#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:08:42 +0300 (Sun, 03 Apr 2016) $ #$Revision: 180969 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/49/2204990.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2204990_Fobs loop_ _publ_author_name 'Cheng, Pi Yun' 'Zeng, Jing Yao' 'Chiu, Pei Ling' 'Lee, Hon Man' _publ_section_title ; 1-(6-Bromopyridin-2-yl)-3-methyl-3H-imidazol-1-ium bromide monohydrate ; _journal_issue 2 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o509 _journal_page_last o510 _journal_volume 61 _journal_year 2005 _space_group_IT_number 33 _symmetry_space_group_name_Hall 'P 2c -2n' _symmetry_space_group_name_H-M 'P n a 21' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 7.1233 _cell_length_b 17.3399 _cell_length_c 9.5533 _exptl_crystal_F_000 656.00 _reflns_d_resolution_high 0.7392 _cod_data_source_file ac6155Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' jen068a in Pna2(1)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 275.41 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, z+1/2' 'x+1/2, -y+1/2, z' '-x+1/2, y+1/2, z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 0 0 -12 3660.31 3863.89 284.54 o 2 0 -12 469.81 472.96 86.27 o 1 1 -12 319.96 284.63 53.56 o 2 1 -12 315.95 383.11 57.87 o 3 1 -12 297.15 290.40 58.19 o 0 2 -12 713.94 783.55 66.33 o 1 2 -12 1424.19 1521.61 94.82 o 2 2 -12 362.89 376.27 56.16 o 3 2 -12 105.34 99.05 54.69 o 1 3 -12 86.38 67.80 49.40 o 2 3 -12 1426.06 1450.96 93.93 o 3 3 -12 247.63 279.99 56.81 o 0 4 -12 53.96 51.93 73.09 o 1 4 -12 473.93 431.29 57.79 o 2 4 -12 54.93 10.50 50.95 o 3 4 -12 847.83 792.75 72.60 o 1 5 -12 422.69 415.67 58.03 o 2 5 -12 301.94 182.15 54.21 o 0 6 -12 795.86 603.60 91.24 o 1 6 -12 764.89 763.21 67.72 o 2 6 -12 4.28 -43.46 52.25 o 1 7 -12 209.39 206.82 80.66 o 2 7 -12 251.62 167.42 80.17 o 0 8 -12 1836.84 1861.58 160.67 o 1 8 -12 540.98 383.11 87.66 o 2 0 -11 335.90 360.64 72.19 o 4 0 -11 888.31 972.71 106.70 o 0 1 -11 2475.70 2621.61 131.94 o 1 1 -11 1482.59 1411.49 88.80 o 2 1 -11 1378.59 1443.72 84.00 o 3 1 -11 288.96 299.93 51.36 o 4 1 -11 226.32 215.69 53.31 o 5 1 -11 346.73 417.13 60.47 o 1 2 -11 458.76 453.59 51.93 o 2 2 -11 1436.56 1377.38 86.93 o 3 2 -11 486.56 431.94 54.69 o 4 2 -11 1037.80 1085.11 78.95 o 0 3 -11 765.90 729.51 62.92 o 1 3 -11 755.87 727.15 62.92 o 2 3 -11 224.90 291.06 47.70 o 3 3 -11 91.67 148.38 48.27 o 4 3 -11 617.98 630.78 63.32 o 1 4 -11 1267.54 1166.17 79.84 o 2 4 -11 145.17 140.48 45.25 o 3 4 -11 1953.42 1835.94 107.44 o 4 4 -11 95.18 29.87 49.81 o 0 5 -11 516.25 440.65 52.09 o 1 5 -11 674.14 657.23 47.78 o 2 5 -11 17.85 31.50 44.20 o 3 5 -11 1150.94 1115.30 77.81 o 4 5 -11 242.66 248.73 54.61 o 1 6 -11 228.12 164.57 38.50 o 2 6 -11 1223.33 1138.18 76.91 o 3 6 -11 579.96 529.53 58.28 o 4 6 -11 272.87 322.15 56.16 o 0 7 -11 382.25 307.09 71.79 o 1 7 -11 1985.53 1867.93 113.46 o 2 7 -11 238.27 191.68 48.83 o 3 7 -11 185.05 161.81 50.54 o 4 7 -11 50.10 -8.55 52.33 o 1 8 -11 102.36 76.10 48.83 o 2 8 -11 375.20 361.62 78.14 o 3 8 -11 221.62 122.17 74.96 o 0 9 -11 3239.17 3237.74 244.42 o 1 9 -11 39.44 10.99 50.38 o 2 9 -11 829.20 719.58 94.41 o 3 9 -11 54.02 26.94 76.67 o 1 10 -11 476.74 522.45 63.24 o 2 10 -11 131.26 143.33 77.57 o 0 11 -11 199.30 151.31 82.86 o 1 11 -11 512.13 478.66 65.11 o 2 11 -11 196.96 129.01 80.41 o 1 12 -11 109.71 148.46 63.16 o 0 0 -10 1598.04 1706.86 125.18 o 2 0 -10 133.07 104.83 54.53 o 4 0 -10 1458.97 1465.29 126.97 o 6 0 -10 30.91 -37.77 69.18 o 1 1 -10 1247.80 1341.49 56.57 o 2 1 -10 2455.90 2473.40 131.85 o 3 1 -10 1286.26 1424.51 87.01 o 4 1 -10 850.58 932.58 66.98 o 5 1 -10 49.84 32.07 35.32 o 6 1 -10 517.06 494.53 59.25 o 0 2 -10 4943.94 5117.31 244.99 o 1 2 -10 261.67 253.05 28.08 o 2 2 -10 792.39 847.20 60.64 o 3 2 -10 1484.01 1561.41 93.19 o 4 2 -10 562.53 589.60 55.83 o 5 2 -10 509.99 426.90 43.71 o 6 2 -10 236.05 207.55 52.33 o 1 3 -10 183.60 168.32 26.29 o 2 3 -10 327.21 276.73 42.16 o 3 3 -10 406.89 405.41 47.70 o 4 3 -10 67.43 71.30 34.02 o 5 3 -10 725.67 662.28 50.71 o 0 4 -10 218.79 221.71 37.60 o 1 4 -10 4271.06 4399.93 155.21 o 2 4 -10 84.80 50.87 37.77 o 3 4 -10 385.34 436.01 49.24 o 4 4 -10 124.00 77.00 34.84 o 5 4 -10 413.18 414.77 44.77 o 1 5 -10 268.10 262.41 33.45 o 2 5 -10 647.32 584.96 52.42 o 3 5 -10 369.42 297.97 46.88 o 4 5 -10 0.15 -28.57 34.51 o 5 5 -10 1921.20 1869.80 154.07 o 0 6 -10 2124.31 2141.65 122.01 o 1 6 -10 1843.22 1730.05 81.23 o 2 6 -10 270.44 309.61 42.40 o 3 6 -10 237.55 179.22 44.44 o 4 6 -10 905.01 933.88 60.31 o 5 6 -10 34.56 31.91 47.53 o 1 7 -10 1403.69 1421.09 68.94 o 2 7 -10 92.23 59.33 40.61 o 3 7 -10 1890.15 1880.46 107.44 o 4 7 -10 262.37 271.11 48.27 o 5 7 -10 196.07 210.40 51.11 o 0 8 -10 573.25 489.32 76.18 o 1 8 -10 48.10 -42.00 42.00 o 2 8 -10 621.75 554.36 76.34 o 3 8 -10 225.69 217.07 67.88 o 4 8 -10 600.21 486.39 81.88 o 5 8 -10 160.44 82.12 73.50 o 1 9 -10 7.21 -43.71 43.71 o 2 9 -10 2640.83 2584.74 200.95 o 3 9 -10 13.51 10.34 66.50 o 4 9 -10 1529.80 1471.96 134.70 o 0 10 -10 728.31 692.07 94.17 o 1 10 -10 717.74 763.37 64.62 o 2 10 -10 548.33 551.59 83.26 o 3 10 -10 370.14 307.41 76.51 o 4 10 -10 349.79 196.64 77.32 o 1 11 -10 375.82 448.87 56.24 o 2 11 -10 202.71 194.28 75.21 o 3 11 -10 445.04 330.61 82.69 o 4 11 -10 299.74 301.64 84.73 o 0 12 -10 2267.10 2402.59 196.40 o 1 12 -10 924.43 984.67 75.94 o 2 12 -10 474.53 440.49 87.82 o 3 12 -10 101.34 148.21 83.18 o 1 13 -10 90.87 80.01 58.76 o 2 13 -10 52.02 -11.48 81.96 o 0 14 -10 492.68 535.15 101.49 o 1 14 -10 1113.07 1058.82 89.12 o 2 14 -10 65.31 118.42 92.22 o 2 0 -9 3265.65 3118.99 231.97 o 4 0 -9 1629.60 1745.11 105.32 o 6 0 -9 597.25 467.43 75.45 o 0 1 -9 1181.35 1271.58 81.15 o 1 1 -9 661.11 727.64 37.11 o 2 1 -9 2594.10 2471.69 133.64 o 3 1 -9 566.33 590.74 48.35 o 4 1 -9 802.39 819.45 48.67 o 5 1 -9 792.62 761.66 42.97 o 6 1 -9 65.95 56.32 44.11 o 1 2 -9 1350.59 1404.41 60.72 o 2 2 -9 680.42 739.85 49.00 o 3 2 -9 3123.72 3019.70 154.64 o 4 2 -9 1472.48 1433.46 73.25 o 5 2 -9 351.18 329.88 31.66 o 6 2 -9 1447.68 1382.19 86.84 o 0 3 -9 4023.14 3998.51 199.41 o 1 3 -9 1437.29 1465.04 56.65 o 2 3 -9 852.10 873.08 60.64 o 3 3 -9 333.62 332.16 32.64 o 4 3 -9 1029.80 1028.46 58.68 o 5 3 -9 66.85 81.15 32.48 o 6 3 -9 114.17 113.46 45.09 o 1 4 -9 706.54 744.16 35.16 o 2 4 -9 197.23 154.97 27.75 o 3 4 -9 1171.24 1190.51 65.52 o 4 4 -9 231.81 236.69 32.72 o 5 4 -9 1434.57 1467.16 76.51 o 6 4 -9 77.75 34.35 44.60 o 0 5 -9 1372.18 1407.50 80.66 o 1 5 -9 5119.16 5337.64 189.72 o 2 5 -9 61.70 76.75 27.02 o 3 5 -9 1102.33 1159.42 61.61 o 4 5 -9 494.91 459.13 39.31 o 5 5 -9 544.48 594.48 46.15 o 6 5 -9 47.19 -10.66 34.51 o 1 6 -9 219.94 247.59 28.65 o 2 6 -9 1569.26 1614.96 74.80 o 3 6 -9 1572.94 1564.34 79.36 o 4 6 -9 150.05 132.26 32.56 o 5 6 -9 1110.13 1063.21 63.49 o 6 6 -9 876.87 882.53 56.65 o 0 7 -9 1660.48 1524.46 126.56 o 1 7 -9 823.46 848.26 45.99 o 2 7 -9 331.27 341.44 34.02 o 3 7 -9 1301.59 1280.94 68.04 o 4 7 -9 157.65 150.41 34.92 o 5 7 -9 618.91 586.26 48.92 o 6 7 -9 37.51 54.86 44.44 o 1 8 -9 139.69 143.90 38.91 o 2 8 -9 2198.42 2107.30 117.28 o 3 8 -9 997.97 923.38 72.68 o 4 8 -9 893.35 852.49 71.71 o 5 8 -9 139.98 133.16 52.33 o 6 8 -9 339.86 334.03 53.80 o 0 9 -9 1635.34 1628.64 136.17 o 1 9 -9 195.19 148.05 40.37 o 2 9 -9 1313.14 1332.62 81.31 o 3 9 -9 49.02 47.61 58.93 o 4 9 -9 1359.16 1364.12 98.40 o 5 9 -9 61.48 44.93 43.06 o 1 10 -9 733.25 735.53 61.12 o 2 10 -9 1513.40 1514.04 94.09 o 3 10 -9 714.33 592.28 81.47 o 4 10 -9 744.44 747.90 71.62 o 5 10 -9 133.77 87.33 47.21 o 0 11 -9 2756.79 2932.61 220.16 o 1 11 -9 243.35 253.13 48.67 o 2 11 -9 765.71 837.27 66.01 o 3 11 -9 197.36 177.51 69.67 o 4 11 -9 336.98 355.84 59.74 o 5 11 -9 241.44 255.32 53.80 o 1 12 -9 29.69 59.74 48.43 o 2 12 -9 614.56 621.02 62.26 o 3 12 -9 481.01 407.36 81.07 o 4 12 -9 505.06 374.32 84.16 o 0 13 -9 891.80 1042.05 110.04 o 1 13 -9 1845.81 1994.90 116.47 o 2 13 -9 152.06 113.78 55.59 o 3 13 -9 253.06 197.54 78.87 o 4 13 -9 12.58 6.84 81.23 o 1 14 -9 141.93 96.94 59.33 o 2 14 -9 903.93 1042.70 82.86 o 3 14 -9 344.91 187.36 87.17 o 0 15 -9 589.06 581.54 104.26 o 1 15 -9 412.48 414.36 70.32 o 2 15 -9 137.61 8.87 93.52 o 3 15 -9 250.46 219.43 94.66 o 1 16 -9 416.42 291.30 103.86 o 2 16 -9 23.01 -79.36 97.91 o 0 0 -8 13878.51 14099.16 988.82 o 2 0 -8 1210.47 1277.11 81.64 o 4 0 -8 677.61 674.73 41.43 o 6 0 -8 567.05 580.81 44.11 o 1 1 -8 159.12 163.27 18.56 o 2 1 -8 991.63 999.57 42.97 o 3 1 -8 684.39 664.64 39.72 o 4 1 -8 1947.84 1924.01 66.01 o 5 1 -8 730.83 699.39 32.88 o 6 1 -8 1678.60 1618.55 62.18 o 7 1 -8 742.22 672.94 44.36 o 0 2 -8 2781.70 2669.14 144.31 o 1 2 -8 5646.08 5719.52 202.75 o 2 2 -8 1018.88 1103.91 42.65 o 3 2 -8 153.26 151.47 24.91 o 4 2 -8 2024.33 1985.21 69.83 o 5 2 -8 1267.98 1205.24 48.27 o 6 2 -8 17.81 3.17 21.08 o 7 2 -8 0.17 28.65 30.60 o 1 3 -8 965.19 995.33 41.51 o 2 3 -8 5246.86 5354.24 174.91 o 3 3 -8 647.89 682.38 35.32 o 4 3 -8 829.70 861.69 43.14 o 5 3 -8 1076.82 1037.09 42.57 o 6 3 -8 336.02 295.45 25.31 o 7 3 -8 163.13 170.43 32.80 o 0 4 -8 713.02 749.61 46.64 o 1 4 -8 717.50 711.77 32.23 o 2 4 -8 114.01 124.37 19.70 o 3 4 -8 1858.43 1800.13 76.26 o 4 4 -8 234.51 225.05 23.93 o 5 4 -8 671.83 658.86 31.17 o 6 4 -8 18.43 16.20 21.65 o 7 4 -8 559.45 520.25 41.27 o 1 5 -8 2910.74 3025.07 112.81 o 2 5 -8 1209.27 1250.66 53.72 o 3 5 -8 5407.32 5313.63 209.18 o 4 5 -8 193.03 187.77 23.85 o 5 5 -8 695.34 670.50 39.31 o 6 5 -8 365.83 399.06 28.08 o 7 5 -8 237.21 210.07 34.92 o 0 6 -8 2229.68 2184.62 116.80 o 1 6 -8 2715.32 2687.86 116.96 o 2 6 -8 98.32 66.33 20.84 o 3 6 -8 867.79 869.99 43.38 o 4 6 -8 1828.29 1841.48 79.60 o 5 6 -8 56.02 70.57 25.31 o 6 6 -8 4.29 -9.28 31.42 o 7 6 -8 384.58 386.04 45.09 o 1 7 -8 714.05 731.46 39.31 o 2 7 -8 1259.30 1225.26 48.27 o 3 7 -8 243.14 276.16 26.05 o 4 7 -8 639.40 652.11 38.17 o 5 7 -8 1484.19 1448.68 66.74 o 6 7 -8 25.25 13.51 39.64 o 7 7 -8 965.77 903.28 75.21 o 0 8 -8 6667.74 6476.79 476.30 o 1 8 -8 1511.29 1598.36 92.70 o 2 8 -8 1387.83 1446.08 64.71 o 3 8 -8 6.79 -24.66 24.66 o 4 8 -8 520.26 565.67 42.49 o 5 8 -8 621.10 621.18 48.10 o 6 8 -8 155.29 174.01 44.85 o 1 9 -8 262.11 256.30 37.85 o 2 9 -8 645.78 603.76 36.87 o 3 9 -8 202.93 207.87 31.25 o 4 9 -8 1199.37 1198.00 69.51 o 5 9 -8 25.44 34.67 33.61 o 6 9 -8 1869.92 1811.52 120.05 o 0 10 -8 5897.04 5971.11 424.21 o 1 10 -8 1168.69 1077.13 58.11 o 2 10 -8 699.34 702.41 45.17 o 3 10 -8 337.20 373.02 37.93 o 4 10 -8 85.63 146.83 34.43 o 5 10 -8 638.19 597.33 50.63 o 6 10 -8 159.64 209.09 50.22 o 1 11 -8 35.45 90.59 37.60 o 2 11 -8 2728.71 2423.42 149.11 o 3 11 -8 173.33 164.65 34.10 o 4 11 -8 1405.00 1417.27 80.98 o 5 11 -8 511.75 442.93 55.10 o 6 11 -8 52.86 103.61 50.79 o 0 12 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101.66 11.48 o 4 1 -7 1194.25 1159.83 35.89 o 5 1 -7 924.99 882.77 37.20 o 6 1 -7 95.03 78.79 19.53 o 7 1 -7 21.29 17.25 22.38 o 8 1 -7 393.85 391.90 38.66 o 1 2 -7 1547.62 1589.41 48.67 o 2 2 -7 5378.40 5502.54 144.47 o 3 2 -7 2514.36 2486.18 77.89 o 4 2 -7 1501.46 1499.71 47.53 o 5 2 -7 1108.24 1006.81 42.00 o 6 2 -7 1137.25 1111.23 44.93 o 7 2 -7 1200.10 1112.78 47.53 o 8 2 -7 75.02 96.77 33.70 o 0 3 -7 5338.80 5441.74 269.08 o 1 3 -7 2009.27 2029.49 60.23 o 2 3 -7 763.72 778.83 27.35 o 3 3 -7 642.21 600.91 27.43 o 4 3 -7 2656.87 2659.13 86.36 o 5 3 -7 25.42 46.56 16.69 o 6 3 -7 68.65 43.71 19.53 o 7 3 -7 286.86 280.56 26.37 o 8 3 -7 563.93 572.02 44.85 o 1 4 -7 1193.33 1262.95 45.33 o 2 4 -7 1109.39 1112.29 33.70 o 3 4 -7 6028.02 5816.63 196.32 o 4 4 -7 164.66 174.99 16.52 o 5 4 -7 760.33 739.76 35.81 o 6 4 -7 314.87 314.33 25.96 o 7 4 -7 481.66 454.98 36.79 o 0 5 -7 1114.39 1061.26 53.07 o 1 5 -7 4335.03 4561.08 130.14 o 2 5 -7 39.03 45.99 13.92 o 3 5 -7 1582.00 1591.85 60.39 o 4 5 -7 1098.56 1138.74 46.23 o 5 5 -7 1318.73 1332.70 55.26 o 6 5 -7 124.64 128.92 22.87 o 7 5 -7 234.14 278.28 36.95 o 1 6 -7 263.24 266.96 16.85 o 2 6 -7 4725.92 4918.07 190.62 o 3 6 -7 1616.28 1747.14 63.49 o 4 6 -7 185.55 215.12 22.71 o 5 6 -7 1346.15 1372.74 61.29 o 6 6 -7 663.28 705.91 36.87 o 7 6 -7 620.93 516.26 56.16 o 0 7 -7 1562.29 1616.76 93.84 o 1 7 -7 5168.79 4896.33 170.68 o 2 7 -7 601.13 644.05 29.06 o 3 7 -7 421.93 449.77 24.25 o 4 7 -7 460.77 462.79 29.95 o 5 7 -7 1130.54 1144.77 65.93 o 6 7 -7 38.78 58.52 32.15 o 7 7 -7 74.58 48.92 42.57 o 1 8 -7 451.43 460.19 25.88 o 2 8 -7 1584.70 1597.30 83.75 o 3 8 -7 604.09 664.56 43.71 o 4 8 -7 900.09 923.47 56.32 o 5 8 -7 507.59 579.59 43.30 o 6 8 -7 1887.04 1923.44 104.99 o 7 8 -7 433.23 517.32 56.65 o 0 9 -7 8150.42 8702.92 468.41 o 1 9 -7 289.85 233.19 26.86 o 2 9 -7 2354.71 2415.29 116.72 o 3 9 -7 119.82 117.85 25.88 o 4 9 -7 1054.78 986.54 60.47 o 5 9 -7 50.21 52.50 30.60 o 6 9 -7 154.70 147.16 42.81 o 7 9 -7 28.28 87.50 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1425.73 41.02 o 5 4 1 3996.44 3797.88 120.54 o 6 4 1 586.30 576.74 27.92 o 7 4 1 2971.47 2793.51 138.37 o 8 4 1 106.32 105.08 32.80 o 9 4 1 14.93 26.05 40.53 o 0 5 1 5180.50 5595.97 406.31 o 1 5 1 15527.68 15459.53 502.27 o 2 5 1 62.54 56.89 6.02 o 3 5 1 4171.14 4087.31 150.49 o 4 5 1 1660.22 1647.93 58.93 o 5 5 1 1203.99 1207.11 46.07 o 6 5 1 71.40 61.12 18.64 o 7 5 1 1019.48 979.62 58.11 o 8 5 1 178.62 227.57 42.89 o 9 5 1 451.69 457.66 60.72 o 1 6 1 1748.65 1767.98 47.45 o 2 6 1 8037.37 7761.71 256.71 o 3 6 1 4396.08 4132.72 137.71 o 4 6 1 1479.65 1427.28 52.50 o 5 6 1 2825.81 2832.33 110.69 o 6 6 1 1976.75 1988.63 100.36 o 7 6 1 347.14 386.45 41.84 o 8 6 1 163.89 103.69 40.21 o 9 6 1 23.79 1.47 47.78 o 0 7 1 8009.95 6806.83 276.16 o 1 7 1 9981.34 10049.54 324.18 o 2 7 1 3287.85 3210.88 136.41 o 3 7 1 1598.85 1555.14 61.29 o 4 7 1 780.36 793.73 35.81 o 5 7 1 3384.10 3429.91 136.57 o 6 7 1 51.53 52.17 24.09 o 7 7 1 426.08 441.38 45.82 o 8 7 1 380.33 422.83 51.60 o 9 7 1 1234.91 1349.55 101.66 o 1 8 1 3868.38 3562.74 150.25 o 2 8 1 3550.43 3416.15 124.12 o 3 8 1 5268.90 5453.54 191.35 o 4 8 1 1907.77 1791.42 72.60 o 5 8 1 1755.23 1712.72 85.70 o 6 8 1 1541.41 1525.19 87.50 o 7 8 1 897.46 924.28 69.02 o 8 8 1 198.78 188.58 44.36 o 9 8 1 38.00 111.26 51.60 o 0 9 1 8459.12 5511.65 344.94 o 1 9 1 1575.06 1672.51 60.80 o 2 9 1 4188.72 4142.49 139.83 o 3 9 1 440.19 453.67 25.56 o 4 9 1 4006.01 4210.13 148.62 o 5 9 1 191.85 198.11 23.85 o 6 9 1 344.20 335.17 35.97 o 7 9 1 5.06 31.17 33.37 o 8 9 1 995.70 1075.50 85.62 o 1 10 1 1534.11 1187.42 45.09 o 2 10 1 3303.47 3243.12 118.91 o 3 10 1 2885.44 2815.89 115.41 o 4 10 1 1920.31 1973.41 84.24 o 5 10 1 831.83 866.98 48.75 o 6 10 1 1889.71 1966.09 117.28 o 7 10 1 903.58 1005.10 75.78 o 8 10 1 201.68 291.14 49.65 o 0 11 1 6898.12 6886.51 297.81 o 1 11 1 2304.93 2370.93 105.40 o 2 11 1 3593.10 3672.78 150.09 o 3 11 1 717.18 741.96 31.50 o 4 11 1 1541.27 1469.52 77.81 o 5 11 1 936.41 1007.62 58.68 o 6 11 1 88.28 91.65 29.63 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1057.43 45.01 o 2 16 1 119.99 95.06 21.89 o 3 16 1 2081.94 1938.66 110.69 o 4 16 1 317.50 288.86 33.94 o 5 16 1 928.14 882.53 58.52 o 6 16 1 64.22 59.66 42.24 o 7 16 1 421.63 493.88 68.12 o 0 17 1 1616.67 1810.47 111.42 o 1 17 1 829.73 972.63 43.63 o 2 17 1 1075.08 963.02 49.81 o 3 17 1 125.14 62.02 27.18 o 4 17 1 753.73 712.01 48.75 o 5 17 1 224.49 233.43 40.94 o 6 17 1 116.93 125.26 48.02 o 1 18 1 96.57 141.13 28.65 o 2 18 1 2384.36 2486.18 112.89 o 3 18 1 277.51 231.64 31.50 o 4 18 1 657.18 550.29 43.79 o 5 18 1 255.80 231.48 48.51 o 6 18 1 676.64 778.51 71.71 o 0 19 1 741.45 904.09 64.71 o 1 19 1 948.70 1077.46 60.23 o 2 19 1 540.30 570.88 44.03 o 3 19 1 625.40 589.76 43.63 o 4 19 1 76.60 80.33 36.06 o 5 19 1 413.34 349.09 54.61 o 1 20 1 50.05 59.58 32.56 o 2 20 1 773.26 915.00 55.35 o 3 20 1 108.04 115.25 48.51 o 4 20 1 385.56 148.78 54.04 o 0 21 1 1632.88 2175.67 196.23 o 1 21 1 477.85 572.75 50.79 o 2 21 1 284.80 376.52 46.80 o 3 21 1 110.19 104.10 52.74 o 4 21 1 538.35 301.47 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196.97 o 7 3 2 611.99 567.22 42.24 o 8 3 2 393.95 441.06 40.94 o 9 3 2 58.81 34.59 41.43 o 0 4 2 8154.74 8870.26 410.70 o 1 4 2 33747.77 34145.01 1087.88 o 2 4 2 2465.40 2606.31 92.13 o 3 4 2 176.83 176.62 9.85 o 4 4 2 1196.56 1173.09 38.58 o 5 4 2 3779.98 3689.30 117.53 o 6 4 2 69.57 59.90 16.85 o 7 4 2 116.40 110.37 27.10 o 8 4 2 16.77 39.72 32.80 o 9 4 2 4.33 -1.87 41.10 o 1 5 2 2466.25 2600.78 95.80 o 2 5 2 3042.54 3057.30 100.52 o 3 5 2 130.20 134.30 8.95 o 4 5 2 55.52 69.18 9.69 o 5 5 2 7941.99 7532.19 278.28 o 6 5 2 554.97 519.28 27.67 o 7 5 2 1899.29 1962.83 98.16 o 8 5 2 81.00 55.43 38.09 o 9 5 2 10.81 42.40 48.02 o 0 6 2 20849.49 18488.51 819.45 o 1 6 2 2228.03 2061.23 74.64 o 2 6 2 1576.26 1590.14 48.51 o 3 6 2 4051.41 4086.17 129.41 o 4 6 2 2135.24 2005.81 75.45 o 5 6 2 34.81 29.46 14.57 o 6 6 2 692.66 677.66 35.81 o 7 6 2 915.23 922.41 64.71 o 8 6 2 299.10 298.30 46.39 o 9 6 2 329.12 448.95 62.10 o 1 7 2 6505.09 6668.63 282.75 o 2 7 2 87.16 99.38 8.30 o 3 7 2 12116.50 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14.16 o 3 11 2 2816.13 2742.64 125.75 o 4 11 2 2348.67 2355.30 123.47 o 5 11 2 29.11 -7.33 21.73 o 6 11 2 2610.84 2722.21 135.52 o 7 11 2 306.26 286.42 45.90 o 8 11 2 348.02 378.06 58.03 o 0 12 2 10702.51 7215.42 617.11 o 1 12 2 1894.30 1806.97 61.61 o 2 12 2 2045.96 2135.79 99.70 o 3 12 2 410.19 437.97 27.43 o 4 12 2 1570.66 1529.26 91.40 o 5 12 2 398.63 451.15 37.11 o 6 12 2 994.33 1086.49 78.38 o 7 12 2 92.41 74.23 41.43 o 8 12 2 157.47 204.62 54.69 o 1 13 2 310.46 260.94 17.74 o 2 13 2 97.54 116.23 16.93 o 3 13 2 268.33 290.57 25.88 o 4 13 2 705.42 806.51 49.57 o 5 13 2 3764.92 3943.16 190.37 o 6 13 2 421.15 450.66 46.07 o 7 13 2 1106.70 1098.13 90.83 o 0 14 2 3252.13 3326.54 190.05 o 1 14 2 6308.39 6603.84 587.89 o 2 14 2 287.37 274.86 21.41 o 3 14 2 151.06 128.84 23.77 o 4 14 2 732.29 733.50 45.25 o 5 14 2 518.11 579.67 42.32 o 6 14 2 38.19 46.39 35.81 o 7 14 2 29.49 42.08 43.54 o 1 15 2 794.58 849.89 38.17 o 2 15 2 2276.00 1460.89 96.04 o 3 15 2 2006.50 1817.14 105.16 o 4 15 2 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205.51 o 5 3 3 12.17 0.81 11.56 o 6 3 3 389.95 377.00 21.32 o 7 3 3 690.64 649.91 41.10 o 8 3 3 1451.63 1418.41 80.90 o 9 3 3 191.60 298.95 47.70 o 1 4 3 4142.12 4079.17 189.23 o 2 4 3 2433.93 2520.28 79.11 o 3 4 3 13133.48 13500.28 456.77 o 4 4 3 807.67 855.67 32.72 o 5 4 3 2412.45 2297.76 77.32 o 6 4 3 652.82 629.97 31.66 o 7 4 3 1772.66 1888.93 93.68 o 8 4 3 112.24 132.18 35.81 o 9 4 3 51.37 50.79 49.65 o 0 5 3 1742.33 1723.22 82.12 o 1 5 3 8357.68 8219.05 349.90 o 2 5 3 144.15 159.85 9.60 o 3 5 3 5179.21 5112.10 171.08 o 4 5 3 1478.62 1360.86 52.99 o 5 5 3 1205.27 1143.06 42.89 o 6 5 3 153.28 101.66 20.75 o 7 5 3 835.08 830.35 59.90 o 8 5 3 193.76 163.19 42.89 o 9 5 3 610.64 730.08 73.82 o 1 6 3 2613.14 2762.26 124.69 o 2 6 3 5645.73 5465.02 188.26 o 3 6 3 2939.96 2905.91 99.38 o 4 6 3 970.33 908.49 40.86 o 5 6 3 2011.84 1916.60 72.68 o 6 6 3 1926.96 1825.69 80.25 o 7 6 3 1010.85 1035.70 72.03 o 8 6 3 348.23 418.51 52.99 o 9 6 3 0.41 24.25 50.63 o 0 7 3 4112.39 4182.13 197.13 o 1 7 3 10532.06 10564.18 406.55 o 2 7 3 2728.76 2684.61 103.20 o 3 7 3 1976.61 1932.07 75.12 o 4 7 3 477.80 482.16 26.05 o 5 7 3 1875.61 1770.50 75.12 o 6 7 3 72.02 67.31 21.08 o 7 7 3 236.58 292.19 39.31 o 8 7 3 315.40 395.15 51.44 o 1 8 3 3472.68 3694.67 125.18 o 2 8 3 3054.86 2997.31 109.63 o 3 8 3 3693.54 3458.48 129.33 o 4 8 3 2627.96 2578.96 104.42 o 5 8 3 1698.96 1643.78 77.40 o 6 8 3 1700.37 1670.96 83.26 o 7 8 3 918.09 1047.18 82.53 o 8 8 3 222.60 299.11 49.97 o 0 9 3 10305.40 9767.44 925.74 o 1 9 3 22.30 34.51 10.66 o 2 9 3 4067.68 3931.93 132.91 o 3 9 3 129.22 129.82 14.65 o 4 9 3 1512.82 1536.02 83.43 o 5 9 3 248.00 251.42 27.27 o 6 9 3 475.57 524.81 37.44 o 7 9 3 128.93 144.31 37.93 o 8 9 3 789.09 821.73 74.64 o 1 10 3 4442.01 4593.88 144.47 o 2 10 3 2151.47 2145.96 75.78 o 3 10 3 2336.03 2358.96 97.43 o 4 10 3 3079.99 3130.71 132.83 o 5 10 3 413.61 417.46 34.10 o 6 10 3 970.29 1057.52 64.79 o 7 10 3 595.99 711.93 61.78 o 8 10 3 35.12 103.53 46.88 o 0 11 3 8159.43 7483.84 551.26 o 1 11 3 3087.11 3098.89 99.62 o 2 11 3 3241.58 3459.21 136.00 o 3 11 3 522.73 528.23 27.84 o 4 11 3 1214.06 1252.04 63.40 o 5 11 3 1219.79 1195.07 68.61 o 6 11 3 61.02 36.22 29.46 o 7 11 3 275.03 284.22 47.13 o 8 11 3 497.85 626.63 68.69 o 1 12 3 8.75 -3.42 13.51 o 2 12 3 3921.79 4086.65 176.21 o 3 12 3 2074.53 2031.77 95.88 o 4 12 3 1779.00 1774.17 88.31 o 5 12 3 240.42 239.94 30.11 o 6 12 3 873.66 843.46 63.81 o 7 12 3 342.93 356.58 51.03 o 0 13 3 2684.73 2451.83 146.75 o 1 13 3 4289.55 3801.38 152.12 o 2 13 3 534.27 532.54 27.35 o 3 13 3 2324.85 2255.43 123.63 o 4 13 3 218.43 193.39 28.00 o 5 13 3 795.18 821.73 54.78 o 6 13 3 84.66 107.52 35.81 o 7 13 3 293.49 396.13 55.75 o 1 14 3 478.64 470.44 31.42 o 2 14 3 1735.30 1814.05 75.69 o 3 14 3 2688.35 3058.19 162.38 o 4 14 3 159.49 155.70 29.30 o 5 14 3 963.23 1030.98 71.05 o 6 14 3 290.45 290.40 43.38 o 7 14 3 628.77 694.76 68.78 o 0 15 3 1126.71 939.99 63.00 o 1 15 3 1549.58 1501.67 65.36 o 2 15 3 237.99 251.50 25.96 o 3 15 3 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91.65 40.94 o 2 21 3 290.55 337.45 54.94 o 3 21 3 127.40 178.08 52.90 o 1 22 3 540.65 764.91 72.85 o 2 22 3 77.66 130.47 60.31 o 0 0 4 38756.98 39540.11 3884.23 o 2 0 4 6224.31 6269.73 305.22 o 4 0 4 826.93 794.54 45.01 o 6 0 4 2196.23 2109.25 96.94 o 8 0 4 183.70 114.35 42.73 o 1 1 4 2608.28 2617.62 139.26 o 2 1 4 316.08 344.37 12.70 o 3 1 4 2983.76 2998.29 99.95 o 4 1 4 2599.96 2487.15 86.11 o 5 1 4 2952.55 2931.31 84.57 o 6 1 4 2642.45 2543.64 82.77 o 7 1 4 1017.86 1016.98 46.88 o 8 1 4 1482.64 1384.79 70.08 o 9 1 4 21.51 33.61 64.30 o 0 2 4 896.10 904.75 96.69 o 1 2 4 15282.35 15899.78 794.05 o 2 2 4 2550.62 2503.35 91.16 o 3 2 4 602.23 644.78 22.14 o 4 2 4 2005.27 1901.22 61.37 o 5 2 4 1926.39 1858.16 59.82 o 6 2 4 28.32 26.45 14.57 o 7 2 4 60.32 74.15 23.68 o 8 2 4 728.79 727.96 54.86 o 9 2 4 14.46 32.64 45.09 o 1 3 4 3926.88 4303.40 227.08 o 2 3 4 12164.82 12355.35 408.75 o 3 3 4 3099.02 2935.94 102.06 o 4 3 4 2773.97 2734.34 88.39 o 5 3 4 2639.30 2530.70 81.23 o 6 3 4 602.64 581.78 27.18 o 7 3 4 130.62 161.81 25.15 o 8 3 4 124.44 115.82 37.20 o 9 3 4 67.73 48.35 45.99 o 0 4 4 2191.08 2426.52 112.73 o 1 4 4 1720.96 1806.64 69.51 o 2 4 4 1067.27 1147.45 41.75 o 3 4 4 5932.81 5924.96 228.14 o 4 4 4 959.12 980.44 37.93 o 5 4 4 1778.29 1812.91 66.66 o 6 4 4 49.01 37.11 18.23 o 7 4 4 1071.46 1076.16 57.71 o 8 4 4 433.24 437.88 55.35 o 9 4 4 1557.64 1601.62 172.22 o 1 5 4 7262.49 7265.15 257.77 o 2 5 4 2116.24 2089.88 63.81 o 3 5 4 10180.68 9721.69 302.94 o 4 5 4 163.00 163.19 13.67 o 5 5 4 1055.09 992.00 38.58 o 6 5 4 476.31 471.99 36.54 o 7 5 4 55.56 66.82 29.30 o 8 5 4 100.86 85.30 80.25 o 0 6 4 1165.56 1086.49 52.58 o 1 6 4 9448.21 9623.62 396.21 o 2 6 4 35.11 31.50 10.50 o 3 6 4 111.94 115.49 12.13 o 4 6 4 4669.76 4643.29 183.54 o 5 6 4 140.55 173.53 17.01 o 6 6 4 124.38 106.70 25.88 o 7 6 4 220.46 218.94 35.41 o 8 6 4 974.16 935.27 126.56 o 1 7 4 1469.37 1593.88 75.29 o 2 7 4 3493.70 3287.39 131.37 o 3 7 4 204.21 235.79 13.67 o 4 7 4 1402.20 1351.91 59.82 o 5 7 4 3810.76 3732.28 159.04 o 6 7 4 164.82 206.25 28.89 o 7 7 4 1766.26 1802.98 103.77 o 8 7 4 31.79 99.46 81.55 o 0 8 4 15546.51 16232.02 756.86 o 1 8 4 8409.77 8420.00 323.61 o 2 8 4 2532.37 2537.62 100.84 o 3 8 4 505.98 547.36 23.03 o 4 8 4 552.07 555.74 29.55 o 5 8 4 1187.41 1044.41 60.80 o 6 8 4 671.70 697.60 46.31 o 7 8 4 73.40 74.47 35.97 o 8 8 4 0.37 -44.03 80.98 o 1 9 4 209.79 205.43 15.06 o 2 9 4 188.55 178.57 17.42 o 3 9 4 392.43 395.97 21.89 o 4 9 4 973.30 1026.26 42.81 o 5 9 4 106.15 91.24 23.44 o 6 9 4 3871.83 4092.27 198.68 o 7 9 4 40.61 48.59 36.63 o 8 9 4 647.98 810.17 114.44 o 0 10 4 9112.83 8711.87 416.15 o 1 10 4 4072.32 4290.86 143.41 o 2 10 4 1573.95 1529.34 63.16 o 3 10 4 1143.88 1213.95 53.96 o 4 10 4 158.61 166.69 23.44 o 5 10 4 1022.66 1058.33 58.85 o 6 10 4 501.97 521.96 43.46 o 7 10 4 76.96 32.23 73.50 o 8 10 4 104.10 126.08 95.88 o 1 11 4 845.28 901.41 37.85 o 2 11 4 7481.93 7176.67 488.43 o 3 11 4 818.85 909.14 48.35 o 4 11 4 2184.37 2127.40 108.90 o 5 11 4 1706.05 1695.71 89.12 o 6 11 4 11.80 -13.02 30.77 o 7 11 4 561.45 708.02 103.37 o 0 12 4 1091.06 927.45 131.20 o 1 12 4 890.35 921.27 38.17 o 2 12 4 221.21 237.99 20.10 o 3 12 4 446.86 504.22 39.80 o 4 12 4 1845.77 1885.67 97.83 o 5 12 4 144.40 125.67 28.81 o 6 12 4 4.50 -21.57 32.80 o 7 12 4 97.82 171.41 87.41 o 1 13 4 5529.59 5261.37 257.28 o 2 13 4 2178.99 2194.80 82.61 o 3 13 4 3716.90 3966.03 190.21 o 4 13 4 57.04 52.42 26.37 o 5 13 4 276.35 245.88 36.71 o 6 13 4 53.80 25.64 36.22 o 7 13 4 121.98 95.96 90.26 o 0 14 4 2142.89 1838.71 98.81 o 1 14 4 478.92 485.25 31.74 o 2 14 4 243.54 297.73 24.17 o 3 14 4 1591.23 1768.47 94.98 o 4 14 4 1063.13 1059.47 69.67 o 5 14 4 348.29 375.62 42.89 o 6 14 4 112.97 114.35 62.59 o 7 14 4 422.65 342.74 106.22 o 1 15 4 13.84 10.50 21.98 o 2 15 4 1078.44 1135.41 52.17 o 3 15 4 203.70 171.90 29.30 o 4 15 4 469.56 363.82 44.44 o 5 15 4 1284.15 1374.37 97.43 o 6 15 4 596.93 615.32 112.32 o 0 16 4 132.03 84.73 36.30 o 1 16 4 4631.04 4253.51 237.17 o 2 16 4 142.54 132.42 27.10 o 3 16 4 285.46 306.03 33.45 o 4 16 4 222.95 162.21 39.07 o 5 16 4 441.37 371.63 56.73 o 6 16 4 32.26 16.12 88.15 o 1 17 4 123.48 91.48 26.21 o 2 17 4 305.48 305.46 32.80 o 3 17 4 48.80 56.73 31.01 o 4 17 4 151.67 127.46 39.64 o 5 17 4 480.92 637.70 86.44 o 0 18 4 4084.28 4438.51 250.85 o 1 18 4 27.39 55.59 27.92 o 2 18 4 730.77 664.40 51.60 o 3 18 4 67.61 39.96 37.60 o 4 18 4 419.18 405.74 53.07 o 5 18 4 136.23 57.14 75.53 o 1 19 4 570.84 624.19 44.20 o 2 19 4 374.58 365.45 45.66 o 3 19 4 680.67 586.02 64.14 o 4 19 4 418.69 383.76 55.10 o 0 20 4 66.28 76.91 47.61 o 1 20 4 233.10 281.45 48.59 o 2 20 4 198.41 233.76 51.85 o 3 20 4 37.93 3.17 48.59 o 4 20 4 600.67 377.90 84.08 o 1 21 4 131.13 172.63 51.03 o 2 21 4 1144.50 1306.65 91.00 o 3 21 4 306.73 212.02 57.46 o 0 22 4 310.49 393.45 91.32 o 1 22 4 62.67 101.82 56.24 o 2 0 5 7317.24 7395.13 323.77 o 4 0 5 4633.71 4554.41 221.47 o 6 0 5 2795.07 2695.52 124.77 o 8 0 5 216.65 329.31 88.47 o 0 1 5 5771.00 5959.47 535.31 o 1 1 5 1840.97 1779.46 83.75 o 2 1 5 4516.76 4628.88 151.47 o 3 1 5 3285.16 3356.66 103.37 o 4 1 5 1469.02 1387.31 45.17 o 5 1 5 1699.06 1643.04 54.37 o 6 1 5 454.47 445.86 34.35 o 7 1 5 325.63 322.39 35.81 o 8 1 5 1289.93 1473.83 104.83 o 1 2 5 3964.18 4056.30 231.97 o 2 2 5 3727.81 3914.51 168.72 o 3 2 5 6431.65 6606.85 192.73 o 4 2 5 1741.99 1650.53 57.30 o 5 2 5 615.50 623.70 31.82 o 6 2 5 2553.23 2446.46 101.25 o 7 2 5 1037.51 988.17 53.31 o 8 2 5 216.84 222.61 59.82 o 0 3 5 15195.87 15394.34 1515.26 o 1 3 5 4919.58 4933.37 265.99 o 2 3 5 1176.47 1120.68 60.96 o 3 3 5 825.04 805.94 30.36 o 4 3 5 3034.34 2952.87 97.10 o 5 3 5 190.28 210.64 17.58 o 6 3 5 335.75 342.01 32.56 o 7 3 5 275.09 263.54 35.73 o 8 3 5 335.15 390.03 64.95 o 1 4 5 1922.14 2037.79 251.99 o 2 4 5 2009.20 1854.82 107.44 o 3 4 5 3878.18 3843.95 125.10 o 4 4 5 169.03 149.35 14.32 o 5 4 5 3361.58 3246.13 159.04 o 6 4 5 585.96 592.77 55.92 o 7 4 5 2040.87 1770.91 108.49 o 8 4 5 27.08 89.77 85.22 o 0 5 5 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