#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2214124.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2214124_Fobs loop_ _publ_author_name 'Castillo-Cruz, Alfredo' 'Toscano, Rub\'en A.' 'Hern\'andez-Ortega, Sim\'on' 'Vald\'es-Mart\'inez, Jes\'us' _publ_section_title ; 2-Methyl-1-(3-pyridylmethylene)thiosemicarbazone hemihydrate ; _journal_coeditor_code CI2398 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3334 _journal_volume 63 _journal_year 2007 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 112.077 _cell_angle_gamma 90.000 _cell_length_a 16.9013 _cell_length_b 10.0909 _cell_length_c 12.6812 _exptl_crystal_F_000 856.00 _reflns_d_resolution_high 0.8289 _[local]_cod_data_source_file ci2398Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' AR8' _shelx_refln_list_code 4 _shelx_f_calc_maximum 293.51 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 1017.41 1036.65 20.83 o 4 0 0 1740.50 1593.48 30.57 o 6 0 0 1358.06 1302.20 34.09 o 8 0 0 4855.25 5428.75 80.51 o 10 0 0 2268.53 2205.63 58.49 o 12 0 0 114.55 105.92 19.30 o 14 0 0 655.02 606.87 46.48 o 16 0 0 1074.09 1079.97 66.86 o 18 0 0 264.00 315.78 40.68 o 1 1 0 279.80 260.28 6.25 o 3 1 0 593.67 500.46 8.99 o 5 1 0 9203.98 9568.14 121.60 o 7 1 0 16.59 24.85 6.18 o 9 1 0 979.93 1003.19 28.98 o 11 1 0 4.60 4.75 6.47 o 13 1 0 96.71 117.53 15.72 o 15 1 0 69.07 72.47 14.26 o 17 1 0 42.35 35.29 13.79 o 0 2 0 16604.10 17009.72 595.32 o 2 2 0 10535.96 11228.12 118.92 o 4 2 0 4397.38 4436.50 35.40 o 6 2 0 6151.08 6905.36 69.43 o 8 2 0 15.76 8.88 3.59 o 10 2 0 1297.13 1253.83 28.69 o 12 2 0 136.68 141.62 14.72 o 14 2 0 656.88 593.10 33.01 o 16 2 0 1256.11 1269.07 52.11 o 18 2 0 38.94 24.51 12.11 o 1 3 0 7018.17 7469.89 52.04 o 3 3 0 6118.92 6515.86 53.35 o 5 3 0 1057.89 1173.84 21.28 o 7 3 0 1236.32 1410.26 24.20 o 9 3 0 47.06 38.69 6.41 o 11 3 0 210.39 198.10 15.95 o 13 3 0 55.63 61.96 12.71 o 15 3 0 115.60 129.31 18.03 o 17 3 0 68.31 66.09 15.59 o 0 4 0 3386.54 3459.91 44.14 o 2 4 0 554.35 592.24 19.87 o 4 4 0 170.14 147.08 7.22 o 6 4 0 2390.29 2482.74 34.26 o 8 4 0 798.37 833.91 21.04 o 10 4 0 1484.00 1487.53 29.66 o 12 4 0 1253.16 1121.48 37.07 o 14 4 0 598.04 626.45 30.71 o 16 4 0 68.79 96.15 19.65 o 1 5 0 0.38 2.77 3.85 o 3 5 0 46.97 39.87 8.47 o 5 5 0 405.37 396.91 17.96 o 7 5 0 770.60 789.38 21.31 o 9 5 0 115.58 143.21 12.22 o 11 5 0 14.65 26.63 10.74 o 13 5 0 54.00 54.35 14.39 o 15 5 0 246.96 270.30 25.94 o 17 5 0 9.01 3.79 11.94 o 0 6 0 390.67 339.58 16.99 o 2 6 0 5.79 7.46 5.48 o 4 6 0 2552.48 2453.93 50.96 o 6 6 0 667.44 676.19 25.65 o 8 6 0 17.78 18.48 8.34 o 10 6 0 829.94 821.92 30.04 o 12 6 0 212.92 201.23 21.79 o 14 6 0 75.68 57.94 15.80 o 16 6 0 58.85 77.01 18.83 o 1 7 0 1374.62 1316.36 32.04 o 3 7 0 0.59 5.42 6.37 o 5 7 0 44.11 41.06 9.99 o 7 7 0 119.10 125.96 14.97 o 9 7 0 5.65 13.59 8.17 o 11 7 0 4.55 2.54 7.34 o 13 7 0 9.49 19.82 11.37 o 15 7 0 41.59 53.67 19.15 o 0 8 0 953.23 908.28 69.58 o 2 8 0 19.77 26.50 10.82 o 4 8 0 26.66 42.41 10.45 o 6 8 0 47.39 39.22 10.69 o 8 8 0 107.56 119.20 16.63 o 10 8 0 629.59 601.89 30.43 o 12 8 0 0.03 3.26 9.89 o 14 8 0 1.20 13.33 14.74 o 1 9 0 11.11 0.14 8.49 o 3 9 0 556.64 564.89 32.25 o 5 9 0 0.52 2.43 8.56 o 7 9 0 13.18 18.14 9.52 o 9 9 0 0.13 1.86 10.25 o 11 9 0 0.24 4.31 11.11 o 0 10 0 4.48 6.31 13.92 o 2 10 0 403.04 402.69 29.40 o 4 10 0 0.09 -0.92 8.57 o 6 10 0 77.96 81.16 17.52 o 8 10 0 55.16 62.79 19.94 o 10 10 0 7.89 28.71 15.24 o 1 11 0 280.93 266.45 26.22 o 3 11 0 13.20 16.89 11.74 o 5 11 0 3.65 11.26 10.77 o 7 11 0 48.28 35.83 17.10 o 0 12 0 11.32 12.99 17.56 o 2 12 0 657.83 624.76 40.35 o -19 1 1 20.45 20.30 13.01 o -17 1 1 345.61 346.29 28.42 o -15 1 1 114.57 130.21 18.39 o -13 1 1 1283.90 1268.31 39.69 o -11 1 1 2973.80 2864.69 53.28 o -9 1 1 327.31 320.41 16.67 o -7 1 1 3381.73 3344.21 50.60 o -5 1 1 1319.84 1365.77 20.03 o -3 1 1 9270.42 9841.61 47.54 o 1 1 1 7050.38 7292.07 50.12 o 3 1 1 933.04 893.58 12.60 o 5 1 1 8950.24 9504.09 115.36 o 7 1 1 584.81 554.26 11.93 o 9 1 1 1.26 14.04 5.98 o 11 1 1 233.08 230.74 17.29 o 13 1 1 973.35 931.18 35.37 o 15 1 1 86.04 80.24 15.20 o 17 1 1 10.84 5.96 10.04 o -18 2 1 228.65 225.54 23.14 o -16 2 1 64.12 55.10 13.40 o -14 2 1 17.66 12.66 8.74 o -12 2 1 2.08 2.64 6.78 o -10 2 1 630.05 673.98 16.91 o -8 2 1 353.68 360.84 11.70 o -6 2 1 6434.79 7148.59 64.15 o -4 2 1 6801.35 6736.01 48.69 o -2 2 1 36.67 38.88 4.22 o 0 2 1 4202.24 4468.71 46.44 o 2 2 1 64164.23 55095.48 1177.55 o 4 2 1 1639.75 1650.60 22.59 o 6 2 1 689.89 703.59 15.64 o 8 2 1 2221.06 2364.63 34.96 o 10 2 1 880.57 889.77 30.03 o 12 2 1 3.83 3.52 7.35 o 14 2 1 4.09 2.04 7.62 o 16 2 1 45.20 42.10 12.67 o 18 2 1 108.61 92.60 18.50 o -17 3 1 263.43 279.33 23.56 o -15 3 1 49.20 42.87 11.66 o -13 3 1 318.85 321.65 21.35 o -11 3 1 831.14 784.59 28.94 o -9 3 1 95.18 103.61 8.24 o -5 3 1 3655.48 3488.67 46.40 o -3 3 1 9520.42 9703.44 78.78 o -1 3 1 11084.50 11478.38 96.40 o 1 3 1 14099.34 14654.22 137.05 o 3 3 1 39.26 28.58 4.28 o 5 3 1 3763.73 3853.74 39.48 o 7 3 1 878.95 743.90 18.34 o 9 3 1 997.22 913.96 21.56 o 11 3 1 8.29 7.24 7.29 o 13 3 1 473.70 453.70 25.57 o 15 3 1 502.69 496.41 28.91 o 17 3 1 89.91 98.03 18.32 o -18 4 1 0.06 5.88 10.60 o -16 4 1 84.02 69.00 17.00 o -14 4 1 246.84 241.04 22.53 o -12 4 1 581.31 539.15 29.95 o -10 4 1 1.81 4.14 5.02 o -8 4 1 9.08 17.96 5.82 o -6 4 1 1054.13 1097.67 22.80 o -4 4 1 589.16 667.23 15.35 o -2 4 1 1121.94 1217.26 19.07 o 0 4 1 218.86 224.30 8.48 o 2 4 1 2149.74 2358.29 35.30 o 4 4 1 1059.52 1140.61 20.61 o 6 4 1 3423.65 3605.88 57.49 o 8 4 1 55.43 72.29 8.87 o 10 4 1 19.79 23.68 6.84 o 12 4 1 14.89 12.54 8.03 o 14 4 1 1.18 4.77 8.84 o 16 4 1 86.37 78.80 18.56 o -17 5 1 95.47 129.51 23.72 o -15 5 1 25.44 22.06 11.80 o -13 5 1 477.20 422.40 28.64 o -11 5 1 1038.19 1059.27 27.13 o -9 5 1 438.57 365.19 16.82 o -7 5 1 2118.90 1925.24 35.57 o -5 5 1 31.99 19.47 4.61 o -3 5 1 3564.05 3576.41 53.59 o -1 5 1 4083.12 4174.45 39.20 o 1 5 1 610.18 554.69 18.69 o 3 5 1 4793.66 4819.63 65.67 o 5 5 1 289.41 271.73 11.07 o 7 5 1 95.13 94.33 9.73 o 9 5 1 615.04 614.93 20.31 o 11 5 1 0.02 -4.97 7.34 o 13 5 1 292.65 309.81 25.74 o 15 5 1 466.69 470.04 33.15 o -16 6 1 7.70 16.67 12.14 o -14 6 1 61.01 57.32 16.37 o -12 6 1 239.62 189.00 19.93 o -10 6 1 312.83 267.39 17.05 o -8 6 1 15.58 16.87 8.07 o -6 6 1 11.22 16.40 7.34 o -4 6 1 1848.09 1909.12 45.45 o -2 6 1 614.89 601.34 26.09 o 0 6 1 596.19 618.17 15.83 o 2 6 1 7.07 6.82 5.58 o 4 6 1 669.31 634.77 23.80 o 6 6 1 21.31 11.88 7.06 o 8 6 1 1.61 1.51 6.52 o 10 6 1 15.47 14.61 7.53 o 12 6 1 143.40 166.99 22.02 o 14 6 1 66.15 59.32 15.68 o -15 7 1 18.01 23.15 13.64 o -13 7 1 1356.94 1205.75 49.98 o -11 7 1 273.37 283.68 18.76 o -9 7 1 6.03 8.95 7.73 o -7 7 1 1072.42 1086.51 35.08 o -5 7 1 247.97 226.60 16.22 o -3 7 1 1717.18 1611.42 37.99 o -1 7 1 2261.17 2298.09 52.68 o 1 7 1 47.75 53.17 9.66 o 3 7 1 1664.00 1696.04 39.94 o 5 7 1 2293.48 2231.92 47.93 o 7 7 1 30.84 43.73 11.08 o 9 7 1 487.09 511.43 25.97 o 11 7 1 0.01 -1.46 8.68 o 13 7 1 406.69 400.88 36.76 o -14 8 1 26.95 26.11 13.17 o -12 8 1 161.43 203.97 23.88 o -10 8 1 87.38 115.58 16.61 o -8 8 1 49.75 43.14 11.55 o -6 8 1 106.22 131.59 16.23 o -4 8 1 157.12 158.44 15.93 o -2 8 1 77.61 63.52 14.21 o 0 8 1 21.87 22.73 10.36 o 2 8 1 168.11 173.89 15.24 o 4 8 1 859.63 870.79 38.59 o 6 8 1 9.82 4.84 7.15 o 8 8 1 8.57 7.65 7.88 o 10 8 1 82.21 81.37 16.69 o 12 8 1 0.50 5.81 12.49 o -13 9 1 230.07 246.20 25.89 o -11 9 1 254.96 308.35 23.71 o -9 9 1 2.88 19.72 13.09 o -7 9 1 126.53 138.41 17.07 o -5 9 1 387.43 318.92 25.26 o -3 9 1 757.06 736.32 36.30 o -1 9 1 297.05 266.67 22.69 o 1 9 1 9.13 10.39 9.40 o 3 9 1 4043.27 4119.61 115.04 o 5 9 1 181.65 168.05 20.70 o 7 9 1 16.20 3.61 8.48 o 9 9 1 143.27 168.15 20.99 o 11 9 1 12.56 17.29 17.56 o -10 10 1 7.30 11.68 11.13 o -8 10 1 18.56 14.12 13.38 o -6 10 1 4.51 -0.11 8.84 o -4 10 1 45.77 56.38 14.92 o -2 10 1 280.34 323.91 31.00 o 0 10 1 284.12 271.89 24.76 o 2 10 1 5.42 11.03 10.37 o 4 10 1 334.41 397.84 29.56 o 6 10 1 15.39 21.70 14.82 o 8 10 1 301.16 313.21 32.68 o 10 10 1 0.45 4.90 11.07 o -7 11 1 0.65 -3.97 10.17 o -5 11 1 9.81 18.04 11.81 o -3 11 1 29.87 27.52 12.83 o -1 11 1 874.41 882.85 44.85 o 1 11 1 271.92 278.80 26.59 o 3 11 1 94.72 81.60 28.54 o 5 11 1 37.54 44.97 19.57 o 7 11 1 21.26 17.26 14.45 o -2 12 1 1.22 8.18 13.52 o 0 12 1 129.81 138.11 27.82 o 2 12 1 251.63 258.41 32.42 o -18 0 2 3.71 8.79 17.22 o -16 0 2 2191.06 2080.25 90.24 o -14 0 2 2886.82 2769.24 95.66 o -12 0 2 1242.39 1193.73 57.91 o -10 0 2 95.95 112.81 18.64 o -8 0 2 4815.35 4823.96 70.58 o -6 0 2 1920.07 1931.29 47.06 o -4 0 2 3180.92 3816.21 62.70 o -2 0 2 13252.92 12616.38 72.53 o 0 0 2 23311.00 22748.25 384.28 o 2 0 2 28352.43 28782.02 334.33 o 4 0 2 2189.54 2032.57 31.12 o 6 0 2 14832.92 14670.57 292.19 o 8 0 2 2451.28 2563.05 39.62 o 10 0 2 695.57 757.41 37.19 o 12 0 2 1490.69 1516.38 63.75 o 14 0 2 5.42 16.02 11.88 o 16 0 2 285.13 302.49 38.76 o -19 1 2 267.29 308.50 33.84 o -17 1 2 259.44 273.73 25.64 o -15 1 2 393.31 362.53 26.81 o -13 1 2 297.55 295.44 20.20 o -11 1 2 35.11 29.79 8.61 o -9 1 2 96.36 90.44 6.37 o -7 1 2 100.57 113.68 6.81 o -5 1 2 1810.54 1936.75 21.74 o -3 1 2 4061.84 4221.25 37.30 o -1 1 2 2172.57 2155.33 24.24 o 1 1 2 23869.02 24422.80 235.86 o 3 1 2 9763.95 10183.14 73.18 o 5 1 2 45.78 48.74 4.93 o 7 1 2 886.08 881.14 17.37 o 9 1 2 448.46 486.17 14.21 o 11 1 2 709.33 700.47 26.75 o 13 1 2 32.00 38.03 11.12 o 15 1 2 13.85 15.51 9.91 o 17 1 2 67.63 91.29 18.09 o -18 2 2 194.54 212.63 25.80 o -16 2 2 231.63 236.48 23.37 o -14 2 2 2240.13 2257.52 60.01 o -12 2 2 781.24 741.46 28.95 o -10 2 2 5502.90 5754.05 118.15 o -8 2 2 4499.08 4613.92 44.50 o -6 2 2 178.33 191.04 8.24 o -4 2 2 372.49 395.54 11.54 o -2 2 2 1212.80 1112.65 16.99 o 0 2 2 8595.76 8833.73 46.35 o 2 2 2 86148.54 72708.37 2061.49 o 4 2 2 126.84 136.85 7.72 o 6 2 2 377.57 333.98 11.89 o 8 2 2 3095.57 3186.10 47.96 o 10 2 2 7.83 4.83 6.53 o 12 2 2 610.93 535.81 26.76 o 14 2 2 60.12 72.27 14.23 o 16 2 2 304.81 295.42 24.01 o -19 3 2 127.53 149.79 22.02 o -17 3 2 36.96 33.16 11.78 o -15 3 2 14.59 16.93 9.26 o -13 3 2 0.01 2.54 6.93 o -11 3 2 163.04 167.86 10.43 o -9 3 2 8.47 19.64 5.13 o -7 3 2 1927.38 1977.01 28.34 o -5 3 2 2244.66 2233.08 30.02 o -3 3 2 5181.69 5089.44 41.33 o -1 3 2 43.43 46.10 5.16 o 1 3 2 143.22 137.23 6.86 o 3 3 2 17.48 20.88 4.43 o 5 3 2 1585.56 1590.53 26.71 o 7 3 2 302.59 292.50 12.50 o 9 3 2 38.58 45.71 7.67 o 11 3 2 84.44 102.74 14.90 o 13 3 2 17.42 32.58 10.95 o 15 3 2 21.83 17.16 10.74 o 17 3 2 68.70 85.96 17.75 o -18 4 2 159.21 173.27 24.90 o -16 4 2 47.59 48.77 12.64 o -14 4 2 956.44 887.06 34.84 o -12 4 2 157.87 139.54 14.97 o -10 4 2 1168.64 1150.10 25.97 o -8 4 2 561.50 492.18 16.07 o -6 4 2 867.90 906.59 21.31 o -4 4 2 12515.29 13343.58 123.06 o -2 4 2 3276.33 3070.44 33.81 o 0 4 2 52.78 53.05 5.67 o 2 4 2 1818.74 1708.20 24.41 o 4 4 2 5444.44 5535.96 49.27 o 6 4 2 3398.39 3527.01 45.26 o 8 4 2 167.10 184.97 11.53 o 10 4 2 528.94 516.84 24.40 o 12 4 2 328.66 322.94 21.57 o 14 4 2 143.12 139.03 18.71 o 16 4 2 46.53 62.96 20.68 o -17 5 2 1.68 2.67 10.51 o -15 5 2 19.10 19.20 11.23 o -13 5 2 539.96 467.46 29.59 o -11 5 2 758.73 759.82 23.11 o -9 5 2 68.20 73.46 9.01 o -7 5 2 172.47 177.41 11.14 o -5 5 2 2576.72 2848.01 36.92 o -3 5 2 3071.97 3252.09 50.72 o -1 5 2 13.33 20.45 5.04 o 1 5 2 1805.81 1784.89 29.02 o 3 5 2 4500.17 4840.08 82.00 o 5 5 2 2281.04 2330.45 41.16 o 7 5 2 37.51 52.71 8.77 o 9 5 2 93.72 99.58 10.85 o 11 5 2 1.54 9.76 9.30 o 13 5 2 27.73 38.40 13.40 o 15 5 2 48.70 43.89 18.59 o -16 6 2 0.30 6.76 10.66 o -14 6 2 61.23 109.27 19.92 o -12 6 2 86.01 104.78 15.46 o -10 6 2 123.88 98.95 13.18 o -8 6 2 964.48 960.30 31.81 o -6 6 2 69.11 70.86 11.50 o -4 6 2 807.90 807.16 33.18 o -2 6 2 1255.68 1287.13 25.07 o 0 6 2 123.21 135.42 8.70 o 2 6 2 1232.64 1202.81 34.13 o 4 6 2 29.71 37.63 8.86 o 6 6 2 187.89 182.89 14.69 o 8 6 2 34.00 35.41 9.89 o 10 6 2 384.55 410.11 21.07 o 12 6 2 742.12 703.23 45.72 o 14 6 2 49.11 46.43 19.08 o -15 7 2 0.60 6.89 10.14 o -13 7 2 165.35 182.26 21.92 o -11 7 2 4.83 4.25 6.99 o -9 7 2 0.33 -1.99 6.35 o -7 7 2 158.80 151.66 15.71 o -5 7 2 53.32 64.95 12.68 o -3 7 2 84.19 85.09 11.60 o -1 7 2 1.59 4.69 5.65 o 1 7 2 69.50 63.20 10.92 o 3 7 2 0.54 3.02 6.34 o 5 7 2 1537.44 1500.77 39.94 o 7 7 2 70.19 69.34 12.77 o 9 7 2 4.48 9.93 9.25 o 11 7 2 2.44 8.44 12.00 o 13 7 2 7.03 16.68 14.18 o -14 8 2 56.50 74.54 20.90 o -12 8 2 2.00 -2.74 7.68 o -10 8 2 11.62 16.25 9.58 o -8 8 2 499.41 470.43 25.62 o -6 8 2 17.94 23.97 9.07 o -4 8 2 621.09 559.79 25.11 o -2 8 2 1154.50 1054.81 40.40 o 0 8 2 144.75 168.07 18.48 o 2 8 2 223.59 224.79 18.62 o 4 8 2 165.75 113.32 14.95 o 6 8 2 58.66 35.24 11.89 o 8 8 2 25.74 18.80 10.61 o 10 8 2 0.50 -3.21 8.57 o 12 8 2 66.95 89.59 23.47 o -13 9 2 16.58 8.20 13.49 o -11 9 2 95.59 97.34 19.22 o -9 9 2 146.60 185.92 19.29 o -7 9 2 0.40 7.51 9.29 o -5 9 2 150.73 155.44 20.31 o -3 9 2 103.63 119.30 21.94 o -1 9 2 62.56 66.90 16.51 o 1 9 2 170.59 173.31 19.03 o 3 9 2 389.78 354.65 25.76 o 5 9 2 4.12 2.49 8.90 o 7 9 2 31.95 25.01 11.47 o 9 9 2 3.17 8.81 10.41 o 11 9 2 21.81 46.81 22.79 o -10 10 2 93.67 106.56 20.47 o -8 10 2 250.55 279.82 25.83 o -6 10 2 102.71 101.17 19.22 o -4 10 2 1.08 -1.42 9.20 o -2 10 2 0.16 3.12 8.84 o 0 10 2 457.29 458.22 31.13 o 2 10 2 58.66 72.15 19.59 o 4 10 2 856.37 759.24 47.67 o 6 10 2 95.05 106.66 23.93 o 8 10 2 120.88 153.59 28.53 o -7 11 2 4.87 9.78 11.63 o -5 11 2 66.59 95.60 19.89 o -3 11 2 127.22 131.49 22.68 o -1 11 2 407.12 395.03 35.52 o 1 11 2 51.07 43.78 17.25 o 3 11 2 48.96 37.18 17.02 o 5 11 2 2.75 8.17 13.55 o -2 12 2 9.09 -4.14 13.15 o 0 12 2 77.12 87.37 23.53 o -19 1 3 195.35 212.49 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