#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/98/2209879.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2209879_Fobs loop_ _publ_author_name 'Aghabozorg, Hossein' 'Ghadermazi, Mohammad' 'Sheshmani, Shabnam' _publ_section_title ; A novel proton-transfer compound: piperazinium oxalate monohydrate ; _journal_coeditor_code HK2071 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3287 _journal_page_last o3289 _journal_volume 62 _journal_year 2006 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 96.858 _cell_angle_gamma 90.000 _cell_length_a 11.9831 _cell_length_b 6.4802 _cell_length_c 11.2561 _exptl_crystal_F_000 400.00 _reflns_d_resolution_high 0.8102 _[local]_cod_data_source_file hk2071Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' a8b8 in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 86.53 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 11.81 1.03 9.21 o 3 0 0 67.05 82.43 15.20 o 4 0 0 6300.36 5958.56 60.45 o 5 0 0 115.56 93.03 20.75 o 6 0 0 3584.45 3720.01 147.69 o 7 0 0 6.70 9.59 15.87 o 8 0 0 2204.27 2467.29 58.14 o 9 0 0 8.52 16.61 18.64 o 10 0 0 319.42 259.77 29.10 o 11 0 0 39.20 7.31 18.43 o 12 0 0 2.35 1.12 19.08 o 13 0 0 215.56 269.20 52.03 o 14 0 0 244.33 236.11 51.85 o 1 1 0 265.62 277.56 24.86 o 2 1 0 5.20 14.07 8.17 o 3 1 0 517.70 475.02 18.62 o 4 1 0 129.78 123.28 14.43 o 5 1 0 2.39 2.93 9.51 o 6 1 0 154.60 159.09 14.82 o 7 1 0 119.89 126.51 15.28 o 8 1 0 26.61 41.55 13.66 o 9 1 0 9.25 47.62 14.61 o 10 1 0 14.52 6.75 13.42 o 11 1 0 0.00 -2.53 16.27 o 12 1 0 9.52 3.47 16.59 o 13 1 0 36.91 50.56 19.81 o 14 1 0 43.79 45.67 21.72 o 1 2 0 9.42 12.12 9.26 o 2 2 0 2738.71 2660.11 27.09 o 3 2 0 0.55 3.37 8.70 o 4 2 0 2780.08 3174.95 60.88 o 5 2 0 5.00 17.59 17.11 o 6 2 0 1800.45 1750.77 46.71 o 7 2 0 73.73 66.28 13.91 o 8 2 0 3.63 2.92 11.82 o 10 2 0 733.82 670.60 33.07 o 11 2 0 60.19 63.20 19.54 o 12 2 0 5.64 5.11 16.23 o 13 2 0 52.45 60.32 21.44 o 14 2 0 13.68 6.88 23.98 o 1 3 0 497.57 588.15 56.10 o 2 3 0 215.26 189.65 13.47 o 3 3 0 4.03 3.32 9.34 o 4 3 0 294.66 315.86 29.13 o 5 3 0 105.55 131.56 17.24 o 6 3 0 26.20 23.91 13.89 o 7 3 0 46.35 30.66 21.72 o 8 3 0 243.86 273.29 24.17 o 10 3 0 48.32 57.53 19.33 o 11 3 0 494.14 452.66 30.85 o 12 3 0 16.56 7.19 21.31 o 13 3 0 7.10 17.99 23.61 o 0 4 0 12.22 16.71 15.09 o 1 4 0 23.50 15.48 10.68 o 2 4 0 218.26 201.50 15.02 o 3 4 0 58.18 64.49 12.92 o 4 4 0 1562.14 1801.15 29.02 o 5 4 0 6.31 4.68 13.01 o 6 4 0 1.91 0.53 12.56 o 7 4 0 1.96 -3.45 13.43 o 8 4 0 266.59 227.97 31.76 o 9 4 0 219.55 322.00 35.80 o 10 4 0 235.02 268.85 39.20 o 11 4 0 90.32 81.76 29.22 o 12 4 0 144.24 145.40 33.45 o 1 5 0 120.12 112.10 14.99 o 2 5 0 211.72 190.54 15.94 o 3 5 0 67.75 59.94 16.31 o 4 5 0 71.93 70.06 16.01 o 5 5 0 69.26 65.75 17.06 o 6 5 0 157.84 173.06 31.02 o 7 5 0 274.98 277.70 36.69 o 8 5 0 78.53 79.05 26.87 o 9 5 0 7.01 7.32 21.26 o 10 5 0 398.98 384.69 40.10 o 11 5 0 0.10 -5.36 22.59 o 0 6 0 30.87 50.74 19.78 o 1 6 0 12.39 8.01 11.54 o 2 6 0 3.31 3.15 13.14 o 3 6 0 201.50 190.90 29.92 o 4 6 0 17.27 29.23 20.86 o 5 6 0 15.08 31.57 21.74 o 6 6 0 2.18 -3.65 19.04 o 7 6 0 171.84 198.36 33.86 o 8 6 0 26.36 16.08 22.09 o 9 6 0 105.38 120.51 31.26 o 1 7 0 25.24 23.56 19.49 o 2 7 0 7.95 7.29 19.60 o 3 7 0 42.95 26.53 22.19 o 4 7 0 23.44 32.37 21.99 o 5 7 0 5.65 17.72 21.59 o 6 7 0 6.60 6.10 21.14 o 7 7 0 140.51 107.96 32.43 o -14 1 1 2.69 -0.07 17.92 o -13 1 1 148.99 187.07 27.67 o -12 1 1 97.37 118.42 22.90 o -11 1 1 374.40 322.76 26.00 o -10 1 1 95.30 75.38 16.13 o -9 1 1 84.68 120.40 16.47 o -8 1 1 75.51 79.38 15.17 o -7 1 1 858.14 849.02 24.50 o -6 1 1 11.35 11.20 10.78 o -5 1 1 0.21 2.04 10.93 o -2 1 1 3937.16 3353.77 50.53 o -1 1 1 2107.36 1513.18 215.53 o 1 1 1 3349.57 3144.35 38.73 o 2 1 1 5008.29 4298.65 91.58 o 3 1 1 305.18 228.50 13.16 o 5 1 1 41.61 57.55 12.20 o 6 1 1 339.32 311.73 17.30 o 7 1 1 862.28 837.56 25.35 o 8 1 1 140.87 146.86 16.92 o 10 1 1 0.38 -4.51 12.43 o 11 1 1 150.77 129.52 19.07 o 12 1 1 26.75 19.61 17.52 o 13 1 1 217.12 184.63 27.83 o 14 1 1 1.14 1.49 19.53 o -14 2 1 3.18 9.45 20.04 o -13 2 1 5.02 -0.65 17.18 o -12 2 1 11.68 14.87 17.91 o -11 2 1 73.34 55.71 20.54 o -10 2 1 202.69 212.62 25.44 o -9 2 1 10.41 10.46 16.30 o -8 2 1 0.36 -2.48 14.19 o -7 2 1 979.16 1006.26 29.14 o -6 2 1 1.03 -2.15 11.77 o -5 2 1 573.28 625.24 41.03 o -4 2 1 1523.74 2274.05 340.78 o -3 2 1 891.11 810.67 22.93 o -2 2 1 48.19 64.71 10.35 o -1 2 1 4406.61 4782.12 157.04 o 0 2 1 69.21 109.78 11.17 o 1 2 1 2625.81 3457.67 220.86 o 2 2 1 78.68 42.55 9.67 o 3 2 1 578.71 565.62 20.55 o 4 2 1 3166.77 3537.08 53.46 o 5 2 1 910.06 973.72 32.64 o 6 2 1 483.69 510.44 19.75 o 7 2 1 452.04 406.35 19.63 o 8 2 1 136.95 139.66 16.43 o 10 2 1 81.69 53.20 19.45 o 11 2 1 0.96 -0.12 16.30 o 12 2 1 77.48 67.17 20.24 o 13 2 1 214.35 245.46 38.06 o 14 2 1 0.10 5.94 23.44 o -13 3 1 81.88 66.97 28.60 o -12 3 1 9.28 9.99 17.36 o -11 3 1 505.37 483.71 31.11 o -10 3 1 15.85 24.56 17.85 o -9 3 1 608.53 888.06 35.42 o -8 3 1 32.61 13.55 20.65 o -7 3 1 14.11 10.18 13.78 o -6 3 1 1132.59 1143.30 32.99 o -5 3 1 678.72 616.38 25.17 o -4 3 1 891.23 1046.29 29.01 o -3 3 1 1439.64 1411.51 23.96 o -2 3 1 2053.98 2107.78 48.51 o -1 3 1 8.59 12.63 9.60 o 1 3 1 18.58 7.96 9.22 o 2 3 1 206.97 222.78 20.95 o 3 3 1 683.92 649.99 18.17 o 4 3 1 538.27 625.18 21.10 o 5 3 1 22.31 22.21 10.58 o 6 3 1 226.00 214.44 18.92 o 7 3 1 50.85 38.86 16.62 o 8 3 1 196.38 196.51 22.25 o 10 3 1 0.40 -2.44 19.98 o 11 3 1 602.97 539.29 70.10 o 12 3 1 89.99 71.41 27.41 o 13 3 1 7.33 61.34 28.29 o -12 4 1 71.82 73.76 28.03 o -11 4 1 17.47 1.07 20.26 o -10 4 1 287.71 267.33 27.36 o -9 4 1 111.19 231.07 34.25 o -8 4 1 5.04 1.04 18.33 o -7 4 1 446.93 381.27 24.71 o -6 4 1 0.01 -3.93 13.44 o -5 4 1 0.08 1.05 12.65 o -4 4 1 895.36 1321.93 137.00 o -3 4 1 16.35 18.69 11.18 o -2 4 1 522.52 473.98 19.14 o -1 4 1 395.78 420.73 19.26 o 1 4 1 28.97 24.78 13.97 o 2 4 1 191.62 173.16 14.29 o 3 4 1 193.76 207.98 15.01 o 4 4 1 401.44 409.78 18.53 o 5 4 1 114.75 114.17 13.74 o 6 4 1 180.71 174.35 19.76 o 7 4 1 94.62 57.94 23.46 o 8 4 1 141.71 155.97 29.84 o 9 4 1 619.25 722.40 47.23 o 10 4 1 199.24 173.90 32.50 o 11 4 1 3.12 5.10 21.48 o 12 4 1 51.81 48.83 26.71 o -11 5 1 50.28 26.82 24.51 o -10 5 1 20.73 10.18 22.05 o -9 5 1 11.76 14.89 20.81 o -8 5 1 52.39 50.25 24.82 o -7 5 1 8.71 9.84 20.15 o -6 5 1 1.33 0.87 14.03 o -5 5 1 11.54 26.23 14.97 o -4 5 1 21.89 39.79 15.46 o -3 5 1 47.98 50.32 16.03 o -2 5 1 59.72 51.95 13.53 o -1 5 1 74.11 79.54 14.27 o 1 5 1 1.63 -0.59 10.58 o 2 5 1 408.38 396.26 19.50 o 3 5 1 24.30 16.11 11.93 o 4 5 1 2.20 28.18 24.71 o 5 5 1 12.95 47.01 26.17 o 6 5 1 90.62 76.60 24.75 o 7 5 1 3.64 5.46 19.86 o 8 5 1 163.39 135.00 30.35 o 9 5 1 5.97 5.43 21.44 o 10 5 1 55.37 67.84 27.91 o 11 5 1 69.14 51.86 28.35 o -9 6 1 87.99 121.65 32.74 o -8 6 1 14.66 20.97 22.74 o -7 6 1 46.75 33.60 22.83 o -6 6 1 52.96 40.76 23.08 o -5 6 1 223.25 190.32 31.91 o -4 6 1 84.00 83.12 17.95 o -3 6 1 296.55 260.58 22.54 o -2 6 1 176.02 165.58 20.38 o -1 6 1 63.27 51.46 15.75 o 1 6 1 11.89 9.17 13.91 o 2 6 1 150.62 129.41 25.84 o 3 6 1 600.06 559.88 38.78 o 4 6 1 3.83 6.71 18.19 o 5 6 1 17.58 12.23 19.73 o 6 6 1 55.36 51.67 23.50 o 7 6 1 208.79 178.45 33.04 o 8 6 1 233.90 278.20 37.13 o 9 6 1 6.64 73.75 27.91 o -7 7 1 90.21 76.52 29.09 o -6 7 1 11.07 2.33 22.98 o -5 7 1 62.49 65.92 24.66 o -4 7 1 55.23 52.67 24.27 o -3 7 1 102.78 94.43 26.63 o -2 7 1 176.72 155.35 42.19 o -1 7 1 167.49 175.69 27.73 o 0 7 1 1.20 7.73 24.80 o 1 7 1 9.72 16.89 26.61 o 2 7 1 30.78 19.82 20.93 o 3 7 1 23.42 10.34 20.43 o 4 7 1 2.13 -1.17 19.60 o 5 7 1 5.60 12.67 21.89 o 6 7 1 6.62 4.62 21.30 o -14 0 2 31.09 23.37 35.21 o -13 0 2 21.11 22.00 33.84 o -12 0 2 106.62 88.24 25.67 o -11 0 2 65.96 43.70 21.38 o -10 0 2 67.48 63.57 26.45 o -9 0 2 14.09 12.13 18.26 o -8 0 2 3.08 8.91 17.64 o -7 0 2 0.01 -0.32 15.60 o -6 0 2 2000.57 2243.47 110.48 o -4 0 2 1723.47 1664.99 45.61 o -3 0 2 5723.38 6367.22 77.27 o -2 0 2 6638.45 5152.95 62.13 o 2 0 2 5862.82 5481.86 119.74 o 3 0 2 6257.27 5844.91 60.49 o 4 0 2 1647.68 1691.08 40.06 o 5 0 2 1.28 2.09 13.57 o 6 0 2 250.93 254.39 24.40 o 7 0 2 14.04 7.23 16.33 o 8 0 2 113.57 140.96 25.92 o 10 0 2 798.23 774.26 41.92 o 11 0 2 659.28 585.02 39.12 o 12 0 2 75.32 76.56 25.82 o 13 0 2 55.46 71.45 27.27 o 14 0 2 84.18 72.85 40.13 o -14 1 2 10.08 13.94 19.01 o -13 1 2 5.79 60.89 20.83 o -12 1 2 57.58 64.58 21.03 o -11 1 2 43.21 28.57 17.13 o -10 1 2 99.69 118.92 17.82 o -9 1 2 57.54 66.03 15.43 o -8 1 2 567.44 570.54 22.84 o -7 1 2 3.25 6.80 11.63 o -6 1 2 168.26 166.46 17.25 o -5 1 2 10.74 7.67 9.91 o -4 1 2 2536.20 2627.96 28.70 o -3 1 2 1750.09 1746.61 31.54 o -2 1 2 244.52 244.52 20.37 o -1 1 2 1.05 1.59 8.07 o 1 1 2 16.94 9.74 10.19 o 2 1 2 4.13 9.86 8.83 o 3 1 2 1334.28 1388.36 31.54 o 4 1 2 1370.11 1355.95 31.60 o 5 1 2 6.56 7.48 10.17 o 6 1 2 3.00 3.34 10.32 o 7 1 2 413.04 361.28 19.92 o 8 1 2 253.81 248.35 19.12 o 10 1 2 5.34 9.25 13.42 o 11 1 2 490.36 482.07 26.53 o 12 1 2 16.88 11.17 17.70 o 13 1 2 51.71 78.30 23.35 o 14 1 2 0.01 -2.76 21.72 o -14 2 2 85.02 66.25 22.98 o -13 2 2 0.30 -6.45 17.21 o -12 2 2 353.84 310.25 28.86 o -11 2 2 11.18 6.96 16.07 o -10 2 2 172.84 174.03 23.80 o -9 2 2 267.71 305.92 24.47 o -8 2 2 62.09 49.55 21.89 o -7 2 2 5.99 -1.92 12.64 o -6 2 2 8.47 12.03 13.05 o -5 2 2 218.54 211.23 23.04 o -3 2 2 1894.84 1697.51 119.74 o -1 2 2 22.74 13.32 9.19 o 1 2 2 103.77 106.54 10.79 o 3 2 2 1101.45 1123.90 22.85 o 4 2 2 90.34 109.80 12.88 o 5 2 2 126.01 147.49 18.19 o 6 2 2 92.45 94.75 14.11 o 7 2 2 322.19 314.61 19.04 o 8 2 2 309.52 277.59 19.41 o 9 2 2 146.84 142.30 17.33 o 10 2 2 148.68 137.92 22.30 o 11 2 2 14.50 13.84 16.31 o 12 2 2 94.92 86.98 29.74 o 13 2 2 0.27 9.03 22.71 o -13 3 2 3.46 22.44 19.04 o -12 3 2 13.65 4.04 16.72 o -11 3 2 10.43 -3.05 16.91 o -10 3 2 64.75 74.41 20.66 o -9 3 2 896.80 1124.99 61.97 o -8 3 2 239.83 250.17 31.41 o -7 3 2 715.18 678.24 29.02 o -6 3 2 2.08 9.55 13.59 o -5 3 2 58.79 61.47 15.77 o -4 3 2 830.02 972.44 75.90 o -3 3 2 561.97 545.14 17.61 o -2 3 2 19.91 20.43 9.98 o -1 3 2 59.77 65.65 11.71 o 1 3 2 317.33 340.37 17.50 o 2 3 2 153.28 127.09 12.18 o 3 3 2 8.31 1.59 8.92 o 4 3 2 262.37 291.35 27.74 o 5 3 2 347.59 302.15 16.66 o 6 3 2 250.49 261.85 16.82 o 7 3 2 448.36 389.86 24.71 o 8 3 2 32.75 30.27 16.35 o 9 3 2 16.66 15.00 19.84 o 10 3 2 17.84 9.37 20.88 o 11 3 2 19.55 18.69 22.03 o 12 3 2 70.58 45.83 24.94 o 13 3 2 3.97 34.15 25.74 o -12 4 2 25.91 18.53 23.60 o -11 4 2 21.43 21.86 18.20 o -10 4 2 333.46 300.08 36.21 o -9 4 2 156.50 303.91 34.33 o -8 4 2 44.38 38.88 16.30 o -7 4 2 0.01 -8.70 13.86 o -6 4 2 25.84 20.19 15.41 o -5 4 2 0.10 9.09 13.70 o -4 4 2 0.54 194.63 129.55 o -3 4 2 193.30 185.92 15.03 o -2 4 2 0.72 -2.67 9.89 o -1 4 2 15.64 3.78 12.22 o 1 4 2 203.01 184.02 14.57 o 2 4 2 255.20 258.83 15.64 o 3 4 2 40.44 33.99 11.20 o 4 4 2 131.50 119.68 17.49 o 5 4 2 1.66 4.17 13.00 o 6 4 2 258.30 230.37 28.77 o 7 4 2 609.66 545.24 39.71 o 8 4 2 2.76 3.25 19.10 o 9 4 2 2.81 78.05 26.81 o 10 4 2 24.58 15.56 22.22 o 11 4 2 103.45 89.55 30.09 o 12 4 2 0.24 9.42 23.67 o -11 5 2 220.70 235.52 41.16 o -10 5 2 17.27 -0.88 20.23 o -9 5 2 0.00 5.62 20.73 o -8 5 2 63.93 52.47 18.21 o -7 5 2 118.41 131.32 21.57 o -6 5 2 24.91 24.14 15.95 o -5 5 2 260.72 225.26 21.54 o -4 5 2 421.91 382.65 31.01 o -3 5 2 306.86 307.55 22.84 o -2 5 2 11.71 12.77 11.53 o -1 5 2 417.32 488.51 43.31 o 1 5 2 675.87 741.94 41.50 o 2 5 2 1.37 0.05 13.12 o 3 5 2 6.60 0.14 13.38 o 4 5 2 963.96 970.41 46.94 o 5 5 2 39.36 31.64 21.19 o 6 5 2 138.21 131.34 27.82 o 7 5 2 321.63 258.27 32.25 o 8 5 2 277.41 257.35 34.71 o 9 5 2 104.26 159.61 33.41 o 10 5 2 16.61 11.86 21.69 o 11 5 2 0.18 -4.70 22.23 o -9 6 2 17.26 100.80 32.96 o -8 6 2 2.28 14.49 22.47 o -7 6 2 9.84 8.26 22.18 o -6 6 2 9.03 15.32 21.12 o -5 6 2 28.30 35.43 16.73 o -4 6 2 5.18 6.38 14.31 o -3 6 2 1.85 5.51 14.67 o -2 6 2 1.75 -0.77 13.62 o -1 6 2 52.27 33.75 19.57 o 0 6 2 3.30 2.76 14.00 o 1 6 2 152.27 142.62 20.80 o 2 6 2 25.23 12.95 17.99 o 3 6 2 101.86 81.08 23.57 o 4 6 2 54.04 53.59 22.58 o 5 6 2 30.01 29.67 21.19 o 6 6 2 27.35 20.94 20.75 o 7 6 2 38.36 41.35 25.73 o 8 6 2 19.08 13.28 22.58 o 9 6 2 224.54 285.58 41.06 o -7 7 2 164.08 186.83 34.32 o -6 7 2 0.00 2.22 20.80 o -5 7 2 12.45 13.51 22.50 o -4 7 2 0.39 3.53 20.01 o -3 7 2 140.07 119.08 40.88 o -2 7 2 8.57 7.23 18.16 o -1 7 2 7.85 9.12 19.32 o 0 7 2 79.26 152.55 36.08 o 1 7 2 51.72 36.27 26.80 o 2 7 2 1.91 3.62 18.82 o 3 7 2 187.92 198.16 32.93 o 4 7 2 43.12 64.43 25.10 o 5 7 2 6.34 3.01 20.65 o 6 7 2 111.25 91.31 32.59 o -14 1 3 6.06 7.12 22.09 o -13 1 3 130.96 113.02 23.46 o -12 1 3 24.23 21.44 18.04 o -11 1 3 888.66 903.07 37.36 o -10 1 3 418.81 400.81 27.85 o -9 1 3 912.27 994.09 29.01 o -8 1 3 0.00 -3.64 12.40 o -7 1 3 12.91 15.34 14.35 o -6 1 3 39.79 40.07 14.21 o -5 1 3 51.80 42.62 11.16 o -4 1 3 90.84 148.36 14.55 o -3 1 3 7487.66 7194.14 207.04 o 1 1 3 4144.67 4577.96 54.98 o 2 1 3 1251.13 1113.05 34.97 o 3 1 3 1831.50 1913.72 28.85 o 4 1 3 183.90 223.85 16.56 o 5 1 3 78.22 155.26 37.70 o 6 1 3 22.26 22.58 11.97 o 7 1 3 397.23 389.57 21.26 o 8 1 3 35.16 36.89 14.27 o 10 1 3 7.64 5.57 13.63 o 11 1 3 244.88 212.83 22.10 o 12 1 3 466.34 486.49 33.10 o 13 1 3 4.45 101.44 29.49 o -14 2 3 1.55 15.53 19.55 o -13 2 3 59.17 54.98 20.88 o -12 2 3 11.01 12.18 17.00 o -11 2 3 7.60 12.83 17.02 o -10 2 3 339.79 327.92 25.67 o -9 2 3 336.69 340.57 32.27 o -8 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