#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2213761.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2213761_Fobs loop_ _publ_author_name 'Walji, Dhiran V. B.' 'Storey, John M. D.' 'Harrison, William T. A.' _publ_section_title ; N-(2-Bromo-3-pyridyl)-3-methylbut-2-enamide ; _journal_coeditor_code FJ2005 _journal_issue 6 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2815 _journal_page_last o2816 _journal_volume 63 _journal_year 2007 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.387 _cell_angle_gamma 90.000 _cell_length_a 6.5351 _cell_length_b 8.1108 _cell_length_c 20.2220 _exptl_crystal_F_000 512.00 _reflns_d_resolution_high 0.7666 _[local]_cod_data_source_file fj2005Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' DHIRAN DW24 SOTON DATA' _shelx_refln_list_code 4 _shelx_f_calc_maximum 212.29 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 22855.06 23330.79 715.29 o 4 0 0 3593.65 3274.54 108.25 o 6 0 0 934.75 675.21 33.41 o 8 0 0 126.44 83.37 59.28 o 1 1 0 5516.72 4202.39 179.26 o 2 1 0 893.51 924.43 26.24 o 3 1 0 34.18 34.53 6.09 o 4 1 0 32.39 28.40 7.46 o 5 1 0 23.68 17.39 11.15 o 6 1 0 340.15 221.78 18.59 o 7 1 0 128.35 104.37 22.56 o 8 1 0 26.89 24.75 48.12 o 0 2 0 1311.93 1182.89 31.18 o 1 2 0 45068.04 44517.83 839.96 o 2 2 0 6745.08 6638.70 174.40 o 3 2 0 5224.77 5053.76 121.93 o 4 2 0 1121.49 1158.71 30.91 o 5 2 0 1997.84 2074.37 48.48 o 6 2 0 171.70 167.56 14.16 o 7 2 0 225.72 212.48 23.53 o 8 2 0 10.21 -9.15 35.01 o 1 3 0 64.87 63.06 3.07 o 2 3 0 1020.25 1049.66 34.85 o 3 3 0 184.19 199.14 9.41 o 4 3 0 11.98 -0.92 11.18 o 5 3 0 123.55 132.76 17.97 o 6 3 0 6.95 25.90 15.91 o 7 3 0 48.34 45.00 22.85 o 0 4 0 1466.29 1496.29 38.46 o 1 4 0 7031.62 6883.04 146.21 o 2 4 0 2877.16 2877.40 65.20 o 3 4 0 4119.35 4380.55 128.87 o 4 4 0 1144.01 1158.76 38.15 o 5 4 0 1133.18 1107.20 75.75 o 6 4 0 339.06 291.16 32.18 o 7 4 0 111.46 134.00 31.57 o 1 5 0 0.78 1.50 3.95 o 2 5 0 0.38 -3.11 4.53 o 3 5 0 214.05 190.66 13.37 o 4 5 0 5.11 23.86 11.34 o 5 5 0 83.46 51.35 21.76 o 6 5 0 1.20 -26.13 26.13 o 7 5 0 44.95 22.90 38.00 o 0 6 0 4651.06 4565.58 145.15 o 1 6 0 148.16 149.94 7.74 o 2 6 0 2277.44 2300.23 65.16 o 3 6 0 8.47 11.10 11.71 o 4 6 0 1828.38 1895.13 117.17 o 5 6 0 6.19 -10.35 16.98 o 6 6 0 359.45 351.43 30.73 o 1 7 0 1.05 -6.75 13.27 o 2 7 0 4.32 -12.90 12.90 o 3 7 0 79.37 60.31 22.14 o 4 7 0 2.97 11.80 13.43 o 5 7 0 21.49 19.40 19.13 o 6 7 0 70.18 189.58 78.12 o 0 8 0 500.66 460.15 39.38 o 1 8 0 689.62 713.04 41.07 o 2 8 0 399.43 381.45 66.24 o 3 8 0 843.58 882.80 40.87 o 4 8 0 278.94 411.46 61.13 o 5 8 0 369.93 399.29 79.85 o 1 9 0 5.46 26.83 30.95 o 2 9 0 82.36 74.13 32.52 o 3 9 0 7.59 -24.98 48.31 o 4 9 0 0.56 -1.19 48.64 o 0 10 0 24.20 29.40 57.00 o 1 10 0 366.10 333.12 47.03 o 2 10 0 152.29 339.89 47.51 o -7 0 1 239.66 239.94 44.89 o -5 0 1 933.27 817.30 39.14 o -3 0 1 2520.64 1929.16 142.54 o 1 0 1 13921.49 13065.25 387.56 o 3 0 1 13639.72 13448.90 385.09 o 5 0 1 3861.00 3798.59 119.77 o 7 0 1 1654.13 1126.59 93.91 o -8 1 1 3.21 -8.89 36.19 o -7 1 1 41.02 72.27 18.39 o -6 1 1 4.16 -4.00 11.06 o -5 1 1 300.82 212.29 20.94 o -4 1 1 16.60 18.66 7.90 o -3 1 1 34.50 28.11 6.77 o -2 1 1 14.45 17.35 4.33 o -1 1 1 24.12 20.59 1.69 o 1 1 1 262.03 235.84 8.19 o 2 1 1 251.03 294.45 10.29 o 3 1 1 61.08 75.00 6.59 o 4 1 1 1.84 6.46 9.10 o 5 1 1 54.24 65.12 11.74 o 6 1 1 34.47 -6.81 15.33 o 7 1 1 76.42 13.87 34.40 o 8 1 1 0.08 18.10 49.26 o -8 2 1 197.66 235.69 29.98 o -7 2 1 133.18 206.30 26.79 o -6 2 1 310.87 256.39 29.88 o -5 2 1 11.02 6.72 16.67 o -4 2 1 932.26 913.37 27.02 o -3 2 1 118.10 120.97 8.66 o -2 2 1 2320.37 2262.40 72.83 o -1 2 1 1104.73 1020.42 20.70 o 0 2 1 10860.26 10044.69 347.69 o 1 2 1 27881.96 28136.98 673.03 o 2 2 1 9152.09 8391.07 226.04 o 3 2 1 5116.93 5051.57 186.08 o 4 2 1 3843.50 3691.76 224.80 o 5 2 1 1093.69 1144.63 52.19 o 6 2 1 2172.21 1924.11 108.63 o 7 2 1 181.13 180.38 21.03 o 8 2 1 328.11 205.38 83.20 o -8 3 1 131.91 149.43 37.14 o -7 3 1 6.75 11.59 18.80 o -6 3 1 213.78 150.30 19.58 o -5 3 1 196.22 228.27 16.27 o -4 3 1 790.68 900.73 25.75 o -3 3 1 207.15 191.60 10.90 o -2 3 1 14.23 22.49 3.95 o -1 3 1 3.37 5.15 2.66 o 0 3 1 548.33 516.69 12.77 o 1 3 1 1386.58 1412.35 34.08 o 2 3 1 124.30 116.11 8.07 o 3 3 1 23.60 39.71 7.39 o 4 3 1 313.42 306.57 16.48 o 5 3 1 261.81 258.37 13.42 o 6 3 1 0.87 -8.24 17.51 o 7 3 1 87.94 10.74 32.49 o 8 3 1 93.47 36.45 41.39 o -7 4 1 166.73 151.34 38.29 o -6 4 1 75.53 78.59 22.80 o -5 4 1 125.64 139.33 22.85 o -4 4 1 746.05 774.24 30.22 o -3 4 1 297.81 273.72 11.21 o -2 4 1 2906.86 2638.05 73.10 o -1 4 1 861.15 891.56 30.64 o 0 4 1 6703.19 6505.75 151.61 o 1 4 1 3287.86 3380.97 82.96 o 2 4 1 16499.22 17401.32 402.24 o 3 4 1 318.99 282.62 29.68 o 4 4 1 4147.55 4664.42 180.08 o 5 4 1 937.71 988.09 58.50 o 6 4 1 1000.18 1098.33 77.52 o 7 4 1 275.64 250.10 47.98 o -7 5 1 82.16 68.01 56.53 o -6 5 1 163.74 84.41 32.82 o -5 5 1 275.47 293.11 36.72 o -4 5 1 439.06 397.36 31.11 o -3 5 1 250.18 233.67 12.68 o -2 5 1 3.85 -5.20 5.20 o -1 5 1 58.53 65.63 7.94 o 0 5 1 174.59 168.31 7.10 o 1 5 1 491.91 523.38 12.98 o 2 5 1 476.64 499.48 20.37 o 3 5 1 39.50 43.96 9.17 o 4 5 1 574.72 500.32 27.63 o 5 5 1 12.87 3.55 15.04 o 6 5 1 89.31 126.21 34.65 o 7 5 1 0.14 -36.10 36.10 o -6 6 1 12.31 -20.57 20.57 o -5 6 1 306.63 193.11 23.44 o -4 6 1 2.46 -14.09 15.59 o -3 6 1 2986.76 2860.84 204.52 o -2 6 1 9.83 7.73 7.71 o -1 6 1 1969.66 1890.41 51.10 o 0 6 1 39.49 29.98 6.53 o 1 6 1 3417.04 3325.69 94.26 o 2 6 1 6.14 0.72 7.25 o 3 6 1 5848.54 6220.96 193.56 o 4 6 1 1.18 18.03 10.94 o 5 6 1 1179.05 854.31 62.77 o 6 6 1 12.90 76.48 47.26 o -6 7 1 9.22 -14.98 42.42 o -5 7 1 247.88 300.66 50.14 o -4 7 1 68.20 66.08 24.44 o -3 7 1 19.26 33.07 12.36 o -2 7 1 16.99 0.14 21.39 o -1 7 1 58.38 90.71 21.90 o 0 7 1 241.64 277.13 21.83 o 1 7 1 94.13 72.81 10.24 o 2 7 1 251.08 203.45 15.44 o 3 7 1 64.02 84.73 17.81 o 4 7 1 158.37 168.28 22.94 o 5 7 1 31.77 37.49 16.78 o 6 7 1 11.95 -65.03 65.03 o -5 8 1 38.44 82.32 53.01 o -4 8 1 695.09 780.64 58.76 o -3 8 1 95.69 90.42 60.14 o -2 8 1 756.88 817.23 110.54 o -1 8 1 283.30 255.21 28.60 o 0 8 1 413.26 437.72 32.69 o 1 8 1 575.25 624.89 34.70 o 2 8 1 1041.29 1074.22 52.33 o 3 8 1 16.83 57.29 45.32 o 4 8 1 808.89 592.39 65.69 o 5 8 1 99.86 286.77 71.96 o -4 9 1 12.34 158.04 69.87 o -3 9 1 3.23 36.32 35.28 o -2 9 1 4.34 33.58 31.72 o -1 9 1 47.90 22.95 32.06 o 0 9 1 50.57 56.61 35.20 o 1 9 1 184.90 137.18 27.32 o 2 9 1 39.27 106.60 34.32 o 3 9 1 5.03 54.39 44.89 o -2 10 1 262.93 326.90 64.89 o -1 10 1 7.35 -8.37 40.27 o 0 10 1 270.13 223.83 43.46 o 1 10 1 103.68 88.99 34.65 o 2 10 1 112.58 245.72 78.59 o -8 0 2 59.88 102.98 53.30 o -6 0 2 1134.58 1163.85 46.55 o -4 0 2 96.59 54.01 12.71 o -2 0 2 334.40 324.84 13.98 o 2 0 2 9237.27 8482.71 311.52 o 4 0 2 8868.77 9257.82 310.30 o 6 0 2 3972.42 3844.33 133.89 o -8 1 2 467.22 402.95 44.66 o -7 1 2 263.69 314.10 28.12 o -6 1 2 884.72 934.90 60.33 o -5 1 2 348.62 294.94 16.82 o -4 1 2 2055.51 2325.62 88.27 o -3 1 2 3804.72 2971.52 96.64 o -2 1 2 3548.44 2616.55 148.44 o -1 1 2 3117.31 2642.86 139.41 o 0 1 2 257.22 131.95 12.87 o 1 1 2 891.86 961.34 21.17 o 2 1 2 1704.29 1656.20 41.02 o 3 1 2 389.41 421.19 11.47 o 4 1 2 684.41 789.39 19.99 o 5 1 2 513.57 527.56 17.54 o 6 1 2 36.10 56.98 14.24 o 7 1 2 10.82 7.13 38.29 o -8 2 2 0.11 23.49 46.05 o -7 2 2 184.20 214.18 31.33 o -6 2 2 42.34 52.60 14.38 o -5 2 2 395.21 297.96 20.36 o -4 2 2 504.59 489.01 33.51 o -3 2 2 308.90 239.79 11.41 o -2 2 2 883.07 903.27 35.75 o -1 2 2 6280.02 5895.53 226.80 o 0 2 2 139.01 192.69 6.58 o 1 2 2 2860.70 2695.56 61.85 o 2 2 2 1277.87 1290.90 40.88 o 3 2 2 4981.27 4987.46 130.95 o 4 2 2 1693.56 1705.06 50.22 o 5 2 2 3598.54 4061.13 112.43 o 6 2 2 79.43 78.57 18.13 o 7 2 2 1035.90 1028.43 67.47 o 8 2 2 284.00 244.63 45.19 o -8 3 2 1.33 -12.92 52.54 o -7 3 2 788.43 815.89 56.07 o -6 3 2 6.71 -13.31 13.31 o -5 3 2 1264.78 1027.99 78.43 o -4 3 2 3.20 4.92 9.96 o -3 3 2 1793.05 1664.33 83.77 o -2 3 2 1638.61 1837.34 41.14 o -1 3 2 58.38 34.30 3.67 o 0 3 2 87.22 84.87 4.51 o 1 3 2 1185.16 1073.97 33.11 o 2 3 2 35.28 29.98 3.93 o 3 3 2 1134.28 1137.84 68.99 o 4 3 2 94.15 105.87 12.41 o 5 3 2 7.40 6.46 10.35 o 6 3 2 1.68 28.28 22.26 o 7 3 2 73.84 42.66 49.07 o -7 4 2 92.99 114.62 35.01 o -6 4 2 9.94 40.16 17.66 o -5 4 2 251.92 221.05 30.29 o -4 4 2 250.20 150.45 16.05 o -3 4 2 1160.27 1236.12 29.93 o -2 4 2 2590.86 2552.99 52.36 o -1 4 2 475.44 405.36 13.87 o 0 4 2 1004.77 1009.26 22.96 o 1 4 2 1464.04 1301.48 30.23 o 2 4 2 56.16 35.69 5.17 o 3 4 2 3380.93 3502.07 109.55 o 4 4 2 660.63 639.16 49.39 o 5 4 2 750.13 590.03 67.45 o 6 4 2 201.87 203.46 29.80 o 7 4 2 409.33 460.24 60.61 o -7 5 2 125.02 247.86 52.49 o -6 5 2 426.79 447.20 39.47 o -5 5 2 148.83 169.31 36.40 o -4 5 2 809.01 683.48 40.01 o -3 5 2 259.76 284.60 14.57 o -2 5 2 97.61 68.60 6.85 o -1 5 2 6.63 7.76 4.38 o 0 5 2 359.75 353.22 11.06 o 1 5 2 3.51 6.75 2.08 o 2 5 2 315.93 305.12 14.93 o 3 5 2 39.99 34.54 8.86 o 4 5 2 3.53 8.91 13.34 o 5 5 2 42.87 21.59 14.77 o 6 5 2 63.28 20.57 31.16 o -6 6 2 221.01 224.56 27.77 o -5 6 2 0.84 11.53 27.06 o -4 6 2 347.15 274.90 25.06 o -3 6 2 341.15 302.57 34.98 o -2 6 2 929.48 917.88 33.12 o -1 6 2 32.75 29.89 8.32 o 0 6 2 953.51 901.31 23.71 o 1 6 2 60.41 52.37 8.71 o 2 6 2 1992.10 2093.41 57.42 o 3 6 2 414.63 453.85 19.85 o 4 6 2 821.17 690.22 99.71 o 5 6 2 52.61 26.77 41.88 o 6 6 2 344.99 345.00 70.44 o -6 7 2 296.13 393.06 78.64 o -5 7 2 71.89 41.24 25.40 o -4 7 2 295.45 320.07 30.04 o -3 7 2 18.45 32.18 12.15 o -2 7 2 623.59 616.34 24.49 o -1 7 2 9.45 18.41 16.53 o 0 7 2 81.20 78.23 19.29 o 1 7 2 70.83 67.56 10.80 o 2 7 2 140.57 143.28 25.50 o 3 7 2 15.35 14.82 15.65 o 4 7 2 18.47 -8.20 16.97 o 5 7 2 80.79 33.73 21.72 o -5 8 2 195.02 255.37 74.05 o -4 8 2 23.79 21.66 51.54 o -3 8 2 223.19 280.64 29.57 o -2 8 2 135.95 107.73 24.52 o -1 8 2 455.08 451.09 31.66 o 0 8 2 412.34 376.08 47.29 o 1 8 2 193.44 133.14 22.93 o 2 8 2 394.51 432.10 31.04 o 3 8 2 467.94 571.06 50.83 o 4 8 2 646.81 375.21 43.94 o 5 8 2 73.35 249.81 77.85 o -4 9 2 28.24 191.67 48.88 o -3 9 2 217.39 230.18 43.84 o -2 9 2 60.39 61.04 32.90 o -1 9 2 233.75 277.27 35.42 o 0 9 2 8.27 -2.21 29.68 o 1 9 2 260.84 274.18 35.70 o 2 9 2 9.84 43.34 34.78 o 3 9 2 69.28 69.68 60.56 o 4 9 2 3.64 -160.84 160.84 o -2 10 2 43.70 -36.07 43.45 o -1 10 2 465.42 424.44 41.06 o 0 10 2 1.52 -25.38 37.22 o 1 10 2 313.21 301.03 51.61 o 2 10 2 8.44 13.63 83.25 o -7 0 3 77.46 65.46 25.96 o -5 0 3 692.38 790.29 45.18 o -3 0 3 2706.17 3276.69 141.24 o -1 0 3 12426.87 10803.27 1158.30 o 1 0 3 1688.36 1577.47 48.51 o 3 0 3 1167.12 1086.07 31.26 o 5 0 3 1914.71 2053.04 90.00 o -8 1 3 51.14 61.75 45.32 o -7 1 3 1042.35 1137.81 48.03 o -6 1 3 1199.88 1288.36 51.09 o -5 1 3 3580.13 3973.31 99.95 o -4 1 3 1391.85 1549.18 47.06 o -3 1 3 7095.38 7489.36 335.29 o -2 1 3 1016.02 966.42 33.24 o -1 1 3 4964.05 4751.45 143.48 o 0 1 3 687.23 654.04 19.35 o 1 1 3 219.79 244.67 8.09 o 2 1 3 717.64 745.30 21.43 o 3 1 3 776.11 679.18 19.03 o 4 1 3 460.70 523.57 18.37 o 5 1 3 652.33 667.92 20.48 o 6 1 3 6.88 23.82 17.79 o -8 2 3 3.69 37.73 27.81 o -7 2 3 0.13 8.39 16.58 o -6 2 3 81.56 79.57 15.38 o -5 2 3 183.22 178.74 13.76 o -4 2 3 1003.32 1066.31 74.77 o -3 2 3 154.28 123.36 10.47 o -2 2 3 2597.26 2777.15 70.39 o -1 2 3 412.11 429.62 12.84 o 0 2 3 5685.34 5613.55 129.42 o 1 2 3 805.14 805.60 20.19 o 2 2 3 359.31 298.95 9.69 o 3 2 3 709.12 683.15 19.93 o 4 2 3 1012.26 1013.98 26.73 o 5 2 3 977.12 915.33 37.93 o 6 2 3 633.28 503.03 41.40 o 7 2 3 452.99 426.98 43.18 o 8 2 3 55.77 30.49 39.53 o -7 3 3 0.15 -42.75 44.46 o -6 3 3 1626.88 1787.97 66.62 o -5 3 3 1.09 9.65 12.25 o -4 3 3 4536.13 4266.56 164.33 o -3 3 3 23.20 30.53 7.43 o -2 3 3 10826.40 11154.63 249.95 o -1 3 3 227.06 262.69 8.61 o 0 3 3 6368.76 6121.33 161.94 o 1 3 3 77.56 67.91 8.68 o 2 3 3 65.55 30.17 3.91 o 3 3 3 30.58 37.08 7.46 o 4 3 3 1058.23 979.31 51.23 o 5 3 3 10.33 4.44 10.41 o 6 3 3 346.23 389.54 26.28 o 7 3 3 23.41 17.24 42.28 o -6 4 3 2.95 -1.12 16.52 o -5 4 3 136.20 123.62 13.13 o -4 4 3 412.89 402.49 22.23 o -3 4 3 290.57 283.59 11.39 o -2 4 3 10.61 12.69 4.68 o -1 4 3 1146.20 1151.59 27.04 o 0 4 3 769.09 699.84 17.27 o 1 4 3 893.36 923.10 22.04 o 2 4 3 2409.84 2361.94 77.68 o 3 4 3 5.75 4.70 10.70 o 4 4 3 1972.20 2075.75 63.08 o 5 4 3 224.32 210.16 16.90 o 6 4 3 904.15 999.56 42.10 o 7 4 3 76.36 92.25 41.99 o -7 5 3 322.00 360.39 51.63 o -6 5 3 507.55 593.51 32.86 o -5 5 3 1514.07 1677.45 137.83 o -4 5 3 446.68 512.80 30.74 o -3 5 3 2064.14 2066.45 88.38 o -2 5 3 452.37 449.16 16.39 o -1 5 3 5320.32 5561.81 159.97 o 0 5 3 946.09 929.15 23.92 o 1 5 3 2422.31 2440.62 64.09 o 2 5 3 614.23 551.17 16.11 o 3 5 3 850.59 792.17 29.22 o 4 5 3 33.58 23.27 11.59 o 5 5 3 165.11 152.76 30.26 o 6 5 3 8.89 -28.88 31.16 o -6 6 3 18.96 69.45 50.45 o -5 6 3 30.18 12.62 18.89 o -4 6 3 59.83 34.03 25.16 o -3 6 3 111.59 102.45 18.35 o -2 6 3 50.92 6.01 17.85 o -1 6 3 402.16 382.13 15.84 o 0 6 3 58.07 72.66 8.41 o 1 6 3 1671.99 1631.52 59.04 o 2 6 3 33.56 13.54 10.66 o 3 6 3 1727.71 1718.45 61.71 o 4 6 3 34.01 11.87 12.99 o 5 6 3 586.03 478.21 79.35 o 6 6 3 22.57 33.87 36.04 o -6 7 3 233.39 156.97 59.64 o -5 7 3 542.00 766.39 76.67 o -4 7 3 305.44 305.81 49.83 o -3 7 3 679.70 718.42 32.29 o -2 7 3 229.54 207.53 16.18 o -1 7 3 1153.31 1085.45 36.23 o 0 7 3 1176.16 1183.24 34.82 o 1 7 3 1043.71 1002.08 31.65 o 2 7 3 1135.48 1098.95 40.28 o 3 7 3 169.59 147.36 56.12 o 4 7 3 50.36 60.90 16.34 o 5 7 3 24.23 144.93 70.06 o 6 7 3 17.44 20.95 37.10 o -5 8 3 0.37 -47.83 47.83 o -4 8 3 12.40 -2.00 36.81 o -3 8 3 49.33 38.62 43.23 o -2 8 3 125.83 107.29 45.70 o -1 8 3 45.45 82.48 26.76 o 0 8 3 508.68 538.88 38.26 o 1 8 3 200.07 190.36 23.42 o 2 8 3 831.83 875.34 37.33 o 3 8 3 38.87 68.61 17.07 o 4 8 3 75.89 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