#------------------------------------------------------------------------------ #$Date: 2016-04-03 01:44:07 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181088 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/68/2216841.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2216841_Fobs loop_ _publ_author_name 'He, Long' _publ_section_title ; Methyl 2-hydroxy-3-(2-nitrophenyl)-2-(2-oxocyclopentyl)propanoate ; _journal_coeditor_code XU2357 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o4595 _journal_volume 63 _journal_year 2007 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 95.121 _cell_angle_gamma 90.000 _cell_length_a 14.5561 _cell_length_b 5.5398 _cell_length_c 18.1940 _exptl_crystal_F_000 648.00 _reflns_d_resolution_high 0.8394 _cod_data_source_file xu2357Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' HL92 in p21/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 148.93 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 80.18 108.64 7.63 o 2 0 0 727.03 745.09 18.51 o 3 0 0 2783.87 2473.89 33.31 o 4 0 0 8615.40 7815.13 66.08 o 5 0 0 107.50 116.12 16.32 o 6 0 0 1286.98 1183.51 34.68 o 7 0 0 4172.61 4740.36 69.44 o 8 0 0 7.81 0.02 26.73 o 9 0 0 1052.36 1205.55 42.36 o 10 0 0 383.06 395.84 27.88 o 11 0 0 0.51 0.05 33.63 o 12 0 0 123.68 110.62 23.56 o 13 0 0 140.70 211.43 29.90 o 14 0 0 70.40 61.80 34.58 o 15 0 0 0.43 0.10 37.26 o 16 0 0 22.91 57.44 31.56 o 17 0 0 43.59 18.26 47.89 o 1 1 0 1214.99 1092.77 22.56 o 2 1 0 19.22 0.00 23.20 o 3 1 0 11.70 23.39 24.13 o 4 1 0 489.95 412.58 20.32 o 5 1 0 54.43 57.26 26.43 o 6 1 0 71.94 6.55 28.82 o 7 1 0 2306.96 2141.23 49.02 o 8 1 0 29.59 32.35 24.35 o 9 1 0 78.53 116.52 19.73 o 10 1 0 176.09 163.99 21.75 o 11 1 0 0.80 24.28 28.23 o 12 1 0 2.13 0.05 33.55 o 13 1 0 2.27 24.13 31.22 o 14 1 0 23.10 0.07 42.68 o 15 1 0 23.48 55.84 31.98 o 16 1 0 0.84 0.10 42.17 o 17 1 0 0.17 0.10 46.56 o 0 2 0 398.21 382.41 26.41 o 1 2 0 586.55 484.35 22.12 o 2 2 0 591.64 521.70 23.29 o 3 2 0 94.93 91.60 17.87 o 4 2 0 21.83 24.20 26.88 o 5 2 0 4.45 15.51 21.53 o 6 2 0 22.62 2.04 29.97 o 7 2 0 75.34 53.63 16.10 o 8 2 0 0.48 0.05 28.08 o 9 2 0 197.35 184.14 27.39 o 10 2 0 315.24 326.67 29.45 o 11 2 0 169.12 108.29 25.92 o 12 2 0 100.82 80.29 40.55 o 13 2 0 328.59 301.00 38.58 o 14 2 0 14.37 3.68 24.37 o 15 2 0 10.05 0.07 55.42 o 16 2 0 7.30 0.10 45.36 o 1 3 0 84.55 55.74 33.26 o 2 3 0 1057.30 914.72 36.35 o 3 3 0 281.17 250.90 22.73 o 4 3 0 48.68 45.02 33.38 o 5 3 0 68.00 20.57 36.65 o 6 3 0 8.90 0.02 35.07 o 7 3 0 0.65 0.02 36.84 o 8 3 0 40.42 70.91 21.94 o 9 3 0 4.56 1.62 34.53 o 10 3 0 133.19 0.05 50.22 o 11 3 0 67.51 43.71 42.63 o 12 3 0 55.30 0.07 44.94 o 13 3 0 54.49 55.96 25.94 o 14 3 0 0.14 0.10 43.20 o 15 3 0 13.44 0.10 51.99 o 0 4 0 313.79 294.59 27.69 o 1 4 0 318.50 129.23 43.94 o 2 4 0 116.81 106.84 22.04 o 3 4 0 23.55 30.93 34.22 o 4 4 0 376.78 306.22 32.84 o 5 4 0 37.70 14.16 42.49 o 6 4 0 436.81 392.84 35.37 o 7 4 0 434.53 373.18 37.90 o 8 4 0 159.23 11.07 53.63 o 9 4 0 469.94 418.15 41.43 o 10 4 0 5.13 0.07 39.25 o 11 4 0 1.85 4.44 38.61 o 12 4 0 66.12 47.00 28.74 o 13 4 0 12.91 0.10 45.78 o 1 5 0 4.83 0.05 38.49 o 2 5 0 8.45 30.39 34.68 o 3 5 0 0.60 0.05 44.16 o 4 5 0 132.62 0.05 55.86 o 5 5 0 128.65 69.17 29.43 o 6 5 0 4.85 0.05 47.54 o 7 5 0 120.62 41.14 48.38 o 8 5 0 0.29 27.10 41.75 o 9 5 0 21.64 0.07 46.07 o 10 5 0 1.72 7.46 43.30 o 11 5 0 3.44 0.10 48.60 o 0 6 0 17.75 0.07 46.81 o 1 6 0 19.54 56.01 40.38 o 2 6 0 0.05 0.07 50.61 o 3 6 0 15.03 0.07 54.39 o 4 6 0 103.26 65.93 54.98 o 5 6 0 26.53 0.07 58.12 o 6 6 0 164.30 48.97 60.95 o 7 6 0 0.33 0.07 59.15 o -17 1 1 3.60 40.03 31.00 o -16 1 1 38.50 0.10 44.11 o -15 1 1 19.64 0.10 38.49 o -14 1 1 0.38 0.07 34.71 o -13 1 1 122.96 118.68 36.82 o -12 1 1 30.70 0.05 34.46 o -11 1 1 72.79 89.37 21.43 o -10 1 1 500.16 635.05 35.32 o -9 1 1 13.98 14.97 25.04 o -8 1 1 158.75 169.75 19.86 o -7 1 1 232.44 238.58 20.86 o -6 1 1 2268.75 1888.57 45.14 o -5 1 1 31.58 24.84 22.70 o -4 1 1 70.65 53.66 15.39 o -3 1 1 3239.78 2760.87 43.20 o -2 1 1 1313.59 1307.61 27.74 o 1 1 1 9264.98 10322.78 63.52 o 2 1 1 32.01 0.00 24.96 o 3 1 1 1305.03 1211.91 29.50 o 4 1 1 378.13 293.75 19.15 o 5 1 1 440.06 395.96 22.68 o 6 1 1 841.77 829.33 31.17 o 7 1 1 12.28 22.14 22.83 o 8 1 1 87.86 43.74 29.55 o 9 1 1 404.73 413.07 30.24 o 10 1 1 0.09 0.05 27.76 o 11 1 1 8.38 0.05 32.96 o 12 1 1 39.62 23.78 41.04 o 13 1 1 41.76 69.56 22.68 o 14 1 1 37.67 53.51 31.61 o 15 1 1 8.63 22.53 33.41 o 16 1 1 7.83 0.10 44.30 o -16 2 1 0.11 20.69 38.19 o -15 2 1 5.57 14.24 37.21 o -14 2 1 6.90 48.94 18.24 o -13 2 1 2.40 0.07 42.36 o -12 2 1 0.34 0.05 52.80 o -11 2 1 152.51 123.29 28.28 o -10 2 1 7.81 57.26 29.65 o -9 2 1 17.73 5.65 31.10 o -8 2 1 463.88 413.34 29.31 o -7 2 1 32.90 0.02 26.16 o -6 2 1 441.49 387.66 25.87 o -5 2 1 78.50 35.34 29.70 o -4 2 1 219.17 204.61 21.28 o -3 2 1 303.50 294.27 21.08 o -2 2 1 319.99 314.94 20.64 o -1 2 1 37.75 38.58 29.36 o 0 2 1 402.45 525.58 23.37 o 1 2 1 488.34 500.55 24.23 o 2 2 1 1031.73 1059.31 30.68 o 3 2 1 105.61 91.41 17.06 o 4 2 1 517.81 461.18 25.92 o 5 2 1 764.79 685.52 30.56 o 6 2 1 109.00 110.40 18.46 o 7 2 1 566.87 525.63 29.13 o 8 2 1 0.12 0.02 29.45 o 9 2 1 91.71 136.22 21.23 o 10 2 1 1.87 0.05 34.95 o 11 2 1 2.78 46.59 15.81 o 12 2 1 195.12 135.44 30.61 o 13 2 1 45.59 66.42 33.26 o 14 2 1 46.55 2.18 46.61 o 15 2 1 0.10 16.72 41.82 o 16 2 1 0.56 0.10 49.51 o -15 3 1 3.68 0.10 49.88 o -14 3 1 0.48 0.07 48.01 o -13 3 1 79.61 95.38 39.25 o -12 3 1 85.22 62.10 40.87 o -11 3 1 24.74 84.85 28.86 o -10 3 1 77.70 43.00 35.12 o -9 3 1 0.95 0.05 31.02 o -8 3 1 58.53 7.76 38.19 o -7 3 1 1.05 24.64 28.13 o -6 3 1 104.37 59.37 35.81 o -5 3 1 6.36 17.67 25.36 o -4 3 1 33.20 18.92 32.74 o -3 3 1 94.54 126.36 21.58 o -2 3 1 7.88 0.02 35.84 o -1 3 1 188.32 120.96 20.20 o 0 3 1 54.90 36.18 30.53 o 1 3 1 61.30 58.05 29.04 o 2 3 1 143.77 47.99 34.02 o 3 3 1 1031.83 966.07 38.09 o 4 3 1 13.68 42.02 30.63 o 5 3 1 76.52 0.02 37.80 o 6 3 1 101.24 142.66 23.74 o 7 3 1 225.95 201.27 27.59 o 8 3 1 187.06 127.83 26.29 o 9 3 1 6.42 11.49 35.05 o 10 3 1 3.20 24.79 32.84 o 11 3 1 55.36 36.40 34.22 o 12 3 1 139.82 132.22 29.09 o 13 3 1 65.58 53.78 36.42 o 14 3 1 3.12 0.07 46.49 o 15 3 1 13.98 0.10 44.23 o -13 4 1 1.64 55.72 33.21 o -12 4 1 56.17 71.70 41.41 o -11 4 1 101.71 31.56 41.82 o -10 4 1 7.42 0.07 45.68 o -9 4 1 23.83 0.05 42.05 o -8 4 1 101.05 135.49 26.24 o -7 4 1 184.27 200.09 28.99 o -6 4 1 9.35 8.59 41.21 o -5 4 1 332.88 313.51 28.03 o -4 4 1 2.35 0.05 36.28 o -3 4 1 33.91 22.51 34.39 o -2 4 1 348.16 296.23 31.71 o -1 4 1 267.88 217.30 26.12 o 0 4 1 63.79 14.53 38.56 o 1 4 1 34.70 37.46 36.60 o 2 4 1 8.76 17.80 34.71 o 3 4 1 14.60 52.31 33.95 o 4 4 1 331.02 292.94 32.60 o 5 4 1 126.49 41.16 47.40 o 6 4 1 74.93 66.59 41.11 o 7 4 1 220.14 230.21 30.80 o 8 4 1 364.09 225.57 32.91 o 9 4 1 45.69 72.90 40.72 o 10 4 1 12.57 48.23 29.87 o 11 4 1 21.57 0.07 45.33 o 12 4 1 5.09 0.07 50.59 o 13 4 1 0.28 0.10 46.19 o -11 5 1 8.61 0.12 40.82 o -10 5 1 14.68 43.17 40.72 o -9 5 1 68.29 41.28 43.22 o -8 5 1 59.14 55.89 33.26 o -7 5 1 35.02 58.29 40.47 o -6 5 1 0.42 6.50 41.31 o -5 5 1 6.27 0.07 42.32 o -4 5 1 0.00 0.05 44.13 o -3 5 1 9.92 0.05 40.99 o -2 5 1 33.82 0.05 46.71 o -1 5 1 6.74 0.05 48.11 o 0 5 1 255.50 216.36 32.96 o 1 5 1 58.84 12.32 43.40 o 2 5 1 33.53 91.65 27.51 o 3 5 1 24.89 66.12 39.22 o 4 5 1 5.63 19.49 40.38 o 5 5 1 189.05 149.45 32.57 o 6 5 1 2.99 0.07 45.48 o 7 5 1 46.16 10.87 49.38 o 8 5 1 324.95 297.19 40.82 o 9 5 1 4.69 28.55 47.72 o 10 5 1 0.01 0.10 44.60 o 11 5 1 0.61 0.10 43.27 o -7 6 1 21.13 35.81 41.14 o -6 6 1 2.64 0.07 52.62 o -5 6 1 98.91 18.16 63.96 o -4 6 1 74.46 15.29 64.28 o -3 6 1 2.63 0.07 51.23 o -2 6 1 50.50 0.07 60.60 o -1 6 1 7.29 0.07 47.45 o 0 6 1 3.56 0.07 50.54 o 1 6 1 88.96 93.93 30.53 o 2 6 1 2.42 36.45 44.18 o 3 6 1 124.31 72.78 33.45 o 4 6 1 0.92 66.12 37.70 o 5 6 1 0.34 17.57 50.05 o 6 6 1 49.65 7.76 51.30 o 7 6 1 38.56 0.07 61.22 o -17 0 2 11.59 0.10 50.42 o -16 0 2 37.55 89.69 24.08 o -15 0 2 49.66 89.93 23.69 o -14 0 2 0.00 0.07 35.57 o -13 0 2 410.66 432.66 35.84 o -12 0 2 178.83 206.96 26.26 o -11 0 2 300.24 356.27 30.63 o -10 0 2 98.21 115.98 20.00 o -9 0 2 9.17 0.02 30.53 o -8 0 2 111.72 93.27 30.68 o -7 0 2 33.08 30.66 12.49 o -6 0 2 15058.87 13357.35 110.21 o -5 0 2 3119.44 2764.82 46.83 o -4 0 2 16256.80 15015.05 95.23 o -3 0 2 5745.41 5846.97 52.55 o -2 0 2 8.20 40.94 22.24 o -1 0 2 1545.07 1335.72 21.82 o 0 0 2 753.98 692.02 15.83 o 1 0 2 16822.58 15748.16 63.67 o 2 0 2 48.01 48.55 11.34 o 3 0 2 2010.86 1871.97 32.67 o 4 0 2 2136.69 2154.29 38.44 o 5 0 2 27.55 41.92 14.21 o 6 0 2 0.16 0.02 23.91 o 7 0 2 69.15 7.41 23.37 o 8 0 2 1512.59 1551.81 45.70 o 9 0 2 183.00 158.68 22.19 o 10 0 2 24.86 14.87 29.97 o 11 0 2 16.74 0.05 35.52 o 12 0 2 439.07 498.95 36.08 o 13 0 2 669.16 657.02 42.19 o 14 0 2 2.34 36.67 32.72 o 15 0 2 13.87 60.31 40.40 o 16 0 2 83.67 31.71 45.19 o 17 0 2 0.47 31.93 21.33 o -17 1 2 0.21 13.33 44.21 o -16 1 2 0.48 39.17 28.55 o -15 1 2 16.77 74.42 21.43 o -14 1 2 16.02 0.05 48.45 o -13 1 2 1.48 35.30 31.59 o -12 1 2 8.69 56.11 29.60 o -11 1 2 82.34 115.75 37.33 o -10 1 2 45.28 0.02 34.85 o -9 1 2 373.27 328.71 26.34 o -8 1 2 463.10 420.65 28.30 o -7 1 2 268.59 280.01 21.80 o -6 1 2 1276.16 1224.67 36.77 o -5 1 2 6504.80 6470.68 53.42 o -4 1 2 1034.95 1092.94 33.14 o -3 1 2 2398.78 2553.91 41.43 o -2 1 2 118.68 158.29 15.02 o -1 1 2 1083.51 1062.06 24.67 o 0 1 2 2166.36 2688.93 34.26 o 1 1 2 502.62 504.11 18.68 o 2 1 2 5366.89 4831.71 80.07 o 3 1 2 145.78 138.95 15.56 o 4 1 2 24.06 0.00 25.72 o 5 1 2 1146.47 1173.74 33.45 o 6 1 2 1090.41 1002.66 36.01 o 7 1 2 155.13 194.62 18.02 o 8 1 2 630.64 589.08 30.68 o 9 1 2 285.75 244.22 23.96 o 10 1 2 54.07 65.09 17.60 o 11 1 2 11.82 0.05 34.98 o 12 1 2 45.91 44.82 33.87 o 13 1 2 62.28 53.16 35.93 o 14 1 2 20.58 39.59 33.53 o 15 1 2 18.42 0.07 48.45 o 16 1 2 0.10 57.14 32.67 o -16 2 2 0.07 2.58 37.53 o -15 2 2 4.15 26.09 32.77 o -14 2 2 25.91 56.48 31.17 o -13 2 2 29.83 41.90 30.31 o -12 2 2 11.88 20.30 32.52 o -11 2 2 115.78 91.16 24.91 o -10 2 2 245.77 260.59 26.51 o -9 2 2 587.56 585.50 36.52 o -8 2 2 2.87 0.02 30.85 o -7 2 2 575.47 583.12 31.17 o -6 2 2 16.97 42.78 14.31 o -5 2 2 2694.72 2467.95 54.49 o -4 2 2 53.97 6.09 29.43 o -3 2 2 395.36 395.22 22.85 o -2 2 2 83.97 55.42 14.90 o 0 2 2 112.22 172.31 17.45 o 1 2 2 543.74 634.39 24.42 o 2 2 2 1.11 0.02 27.22 o 3 2 2 146.19 161.14 18.70 o 4 2 2 248.13 224.19 18.51 o 5 2 2 272.28 292.63 24.20 o 6 2 2 734.21 808.00 34.09 o 7 2 2 342.07 317.29 25.67 o 8 2 2 117.86 79.16 25.80 o 9 2 2 145.92 60.82 40.57 o 10 2 2 5.79 0.05 35.10 o 11 2 2 78.76 54.54 39.66 o 12 2 2 15.74 0.05 42.22 o 13 2 2 5.28 0.07 36.84 o 14 2 2 4.41 0.07 43.17 o 15 2 2 2.34 43.44 38.78 o 16 2 2 0.00 0.10 52.11 o -15 3 2 12.04 52.04 30.78 o -14 3 2 0.16 7.22 35.07 o -13 3 2 1.57 53.24 31.69 o -12 3 2 0.82 0.07 41.68 o -11 3 2 324.12 287.30 31.54 o -10 3 2 8.43 0.05 36.55 o -9 3 2 283.41 272.23 31.91 o -8 3 2 42.99 23.39 36.74 o -7 3 2 1.22 10.19 30.09 o -6 3 2 204.59 190.76 24.08 o -5 3 2 25.64 0.02 34.19 o -4 3 2 9.30 40.62 24.59 o -3 3 2 435.00 361.35 25.77 o -2 3 2 689.60 882.93 35.34 o -1 3 2 1978.74 2434.74 54.54 o 0 3 2 751.04 816.81 31.76 o 1 3 2 796.41 1057.01 38.12 o 2 3 2 27.77 36.65 29.60 o 3 3 2 120.71 128.32 21.11 o 4 3 2 1114.26 1101.19 41.36 o 5 3 2 470.55 419.84 28.05 o 6 3 2 106.52 85.29 24.37 o 7 3 2 0.29 0.05 34.49 o 8 3 2 105.43 49.31 37.80 o 9 3 2 9.48 47.99 17.57 o 10 3 2 42.31 61.02 34.24 o 11 3 2 307.80 318.08 32.99 o 12 3 2 1.14 0.07 42.78 o 13 3 2 0.00 0.07 51.72 o 14 3 2 25.93 31.81 43.27 o 15 3 2 0.35 18.46 41.43 o -13 4 2 98.62 91.18 44.30 o -12 4 2 10.90 0.10 36.67 o -11 4 2 0.32 0.07 46.81 o -10 4 2 251.92 242.26 31.47 o -9 4 2 1.97 0.05 44.25 o -8 4 2 339.30 277.29 34.78 o -7 4 2 41.23 58.10 33.09 o -6 4 2 7.61 0.05 37.50 o -5 4 2 27.36 29.70 35.69 o -4 4 2 27.25 50.54 37.77 o -3 4 2 514.00 465.32 32.79 o -2 4 2 0.03 0.02 40.25 o -1 4 2 55.05 45.51 39.79 o 0 4 2 258.62 336.29 27.39 o 1 4 2 136.46 136.62 44.67 o 2 4 2 11.40 0.05 35.54 o 3 4 2 0.57 0.02 39.98 o 4 4 2 324.02 290.34 32.18 o 5 4 2 0.08 56.09 33.04 o 6 4 2 404.32 302.37 32.33 o 7 4 2 1.11 0.05 49.53 o 8 4 2 255.12 184.21 32.62 o 9 4 2 14.25 4.93 20.62 o 10 4 2 51.28 36.01 37.73 o 11 4 2 93.05 9.03 51.23 o 12 4 2 20.59 0.07 48.11 o 13 4 2 5.87 0.10 46.29 o -11 5 2 2.38 2.68 38.73 o -10 5 2 24.97 48.30 38.49 o -9 5 2 159.44 182.57 35.74 o -8 5 2 60.11 18.68 42.90 o -7 5 2 6.79 22.48 41.46 o -6 5 2 15.35 22.95 23.17 o -5 5 2 0.12 0.05 44.08 o -4 5 2 80.46 40.70 42.68 o -3 5 2 26.64 0.05 40.82 o -2 5 2 4.16 26.78 39.84 o -1 5 2 46.06 16.84 46.17 o 0 5 2 10.48 0.05 40.50 o 1 5 2 236.57 202.64 30.75 o 2 5 2 0.21 0.05 42.98 o 3 5 2 179.09 37.04 58.86 o 4 5 2 31.49 0.05 51.42 o 5 5 2 45.80 46.68 39.71 o 6 5 2 25.52 0.07 47.03 o 7 5 2 63.86 64.04 23.51 o 8 5 2 283.95 261.45 34.44 o 9 5 2 17.62 0.07 49.95 o 10 5 2 4.72 22.70 42.14 o -7 6 2 1.37 0.07 55.45 o -6 6 2 8.32 53.93 38.12 o -5 6 2 20.85 28.64 48.08 o -4 6 2 0.00 17.92 44.82 o -3 6 2 10.23 0.07 62.37 o -2 6 2 80.76 0.07 55.62 o -1 6 2 1.89 47.62 44.55 o 0 6 2 133.60 127.05 30.31 o 1 6 2 2.58 9.03 43.08 o 2 6 2 271.29 266.56 41.68 o 3 6 2 52.42 101.03 29.80 o 4 6 2 61.46 36.99 51.42 o 5 6 2 213.43 91.04 55.77 o 6 6 2 45.81 0.07 56.72 o -17 1 3 0.52 0.10 43.22 o -16 1 3 0.75 0.07 48.72 o -15 1 3 0.13 58.29 32.18 o -14 1 3 28.91 69.12 23.34 o -13 1 3 63.44 108.29 22.68 o -12 1 3 48.30 54.76 35.15 o -11 1 3 5.24 40.45 26.75 o -10 1 3 230.76 206.01 25.82 o -9 1 3 86.72 81.15 19.02 o -8 1 3 295.24 222.84 21.04 o -7 1 3 1291.74 1199.12 39.35 o 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