#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:19:25 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181002 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/82/2208216.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2208216_Fobs loop_ _publ_author_name 'Zhang, Bao-Feng' 'Xie, Cheng-Zhi' 'Wang, Xiao-Qing' 'Shen, Guang-Qiu' 'Shen, De-Zhong' _publ_section_title ; Poly[[hexaaquabis(\m~3~-pyridine-2,5-dicarboxylato-\k^4^O:O',N:O'')bis(\m~2~-pyridine-2,5-dicarboxylato-\k^3^O:O',N)dieuropium(III)copper(II)] dihydrate] ; _journal_coeditor_code XU6074 _journal_issue 2 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m297 _journal_page_last m299 _journal_volume 62 _journal_year 2006 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 97.273 _cell_angle_gamma 90.000 _cell_length_a 9.2710 _cell_length_b 25.5475 _cell_length_c 7.7925 _exptl_crystal_F_000 1142.00 _reflns_d_resolution_high 0.8004 _cod_data_source_file xu6074Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 040428H in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 282.90 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 29370.09 22198.20 508.11 o 2 0 0 69973.71 61666.12 2175.33 o 3 0 0 37618.66 35492.77 673.84 o 4 0 0 59463.97 56400.27 1105.40 o 5 0 0 14316.48 13412.91 285.16 o 6 0 0 29405.79 29143.06 552.93 o 7 0 0 1230.37 1236.83 91.89 o 8 0 0 38431.25 37866.92 724.99 o 9 0 0 5711.11 6034.94 209.49 o 10 0 0 9100.80 9032.08 396.09 o 11 0 0 3422.27 2952.90 254.76 o 1 1 0 4288.51 4140.39 202.38 o 2 1 0 2437.95 2539.65 54.08 o 3 1 0 4285.57 4315.39 119.24 o 4 1 0 2851.34 2868.08 69.82 o 5 1 0 2050.92 1996.27 61.82 o 6 1 0 3645.06 3809.38 93.28 o 7 1 0 2713.34 2872.30 90.24 o 8 1 0 2629.62 2689.72 94.53 o 9 1 0 3575.81 3683.38 116.36 o 10 1 0 3375.83 3190.32 199.24 o 11 1 0 5162.00 5007.16 242.86 o 0 2 0 47.40 -9.17 9.17 o 1 2 0 44171.40 39517.88 953.99 o 2 2 0 213.33 318.23 17.76 o 3 2 0 5968.23 5952.68 96.36 o 4 2 0 3556.85 3937.07 74.74 o 5 2 0 7035.53 7002.04 134.76 o 6 2 0 1270.06 1391.74 54.06 o 7 2 0 1948.58 2025.04 154.49 o 8 2 0 2909.60 2914.82 97.84 o 9 2 0 4958.19 4844.08 156.05 o 10 2 0 324.93 296.66 87.79 o 11 2 0 1491.15 1211.12 145.50 o 1 3 0 280.48 258.86 22.50 o 2 3 0 468.16 520.55 22.67 o 3 3 0 4345.20 4424.49 68.28 o 4 3 0 538.84 568.95 33.71 o 5 3 0 1688.17 1707.49 61.37 o 6 3 0 287.23 314.72 32.50 o 7 3 0 3530.66 3481.81 96.84 o 8 3 0 306.29 370.18 65.19 o 9 3 0 1468.17 1653.76 99.86 o 10 3 0 1792.42 1706.97 144.83 o 11 3 0 1521.23 1589.49 152.87 o 0 4 0 24362.25 22487.34 874.16 o 1 4 0 53837.60 46492.14 1307.20 o 2 4 0 17261.26 16474.54 487.48 o 3 4 0 39190.93 36577.23 508.79 o 4 4 0 10089.00 10603.30 135.50 o 5 4 0 41187.03 40486.18 444.28 o 6 4 0 8433.08 8512.75 152.80 o 7 4 0 5520.46 5752.60 127.38 o 8 4 0 6224.52 5997.47 166.10 o 9 4 0 11513.36 10824.44 247.12 o 10 4 0 1611.59 1574.20 112.09 o 11 4 0 2991.90 2864.30 175.91 o 1 5 0 841.12 800.19 23.07 o 2 5 0 1090.81 1104.60 32.57 o 3 5 0 317.66 380.76 26.38 o 4 5 0 256.49 269.46 42.66 o 5 5 0 7175.51 7157.43 105.71 o 6 5 0 11557.02 11691.86 190.78 o 7 5 0 4153.83 4217.38 150.89 o 8 5 0 15108.32 15001.21 325.68 o 9 5 0 4937.26 5245.75 164.66 o 10 5 0 5855.32 5988.75 189.13 o 11 5 0 5878.19 5999.40 202.28 o 0 6 0 40598.12 36271.57 1387.81 o 1 6 0 10530.08 10548.54 229.05 o 2 6 0 21404.13 19795.71 314.82 o 3 6 0 2470.16 2178.92 59.26 o 4 6 0 53552.01 53672.46 520.07 o 5 6 0 4816.89 4722.46 79.60 o 6 6 0 19896.01 19663.15 282.15 o 7 6 0 12118.25 11948.68 240.74 o 8 6 0 11855.08 12073.95 289.72 o 9 6 0 1544.25 1482.94 101.18 o 10 6 0 5661.93 5632.72 184.38 o 11 6 0 534.30 365.05 127.86 o 1 7 0 2254.33 2377.55 61.20 o 2 7 0 8588.02 8667.25 113.51 o 3 7 0 4308.83 4542.16 73.07 o 4 7 0 1017.62 985.08 36.58 o 5 7 0 136.67 153.87 29.08 o 6 7 0 159.85 201.78 42.73 o 7 7 0 1475.63 1436.99 107.93 o 8 7 0 995.54 1084.37 84.57 o 9 7 0 2025.70 1971.77 112.45 o 10 7 0 498.17 461.90 102.49 o 11 7 0 7.48 129.01 137.87 o 0 8 0 18066.62 17793.66 264.39 o 1 8 0 1900.95 2180.11 41.19 o 2 8 0 189.75 163.03 21.75 o 3 8 0 1053.39 1261.02 39.22 o 4 8 0 2928.50 2700.70 58.69 o 5 8 0 21.27 7.52 25.70 o 6 8 0 4563.19 4501.76 161.96 o 7 8 0 371.96 476.35 103.34 o 8 8 0 1336.68 1223.06 89.60 o 9 8 0 396.75 441.27 81.92 o 10 8 0 2041.74 2012.08 169.67 o 11 8 0 175.20 193.38 185.07 o 1 9 0 347.19 359.42 28.00 o 2 9 0 723.48 716.40 31.23 o 3 9 0 5731.39 5836.47 94.47 o 4 9 0 4012.19 3891.65 73.58 o 5 9 0 1080.68 1049.66 42.79 o 6 9 0 3079.54 2919.72 101.19 o 7 9 0 3688.33 3710.08 123.50 o 8 9 0 2626.73 2476.64 111.10 o 9 9 0 1453.10 1426.86 103.18 o 10 9 0 2766.03 2797.50 183.39 o 11 9 0 5062.70 5083.84 237.93 o 0 10 0 18451.01 17568.54 269.22 o 1 10 0 45233.70 41572.72 747.76 o 2 10 0 21402.03 20985.38 266.28 o 3 10 0 41569.89 38252.46 420.79 o 4 10 0 8231.23 7788.97 118.30 o 5 10 0 26674.99 25974.99 307.79 o 6 10 0 2396.73 2347.68 201.12 o 7 10 0 11528.55 11481.91 307.70 o 8 10 0 5727.69 5672.33 206.99 o 9 10 0 9227.27 8958.83 293.76 o 10 10 0 2616.69 2511.09 299.99 o 1 11 0 2077.35 2330.43 51.32 o 2 11 0 188.50 210.55 27.72 o 3 11 0 1533.81 1649.58 68.30 o 4 11 0 1883.05 2011.97 55.27 o 5 11 0 629.97 566.41 40.81 o 6 11 0 2513.51 2346.39 92.44 o 7 11 0 4612.18 4570.16 139.73 o 8 11 0 7030.56 6607.69 235.79 o 9 11 0 5587.22 5722.65 236.69 o 10 11 0 2412.95 2679.55 180.36 o 0 12 0 16636.41 15548.91 603.29 o 1 12 0 1534.92 1515.24 40.55 o 2 12 0 6681.63 6502.92 104.24 o 3 12 0 1070.29 1179.48 45.22 o 4 12 0 6272.63 6263.61 106.77 o 5 12 0 337.78 434.91 41.17 o 6 12 0 3647.25 3464.93 97.73 o 7 12 0 170.16 144.66 66.14 o 8 12 0 2289.39 2344.55 153.29 o 9 12 0 15.46 72.51 97.44 o 10 12 0 390.80 403.67 137.80 o 1 13 0 146.16 257.84 28.22 o 2 13 0 94.61 129.47 44.92 o 3 13 0 11.35 85.96 30.12 o 4 13 0 257.66 336.30 44.59 o 5 13 0 271.36 347.53 74.90 o 6 13 0 174.08 205.28 48.09 o 7 13 0 7.02 -86.19 86.19 o 8 13 0 60.69 134.44 89.64 o 9 13 0 612.90 568.56 125.22 o 10 13 0 46.61 75.14 132.10 o 0 14 0 48406.87 46074.98 651.42 o 1 14 0 11319.93 11093.95 178.46 o 2 14 0 21823.51 21041.74 258.62 o 3 14 0 16727.12 16390.59 214.38 o 4 14 0 17234.10 16346.06 217.42 o 5 14 0 7439.55 7379.74 171.11 o 6 14 0 14983.23 14818.03 241.80 o 7 14 0 3551.25 3414.35 174.87 o 8 14 0 10417.75 10574.83 326.84 o 9 14 0 892.61 1032.06 129.45 o 10 14 0 2454.60 2668.07 256.09 o 1 15 0 448.07 616.49 47.49 o 2 15 0 110.43 402.06 45.23 o 3 15 0 3664.00 3915.96 90.62 o 4 15 0 5510.70 5328.10 103.91 o 5 15 0 2445.37 2512.79 84.05 o 6 15 0 3889.37 4044.87 134.79 o 7 15 0 4345.97 4437.58 317.17 o 8 15 0 6327.64 6186.74 248.16 o 9 15 0 3561.63 3776.87 203.63 o 10 15 0 3866.67 3867.03 227.74 o 0 16 0 21259.11 21867.46 535.88 o 1 16 0 18569.61 18034.81 210.39 o 2 16 0 15511.94 15988.19 234.16 o 3 16 0 24473.54 23133.52 287.92 o 4 16 0 13313.54 12935.74 188.02 o 5 16 0 15031.37 14974.88 294.44 o 6 16 0 4735.29 4688.76 149.64 o 7 16 0 8250.36 7809.54 265.07 o 8 16 0 7525.86 7168.26 515.04 o 9 16 0 7133.24 6759.09 272.64 o 1 17 0 94.10 515.35 72.88 o 2 17 0 203.62 416.48 63.93 o 3 17 0 1132.06 1201.23 54.57 o 4 17 0 311.22 386.16 63.69 o 5 17 0 320.54 271.55 93.23 o 6 17 0 488.14 410.74 77.69 o 7 17 0 943.53 872.54 110.10 o 8 17 0 523.05 688.72 132.42 o 9 17 0 1352.20 1224.92 144.32 o 0 18 0 302.67 240.32 51.23 o 1 18 0 487.36 552.15 43.96 o 2 18 0 2590.34 2641.09 74.55 o 3 18 0 6742.72 6701.52 122.77 o 4 18 0 115.31 128.21 46.04 o 5 18 0 3529.07 3566.15 132.13 o 6 18 0 1994.97 1847.97 104.51 o 7 18 0 1470.38 1694.08 137.57 o 8 18 0 43.97 48.76 117.16 o 9 18 0 800.10 843.04 145.06 o 1 19 0 0.86 89.66 41.40 o 2 19 0 605.73 718.50 60.65 o 3 19 0 1323.06 1462.61 73.64 o 4 19 0 784.13 895.15 68.27 o 5 19 0 3559.72 3455.42 130.63 o 6 19 0 1141.92 1158.79 91.55 o 7 19 0 3301.07 3348.77 140.33 o 8 19 0 3156.24 3398.12 207.77 o 9 19 0 3783.27 4076.11 226.80 o 0 20 0 22907.81 23462.44 382.64 o 1 20 0 11539.29 11768.12 178.89 o 2 20 0 26339.93 25992.84 374.27 o 3 20 0 11089.37 10823.15 224.80 o 4 20 0 25016.31 25401.09 374.79 o 5 20 0 9659.12 9758.20 200.83 o 6 20 0 16806.91 16604.84 406.06 o 7 20 0 6642.52 6807.52 206.47 o 8 20 0 10059.82 9909.17 383.64 o 1 21 0 21.47 453.45 58.36 o 2 21 0 136.96 939.89 148.68 o 3 21 0 7.65 179.43 57.82 o 4 21 0 1471.87 1594.08 128.89 o 5 21 0 494.47 629.30 90.19 o 6 21 0 3301.84 3083.71 120.05 o 7 21 0 1051.98 1131.32 108.42 o 8 21 0 2631.32 2961.95 190.22 o 0 22 0 1179.17 1158.61 93.63 o 1 22 0 5527.06 5882.31 167.02 o 2 22 0 619.62 649.75 65.26 o 3 22 0 1770.33 1887.31 88.15 o 4 22 0 3114.46 3029.49 128.03 o 5 22 0 2451.34 2496.76 122.21 o 6 22 0 80.99 79.66 75.36 o 7 22 0 1809.84 1611.21 102.35 o 8 22 0 183.06 36.07 189.51 o 1 23 0 111.63 429.91 68.26 o 2 23 0 6.92 35.03 59.15 o 3 23 0 1558.20 1685.26 89.39 o 4 23 0 932.59 932.36 89.10 o 5 23 0 42.25 191.15 83.57 o 6 23 0 443.96 623.89 91.20 o 7 23 0 1.90 38.33 95.98 o 0 24 0 3228.92 3653.15 234.82 o 1 24 0 11790.64 11937.01 251.37 o 2 24 0 4961.09 4985.60 134.70 o 3 24 0 9717.88 9857.86 202.89 o 4 24 0 1517.46 1353.37 105.14 o 5 24 0 5633.58 5915.34 187.73 o 6 24 0 1489.90 1571.39 119.29 o 7 24 0 3874.54 4076.75 212.83 o 1 25 0 137.31 771.02 119.33 o 2 25 0 555.40 739.93 75.14 o 3 25 0 2186.91 2414.58 105.11 o 4 25 0 893.27 1010.32 96.81 o 5 25 0 363.03 389.00 89.67 o 6 25 0 932.57 1103.26 161.91 o 7 25 0 2528.12 2578.94 167.71 o 0 26 0 12325.10 12489.24 480.62 o 1 26 0 5408.52 5372.56 211.41 o 2 26 0 9715.10 10015.85 299.30 o 3 26 0 1391.09 1433.57 92.06 o 4 26 0 7957.19 8613.63 230.41 o 5 26 0 2631.53 2853.29 140.93 o 6 26 0 3611.98 3777.56 166.65 o 1 27 0 0.91 221.73 101.82 o 2 27 0 320.49 676.51 164.43 o 3 27 0 752.96 879.75 104.64 o 4 27 0 854.89 932.08 115.17 o 5 27 0 160.51 225.72 89.70 o 6 27 0 655.49 709.32 107.16 o 0 28 0 30.73 187.38 136.16 o 1 28 0 38.32 33.83 96.04 o 2 28 0 1378.22 1375.18 128.18 o 3 28 0 74.69 123.24 107.76 o 4 28 0 559.04 397.00 115.83 o 5 28 0 729.35 580.36 110.43 o 1 29 0 0.39 116.47 103.28 o 2 29 0 1.98 73.38 102.55 o 3 29 0 412.79 499.30 146.72 o 4 29 0 481.38 554.83 271.90 o 0 30 0 3326.76 3503.97 260.49 o 1 30 0 7934.46 8252.09 282.73 o 2 30 0 3950.78 4278.69 206.33 o 3 30 0 9223.01 9351.83 432.76 o 1 31 0 91.74 414.93 116.17 o 2 31 0 23.08 244.09 204.94 o -11 1 1 2540.53 2319.01 153.01 o -10 1 1 4377.10 4017.15 213.79 o -9 1 1 485.62 562.63 65.22 o -8 1 1 17570.43 17317.46 275.32 o -7 1 1 2998.84 3067.29 97.15 o -6 1 1 16636.16 16974.39 261.08 o -5 1 1 1994.91 1910.22 59.99 o -4 1 1 18387.47 18471.36 215.95 o -3 1 1 6291.18 6474.83 101.28 o -2 1 1 25649.85 24364.64 347.56 o -1 1 1 8157.70 8348.87 146.86 o 0 1 1 47134.25 43867.60 695.20 o 1 1 1 1094.31 987.64 23.47 o 2 1 1 17271.83 17219.99 421.14 o 3 1 1 25001.12 25247.11 705.25 o 4 1 1 39298.45 38830.99 480.18 o 5 1 1 1008.01 1029.02 50.63 o 6 1 1 9194.05 9143.33 164.44 o 7 1 1 162.31 238.49 50.40 o 8 1 1 601.75 555.29 63.77 o 9 1 1 282.30 339.87 71.39 o 10 1 1 190.19 185.33 113.78 o 11 1 1 93.12 -92.37 117.71 o -11 2 1 1047.18 1039.28 127.20 o -10 2 1 435.83 562.70 97.73 o -9 2 1 13.99 29.47 64.47 o -8 2 1 7068.74 6727.17 147.66 o -7 2 1 77.32 188.63 46.57 o -6 2 1 5.79 156.91 37.83 o -5 2 1 25.80 134.56 32.99 o -4 2 1 9.46 82.41 22.42 o -3 2 1 794.87 875.87 30.21 o -2 2 1 1747.46 1709.06 37.89 o -1 2 1 34483.65 32872.06 439.06 o 0 2 1 5989.24 6267.84 191.36 o 1 2 1 13069.32 12935.57 180.71 o 2 2 1 8305.09 8034.41 165.62 o 3 2 1 12075.23 12484.85 168.53 o 4 2 1 12871.72 12911.89 179.11 o 5 2 1 21208.84 21391.99 257.53 o 6 2 1 10773.49 10416.49 160.70 o 7 2 1 6657.92 6841.49 146.90 o 8 2 1 16127.39 15797.51 264.63 o 9 2 1 9380.54 9285.38 234.38 o 10 2 1 9603.55 9872.46 250.04 o 11 2 1 8610.44 8371.03 321.26 o -11 3 1 11777.00 11769.45 341.86 o -10 3 1 5697.17 5432.62 176.44 o -9 3 1 15364.03 14939.79 299.72 o -8 3 1 13910.37 14040.17 294.82 o -7 3 1 29106.37 28424.52 392.27 o -6 3 1 19291.74 19403.94 278.87 o -5 3 1 69793.88 67587.70 716.26 o -4 3 1 22418.92 22932.58 263.17 o -3 3 1 59692.63 54399.65 1164.92 o -2 3 1 19871.66 19263.22 239.07 o -1 3 1 14039.11 13920.72 199.52 o 0 3 1 36191.85 34781.65 459.50 o 1 3 1 51236.28 47409.82 622.26 o 2 3 1 17008.07 17120.86 240.61 o 3 3 1 41233.81 39267.91 466.41 o 4 3 1 14555.83 14741.95 288.73 o 5 3 1 19829.27 19646.36 239.87 o 6 3 1 542.70 585.77 40.01 o 7 3 1 1689.77 1769.08 97.78 o 8 3 1 7048.64 7161.82 158.98 o 9 3 1 1542.20 1704.14 107.57 o 10 3 1 79.60 143.52 92.37 o 11 3 1 182.73 257.28 186.68 o -11 4 1 37.96 76.85 108.01 o -10 4 1 8.94 64.79 76.85 o -9 4 1 498.47 437.19 71.67 o -8 4 1 21.68 6.89 56.62 o -7 4 1 566.35 662.71 83.92 o -6 4 1 5.65 56.50 39.91 o -5 4 1 269.27 354.78 43.53 o -4 4 1 1616.62 1966.61 46.77 o -3 4 1 452.81 357.67 26.95 o -2 4 1 1421.05 1542.32 39.61 o -1 4 1 184.97 193.67 15.92 o 0 4 1 2260.37 2320.49 44.13 o 1 4 1 17077.30 16320.50 229.62 o 2 4 1 10796.64 10068.90 277.27 o 3 4 1 8047.82 8201.15 160.11 o 4 4 1 3827.93 3630.82 65.85 o 5 4 1 6096.13 6272.23 101.46 o 6 4 1 6210.73 6035.42 110.87 o 7 4 1 5977.57 6070.23 135.61 o 8 4 1 1347.88 1443.18 92.66 o 9 4 1 7339.08 7629.23 230.25 o 10 4 1 2497.10 2513.73 133.72 o 11 4 1 2278.63 2129.08 226.98 o -11 5 1 587.97 728.71 127.73 o -10 5 1 1193.64 1147.98 99.49 o -9 5 1 13.74 21.12 65.86 o -8 5 1 3654.54 3733.66 156.46 o -7 5 1 16.85 84.15 47.70 o -6 5 1 1098.38 1084.01 46.44 o -5 5 1 5476.88 5868.07 96.33 o -4 5 1 13215.48 14061.92 175.89 o -3 5 1 2652.71 2639.42 60.43 o -2 5 1 1777.20 1742.42 44.18 o -1 5 1 1698.47 1623.94 52.49 o 0 5 1 22635.21 22929.57 270.58 o 1 5 1 9269.28 9178.52 176.79 o 2 5 1 851.13 739.57 33.52 o 3 5 1 10197.91 11284.37 205.43 o 4 5 1 1438.04 1522.22 41.85 o 5 5 1 2104.20 2089.00 54.50 o 6 5 1 1420.22 1509.32 52.10 o 7 5 1 1738.71 1820.85 77.89 o 8 5 1 2.99 65.51 66.82 o 9 5 1 300.45 370.36 89.67 o 10 5 1 949.66 791.25 128.34 o 11 5 1 219.14 251.88 141.52 o -11 6 1 229.03 295.21 102.18 o -10 6 1 4.38 64.83 78.34 o -9 6 1 103.95 99.36 65.34 o -8 6 1 0.37 78.62 71.06 o -7 6 1 1010.74 1115.10 71.92 o -6 6 1 283.23 502.63 70.21 o -5 6 1 2736.03 3005.55 64.96 o -4 6 1 1470.13 1742.55 116.49 o -3 6 1 29.61 83.66 23.28 o -2 6 1 1507.27 1515.75 35.40 o -1 6 1 7560.01 7764.08 98.65 o 0 6 1 44975.69 41841.55 481.08 o 1 6 1 7268.77 7875.25 107.39 o 2 6 1 3482.89 3390.61 60.80 o 3 6 1 8243.79 8136.14 122.80 o 4 6 1 12392.46 12781.40 183.03 o 5 6 1 12420.80 12378.34 191.60 o 6 6 1 7883.88 8203.46 128.98 o 7 6 1 6333.20 6386.81 273.84 o 8 6 1 11957.85 11938.31 256.27 o 9 6 1 4505.71 4581.46 158.75 o 10 6 1 2887.92 3163.22 180.55 o 11 6 1 3571.20 4084.03 538.13 o -11 7 1 3220.88 3392.33 158.32 o -10 7 1 8268.22 8428.02 225.15 o -9 7 1 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