#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2214893.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2214893_Fobs loop_ _publ_author_name 'Thiruvalluvar, A.' 'Subramanyam, M.' 'Kalluraya, Balakrishna' 'Lingappa, B.' _publ_section_title ; 1-(5-Bromopyrimidin-2-yl)-3-phenyl-1H-pyrazole-4-carbaldehyde ; _journal_coeditor_code WN2161 _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3362 _journal_volume 63 _journal_year 2007 _space_group_IT_number 12 _symmetry_space_group_name_Hall '-C 2y' _symmetry_space_group_name_H-M 'C 1 2/m 1' _cell_angle_alpha 90.000 _cell_angle_beta 90.584 _cell_angle_gamma 90.000 _cell_length_a 15.1590 _cell_length_b 6.4761 _cell_length_c 13.1979 _exptl_crystal_F_000 656.00 _reflns_d_resolution_high 0.7100 _[local]_cod_data_source_file wn2161Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' LPA1 C14H9BR1N4O1 Z=4 C2/m' _shelx_refln_list_code 4 _shelx_f_calc_maximum 210.06 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z' '-x, -y, -z' 'x, -y, z' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 19650.44 38773.18 568.50 o 4 0 0 11791.89 15525.77 175.96 o 6 0 0 7540.41 7455.62 137.64 o 8 0 0 1050.15 911.19 22.02 o 10 0 0 1337.14 1244.01 57.19 o 12 0 0 1628.65 1664.40 110.58 o 14 0 0 242.16 248.56 25.25 o 16 0 0 448.36 579.72 53.78 o 18 0 0 236.73 297.49 42.44 o 20 0 0 88.79 86.27 8.15 o 1 1 0 5535.51 5791.24 67.68 o 3 1 0 44125.32 106915.40 3327.70 o 5 1 0 2222.86 1647.51 47.40 o 7 1 0 10222.58 10418.18 112.57 o 9 1 0 3426.52 2899.44 63.92 o 11 1 0 46.16 57.14 15.43 o 13 1 0 207.32 171.46 18.53 o 15 1 0 7.20 4.10 1.86 o 17 1 0 333.06 395.00 24.02 o 19 1 0 177.74 117.74 24.67 o 21 1 0 4.17 3.01 5.65 o 2 2 0 9994.26 11341.01 185.32 o 4 2 0 6494.15 6262.65 134.02 o 6 2 0 4723.79 4092.74 77.39 o 8 2 0 582.97 567.42 13.95 o 10 2 0 866.02 826.77 16.64 o 12 2 0 1174.84 1323.38 37.86 o 14 2 0 161.00 155.06 12.23 o 16 2 0 315.82 397.64 19.79 o 18 2 0 178.21 172.87 35.45 o 20 2 0 64.84 70.14 10.33 o 1 3 0 1936.62 1503.53 62.63 o 3 3 0 13439.63 16476.78 334.37 o 5 3 0 541.97 529.45 15.57 o 7 3 0 3913.50 3532.55 76.15 o 9 3 0 1516.85 1536.94 33.57 o 11 3 0 9.95 4.10 2.30 o 13 3 0 174.42 156.30 18.17 o 15 3 0 2.06 -0.55 1.61 o 17 3 0 178.15 194.06 10.48 o 19 3 0 89.68 70.04 5.53 o 0 4 0 35896.70 67650.54 2851.15 o 2 4 0 2357.03 2390.23 69.49 o 4 4 0 1582.51 1698.37 19.47 o 6 4 0 1421.44 1547.20 23.18 o 8 4 0 127.11 152.72 18.44 o 10 4 0 225.83 243.41 19.20 o 12 4 0 454.31 581.39 24.21 o 14 4 0 48.53 22.23 11.38 o 16 4 0 111.74 74.48 18.90 o 18 4 0 77.11 74.39 6.33 o 1 5 0 337.58 389.94 23.26 o 3 5 0 2424.00 3097.22 53.91 o 5 5 0 74.71 93.19 14.81 o 7 5 0 740.23 926.50 37.08 o 9 5 0 329.76 420.62 12.64 o 11 5 0 0.50 -0.02 1.27 o 13 5 0 125.35 58.35 15.97 o 15 5 0 2.35 1.56 3.75 o 17 5 0 54.13 65.75 5.34 o 0 6 0 5770.21 8461.28 289.49 o 2 6 0 452.18 640.21 28.83 o 4 6 0 226.06 291.50 16.38 o 6 6 0 238.51 332.03 23.91 o 8 6 0 13.78 13.20 3.08 o 10 6 0 18.77 3.28 2.31 o 12 6 0 96.71 42.26 10.86 o 14 6 0 7.06 13.49 5.56 o 16 6 0 20.92 45.52 8.07 o 1 7 0 31.38 12.73 5.87 o 3 7 0 299.96 428.74 21.68 o 5 7 0 9.53 1.84 2.45 o 7 7 0 75.95 33.08 6.51 o 9 7 0 35.80 31.45 6.72 o 11 7 0 2.70 5.91 5.36 o 13 7 0 60.23 64.10 8.81 o 0 8 0 819.57 1437.20 102.34 o 2 8 0 77.44 48.14 10.15 o 4 8 0 18.78 29.56 4.27 o 6 8 0 23.33 36.08 7.20 o 8 8 0 0.46 4.41 4.73 o 10 8 0 0.26 -5.39 8.46 o 1 9 0 1.66 -1.77 11.08 o 3 9 0 25.09 49.11 7.92 o -20 0 1 258.16 302.38 41.64 o -18 0 1 15.17 10.91 4.03 o -16 0 1 478.08 622.84 51.02 o -14 0 1 42.30 46.91 8.66 o -12 0 1 4590.99 4087.16 153.00 o -10 0 1 8251.03 7594.47 262.65 o -8 0 1 7.03 35.03 12.89 o -6 0 1 10017.98 10236.54 210.55 o -4 0 1 8164.14 8646.45 123.26 o -2 0 1 5366.07 5882.08 84.69 o 2 0 1 3661.54 3415.01 43.86 o 4 0 1 9111.14 10302.40 137.37 o 6 0 1 4503.08 3760.05 48.86 o 8 0 1 391.78 410.21 9.91 o 10 0 1 1248.00 1111.48 37.60 o 12 0 1 351.21 384.98 42.05 o 14 0 1 84.95 88.73 14.65 o 16 0 1 794.39 888.06 42.81 o 18 0 1 71.20 22.40 13.14 o 20 0 1 20.33 27.26 9.51 o -21 1 1 3.37 1.28 14.32 o -19 1 1 47.36 43.67 13.23 o -17 1 1 59.80 23.41 9.52 o -15 1 1 974.79 1078.52 30.20 o -13 1 1 3333.89 3529.73 65.73 o -11 1 1 39.06 66.51 20.79 o -9 1 1 4640.10 4036.01 96.79 o -7 1 1 1362.21 1086.63 17.54 o -5 1 1 6003.63 5731.69 76.42 o -3 1 1 23192.79 37906.29 439.51 o -1 1 1 4047.79 3582.09 35.17 o 1 1 1 3772.72 3465.89 58.83 o 3 1 1 349.15 256.14 8.09 o 5 1 1 432.71 423.60 15.74 o 7 1 1 5228.98 4236.56 67.75 o 9 1 1 1353.71 1205.72 17.31 o 11 1 1 1328.29 1321.10 31.50 o 13 1 1 3409.67 3551.65 103.32 o 15 1 1 115.03 112.45 10.55 o 17 1 1 48.45 11.63 5.12 o 19 1 1 510.62 511.34 23.07 o 21 1 1 30.13 38.71 8.10 o -20 2 1 186.71 164.92 22.41 o -18 2 1 12.29 9.05 3.19 o -16 2 1 325.51 399.26 24.04 o -14 2 1 22.73 12.36 5.45 o -12 2 1 3174.68 3255.33 84.36 o -10 2 1 5403.25 5083.36 53.54 o -8 2 1 3.56 2.40 0.78 o -6 2 1 6012.76 5051.59 64.03 o -4 2 1 4833.44 3826.62 73.37 o -2 2 1 2327.89 1800.03 67.04 o 0 2 1 148.24 87.50 4.92 o 2 2 1 1771.78 1176.37 41.47 o 4 2 1 5294.65 4381.77 89.94 o 6 2 1 2930.56 2302.08 41.28 o 8 2 1 245.00 225.45 5.76 o 10 2 1 874.22 924.42 34.33 o 12 2 1 244.81 265.40 17.83 o 14 2 1 70.31 66.45 7.13 o 16 2 1 554.21 641.81 36.27 o 18 2 1 50.91 35.92 7.51 o 20 2 1 13.00 15.89 5.55 o -19 3 1 17.43 32.87 5.45 o -17 3 1 17.50 19.22 5.67 o -15 3 1 558.60 639.37 22.89 o -13 3 1 1617.15 2133.37 73.10 o -11 3 1 6.67 4.12 1.48 o -9 3 1 2013.16 2011.95 46.97 o -7 3 1 564.69 472.88 6.14 o -5 3 1 1858.20 1698.36 54.71 o -3 3 1 7431.83 7138.44 182.97 o -1 3 1 1488.65 1252.17 43.30 o 1 3 1 1265.08 1082.22 34.84 o 3 3 1 416.33 341.01 10.76 o 5 3 1 96.60 110.86 5.43 o 7 3 1 2291.47 2002.43 47.50 o 9 3 1 609.44 603.04 18.53 o 11 3 1 737.46 753.50 28.47 o 13 3 1 1825.27 2318.34 67.96 o 15 3 1 55.26 35.04 11.49 o 17 3 1 22.88 16.40 5.73 o 19 3 1 277.71 235.76 16.14 o -18 4 1 6.79 16.22 4.58 o -16 4 1 103.41 36.16 6.67 o -14 4 1 2.47 -2.38 2.38 o -12 4 1 1132.22 1416.16 42.17 o -10 4 1 1680.06 2049.54 48.94 o -8 4 1 0.59 0.83 1.12 o -6 4 1 1579.65 1680.68 24.13 o -4 4 1 1377.20 1463.82 38.37 o -2 4 1 583.68 727.20 14.22 o 0 4 1 93.46 70.31 8.09 o 2 4 1 465.96 474.86 13.13 o 4 4 1 1330.25 1428.21 19.92 o 6 4 1 867.21 961.06 19.81 o 8 4 1 74.16 64.12 16.72 o 10 4 1 280.02 313.20 22.67 o 12 4 1 79.65 93.89 8.86 o 14 4 1 43.56 4.77 2.33 o 16 4 1 188.48 147.98 13.61 o 18 4 1 19.36 38.89 4.86 o -17 5 1 0.61 -2.45 4.37 o -15 5 1 197.71 180.00 19.76 o -13 5 1 419.03 606.12 20.50 o -11 5 1 0.88 0.75 1.44 o -9 5 1 446.11 524.11 20.83 o -7 5 1 82.87 68.01 7.17 o -5 5 1 314.13 404.15 21.41 o -3 5 1 1276.06 1635.11 37.41 o -1 5 1 296.06 346.75 31.48 o 1 5 1 227.13 256.94 21.97 o 3 5 1 113.63 147.38 24.94 o 5 5 1 11.47 15.27 3.05 o 7 5 1 507.35 602.18 23.96 o 9 5 1 114.68 130.61 13.02 o 11 5 1 270.29 266.24 17.26 o 13 5 1 567.50 812.53 48.81 o 15 5 1 13.68 18.70 5.16 o 17 5 1 4.85 12.00 4.82 o -16 6 1 15.54 42.51 14.47 o -14 6 1 0.67 13.81 5.09 o -12 6 1 238.99 302.46 10.80 o -10 6 1 288.64 410.51 16.54 o -8 6 1 0.02 -0.29 1.49 o -6 6 1 214.29 247.63 8.54 o -4 6 1 249.43 300.98 19.11 o -2 6 1 234.63 302.69 15.44 o 0 6 1 5.95 7.28 2.45 o 2 6 1 95.81 112.20 12.42 o 4 6 1 167.56 221.93 19.78 o 6 6 1 114.30 162.37 16.87 o 8 6 1 16.34 8.92 2.58 o 10 6 1 37.18 3.20 3.35 o 12 6 1 11.35 5.56 4.13 o 14 6 1 19.96 29.27 4.73 o 16 6 1 31.04 56.97 13.12 o -13 7 1 66.05 68.80 12.25 o -11 7 1 3.13 8.15 4.49 o -9 7 1 58.42 24.90 6.68 o -7 7 1 2.44 4.67 2.75 o -5 7 1 36.82 1.49 3.28 o -3 7 1 122.60 161.30 10.17 o -1 7 1 31.51 24.74 8.16 o 1 7 1 19.89 9.72 3.44 o 3 7 1 5.44 8.42 3.43 o 5 7 1 2.03 -0.36 2.46 o 7 7 1 59.90 20.83 7.83 o 9 7 1 5.96 11.98 4.26 o 11 7 1 76.10 54.09 9.73 o 13 7 1 115.42 115.34 30.54 o -10 8 1 30.30 52.86 9.05 o -8 8 1 0.00 1.18 4.59 o -6 8 1 15.50 24.54 4.28 o -4 8 1 34.15 46.53 5.80 o -2 8 1 87.33 35.99 4.16 o 0 8 1 14.87 20.58 4.41 o 2 8 1 12.53 16.69 3.68 o 4 8 1 9.39 19.59 4.15 o 6 8 1 5.63 30.86 6.27 o 8 8 1 3.41 8.57 4.64 o 10 8 1 1.95 26.61 11.50 o -3 9 1 5.71 16.78 7.20 o -1 9 1 1.76 2.72 9.02 o 1 9 1 0.65 0.70 7.77 o 3 9 1 0.34 -4.24 7.10 o -20 0 2 58.39 40.81 25.24 o -18 0 2 1.47 -0.68 4.48 o -16 0 2 1748.18 2348.97 125.03 o -14 0 2 1583.99 1672.18 89.69 o -12 0 2 1133.83 1209.79 84.24 o -10 0 2 4877.37 4225.54 146.43 o -8 0 2 1440.17 1208.09 40.17 o -6 0 2 4631.53 3534.71 87.18 o -4 0 2 667.98 534.16 19.21 o -2 0 2 7900.83 9587.56 274.77 o 0 0 2 110.92 134.21 7.48 o 2 0 2 5542.96 5610.29 63.60 o 4 0 2 5636.03 4758.02 94.63 o 6 0 2 9521.79 9955.39 196.29 o 8 0 2 1611.36 1534.41 60.50 o 10 0 2 3785.78 3169.49 89.78 o 12 0 2 53.03 39.82 12.81 o 14 0 2 657.21 755.33 21.74 o 16 0 2 450.13 479.19 38.46 o 18 0 2 12.66 7.30 4.57 o 20 0 2 24.38 22.78 6.58 o -21 1 2 0.99 4.92 13.87 o -19 1 2 318.16 386.09 43.83 o -17 1 2 234.65 197.43 14.81 o -15 1 2 477.18 509.34 25.49 o -13 1 2 5226.56 5648.33 146.26 o -11 1 2 987.12 997.64 35.05 o -9 1 2 3665.06 3175.22 70.90 o -7 1 2 7055.61 6844.91 118.11 o -5 1 2 6485.14 6071.47 101.79 o -3 1 2 6795.89 6520.63 74.91 o -1 1 2 9849.36 11856.85 202.59 o 1 1 2 2434.73 1703.73 27.23 o 3 1 2 8047.95 8172.67 90.13 o 5 1 2 4437.19 3867.89 52.62 o 7 1 2 6304.30 5584.14 63.89 o 9 1 2 6043.57 5862.79 93.18 o 11 1 2 707.09 695.91 31.16 o 13 1 2 2134.28 2337.17 48.59 o 15 1 2 43.05 24.87 6.68 o 17 1 2 65.41 16.51 5.58 o 19 1 2 14.32 19.22 4.72 o 21 1 2 36.94 76.18 7.01 o -20 2 2 37.85 51.63 4.44 o -18 2 2 1.59 -5.60 6.38 o -16 2 2 1238.51 1657.49 57.39 o -14 2 2 1167.37 1309.04 28.15 o -12 2 2 740.32 774.77 27.67 o -10 2 2 3329.72 3109.11 80.67 o -8 2 2 799.25 767.32 15.85 o -6 2 2 2935.44 2160.12 50.02 o -4 2 2 455.31 417.71 14.83 o -2 2 2 4502.98 3653.47 82.09 o 0 2 2 291.38 212.75 13.98 o 2 2 2 2664.02 2064.86 60.19 o 4 2 2 3380.86 2341.51 42.46 o 6 2 2 5932.18 5227.11 109.55 o 8 2 2 930.05 980.50 30.62 o 10 2 2 2583.18 2504.05 49.37 o 12 2 2 57.93 52.57 6.37 o 14 2 2 482.38 566.95 19.77 o 16 2 2 298.05 275.60 13.15 o 18 2 2 11.68 11.17 2.97 o 20 2 2 14.52 21.95 5.61 o -19 3 2 168.58 109.56 12.08 o -17 3 2 128.13 60.29 13.31 o -15 3 2 209.67 225.90 9.29 o -13 3 2 2625.85 3368.05 114.11 o -11 3 2 569.24 592.83 30.65 o -9 3 2 1582.69 1766.80 56.54 o -7 3 2 3055.59 2846.00 54.02 o -5 3 2 2086.99 2022.09 48.93 o -3 3 2 2851.93 2229.90 94.03 o -1 3 2 2803.37 2195.57 91.59 o 1 3 2 1095.07 922.47 29.19 o 3 3 2 3287.08 2585.36 67.86 o 5 3 2 1406.55 1418.50 31.34 o 7 3 2 2960.91 2861.58 71.47 o 9 3 2 2869.76 2950.40 68.84 o 11 3 2 395.76 418.52 25.46 o 13 3 2 989.03 1181.88 33.75 o 15 3 2 14.86 11.81 4.19 o 17 3 2 26.12 32.16 6.59 o 19 3 2 3.28 5.75 3.99 o -18 4 2 1.91 8.55 5.24 o -16 4 2 454.64 582.78 21.53 o -14 4 2 493.01 590.47 34.92 o -12 4 2 210.37 230.92 15.51 o -10 4 2 1149.56 1381.63 33.32 o -8 4 2 164.47 179.92 17.40 o -6 4 2 770.50 836.00 19.71 o -4 4 2 141.73 152.92 12.16 o -2 4 2 1213.51 1300.60 17.73 o 0 4 2 285.83 248.48 12.67 o 2 4 2 579.29 648.68 25.48 o 4 4 2 968.58 925.03 19.14 o 6 4 2 1768.72 1946.41 40.18 o 8 4 2 243.84 288.74 21.91 o 10 4 2 861.60 978.39 34.57 o 12 4 2 62.78 45.62 6.67 o 14 4 2 196.68 210.27 7.67 o 16 4 2 86.00 44.09 13.88 o 18 4 2 8.14 9.59 4.94 o -17 5 2 41.87 54.71 8.71 o -15 5 2 39.93 19.09 4.75 o -13 5 2 729.82 1142.52 41.72 o -11 5 2 217.53 217.41 10.95 o -9 5 2 325.00 457.30 18.71 o -7 5 2 737.03 988.17 34.30 o -5 5 2 360.74 405.54 17.17 o -3 5 2 628.08 762.02 37.52 o -1 5 2 597.94 758.83 27.68 o 1 5 2 227.86 251.36 20.12 o 3 5 2 732.86 909.95 30.30 o 5 5 2 268.06 333.32 23.97 o 7 5 2 795.83 1044.51 36.29 o 9 5 2 792.50 1019.30 30.74 o 11 5 2 168.02 170.41 12.98 o 13 5 2 218.71 224.46 21.11 o 15 5 2 1.57 8.14 3.79 o 17 5 2 3.54 -3.37 6.59 o -14 6 2 131.58 61.03 12.05 o -12 6 2 25.30 10.79 4.03 o -10 6 2 224.57 288.87 9.69 o -8 6 2 14.59 7.23 3.91 o -6 6 2 71.60 106.84 9.93 o -4 6 2 9.00 9.67 3.85 o -2 6 2 223.70 303.60 22.43 o 0 6 2 46.38 68.35 4.09 o 2 6 2 87.86 117.07 12.85 o 4 6 2 148.56 149.65 14.01 o 6 6 2 301.99 406.64 23.05 o 8 6 2 46.54 35.35 13.05 o 10 6 2 146.69 128.04 6.99 o 12 6 2 42.35 9.37 5.43 o 14 6 2 48.32 47.40 5.28 o -13 7 2 124.88 104.56 9.82 o -11 7 2 59.39 46.80 9.17 o -9 7 2 32.44 37.67 9.20 o -7 7 2 110.10 77.52 10.69 o -5 7 2 41.92 5.84 4.57 o -3 7 2 70.30 47.68 13.85 o -1 7 2 96.48 98.30 10.11 o 1 7 2 19.51 12.23 4.82 o 3 7 2 89.18 92.23 17.37 o 5 7 2 39.41 2.78 3.76 o 7 7 2 132.28 147.55 7.39 o 9 7 2 152.87 146.40 11.39 o 11 7 2 57.27 43.76 7.09 o 13 7 2 22.65 34.66 9.68 o -8 8 2 0.24 -2.71 5.26 o -6 8 2 0.75 6.51 3.90 o -4 8 2 1.87 2.89 3.95 o -2 8 2 33.79 33.86 6.06 o 0 8 2 1.53 7.57 3.94 o 2 8 2 7.61 13.45 5.25 o 4 8 2 11.89 20.88 5.11 o 6 8 2 31.42 32.88 6.06 o 8 8 2 7.32 4.87 6.05 o -1 9 2 9.95 17.26 6.40 o 1 9 2 0.56 5.68 5.38 o -20 0 3 7.16 14.42 8.66 o -18 0 3 432.23 506.23 25.48 o -16 0 3 171.48 166.19 10.63 o -14 0 3 3.99 1.00 1.73 o -12 0 3 221.94 281.99 32.07 o -10 0 3 785.86 752.81 30.37 o -8 0 3 1323.99 1307.03 38.53 o -6 0 3 13844.23 16655.83 269.92 o -4 0 3 5516.22 4530.78 106.81 o -2 0 3 317.96 210.52 11.70 o 0 0 3 7060.54 7305.39 446.37 o 2 0 3 86.81 86.81 9.35 o 4 0 3 6981.46 6630.37 115.53 o 6 0 3 6106.42 5186.74 97.13 o 8 0 3 801.28 748.04 22.40 o 10 0 3 5014.10 4319.13 95.22 o 12 0 3 2866.14 2538.81 119.78 o 14 0 3 487.01 609.11 27.76 o 16 0 3 415.99 564.77 15.61 o 18 0 3 35.56 12.09 5.18 o 20 0 3 323.59 275.57 17.18 o -19 1 3 157.43 117.63 20.42 o -17 1 3 17.62 10.79 3.72 o -15 1 3 387.18 466.00 19.29 o -13 1 3 94.39 109.00 13.16 o -11 1 3 388.37 305.04 20.34 o -9 1 3 1164.00 1048.23 32.90 o -7 1 3 2946.72 2331.55 51.99 o -5 1 3 78.91 123.81 9.34 o -3 1 3 10328.35 10699.30 235.67 o -1 1 3 1055.11 677.09 18.46 o 1 1 3 5326.55 4704.69 75.45 o 3 1 3 10150.82 11172.15 166.63 o 5 1 3 1566.82 1210.11 30.56 o 7 1 3 131.16 82.51 7.18 o 9 1 3 443.86 366.13 18.70 o 11 1 3 937.07 934.89 26.21 o 13 1 3 807.44 933.28 27.88 o 15 1 3 407.38 390.68 13.38 o 17 1 3 368.57 356.61 17.32 o 19 1 3 263.33 233.68 11.13 o -20 2 3 4.41 -8.04 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