#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/30/2213067.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2213067_Fobs loop_ _publ_author_name 'Jin, Hua-Shu' 'Wang, Hai-Jing' 'Zhang, Ying' 'Zuo, Ya-Jie' 'Zhong, Chong-Min' _publ_section_title ; 3,3'-Dimethyl-1,1'-ethylenediimidazolium dibromide ; _journal_coeditor_code XU2219 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1880 _journal_page_last o1881 _journal_volume 63 _journal_year 2007 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 107.676 _cell_angle_gamma 90.000 _cell_length_a 8.4978 _cell_length_b 8.9630 _cell_length_c 9.2599 _exptl_crystal_F_000 348.00 _reflns_d_resolution_high 0.7500 _[local]_cod_data_source_file xu2219Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' Mim_C2H4Br2_0m in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 175.94 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 896.47 924.57 20.58 o 2 0 0 12682.91 11710.88 291.70 o 3 0 0 3819.09 3692.61 45.71 o 4 0 0 3069.96 3052.93 50.83 o 5 0 0 2647.91 2515.41 63.05 o 6 0 0 4.52 6.61 1.76 o 7 0 0 1833.06 1839.91 28.90 o 8 0 0 59.26 63.16 3.83 o 9 0 0 711.85 729.41 12.88 o 10 0 0 41.91 42.12 4.57 o 1 1 0 1281.54 1494.56 36.87 o 2 1 0 1382.95 1464.75 12.93 o 3 1 0 4715.43 4608.44 64.49 o 4 1 0 2531.89 2475.73 23.93 o 5 1 0 2056.51 2046.67 20.00 o 6 1 0 1668.24 1696.50 16.83 o 7 1 0 124.17 139.27 2.93 o 8 1 0 419.05 435.02 5.95 o 9 1 0 24.23 29.54 5.21 o 10 1 0 105.17 115.45 3.41 o 0 2 0 18.39 45.03 2.27 o 1 2 0 77.41 91.28 3.45 o 2 2 0 2695.97 2803.50 27.02 o 3 2 0 103.56 103.35 1.79 o 4 2 0 32.03 34.62 1.06 o 5 2 0 62.90 65.07 2.00 o 6 2 0 0.58 2.72 1.30 o 7 2 0 55.85 57.41 2.20 o 8 2 0 154.02 148.92 3.28 o 9 2 0 0.74 0.12 1.90 o 10 2 0 1.92 -2.17 2.24 o 1 3 0 1580.45 1674.03 32.11 o 2 3 0 250.40 237.76 3.45 o 3 3 0 1828.18 1780.20 19.40 o 4 3 0 434.31 420.96 5.15 o 5 3 0 234.18 252.67 3.70 o 6 3 0 407.84 419.62 6.59 o 7 3 0 42.24 38.34 2.30 o 8 3 0 17.73 22.30 3.30 o 9 3 0 74.62 77.14 4.16 o 10 3 0 10.74 14.41 3.79 o 0 4 0 4790.39 5097.31 95.91 o 1 4 0 2.24 7.88 2.11 o 2 4 0 3273.94 3145.92 33.11 o 3 4 0 1573.75 1534.44 19.57 o 4 4 0 451.61 392.40 4.99 o 5 4 0 788.98 797.45 9.31 o 6 4 0 202.37 205.74 7.02 o 7 4 0 1126.48 1089.79 24.46 o 8 4 0 13.31 16.57 2.86 o 9 4 0 225.39 234.22 6.53 o 10 4 0 7.12 6.85 3.49 o 1 5 0 8659.19 8748.50 143.02 o 2 5 0 1332.00 1415.84 22.43 o 3 5 0 3543.06 3592.53 44.85 o 4 5 0 2070.83 2064.31 26.18 o 5 5 0 510.39 513.15 10.84 o 6 5 0 963.52 944.49 16.70 o 7 5 0 17.59 20.53 2.74 o 8 5 0 504.99 519.68 13.52 o 9 5 0 36.66 37.77 4.99 o 0 6 0 796.48 777.89 18.55 o 1 6 0 165.40 196.96 3.96 o 2 6 0 1334.36 1284.70 16.84 o 3 6 0 169.76 174.66 4.17 o 4 6 0 1318.33 1304.68 14.87 o 5 6 0 1271.98 1237.56 20.35 o 6 6 0 262.13 247.07 7.14 o 7 6 0 305.82 330.37 7.62 o 8 6 0 0.00 1.73 3.28 o 9 6 0 134.88 156.86 6.17 o 1 7 0 301.39 323.49 7.09 o 2 7 0 0.66 24.75 11.49 o 3 7 0 12.21 11.09 2.53 o 4 7 0 11.60 10.75 1.81 o 5 7 0 47.25 47.28 2.68 o 6 7 0 0.13 3.10 2.66 o 7 7 0 31.91 27.86 3.45 o 8 7 0 1.01 -0.46 3.50 o 0 8 0 1503.32 1487.28 34.03 o 1 8 0 20.25 20.29 4.92 o 2 8 0 845.16 851.74 14.97 o 3 8 0 15.03 24.90 7.64 o 4 8 0 192.50 199.32 6.10 o 5 8 0 265.19 264.61 6.99 o 6 8 0 0.52 0.37 3.21 o 7 8 0 122.27 116.18 5.31 o 8 8 0 3.45 0.09 3.39 o 1 9 0 892.00 913.17 16.14 o 2 9 0 364.48 370.43 10.53 o 3 9 0 323.54 305.09 9.59 o 4 9 0 393.11 382.97 8.87 o 5 9 0 162.91 141.74 5.73 o 6 9 0 241.32 243.83 7.24 o 7 9 0 20.78 24.92 6.06 o 0 10 0 776.68 795.57 21.02 o 1 10 0 15.24 29.36 4.23 o 2 10 0 843.13 842.46 15.61 o 3 10 0 175.21 194.44 7.06 o 4 10 0 257.94 251.75 7.64 o 5 10 0 234.07 241.68 7.74 o 1 11 0 200.55 206.76 7.54 o 2 11 0 13.06 10.23 4.66 o 3 11 0 135.50 135.40 6.65 o 4 11 0 89.43 86.34 5.45 o -11 1 1 40.22 46.72 4.73 o -10 1 1 12.23 9.81 2.15 o -9 1 1 179.42 180.60 3.64 o -8 1 1 140.27 138.39 2.98 o -7 1 1 870.56 839.24 9.86 o -6 1 1 622.40 634.78 7.55 o -5 1 1 426.76 401.60 4.44 o -4 1 1 1341.58 1327.25 11.03 o -3 1 1 1050.06 1084.25 12.29 o -2 1 1 6088.91 6133.57 85.75 o -1 1 1 149.44 166.40 2.77 o 0 1 1 224.76 304.39 5.84 o 1 1 1 934.97 938.19 9.18 o 2 1 1 3412.07 3395.67 46.59 o 3 1 1 1478.48 1545.82 13.78 o 4 1 1 697.90 704.41 7.22 o 5 1 1 1425.27 1342.06 12.26 o 6 1 1 58.10 65.18 2.01 o 7 1 1 383.47 405.85 5.56 o 8 1 1 11.09 9.43 1.76 o 9 1 1 12.49 15.13 2.19 o 10 1 1 17.64 19.69 3.32 o -10 2 1 239.08 243.54 4.66 o -9 2 1 18.94 27.44 2.12 o -8 2 1 653.03 650.15 8.11 o -7 2 1 484.92 489.19 6.31 o -6 2 1 2376.42 2304.54 25.20 o -5 2 1 708.58 626.88 6.47 o -4 2 1 2242.20 2356.34 33.22 o -3 2 1 7412.65 7270.91 70.10 o -2 2 1 1023.37 1023.62 11.26 o -1 2 1 13403.83 12891.40 216.29 o 0 2 1 6424.03 6811.05 84.57 o 1 2 1 17957.19 17422.97 865.88 o 2 2 1 3098.35 3332.81 73.06 o 3 2 1 2088.70 2128.69 23.13 o 4 2 1 2751.04 2583.84 28.08 o 5 2 1 311.39 289.53 3.60 o 6 2 1 1127.03 1106.12 11.31 o 7 2 1 29.02 27.57 1.72 o 8 2 1 1026.55 1049.18 12.39 o 9 2 1 60.74 57.02 3.18 o 10 2 1 139.94 159.69 5.81 o -10 3 1 12.63 8.92 3.25 o -9 3 1 516.00 535.71 8.75 o -8 3 1 97.72 101.45 3.55 o -7 3 1 564.88 576.16 8.49 o -6 3 1 691.80 717.00 11.90 o -5 3 1 1334.35 1302.59 14.57 o -4 3 1 5829.56 5906.82 56.75 o -3 3 1 134.70 135.48 4.04 o -2 3 1 7246.44 6694.60 106.77 o -1 3 1 49.00 61.72 2.77 o 0 3 1 11436.78 11815.13 180.09 o 1 3 1 2784.85 2849.12 35.35 o 2 3 1 3057.11 2986.26 38.08 o 3 3 1 3407.58 3555.56 38.36 o 4 3 1 1247.27 1272.27 14.19 o 5 3 1 3392.33 3307.49 35.93 o 6 3 1 46.81 44.82 1.84 o 7 3 1 1081.18 1132.46 18.46 o 8 3 1 16.50 15.11 4.67 o 9 3 1 217.97 232.33 6.24 o 10 3 1 69.67 72.54 4.18 o -10 4 1 19.17 26.09 3.74 o -9 4 1 4.25 -0.78 3.65 o -8 4 1 275.13 278.39 6.93 o -7 4 1 1.38 2.06 2.28 o -6 4 1 389.33 427.95 6.61 o -5 4 1 782.60 764.48 10.15 o -4 4 1 374.62 353.10 4.46 o -3 4 1 978.05 1011.12 17.77 o -2 4 1 11.28 11.62 1.27 o -1 4 1 1697.73 1656.52 39.99 o 0 4 1 150.17 180.92 3.65 o 1 4 1 846.37 904.74 14.54 o 2 4 1 650.43 640.75 8.72 o 3 4 1 1095.70 1170.50 14.45 o 4 4 1 612.55 617.09 8.55 o 5 4 1 33.14 34.72 2.58 o 6 4 1 612.84 588.94 15.65 o 7 4 1 13.98 6.80 4.26 o 8 4 1 12.90 17.17 2.92 o 9 4 1 15.58 18.62 3.26 o -10 5 1 3.33 1.13 3.78 o -9 5 1 37.41 35.47 3.58 o -8 5 1 6.45 6.90 2.88 o -7 5 1 4.60 7.81 2.38 o -6 5 1 26.27 21.42 2.66 o -5 5 1 87.80 75.80 6.36 o -4 5 1 672.85 693.08 9.48 o -3 5 1 118.79 125.69 3.69 o -2 5 1 251.52 242.57 5.69 o -1 5 1 85.03 114.58 3.36 o 0 5 1 103.17 101.43 3.92 o 1 5 1 13.33 21.36 1.64 o 2 5 1 17.74 24.51 1.82 o 3 5 1 243.57 244.91 3.75 o 4 5 1 136.98 124.87 4.55 o 5 5 1 463.33 449.47 6.92 o 6 5 1 10.47 17.55 6.53 o 7 5 1 29.75 30.56 2.98 o 8 5 1 4.26 6.14 2.98 o 9 5 1 2.48 1.09 3.37 o -9 6 1 5.68 6.28 3.20 o -8 6 1 219.29 220.38 6.44 o -7 6 1 67.28 67.74 3.73 o -6 6 1 547.79 492.65 9.45 o -5 6 1 319.77 299.32 6.71 o -4 6 1 459.52 458.89 9.54 o -3 6 1 768.69 747.08 11.97 o -2 6 1 19.58 37.67 5.52 o -1 6 1 1831.50 1668.16 26.22 o 0 6 1 109.68 125.56 2.91 o 1 6 1 2292.17 2427.05 30.70 o 2 6 1 470.93 432.44 6.77 o 3 6 1 807.13 770.92 10.81 o 4 6 1 286.85 288.37 4.53 o 5 6 1 172.17 160.41 5.03 o 6 6 1 408.21 413.85 9.18 o 7 6 1 6.38 5.72 2.87 o 8 6 1 154.57 155.39 5.83 o 9 6 1 8.11 10.68 3.73 o -8 7 1 0.96 4.90 3.40 o -7 7 1 520.45 504.77 10.20 o -6 7 1 183.34 177.47 5.43 o -5 7 1 654.52 639.73 9.69 o -4 7 1 989.72 947.20 16.03 o -3 7 1 996.94 982.48 23.45 o -2 7 1 3610.11 3528.17 54.06 o -1 7 1 0.05 1.01 3.50 o 0 7 1 3431.51 3401.60 52.10 o 1 7 1 574.73 609.99 11.05 o 2 7 1 1496.99 1522.13 24.36 o 3 7 1 1408.16 1423.39 18.89 o 4 7 1 145.53 156.26 3.54 o 5 7 1 716.23 697.47 10.50 o 6 7 1 21.34 27.34 4.76 o 7 7 1 379.76 399.11 7.56 o 8 7 1 6.87 6.19 3.81 o -8 8 1 256.48 266.54 7.65 o -7 8 1 74.20 76.46 4.46 o -6 8 1 202.08 202.11 6.34 o -5 8 1 757.18 726.46 13.26 o -4 8 1 88.64 95.98 4.63 o -3 8 1 1185.08 1116.27 18.76 o -2 8 1 2.15 9.53 4.14 o -1 8 1 1353.33 1377.02 22.57 o 0 8 1 31.33 34.71 3.20 o 1 8 1 817.49 824.34 14.45 o 2 8 1 396.90 407.64 8.44 o 3 8 1 939.73 901.87 15.70 o 4 8 1 933.78 923.58 12.81 o 5 8 1 66.48 64.18 3.90 o 6 8 1 512.55 521.02 9.04 o 7 8 1 0.85 9.62 3.24 o -7 9 1 33.58 30.79 4.34 o -6 9 1 7.54 5.55 3.85 o -5 9 1 122.90 133.86 10.47 o -4 9 1 64.36 66.06 5.54 o -3 9 1 16.25 18.68 3.32 o -2 9 1 155.95 147.82 5.70 o -1 9 1 19.45 24.79 3.48 o 0 9 1 429.57 415.44 10.76 o 1 9 1 171.98 166.57 6.01 o 2 9 1 152.08 154.45 5.97 o 3 9 1 59.57 63.52 4.30 o 4 9 1 10.74 6.05 3.68 o 5 9 1 58.07 68.05 5.68 o 6 9 1 9.77 4.82 3.75 o -6 10 1 59.83 63.59 5.03 o -5 10 1 47.59 51.26 4.83 o -4 10 1 34.48 33.67 4.47 o -3 10 1 59.37 65.41 4.61 o -2 10 1 9.76 12.76 3.82 o -1 10 1 176.83 179.44 6.67 o 0 10 1 39.82 38.89 5.76 o 1 10 1 129.01 134.77 6.16 o 2 10 1 54.52 58.31 4.66 o 3 10 1 121.49 120.22 5.84 o 4 10 1 88.66 95.85 5.02 o 5 10 1 10.42 9.92 7.12 o -4 11 1 173.20 172.22 7.40 o -3 11 1 45.50 49.37 4.67 o -2 11 1 347.66 358.48 9.32 o -1 11 1 0.12 -3.96 4.39 o 0 11 1 436.78 470.27 11.00 o 1 11 1 98.13 100.81 5.65 o 2 11 1 158.93 169.90 7.20 o 3 11 1 124.13 123.47 6.46 o -11 0 2 55.05 57.72 4.01 o -10 0 2 2.91 6.00 3.14 o -9 0 2 509.46 498.79 9.50 o -8 0 2 336.90 329.16 6.64 o -7 0 2 439.01 432.43 6.45 o -6 0 2 1248.38 1244.24 16.11 o -5 0 2 4767.32 4915.91 75.48 o -4 0 2 4487.88 4252.30 64.41 o -2 0 2 14206.35 13341.35 608.59 o -1 0 2 3966.72 4159.18 123.84 o 0 0 2 8623.73 9239.12 188.11 o 1 0 2 30954.58 32009.98 571.32 o 2 0 2 4492.61 4337.85 55.37 o 3 0 2 5479.44 5287.57 65.47 o 4 0 2 160.23 159.18 3.25 o 5 0 2 1858.85 1915.97 24.45 o 6 0 2 0.29 -0.03 2.24 o 7 0 2 615.22 603.11 11.84 o 8 0 2 432.08 425.62 13.47 o 9 0 2 209.29 235.45 11.44 o 10 0 2 130.42 122.32 8.73 o -11 1 2 6.51 7.24 2.46 o -10 1 2 204.73 212.15 4.20 o -9 1 2 22.27 25.71 1.93 o -8 1 2 695.72 655.82 8.06 o -7 1 2 418.25 431.90 8.31 o -6 1 2 334.77 337.33 4.10 o -5 1 2 3091.42 3094.82 27.37 o -4 1 2 6.35 11.29 0.68 o -3 1 2 6109.00 5902.44 63.42 o -2 1 2 1.56 6.81 2.59 o -1 1 2 7025.28 7266.42 78.26 o 0 1 2 587.77 607.20 6.04 o 1 1 2 3433.66 3633.04 35.81 o 2 1 2 1009.88 931.34 9.28 o 3 1 2 822.19 767.29 7.12 o 4 1 2 3309.87 3367.59 29.71 o 5 1 2 3.55 4.14 1.17 o 6 1 2 1863.50 1804.37 17.02 o 7 1 2 47.02 50.33 3.50 o 8 1 2 344.65 368.49 5.44 o 9 1 2 28.12 28.54 6.04 o 10 1 2 30.84 39.47 5.39 o -11 2 2 29.02 29.88 2.83 o -10 2 2 0.18 -2.81 2.81 o -9 2 2 45.48 45.65 2.16 o -8 2 2 15.01 13.93 2.68 o -7 2 2 807.73 811.51 8.56 o -6 2 2 87.05 91.98 1.98 o -5 2 2 111.86 104.26 1.67 o -4 2 2 156.41 149.31 2.02 o -3 2 2 714.98 731.41 8.20 o -2 2 2 1005.45 1054.44 13.39 o -1 2 2 776.29 815.40 10.43 o 0 2 2 2154.61 2442.30 27.01 o 1 2 2 156.94 150.87 3.95 o 2 2 2 1022.71 1023.48 11.35 o 3 2 2 601.90 670.21 8.78 o 4 2 2 160.61 176.46 2.94 o 5 2 2 81.15 73.70 2.50 o 6 2 2 7.81 6.29 1.60 o 7 2 2 2.44 3.74 1.81 o 8 2 2 3.39 4.60 2.44 o 9 2 2 0.25 -2.97 6.80 o -10 3 2 46.07 41.29 3.33 o -9 3 2 1.09 3.33 2.35 o -8 3 2 626.97 596.55 8.90 o -7 3 2 1.54 -0.33 1.47 o -6 3 2 346.13 354.64 4.74 o -5 3 2 507.31 501.77 6.05 o -4 3 2 5.36 4.73 1.11 o -3 3 2 722.64 703.90 7.97 o -2 3 2 341.38 354.53 4.19 o -1 3 2 2284.55 2304.16 24.84 o 0 3 2 7.70 4.78 0.57 o 1 3 2 2205.64 2257.46 24.42 o 2 3 2 945.38 962.93 11.67 o 3 3 2 295.04 301.29 4.00 o 4 3 2 966.02 995.19 11.38 o 5 3 2 6.43 8.10 1.50 o 6 3 2 264.28 248.23 4.24 o 7 3 2 30.98 29.05 4.56 o 8 3 2 1.45 3.32 2.76 o 9 3 2 0.73 4.01 6.65 o -10 4 2 5.33 7.33 3.38 o -9 4 2 148.24 146.03 8.42 o -8 4 2 103.74 107.43 4.39 o -7 4 2 524.76 532.19 6.83 o -6 4 2 1649.78 1613.83 18.03 o -5 4 2 875.02 894.65 10.27 o -4 4 2 2410.08 2193.42 27.67 o -3 4 2 1109.56 1178.53 13.11 o -2 4 2 5547.76 5369.86 57.86 o -1 4 2 73.60 57.54 1.24 o 0 4 2 2721.09 2727.01 33.98 o 1 4 2 1562.55 1549.51 19.69 o 2 4 2 2577.29 2570.50 24.93 o 3 4 2 1446.38 1470.12 18.84 o 4 4 2 423.02 441.53 6.55 o 5 4 2 1240.32 1183.58 15.58 o 6 4 2 22.07 26.79 2.10 o 7 4 2 523.59 543.43 20.92 o 8 4 2 62.66 62.65 3.62 o 9 4 2 221.59 225.78 11.66 o -10 5 2 185.13 190.86 6.48 o -9 5 2 13.21 18.93 3.45 o -8 5 2 526.78 521.10 10.09 o -7 5 2 192.80 192.85 5.14 o -6 5 2 940.67 942.08 21.61 o -5 5 2 1191.62 1153.30 39.26 o -4 5 2 281.27 266.89 4.41 o -3 5 2 4877.95 4546.82 81.48 o -2 5 2 122.81 133.10 2.68 o -1 5 2 7114.49 7065.09 79.17 o 0 5 2 2832.01 3107.80 38.78 o 1 5 2 2861.08 2956.38 37.03 o 2 5 2 2990.78 3030.39 37.99 o 3 5 2 556.80 546.43 6.87 o 4 5 2 2338.56 2368.47 30.03 o 5 5 2 0.30 0.97 1.81 o 6 5 2 736.71 761.44 16.91 o 7 5 2 40.69 46.22 3.25 o 8 5 2 257.50 280.99 8.72 o 9 5 2 89.63 92.21 9.55 o -9 6 2 127.74 132.54 5.80 o -8 6 2 136.80 141.17 5.37 o -7 6 2 155.44 156.71 5.31 o -6 6 2 420.06 418.07 8.35 o -5 6 2 11.66 20.67 3.24 o -4 6 2 1727.26 1695.17 26.11 o -3 6 2 26.18 24.24 2.24 o -2 6 2 849.44 795.36 18.86 o -1 6 2 13.44 11.84 1.95 o 0 6 2 1578.07 1607.09 20.64 o 1 6 2 117.45 106.28 3.34 o 2 6 2 378.48 395.15 6.44 o 3 6 2 1222.10 1210.46 13.90 o 4 6 2 80.02 78.18 2.56 o 5 6 2 932.14 953.51 11.41 o 6 6 2 68.76 73.03 3.90 o 7 6 2 352.28 357.61 8.04 o 8 6 2 26.40 29.64 7.81 o -9 7 2 0.16 5.20 3.91 o -8 7 2 0.61 3.56 4.14 o -7 7 2 1.48 3.85 4.94 o -6 7 2 86.41 89.49 4.48 o -5 7 2 4.70 7.27 2.84 o -4 7 2 195.12 191.14 5.58 o -3 7 2 36.79 35.44 3.29 o -2 7 2 0.73 -0.41 2.77 o -1 7 2 16.81 18.35 2.74 o 0 7 2 200.49 190.63 5.41 o 1 7 2 95.33 108.55 4.33 o 2 7 2 186.08 187.14 6.58 o 3 7 2 27.05 31.31 3.63 o 4 7 2 25.95 25.78 2.12 o 5 7 2 51.45 49.24 2.62 o 6 7 2 3.47 4.11 2.77 o 7 7 2 0.31 3.89 3.09 o 8 7 2 1.33 1.55 5.69 o -8 8 2 33.26 36.15 7.14 o -7 8 2 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