#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2216180.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2216180_Fobs loop_ _publ_author_name 'Li, Xiu-Ling' 'Lu, Zai-Sheng' 'Niu, De-Zhong' _publ_section_title ; Bis(4-carboxypyridinium) aquapentakis(isothiocyanato-\kN)iron(III) bis(pyridinium-4-carboxylate) ; _journal_coeditor_code ZL2066 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m2640 _journal_volume 63 _journal_year 2007 _space_group_IT_number 62 _symmetry_space_group_name_Hall '-P 2ac 2n' _symmetry_space_group_name_H-M 'P n m a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 14.8713 _cell_length_b 21.0882 _cell_length_c 11.9741 _exptl_crystal_F_000 1756.00 _reflns_d_resolution_high 0.8409 _[local]_cod_data_source_file zl2066Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 62 in Pnma' _shelx_refln_list_code 4 _shelx_f_calc_maximum 621.37 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z' 'x+1/2, -y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z' '-x-1/2, y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 2135.79 2876.12 43.37 o 4 0 0 12319.55 13583.82 218.19 o 6 0 0 41344.77 45743.86 665.88 o 8 0 0 1835.60 1570.54 35.44 o 10 0 0 1956.34 1864.25 73.55 o 12 0 0 388.21 503.77 49.89 o 14 0 0 761.31 630.93 57.19 o 16 0 0 48.64 55.97 43.81 o 2 1 0 6102.88 6911.40 97.08 o 4 1 0 51257.36 55335.21 567.45 o 6 1 0 27609.77 28238.47 292.17 o 8 1 0 695.51 682.62 13.01 o 10 1 0 2.59 42.00 11.02 o 12 1 0 6195.47 6435.31 113.02 o 14 1 0 182.07 108.90 140.85 o 16 1 0 1068.11 1094.56 63.28 o 0 2 0 11271.92 10862.41 1136.83 o 2 2 0 656.70 637.90 12.28 o 4 2 0 8381.31 9000.19 103.31 o 6 2 0 7045.94 7434.76 80.00 o 8 2 0 9944.35 10258.93 110.01 o 10 2 0 8287.57 9264.85 111.84 o 12 2 0 195.94 196.14 25.58 o 14 2 0 178.89 163.16 131.42 o 16 2 0 358.28 288.61 38.97 o 2 3 0 5264.61 4346.28 50.50 o 4 3 0 9765.73 8856.95 122.15 o 6 3 0 36162.98 37376.48 421.91 o 8 3 0 677.31 699.24 12.65 o 10 3 0 490.13 495.90 41.80 o 12 3 0 10596.02 10379.70 161.23 o 14 3 0 7.15 -25.55 17.04 o 16 3 0 401.89 327.56 108.60 o 0 4 0 17880.03 17668.76 316.10 o 2 4 0 10745.66 10312.39 117.68 o 4 4 0 1672.99 1597.20 22.60 o 6 4 0 912.28 1200.40 37.48 o 8 4 0 810.73 1024.61 20.63 o 10 4 0 2110.33 2127.01 38.43 o 12 4 0 5564.36 5337.02 153.07 o 14 4 0 9.65 59.72 28.55 o 16 4 0 139.48 155.04 53.54 o 2 5 0 20242.94 20417.82 231.30 o 4 5 0 5154.13 4808.88 64.64 o 6 5 0 800.60 608.28 27.14 o 8 5 0 40.70 82.53 21.72 o 10 5 0 2263.73 2087.47 43.72 o 12 5 0 2242.66 2296.63 71.62 o 14 5 0 1186.85 1194.74 53.10 o 16 5 0 1496.69 1565.59 67.23 o 0 6 0 386094.81 333108.50 5895.46 o 2 6 0 6899.72 7102.98 90.75 o 4 6 0 1576.05 1387.27 19.22 o 6 6 0 1201.65 1138.96 44.41 o 8 6 0 141.21 122.51 23.71 o 10 6 0 1356.57 1311.27 32.40 o 12 6 0 62.34 66.06 31.53 o 14 6 0 148.72 119.16 26.41 o 16 6 0 43.67 109.84 126.55 o 2 7 0 1404.35 1701.78 23.41 o 4 7 0 2011.69 1945.28 29.46 o 6 7 0 38413.26 37531.94 551.21 o 8 7 0 37.95 34.77 14.03 o 10 7 0 166.17 206.85 19.76 o 12 7 0 7538.46 8170.67 117.03 o 14 7 0 208.70 181.28 26.06 o 16 7 0 694.23 628.34 98.56 o 0 8 0 114810.61 105846.74 1878.90 o 2 8 0 139.64 190.22 21.52 o 4 8 0 1.74 15.01 5.09 o 6 8 0 24706.02 24852.09 317.65 o 8 8 0 715.96 652.17 23.53 o 10 8 0 3345.03 3306.66 62.96 o 12 8 0 1041.73 972.13 30.26 o 14 8 0 40.86 33.83 19.49 o 16 8 0 416.34 611.21 76.05 o 2 9 0 15483.41 16054.13 206.58 o 4 9 0 22773.50 22982.94 262.37 o 6 9 0 5303.03 5101.54 71.82 o 8 9 0 1927.54 1967.27 50.28 o 10 9 0 216.56 293.56 21.28 o 12 9 0 3898.35 4611.46 77.97 o 14 9 0 42.00 12.47 19.14 o 16 9 0 389.16 504.66 156.67 o 0 10 0 44616.98 43868.32 785.08 o 2 10 0 1200.88 1133.69 31.26 o 4 10 0 557.48 593.45 13.28 o 6 10 0 360.33 256.71 12.17 o 8 10 0 1315.23 1199.77 33.21 o 10 10 0 3185.47 2925.89 59.00 o 12 10 0 1385.04 1287.37 37.42 o 14 10 0 38.47 22.72 20.10 o 16 10 0 45.51 139.69 32.49 o 2 11 0 61.84 55.32 9.33 o 4 11 0 17948.08 18476.58 341.82 o 6 11 0 9834.41 8717.27 130.54 o 8 11 0 1.86 19.62 27.07 o 10 11 0 1019.41 954.45 33.60 o 12 11 0 303.85 312.96 52.34 o 14 11 0 555.69 551.27 39.79 o 0 12 0 38278.64 38247.77 687.48 o 2 12 0 4333.26 4270.85 62.01 o 4 12 0 3480.90 3130.90 47.28 o 6 12 0 203.30 215.84 44.28 o 8 12 0 1538.40 1329.43 37.65 o 10 12 0 2211.14 2125.50 146.32 o 12 12 0 9.89 47.98 27.31 o 14 12 0 0.21 55.25 24.27 o 2 13 0 3105.39 3227.23 51.64 o 4 13 0 733.90 659.68 20.01 o 6 13 0 5770.77 5394.64 151.10 o 8 13 0 19.31 39.54 18.27 o 10 13 0 439.63 488.44 30.22 o 12 13 0 567.43 427.71 45.05 o 14 13 0 327.02 380.38 44.64 o 0 14 0 20026.61 20418.88 374.82 o 2 14 0 56.86 104.54 12.88 o 4 14 0 817.53 847.04 44.52 o 6 14 0 4431.95 4482.47 80.67 o 8 14 0 437.13 556.21 125.33 o 10 14 0 1618.55 1262.52 184.05 o 12 14 0 116.27 119.02 28.45 o 14 14 0 25.00 86.69 33.11 o 2 15 0 51.13 99.75 13.46 o 4 15 0 11.39 -6.88 24.85 o 6 15 0 5311.69 4940.96 156.36 o 8 15 0 234.65 153.15 50.52 o 10 15 0 350.97 437.35 45.91 o 12 15 0 102.39 91.01 32.47 o 14 15 0 50.69 201.59 64.44 o 0 16 0 3350.97 3344.99 107.69 o 2 16 0 5.91 13.62 13.09 o 4 16 0 773.61 711.23 60.09 o 6 16 0 34.04 25.97 24.08 o 8 16 0 1259.99 1192.33 39.22 o 10 16 0 546.00 532.86 33.68 o 12 16 0 35.36 -1.38 32.45 o 2 17 0 7.71 10.18 12.81 o 4 17 0 3741.84 3836.08 127.16 o 6 17 0 1195.93 1003.28 66.93 o 8 17 0 193.53 249.58 33.09 o 10 17 0 69.75 114.73 63.32 o 12 17 0 48.96 16.28 30.65 o 0 18 0 16891.33 17181.55 322.63 o 2 18 0 826.01 703.62 35.21 o 4 18 0 184.23 289.67 34.13 o 6 18 0 16.14 27.57 29.17 o 8 18 0 0.43 86.93 33.29 o 10 18 0 97.23 81.38 62.97 o 12 18 0 106.77 124.97 40.27 o 2 19 0 1159.07 1262.78 39.40 o 4 19 0 2236.53 2308.47 67.54 o 6 19 0 878.56 798.09 45.35 o 8 19 0 168.09 222.93 66.32 o 10 19 0 4.01 -44.51 29.68 o 0 20 0 3161.61 3482.19 84.75 o 2 20 0 40.57 69.08 19.40 o 4 20 0 329.25 306.80 81.53 o 6 20 0 607.32 602.02 42.58 o 8 20 0 256.88 136.67 59.62 o 10 20 0 1910.49 1749.37 69.63 o 2 21 0 10.05 4.75 69.36 o 4 21 0 423.50 443.36 42.92 o 6 21 0 2943.70 2924.65 83.46 o 8 21 0 133.52 90.96 36.50 o 0 22 0 4607.63 5111.93 164.88 o 2 22 0 37.84 -8.38 27.19 o 4 22 0 24.37 46.93 30.22 o 6 22 0 167.36 238.06 39.98 o 8 22 0 0.90 -12.70 34.84 o 2 23 0 170.40 194.26 90.35 o 4 23 0 264.87 108.35 35.64 o 6 23 0 95.39 116.00 37.60 o 0 24 0 535.35 419.20 60.84 o 2 24 0 132.06 103.72 33.12 o 4 24 0 75.85 51.00 33.12 o 1 0 1 5265.65 5297.69 89.26 o 2 0 1 8888.25 9750.97 123.86 o 3 0 1 1221.10 1221.12 16.03 o 4 0 1 367.31 440.69 12.82 o 5 0 1 6274.36 6367.30 74.78 o 6 0 1 8834.89 9680.60 102.94 o 7 0 1 14306.47 15997.09 168.09 o 8 0 1 223.29 159.78 8.32 o 9 0 1 4540.24 4391.68 51.27 o 10 0 1 218.98 202.36 21.37 o 11 0 1 25.23 16.34 17.85 o 12 0 1 934.68 966.78 55.97 o 13 0 1 6606.10 6905.55 147.09 o 14 0 1 45.18 56.78 64.49 o 15 0 1 44.95 -37.14 117.12 o 16 0 1 281.71 158.07 49.59 o 17 0 1 271.67 269.11 45.63 o 0 1 1 1110.80 1053.19 28.97 o 1 1 1 290.36 347.75 6.51 o 2 1 1 790.28 912.00 9.06 o 3 1 1 16090.02 15973.61 134.87 o 4 1 1 2809.74 2969.86 24.50 o 5 1 1 4349.14 4062.10 33.14 o 6 1 1 3102.30 3544.47 29.76 o 7 1 1 11103.86 11212.37 84.33 o 8 1 1 0.53 -0.63 4.24 o 9 1 1 2520.14 2379.75 26.51 o 10 1 1 238.56 202.78 10.84 o 11 1 1 34.64 34.63 8.97 o 12 1 1 505.11 515.97 19.97 o 13 1 1 427.81 432.52 24.79 o 14 1 1 235.96 186.27 22.14 o 15 1 1 577.24 601.85 48.83 o 16 1 1 204.26 192.13 54.62 o 17 1 1 1.50 -63.23 42.15 o 1 2 1 10179.79 10391.47 83.36 o 2 2 1 1510.51 1661.84 15.58 o 3 2 1 29846.39 29403.42 234.31 o 4 2 1 8.37 31.59 4.59 o 5 2 1 9490.40 9174.94 71.61 o 6 2 1 4747.53 4622.54 37.84 o 7 2 1 192.94 181.74 7.16 o 8 2 1 84.64 108.35 5.89 o 9 2 1 13062.81 12940.11 97.77 o 10 2 1 185.73 193.02 9.86 o 11 2 1 5.13 17.62 10.09 o 12 2 1 560.91 535.53 23.64 o 13 2 1 382.51 364.40 27.40 o 14 2 1 83.72 67.70 32.93 o 15 2 1 68.28 66.93 23.80 o 16 2 1 61.39 90.01 25.54 o 17 2 1 8.50 -104.04 69.36 o 0 3 1 707.55 942.97 19.17 o 1 3 1 1274.01 1410.38 13.34 o 2 3 1 51.84 32.85 3.47 o 3 3 1 833.73 696.23 8.66 o 4 3 1 24700.05 24166.25 216.74 o 5 3 1 419.80 559.01 14.15 o 6 3 1 277.98 291.86 10.63 o 7 3 1 7233.66 6922.50 55.63 o 8 3 1 1179.94 1051.35 18.24 o 9 3 1 1620.54 1575.72 18.51 o 10 3 1 154.16 138.07 8.34 o 11 3 1 948.99 939.24 30.19 o 12 3 1 176.91 202.34 19.29 o 13 3 1 4129.45 4291.37 93.59 o 14 3 1 295.86 243.33 27.22 o 15 3 1 1236.39 1182.54 59.62 o 16 3 1 216.95 139.76 34.86 o 17 3 1 83.56 51.51 23.21 o 1 4 1 26295.33 26794.01 225.16 o 2 4 1 1728.12 1999.75 20.23 o 3 4 1 1273.58 1117.94 23.48 o 4 4 1 1838.74 2087.16 24.39 o 5 4 1 48.34 70.35 7.51 o 6 4 1 344.89 318.79 7.15 o 7 4 1 1095.20 1033.36 15.21 o 8 4 1 98.47 109.09 6.68 o 9 4 1 1642.00 1507.08 20.25 o 10 4 1 1536.70 1519.03 29.58 o 11 4 1 48.06 53.70 9.13 o 12 4 1 3002.88 2840.75 50.57 o 13 4 1 957.49 1018.38 28.69 o 14 4 1 4.25 -30.43 20.29 o 15 4 1 0.44 -22.07 18.56 o 16 4 1 253.38 327.82 39.22 o 17 4 1 0.44 6.79 36.88 o 0 5 1 3825.35 4334.20 57.80 o 1 5 1 1587.57 1675.76 16.36 o 2 5 1 4384.93 4657.44 39.14 o 3 5 1 6062.21 5746.53 47.84 o 4 5 1 793.89 846.86 12.44 o 5 5 1 10.19 17.72 5.61 o 6 5 1 180.09 181.97 10.18 o 7 5 1 2575.47 2576.97 26.21 o 8 5 1 50.62 68.78 8.56 o 9 5 1 1291.41 1146.96 18.70 o 10 5 1 621.68 674.50 22.73 o 11 5 1 1047.12 966.43 25.35 o 12 5 1 1792.40 1837.34 26.97 o 13 5 1 4.60 22.07 15.30 o 14 5 1 242.06 258.68 23.84 o 15 5 1 588.72 620.87 39.43 o 16 5 1 315.49 275.98 36.80 o 17 5 1 8.68 -3.36 26.70 o 1 6 1 3779.94 3963.15 38.06 o 2 6 1 332.67 350.41 7.01 o 3 6 1 2533.67 2324.48 21.26 o 4 6 1 7074.27 7466.29 70.41 o 5 6 1 359.04 373.68 9.61 o 6 6 1 1373.32 1473.04 21.19 o 7 6 1 6648.89 6987.52 63.06 o 8 6 1 2733.55 2924.69 34.41 o 9 6 1 5777.04 5829.75 64.64 o 10 6 1 903.12 868.41 18.11 o 11 6 1 254.63 228.97 18.13 o 12 6 1 402.24 372.60 15.59 o 13 6 1 788.05 789.31 19.44 o 14 6 1 224.33 175.26 16.84 o 15 6 1 18.68 -37.68 32.49 o 16 6 1 42.39 28.13 33.63 o 17 6 1 13.34 -43.98 29.32 o 0 7 1 16310.14 16917.21 216.27 o 1 7 1 1907.21 1784.67 19.31 o 2 7 1 149.44 136.12 7.38 o 3 7 1 980.46 843.85 10.75 o 4 7 1 341.62 382.52 11.89 o 5 7 1 4195.03 4330.98 42.78 o 6 7 1 216.75 208.38 14.42 o 7 7 1 10644.52 10612.24 99.06 o 8 7 1 1545.39 1583.94 23.37 o 9 7 1 4.16 12.85 12.82 o 10 7 1 320.19 355.93 16.39 o 11 7 1 53.22 61.90 12.94 o 12 7 1 884.25 788.71 19.02 o 13 7 1 74.09 67.50 20.84 o 14 7 1 320.01 362.52 19.79 o 15 7 1 87.04 31.98 19.75 o 16 7 1 176.89 176.45 28.10 o 1 8 1 14729.47 14943.19 135.91 o 2 8 1 4053.17 4158.52 38.21 o 3 8 1 7895.84 7664.49 64.14 o 4 8 1 77.22 90.94 7.52 o 5 8 1 630.96 519.02 10.52 o 6 8 1 0.66 -1.44 6.75 o 7 8 1 1.84 36.98 13.58 o 8 8 1 257.69 225.64 14.97 o 9 8 1 3932.36 3940.12 50.26 o 10 8 1 28.70 46.90 13.66 o 11 8 1 2.31 1.77 9.74 o 12 8 1 28.39 -5.79 10.89 o 13 8 1 1225.25 1252.29 29.42 o 14 8 1 347.12 384.02 19.74 o 15 8 1 122.77 132.46 18.72 o 16 8 1 73.62 40.20 42.15 o 0 9 1 11214.71 11895.25 154.90 o 1 9 1 2876.71 3190.69 32.66 o 2 9 1 1194.92 1335.74 18.63 o 3 9 1 12824.79 12705.55 109.93 o 4 9 1 265.13 263.29 12.66 o 5 9 1 686.72 604.74 19.39 o 6 9 1 1557.02 1671.23 27.37 o 7 9 1 547.52 538.69 24.48 o 8 9 1 16.74 26.33 16.84 o 9 9 1 3438.75 3325.99 41.18 o 10 9 1 91.24 112.91 12.36 o 11 9 1 13.19 17.84 19.75 o 12 9 1 199.27 150.36 14.29 o 13 9 1 3511.57 3537.67 44.67 o 14 9 1 3.72 46.06 22.44 o 15 9 1 1552.27 1606.23 60.27 o 16 9 1 5.99 87.73 43.91 o 1 10 1 9730.72 10073.11 93.96 o 2 10 1 23.51 39.17 5.38 o 3 10 1 2793.11 2694.94 27.20 o 4 10 1 710.40 883.89 12.75 o 5 10 1 539.87 518.57 12.53 o 6 10 1 319.31 370.50 17.64 o 7 10 1 121.35 169.80 17.93 o 8 10 1 193.10 195.19 12.35 o 9 10 1 3198.86 3247.89 48.77 o 10 10 1 56.99 96.39 16.40 o 11 10 1 95.14 105.63 17.57 o 12 10 1 199.29 233.80 20.11 o 13 10 1 1575.79 1533.23 27.87 o 14 10 1 53.47 60.24 20.64 o 15 10 1 45.85 72.05 24.99 o 16 10 1 15.93 -2.84 41.41 o 0 11 1 27.31 28.73 8.48 o 1 11 1 78.44 82.98 19.12 o 2 11 1 2176.10 2087.25 29.05 o 3 11 1 56.82 58.17 8.31 o 4 11 1 270.08 261.80 8.99 o 5 11 1 3607.22 3724.28 52.92 o 6 11 1 202.00 183.27 10.26 o 7 11 1 9932.34 10317.01 115.13 o 8 11 1 28.07 68.44 11.91 o 9 11 1 1391.51 1378.08 33.11 o 10 11 1 18.34 17.77 14.78 o 11 11 1 462.32 512.98 18.26 o 12 11 1 130.98 122.30 21.82 o 13 11 1 128.36 225.09 17.05 o 14 11 1 81.99 59.24 20.04 o 15 11 1 78.58 109.93 18.79 o 1 12 1 61.94 71.43 7.06 o 2 12 1 812.82 833.64 14.69 o 3 12 1 4221.24 4140.25 45.26 o 4 12 1 280.47 248.80 12.86 o 5 12 1 0.28 -9.08 6.05 o 6 12 1 321.17 376.39 16.04 o 7 12 1 3910.34 4092.60 65.76 o 8 12 1 277.68 336.38 20.63 o 9 12 1 4430.44 4504.90 58.69 o 10 12 1 19.67 12.80 20.12 o 11 12 1 3.68 47.41 17.42 o 12 12 1 72.57 133.37 23.57 o 13 12 1 178.82 200.10 23.25 o 14 12 1 126.46 75.01 23.74 o 15 12 1 36.17 13.54 20.87 o 0 13 1 790.05 893.32 30.03 o 1 13 1 3325.45 3394.03 36.70 o 2 13 1 179.03 163.19 9.44 o 3 13 1 7582.42 7771.08 75.07 o 4 13 1 86.47 91.99 13.00 o 5 13 1 202.69 230.69 10.56 o 6 13 1 4.87 -0.59 9.46 o 7 13 1 366.35 359.51 15.72 o 8 13 1 38.14 57.05 13.92 o 9 13 1 23.33 37.95 14.33 o 10 13 1 154.98 212.94 17.71 o 11 13 1 377.77 331.20 18.28 o 12 13 1 40.08 37.69 19.27 o 13 13 1 73.23 146.01 25.80 o 14 13 1 13.71 78.93 21.14 o 15 13 1 443.35 506.44 26.70 o 1 14 1 7647.79 8036.55 78.12 o 2 14 1 1151.88 1162.92 18.31 o 3 14 1 740.65 818.24 25.61 o 4 14 1 580.07 535.12 14.43 o 5 14 1 567.30 552.95 19.97 o 6 14 1 497.28 412.67 28.25 o 7 14 1 41.30 19.62 15.35 o 8 14 1 67.42 79.23 13.85 o 9 14 1 293.09 353.14 18.74 o 10 14 1 914.74 826.40 24.82 o 11 14 1 4.20 -19.07 19.75 o 12 14 1 225.43 266.92 19.81 o 13 14 1 357.51 372.15 37.16 o 14 14 1 123.97 194.55 49.44 o 0 15 1 4.29 -25.00 18.35 o 1 15 1 108.84 199.67 27.16 o 2 15 1 213.74 250.07 11.10 o 3 15 1 962.31 956.53 31.50 o 4 15 1 544.08 577.15 17.39 o 5 15 1 10.55 -15.30 23.45 o 6 15 1 14.98 -5.95 13.19 o 7 15 1 835.08 871.20 25.74 o 8 15 1 255.16 308.18 17.37 o 9 15 1 58.41 28.49 14.88 o 10 15 1 0.12 -12.25 13.90 o 11 15 1 83.96 152.17 21.40 o 12 15 1 41.23 107.09 38.50 o 13 15 1 612.98 737.27 36.64 o 14 15 1 1.78 9.87 31.93 o 1 16 1 2.56 11.50 10.86 o 2 16 1 248.28 248.37 11.55 o 3 16 1 1690.76 1688.81 42.57 o 4 16 1 89.44 65.13 13.22 o 5 16 1 1314.19 1331.34 33.23 o 6 16 1 208.13 248.23 23.97 o 7 16 1 359.36 416.57 29.41 o 8 16 1 59.00 46.79 15.66 o 9 16 1 1899.43 2071.70 84.33 o 10 16 1 7.68 5.29 21.61 o 11 16 1 158.47 166.30 41.57 o 12 16 1 529.67 597.54 33.21 o 13 16 1 162.86 149.68 22.72 o 0 17 1 59.12 43.69 18.39 o 1 17 1 66.24 98.48 14.10 o 2 17 1 23.25 35.72 10.46 o 3 17 1 78.38 120.54 12.70 o 4 17 1 38.26 -6.81 21.02 o 5 17 1 262.74 258.42 20.21 o 6 17 1 383.14 325.23 22.92 o 7 17 1 1228.63 1288.57 36.41 o 8 17 1 37.98 100.24 23.76 o 9 17 1 615.02 632.97 33.20 o 10 17 1 284.15 247.91 33.73 o 11 17 1 8.46 28.69 28.79 o 12 17 1 6.23 -5.57 41.81 o 1 18 1 755.99 756.17 26.50 o 2 18 1 763.09 668.25 18.34 o 3 18 1 14.42 10.16 22.87 o 4 18 1 120.54 139.42 19.68 o 5 18 1 401.25 394.25 34.07 o 6 18 1 5.16 1.11 18.50 o 7 18 1 46.02 26.80 33.55 o 8 18 1 130.75 82.09 51.46 o 9 18 1 208.74 261.28 26.69 o 10 18 1 10.72 27.19 26.17 o 11 18 1 128.16 234.24 30.97 o 12 18 1 144.64 105.87 39.67 o 0 19 1 16.42 -31.19 29.51 o 1 19 1 1311.47 1309.92 33.09 o 2 19 1 6.30 -2.79 28.07 o 3 19 1 1611.75 1655.68 35.91 o 4 19 1 5.28 18.58 18.13 o 5 19 1 5.32 22.29 19.35 o 6 19 1 123.65 162.71 63.48 o 7 19 1 141.64 135.56 50.28 o 8 19 1 0.57 36.91 49.47 o 9 19 1 407.79 333.91 32.67 o 10 19 1 151.77 143.69 28.66 o 11 19 1 24.36 68.81 67.88 o 1 20 1 359.82 396.15 17.80 o 2 20 1 12.89 8.53 13.52 o 3 20 1 1763.29 1877.80 76.03 o 4 20 1 26.53 5.01 23.18 o 5 20 1 193.35 168.75 38.31 o 6 20 1 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36.70 o 8 20 3 68.41 111.23 32.23 o 9 20 3 103.16 137.87 25.46 o 0 21 3 2.08 -59.23 62.14 o 1 21 3 106.91 147.89 15.00 o 2 21 3 173.66 150.20 43.94 o 3 21 3 10.05 -9.91 28.10 o 4 21 3 573.89 615.55 30.10 o 5 21 3 170.86 173.71 23.45 o 6 21 3 0.83 -38.13 25.42 o 7 21 3 154.57 153.43 27.26 o 8 21 3 566.73 644.48 65.74 o 1 22 3 1.20 75.92 33.67 o 2 22 3 691.10 748.98 37.15 o 3 22 3 100.20 26.01 31.53 o 4 22 3 147.45 151.76 50.32 o 5 22 3 73.10 116.32 23.62 o 6 22 3 15.02 36.07 21.97 o 7 22 3 21.12 12.63 43.03 o 0 23 3 423.73 473.30 51.72 o 1 23 3 90.19 132.55 39.54 o 2 23 3 1.83 60.73 48.12 o 3 23 3 74.59 97.23 79.70 o 4 23 3 6.66 88.94 23.78 o 5 23 3 71.78 124.68 28.19 o 1 24 3 3.18 -14.32 60.59 o 2 24 3 0.78 -84.03 93.52 o 3 24 3 75.47 85.88 25.57 o 0 0 4 936.31 1086.03 40.16 o 1 0 4 3217.98 2866.11 60.23 o 2 0 4 5432.04 5345.60 103.90 o 3 0 4 10172.24 9882.67 129.76 o 4 0 4 10120.47 9782.07 128.81 o 5 0 4 1683.33 1767.80 29.39 o 6 0 4 14036.83 16227.56 188.06 o 7 0 4 336.50 444.21 17.47 o 8 0 4 242.58 159.71 10.52 o 9 0 4 1788.81 1929.65 42.01 o 10 0 4 2088.63 2110.22 71.48 o 11 0 4 1146.95 1193.39 29.77 o 12 0 4 27.82 -23.91 42.63 o 13 0 4 196.40 165.09 39.85 o 14 0 4 133.09 122.21 28.29 o 15 0 4 1317.96 1500.64 60.66 o 16 0 4 39.69 30.37 32.89 o 1 1 4 21349.48 21835.30 279.53 o 2 1 4 2444.48 2542.84 34.53 o 3 1 4 51.55 88.65 8.68 o 4 1 4 232.79 287.54 11.50 o 5 1 4 649.30 648.79 19.95 o 6 1 4 7577.43 7586.16 68.20 o 7 1 4 186.97 152.74 7.68 o 8 1 4 2002.42 1852.30 20.41 o 9 1 4 1810.62 1733.89 31.64 o 10 1 4 253.81 241.34 13.20 o 11 1 4 222.65 260.77 25.70 o 12 1 4 317.64 269.36 16.20 o 13 1 4 14.82 -2.04 13.21 o 14 1 4 949.48 906.45 32.46 o 15 1 4 0.20 -15.84 19.20 o 16 1 4 245.96 261.30 39.69 o 0 2 4 9072.98 9150.09 178.27 o 1 2 4 28111.71 27635.95 314.78 o 2 2 4 646.89 729.14 17.24 o 3 2 4 26.71 29.08 6.94 o 4 2 4 500.77 472.88 11.52 o 5 2 4 4600.83 4596.45 45.86 o 6 2 4 18.43 13.99 5.03 o 7 2 4 18629.68 18569.92 160.00 o 8 2 4 1127.64 1111.34 14.94 o 9 2 4 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o 13 6 4 131.24 160.92 17.01 o 14 6 4 34.03 78.29 21.14 o 15 6 4 633.75 718.13 29.00 o 16 6 4 4.62 101.93 28.98 o 1 7 4 1455.83 1403.90 16.79 o 2 7 4 731.80 792.16 12.72 o 3 7 4 493.62 463.26 11.76 o 4 7 4 161.24 159.84 6.65 o 5 7 4 339.20 359.63 12.96 o 6 7 4 2300.36 2422.03 29.63 o 7 7 4 7.80 27.49 7.57 o 8 7 4 787.63 747.05 21.58 o 9 7 4 2693.86 2594.92 39.78 o 10 7 4 131.69 133.59 11.85 o 11 7 4 31.35 43.88 13.76 o 12 7 4 251.21 259.39 22.36 o 13 7 4 78.81 41.34 14.48 o 14 7 4 592.06 684.03 37.66 o 15 7 4 9.73 -8.19 17.83 o 16 7 4 344.00 409.76 31.24 o 0 8 4 4883.57 4939.18 69.70 o 1 8 4 6785.72 6697.57 64.86 o 2 8 4 113.22 81.66 8.08 o 3 8 4 2747.67 2660.90 27.36 o 4 8 4 1223.52 1199.91 15.58 o 5 8 4 1848.21 1868.54 21.18 o 6 8 4 1862.57 2007.79 21.62 o 7 8 4 4072.90 4189.04 48.09 o 8 8 4 906.27 949.50 17.65 o 9 8 4 142.55 139.71 12.11 o 10 8 4 125.77 174.19 18.75 o 11 8 4 23.63 13.02 11.25 o 12 8 4 92.64 122.14 21.39 o 13 8 4 371.09 350.93 18.17 o 14 8 4 212.15 161.03 17.74 o 15 8 4 27.53 46.57 27.22 o 16 8 4 214.43 255.33 48.29 o 1 9 4 27586.42 28274.22 255.80 o 2 9 4 53.07 42.36 6.33 o 3 9 4 4296.70 4433.16 39.80 o 4 9 4 822.42 835.89 21.99 o 5 9 4 6593.75 6563.12 60.37 o 6 9 4 1734.77 1647.15 22.95 o 7 9 4 433.79 378.92 13.19 o 8 9 4 802.29 825.96 18.41 o 9 9 4 439.18 473.62 19.36 o 10 9 4 68.93 101.14 16.70 o 11 9 4 393.55 420.40 21.61 o 12 9 4 623.27 614.79 20.04 o 13 9 4 1375.01 1357.90 63.40 o 14 9 4 50.88 42.91 24.08 o 15 9 4 29.50 25.50 62.37 o 0 10 4 1132.81 1152.62 28.45 o 1 10 4 6846.23 7155.49 69.83 o 2 10 4 26.96 29.54 6.96 o 3 10 4 4967.41 4891.37 43.79 o 4 10 4 1711.64 1771.92 25.70 o 5 10 4 1050.21 994.24 24.23 o 6 10 4 0.24 -1.32 13.53 o 7 10 4 3902.54 4078.40 51.54 o 8 10 4 339.40 392.67 15.85 o 9 10 4 601.13 516.93 26.27 o 10 10 4 1240.89 1384.77 25.58 o 11 10 4 731.93 718.74 28.64 o 12 10 4 226.84 196.38 16.69 o 13 10 4 403.48 398.25 24.81 o 14 10 4 64.86 29.01 24.48 o 15 10 4 347.34 336.72 35.38 o 1 11 4 209.99 228.04 12.02 o 2 11 4 5606.86 5691.68 61.29 o 3 11 4 3420.89 3488.95 35.41 o 4 11 4 193.28 267.38 22.77 o 5 11 4 2811.88 2955.87 40.78 o 6 11 4 159.25 195.15 21.79 o 7 11 4 198.49 177.01 19.55 o 8 11 4 677.56 706.44 19.72 o 9 11 4 4036.49 4234.74 91.24 o 10 11 4 180.72 240.87 21.40 o 11 11 4 401.92 455.05 31.37 o 12 11 4 63.47 62.33 16.87 o 13 11 4 11.95 6.64 21.54 o 14 11 4 369.90 362.46 21.59 o 15 11 4 23.72 70.83 38.72 o 0 12 4 574.78 616.37 43.12 o 1 12 4 1463.64 1395.24 23.66 o 2 12 4 480.65 490.39 14.02 o 3 12 4 100.76 79.59 11.66 o 4 12 4 204.29 225.12 13.71 o 5 12 4 1568.77 1600.35 26.58 o 6 12 4 70.87 122.21 20.98 o 7 12 4 1368.88 1331.40 36.66 o 8 12 4 258.67 328.25 16.17 o 9 12 4 410.08 409.60 37.57 o 10 12 4 1035.54 1072.62 48.02 o 11 12 4 114.22 113.32 26.57 o 12 12 4 572.02 571.46 31.90 o 13 12 4 66.15 53.91 18.37 o 14 12 4 0.34 19.02 18.58 o 1 13 4 1365.41 1302.06 20.12 o 2 13 4 23.88 46.70 12.39 o 3 13 4 59.00 24.67 9.54 o 4 13 4 373.79 456.45 16.44 o 5 13 4 92.21 75.08 12.89 o 6 13 4 962.74 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101.12 35.03 o 5 12 11 50.79 25.85 46.76 o 6 12 11 180.76 119.56 35.68 o 7 12 11 0.04 88.31 36.94 o 0 13 11 1.66 53.12 46.13 o 1 13 11 92.07 76.82 31.74 o 2 13 11 164.50 196.48 28.25 o 3 13 11 0.16 -12.37 33.79 o 4 13 11 3.94 -40.47 41.71 o 5 13 11 195.21 186.06 38.16 o 6 13 11 24.90 29.89 32.12 o 1 14 11 10.01 71.48 19.49 o 2 14 11 4.69 14.61 24.76 o 3 14 11 173.60 217.08 36.61 o 4 14 11 118.37 181.97 37.31 o 5 14 11 46.45 52.74 39.75 o 0 15 11 93.06 238.33 120.28 o 1 15 11 5.52 23.35 19.79 o 2 15 11 226.04 282.68 38.29 o 3 15 11 107.45 116.72 24.76 o 0 0 12 1629.29 1542.95 85.79 o 1 0 12 7.93 25.74 28.16 o 2 0 12 372.93 400.98 38.42 o 3 0 12 1.67 -27.75 98.87 o 4 0 12 1157.69 1246.07 70.58 o 5 0 12 203.11 186.68 75.14 o 6 0 12 347.77 248.60 109.82 o 7 0 12 1971.92 1838.03 90.05 o 8 0 12 29.79 -8.91 31.03 o 9 0 12 331.73 330.40 88.83 o 1 1 12 59.53 96.26 30.70 o 2 1 12 188.16 142.50 24.95 o 3 1 12 175.55 171.66 24.62 o 4 1 12 170.84 260.26 36.84 o 5 1 12 80.93 106.11 28.89 o 6 1 12 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40.22 o 4 5 12 139.66 191.39 35.84 o 5 5 12 3.24 -33.21 22.14 o 6 5 12 161.01 222.63 24.13 o 7 5 12 30.07 37.97 27.57 o 8 5 12 22.12 11.82 22.22 o 0 6 12 1250.26 1303.63 119.86 o 1 6 12 139.99 138.25 24.23 o 2 6 12 160.01 173.48 24.22 o 3 6 12 23.91 -16.10 25.64 o 4 6 12 130.93 131.24 30.50 o 5 6 12 12.65 13.26 37.00 o 6 6 12 0.08 3.58 22.08 o 7 6 12 456.99 358.78 31.21 o 8 6 12 6.78 -1.79 42.94 o 1 7 12 229.17 198.03 33.46 o 2 7 12 320.82 364.59 39.87 o 3 7 12 3.01 -30.27 20.18 o 4 7 12 106.72 87.56 21.40 o 5 7 12 7.02 -24.00 19.57 o 6 7 12 30.57 47.97 26.67 o 7 7 12 4.46 20.58 25.64 o 8 7 12 63.77 100.91 62.35 o 0 8 12 312.17 268.07 52.02 o 1 8 12 23.28 18.56 30.70 o 2 8 12 23.38 -1.77 22.81 o 3 8 12 110.93 80.35 21.18 o 4 8 12 145.11 180.81 28.04 o 5 8 12 5.34 -36.29 47.42 o 6 8 12 475.72 363.56 32.05 o 7 8 12 45.76 32.43 37.67 o 1 9 12 46.83 7.05 16.59 o 2 9 12 47.52 2.94 31.95 o 3 9 12 109.84 67.37 24.41 o 4 9 12 34.54 23.08 19.51 o 5 9 12 851.46 855.29 42.42 o 6 9 12 508.68 554.67 34.21 o 7 9 12 205.23 167.79 41.98 o 0 10 12 3.38 14.76 24.42 o 1 10 12 169.73 177.26 21.77 o 2 10 12 131.59 124.72 25.67 o 3 10 12 34.96 34.42 20.74 o 4 10 12 392.85 385.93 39.96 o 5 10 12 218.39 189.45 47.42 o 6 10 12 143.80 166.41 26.92 o 1 11 12 105.10 98.62 21.31 o 2 11 12 301.42 306.79 32.92 o 3 11 12 216.40 196.62 38.68 o 4 11 12 167.12 214.14 38.55 o 5 11 12 3.12 83.29 43.37 o 0 12 12 511.76 397.59 43.95 o 1 12 12 279.49 260.77 71.02 o 2 12 12 124.68 136.95 39.62 o 3 12 12 86.69 108.04 27.18 o 4 12 12 92.54 74.82 27.17 o 1 13 12 74.63 63.11 29.27 o 2 13 12 7.31 5.23 21.06 o 1 0 13 49.47 184.66 41.35 o 2 0 13 59.34 39.38 32.55 o 3 0 13 164.06 226.70 65.40 o 4 0 13 129.33 185.44 40.65 o 5 0 13 106.61 82.52 34.44 o 6 0 13 290.32 287.83 127.16 o 7 0 13 19.33 59.38 48.67 o 0 1 13 1.52 44.19 34.30 o 1 1 13 29.04 83.42 26.47 o 2 1 13 274.26 351.79 30.52 o 3 1 13 128.09 132.06 32.67 o 4 1 13 1.42 10.46 41.36 o 5 1 13 108.27 52.56 31.26 o 6 1 13 17.34 34.69 23.97 o 7 1 13 194.87 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26.83 o 4 7 13 19.06 62.23 22.92 o 5 7 13 24.30 93.85 26.10 o 1 8 13 277.48 260.87 28.00 o 2 8 13 27.42 -27.79 18.53 o 3 8 13 71.79 39.07 21.46 o 4 8 13 23.65 -11.68 19.47 o 0 9 13 31.05 65.28 38.10 o 1 9 13 9.20 -26.05 17.36 o 2 9 13 172.05 151.53 34.83 o 3 9 13 14.80 -6.52 42.63 o 1 10 13 85.19 86.46 35.23 o 0 0 14 75.64 76.66 54.15 o 1 0 14 362.79 442.64 75.44 o 2 0 14 204.19 305.90 46.43 o 3 0 14 17.71 72.16 51.11 o 1 1 14 4.06 64.93 27.53 o 2 1 14 23.34 51.96 37.59 o 3 1 14 0.27 85.78 41.36 o 0 2 14 105.89 87.00 73.62 o 1 2 14 6.76 64.13 28.43 o 2 2 14 11.19 39.76 27.16 o 1 3 14 173.58 175.07 30.36 o 2 3 14 45.66 95.98 28.15 o 0 4 14 1.00 -0.17 35.48 o 1 4 14 6.94 37.85 37.15 o