#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/16/2211680.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2211680_Fobs loop_ _publ_author_name 'Zhang, Chen-Xi' 'Sun, Dong-Lan' 'Wang, Xiao-Cong' _publ_section_title ; 4,4,5,5-Tetramethyl-2-(4-pyridyl)imidazolin-1-oxyl 3-oxide ; _journal_coeditor_code XU2158 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o5666 _journal_page_last o5667 _journal_volume 62 _journal_year 2006 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 108.051 _cell_angle_gamma 90.000 _cell_length_a 11.2051 _cell_length_b 10.4517 _cell_length_c 11.0315 _exptl_crystal_F_000 500.00 _reflns_d_resolution_high 0.7968 _[local]_cod_data_source_file xu2158Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 030509D in C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 236.14 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 17237.96 15236.19 1157.94 o 4 0 0 26.32 15.56 6.12 o 6 0 0 53.64 44.44 9.89 o 8 0 0 1133.62 1166.95 75.99 o 10 0 0 42.92 59.89 16.20 o 12 0 0 199.63 326.21 41.24 o 1 1 0 3890.19 3649.35 197.24 o 3 1 0 6015.39 4707.52 190.98 o 5 1 0 16.22 15.53 5.44 o 7 1 0 155.32 148.73 11.42 o 9 1 0 13.45 -1.86 12.24 o 11 1 0 126.80 166.95 17.95 o 13 1 0 3.82 -5.01 20.65 o 0 2 0 4678.15 5481.03 296.35 o 2 2 0 212.44 171.15 8.40 o 4 2 0 42.33 25.51 7.66 o 6 2 0 152.93 182.33 9.60 o 8 2 0 124.40 114.09 11.31 o 10 2 0 3.27 9.44 11.99 o 12 2 0 0.49 5.57 14.84 o 1 3 0 2502.89 2822.65 125.37 o 3 3 0 0.86 -3.80 3.80 o 5 3 0 647.11 630.04 24.11 o 7 3 0 105.87 115.50 10.10 o 9 3 0 10.93 1.79 10.97 o 11 3 0 2.84 0.32 16.01 o 13 3 0 0.12 -35.68 35.68 o 0 4 0 2939.01 3025.78 164.62 o 2 4 0 638.39 681.18 32.35 o 4 4 0 65.52 45.31 6.49 o 6 4 0 43.66 27.99 6.28 o 8 4 0 275.93 275.39 21.22 o 10 4 0 10.92 -11.96 14.59 o 12 4 0 3.43 28.11 18.13 o 1 5 0 4675.38 5608.29 248.96 o 3 5 0 3.88 -5.86 5.86 o 5 5 0 331.03 288.78 17.18 o 7 5 0 51.51 44.02 8.83 o 9 5 0 39.95 25.16 14.56 o 11 5 0 23.25 13.91 16.10 o 0 6 0 142.01 140.78 11.30 o 2 6 0 303.43 310.74 17.54 o 4 6 0 30.96 31.87 8.35 o 6 6 0 169.56 146.47 12.70 o 8 6 0 0.36 9.01 9.09 o 10 6 0 36.08 36.22 15.80 o 1 7 0 74.65 72.47 8.39 o 3 7 0 70.00 67.59 9.53 o 5 7 0 48.19 25.83 9.37 o 7 7 0 209.26 195.94 13.63 o 9 7 0 31.45 33.35 20.39 o 11 7 0 2.07 -2.63 17.42 o 0 8 0 97.53 88.50 20.85 o 2 8 0 0.89 -5.28 7.39 o 4 8 0 149.34 140.98 12.86 o 6 8 0 301.92 303.24 19.70 o 8 8 0 87.74 86.38 13.06 o 10 8 0 2.54 -22.24 22.24 o 1 9 0 9.53 -1.93 12.91 o 3 9 0 20.94 10.49 13.52 o 5 9 0 53.68 70.56 11.06 o 7 9 0 1.27 22.01 9.71 o 9 9 0 26.12 34.91 16.16 o 0 10 0 186.36 117.69 22.70 o 2 10 0 167.16 141.20 18.51 o 4 10 0 1.89 -14.06 27.57 o 6 10 0 31.65 37.18 15.69 o 8 10 0 0.25 29.75 13.01 o 1 11 0 42.89 55.96 39.85 o 3 11 0 8.62 -10.44 13.57 o 5 11 0 42.26 60.30 25.48 o 7 11 0 0.57 26.19 20.26 o 0 12 0 25.88 2.78 22.24 o 2 12 0 3.50 6.76 16.16 o 4 12 0 5.21 -16.01 16.01 o 1 13 0 3.65 -17.66 17.66 o -13 1 1 6.62 14.91 19.91 o -11 1 1 10.88 12.98 20.62 o -9 1 1 61.26 47.16 10.10 o -7 1 1 66.98 63.73 9.52 o -5 1 1 1.86 -1.64 3.74 o -3 1 1 1200.65 1099.80 65.18 o -1 1 1 1687.88 1570.38 85.19 o 1 1 1 22.91 19.45 3.06 o 3 1 1 1938.36 2039.68 111.73 o 5 1 1 172.98 153.21 11.70 o 7 1 1 14.23 14.94 7.73 o 9 1 1 137.03 116.15 14.83 o 11 1 1 15.13 9.12 15.89 o -12 2 1 29.07 29.21 15.06 o -10 2 1 245.66 289.85 19.74 o -8 2 1 586.42 605.26 29.06 o -6 2 1 185.88 188.00 8.69 o -4 2 1 1673.67 1454.95 113.52 o -2 2 1 704.37 610.54 25.17 o 0 2 1 4472.74 5198.43 399.42 o 2 2 1 16.94 7.91 4.84 o 4 2 1 5243.13 5002.85 231.49 o 6 2 1 400.11 347.30 24.55 o 8 2 1 323.89 303.55 24.28 o 10 2 1 120.34 124.75 15.98 o 12 2 1 21.14 9.27 24.56 o -13 3 1 0.05 12.58 20.15 o -11 3 1 0.37 -1.67 16.14 o -9 3 1 21.88 16.47 8.48 o -7 3 1 0.18 -3.36 5.50 o -5 3 1 261.56 255.60 13.13 o -3 3 1 378.47 455.41 22.29 o -1 3 1 1270.36 1292.68 50.50 o 1 3 1 1899.05 2040.03 78.99 o 3 3 1 372.83 399.65 17.43 o 5 3 1 16.84 3.33 5.06 o 7 3 1 344.74 368.42 28.92 o 9 3 1 60.86 94.47 19.02 o 11 3 1 1.28 -16.71 16.71 o -12 4 1 40.28 40.43 37.30 o -10 4 1 4.32 -5.93 14.14 o -8 4 1 19.61 0.31 12.76 o -6 4 1 82.29 78.40 8.12 o -4 4 1 45.47 41.23 6.49 o -2 4 1 3157.73 3211.82 143.03 o 0 4 1 3699.49 4503.20 172.07 o 2 4 1 1256.89 1363.57 75.50 o 4 4 1 1.58 -4.10 5.08 o 6 4 1 3.12 -2.25 6.27 o 8 4 1 30.79 22.84 14.23 o 10 4 1 177.93 158.57 44.25 o 12 4 1 11.97 2.08 18.26 o -11 5 1 17.09 -13.50 15.60 o -9 5 1 76.73 70.48 15.51 o -7 5 1 62.80 53.24 8.44 o -5 5 1 31.16 12.95 7.43 o -3 5 1 42.01 53.18 8.06 o -1 5 1 2122.94 2422.71 93.76 o 1 5 1 15.56 18.35 3.76 o 3 5 1 1431.19 1537.68 60.56 o 5 5 1 152.81 153.74 10.52 o 7 5 1 60.66 47.51 8.74 o 9 5 1 8.28 16.52 13.69 o 11 5 1 25.46 39.92 16.92 o -12 6 1 6.45 -10.25 18.36 o -10 6 1 0.02 8.96 15.23 o -8 6 1 81.68 69.13 14.56 o -6 6 1 70.94 102.64 21.60 o -4 6 1 57.15 57.99 8.56 o -2 6 1 0.06 -6.14 6.14 o 0 6 1 376.13 401.50 17.60 o 2 6 1 53.25 72.10 8.36 o 4 6 1 230.44 243.46 16.16 o 6 6 1 9.43 4.17 9.94 o 8 6 1 1.47 3.39 9.66 o 10 6 1 3.24 6.28 15.80 o -11 7 1 37.09 43.06 36.61 o -9 7 1 207.43 196.41 21.90 o -7 7 1 697.58 659.00 35.16 o -5 7 1 204.53 188.91 16.08 o -3 7 1 98.35 122.53 11.45 o -1 7 1 146.54 186.65 13.45 o 1 7 1 256.36 264.12 16.22 o 3 7 1 482.34 521.47 27.40 o 5 7 1 1488.85 1509.86 97.04 o 7 7 1 420.83 405.18 23.80 o 9 7 1 111.04 80.85 15.56 o -10 8 1 71.31 90.51 18.46 o -8 8 1 42.11 53.92 24.09 o -6 8 1 76.71 66.42 14.23 o -4 8 1 14.44 17.47 9.34 o -2 8 1 19.19 16.58 7.78 o 0 8 1 0.05 2.52 10.64 o 2 8 1 724.18 747.82 37.28 o 4 8 1 28.78 41.08 9.87 o 6 8 1 73.29 81.24 11.35 o 8 8 1 79.42 90.26 12.34 o 10 8 1 1.49 10.19 17.00 o -9 9 1 0.02 28.27 16.01 o -7 9 1 64.59 66.39 10.50 o -5 9 1 3.91 24.95 16.32 o -3 9 1 385.13 404.80 30.30 o -1 9 1 24.53 14.87 12.46 o 1 9 1 319.39 291.69 25.06 o 3 9 1 31.59 12.61 12.57 o 5 9 1 230.91 214.07 16.29 o 7 9 1 11.84 16.81 11.59 o 9 9 1 3.23 34.79 16.22 o -8 10 1 0.77 27.24 17.14 o -6 10 1 26.44 16.71 13.21 o -4 10 1 84.59 81.81 16.49 o -2 10 1 126.01 108.97 16.16 o 0 10 1 26.99 19.34 13.24 o 2 10 1 94.33 118.26 17.68 o 4 10 1 39.75 25.13 14.88 o 6 10 1 9.50 -0.34 26.64 o 8 10 1 6.85 28.19 12.55 o -7 11 1 0.00 7.22 12.60 o -5 11 1 0.22 16.18 25.68 o -3 11 1 1.77 -9.44 14.37 o -1 11 1 8.54 1.42 15.52 o 1 11 1 5.41 11.18 18.07 o 3 11 1 9.76 8.15 15.06 o 5 11 1 4.83 23.57 23.86 o -4 12 1 2.57 10.00 12.29 o -2 12 1 2.17 1.47 15.83 o 0 12 1 1.90 -1.74 15.83 o 2 12 1 0.28 4.60 15.89 o 4 12 1 34.31 59.96 19.23 o -1 13 1 10.33 20.07 18.79 o 1 13 1 23.82 11.82 17.84 o -12 0 2 24.68 48.03 17.55 o -10 0 2 165.71 161.85 19.39 o -8 0 2 128.59 146.17 17.42 o -6 0 2 2586.55 2637.07 154.24 o -2 0 2 55760.09 42677.87 3452.49 o 2 0 2 6238.90 6109.86 466.60 o 4 0 2 1375.94 1273.31 101.94 o 6 0 2 515.08 532.38 50.04 o 8 0 2 242.24 292.30 43.09 o 10 0 2 492.04 699.67 67.65 o 12 0 2 138.88 216.85 36.61 o -13 1 2 30.85 29.94 16.90 o -11 1 2 18.52 6.20 10.60 o -9 1 2 188.33 176.12 13.83 o -7 1 2 131.93 126.34 10.41 o -5 1 2 878.46 799.38 46.20 o -3 1 2 260.60 261.89 13.04 o -1 1 2 3420.25 3330.67 131.52 o 1 1 2 1128.97 1240.93 55.91 o 3 1 2 109.63 83.88 15.52 o 5 1 2 98.92 90.01 12.92 o 7 1 2 19.73 4.36 8.25 o 9 1 2 98.22 83.10 21.55 o 11 1 2 1.30 -1.62 19.23 o -12 2 2 0.24 -3.69 12.36 o -10 2 2 23.66 13.71 9.74 o -8 2 2 95.36 103.70 11.13 o -6 2 2 205.24 207.51 12.24 o -4 2 2 18.08 13.27 4.96 o -2 2 2 5160.94 4778.87 258.02 o 0 2 2 903.16 984.88 39.04 o 2 2 2 10.11 4.64 5.41 o 4 2 2 117.33 137.65 9.99 o 6 2 2 623.34 664.79 41.45 o 8 2 2 0.46 2.56 11.77 o 10 2 2 13.80 24.96 13.31 o 12 2 2 0.43 32.90 26.41 o -13 3 2 0.01 7.79 32.20 o -11 3 2 4.98 23.40 16.24 o -9 3 2 2.98 15.55 13.37 o -7 3 2 402.22 439.11 24.81 o -5 3 2 1027.04 1006.37 42.17 o -3 3 2 4.43 4.79 4.11 o -1 3 2 79.03 81.93 6.12 o 1 3 2 3.91 -2.40 4.57 o 3 3 2 11.50 9.88 5.32 o 5 3 2 495.39 563.35 30.03 o 7 3 2 70.07 65.77 11.24 o 9 3 2 8.01 3.23 11.59 o 11 3 2 0.21 8.67 17.83 o -12 4 2 0.79 0.83 37.30 o -10 4 2 61.06 66.30 16.63 o -8 4 2 38.17 32.77 14.38 o -6 4 2 63.87 57.80 6.64 o -4 4 2 161.47 151.09 12.00 o -2 4 2 1.37 4.57 4.22 o 0 4 2 12.09 -1.20 4.07 o 2 4 2 612.19 641.12 26.80 o 4 4 2 0.22 -6.82 6.82 o 6 4 2 65.40 68.27 10.12 o 8 4 2 21.51 18.30 14.25 o 10 4 2 0.03 13.92 17.14 o -11 5 2 0.56 11.42 15.51 o -9 5 2 41.21 64.00 15.85 o -7 5 2 50.80 40.11 8.66 o -5 5 2 173.80 158.10 10.99 o -3 5 2 1614.57 1780.75 63.67 o -1 5 2 3732.70 4443.84 171.08 o 1 5 2 0.02 7.94 4.73 o 3 5 2 157.41 137.28 9.24 o 5 5 2 35.92 27.04 7.25 o 7 5 2 103.54 97.11 11.95 o 9 5 2 37.39 42.75 14.57 o 11 5 2 22.52 22.64 34.29 o -12 6 2 20.58 0.26 17.65 o -10 6 2 5.60 7.02 15.42 o -8 6 2 0.52 3.51 22.47 o -6 6 2 134.01 117.41 10.86 o -4 6 2 455.67 458.24 21.71 o -2 6 2 448.73 438.53 22.78 o 0 6 2 101.36 131.76 8.26 o 2 6 2 405.74 386.49 17.81 o 4 6 2 605.13 608.00 34.06 o 6 6 2 130.05 140.27 17.61 o 8 6 2 1.34 15.31 9.28 o 10 6 2 2.15 -7.20 15.25 o -11 7 2 25.59 9.29 17.25 o -9 7 2 51.19 58.57 22.70 o -7 7 2 72.66 67.31 9.41 o -5 7 2 212.62 181.73 12.84 o -3 7 2 195.89 173.34 13.99 o -1 7 2 344.08 366.06 20.35 o 1 7 2 115.42 112.38 10.60 o 3 7 2 0.04 -1.74 8.61 o 5 7 2 455.46 418.62 24.30 o 7 7 2 238.70 215.63 16.28 o 9 7 2 6.46 20.16 14.57 o -10 8 2 48.37 54.01 17.59 o -8 8 2 63.81 75.82 15.47 o -6 8 2 98.48 105.73 12.13 o -4 8 2 0.20 -6.75 8.03 o -2 8 2 235.21 219.16 15.19 o 0 8 2 64.27 48.91 14.73 o 2 8 2 243.35 261.81 16.96 o 4 8 2 257.91 204.49 15.40 o 6 8 2 235.25 274.88 19.10 o 8 8 2 1.26 21.91 21.66 o -9 9 2 1.10 -1.34 32.20 o -7 9 2 9.47 1.16 9.25 o -5 9 2 23.91 26.90 12.71 o -3 9 2 10.30 11.10 10.07 o -1 9 2 35.75 24.48 14.08 o 1 9 2 45.60 59.83 15.21 o 3 9 2 22.43 18.77 14.23 o 5 9 2 7.73 9.64 10.36 o 7 9 2 51.92 45.76 12.58 o -8 10 2 0.00 26.82 16.49 o -6 10 2 43.09 17.90 22.68 o -4 10 2 174.54 141.11 17.09 o -2 10 2 43.52 45.55 15.03 o 0 10 2 26.16 24.78 15.03 o 2 10 2 66.17 61.09 16.22 o 4 10 2 128.06 111.85 31.05 o 6 10 2 24.93 14.93 26.87 o -7 11 2 19.92 11.97 17.61 o -5 11 2 1.51 2.15 11.52 o -3 11 2 48.92 39.54 11.63 o -1 11 2 46.22 51.17 15.36 o 1 11 2 0.06 10.92 15.39 o 3 11 2 91.47 105.17 19.17 o 5 11 2 0.30 -11.75 16.81 o -4 12 2 0.47 20.47 17.39 o -2 12 2 11.79 0.28 19.23 o 0 12 2 41.23 48.19 15.81 o 2 12 2 29.28 44.99 18.01 o 4 12 2 1.13 3.11 18.18 o -13 1 3 6.18 23.96 15.86 o -11 1 3 0.17 -7.59 10.33 o -9 1 3 121.95 122.01 12.36 o -7 1 3 102.97 94.43 9.69 o -5 1 3 21.29 7.03 6.31 o -3 1 3 7919.27 7010.38 276.09 o -1 1 3 516.02 597.18 25.28 o 1 1 3 106.33 104.81 18.04 o 3 1 3 682.10 751.57 44.48 o 5 1 3 210.18 138.69 22.10 o 7 1 3 66.95 30.05 17.05 o 9 1 3 252.93 307.44 27.19 o 11 1 3 13.65 6.02 18.34 o -12 2 3 36.82 53.16 14.55 o -10 2 3 64.46 65.79 10.62 o -8 2 3 108.31 119.81 11.71 o -6 2 3 1475.42 1404.30 70.65 o -4 2 3 107.49 114.93 6.63 o -2 2 3 4109.75 4350.09 153.26 o 0 2 3 152.95 142.04 8.67 o 2 2 3 5400.83 6484.25 498.57 o 4 2 3 1050.24 1429.24 65.99 o 6 2 3 44.45 61.26 13.09 o 8 2 3 281.92 246.06 25.78 o 10 2 3 6.80 56.83 30.81 o -13 3 3 0.70 4.44 18.42 o -11 3 3 8.49 15.36 22.47 o -9 3 3 11.99 0.80 10.69 o -7 3 3 0.27 -6.43 11.13 o -5 3 3 542.74 569.58 29.53 o -3 3 3 1175.84 974.80 40.36 o -1 3 3 1001.86 1062.53 39.03 o 1 3 3 2856.77 3455.15 133.39 o 3 3 3 5.17 0.98 5.37 o 5 3 3 703.64 834.05 69.97 o 7 3 3 76.77 58.96 10.36 o 9 3 3 111.64 125.17 12.51 o 11 3 3 22.67 46.34 25.02 o -12 4 3 8.10 14.51 17.49 o -10 4 3 0.12 6.01 12.93 o -8 4 3 56.58 39.51 13.21 o -6 4 3 100.50 98.51 10.13 o -4 4 3 391.88 349.02 14.87 o -2 4 3 541.24 552.19 21.65 o 0 4 3 1079.62 1353.54 51.06 o 2 4 3 0.09 -4.88 4.88 o 4 4 3 47.33 53.28 7.60 o 6 4 3 132.60 112.17 15.19 o 8 4 3 461.06 453.76 75.99 o 10 4 3 8.98 22.47 16.43 o -11 5 3 1.07 -7.44 15.23 o -9 5 3 40.63 58.47 15.94 o -7 5 3 0.52 -10.54 10.54 o -5 5 3 11.81 14.96 8.46 o -3 5 3 0.39 13.22 13.60 o -1 5 3 88.78 87.83 7.19 o 1 5 3 712.07 793.65 30.05 o 3 5 3 322.27 330.88 16.59 o 5 5 3 17.05 10.37 7.76 o 7 5 3 79.15 84.08 10.95 o 9 5 3 7.51 12.67 15.03 o 11 5 3 1.62 8.36 18.48 o -12 6 3 1.10 -0.83 17.83 o -10 6 3 24.56 38.57 16.01 o -8 6 3 201.71 209.51 27.11 o -6 6 3 22.95 15.54 8.90 o -4 6 3 3.85 5.92 7.87 o -2 6 3 7.58 6.66 6.09 o 0 6 3 194.72 196.12 10.58 o 2 6 3 139.15 159.32 12.51 o 4 6 3 75.49 68.19 9.71 o 6 6 3 15.42 29.12 10.20 o 8 6 3 1.13 4.98 10.35 o 10 6 3 1.12 22.47 44.95 o -11 7 3 60.99 71.53 22.47 o -9 7 3 236.39 236.06 77.15 o -7 7 3 142.00 149.57 21.60 o -5 7 3 129.18 141.53 11.91 o -3 7 3 77.03 65.80 9.46 o -1 7 3 76.59 87.19 9.03 o 1 7 3 517.10 522.01 29.11 o 3 7 3 2778.16 2898.16 131.69 o 5 7 3 624.60 653.13 34.48 o 7 7 3 99.92 95.26 19.27 o 9 7 3 0.53 21.02 34.06 o -10 8 3 0.26 1.65 29.19 o -8 8 3 117.38 109.88 18.41 o -6 8 3 68.24 62.66 10.04 o -4 8 3 29.51 47.54 13.18 o -2 8 3 322.34 294.46 16.68 o 0 8 3 1414.56 1373.35 81.25 o 2 8 3 141.64 157.41 13.60 o 4 8 3 16.83 16.84 9.39 o 6 8 3 8.21 11.91 10.85 o 8 8 3 13.79 16.07 14.82 o -9 9 3 2.56 10.38 15.96 o -7 9 3 2.22 2.78 15.18 o -5 9 3 108.34 96.75 13.29 o -3 9 3 174.66 155.18 15.08 o -1 9 3 210.15 202.62 21.23 o 1 9 3 1.07 20.93 14.36 o 3 9 3 286.38 265.18 24.00 o 5 9 3 36.51 33.61 11.05 o 7 9 3 12.01 34.45 12.81 o -8 10 3 0.04 1.85 15.07 o -6 10 3 18.24 13.88 12.10 o -4 10 3 50.94 42.05 12.30 o -2 10 3 16.40 -5.50 17.84 o 0 10 3 21.85 10.42 15.75 o 2 10 3 11.23 -9.49 20.85 o 4 10 3 0.49 -14.08 14.08 o 6 10 3 20.05 40.55 16.22 o -7 11 3 1.08 -14.25 14.73 o -5 11 3 1.34 -0.41 12.16 o 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