 1 77.22 83.68 10.74 o -1 10 1 347.79 370.80 13.28 o 1 10 1 911.18 822.13 17.34 o 3 10 1 89.40 88.01 11.25 o 5 10 1 799.56 758.43 37.48 o 7 10 1 64.21 71.30 12.04 o -8 11 1 0.70 3.21 13.85 o -6 11 1 42.93 64.91 12.43 o -4 11 1 624.71 594.47 27.35 o -2 11 1 19.35 22.82 6.83 o 0 11 1 89.33 100.56 8.44 o 2 11 1 25.77 24.65 6.07 o 4 11 1 272.87 268.66 17.26 o 6 11 1 193.55 180.45 16.08 o 8 11 1 2.51 10.88 14.58 o -7 12 1 23.55 -8.74 14.91 o -5 12 1 463.25 465.82 26.74 o -3 12 1 237.16 257.29 13.93 o -1 12 1 245.52 270.95 26.77 o 1 12 1 48.73 51.95 7.85 o 3 12 1 351.40 350.16 29.89 o 5 12 1 139.74 143.56 14.67 o 7 12 1 108.29 135.38 21.06 o -8 13 1 17.50 11.48 18.22 o -6 13 1 34.05 25.12 15.65 o -4 13 1 422.64 428.87 36.64 o -2 13 1 774.44 742.36 20.87 o 0 13 1 1964.90 1762.62 32.64 o 2 13 1 112.53 100.36 16.04 o 4 13 1 263.64 232.09 18.66 o 6 13 1 127.06 125.00 20.00 o -7 14 1 2.62 -15.90 15.90 o -5 14 1 120.80 91.61 17.46 o -3 14 1 92.42 92.87 16.01 o -1 14 1 117.11 113.26 11.31 o 1 14 1 14.10 20.77 8.48 o 3 14 1 9.16 3.58 9.44 o 5 14 1 6.47 19.71 18.56 o 7 14 1 18.74 19.17 23.41 o -6 15 1 11.73 10.40 15.78 o -4 15 1 23.15 6.03 14.52 o -2 15 1 83.00 107.30 13.23 o 0 15 1 448.05 403.09 17.32 o 2 15 1 44.23 64.01 13.18 o 4 15 1 217.96 197.55 14.64 o 6 15 1 30.55 36.31 18.45 o -5 16 1 46.72 42.20 17.12 o -3 16 1 6.54 7.20 14.21 o -1 16 1 17.49 12.11 11.83 o 1 16 1 21.42 26.39 10.15 o 3 16 1 114.21 138.58 13.43 o 5 16 1 2.86 13.59 16.00 o -4 17 1 56.09 57.96 17.93 o -2 17 1 24.57 64.62 16.86 o 0 17 1 14.79 31.31 10.70 o 2 17 1 90.05 117.80 15.81 o 4 17 1 21.90 18.07 17.21 o -3 18 1 8.20 5.85 16.25 o -1 18 1 40.30 14.87 15.46 o 1 18 1 6.09 -1.99 12.48 o 3 18 1 37.18 35.68 13.28 o -2 19 1 157.37 149.94 22.32 o 0 19 1 12.36 5.95 15.05 o 2 19 1 95.85 141.36 29.97 o -10 0 2 175.32 209.62 33.75 o -8 0 2 75.51 62.68 17.12 o -6 0 2 1715.03 1751.55 34.96 o -4 0 2 369.52 393.65 25.82 o -2 0 2 36209.20 37836.62 694.85 o 0 0 2 14586.82 14935.22 281.03 o 2 0 2 1856.49 1821.11 53.33 o 4 0 2 1510.34 1672.43 27.66 o 6 0 2 972.59 849.89 26.70 o 8 0 2 275.05 239.26 21.62 o -9 1 2 151.98 176.38 45.88 o -7 1 2 9.68 10.92 9.97 o -5 1 2 734.84 780.13 16.32 o -3 1 2 2902.91 2888.72 75.35 o -1 1 2 200.96 166.15 10.09 o 1 1 2 12355.60 12028.86 287.56 o 3 1 2 169.25 178.95 7.52 o 5 1 2 106.51 113.58 6.98 o 7 1 2 290.12 293.82 13.16 o 9 1 2 10.09 12.33 11.33 o -10 2 2 28.31 21.51 17.55 o -8 2 2 166.51 189.45 14.20 o -6 2 2 189.64 211.23 9.70 o -4 2 2 1439.79 1449.68 35.23 o -2 2 2 4932.72 4858.87 73.47 o 0 2 2 2476.78 2540.35 41.13 o 4 2 2 1426.45 1415.86 17.82 o 6 2 2 355.26 341.12 14.52 o 8 2 2 140.99 137.40 13.14 o -9 3 2 79.74 66.10 17.88 o -7 3 2 143.46 127.30 10.58 o -5 3 2 15.21 22.23 6.25 o -3 3 2 138.41 126.74 16.85 o -1 3 2 869.93 833.30 18.80 o 1 3 2 26538.65 27647.02 362.25 o 3 3 2 204.06 212.29 8.74 o 5 3 2 184.40 185.50 8.53 o 7 3 2 246.75 237.19 12.47 o 9 3 2 6.81 4.55 11.28 o -10 4 2 55.66 27.73 23.32 o -8 4 2 0.41 4.64 10.48 o -6 4 2 25.62 22.86 7.51 o -4 4 2 687.76 732.65 19.15 o -2 4 2 312.82 294.03 12.78 o 0 4 2 5279.31 5476.14 79.04 o 2 4 2 579.92 625.21 12.77 o 4 4 2 9.73 5.42 5.03 o 6 4 2 36.29 44.67 7.62 o 8 4 2 11.32 0.11 9.83 o -9 5 2 25.84 17.56 16.60 o -7 5 2 125.43 143.68 14.25 o -5 5 2 400.63 420.45 14.46 o -3 5 2 1138.89 1180.11 20.15 o -1 5 2 193.27 171.05 7.34 o 1 5 2 687.41 626.74 14.69 o 3 5 2 258.00 261.90 17.98 o 5 5 2 136.85 135.85 8.65 o 7 5 2 42.25 43.02 9.79 o 9 5 2 2.94 21.61 14.37 o -10 6 2 26.66 24.95 18.99 o -8 6 2 410.52 436.70 22.64 o -6 6 2 91.42 112.94 9.35 o -4 6 2 5762.84 6252.54 61.58 o -2 6 2 127.42 125.43 7.37 o 0 6 2 1505.71 1610.53 22.01 o 2 6 2 551.28 600.87 13.60 o 4 6 2 236.54 253.53 10.21 o 6 6 2 682.75 655.59 19.12 o 8 6 2 38.66 37.87 13.33 o -9 7 2 211.71 210.82 23.40 o -7 7 2 79.66 67.27 12.68 o -5 7 2 326.98 317.38 13.65 o -3 7 2 5.96 4.79 6.61 o -1 7 2 23.46 28.56 4.28 o 1 7 2 1893.29 1995.99 25.86 o 3 7 2 478.53 449.04 19.92 o 5 7 2 471.56 420.80 17.69 o 7 7 2 82.77 84.50 12.07 o 9 7 2 1.70 -3.31 14.86 o -10 8 2 35.77 50.22 20.80 o -8 8 2 762.90 695.49 33.31 o -6 8 2 137.66 126.49 12.09 o -4 8 2 1350.79 1455.16 26.69 o -2 8 2 167.92 172.31 14.16 o 0 8 2 478.77 505.64 11.26 o 2 8 2 460.47 539.10 28.97 o 4 8 2 23.34 21.81 8.56 o 6 8 2 2101.61 1947.39 33.80 o 8 8 2 13.36 28.62 11.50 o -9 9 2 24.83 24.64 17.95 o -7 9 2 168.59 166.25 14.22 o -5 9 2 103.49 96.72 11.76 o -3 9 2 341.12 327.62 14.41 o -1 9 2 32.16 35.81 6.20 o 1 9 2 401.40 402.19 14.27 o 3 9 2 50.68 48.39 7.31 o 5 9 2 254.12 238.59 12.65 o 7 9 2 22.23 41.34 11.28 o -8 10 2 39.81 49.88 17.74 o -6 10 2 37.48 28.98 12.02 o -4 10 2 335.44 347.50 16.36 o -2 10 2 218.61 217.04 11.03 o 0 10 2 353.66 375.67 12.27 o 2 10 2 5.50 9.11 7.99 o 4 10 2 164.76 165.99 14.49 o 6 10 2 53.53 57.44 11.70 o 8 10 2 46.45 52.16 14.14 o -9 11 2 12.39 -5.66 17.61 o -7 11 2 1.75 16.07 11.72 o -5 11 2 193.34 188.16 18.62 o -3 11 2 13.17 19.00 11.38 o -1 11 2 874.88 871.54 24.72 o 1 11 2 590.03 613.64 16.40 o 3 11 2 273.79 263.51 16.28 o 5 11 2 4.30 13.25 11.38 o 7 11 2 40.07 41.71 12.68 o -8 12 2 17.22 38.23 15.48 o -6 12 2 124.15 129.35 18.13 o -4 12 2 239.93 234.96 56.61 o -2 12 2 205.84 192.21 13.91 o 0 12 2 240.77 252.14 11.46 o 2 12 2 5.74 12.11 8.86 o 4 12 2 68.55 62.43 12.08 o 6 12 2 21.02 34.78 15.96 o -7 13 2 61.74 78.23 19.22 o -5 13 2 61.87 98.91 20.49 o -3 13 2 42.78 58.90 14.06 o -1 13 2 108.84 113.17 13.16 o 1 13 2 364.10 329.76 18.56 o 3 13 2 42.07 24.94 11.16 o 5 13 2 192.41 211.38 17.42 o 7 13 2 11.84 18.62 14.71 o -6 14 2 132.96 136.34 20.52 o -4 14 2 482.19 480.01 27.71 o -2 14 2 848.32 742.63 32.25 o 0 14 2 199.32 176.66 11.60 o 2 14 2 15.23 9.18 8.53 o 4 14 2 5.59 30.10 15.08 o 6 14 2 3.59 -10.97 12.32 o -7 15 2 5.07 9.78 18.91 o -5 15 2 48.53 27.07 15.62 o -3 15 2 286.10 290.02 22.91 o -1 15 2 12.74 2.88 13.72 o 1 15 2 103.05 129.36 14.40 o 3 15 2 76.14 87.62 11.62 o 5 15 2 19.63 13.58 13.03 o -6 16 2 15.85 23.37 17.77 o -4 16 2 375.96 387.71 27.61 o -2 16 2 153.50 181.88 20.91 o 0 16 2 89.93 103.05 12.10 o 2 16 2 182.42 211.81 15.91 o 4 16 2 37.42 55.47 12.63 o -5 17 2 111.17 89.37 27.92 o -3 17 2 157.75 146.01 20.48 o -1 17 2 75.56 134.81 36.59 o 1 17 2 27.05 43.08 10.79 o 3 17 2 1.31 22.70 11.97 o -4 18 2 104.53 120.08 20.80 o -2 18 2 22.81 13.95 15.77 o 0 18 2 80.63 107.73 20.36 o 2 18 2 4.10 -2.92 12.33 o -1 19 2 13.21 18.66 17.69 o 1 19 2 15.18 19.17 17.26 o -10 1 3 21.03 43.59 17.07 o -8 1 3 181.62 206.40 14.91 o -6 1 3 253.06 277.11 12.30 o -4 1 3 310.09 277.15 19.45 o -2 1 3 41549.69 45330.37 589.07 o 0 1 3 3582.56 3481.59 57.50 o 2 1 3 1220.60 1321.57 16.56 o 4 1 3 341.62 325.76 8.79 o 6 1 3 322.52 293.34 11.40 o 8 1 3 184.31 154.04 14.24 o -11 2 3 17.79 36.15 19.75 o -9 2 3 174.46 187.57 21.02 o -7 2 3 34.27 37.83 13.27 o -5 2 3 441.72 460.10 15.08 o -3 2 3 2547.73 2600.58 49.22 o -1 2 3 12156.76 12318.27 169.66 o 1 2 3 1468.37 1417.44 46.18 o 3 2 3 63.58 76.03 6.43 o 5 2 3 39.36 42.50 5.44 o 7 2 3 19.30 12.91 8.27 o 9 2 3 34.30 46.33 12.75 o -10 3 3 8.81 -5.87 21.77 o -8 3 3 70.73 72.17 11.89 o -6 3 3 250.50 256.55 12.32 o -4 3 3 1464.47 1548.98 37.31 o -2 3 3 262.34 234.08 10.15 o 0 3 3 6.42 12.40 9.31 o 2 3 3 31.78 30.90 4.60 o 4 3 3 55.45 52.00 5.53 o 6 3 3 50.00 56.48 7.75 o 8 3 3 43.68 44.31 11.68 o -9 4 3 219.34 188.95 29.42 o -7 4 3 130.95 134.51 12.25 o -5 4 3 44.19 68.04 9.04 o -3 4 3 782.46 825.28 33.52 o -1 4 3 763.83 754.17 16.39 o 1 4 3 7821.11 8238.94 73.80 o 3 4 3 10.97 20.42 6.34 o 5 4 3 459.65 421.76 11.34 o 7 4 3 200.77 211.88 18.82 o 9 4 3 10.77 13.46 12.31 o -10 5 3 76.04 64.67 26.09 o -8 5 3 909.11 864.92 25.74 o -6 5 3 158.77 173.04 11.80 o -4 5 3 60.85 62.88 8.13 o -2 5 3 218.54 223.94 8.65 o 0 5 3 1585.85 1581.07 23.20 o 2 5 3 3161.05 3202.60 33.19 o 4 5 3 353.81 345.13 10.78 o 6 5 3 1699.68 1648.72 30.41 o 8 5 3 1.55 22.30 13.55 o -9 6 3 307.95 321.39 25.66 o -7 6 3 2.54 9.07 9.58 o -5 6 3 9.94 14.68 6.95 o -3 6 3 549.25 533.09 14.02 o -1 6 3 1323.27 1228.52 18.14 o 1 6 3 6865.21 7377.77 62.22 o 3 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