#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:14:46 +0300 (Sun, 03 Apr 2016) $ #$Revision: 180987 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/67/2206710.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2206710_Fobs loop_ _publ_author_name 'Mart\'inez-Mart\'inez, Francisco J.' 'Maya-Lugardo, Paloma' 'Garc\'ia-B\'aez, Efr\'en V.' 'H\"opfl, Herbert' 'Hern\'andez-D\'iaz, Julio' 'Padilla-Mart\'inez, Itzia I.' _publ_section_title ; Diethyl N,N'-cyclohexane-1,4-diyldioxalamate ; _journal_coeditor_code HG6227 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2994 _journal_page_last o2996 _journal_volume 61 _journal_year 2005 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 106.709 _cell_angle_gamma 90.000 _cell_length_a 13.1453 _cell_length_b 7.2093 _cell_length_c 8.6617 _exptl_crystal_F_000 336.00 _reflns_d_resolution_high 0.8107 _cod_data_source_file hg6227Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' ipsecx in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 91.58 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 200.19 233.30 5.25 o 2 0 0 1961.55 2078.84 31.47 o 3 0 0 257.41 237.70 3.96 o 4 0 0 418.61 400.96 6.55 o 5 0 0 45.75 42.11 1.25 o 6 0 0 663.57 672.41 10.91 o 7 0 0 65.17 57.26 1.65 o 8 0 0 655.90 613.19 11.19 o 9 0 0 379.77 357.55 8.57 o 10 0 0 579.68 512.13 20.79 o 11 0 0 4.83 7.11 1.24 o 12 0 0 4.42 8.86 1.37 o 13 0 0 1.33 1.37 0.84 o 14 0 0 14.16 17.55 2.44 o 15 0 0 8.49 10.19 2.77 o 1 1 0 442.86 518.51 6.12 o 2 1 0 4009.32 4015.76 46.01 o 3 1 0 2165.62 2102.96 22.63 o 4 1 0 441.18 434.20 5.04 o 5 1 0 49.89 60.85 1.11 o 6 1 0 48.57 41.23 0.95 o 7 1 0 37.17 29.73 0.86 o 8 1 0 91.97 95.56 1.74 o 9 1 0 166.95 143.25 6.24 o 10 1 0 118.40 114.91 2.59 o 11 1 0 14.51 17.17 1.28 o 12 1 0 0.45 2.31 0.73 o 13 1 0 9.60 13.35 1.40 o 14 1 0 2.25 3.75 0.93 o 15 1 0 1.54 3.70 1.09 o 0 2 0 37.28 39.66 1.28 o 1 2 0 122.32 113.83 1.58 o 2 2 0 977.07 1100.17 12.94 o 3 2 0 6.71 7.54 0.45 o 4 2 0 63.26 43.08 1.26 o 5 2 0 703.50 693.06 7.96 o 6 2 0 83.79 99.40 1.67 o 7 2 0 3.69 6.97 0.55 o 8 2 0 65.76 50.06 2.12 o 9 2 0 72.25 68.86 1.86 o 10 2 0 49.09 47.70 1.81 o 11 2 0 8.23 7.23 1.11 o 12 2 0 66.11 55.56 2.35 o 13 2 0 4.81 6.14 1.11 o 14 2 0 10.31 11.79 1.45 o 15 2 0 1.71 4.20 1.10 o 1 3 0 396.86 408.13 4.91 o 2 3 0 219.71 239.14 3.38 o 3 3 0 392.27 416.76 5.46 o 4 3 0 76.53 74.99 1.51 o 5 3 0 77.27 91.54 1.76 o 6 3 0 267.06 249.13 3.76 o 7 3 0 1.32 2.01 0.41 o 8 3 0 22.52 21.70 1.11 o 9 3 0 45.94 35.80 1.58 o 10 3 0 10.15 13.13 1.23 o 11 3 0 73.11 70.18 2.67 o 12 3 0 46.40 44.70 2.61 o 13 3 0 16.53 15.52 1.65 o 14 3 0 3.30 6.03 1.44 o 0 4 0 385.00 403.93 7.15 o 1 4 0 8.99 13.04 0.64 o 2 4 0 11.97 10.96 0.63 o 3 4 0 148.27 165.01 3.01 o 4 4 0 3.08 5.27 0.57 o 5 4 0 284.56 269.73 4.07 o 6 4 0 5.93 5.73 0.62 o 7 4 0 184.98 164.43 3.59 o 8 4 0 1.84 1.05 0.68 o 9 4 0 469.51 430.69 10.13 o 10 4 0 6.00 9.85 1.20 o 11 4 0 11.08 13.47 1.50 o 12 4 0 9.39 15.32 1.66 o 13 4 0 0.11 1.11 0.94 o 1 5 0 245.47 234.25 3.71 o 2 5 0 2.60 2.92 0.53 o 3 5 0 355.46 360.29 5.23 o 4 5 0 0.46 0.93 0.56 o 5 5 0 46.82 44.95 1.57 o 6 5 0 1.33 0.80 0.65 o 7 5 0 561.65 518.45 9.41 o 8 5 0 18.01 18.34 1.50 o 9 5 0 4.88 7.51 1.13 o 10 5 0 0.68 2.64 0.83 o 11 5 0 0.03 1.21 0.79 o 12 5 0 0.53 2.73 0.97 o 0 6 0 95.08 100.63 3.47 o 1 6 0 8.61 9.14 0.91 o 2 6 0 25.82 27.61 1.33 o 3 6 0 112.86 99.64 2.50 o 4 6 0 91.54 91.38 2.41 o 5 6 0 22.64 24.42 1.37 o 6 6 0 14.18 19.04 1.60 o 7 6 0 6.20 8.18 1.18 o 8 6 0 0.60 1.73 0.71 o 9 6 0 0.68 1.34 1.12 o 10 6 0 2.28 3.19 0.93 o 11 6 0 0.08 3.20 1.02 o 1 7 0 0.57 2.00 0.74 o 2 7 0 33.06 28.96 1.72 o 3 7 0 0.35 2.18 1.18 o 4 7 0 1.92 4.56 0.89 o 5 7 0 0.61 1.23 0.70 o 6 7 0 9.03 10.29 1.34 o 7 7 0 2.18 4.30 1.08 o 8 7 0 1.67 5.29 1.55 o 9 7 0 7.80 12.89 1.55 o 0 8 0 15.11 17.68 2.49 o 1 8 0 13.41 14.76 1.67 o 2 8 0 11.77 15.04 1.68 o 3 8 0 0.07 1.64 0.82 o 4 8 0 13.11 13.95 1.46 o 5 8 0 5.36 6.27 1.31 o 6 8 0 0.88 2.33 1.11 o -15 1 1 24.50 27.59 1.73 o -14 1 1 39.20 38.71 1.95 o -13 1 1 4.06 5.85 1.24 o -12 1 1 129.91 113.23 2.94 o -11 1 1 3.00 3.61 0.72 o -10 1 1 20.44 17.90 0.93 o -9 1 1 49.72 38.46 1.11 o -8 1 1 67.18 60.51 1.32 o -7 1 1 25.85 22.51 0.76 o -6 1 1 1.49 1.20 0.30 o -5 1 1 1014.25 1048.33 11.64 o -4 1 1 5168.40 5309.85 56.63 o -3 1 1 5155.62 5194.89 55.35 o -2 1 1 4134.38 4706.95 53.53 o -1 1 1 164.76 204.29 2.42 o 0 1 1 317.26 324.42 3.70 o 1 1 1 2893.91 3112.78 33.26 o 2 1 1 0.36 0.54 0.17 o 3 1 1 50.55 41.37 0.94 o 4 1 1 259.47 213.04 2.98 o 5 1 1 2471.02 2543.17 29.56 o 6 1 1 89.87 90.66 1.71 o 7 1 1 712.49 701.72 8.87 o 8 1 1 33.54 30.84 1.06 o 9 1 1 0.53 0.03 0.42 o 10 1 1 64.92 54.10 1.72 o 11 1 1 35.01 37.12 1.66 o 12 1 1 0.20 1.86 0.71 o 13 1 1 1.06 3.73 0.85 o 14 1 1 6.49 11.76 2.54 o -15 2 1 11.58 14.61 1.64 o -14 2 1 12.35 15.89 1.60 o -13 2 1 20.74 22.71 1.74 o -12 2 1 65.58 55.68 2.90 o -11 2 1 141.12 120.32 3.00 o -10 2 1 25.34 23.36 1.28 o -9 2 1 8.59 10.02 0.76 o -8 2 1 0.83 0.21 0.36 o -7 2 1 27.29 22.33 0.81 o -6 2 1 1004.19 987.74 11.17 o -5 2 1 157.40 171.60 2.39 o -4 2 1 1320.02 1403.10 14.53 o -3 2 1 0.12 0.83 0.21 o -2 2 1 756.87 883.72 10.52 o -1 2 1 382.15 360.72 4.26 o 0 2 1 138.14 132.90 1.82 o 1 2 1 49.16 40.30 0.80 o 2 2 1 747.46 743.71 8.96 o 3 2 1 837.30 828.33 9.96 o 4 2 1 792.29 917.76 11.07 o 5 2 1 101.46 96.58 1.55 o 6 2 1 0.18 0.07 0.24 o 7 2 1 0.15 0.69 0.39 o 8 2 1 6.53 8.60 0.81 o 9 2 1 32.15 26.95 1.40 o 10 2 1 60.96 54.11 1.98 o 11 2 1 62.71 50.96 1.98 o 12 2 1 7.72 8.98 1.24 o 13 2 1 3.37 5.43 1.09 o 14 2 1 2.74 5.67 1.32 o -14 3 1 2.01 4.89 1.07 o -13 3 1 16.76 21.09 1.73 o -12 3 1 23.37 21.71 1.59 o -11 3 1 92.85 84.50 2.54 o -10 3 1 25.80 31.59 1.56 o -9 3 1 10.12 11.18 1.09 o -8 3 1 31.17 30.15 1.56 o -7 3 1 23.48 25.25 1.28 o -6 3 1 41.93 31.41 1.04 o -5 3 1 191.27 192.64 3.23 o -4 3 1 16.69 15.67 0.58 o -3 3 1 51.91 50.12 1.04 o -2 3 1 539.30 567.81 6.64 o -1 3 1 193.07 191.45 2.61 o 0 3 1 672.35 753.12 8.59 o 1 3 1 625.35 657.56 7.59 o 2 3 1 0.74 0.76 0.31 o 3 3 1 0.23 0.29 0.29 o 4 3 1 34.53 31.57 1.33 o 5 3 1 1.46 2.96 0.43 o 6 3 1 140.65 130.65 2.79 o 7 3 1 5.77 7.56 0.78 o 8 3 1 76.90 84.09 2.36 o 9 3 1 11.26 11.41 1.05 o 10 3 1 170.08 156.24 4.22 o 11 3 1 9.44 9.51 1.28 o 12 3 1 6.06 11.03 1.36 o 13 3 1 5.34 7.32 1.24 o 14 3 1 8.66 9.59 2.11 o -14 4 1 1.33 4.07 1.08 o -13 4 1 4.82 5.68 1.16 o -12 4 1 1.43 3.56 0.88 o -11 4 1 15.05 15.93 1.45 o -10 4 1 71.93 61.70 2.20 o -9 4 1 81.79 87.43 2.57 o -8 4 1 9.20 7.50 0.86 o -7 4 1 138.84 123.98 2.90 o -6 4 1 2.17 3.01 0.66 o -5 4 1 0.01 0.70 0.54 o -4 4 1 169.98 162.59 2.72 o -3 4 1 123.89 114.19 1.92 o -2 4 1 648.21 723.29 8.48 o -1 4 1 308.58 333.07 4.31 o 0 4 1 779.49 840.56 9.71 o 1 4 1 123.90 132.92 2.13 o 2 4 1 217.17 221.46 3.42 o 3 4 1 35.08 28.34 1.45 o 4 4 1 172.93 156.68 2.72 o 5 4 1 58.71 51.50 1.84 o 6 4 1 69.56 52.13 1.99 o 7 4 1 6.71 11.27 0.91 o 8 4 1 233.50 212.88 4.46 o 9 4 1 8.61 7.56 0.99 o 10 4 1 1.66 4.35 0.98 o 11 4 1 0.02 1.94 0.99 o 12 4 1 8.90 12.01 2.01 o 13 4 1 0.96 4.69 1.17 o -13 5 1 4.50 6.24 1.96 o -12 5 1 8.41 16.06 2.68 o -11 5 1 19.67 21.04 1.59 o -10 5 1 0.01 -0.21 0.70 o -9 5 1 1.05 1.75 0.71 o -8 5 1 30.50 30.20 1.57 o -7 5 1 37.91 43.36 1.61 o -6 5 1 139.24 121.33 3.93 o -5 5 1 48.27 45.09 2.04 o -4 5 1 131.62 117.62 2.63 o -3 5 1 80.12 83.01 2.11 o -2 5 1 0.73 2.57 0.52 o -1 5 1 41.73 38.08 1.16 o 0 5 1 0.08 0.78 0.45 o 1 5 1 21.31 24.83 1.04 o 2 5 1 1.46 0.85 0.44 o 3 5 1 24.92 27.14 1.11 o 4 5 1 154.45 147.28 2.77 o 5 5 1 530.55 513.24 7.12 o 6 5 1 30.12 33.10 1.71 o 7 5 1 6.45 8.56 1.17 o 8 5 1 34.19 32.90 1.63 o 9 5 1 3.49 6.36 1.18 o 10 5 1 1.82 3.23 0.91 o 11 5 1 0.83 2.68 1.91 o 12 5 1 0.15 1.32 0.96 o -11 6 1 3.31 6.90 1.42 o -10 6 1 0.71 2.75 1.10 o -9 6 1 2.71 4.81 0.99 o -8 6 1 4.31 7.73 1.08 o -7 6 1 2.58 4.56 0.85 o -6 6 1 1.82 1.54 0.69 o -5 6 1 93.58 86.57 2.46 o -4 6 1 46.77 37.66 1.55 o -3 6 1 31.00 28.97 1.35 o -2 6 1 26.55 20.17 1.39 o -1 6 1 69.46 61.78 2.08 o 0 6 1 1.24 1.78 0.57 o 1 6 1 0.78 1.80 0.63 o 2 6 1 2.90 2.33 0.60 o 3 6 1 291.29 273.04 4.45 o 4 6 1 0.63 1.08 0.66 o 5 6 1 97.56 98.36 2.92 o 6 6 1 2.81 3.02 0.92 o 7 6 1 5.95 9.54 1.26 o 8 6 1 10.18 13.24 1.40 o 9 6 1 7.04 9.43 1.22 o 10 6 1 0.91 4.41 1.27 o -9 7 1 0.05 1.19 1.37 o -8 7 1 0.02 1.97 1.02 o -7 7 1 35.41 36.98 2.15 o -6 7 1 8.30 9.24 1.16 o -5 7 1 17.74 20.32 1.62 o -4 7 1 0.03 1.90 0.73 o -3 7 1 0.00 0.92 1.08 o -2 7 1 6.11 4.26 0.90 o -1 7 1 54.80 53.40 2.06 o 0 7 1 4.55 6.28 0.94 o 1 7 1 70.53 67.11 2.59 o 2 7 1 0.99 1.89 0.72 o 3 7 1 6.60 9.54 1.45 o 4 7 1 1.50 1.03 0.65 o 5 7 1 2.09 3.78 1.25 o 6 7 1 3.54 7.36 1.20 o 7 7 1 0.13 2.15 0.88 o 8 7 1 2.18 3.06 0.97 o 9 7 1 10.29 16.28 1.63 o -7 8 1 4.45 7.27 1.78 o -6 8 1 2.28 4.08 1.38 o -5 8 1 3.55 5.32 1.06 o -4 8 1 5.94 9.95 1.32 o -3 8 1 0.04 2.57 0.91 o -2 8 1 0.35 2.75 0.88 o -1 8 1 0.15 1.79 0.94 o 0 8 1 3.26 6.32 1.17 o 1 8 1 2.27 4.54 1.04 o 2 8 1 2.21 7.60 1.47 o 3 8 1 10.60 17.81 1.65 o 4 8 1 1.08 2.62 1.38 o 5 8 1 0.86 4.68 1.21 o 6 8 1 2.45 4.39 1.31 o -16 0 2 28.61 37.49 3.96 o -15 0 2 0.12 4.41 2.03 o -14 0 2 1.47 2.38 1.08 o -13 0 2 6.90 6.50 1.49 o -12 0 2 1.55 0.71 0.78 o -11 0 2 36.03 27.01 1.50 o -10 0 2 30.21 24.37 1.36 o -9 0 2 21.61 19.13 1.17 o -8 0 2 8.48 13.29 0.96 o -7 0 2 744.73 765.91 12.52 o -6 0 2 241.43 267.89 4.89 o -5 0 2 60.13 69.75 1.72 o -4 0 2 117.04 143.70 2.75 o -3 0 2 2874.34 3095.19 46.90 o -2 0 2 8226.55 9238.89 138.89 o -1 0 2 8387.05 9609.98 144.34 o 0 0 2 8.80 16.22 0.70 o 1 0 2 4388.55 5031.10 78.89 o 2 0 2 2248.09 2539.64 42.91 o 3 0 2 321.94 346.22 7.00 o 4 0 2 417.34 436.63 7.32 o 5 0 2 371.30 376.53 7.83 o 6 0 2 104.98 110.01 3.19 o 7 0 2 100.57 89.75 2.94 o 8 0 2 422.70 397.82 8.76 o 9 0 2 114.08 110.24 3.61 o 10 0 2 123.44 126.82 4.73 o 11 0 2 92.98 77.43 3.16 o 12 0 2 7.70 12.52 1.58 o 13 0 2 6.98 8.92 1.88 o 14 0 2 1.97 4.01 3.07 o -16 1 2 13.76 15.51 1.98 o -15 1 2 2.91 5.82 1.13 o -14 1 2 3.46 3.26 0.86 o -13 1 2 10.76 12.71 1.38 o -12 1 2 21.98 20.23 1.24 o -11 1 2 60.93 56.68 1.71 o -10 1 2 2.83 4.60 0.60 o -9 1 2 0.06 0.49 0.37 o -8 1 2 269.61 286.09 3.86 o -7 1 2 16.60 16.79 0.69 o -6 1 2 0.00 0.53 0.25 o -5 1 2 1988.61 1952.00 21.22 o -4 1 2 1.33 1.23 0.37 o -3 1 2 904.41 998.10 10.99 o -2 1 2 1133.48 1353.52 15.76 o -1 1 2 94.42 101.06 1.56 o 0 1 2 1592.74 1743.11 18.85 o 1 1 2 1045.74 1155.61 12.96 o 2 1 2 81.73 63.55 1.08 o 3 1 2 143.13 150.55 2.44 o 4 1 2 135.26 165.22 2.89 o 5 1 2 986.36 1039.58 12.61 o 6 1 2 25.35 25.54 0.92 o 7 1 2 2.35 1.42 0.52 o 8 1 2 86.96 92.71 2.22 o 9 1 2 218.23 190.44 3.65 o 10 1 2 24.05 25.21 1.41 o 11 1 2 0.00 0.35 0.71 o 12 1 2 4.99 6.69 1.31 o 13 1 2 6.67 10.39 1.26 o 14 1 2 0.91 2.56 0.81 o -15 2 2 11.40 17.38 1.72 o -14 2 2 15.11 20.74 1.62 o -13 2 2 15.71 18.24 1.53 o -12 2 2 0.09 0.30 0.61 o -11 2 2 38.45 39.95 1.86 o -10 2 2 42.68 42.02 1.33 o -9 2 2 95.61 86.38 1.88 o -8 2 2 26.56 24.04 0.96 o -7 2 2 1198.55 1182.02 13.33 o -6 2 2 78.97 84.36 1.82 o -5 2 2 544.01 562.19 7.10 o -4 2 2 3.48 4.74 0.43 o -3 2 2 83.74 95.78 1.67 o -2 2 2 1008.30 1084.15 12.02 o -1 2 2 38.18 56.05 1.09 o 0 2 2 73.46 101.13 1.52 o 1 2 2 544.49 545.37 6.30 o 2 2 2 17.61 19.05 0.86 o 3 2 2 2224.92 2595.49 28.07 o 4 2 2 240.18 275.95 3.36 o 5 2 2 5.57 2.97 0.46 o 6 2 2 1.02 0.32 0.36 o 7 2 2 22.63 19.84 1.04 o 8 2 2 5.07 4.71 0.79 o 9 2 2 17.63 17.64 1.30 o 10 2 2 7.46 8.62 1.07 o 11 2 2 11.90 14.42 1.36 o 12 2 2 1.31 2.89 0.81 o 13 2 2 6.09 8.94 1.38 o -15 3 2 2.91 5.39 1.52 o -14 3 2 46.84 44.02 2.19 o -13 3 2 0.17 2.10 0.87 o -12 3 2 35.54 34.37 1.61 o -11 3 2 0.58 0.98 0.67 o -10 3 2 34.31 30.40 1.45 o -9 3 2 87.20 77.57 2.04 o -8 3 2 149.65 131.00 2.74 o -7 3 2 309.02 296.25 4.37 o -6 3 2 847.89 836.74 10.42 o -5 3 2 3.64 3.81 0.49 o -4 3 2 1040.43 1145.60 13.84 o -3 3 2 49.52 52.70 1.29 o -2 3 2 115.66 105.16 1.72 o -1 3 2 461.61 490.86 6.60 o 0 3 2 1535.97 1695.99 18.64 o 1 3 2 665.10 685.57 7.96 o 2 3 2 124.45 129.06 1.98 o 3 3 2 89.18 73.95 1.34 o 4 3 2 47.90 58.16 1.38 o 5 3 2 4.62 1.79 0.50 o 6 3 2 25.66 22.46 1.16 o 7 3 2 48.28 42.91 1.46 o 8 3 2 2.71 2.40 0.65 o 9 3 2 0.93 3.13 0.79 o 10 3 2 3.87 2.95 0.79 o 11 3 2 22.73 22.78 1.81 o 12 3 2 2.17 2.24 0.93 o 13 3 2 7.01 13.26 1.65 o -14 4 2 1.45 2.95 1.25 o -13 4 2 0.19 1.30 0.89 o -12 4 2 23.90 23.43 1.89 o -11 4 2 78.79 71.93 2.41 o -10 4 2 114.92 99.05 2.80 o -9 4 2 81.91 72.00 2.52 o -8 4 2 25.51 23.57 1.47 o -7 4 2 131.20 116.35 3.73 o -6 4 2 33.49 26.06 1.19 o -5 4 2 2.97 5.47 0.78 o -4 4 2 0.77 0.12 0.44 o -3 4 2 4.30 7.40 0.67 o -2 4 2 2.39 1.34 0.39 o -1 4 2 362.63 379.69 4.86 o 0 4 2 20.43 26.73 0.92 o 1 4 2 28.51 27.79 0.91 o 2 4 2 3.79 5.77 0.65 o 3 4 2 44.14 51.23 1.38 o 4 4 2 9.34 9.82 0.76 o 5 4 2 96.35 107.75 2.70 o 6 4 2 174.48 160.85 3.29 o 7 4 2 155.75 135.27 3.21 o 8 4 2 62.96 50.80 1.87 o 9 4 2 4.07 5.70 1.05 o 10 4 2 8.71 12.37 1.47 o 11 4 2 4.00 6.15 1.21 o 12 4 2 3.00 5.69 1.22 o -13 5 2 3.45 6.04 1.38 o -12 5 2 6.28 7.24 1.33 o -11 5 2 3.60 6.94 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