#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/44/2204466.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2204466_Fobs loop_ _publ_author_name 'You, Zhong-Lu' 'Ma, Ji-Long' 'Zhu, Hai-Liang' 'Liu, Wei-Sheng' _publ_section_title ; Tetrakis{\m-1-[2-(2-oxidoethylamino)ethyliminomethyl]-2-naphtholato}tetrazinc(II) ; _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m1599 _journal_page_last m1601 _journal_volume 60 _journal_year 2004 _space_group_IT_number 86 _symmetry_space_group_name_Hall '-P 4bc' _symmetry_space_group_name_H-M 'P 42/n :2' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 18.2300 _cell_length_b 18.2300 _cell_length_c 8.5310 _exptl_crystal_F_000 1328.00 _reflns_d_resolution_high 0.7824 _[local]_cod_data_source_file ci6463Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' CI6463 C60 H64 N8 O8 ZN4' _shelx_refln_list_code 4 _shelx_f_calc_maximum 269.24 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y+1/2, z' '-y, x+1/2, z+1/2' 'y+1/2, -x, z+1/2' '-x, -y, -z' 'x-1/2, y-1/2, -z' 'y, -x-1/2, -z-1/2' '-y-1/2, x, -z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 1 0 40125.14 47154.68 6951.65 o 0 2 0 11211.80 11382.18 711.16 o 2 2 0 14996.04 14216.48 317.93 o -1 3 0 15063.27 18323.17 102.00 o 1 3 0 28554.94 27864.29 1116.49 o 3 3 0 8151.12 9166.04 1120.96 o -2 4 0 814.28 830.59 22.49 o 0 4 0 23467.57 23524.90 724.99 o 2 4 0 72489.55 73042.45 1192.32 o 4 4 0 12568.97 12242.33 2922.07 o -3 5 0 4051.04 3953.39 571.93 o -1 5 0 9896.58 9759.57 888.98 o 1 5 0 7314.58 7273.70 617.33 o 3 5 0 51732.23 47207.42 1096.43 o 5 5 0 4730.44 5921.95 1036.37 o -4 6 0 26472.27 27368.74 1224.36 o -2 6 0 1991.84 1881.47 187.91 o 0 6 0 1947.69 2064.55 97.77 o 2 6 0 12525.46 10893.68 1187.90 o 4 6 0 4.74 8.42 10.92 o 6 6 0 64.42 71.17 12.34 o -5 7 0 4163.97 4471.46 265.82 o -3 7 0 28526.75 35288.21 1917.47 o -1 7 0 3318.34 3049.02 206.99 o 1 7 0 88.49 95.11 38.78 o 3 7 0 917.54 939.01 47.84 o 5 7 0 1291.68 1340.60 239.43 o 7 7 0 12424.56 16561.65 2044.53 o -6 8 0 317.37 345.05 55.85 o -4 8 0 5819.50 7313.18 582.94 o -2 8 0 5391.84 6119.62 672.80 o 0 8 0 2178.03 2174.08 176.83 o 2 8 0 290.38 260.61 13.90 o 4 8 0 30216.89 28008.65 649.61 o 6 8 0 2564.54 2790.81 461.84 o 8 8 0 27671.78 26481.04 5928.22 o -7 9 0 4321.85 4747.43 615.56 o -5 9 0 39.06 85.95 26.57 o -3 9 0 624.40 805.40 113.59 o -1 9 0 445.70 527.07 19.13 o 1 9 0 8012.53 8482.70 550.82 o 3 9 0 18758.00 18237.74 1328.53 o 5 9 0 2729.04 2212.36 216.91 o 7 9 0 6418.49 5943.39 424.08 o 9 9 0 8778.37 9809.79 173.69 o -8 10 0 6111.11 5274.22 1193.58 o -6 10 0 881.77 1121.64 134.08 o -4 10 0 222.56 218.80 17.47 o -2 10 0 6854.43 6790.79 327.83 o 0 10 0 4480.62 4623.72 69.62 o 2 10 0 4072.78 3646.96 133.89 o 4 10 0 25277.93 22981.06 1585.05 o 6 10 0 400.17 428.49 43.56 o 8 10 0 2218.14 1818.70 393.45 o 10 10 0 89.00 131.08 34.43 o -9 11 0 804.90 604.74 81.40 o -7 11 0 3984.70 4131.90 958.17 o -5 11 0 2417.15 2402.55 140.46 o -3 11 0 3666.14 3561.18 205.80 o -1 11 0 19218.52 19551.63 1145.40 o 1 11 0 1846.38 1710.80 174.63 o 3 11 0 7875.47 7163.97 1005.82 o 5 11 0 1568.34 1277.69 369.37 o 7 11 0 76.40 55.36 23.86 o 9 11 0 338.76 436.85 53.32 o 11 11 0 1094.11 894.44 143.39 o -10 12 0 14.28 10.53 21.03 o -8 12 0 384.06 466.14 146.36 o -6 12 0 8858.97 9450.78 1578.71 o -4 12 0 1172.20 1167.45 90.21 o -2 12 0 7285.02 7042.47 178.17 o 0 12 0 12682.55 12207.88 371.02 o 2 12 0 552.32 454.31 47.03 o 4 12 0 2037.62 1965.98 296.41 o 6 12 0 95.82 94.17 26.50 o 8 12 0 511.30 379.91 42.37 o 10 12 0 4835.55 4604.87 657.86 o 12 12 0 1310.83 966.45 163.31 o -11 13 0 178.70 186.31 40.21 o -9 13 0 201.32 229.96 41.22 o -7 13 0 9603.99 10120.37 2023.97 o -5 13 0 6697.38 7557.64 1210.62 o -3 13 0 34.71 20.38 13.36 o -1 13 0 4598.01 4326.79 381.05 o 1 13 0 3419.71 3560.14 233.45 o 3 13 0 276.92 292.08 47.49 o 5 13 0 93.33 58.40 24.04 o 7 13 0 30.94 66.37 29.11 o 9 13 0 825.86 1153.59 163.09 o 11 13 0 5351.37 4748.54 822.36 o 13 13 0 124.90 114.60 37.42 o -12 14 0 1159.03 1069.82 97.97 o -10 14 0 3119.63 2970.28 666.70 o -8 14 0 241.16 267.13 84.07 o -6 14 0 3443.52 3420.47 914.53 o -4 14 0 1916.89 2081.04 264.95 o -2 14 0 23.47 40.03 20.69 o 0 14 0 189.65 208.36 29.18 o 2 14 0 1183.43 1181.27 137.98 o 4 14 0 5854.11 5377.56 648.88 o 6 14 0 2655.46 1968.83 84.15 o 8 14 0 127.55 95.57 51.89 o 10 14 0 2632.17 2225.99 244.93 o 12 14 0 589.89 486.83 53.52 o 14 14 0 1.44 1.07 27.60 o -13 15 0 133.78 128.99 39.48 o -11 15 0 3423.04 3427.96 752.78 o -9 15 0 1345.03 1264.22 239.13 o -7 15 0 7.42 -10.09 26.25 o -5 15 0 26.61 8.75 18.26 o -3 15 0 860.84 1046.38 92.31 o -1 15 0 201.20 210.00 41.93 o 1 15 0 3787.92 4015.68 266.24 o 3 15 0 297.10 240.86 65.17 o 5 15 0 5162.99 3994.96 281.95 o 7 15 0 923.22 1018.86 148.89 o 9 15 0 94.41 75.34 33.04 o 11 15 0 56.48 58.13 32.97 o 13 15 0 184.27 113.30 39.89 o 15 15 0 634.57 504.95 59.54 o -14 16 0 499.29 530.72 78.50 o -12 16 0 223.47 169.15 43.19 o -10 16 0 1875.53 1797.43 135.07 o -8 16 0 0.47 3.78 28.16 o -6 16 0 843.43 792.57 66.02 o -4 16 0 663.65 679.46 62.22 o -2 16 0 229.85 257.86 32.49 o 0 16 0 4412.66 4473.15 143.22 o 2 16 0 1957.29 1799.07 272.47 o 4 16 0 40.95 20.52 19.79 o 6 16 0 1593.47 1487.96 635.41 o 8 16 0 1385.79 1092.51 68.93 o 10 16 0 45.84 11.12 31.76 o 12 16 0 966.17 916.52 78.26 o 14 16 0 9.83 9.66 31.74 o 16 16 0 568.94 481.98 86.97 o -15 17 0 1066.67 1199.31 128.15 o -13 17 0 114.40 94.01 42.90 o -11 17 0 9.26 -2.76 30.73 o -9 17 0 1.28 -9.44 34.71 o -7 17 0 294.24 312.78 53.38 o -5 17 0 34.27 37.41 35.26 o -3 17 0 53.01 35.16 27.79 o -1 17 0 1224.04 1336.22 98.81 o 1 17 0 2002.66 1882.35 217.31 o 3 17 0 989.90 795.25 132.17 o 5 17 0 58.18 54.19 32.98 o 7 17 0 16.15 19.60 25.97 o 9 17 0 109.34 92.34 34.86 o 11 17 0 2255.14 2259.98 115.03 o 13 17 0 951.23 854.71 74.99 o 15 17 0 5.55 0.89 37.76 o -14 18 0 104.12 66.45 47.72 o -12 18 0 3.33 -7.65 26.76 o -10 18 0 297.97 372.27 94.70 o -8 18 0 193.29 216.81 50.63 o -6 18 0 205.63 223.42 51.19 o -4 18 0 9103.82 9105.90 193.26 o -2 18 0 123.41 166.07 39.63 o 0 18 0 915.51 1007.92 145.83 o 2 18 0 114.30 116.45 48.21 o 4 18 0 174.21 154.11 40.17 o 6 18 0 1930.69 1543.47 327.44 o 8 18 0 686.39 534.24 62.69 o 10 18 0 255.07 199.77 48.90 o 12 18 0 1201.65 1202.74 100.65 o -11 19 0 42.79 73.89 68.39 o -9 19 0 842.51 998.04 87.69 o -7 19 0 240.89 277.66 54.86 o -5 19 0 1752.08 1949.23 148.15 o -3 19 0 654.59 763.81 70.79 o -1 19 0 5.02 -8.85 28.05 o 1 19 0 9.31 14.76 28.09 o 3 19 0 262.95 290.92 94.64 o 5 19 0 312.52 265.48 52.93 o 7 19 0 2712.59 2234.88 309.53 o 9 19 0 212.14 155.56 45.52 o 11 19 0 224.98 318.87 58.21 o -10 20 0 325.95 347.58 60.56 o -8 20 0 787.98 840.58 82.68 o -6 20 0 48.15 30.48 38.20 o -4 20 0 578.01 568.55 65.91 o -2 20 0 28.52 34.88 38.16 o 0 20 0 688.29 675.89 54.49 o 2 20 0 898.22 787.36 122.89 o 4 20 0 436.66 322.27 99.38 o 6 20 0 1279.55 907.82 145.25 o 8 20 0 954.46 915.37 79.45 o 10 20 0 47.92 49.06 39.42 o -7 21 0 190.30 249.84 56.55 o -5 21 0 168.72 145.42 46.16 o -3 21 0 1024.79 983.89 124.73 o -1 21 0 11.20 19.97 35.07 o 1 21 0 1323.08 1232.47 289.48 o 3 21 0 2766.76 2622.29 286.55 o 5 21 0 2.05 -11.68 29.28 o 7 21 0 307.11 397.96 85.71 o -4 22 0 473.99 461.06 67.63 o -2 22 0 1333.86 1785.15 112.61 o 0 22 0 112.66 98.05 42.02 o 2 22 0 1386.92 1459.94 169.67 o 4 22 0 468.37 408.41 134.84 o 3 23 0 121.44 169.93 78.50 o 0 1 1 50783.19 55083.10 887.03 o 1 1 1 235.60 282.20 8.48 o -1 2 1 815.23 881.33 43.29 o 0 2 1 6185.23 7039.58 170.74 o 1 2 1 14342.04 14944.24 386.35 o 2 2 1 6603.75 7121.86 180.57 o -2 3 1 27082.39 28614.74 881.88 o -1 3 1 170.04 149.79 12.35 o 0 3 1 20190.90 21523.25 585.83 o 1 3 1 3018.98 3239.74 110.08 o 2 3 1 30643.30 30680.79 496.34 o 3 3 1 6446.91 7550.18 254.59 o -3 4 1 1886.56 1986.94 44.49 o -2 4 1 11.91 18.25 4.68 o -1 4 1 2612.89 2755.78 163.54 o 0 4 1 2244.30 2398.80 110.52 o 1 4 1 15602.99 14990.93 817.62 o 2 4 1 31914.04 33866.96 464.21 o 3 4 1 38103.55 39302.56 606.09 o 4 4 1 46.42 57.86 7.21 o -4 5 1 2058.16 1993.74 53.39 o -3 5 1 10730.29 12075.19 266.33 o -2 5 1 2798.35 3122.88 56.44 o -1 5 1 56.94 56.90 6.17 o 0 5 1 10737.38 10982.78 212.07 o 1 5 1 2168.25 2143.39 67.10 o 2 5 1 13635.59 12363.14 624.37 o 3 5 1 8099.77 8376.72 126.69 o 4 5 1 2384.86 2291.61 53.66 o 5 5 1 1040.57 1096.88 87.36 o -5 6 1 10619.85 12425.56 789.56 o -4 6 1 7023.06 8263.26 158.66 o -3 6 1 16877.48 15199.34 1760.13 o -2 6 1 282.64 290.11 13.29 o -1 6 1 41.98 44.69 5.87 o 0 6 1 8.73 4.96 3.90 o 1 6 1 4829.12 4700.79 117.22 o 2 6 1 3210.75 2969.37 129.78 o 3 6 1 2594.98 2220.93 117.87 o 4 6 1 3.10 -1.34 5.70 o 5 6 1 45.95 54.19 8.53 o 6 6 1 255.54 262.63 27.85 o -6 7 1 7565.06 8755.20 613.66 o -5 7 1 104.65 104.39 9.75 o -4 7 1 17355.14 18380.23 1109.04 o -3 7 1 1429.15 1514.10 84.90 o -2 7 1 16478.91 17723.60 1175.67 o -1 7 1 714.15 760.92 25.66 o 0 7 1 33.02 25.72 4.97 o 1 7 1 6.04 8.93 4.39 o 2 7 1 2057.26 1709.23 131.13 o 3 7 1 500.18 577.14 17.32 o 4 7 1 1142.58 1014.32 51.89 o 5 7 1 1567.49 1742.83 173.34 o 6 7 1 115.16 74.77 10.33 o 7 7 1 16.05 23.54 10.07 o -7 8 1 11410.30 12069.33 689.03 o -6 8 1 646.48 760.17 26.87 o -5 8 1 1131.38 1235.90 78.99 o -4 8 1 10.15 23.20 7.69 o -3 8 1 1134.74 1004.39 60.73 o -2 8 1 2376.85 2624.01 70.73 o -1 8 1 2449.01 2238.61 70.87 o 0 8 1 299.82 293.28 17.18 o 1 8 1 12.07 10.01 4.69 o 2 8 1 2642.57 2654.39 147.96 o 3 8 1 15992.50 15369.82 790.58 o 4 8 1 2568.05 2409.42 77.37 o 5 8 1 5510.38 5428.46 242.84 o 6 8 1 167.85 164.86 13.79 o 7 8 1 9664.37 11411.76 531.16 o 8 8 1 12.81 17.98 10.97 o -8 9 1 9070.75 8247.58 656.26 o -7 9 1 195.22 178.35 15.07 o -6 9 1 2694.20 2649.76 154.49 o -5 9 1 11.00 16.61 7.86 o -4 9 1 3.70 12.80 7.27 o -3 9 1 155.85 166.86 10.43 o -2 9 1 948.80 1057.18 74.53 o -1 9 1 5108.46 5224.41 239.90 o 0 9 1 365.40 381.12 14.43 o 1 9 1 177.53 198.75 10.17 o 2 9 1 10354.69 9649.92 476.81 o 3 9 1 79.99 51.42 8.27 o 4 9 1 12580.46 11079.00 254.62 o 5 9 1 257.15 249.21 15.27 o 6 9 1 14.01 15.74 13.45 o 7 9 1 33.58 36.32 15.41 o 8 9 1 10231.32 9367.81 1357.77 o 9 9 1 306.96 318.88 27.35 o -9 10 1 2693.27 2375.42 175.06 o -8 10 1 8.96 7.00 11.78 o -7 10 1 2382.04 2492.48 305.85 o -6 10 1 730.74 936.96 86.97 o -5 10 1 829.99 1085.28 107.07 o -4 10 1 4.66 1.47 6.45 o -3 10 1 3372.68 3971.37 240.92 o -2 10 1 98.91 91.28 7.83 o -1 10 1 3897.28 3744.22 112.17 o 0 10 1 3492.96 3938.00 134.46 o 1 10 1 0.73 2.08 5.32 o 2 10 1 177.39 170.89 15.13 o 3 10 1 16184.70 14036.15 1051.36 o 4 10 1 3.86 -4.85 7.17 o 5 10 1 5693.95 4609.29 157.75 o 6 10 1 45.63 51.47 18.39 o 7 10 1 707.80 575.76 33.63 o 8 10 1 536.91 504.05 32.41 o 9 10 1 801.55 802.45 39.85 o 10 10 1 356.78 365.09 29.08 o -10 11 1 127.54 113.90 20.00 o -9 11 1 220.65 223.30 23.05 o -8 11 1 262.82 310.08 24.97 o -7 11 1 373.20 356.75 33.65 o -6 11 1 3053.14 3255.62 268.19 o -5 11 1 109.04 145.94 13.57 o -4 11 1 122.27 127.03 13.18 o -3 11 1 157.25 173.25 12.55 o -2 11 1 11434.45 11989.05 680.04 o -1 11 1 149.91 159.76 11.26 o 0 11 1 9847.58 9135.58 414.55 o 1 11 1 84.78 87.69 11.15 o 2 11 1 7859.35 7425.66 251.73 o 3 11 1 331.15 297.98 24.95 o 4 11 1 7779.26 6142.97 339.77 o 5 11 1 60.68 40.68 14.37 o 6 11 1 29.10 36.44 15.97 o 7 11 1 422.53 335.66 26.41 o 8 11 1 21.11 34.18 17.75 o 9 11 1 25.04 31.99 17.99 o 10 11 1 1638.38 1567.53 70.83 o 11 11 1 222.76 211.34 24.90 o -11 12 1 201.14 145.67 22.59 o -10 12 1 553.12 481.90 30.88 o -9 12 1 121.16 142.16 20.49 o -8 12 1 1024.88 1231.86 100.92 o -7 12 1 6814.90 6802.50 495.78 o -6 12 1 58.54 54.00 14.23 o -5 12 1 5478.82 5510.88 456.62 o -4 12 1 449.46 423.86 30.10 o -3 12 1 1532.26 1608.83 86.10 o -2 12 1 253.44 223.61 13.59 o -1 12 1 11468.57 10433.97 665.66 o 0 12 1 18.71 27.59 9.02 o 1 12 1 4045.19 3997.40 74.01 o 2 12 1 109.96 115.32 15.08 o 3 12 1 220.70 193.53 16.38 o 4 12 1 60.92 52.69 13.40 o 5 12 1 62.28 55.66 27.33 o 6 12 1 49.52 45.62 15.93 o 7 12 1 254.81 241.53 26.95 o 8 12 1 219.04 230.37 26.94 o 9 12 1 2768.13 2555.12 119.61 o 10 12 1 107.42 104.94 24.39 o 11 12 1 3500.22 3306.32 144.30 o 12 12 1 0.46 1.89 15.10 o -12 13 1 104.46 115.79 24.54 o -11 13 1 304.54 311.44 29.77 o -10 13 1 1080.55 1043.51 106.67 o -9 13 1 153.73 138.34 20.74 o -8 13 1 275.04 269.23 24.41 o -7 13 1 0.09 7.08 15.71 o -6 13 1 6490.90 6446.57 363.58 o -5 13 1 923.79 1056.72 48.42 o -4 13 1 1453.78 1448.89 69.32 o -3 13 1 839.26 788.94 33.39 o -2 13 1 2884.04 2761.82 99.31 o -1 13 1 181.22 172.04 15.86 o 0 13 1 1369.45 1223.61 42.50 o 1 13 1 30.92 38.60 13.39 o 2 13 1 92.55 78.36 14.75 o 3 13 1 804.93 720.79 76.24 o 4 13 1 2642.18 2262.05 138.44 o 5 13 1 23.13 13.02 14.25 o 6 13 1 2155.38 1673.67 135.85 o 7 13 1 22.22 17.67 19.41 o 8 13 1 102.05 63.44 20.94 o 9 13 1 148.52 168.77 28.15 o 10 13 1 3175.26 3316.62 148.82 o 11 13 1 121.84 103.32 25.66 o 12 13 1 1538.11 1415.73 77.29 o 13 13 1 88.02 83.71 24.04 o -13 14 1 256.33 235.20 31.90 o -12 14 1 71.91 54.09 25.57 o -11 14 1 2780.78 2950.23 164.51 o -10 14 1 11.48 -1.21 22.09 o -9 14 1 61.01 78.57 24.77 o -8 14 1 622.30 621.62 58.03 o -7 14 1 3909.95 3455.38 204.76 o -6 14 1 258.78 234.75 27.34 o -5 14 1 1926.81 2017.25 97.13 o -4 14 1 665.61 721.85 54.97 o -3 14 1 8.32 1.08 10.98 o -2 14 1 61.45 57.48 13.76 o -1 14 1 0.47 9.89 12.32 o 0 14 1 393.59 397.01 24.91 o 1 14 1 271.04 258.74 21.77 o 2 14 1 71.95 51.19 14.88 o 3 14 1 605.32 484.57 41.02 o 4 14 1 11.28 10.77 12.49 o 5 14 1 4658.29 3724.14 232.65 o 6 14 1 38.41 28.52 17.23 o 7 14 1 1183.10 1095.36 78.18 o 8 14 1 147.44 96.66 22.63 o 9 14 1 1541.19 1519.03 102.87 o 10 14 1 272.71 264.40 33.45 o 11 14 1 2014.18 1876.69 123.17 o 12 14 1 113.14 87.29 25.19 o 13 14 1 28.67 28.47 21.55 o 14 14 1 82.44 67.47 24.02 o -14 15 1 161.17 171.22 30.46 o -13 15 1 0.14 -3.63 20.75 o -12 15 1 1084.87 1035.22 118.45 o -11 15 1 32.78 44.89 22.17 o -10 15 1 3538.43 3366.20 434.62 o -9 15 1 62.92 53.56 19.98 o -8 15 1 31.63 39.37 17.08 o -7 15 1 312.21 273.43 29.88 o -6 15 1 2421.89 2243.06 180.37 o -5 15 1 21.86 28.55 17.57 o -4 15 1 772.48 765.80 77.43 o -3 15 1 316.73 334.51 26.43 o -2 15 1 243.34 229.26 21.56 o -1 15 1 807.70 830.08 51.54 o 0 15 1 4982.80 5178.46 170.75 o 1 15 1 279.60 252.43 21.67 o 2 15 1 1028.88 942.38 56.20 o 3 15 1 12.95 12.72 12.45 o 4 15 1 3193.56 2603.08 170.91 o 5 15 1 105.41 73.31 20.43 o 6 15 1 3718.06 2909.12 260.18 o 7 15 1 386.26 360.33 34.39 o 8 15 1 30.98 21.30 19.45 o 9 15 1 190.15 201.63 31.46 o 10 15 1 22.74 36.93 23.70 o 11 15 1 5.53 13.98 20.56 o 12 15 1 174.10 157.50 31.20 o 13 15 1 137.05 123.91 30.22 o 14 15 1 15.68 -12.41 20.22 o 15 15 1 53.38 45.28 24.83 o -15 16 1 1104.25 1133.01 80.87 o 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