#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:09:23 +0300 (Sun, 03 Apr 2016) $ #$Revision: 180971 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/51/2205166.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2205166_Fobs loop_ _publ_author_name 'Alley, Steven' 'Gallagher, John F.' 'Kenny, Peter T. M.' 'Lough, Alan J.' _publ_section_title ; Methyl 2-[(ferrocenylcarbonyl)amino]thiophene-3-carboxylate ; _journal_issue 2 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m201 _journal_page_last m203 _journal_volume 61 _journal_year 2005 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 95.721 _cell_angle_gamma 90.000 _cell_length_a 7.1714 _cell_length_b 8.1184 _cell_length_c 26.4299 _exptl_crystal_F_000 760.00 _reflns_d_resolution_high 0.7684 _cod_data_source_file tk6199Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title 'TK6199 Fc-CONH-thienyl-CO2Me' _shelx_refln_list_code 4 _shelx_f_calc_maximum 132.75 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 693.65 838.23 23.86 o 3 0 0 185.91 121.04 6.46 o 4 0 0 4920.55 4872.27 119.39 o 5 0 0 637.51 659.03 44.91 o 6 0 0 501.56 500.69 29.08 o 7 0 0 1081.41 1114.93 60.75 o 8 0 0 196.78 168.88 23.43 o 1 1 0 3486.40 3498.82 58.77 o 2 1 0 10255.22 10389.24 363.51 o 3 1 0 2.28 4.16 2.41 o 4 1 0 5563.87 5490.02 108.65 o 5 1 0 1421.10 1530.81 47.41 o 6 1 0 157.65 161.01 12.07 o 7 1 0 194.57 233.24 15.59 o 8 1 0 349.25 347.53 25.25 o 9 1 0 25.53 19.01 18.42 o 1 2 0 494.91 520.36 9.28 o 2 2 0 888.72 891.18 17.48 o 3 2 0 4882.27 4873.89 83.81 o 4 2 0 579.07 578.36 14.02 o 5 2 0 311.83 321.25 13.04 o 6 2 0 356.37 363.85 18.57 o 7 2 0 1023.50 1028.04 40.03 o 8 2 0 5.90 1.42 9.82 o 9 2 0 226.84 217.09 18.90 o 1 3 0 763.09 792.97 11.68 o 2 3 0 3031.70 3139.77 50.36 o 3 3 0 90.28 83.04 3.67 o 4 3 0 1991.47 2019.72 47.44 o 5 3 0 42.69 42.97 6.63 o 6 3 0 141.86 130.76 10.49 o 7 3 0 21.13 15.68 16.60 o 8 3 0 56.10 56.21 15.95 o 0 4 0 322.29 411.19 9.64 o 1 4 0 724.86 827.64 12.80 o 2 4 0 119.58 117.36 4.68 o 3 4 0 39.98 31.42 2.96 o 4 4 0 217.89 227.05 8.80 o 5 4 0 51.37 48.87 5.42 o 6 4 0 9.38 6.79 6.85 o 7 4 0 10.94 23.44 18.69 o 8 4 0 0.39 21.78 11.54 o 1 5 0 575.63 663.17 11.58 o 2 5 0 74.45 87.94 3.81 o 3 5 0 677.69 712.20 17.13 o 4 5 0 122.83 136.50 5.96 o 5 5 0 4.94 17.45 6.39 o 6 5 0 10.80 14.75 12.42 o 7 5 0 37.19 55.04 17.48 o 0 6 0 2695.87 2749.33 79.61 o 1 6 0 3767.29 3999.18 64.94 o 2 6 0 464.62 460.41 18.13 o 3 6 0 701.99 752.59 25.80 o 4 6 0 618.03 628.10 30.03 o 5 6 0 38.10 16.89 16.25 o 6 6 0 486.42 506.87 38.14 o 1 7 0 1026.55 1007.24 23.93 o 2 7 0 4.59 11.04 14.33 o 3 7 0 798.46 802.70 30.30 o 4 7 0 543.67 576.67 25.19 o 5 7 0 250.19 292.40 27.61 o 6 7 0 19.55 25.96 12.37 o 0 8 0 2425.22 2515.69 107.84 o 1 8 0 639.45 681.38 26.93 o 2 8 0 295.28 300.42 15.53 o 3 8 0 1341.16 1497.65 52.58 o 4 8 0 968.13 942.28 47.41 o 5 8 0 26.29 7.24 10.07 o 6 8 0 169.50 147.26 16.23 o 1 9 0 277.68 303.45 21.88 o 2 9 0 2.78 2.53 15.30 o 3 9 0 326.82 278.25 30.49 o 4 9 0 279.93 260.41 27.25 o 0 10 0 1213.72 1305.05 80.47 o 1 10 0 158.73 100.13 21.07 o 2 10 0 224.05 195.48 29.31 o -9 1 1 25.25 27.90 19.66 o -8 1 1 87.00 111.07 19.54 o -7 1 1 71.71 61.68 15.33 o -6 1 1 8.36 17.39 6.26 o -5 1 1 1218.37 1227.64 53.89 o -4 1 1 0.77 17.94 3.74 o -3 1 1 1121.65 1096.93 21.92 o -2 1 1 2470.42 2539.16 55.74 o -1 1 1 3362.31 3311.36 55.14 o 0 1 1 3875.76 3800.56 52.58 o 1 1 1 1363.20 1387.94 24.78 o 2 1 1 1323.32 1365.98 24.82 o 3 1 1 1884.75 1970.66 36.30 o 4 1 1 1434.98 1423.16 28.37 o 5 1 1 651.56 673.06 22.76 o 6 1 1 41.30 38.80 7.60 o 7 1 1 49.81 44.31 18.13 o 8 1 1 7.37 8.18 15.78 o 9 1 1 31.32 24.13 18.42 o -9 2 1 103.60 105.70 15.67 o -8 2 1 11.22 28.06 10.89 o -7 2 1 485.75 535.44 24.33 o -6 2 1 1458.13 1474.50 44.33 o -5 2 1 192.83 169.17 11.21 o -4 2 1 2013.66 2021.67 39.59 o -3 2 1 324.56 300.59 8.23 o -2 2 1 39.69 29.85 1.98 o -1 2 1 160.25 140.01 3.84 o 0 2 1 11001.30 10822.96 203.60 o 1 2 1 4106.62 4084.78 61.66 o 2 2 1 473.47 493.33 10.63 o 3 2 1 85.07 92.08 3.92 o 4 2 1 6.04 1.57 3.55 o 5 2 1 400.82 396.97 13.21 o 6 2 1 238.04 242.86 31.87 o 7 2 1 67.93 77.35 15.07 o 8 2 1 121.76 118.43 15.15 o -8 3 1 182.12 164.70 21.07 o -7 3 1 87.66 63.68 12.77 o -6 3 1 630.06 666.94 26.42 o -5 3 1 344.85 347.18 12.88 o -4 3 1 297.34 304.50 10.18 o -3 3 1 3335.79 3476.49 59.57 o -2 3 1 7836.58 7525.98 180.68 o -1 3 1 130.00 121.72 2.65 o 0 3 1 3333.63 3265.67 44.37 o 1 3 1 12479.38 11898.46 254.12 o 2 3 1 5196.99 5334.45 81.51 o 3 3 1 1100.37 1129.14 23.19 o 4 3 1 4049.33 3869.29 82.81 o 5 3 1 1358.46 1347.16 47.36 o 6 3 1 175.68 166.83 11.39 o 7 3 1 1327.80 1371.45 53.51 o 8 3 1 491.78 496.86 36.44 o -8 4 1 37.25 32.67 13.48 o -7 4 1 1186.30 1233.86 77.41 o -6 4 1 1768.43 1859.24 60.21 o -5 4 1 20.75 19.98 4.30 o -4 4 1 22.54 35.71 3.79 o -3 4 1 2896.57 2812.61 50.77 o -2 4 1 1212.53 1230.78 19.63 o -1 4 1 731.74 633.62 13.24 o 0 4 1 368.02 302.18 5.31 o 1 4 1 1969.68 2068.58 28.98 o 2 4 1 559.28 511.54 10.40 o 3 4 1 2246.18 2212.41 42.73 o 4 4 1 251.23 283.45 12.29 o 5 4 1 525.00 505.50 21.39 o 6 4 1 634.88 646.14 29.90 o 7 4 1 23.00 22.81 9.85 o 8 4 1 32.47 22.43 13.48 o -8 5 1 71.31 36.91 21.90 o -7 5 1 1.89 6.89 14.36 o -6 5 1 1493.67 1450.17 53.06 o -5 5 1 1086.82 1079.97 79.64 o -4 5 1 16.11 21.28 3.38 o -3 5 1 1112.96 1150.47 28.28 o -2 5 1 7000.39 7163.69 178.46 o -1 5 1 118.50 107.87 4.96 o 0 5 1 1229.44 1181.21 18.45 o 1 5 1 5813.11 5620.79 88.43 o 2 5 1 2146.09 2153.72 44.38 o 3 5 1 1233.15 1232.15 40.05 o 4 5 1 2741.15 2847.52 62.74 o 5 5 1 1631.66 1646.76 52.94 o 6 5 1 504.40 486.15 30.26 o 7 5 1 958.49 973.30 60.10 o -6 6 1 761.58 829.97 49.45 o -5 6 1 21.07 16.40 8.62 o -4 6 1 242.70 240.47 14.31 o -3 6 1 1961.76 1997.91 60.45 o -2 6 1 422.76 393.19 16.76 o -1 6 1 144.71 143.35 5.98 o 0 6 1 126.53 121.55 5.60 o 1 6 1 1155.27 1130.74 18.91 o 2 6 1 774.80 850.35 30.49 o 3 6 1 100.57 109.71 6.06 o 4 6 1 0.12 -1.03 9.26 o 5 6 1 88.05 88.06 16.25 o 6 6 1 174.32 171.82 20.60 o -6 7 1 530.37 477.06 27.30 o -5 7 1 217.73 219.40 14.66 o -4 7 1 0.68 -2.35 7.53 o -3 7 1 167.25 186.80 32.40 o -2 7 1 70.99 76.04 8.23 o -1 7 1 255.03 222.53 8.98 o 0 7 1 4.38 4.86 1.77 o 1 7 1 2728.01 2729.61 43.56 o 2 7 1 2783.49 2973.91 236.10 o 3 7 1 367.81 360.92 17.16 o 4 7 1 548.85 564.20 35.49 o 5 7 1 261.68 241.03 15.28 o 6 7 1 65.73 54.07 11.69 o -6 8 1 6.30 -11.57 11.57 o -5 8 1 21.36 20.24 11.24 o -4 8 1 6.52 3.28 9.87 o -3 8 1 114.33 130.01 12.57 o -2 8 1 163.06 164.97 13.40 o -1 8 1 311.10 326.57 14.10 o 0 8 1 25.25 36.59 10.62 o 1 8 1 71.78 67.58 11.04 o 2 8 1 329.57 322.41 17.67 o 3 8 1 90.67 101.24 11.02 o 4 8 1 34.12 19.49 25.72 o 5 8 1 35.54 48.80 15.01 o 6 8 1 78.54 71.75 20.78 o -4 9 1 10.57 -9.54 16.48 o -3 9 1 128.39 83.94 18.42 o -2 9 1 1.85 7.65 14.01 o -1 9 1 70.72 72.03 14.06 o 0 9 1 276.70 282.67 20.23 o 1 9 1 316.96 305.26 28.67 o 2 9 1 46.85 25.43 16.54 o 3 9 1 51.30 73.64 17.78 o 4 9 1 46.19 7.59 16.48 o -2 10 1 37.48 25.49 19.78 o -1 10 1 0.23 35.08 23.60 o 0 10 1 1.94 17.90 12.86 o 1 10 1 34.22 49.09 19.13 o 2 10 1 8.95 16.54 17.19 o -9 0 2 15.80 27.84 19.01 o -8 0 2 26.21 32.90 13.30 o -7 0 2 9.50 3.18 11.36 o -6 0 2 29.63 29.08 8.83 o -5 0 2 541.91 524.24 27.84 o -3 0 2 1070.02 1146.94 32.35 o 1 0 2 4252.94 4217.15 102.02 o 2 0 2 952.24 1161.94 32.44 o 3 0 2 1141.23 1054.87 29.09 o 4 0 2 589.37 651.88 23.67 o 5 0 2 7375.31 7483.21 255.05 o 6 0 2 2317.91 2514.63 100.01 o 7 0 2 418.46 446.06 33.49 o 8 0 2 1726.52 1717.04 93.65 o -9 1 2 457.79 501.06 35.58 o -8 1 2 1422.99 1525.50 73.34 o -7 1 2 52.11 48.86 19.16 o -6 1 2 314.48 314.72 27.52 o -5 1 2 5692.21 5627.86 119.67 o -4 1 2 2807.35 2894.73 53.47 o -3 1 2 847.80 784.51 15.86 o -2 1 2 222.75 171.23 4.71 o -1 1 2 4606.42 4720.07 69.54 o 0 1 2 6979.64 6742.63 110.36 o 2 1 2 1245.78 1242.13 23.85 o 3 1 2 348.29 381.98 9.64 o 4 1 2 4170.17 4369.31 77.79 o 5 1 2 1030.63 997.60 31.98 o 6 1 2 2.25 -2.81 7.56 o 7 1 2 434.84 490.69 22.56 o 8 1 2 14.50 22.07 15.78 o 9 1 2 19.27 44.09 19.54 o -9 2 2 72.26 49.32 14.79 o -8 2 2 1.38 4.62 9.27 o -7 2 2 130.08 163.44 17.42 o -6 2 2 1.70 13.92 6.99 o -5 2 2 475.96 482.89 32.35 o -4 2 2 3887.48 4094.37 74.13 o -3 2 2 911.41 923.70 18.79 o -2 2 2 1949.32 1938.93 31.39 o -1 2 2 3256.63 3204.52 45.08 o 0 2 2 1268.66 1231.69 17.09 o 1 2 2 351.21 343.24 6.96 o 2 2 2 1108.83 1012.38 19.96 o 3 2 2 530.86 509.93 11.61 o 4 2 2 402.01 459.42 13.79 o 5 2 2 2791.63 2851.16 75.43 o 6 2 2 1045.65 1138.60 46.59 o 7 2 2 44.51 37.50 13.36 o 8 2 2 345.79 329.46 22.57 o -8 3 2 321.21 280.76 41.65 o -7 3 2 0.22 17.33 9.09 o -6 3 2 1567.35 1714.16 59.51 o -5 3 2 1099.05 1095.05 60.41 o -4 3 2 0.39 4.62 3.02 o -3 3 2 809.61 841.11 17.37 o -2 3 2 1765.38 1735.95 28.52 o -1 3 2 95.76 73.62 3.09 o 0 3 2 633.29 648.15 10.88 o 1 3 2 958.04 897.91 15.89 o 2 3 2 8.00 19.33 1.89 o 3 3 2 629.96 672.99 14.98 o 4 3 2 133.43 158.02 7.74 o 5 3 2 87.89 85.10 11.68 o 6 3 2 46.80 60.12 9.60 o 7 3 2 287.10 336.74 34.94 o 8 3 2 27.46 25.55 14.72 o -8 4 2 0.45 12.18 12.83 o -7 4 2 22.70 33.51 16.72 o -6 4 2 48.78 68.22 9.73 o -5 4 2 366.07 462.61 30.61 o -4 4 2 198.58 196.00 7.56 o -3 4 2 111.26 107.41 4.21 o -2 4 2 55.60 54.12 4.95 o -1 4 2 6.98 9.23 2.01 o 0 4 2 169.12 180.34 4.34 o 1 4 2 105.87 109.17 4.29 o 2 4 2 1583.95 1684.11 39.14 o 3 4 2 1201.62 1324.03 30.69 o 4 4 2 76.78 79.44 6.03 o 5 4 2 149.54 153.76 10.71 o 6 4 2 3.72 6.59 8.28 o 7 4 2 16.95 -3.08 8.81 o 8 4 2 0.07 -10.01 18.13 o -8 5 2 8.53 -5.00 16.89 o -7 5 2 41.91 45.68 15.01 o -6 5 2 44.88 37.98 7.88 o -5 5 2 580.69 606.33 23.71 o -4 5 2 79.11 84.87 5.98 o -3 5 2 75.76 77.75 3.91 o -2 5 2 72.00 80.58 5.73 o -1 5 2 1036.81 1030.14 21.89 o 0 5 2 26.38 28.52 2.27 o 1 5 2 146.63 156.02 4.98 o 2 5 2 0.44 -1.96 1.96 o 3 5 2 41.81 39.62 4.08 o 4 5 2 86.14 70.25 5.43 o 5 5 2 79.71 71.57 8.46 o 6 5 2 22.34 5.77 7.71 o 7 5 2 0.16 9.36 16.89 o -6 6 2 6.55 5.65 13.13 o -5 6 2 429.59 398.66 41.20 o -4 6 2 8.20 6.60 5.79 o -3 6 2 192.49 217.41 32.76 o -2 6 2 15.38 12.87 4.10 o -1 6 2 1383.55 1347.12 28.74 o 0 6 2 1460.12 1388.79 25.63 o 1 6 2 1276.50 1357.74 25.29 o 2 6 2 1492.88 1552.18 28.21 o 3 6 2 1.69 0.67 2.84 o 4 6 2 101.74 97.70 10.69 o 6 6 2 215.31 222.27 22.49 o -6 7 2 378.65 361.79 22.41 o -5 7 2 1990.67 1996.21 70.05 o -4 7 2 562.67 578.37 49.59 o -3 7 2 225.11 232.89 17.48 o -2 7 2 204.88 216.50 12.06 o -1 7 2 427.91 401.51 12.65 o 0 7 2 882.99 864.65 16.67 o 1 7 2 1048.56 1065.22 19.22 o 2 7 2 510.89 543.99 12.64 o 3 7 2 118.89 110.84 27.78 o 4 7 2 325.68 336.63 36.47 o 5 7 2 322.71 329.22 29.08 o 6 7 2 101.81 111.02 13.98 o -6 8 2 71.94 46.78 23.16 o -5 8 2 289.36 350.81 52.09 o -4 8 2 776.27 734.84 35.19 o -3 8 2 555.52 524.43 39.76 o -2 8 2 485.96 500.49 22.35 o -1 8 2 861.07 897.27 29.22 o 0 8 2 127.61 115.92 10.75 o 1 8 2 38.05 56.20 8.21 o 2 8 2 990.94 980.27 39.00 o 3 8 2 133.04 118.91 11.72 o 4 8 2 522.24 537.20 26.22 o 5 8 2 1229.40 1206.38 123.67 o -4 9 2 545.58 513.35 27.44 o -3 9 2 496.11 517.35 40.09 o -2 9 2 1130.14 1151.13 70.81 o -1 9 2 26.04 36.54 11.69 o 0 9 2 30.97 43.15 16.89 o 1 9 2 391.09 395.62 31.26 o 2 9 2 864.80 947.34 54.10 o 3 9 2 25.41 14.60 14.60 o 4 9 2 252.94 284.43 35.44 o -2 10 2 315.43 265.30 32.55 o -1 10 2 368.61 394.07 24.57 o 0 10 2 2.45 -2.28 11.50 o 1 10 2 943.84 1039.23 77.76 o 2 10 2 505.44 584.33 47.09 o -9 1 3 156.94 125.67 23.37 o -8 1 3 13.51 33.43 15.13 o -7 1 3 62.94 40.55 24.16 o -6 1 3 60.57 62.79 9.99 o -5 1 3 97.25 114.87 7.84 o -4 1 3 1061.29 1065.96 23.63 o -3 1 3 973.46 973.01 19.68 o -2 1 3 8838.58 8892.36 207.79 o -1 1 3 678.24 633.41 10.13 o 0 1 3 6040.10 5237.82 354.40 o 1 1 3 638.18 733.49 14.58 o 2 1 3 403.76 408.25 9.14 o 3 1 3 357.98 342.46 8.72 o 4 1 3 798.43 788.90 19.12 o 5 1 3 18.94 22.61 6.38 o 6 1 3 50.98 49.46 9.62 o 7 1 3 120.74 133.61 12.88 o 8 1 3 0.80 5.98 19.90 o 9 1 3 94.05 123.38 23.90 o -9 2 3 109.44 95.53 19.13 o -8 2 3 603.02 617.01 34.41 o -7 2 3 438.00 484.97 33.38 o -6 2 3 34.12 25.98 9.01 o -5 2 3 1589.63 1562.32 84.50 o -4 2 3 2752.34 2697.49 51.80 o -3 2 3 3116.04 3022.90 53.20 o -2 2 3 167.62 143.56 3.69 o -1 2 3 12130.55 11461.94 214.08 o 0 2 3 208.03 194.30 3.66 o 1 2 3 1570.24 1542.89 28.69 o 2 2 3 2853.08 2824.70 49.16 o 3 2 3 1626.81 1652.94 31.47 o 4 2 3 13.49 12.77 6.43 o 5 2 3 16.09 18.89 6.18 o 6 2 3 133.11 123.99 14.13 o 8 2 3 92.39 79.46 13.63 o -8 3 3 82.83 88.35 14.48 o -7 3 3 50.14 57.55 10.50 o -6 3 3 101.82 121.03 23.52 o -5 3 3 37.00 30.49 4.94 o -4 3 3 32.24 30.63 3.75 o -3 3 3 618.54 605.74 11.85 o -2 3 3 723.16 666.09 11.37 o -1 3 3 1621.33 1534.88 29.85 o 0 3 3 622.64 509.02 8.06 o 1 3 3 73.73 70.81 3.24 o 2 3 3 5668.63 5879.03 101.70 o 3 3 3 7744.01 7840.92 156.93 o 4 3 3 125.31 130.63 7.46 o 5 3 3 165.90 157.48 8.87 o 6 3 3 1747.63 1752.85 85.53 o 7 3 3 1410.83 1431.49 51.41 o -8 4 3 312.84 374.78 37.61 o -7 4 3 1180.18 1202.97 61.10 o -6 4 3 320.29 316.98 21.78 o -5 4 3 1269.30 1315.59 42.91 o -4 4 3 3488.17 3507.26 73.58 o -3 4 3 2116.08 2109.99 33.12 o -2 4 3 3967.16 3853.46 64.28 o -1 4 3 7537.44 7422.44 112.99 o 0 4 3 2971.34 2955.60 40.13 o 1 4 3 2470.15 2566.30 37.28 o 2 4 3 15194.69 16005.83 531.59 o 3 4 3 711.77 682.33 15.64 o 4 4 3 11.60 1.54 4.04 o 5 4 3 212.92 229.76 12.80 o 6 4 3 782.24 823.55 45.68 o 7 4 3 3.16 11.44 12.51 o 8 4 3 85.80 149.34 23.13 o -8 5 3 5.42 14.42 20.01 o -7 5 3 38.85 77.52 17.54 o -6 5 3 524.30 518.09 26.84 o -5 5 3 3.01 2.38 7.89 o -4 5 3 64.92 70.75 4.67 o -3 5 3 729.76 761.81 24.80 o -2 5 3 1065.91 1051.96 23.15 o -1 5 3 1008.51 978.76 21.33 o 0 5 3 650.28 520.43 9.16 o 1 5 3 876.15 866.71 16.88 o 2 5 3 1072.01 1016.69 19.42 o 3 5 3 1597.22 1551.90 44.83 o 4 5 3 37.32 38.10 6.10 o 5 5 3 553.18 554.10 23.06 o 6 5 3 1658.12 1681.06 83.76 o 7 5 3 230.05 204.73 24.37 o -6 6 3 0.38 3.96 9.36 o -5 6 3 1265.32 1288.68 51.83 o -4 6 3 798.19 830.68 31.47 o -3 6 3 2243.59 2237.33 62.73 o -2 6 3 1637.80 1679.22 50.44 o -1 6 3 5746.35 5691.63 120.01 o 0 6 3 510.00 492.68 10.26 o 1 6 3 49.35 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