#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/29/2212933.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2212933_Fobs loop_ _publ_author_name 'Peng, Shao-Wei' 'Miao, Yan-Li' 'Song, Wen-Dong' _publ_section_title ; Tetraamminebis(pyrazine-2-carboxylato-\kN^4^)copper(II) ; _journal_coeditor_code HY2048 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m1145 _journal_page_last m1146 _journal_volume 63 _journal_year 2007 _space_group_IT_number 64 _symmetry_space_group_name_Hall '-C 2ac 2' _symmetry_space_group_name_H-M 'C m c a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 7.1242 _cell_length_b 12.9594 _cell_length_c 16.3909 _exptl_crystal_F_000 780.00 _reflns_d_resolution_high 0.8335 _[local]_cod_data_source_file hy2048Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' S in Cmca' _shelx_refln_list_code 4 _shelx_f_calc_maximum 369.85 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y+1/2, z+1/2' '-x, y+1/2, -z+1/2' 'x, -y, -z' 'x+1/2, y+1/2, z' '-x+1/2, -y+1, z+1/2' '-x+1/2, y+1, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x, y-1/2, -z-1/2' 'x, -y-1/2, z-1/2' '-x, y, z' '-x+1/2, -y+1/2, -z' 'x+1/2, y, -z-1/2' 'x+1/2, -y, z-1/2' '-x+1/2, y+1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 136791.05 105832.91 3234.16 o 4 0 0 72646.27 67918.37 629.82 o 6 0 0 18319.60 17792.38 195.66 o 8 0 0 3514.97 3239.90 147.37 o 0 2 0 1117.30 1065.30 17.55 o 2 2 0 942.46 1056.63 11.03 o 4 2 0 1033.85 870.48 9.85 o 6 2 0 503.85 512.57 10.55 o 8 2 0 106.82 166.68 11.11 o 0 4 0 1390.54 1630.42 23.90 o 2 4 0 19027.96 19235.18 138.59 o 4 4 0 3204.53 3034.04 24.95 o 6 4 0 1098.94 1114.52 18.72 o 8 4 0 655.18 723.78 17.95 o 0 6 0 278.00 254.39 11.23 o 2 6 0 11284.57 11324.05 84.94 o 4 6 0 1599.29 1531.42 23.15 o 6 6 0 980.00 995.56 18.56 o 0 8 0 5597.72 5727.52 96.87 o 2 8 0 4973.75 5075.41 56.21 o 4 8 0 2708.57 2774.30 35.95 o 6 8 0 1417.90 1408.05 28.58 o 0 10 0 7705.45 7473.50 99.84 o 2 10 0 1626.33 1545.20 25.46 o 4 10 0 2328.71 2257.39 41.39 o 6 10 0 931.64 882.63 25.95 o 0 12 0 413.59 459.28 34.23 o 2 12 0 29.49 25.01 7.62 o 4 12 0 161.83 219.11 19.58 o 0 14 0 460.62 445.18 37.70 o 2 14 0 726.69 733.34 26.97 o 1 1 1 6964.35 6839.60 39.41 o 3 1 1 204.80 175.58 2.75 o 5 1 1 4264.44 4171.28 22.23 o 7 1 1 300.96 344.50 7.64 o 0 2 1 13316.42 14050.89 116.87 o 2 2 1 17804.30 18796.23 88.89 o 4 2 1 3224.62 3576.10 18.32 o 6 2 1 901.32 915.57 10.30 o 8 2 1 419.78 412.27 10.77 o 1 3 1 10911.87 10920.14 61.82 o 3 3 1 9381.26 9312.92 43.90 o 5 3 1 2612.71 2560.27 17.20 o 7 3 1 1321.51 1304.46 15.55 o 0 4 1 197.26 202.23 4.42 o 2 4 1 1475.92 1496.97 11.10 o 4 4 1 73.82 66.86 2.64 o 6 4 1 12.56 7.94 2.80 o 8 4 1 4.85 12.04 3.94 o 1 5 1 236.07 176.21 3.25 o 3 5 1 4818.56 4616.91 27.61 o 5 5 1 109.86 114.96 4.68 o 7 5 1 1240.45 1259.92 16.10 o 0 6 1 517.79 579.08 10.77 o 2 6 1 672.29 773.40 7.79 o 4 6 1 283.56 316.22 7.27 o 6 6 1 109.27 107.95 5.61 o 1 7 1 5192.45 4983.03 31.01 o 3 7 1 5542.90 5267.67 38.26 o 5 7 1 817.14 803.47 12.27 o 7 7 1 883.02 903.30 15.96 o 0 8 1 1568.77 1737.73 21.17 o 2 8 1 343.23 360.38 7.40 o 4 8 1 389.73 382.98 8.75 o 6 8 1 151.72 148.83 7.36 o 1 9 1 6469.20 6612.50 44.14 o 3 9 1 2725.67 2785.80 25.90 o 5 9 1 2722.94 2689.47 27.79 o 0 10 1 70.51 95.07 7.75 o 2 10 1 1.83 3.25 3.17 o 4 10 1 12.19 15.07 3.96 o 6 10 1 2.04 2.31 4.33 o 1 11 1 2661.93 2613.25 28.94 o 3 11 1 599.58 584.24 12.41 o 5 11 1 1765.83 1677.45 24.25 o 0 12 1 248.76 227.96 18.74 o 2 12 1 348.53 315.69 10.05 o 4 12 1 114.23 113.53 7.35 o 1 13 1 2659.41 2627.20 40.81 o 3 13 1 1469.59 1480.15 23.26 o 0 14 1 16.38 22.49 11.70 o 2 14 1 9.57 14.65 6.30 o 1 15 1 220.63 199.88 15.31 o 0 0 2 7988.04 7487.40 414.20 o 2 0 2 6404.50 6993.07 49.87 o 4 0 2 1068.93 883.84 9.85 o 6 0 2 394.72 432.75 10.87 o 8 0 2 9.67 24.25 7.15 o 1 1 2 33.32 88.61 1.76 o 3 1 2 326.63 299.84 3.57 o 5 1 2 81.77 101.43 3.16 o 7 1 2 10.95 13.38 2.95 o 0 2 2 36296.37 33420.99 720.85 o 2 2 2 10278.83 10714.93 53.59 o 4 2 2 8686.34 8731.58 41.03 o 6 2 2 3077.88 3119.28 22.84 o 8 2 2 856.72 836.80 16.38 o 1 3 2 1367.40 1298.89 9.78 o 3 3 2 94.49 89.90 2.37 o 5 3 2 526.42 542.73 7.07 o 7 3 2 0.44 4.56 3.18 o 0 4 2 2397.09 2467.58 23.99 o 2 4 2 16477.25 16554.92 94.30 o 4 4 2 3508.70 3467.55 22.03 o 6 4 2 1612.55 1618.90 16.43 o 8 4 2 965.39 981.70 17.86 o 1 5 2 41.47 41.99 1.74 o 3 5 2 6.93 5.71 1.98 o 5 5 2 0.81 1.94 2.37 o 7 5 2 29.77 34.07 4.79 o 0 6 2 3089.83 2984.23 25.92 o 2 6 2 14696.78 14371.13 87.60 o 4 6 2 2895.70 2826.95 25.55 o 6 6 2 1293.67 1307.37 16.63 o 1 7 2 2969.29 3424.13 21.75 o 3 7 2 2921.57 2991.35 25.96 o 5 7 2 182.51 178.31 6.70 o 7 7 2 229.91 247.18 10.51 o 0 8 2 2184.87 1935.66 21.12 o 2 8 2 1998.41 1806.92 17.60 o 4 8 2 1298.42 1279.53 16.22 o 6 8 2 741.46 748.29 15.58 o 1 9 2 107.70 124.21 4.43 o 3 9 2 430.46 445.62 9.63 o 5 9 2 2.16 7.99 4.70 o 0 10 2 5103.03 4901.90 74.86 o 2 10 2 1011.35 990.89 14.93 o 4 10 2 1677.75 1655.82 21.40 o 6 10 2 755.70 742.78 21.80 o 1 11 2 11.95 11.16 4.11 o 3 11 2 26.54 31.82 4.58 o 5 11 2 15.07 15.92 4.97 o 0 12 2 1375.54 1357.41 42.91 o 2 12 2 199.49 213.39 8.08 o 4 12 2 481.04 475.64 12.41 o 1 13 2 13.38 11.85 6.21 o 3 13 2 24.26 21.82 4.84 o 0 14 2 779.94 766.07 84.56 o 2 14 2 1037.49 1010.95 25.25 o 1 15 2 33.49 10.00 8.16 o 1 1 3 17895.78 17690.40 108.85 o 3 1 3 4633.33 4548.99 25.40 o 5 1 3 5704.50 5563.78 29.35 o 7 1 3 866.24 886.47 12.74 o 0 2 3 181.34 137.95 5.35 o 2 2 3 10266.44 10926.76 57.43 o 4 2 3 349.82 357.88 5.08 o 6 2 3 46.25 51.80 3.79 o 8 2 3 114.91 148.07 12.08 o 1 3 3 9852.98 10553.55 63.11 o 3 3 3 7247.88 7226.56 37.75 o 5 3 3 2387.48 2402.86 17.85 o 7 3 3 953.19 999.49 16.65 o 0 4 3 9260.81 9774.01 83.45 o 2 4 3 39.18 47.25 2.56 o 4 4 3 733.96 750.66 9.09 o 6 4 3 85.06 85.12 5.39 o 8 4 3 7.26 10.84 4.51 o 1 5 3 10996.76 11215.52 60.65 o 3 5 3 11881.81 11784.74 73.69 o 5 5 3 1880.08 1929.00 19.02 o 7 5 3 1795.19 1792.03 23.77 o 0 6 3 8196.24 8924.74 71.51 o 2 6 3 3080.99 3249.80 24.53 o 4 6 3 1286.12 1319.15 17.04 o 6 6 3 378.23 379.62 10.85 o 1 7 3 6374.99 6536.28 37.83 o 3 7 3 6136.45 6185.14 45.68 o 5 7 3 1695.31 1685.33 20.46 o 7 7 3 1297.37 1267.58 21.52 o 0 8 3 77.84 65.48 3.71 o 2 8 3 1071.06 1108.66 12.43 o 4 8 3 15.70 16.42 4.25 o 6 8 3 7.43 -4.06 3.67 o 1 9 3 739.09 686.14 9.46 o 3 9 3 250.63 258.78 7.73 o 5 9 3 526.95 529.07 12.82 o 0 10 3 4210.04 4174.98 43.65 o 2 10 3 1838.84 1735.47 19.81 o 4 10 3 1567.14 1506.41 20.16 o 6 10 3 645.08 612.28 15.16 o 1 11 3 1858.47 1801.64 22.74 o 3 11 3 582.27 576.51 11.87 o 5 11 3 1163.63 1131.48 19.89 o 0 12 3 237.14 232.80 14.46 o 2 12 3 1.15 5.90 4.43 o 4 12 3 67.14 83.65 6.97 o 1 13 3 597.65 638.61 18.82 o 3 13 3 357.70 367.07 16.12 o 0 14 3 653.23 596.57 31.38 o 2 14 3 36.80 31.38 8.00 o 1 15 3 705.68 705.11 24.94 o 0 0 4 3218.67 3101.26 43.34 o 2 0 4 71.51 100.42 3.15 o 4 0 4 1394.70 1294.93 14.74 o 6 0 4 643.52 636.23 12.83 o 8 0 4 175.27 219.67 15.35 o 1 1 4 5952.99 6390.66 35.96 o 3 1 4 109.20 113.69 2.86 o 5 1 4 767.90 779.24 8.62 o 7 1 4 3.84 11.70 3.74 o 0 2 4 5989.63 5698.95 60.67 o 2 2 4 2560.15 2437.42 15.67 o 4 2 4 2390.61 2274.05 16.41 o 6 2 4 1112.47 1122.24 13.05 o 8 2 4 363.15 393.04 14.39 o 1 3 4 916.46 974.05 8.92 o 3 3 4 808.87 807.86 7.34 o 5 3 4 707.77 685.87 8.70 o 7 3 4 65.13 77.64 6.19 o 0 4 4 5846.06 5855.68 59.81 o 2 4 4 11550.04 11519.44 71.16 o 4 4 4 3516.78 3441.05 23.75 o 6 4 4 1760.19 1707.90 20.40 o 8 4 4 781.82 767.12 17.00 o 1 5 4 11.63 22.90 1.79 o 3 5 4 0.11 4.67 2.15 o 5 5 4 48.00 63.05 5.16 o 7 5 4 0.03 7.09 4.11 o 0 6 4 1371.54 1449.77 16.46 o 2 6 4 4694.64 4594.22 29.06 o 4 6 4 1521.42 1494.62 16.67 o 6 6 4 872.21 841.26 14.74 o 1 7 4 33.93 44.26 2.45 o 3 7 4 348.86 322.60 6.79 o 5 7 4 298.94 310.55 10.78 o 7 7 4 9.76 19.05 5.32 o 0 8 4 2097.25 2191.36 22.09 o 2 8 4 1476.83 1424.09 14.80 o 4 8 4 954.21 953.85 15.72 o 6 8 4 366.78 360.19 11.47 o 1 9 4 1654.12 1655.37 16.22 o 3 9 4 141.86 161.77 6.59 o 5 9 4 806.78 758.14 15.38 o 0 10 4 4244.24 4400.07 45.84 o 2 10 4 1662.99 1685.01 22.60 o 4 10 4 1692.66 1621.37 22.53 o 6 10 4 729.71 706.89 16.23 o 1 11 4 939.57 933.18 15.60 o 3 11 4 483.95 498.19 11.73 o 5 11 4 256.11 287.24 10.99 o 0 12 4 7384.10 7131.72 103.17 o 2 12 4 4764.80 4536.41 45.38 o 4 12 4 3465.62 3357.19 37.32 o 1 13 4 148.47 142.97 10.60 o 3 13 4 516.91 470.54 14.21 o 0 14 4 485.99 504.48 34.23 o 2 14 4 592.70 645.70 26.97 o 1 15 4 0.60 8.24 8.37 o 1 1 5 20006.33 20225.65 101.68 o 3 1 5 10475.88 10428.73 54.72 o 5 1 5 4615.29 4532.50 30.14 o 7 1 5 1219.73 1226.29 17.63 o 0 2 5 10257.02 10870.38 95.03 o 2 2 5 935.83 973.77 8.25 o 4 2 5 499.07 549.49 6.82 o 6 2 5 151.70 158.51 5.29 o 8 2 5 11.03 15.55 4.69 o 1 3 5 15799.52 16281.15 92.17 o 3 3 5 8442.47 8400.93 46.55 o 5 3 5 3826.99 3798.49 28.19 o 7 3 5 1466.95 1480.25 19.92 o 0 4 5 4813.42 5157.89 47.55 o 2 4 5 233.89 217.02 4.65 o 4 4 5 302.76 313.66 6.14 o 6 4 5 30.80 34.23 4.11 o 1 5 5 3791.03 3782.95 26.43 o 3 5 5 2801.41 2590.99 21.04 o 5 5 5 902.37 903.54 13.42 o 7 5 5 441.25 458.12 12.01 o 0 6 5 1501.93 1545.21 17.73 o 2 6 5 99.81 100.49 3.45 o 4 6 5 190.01 220.68 7.07 o 6 6 5 89.33 91.79 6.38 o 1 7 5 2664.18 2623.72 18.28 o 3 7 5 2423.34 2486.97 21.89 o 5 7 5 1109.23 1084.42 17.65 o 7 7 5 592.82 590.50 14.87 o 0 8 5 1089.92 1090.61 13.98 o 2 8 5 431.00 458.14 8.11 o 4 8 5 103.15 113.79 6.50 o 6 8 5 54.05 51.14 6.35 o 1 9 5 3023.23 2938.42 25.64 o 3 9 5 2054.62 2065.34 24.35 o 5 9 5 1323.44 1273.74 20.43 o 0 10 5 968.70 950.07 18.41 o 2 10 5 2091.05 2104.90 22.82 o 4 10 5 618.87 606.62 13.55 o 6 10 5 293.39 339.67 12.18 o 1 11 5 1035.13 1072.81 17.03 o 3 11 5 610.74 627.94 13.39 o 5 11 5 467.59 474.24 14.74 o 0 12 5 184.68 163.79 13.06 o 2 12 5 905.19 877.55 17.87 o 4 12 5 203.77 202.97 13.28 o 1 13 5 402.44 417.95 14.14 o 3 13 5 335.32 335.57 16.92 o 0 14 5 63.46 70.39 17.45 o 2 14 5 217.44 203.08 12.91 o 0 0 6 101.51 76.73 3.83 o 2 0 6 1440.99 1370.54 14.03 o 4 0 6 1087.89 1102.43 15.74 o 6 0 6 555.60 592.45 16.19 o 8 0 6 359.67 398.64 19.62 o 1 1 6 2333.09 2557.73 16.12 o 3 1 6 23.95 33.00 1.95 o 5 1 6 736.12 740.71 11.03 o 7 1 6 1.64 9.63 3.45 o 0 2 6 11503.32 11642.88 99.29 o 2 2 6 10981.93 10898.71 61.82 o 4 2 6 4511.49 4419.08 29.76 o 6 2 6 1759.08 1745.05 19.28 o 8 2 6 628.38 633.97 14.98 o 1 3 6 3256.83 3425.17 23.26 o 3 3 6 6648.06 6669.06 39.16 o 5 3 6 43.59 65.13 4.91 o 7 3 6 734.46 720.97 13.30 o 0 4 6 1503.13 1375.69 17.35 o 2 4 6 1328.24 1206.96 10.59 o 4 4 6 932.41 917.15 12.12 o 6 4 6 752.95 776.65 12.62 o 1 5 6 510.09 593.00 7.59 o 3 5 6 500.28 491.54 9.47 o 5 5 6 24.10 38.93 4.02 o 7 5 6 48.56 59.70 6.37 o 0 6 6 5584.81 5886.03 55.76 o 2 6 6 3630.50 3609.77 28.80 o 4 6 6 2371.31 2389.33 24.36 o 6 6 6 1090.48 1079.28 17.63 o 1 7 6 919.73 809.35 9.00 o 3 7 6 4.54 12.66 3.04 o 5 7 6 462.71 441.25 11.51 o 7 7 6 24.82 27.87 6.15 o 0 8 6 5630.82 5789.60 48.52 o 2 8 6 3768.15 3661.42 29.08 o 4 8 6 2445.32 2360.03 26.63 o 6 8 6 953.09 892.32 23.58 o 1 9 6 302.44 321.14 7.11 o 3 9 6 32.04 29.63 4.52 o 5 9 6 328.62 328.30 10.77 o 0 10 6 1745.69 1769.87 32.09 o 2 10 6 1516.85 1490.04 20.24 o 4 10 6 1048.00 1038.43 17.99 o 6 10 6 495.60 509.14 14.42 o 1 11 6 420.77 447.20 14.19 o 3 11 6 387.40 395.07 12.14 o 5 11 6 148.96 134.11 8.89 o 0 12 6 585.00 597.94 21.59 o 2 12 6 649.39 702.28 16.19 o 4 12 6 340.38 334.91 11.37 o 1 13 6 0.41 9.84 5.93 o 3 13 6 146.79 156.91 9.88 o 0 14 6 955.60 917.11 38.32 o 2 14 6 898.54 871.59 23.90 o 1 1 7 4645.52 4605.65 27.82 o 3 1 7 5643.26 5506.54 33.62 o 5 1 7 1235.73 1210.09 14.01 o 7 1 7 888.93 908.70 15.17 o 0 2 7 10183.56 11067.96 80.43 o 2 2 7 113.38 142.98 3.75 o 4 2 7 1206.79 1227.20 11.96 o 6 2 7 308.67 302.47 7.73 o 1 3 7 92.90 54.94 2.96 o 3 3 7 88.33 57.13 3.10 o 5 3 7 359.49 392.90 8.90 o 7 3 7 177.64 212.78 8.38 o 0 4 7 921.63 980.71 14.43 o 2 4 7 531.79 510.94 7.39 o 4 4 7 16.60 19.16 3.25 o 6 4 7 0.03 2.42 3.26 o 1 5 7 12773.15 13055.47 80.22 o 3 5 7 5256.90 5356.31 43.62 o 5 5 7 4116.52 4150.28 34.30 o 7 5 7 1003.36 960.64 18.61 o 0 6 7 53.10 70.97 4.84 o 2 6 7 613.81 672.01 11.25 o 4 6 7 33.04 32.05 3.70 o 6 6 7 3.46 4.12 4.35 o 1 7 7 2266.78 2173.55 18.92 o 3 7 7 1321.34 1329.50 15.63 o 5 7 7 1203.97 1174.38 18.93 o 7 7 7 349.60 361.29 13.36 o 0 8 7 581.18 595.20 11.50 o 2 8 7 435.82 411.88 9.06 o 4 8 7 36.90 52.63 5.44 o 6 8 7 11.52 12.05 5.08 o 1 9 7 1505.93 1433.41 16.42 o 3 9 7 1320.80 1348.98 19.31 o 5 9 7 422.76 388.10 11.77 o 0 10 7 4.61 6.29 5.32 o 2 10 7 246.31 251.64 8.41 o 4 10 7 17.17 17.41 4.26 o 1 11 7 1604.50 1658.78 21.26 o 3 11 7 1677.48 1700.89 23.39 o 5 11 7 495.55 489.37 14.61 o 0 12 7 113.26 123.76 12.14 o 2 12 7 53.72 57.83 7.71 o 4 12 7 3.73 12.71 4.48 o 1 13 7 292.65 313.19 14.35 o 3 13 7 346.67 356.70 13.28 o 0 14 7 15.12 18.12 11.41 o 2 14 7 484.41 509.30 24.45 o 0 0 8 8383.24 8344.95 83.96 o 2 0 8 18655.11 18204.82 138.67 o 4 0 8 6037.61 5952.99 55.82 o 6 0 8 2388.59 2268.65 51.41 o 1 1 8 2836.64 3038.88 19.80 o 3 1 8 2593.75 2626.23 19.89 o 5 1 8 210.15 206.13 6.53 o 7 1 8 314.02 292.12 9.95 o 0 2 8 8296.99 8528.24 64.00 o 2 2 8 10407.20 10192.51 57.33 o 4 2 8 3512.84 3348.14 25.63 o 6 2 8 1266.68 1250.43 16.92 o 1 3 8 1005.24 1206.13 11.18 o 3 3 8 7.18 5.85 2.18 o 5 3 8 584.63 573.93 10.50 o 7 3 8 10.10 12.62 3.78 o 0 4 8 5985.19 6086.61 54.44 o 2 4 8 1975.28 1967.66 17.23 o 4 4 8 1767.45 1738.18 18.65 o 6 4 8 888.16 929.36 15.22 o 1 5 8 2.84 1.20 1.93 o 3 5 8 56.07 52.94 4.18 o 5 5 8 5.00 18.76 3.84 o 7 5 8 1.59 6.69 5.02 o 0 6 8 3384.71 3214.36 37.41 o 2 6 8 474.54 423.09 11.10 o 4 6 8 1099.39 1088.53 16.14 o 6 6 8 566.70 572.04 14.21 o 1 7 8 729.08 754.36 11.29 o 3 7 8 47.23 62.88 4.90 o 5 7 8 490.13 485.26 12.88 o 0 8 8 8547.10 8705.67 116.34 o 2 8 8 5982.92 5907.90 45.32 o 4 8 8 3839.65 3832.50 38.85 o 6 8 8 1602.34 1526.12 27.90 o 1 9 8 688.63 670.71 11.81 o 3 9 8 76.31 87.98 6.29 o 5 9 8 469.41 453.81 16.71 o 0 10 8 10.74 17.81 6.67 o 2 10 8 261.06 282.48 8.57 o 4 10 8 69.35 73.32 6.55 o 1 11 8 15.38 16.72 4.57 o 3 11 8 19.68 16.04 4.40 o 0 12 8 149.45 141.22 13.01 o 2 12 8 597.15 633.56 15.98 o 4 12 8 163.63 168.30 11.35 o 1 13 8 7.96 9.09 5.92 o 3 13 8 60.77 91.53 12.01 o 0 14 8 256.27 315.65 36.58 o 1 1 9 1457.72 1525.56 12.40 o 3 1 9 3441.55 3436.74 24.98 o 5 1 9 246.88 262.83 7.53 o 7 1 9 618.71 674.49 14.53 o 0 2 9 297.97 344.01 7.10 o 2 2 9 1818.50 2018.27 15.88 o 4 2 9 228.94 234.59 6.49 o 6 2 9 157.47 167.05 7.12 o 1 3 9 1690.14 1800.33 14.34 o 3 3 9 1032.65 1009.34 12.09 o 5 3 9 1123.91 1138.44 15.45 o 7 3 9 478.98 455.15 11.73 o 0 4 9 30.89 26.63 3.21 o 2 4 9 558.06 510.41 8.09 o 4 4 9 33.17 31.63 4.39 o 6 4 9 7.68 9.58 3.48 o 1 5 9 4778.34 4688.31 33.59 o 3 5 9 1052.47 1015.52 14.11 o 5 5 9 2270.11 2257.85 33.18 o 7 5 9 219.77 234.29 10.28 o 0 6 9 67.22 74.26 5.71 o 2 6 9 339.47 360.77 8.71 o 4 6 9 24.95 28.37 4.19 o 6 6 9 17.29 24.89 5.70 o 1 7 9 80.70 101.58 5.14 o 3 7 9 14.92 13.76 3.75 o 5 7 9 178.47 175.26 9.24 o 0 8 9 601.78 632.23 17.22 o 2 8 9 4.36 5.95 3.00 o 4 8 9 85.77 83.47 6.68 o 6 8 9 13.44 11.08 5.98 o 1 9 9 5074.31 4897.42 43.77 o 3 9 9 4510.63 4309.60 38.78 o 5 9 9 1588.04 1473.48 23.31 o 0 10 9 1513.03 1536.36 38.19 o 2 10 9 851.75 874.82 14.82 o 4 10 9 673.70 643.15 18.70 o 1 11 9 1054.47 1048.66 21.67 o 3 11 9 1586.21 1569.35 23.00 o 0 12 9 5.06 10.21 7.31 o 2 12 9 78.69 113.94 12.47 o 1 13 9 1124.26 1227.04 31.46 o 0 0 10 754.25 730.64 15.16 o 2 0 10 6117.09 5949.77 55.49 o 4 0 10 1313.75 1321.58 20.16 o 6 0 10 586.21 615.39 18.25 o 1 1 10 1.64 4.87 1.73 o 3 1 10 0.32 -0.01 2.32 o 5 1 10 50.87 58.04 4.54 o 7 1 10 6.27 10.20 4.21 o 0 2 10 2669.88 2642.21 25.11 o 2 2 10 4645.96 4565.83 31.10 o 4 2 10 1690.57 1688.32 18.98 o 6 2 10 734.51 790.98 15.66 o 1 3 10 3.26 3.10 1.92 o 3 3 10 29.60 37.40 3.52 o 5 3 10 15.48 23.54 3.99 o 7 3 10 17.38 22.75 5.08 o 0 4 10 6858.51 6755.44 59.78 o 2 4 10 2000.24 1946.10 18.10 o 4 4 10 2182.46 2123.09 23.34 o 6 4 10 987.17 985.50 15.76 o 1 5 10 0.14 -1.35 2.44 o 3 5 10 29.16 39.09 4.55 o 5 5 10 22.47 22.80 4.72 o 0 6 10 6390.42 6376.98 69.62 o 2 6 10 1218.78 1216.12 16.49 o 4 6 10 2038.04 2009.84 24.37 o 6 6 10 965.03 926.84 19.55 o 1 7 10 80.33 63.00 5.02 o 3 7 10 143.72 131.56 6.64 o 5 7 10 9.07 14.42 5.28 o 0 8 10 208.53 215.26 13.46 o 2 8 10 101.20 100.44 6.10 o 4 8 10 129.34 143.44 7.46 o 1 9 10 694.97 690.73 14.11 o 3 9 10 590.19 607.82 12.55 o 5 9 10 121.72 115.80 9.02 o 0 10 10 464.73 557.91 22.30 o 2 10 10 1833.95 1850.17 24.01 o 4 10 10 535.74 551.14 13.96 o 1 11 10 352.06 379.62 19.92 o 3 11 10 297.07 274.11 11.91 o 0 12 10 269.34 332.02 19.00 o 2 12 10 1057.30 1183.48 31.00 o 1 13 10 35.09 37.41 11.64 o 1 1 11 822.55 756.67 9.19 o 3 1 11 2335.95 2206.19 19.60 o 5 1 11 151.21 159.66 8.02 o 7 1 11 638.25 672.06 20.74 o 0 2 11 303.08 260.26 8.59 o 2 2 11 197.56 196.05 5.40 o 4 2 11 108.47 109.67 5.54 o 6 2 11 116.75 134.57 7.53 o 1 3 11 4990.77 5031.57 34.68 o 3 3 11 2712.26 2645.67 23.49 o 5 3 11 1490.41 1485.91 19.36 o 0 4 11 1020.92 1021.88 18.29 o 2 4 11 608.93 623.79 10.25 o 4 4 11 225.12 236.11 8.05 o 6 4 11 55.83 55.58 5.84 o 1 5 11 1789.91 1728.64 18.12 o 3 5 11 231.12 218.82 8.00 o 5 5 11 1353.59 1382.24 22.61 o 0 6 11 72.30 78.07 7.24 o 2 6 11 21.79 24.00 4.19 o 4 6 11 48.06 56.89 5.89 o 6 6 11 11.56 16.81 5.96 o 1 7 11 6043.70 5877.75 54.02 o 3 7 11 2841.01 2809.40 33.48 o 5 7 11 2702.70 2611.16 32.40 o 0 8 11 601.66 576.21 17.74 o 2 8 11 373.07 377.75 10.04 o 4 8 11 256.65 237.96 10.40 o 1 9 11 55.02 56.43 11.64 o 3 9 11 15.75 40.54 5.08 o 5 9 11 35.84 41.51 7.14 o 0 10 11 211.69 220.11 18.54 o 2 10 11 216.92 238.74 9.90 o 4 10 11 109.86 121.39 8.92 o 1 11 11 778.32 760.94 19.33 o 3 11 11 1343.05 1242.72 25.75 o 0 12 11 10.02 19.87 8.04 o 2 12 11 0.46 17.03 6.44 o 0 0 12 456.53 472.15 19.93 o 2 0 12 313.59 302.65 9.87 o 4 0 12 29.63 32.04 5.07 o 6 0 12 13.40 11.11 5.85 o 1 1 12 745.68 708.87 10.16 o 3 1 12 265.77 254.33 6.69 o 5 1 12 206.86 235.39 7.96 o 0 2 12 464.75 486.38 14.90 o 2 2 12 1302.09 1283.92 14.06 o 4 2 12 613.28 614.11 11.23 o 6 2 12 397.40 413.39 11.07 o 1 3 12 1541.33 1514.31 17.00 o 3 3 12 1334.02 1314.32 17.57 o 5 3 12 251.18 267.51 8.97 o 0 4 12 4857.33 4779.19 49.71 o 2 4 12 1626.56 1572.94 17.47 o 4 4 12 1932.07 1900.25 21.71 o 6 4 12 905.83 906.57 19.52 o 1 5 12 18.01 12.93 3.22 o 3 5 12 4.91 3.93 3.78 o 5 5 12 10.99 12.05 4.11 o 0 6 12 2770.19 2754.45 38.67 o 2 6 12 329.57 345.39 10.24 o 4 6 12 813.82 816.64 16.17 o 1 7 12 311.29 306.50 13.60 o 3 7 12 341.10 352.14 11.03 o 5 7 12 90.20 91.60 7.68 o 0 8 12 487.12 517.56 17.47 o 2 8 12 368.94 412.99 11.74 o 4 8 12 281.63 304.80 11.04 o 1 9 12 36.41 59.14 11.28 o 3 9 12 0.36 2.05 4.41 o 0 10 12 468.02 516.39 45.36 o 2 10 12 1642.52 1639.50 24.81 o 1 11 12 16.46 39.74 7.19 o 3 11 12 14.55 20.48 6.01 o 0 12 12 282.13 372.88 48.42 o 1 1 13 3517.44 3453.69 31.00 o 3 1 13 3850.51 3754.06 29.65 o 5 1 13 750.49 735.11 13.89 o 0 2 13 986.58 979.26 19.72 o 2 2 13 2032.04 1963.96 18.71 o 4 2 13 738.54 744.73 12.81 o 6 2 13 279.54 275.25 13.93 o 1 3 13 2343.64 2263.46 23.47 o 3 3 13 1386.71 1332.86 16.52 o 5 3 13 819.78 832.67 15.76 o 0 4 13 611.34 591.95 16.14 o 2 4 13 80.30 91.29 5.85 o 4 4 13 169.23 195.58 7.66 o 6 4 13 103.78 128.36 11.21 o 1 5 13 674.65 660.40 13.14 o 3 5 13 88.46 99.85 6.28 o 5 5 13 608.38 638.96 14.91 o 0 6 13 124.61 111.40 8.72 o 2 6 13 183.47 169.40 8.61 o 4 6 13 103.71 96.06 6.87 o 1 7 13 1154.25 1157.83 19.46 o 3 7 13 443.16 447.30 13.65 o 5 7 13 596.48 614.51 18.82 o 0 8 13 25.70 30.15 8.91 o 2 8 13 278.72 300.91 19.63 o 4 8 13 53.38 63.56 7.14 o 1 9 13 1114.22 1134.59 21.30 o 3 9 13 1213.55 1249.21 21.89 o 0 10 13 99.17 132.08 15.68 o 2 10 13 5.87 5.51 5.06 o 1 11 13 15.25 46.31 8.45 o 0 0 14 3668.42 3510.95 73.48 o 2 0 14 5341.13 5171.23 53.10 o 4 0 14 2096.03 1974.39 28.75 o 6 0 14 1085.49 1044.83 30.64 o 1 1 14 323.48 319.45 9.15 o 3 1 14 448.85 466.01 12.06 o 5 1 14 32.22 33.78 5.26 o 0 2 14 124.36 121.41 9.98 o 2 2 14 332.81 342.53 9.12 o 4 2 14 163.17 182.59 7.48 o 1 3 14 2066.05 1987.13 26.21 o 3 3 14 584.70 592.97 11.93 o 5 3 14 969.13 945.59 16.46 o 0 4 14 251.57 301.22 14.56 o 2 4 14 8.46 18.20 4.26 o 4 4 14 89.29 99.81 6.59 o 1 5 14 19.16 13.39 4.30 o 3 5 14 56.59 41.84 5.61 o 5 5 14 3.83 11.95 4.78 o 0 6 14 1660.69 1667.84 32.61 o 2 6 14 468.73 483.81 12.81 o 4 6 14 697.13 707.98 15.84 o 1 7 14 76.14 75.04 7.18 o 3 7 14 216.97 221.24 10.96 o 0 8 14 802.64 844.46 28.34 o 2 8 14 723.77 721.34 17.53 o 4 8 14 475.85 486.52 17.37 o 1 9 14 227.66 266.82 11.44 o 3 9 14 429.37 418.06 20.03 o 0 10 14 591.79 662.29 51.39 o 2 10 14 1209.02 1248.50 25.64 o 1 1 15 438.20 399.83 10.43 o 3 1 15 524.59 544.37 10.80 o 5 1 15 123.48 146.69 8.63 o 0 2 15 1116.31 1080.43 25.77 o 2 2 15 88.02 90.03 6.43 o 4 2 15 283.16 302.82 9.25 o 1 3 15 1488.84 1386.65 20.41 o 3 3 15 988.63 942.47 17.55 o 5 3 15 600.64 609.32 14.14 o 0 4 15 15.27 14.87 7.09 o 2 4 15 375.24 371.61 11.31 o 4 4 15 38.24 35.05 5.65 o 1 5 15 232.20 263.78 17.03 o 3 5 15 94.60 113.12 9.26 o 0 6 15 43.57 30.03 8.99 o 2 6 15 0.19 2.77 4.48 o 4 6 15 7.56 4.97 4.74 o 1 7 15 850.58 902.44 20.60 o 3 7 15 484.29 535.84 15.86 o 0 8 15 326.06 370.55 35.01 o 2 8 15 3.79 7.67 5.45 o 1 9 15 232.98 258.84 21.18 o 0 10 15 103.17 181.97 16.48 o 0 0 16 1616.50 1456.21 44.59 o 2 0 16 1592.24 1532.05 30.33 o 4 0 16 751.11 763.26 24.39 o 1 1 16 80.53 91.82 7.24 o 3 1 16 1.16 2.93 4.43 o 0 2 16 301.04 300.74 15.02 o 2 2 16 298.00 295.18 9.90 o 4 2 16 184.59 189.49 9.04 o 1 3 16 119.51 115.21 7.92 o 3 3 16 15.28 9.74 4.87 o 0 4 16 1595.10 1473.01 32.14 o 2 4 16 1113.52 1051.69 21.54 o 4 4 16 811.77 790.63 17.47 o 1 5 16 268.17 253.32 10.92 o 3 5 16 109.24 117.95 8.45 o 0 6 16 653.66 679.34 24.74 o 2 6 16 417.23 418.39 14.83 o 1 7 16 41.13 52.23 8.34 o 3 7 16 9.82 13.42 6.20 o 0 8 16 400.91 497.74 104.03 o 2 8 16 425.03 464.55 16.08 o 1 1 17 89.18 87.37 7.48 o 3 1 17 51.72 56.97 6.91 o 0 2 17 275.48 265.40 15.00 o 2 2 17 7.70 6.32 5.03 o 4 2 17 42.65 36.24 6.01 o 1 3 17 209.94 212.22 9.88 o 3 3 17 162.92 192.83 10.60 o 0 4 17 5.14 6.01 7.64 o 2 4 17 118.23 139.38 13.06 o 1 5 17 844.56 824.44 20.64 o 3 5 17 719.42 707.13 19.74 o 0 6 17 3.94 0.51 6.91 o 2 6 17 55.89 50.41 8.89 o 1 7 17 41.25 57.50 15.91 o 0 0 18 519.72 535.01 28.52 o 2 0 18 228.02 260.04 15.94 o 1 1 18 29.57 30.27 6.19 o 3 1 18 76.25 93.15 8.75 o 0 2 18 936.86 909.99 25.95 o 2 2 18 626.89 606.57 16.54 o 1 3 18 7.15 8.02 6.17 o 3 3 18 121.66 144.36 11.24 o 0 4 18 323.57 348.13 17.78 o 2 4 18 411.52 451.68 16.57 o 1 5 18 13.46 12.41 6.54 o 0 6 18 131.77 122.77 48.88 o 1 1 19 372.44 389.70 13.20 o 0 2 19 385.08 391.05 18.64 o 1 3 19 142.48 128.64 10.03 o 0 4 19 16.09 12.18 9.68 o