#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/51/2215185.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2215185_Fobs loop_ _publ_author_name 'Hu, Sheng-Li' 'Zhang, Jian-Min' 'Yan, Gang' 'Wang, Shuai' _publ_section_title ; rac-12a,11b-Diphenyl-1,2,3,4,5,11-hexahydro-2,3,4a,5a,10a,11a-hexaazabenz[f]indeno[2,1,8-ija]naphth[2,3-f]azulene-1,4,10-trione chloroform solvate ; _journal_coeditor_code KP2109 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3909 _journal_volume 63 _journal_year 2007 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 94.652 _cell_angle_gamma 90.000 _cell_length_a 17.3315 _cell_length_b 8.4507 _cell_length_c 17.7874 _exptl_crystal_F_000 1176.00 _reflns_d_resolution_high 0.8107 _[local]_cod_data_source_file kp2109Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 051122dm in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 185.01 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 68.24 102.07 13.48 o 4 0 0 1482.14 1897.03 111.16 o 6 0 0 21542.82 23906.30 969.36 o 8 0 0 233.80 253.36 7.86 o 10 0 0 2600.98 2710.89 46.13 o 12 0 0 35.35 31.22 3.65 o 14 0 0 251.56 367.94 16.46 o 16 0 0 1682.57 1497.07 36.99 o 18 0 0 0.75 0.47 4.92 o 20 0 0 37.40 64.82 16.94 o 1 1 0 99.39 107.09 2.59 o 2 1 0 469.03 491.74 18.63 o 3 1 0 4174.59 4760.76 203.21 o 4 1 0 2522.71 2942.62 100.47 o 5 1 0 71.98 96.71 2.94 o 6 1 0 224.46 387.89 21.28 o 7 1 0 827.00 986.59 50.84 o 8 1 0 2946.78 3218.33 51.11 o 9 1 0 3176.81 3825.03 62.81 o 10 1 0 0.56 14.01 1.97 o 11 1 0 1044.59 1144.28 31.68 o 12 1 0 501.08 530.92 12.50 o 13 1 0 56.32 60.89 4.37 o 14 1 0 124.06 118.51 5.71 o 15 1 0 19.01 32.69 3.98 o 16 1 0 24.04 17.43 4.63 o 17 1 0 16.53 15.32 4.74 o 18 1 0 1.84 5.90 4.16 o 19 1 0 3.45 0.42 4.14 o 20 1 0 11.40 13.00 5.30 o 21 1 0 29.82 31.76 6.63 o 1 2 0 960.01 608.10 129.03 o 2 2 0 13416.98 12861.29 316.07 o 4 2 0 36.96 31.63 1.32 o 5 2 0 3350.65 3152.03 106.85 o 6 2 0 82.64 85.38 2.87 o 7 2 0 15763.00 18079.57 717.71 o 8 2 0 689.33 693.63 25.99 o 9 2 0 4.45 17.93 1.59 o 10 2 0 1.00 0.87 1.48 o 11 2 0 64.29 77.81 5.01 o 12 2 0 657.35 668.33 21.62 o 13 2 0 89.24 108.18 6.20 o 14 2 0 191.32 156.51 7.73 o 15 2 0 1603.18 1567.77 48.39 o 16 2 0 303.52 319.41 10.62 o 17 2 0 113.44 95.58 8.70 o 18 2 0 232.08 237.68 11.48 o 19 2 0 2.31 0.00 3.92 o 20 2 0 28.92 46.88 7.14 o 1 3 0 9.12 6.11 2.34 o 2 3 0 119.83 87.78 2.46 o 3 3 0 1505.58 1384.36 30.62 o 4 3 0 2798.41 2457.57 74.05 o 5 3 0 3.73 1.17 0.97 o 6 3 0 1487.38 1351.95 49.66 o 7 3 0 1832.85 1768.33 58.90 o 8 3 0 186.63 213.73 16.22 o 9 3 0 963.38 1040.27 50.16 o 10 3 0 300.97 331.55 19.74 o 11 3 0 1077.95 983.60 50.31 o 12 3 0 230.28 212.49 9.60 o 13 3 0 14.18 13.23 3.20 o 14 3 0 92.46 94.44 5.75 o 15 3 0 40.63 23.33 3.90 o 16 3 0 27.40 23.80 4.15 o 17 3 0 220.73 241.89 9.17 o 18 3 0 3.29 8.79 4.05 o 19 3 0 4.48 0.90 4.23 o 20 3 0 0.31 5.19 4.61 o 0 4 0 192.17 124.38 6.77 o 1 4 0 946.47 812.55 20.75 o 2 4 0 330.55 338.65 6.56 o 3 4 0 6128.24 5839.09 128.28 o 4 4 0 1730.06 1768.62 47.35 o 5 4 0 158.50 122.39 3.44 o 6 4 0 115.73 97.72 4.42 o 7 4 0 1032.42 1185.29 56.28 o 8 4 0 469.13 433.96 23.25 o 9 4 0 342.22 296.65 15.37 o 10 4 0 181.77 207.40 8.99 o 11 4 0 151.29 174.18 7.70 o 12 4 0 58.73 56.13 4.71 o 13 4 0 19.49 18.37 3.56 o 14 4 0 55.56 41.70 4.71 o 15 4 0 233.20 231.13 14.92 o 16 4 0 196.46 190.56 10.47 o 17 4 0 35.37 51.79 5.62 o 18 4 0 0.11 0.00 3.34 o 19 4 0 0.20 1.30 4.09 o 1 5 0 35.29 14.04 3.29 o 2 5 0 31.58 27.14 2.29 o 3 5 0 232.29 223.52 4.85 o 4 5 0 235.50 220.67 7.70 o 5 5 0 28.13 29.55 2.22 o 6 5 0 1104.12 1143.55 67.82 o 7 5 0 30.98 30.08 3.27 o 8 5 0 69.99 72.98 4.66 o 9 5 0 452.50 437.60 43.29 o 10 5 0 59.83 41.80 4.15 o 11 5 0 43.71 45.05 4.29 o 12 5 0 254.96 222.18 11.64 o 13 5 0 27.43 37.74 4.58 o 14 5 0 38.39 34.30 4.66 o 15 5 0 18.29 20.20 4.14 o 16 5 0 1.91 5.71 3.34 o 17 5 0 4.77 2.07 3.62 o 18 5 0 20.20 22.97 5.31 o 0 6 0 1600.94 1641.88 47.86 o 1 6 0 1414.47 1279.38 81.80 o 2 6 0 24.91 23.45 2.38 o 3 6 0 118.66 88.83 3.68 o 4 6 0 245.74 229.89 6.06 o 5 6 0 282.01 296.74 14.59 o 6 6 0 207.74 206.42 11.78 o 7 6 0 63.68 62.99 4.56 o 8 6 0 414.63 376.78 18.12 o 9 6 0 4.37 2.09 2.33 o 10 6 0 178.45 193.41 11.03 o 11 6 0 222.63 208.48 12.81 o 12 6 0 46.32 54.87 5.18 o 13 6 0 10.36 12.29 3.57 o 14 6 0 1.31 1.31 3.45 o 15 6 0 52.72 60.32 7.58 o 16 6 0 0.03 0.63 4.12 o 17 6 0 2.45 1.41 4.65 o 1 7 0 9.67 8.24 1.99 o 2 7 0 19.68 24.99 2.85 o 3 7 0 24.44 24.09 3.07 o 4 7 0 339.40 294.23 8.29 o 5 7 0 210.04 192.35 7.04 o 6 7 0 204.59 218.87 11.27 o 7 7 0 103.51 112.50 12.32 o 8 7 0 147.36 137.47 9.06 o 9 7 0 0.33 0.00 2.59 o 10 7 0 100.22 95.28 6.93 o 11 7 0 0.03 0.74 3.63 o 12 7 0 91.71 84.55 8.16 o 13 7 0 6.00 10.48 4.61 o 14 7 0 16.54 17.72 5.28 o 15 7 0 1.43 0.00 3.85 o 0 8 0 25.79 12.24 5.46 o 1 8 0 22.08 22.14 3.29 o 2 8 0 211.19 219.84 7.67 o 3 8 0 45.48 65.41 5.12 o 4 8 0 18.28 20.43 3.59 o 5 8 0 12.75 18.74 3.86 o 6 8 0 0.89 1.94 4.57 o 7 8 0 150.69 149.12 9.01 o 8 8 0 589.90 603.03 20.56 o 9 8 0 33.48 30.87 5.67 o 10 8 0 6.33 2.95 3.80 o 11 8 0 42.03 43.80 6.91 o 12 8 0 13.05 8.71 4.30 o 13 8 0 2.17 2.01 4.15 o 1 9 0 3.45 0.00 4.22 o 2 9 0 207.66 203.86 13.98 o 3 9 0 67.30 65.70 7.84 o 4 9 0 10.55 12.30 4.35 o 5 9 0 16.19 20.18 5.00 o 6 9 0 76.63 77.32 7.89 o 7 9 0 22.16 27.07 5.51 o 8 9 0 7.15 7.44 4.30 o 9 9 0 2.93 0.00 3.75 o 10 9 0 97.63 117.02 9.96 o 2 10 0 0.25 0.00 6.73 o 3 10 0 40.04 55.31 10.39 o 4 10 0 103.61 136.24 14.33 o 5 10 0 21.45 30.08 8.68 o 6 10 0 7.21 10.57 5.83 o -21 0 1 25.70 34.75 9.69 o -19 0 1 21.53 36.18 8.89 o -17 0 1 28.54 64.84 9.86 o -15 0 1 76.96 73.02 9.60 o -13 0 1 2531.77 2781.35 47.24 o -11 0 1 373.71 362.44 8.75 o -9 0 1 2153.37 2631.23 47.64 o -7 0 1 9822.86 10755.58 230.05 o -5 0 1 2412.80 3078.88 84.34 o -3 0 1 70.94 107.46 6.73 o 3 0 1 727.05 547.55 54.32 o 5 0 1 18441.41 20024.14 1544.15 o 7 0 1 669.38 625.64 44.51 o 9 0 1 607.11 826.21 41.24 o 11 0 1 1745.57 1899.53 63.31 o 13 0 1 149.67 169.73 7.33 o 15 0 1 1771.93 1751.53 36.49 o 17 0 1 124.40 145.88 13.11 o 19 0 1 34.94 58.27 10.78 o 21 0 1 2.86 14.20 7.93 o -21 1 1 31.62 43.76 7.23 o -20 1 1 37.53 56.02 7.54 o -19 1 1 2.71 4.76 4.24 o -18 1 1 0.02 0.00 3.62 o -17 1 1 28.69 41.23 5.95 o -16 1 1 164.38 159.27 8.83 o -15 1 1 13.69 8.01 2.97 o -14 1 1 186.48 159.04 6.36 o -13 1 1 70.55 72.00 4.56 o -12 1 1 1.24 1.32 1.62 o -11 1 1 759.25 850.52 28.23 o -10 1 1 43.48 38.91 5.59 o -9 1 1 1226.49 1372.50 20.53 o -8 1 1 1527.49 1964.36 58.32 o -7 1 1 244.32 371.17 12.79 o -6 1 1 658.49 577.48 19.17 o -5 1 1 4010.44 4025.06 125.19 o -4 1 1 1180.36 1378.93 52.34 o -3 1 1 1672.38 2314.42 100.47 o -2 1 1 5992.40 6615.58 261.27 o -1 1 1 2838.92 2938.67 57.53 o 0 1 1 438.42 474.39 9.01 o 1 1 1 19013.61 17538.03 748.03 o 2 1 1 10007.14 10411.22 456.70 o 3 1 1 18631.37 19543.57 1009.07 o 4 1 1 114.93 106.08 6.07 o 5 1 1 1313.35 1638.97 56.85 o 6 1 1 419.09 500.92 15.78 o 7 1 1 1101.78 1157.85 36.19 o 8 1 1 2409.29 2729.52 72.47 o 9 1 1 155.85 247.97 14.12 o 10 1 1 961.25 1119.32 28.03 o 11 1 1 87.35 89.22 3.37 o 12 1 1 374.83 354.71 8.11 o 13 1 1 158.26 132.92 5.69 o 14 1 1 719.75 747.66 15.87 o 15 1 1 2.55 0.00 2.78 o 16 1 1 29.10 20.20 4.82 o 17 1 1 17.06 15.85 4.74 o 18 1 1 27.56 28.15 5.77 o 19 1 1 0.05 1.88 4.38 o 20 1 1 29.17 26.42 6.11 o 21 1 1 3.85 7.98 5.07 o -20 2 1 0.11 0.26 4.25 o -19 2 1 16.96 19.02 5.54 o -18 2 1 35.70 33.06 5.72 o -17 2 1 31.47 21.04 5.02 o -16 2 1 506.83 504.03 18.12 o -15 2 1 3.14 3.05 2.45 o -14 2 1 77.39 67.09 4.93 o -13 2 1 34.95 30.63 4.20 o -12 2 1 26.55 16.78 2.96 o -11 2 1 753.73 738.48 30.13 o -10 2 1 66.53 81.69 3.12 o -9 2 1 264.41 342.53 13.49 o -8 2 1 381.31 334.94 15.04 o -7 2 1 2469.22 3079.55 125.52 o -6 2 1 1648.36 1557.46 61.45 o -5 2 1 173.68 159.90 4.26 o -4 2 1 7198.35 6981.08 235.30 o -3 2 1 2806.44 2723.48 88.87 o -2 2 1 1620.45 1553.04 39.46 o -1 2 1 6773.53 6581.26 78.05 o 0 2 1 2662.41 2853.53 38.40 o 1 2 1 2281.29 2071.69 49.92 o 2 2 1 9647.05 9484.72 284.49 o 3 2 1 2204.14 2079.45 58.18 o 4 2 1 10589.80 10652.95 466.98 o 5 2 1 4306.30 4583.50 205.23 o 6 2 1 1954.91 1886.32 91.94 o 7 2 1 2.06 10.25 1.89 o 8 2 1 242.37 268.76 12.66 o 9 2 1 149.37 148.70 5.36 o 10 2 1 2004.77 2269.88 80.03 o 11 2 1 444.54 427.86 25.70 o 12 2 1 16.98 11.85 2.68 o 13 2 1 1351.40 1337.24 69.45 o 14 2 1 173.25 127.54 15.87 o 15 2 1 399.76 384.31 11.13 o 16 2 1 149.28 112.83 6.46 o 17 2 1 340.99 343.37 18.73 o 18 2 1 0.07 0.93 4.12 o 19 2 1 74.84 77.59 8.59 o 20 2 1 33.38 30.97 6.24 o -20 3 1 0.27 5.22 4.72 o -19 3 1 14.75 20.59 5.63 o -18 3 1 18.44 21.91 4.46 o -17 3 1 0.88 0.00 3.05 o -16 3 1 169.56 140.93 7.15 o -15 3 1 12.54 17.15 3.66 o -14 3 1 255.70 257.06 8.80 o -13 3 1 17.30 21.78 3.46 o -12 3 1 32.61 27.29 3.48 o -11 3 1 8.75 7.41 2.45 o -10 3 1 514.47 472.43 26.29 o -9 3 1 42.08 48.00 3.53 o -8 3 1 187.68 144.26 5.90 o -7 3 1 3675.78 4100.89 153.41 o -6 3 1 206.27 177.37 6.75 o -5 3 1 1509.11 1359.56 58.51 o -4 3 1 3934.77 3853.22 116.92 o -3 3 1 22.05 22.04 1.49 o -2 3 1 9.84 20.21 1.43 o -1 3 1 976.97 1099.14 17.45 o 0 3 1 699.08 582.81 8.97 o 1 3 1 1638.39 1594.73 31.00 o 2 3 1 5537.64 4725.18 221.40 o 3 3 1 0.41 1.75 0.81 o 4 3 1 301.34 287.44 10.16 o 5 3 1 52.07 51.96 2.49 o 6 3 1 4.80 23.37 12.98 o 7 3 1 0.71 0.53 1.44 o 8 3 1 434.28 469.23 27.49 o 9 3 1 732.63 851.12 45.00 o 10 3 1 2102.68 1995.85 138.73 o 11 3 1 133.19 147.32 7.70 o 12 3 1 121.66 125.40 5.87 o 13 3 1 548.84 471.10 18.86 o 14 3 1 87.19 82.05 5.59 o 15 3 1 10.75 9.28 3.11 o 16 3 1 66.17 55.26 5.32 o 17 3 1 31.34 32.54 4.77 o 18 3 1 28.41 14.91 4.60 o 19 3 1 33.85 47.43 7.12 o 20 3 1 6.17 8.29 4.82 o -19 4 1 14.82 21.08 5.08 o -18 4 1 39.18 36.04 5.18 o -17 4 1 1.74 2.91 3.47 o -16 4 1 62.55 59.91 5.71 o -15 4 1 35.48 45.55 4.99 o -14 4 1 61.04 56.93 5.20 o -13 4 1 11.94 1.85 2.58 o -12 4 1 449.10 421.90 21.53 o -11 4 1 568.38 590.03 35.36 o -10 4 1 592.01 633.92 37.47 o -9 4 1 74.46 71.42 6.16 o -8 4 1 47.56 40.77 3.35 o -7 4 1 277.58 328.49 12.20 o -6 4 1 236.47 286.44 14.59 o -5 4 1 559.11 524.07 18.98 o -4 4 1 337.79 305.81 9.18 o -3 4 1 20.16 13.18 1.50 o -2 4 1 287.90 202.88 5.30 o -1 4 1 712.46 538.31 70.41 o 0 4 1 1056.95 831.35 100.20 o 1 4 1 1597.99 1144.68 166.46 o 2 4 1 3792.36 3622.20 164.08 o 3 4 1 3179.60 3085.21 63.47 o 4 4 1 1777.23 1771.33 46.46 o 5 4 1 455.91 511.78 15.37 o 6 4 1 438.45 493.03 15.94 o 7 4 1 343.99 366.74 16.85 o 8 4 1 114.84 110.65 6.08 o 9 4 1 16.98 23.86 3.12 o 10 4 1 21.85 24.03 3.25 o 11 4 1 2.34 0.96 2.49 o 12 4 1 31.75 40.20 4.29 o 13 4 1 244.56 208.54 11.22 o 14 4 1 404.02 361.65 21.07 o 15 4 1 21.02 18.80 4.12 o 16 4 1 0.31 0.00 3.21 o 17 4 1 4.47 2.93 3.56 o 18 4 1 0.00 0.00 3.39 o 19 4 1 13.80 14.76 4.91 o -18 5 1 0.64 0.00 4.46 o -17 5 1 1.67 0.00 4.14 o -16 5 1 9.96 12.45 4.26 o -15 5 1 43.33 40.51 5.64 o -14 5 1 5.24 4.01 3.01 o -13 5 1 819.04 789.59 45.04 o -12 5 1 27.10 34.20 4.21 o -11 5 1 38.59 47.62 5.24 o -10 5 1 6.77 2.24 2.39 o -9 5 1 783.06 745.96 50.33 o -8 5 1 42.56 41.51 3.79 o -7 5 1 1127.48 1137.14 67.48 o -6 5 1 212.37 203.50 11.58 o -5 5 1 364.37 321.24 9.31 o -4 5 1 0.21 0.98 1.19 o -3 5 1 178.12 213.61 5.42 o -2 5 1 248.96 254.54 5.54 o -1 5 1 137.97 106.96 13.26 o 0 5 1 7.56 4.55 1.12 o 1 5 1 1158.78 1015.77 153.38 o 2 5 1 1509.33 1277.92 57.92 o 3 5 1 125.77 133.15 3.89 o 4 5 1 274.68 267.58 6.34 o 5 5 1 9.12 7.76 1.51 o 6 5 1 33.30 23.21 2.88 o 7 5 1 71.88 58.96 4.11 o 8 5 1 11.40 11.44 2.85 o 9 5 1 4.57 4.10 2.36 o 10 5 1 26.35 21.60 3.40 o 11 5 1 0.26 1.63 2.71 o 12 5 1 41.48 44.57 4.60 o 13 5 1 0.10 0.00 2.57 o 14 5 1 52.30 48.99 5.22 o 15 5 1 14.01 8.93 3.69 o 16 5 1 0.15 2.23 3.20 o 17 5 1 130.43 146.94 8.40 o 18 5 1 33.73 51.53 6.01 o -17 6 1 9.91 16.22 6.03 o -16 6 1 0.01 5.11 4.51 o -15 6 1 0.16 4.38 4.20 o -14 6 1 80.67 70.28 7.72 o -13 6 1 0.48 3.33 3.62 o -12 6 1 44.29 42.70 6.06 o -11 6 1 6.01 5.30 3.02 o -10 6 1 8.75 9.20 2.97 o -9 6 1 75.39 72.23 5.04 o -8 6 1 106.84 132.55 6.67 o -7 6 1 164.13 159.33 6.23 o -6 6 1 27.21 31.23 3.78 o -5 6 1 16.55 13.85 2.76 o -4 6 1 213.43 202.13 6.83 o -3 6 1 0.01 0.00 1.24 o -2 6 1 257.46 261.91 6.27 o -1 6 1 739.02 708.32 10.78 o 0 6 1 49.07 31.21 4.62 o 1 6 1 39.17 19.79 6.22 o 2 6 1 23.06 25.51 2.68 o 3 6 1 88.82 98.17 3.85 o 4 6 1 462.18 458.57 13.61 o 5 6 1 0.17 0.12 1.81 o 6 6 1 7.31 7.70 2.42 o 7 6 1 517.48 485.78 18.19 o 8 6 1 31.60 37.46 4.06 o 9 6 1 136.78 150.11 7.48 o 10 6 1 703.75 714.91 44.34 o 11 6 1 781.65 767.07 38.30 o 12 6 1 3.96 1.61 2.87 o 13 6 1 53.06 49.07 5.22 o 14 6 1 122.04 122.66 7.47 o 15 6 1 0.06 0.00 3.30 o 16 6 1 1.14 4.12 3.95 o 17 6 1 84.62 92.79 9.48 o -15 7 1 24.65 17.24 5.73 o -14 7 1 40.95 51.33 7.44 o -13 7 1 3.92 5.75 4.06 o -12 7 1 0.34 0.00 3.21 o -11 7 1 84.01 75.13 7.57 o -10 7 1 28.04 21.63 5.54 o -9 7 1 9.04 8.95 3.81 o -8 7 1 77.66 75.55 6.93 o -7 7 1 0.30 0.41 2.42 o -6 7 1 164.18 156.44 6.54 o -5 7 1 83.23 101.05 5.46 o -4 7 1 94.00 86.48 7.12 o -3 7 1 42.35 42.20 3.70 o -2 7 1 24.73 25.84 2.79 o -1 7 1 0.63 0.00 1.41 o 0 7 1 8.52 8.20 1.79 o 1 7 1 62.40 40.45 12.02 o 2 7 1 62.23 71.09 7.54 o 3 7 1 749.46 746.56 19.20 o 4 7 1 106.48 121.37 5.80 o 5 7 1 0.88 0.64 2.31 o 6 7 1 2.54 0.00 2.36 o 7 7 1 549.15 542.33 27.21 o 8 7 1 21.36 26.55 4.06 o 9 7 1 243.35 212.95 12.51 o 10 7 1 2.63 2.18 3.05 o 11 7 1 1.45 0.00 2.60 o 12 7 1 23.73 21.98 4.81 o 13 7 1 15.03 17.23 4.97 o 14 7 1 6.35 11.05 5.03 o 15 7 1 24.96 32.47 6.58 o -13 8 1 0.90 5.37 4.56 o -12 8 1 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