#------------------------------------------------------------------------------ #$Date: 2016-04-03 01:45:29 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181091 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/71/2217179.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2217179_Fobs loop_ _publ_author_name 'Li, Jing' 'Lowary, Todd L.' 'Ferguson, Michael J.' _publ_section_title ; 2-(Methoxymethoxy)-1-(4-oxobicyclo[3.1.0]hexan-1-yl)ethyl 4-nitrobenzoate ; _journal_coeditor_code LH2582 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o329 _journal_volume 64 _journal_year 2008 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 98.526 _cell_angle_beta 100.497 _cell_angle_gamma 101.156 _cell_length_a 8.3387 _cell_length_b 10.1389 _cell_length_c 10.4935 _exptl_crystal_F_000 368.00 _reflns_d_resolution_high 0.7696 _cod_data_source_file lh2582Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' tll0702 in P-1' _shelx_refln_list_code 4 _shelx_f_calc_maximum 85.55 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 520.21 531.99 8.77 o 2 0 0 1757.63 1867.15 35.57 o 3 0 0 528.42 608.53 9.41 o 4 0 0 11.93 16.81 0.25 o 5 0 0 107.34 101.53 0.90 o 6 0 0 0.34 0.30 0.23 o 7 0 0 145.30 134.59 1.42 o 8 0 0 11.13 12.10 0.34 o 9 0 0 0.47 0.59 0.19 o 10 0 0 10.96 11.89 0.46 o -10 1 0 0.81 0.85 0.25 o -9 1 0 3.12 3.13 0.28 o -8 1 0 168.19 162.37 2.52 o -7 1 0 375.05 371.32 3.28 o -6 1 0 162.46 154.58 1.84 o -5 1 0 315.10 330.21 2.49 o -4 1 0 80.24 79.20 1.43 o -3 1 0 823.71 863.09 6.12 o -1 1 0 135.89 143.32 1.79 o 0 1 0 87.81 84.33 1.49 o 1 1 0 348.80 385.20 2.76 o 2 1 0 1061.60 1103.47 7.98 o 3 1 0 330.37 384.62 2.80 o 4 1 0 0.15 2.06 0.29 o 5 1 0 384.10 373.52 2.81 o 6 1 0 67.19 68.81 0.83 o 7 1 0 93.37 96.01 2.33 o 8 1 0 4.36 3.23 0.22 o 9 1 0 6.43 7.95 0.44 o 10 1 0 43.21 58.48 1.33 o -10 2 0 7.49 7.75 0.36 o -9 2 0 9.41 9.95 0.47 o -8 2 0 105.89 105.76 1.48 o -7 2 0 621.06 611.39 5.16 o -6 2 0 5.80 6.78 0.22 o -5 2 0 107.34 106.01 1.33 o -4 2 0 90.35 94.66 1.11 o -3 2 0 283.61 306.59 2.26 o -2 2 0 1210.97 1235.91 9.87 o -1 2 0 481.20 531.47 4.21 o 0 2 0 171.38 178.63 1.32 o 1 2 0 120.67 125.46 1.95 o 2 2 0 24.68 24.08 0.30 o 3 2 0 1303.14 1407.77 10.04 o 4 2 0 110.00 107.18 2.05 o 5 2 0 15.73 15.41 0.46 o 6 2 0 37.71 40.05 0.59 o 7 2 0 83.89 80.26 0.98 o 8 2 0 38.44 41.56 1.40 o 9 2 0 1.70 1.77 0.26 o -10 3 0 0.27 0.10 0.22 o -9 3 0 0.46 0.46 0.23 o -8 3 0 2.02 2.10 0.37 o -7 3 0 106.56 97.54 1.28 o -6 3 0 11.87 9.53 0.37 o -5 3 0 28.06 24.25 0.56 o -4 3 0 62.18 78.32 0.71 o -3 3 0 34.98 38.96 0.43 o -2 3 0 0.28 -0.02 0.05 o -1 3 0 208.12 203.63 1.68 o 0 3 0 84.95 84.68 0.68 o 1 3 0 402.11 397.76 2.80 o 2 3 0 189.25 195.08 1.61 o 3 3 0 1469.16 1700.69 12.06 o 4 3 0 106.17 114.39 1.00 o 5 3 0 0.07 0.22 0.11 o 6 3 0 11.60 10.03 0.29 o 7 3 0 38.09 35.07 0.69 o 8 3 0 0.55 0.69 0.18 o 9 3 0 1.49 1.65 0.28 o -10 4 0 41.85 44.25 1.16 o -9 4 0 37.80 38.24 1.02 o -8 4 0 8.08 6.80 0.41 o -7 4 0 14.94 13.56 0.91 o -6 4 0 1.26 2.57 0.18 o -5 4 0 0.11 1.31 0.09 o -4 4 0 990.68 1106.34 8.75 o -3 4 0 249.51 260.29 2.78 o -2 4 0 31.46 30.01 0.37 o -1 4 0 425.11 411.60 2.98 o 0 4 0 499.42 540.90 3.88 o 1 4 0 8.35 9.57 0.15 o 2 4 0 278.24 259.46 1.97 o 3 4 0 6.88 9.47 0.19 o 4 4 0 0.75 0.62 0.10 o 5 4 0 127.96 115.10 1.37 o 6 4 0 1.51 0.95 0.16 o 7 4 0 0.54 0.87 0.17 o 8 4 0 25.85 27.29 0.65 o 9 4 0 0.13 0.47 0.23 o -10 5 0 3.37 4.75 0.40 o -9 5 0 30.14 33.00 1.37 o -8 5 0 33.27 29.62 0.83 o -7 5 0 91.41 79.44 1.44 o -6 5 0 1.07 0.66 0.15 o -5 5 0 10.33 13.45 0.26 o -4 5 0 250.74 254.97 4.78 o -3 5 0 39.55 37.16 0.45 o -2 5 0 4.49 3.12 0.11 o -1 5 0 43.76 49.85 0.49 o 0 5 0 61.48 59.33 0.56 o 1 5 0 110.33 102.87 1.49 o 2 5 0 49.96 51.95 0.97 o 3 5 0 32.14 36.42 0.51 o 4 5 0 29.31 26.81 0.45 o 5 5 0 43.66 38.12 0.66 o 6 5 0 70.80 66.23 2.08 o 7 5 0 122.44 121.66 1.62 o 8 5 0 4.46 4.33 0.29 o -10 6 0 15.10 17.51 1.12 o -9 6 0 119.82 111.09 2.94 o -8 6 0 1.43 1.97 0.38 o -7 6 0 8.13 8.84 0.50 o -6 6 0 10.56 14.71 0.51 o -5 6 0 9.23 6.49 0.22 o -4 6 0 120.33 126.04 1.17 o -3 6 0 54.22 54.87 0.63 o -2 6 0 109.16 106.84 1.25 o -1 6 0 202.14 216.13 1.69 o 0 6 0 21.02 19.98 0.38 o 1 6 0 593.79 610.31 4.43 o 2 6 0 70.93 71.73 1.17 o 3 6 0 15.52 16.57 0.52 o 4 6 0 27.25 22.82 0.53 o 5 6 0 0.42 0.27 0.14 o 6 6 0 12.21 10.66 0.41 o 7 6 0 0.17 0.48 0.22 o 8 6 0 7.01 7.68 0.46 o -10 7 0 0.13 -0.04 0.32 o -9 7 0 81.06 81.00 1.65 o -8 7 0 1.04 1.19 0.25 o -7 7 0 159.62 147.55 2.31 o -6 7 0 59.58 49.82 1.05 o -5 7 0 0.06 0.16 0.09 o -4 7 0 40.36 39.28 0.54 o -3 7 0 4.36 3.85 0.16 o -2 7 0 172.52 161.78 1.35 o -1 7 0 22.84 22.55 0.33 o 0 7 0 7.60 8.47 0.31 o 1 7 0 5.71 4.56 0.19 o 2 7 0 3.66 3.85 0.26 o 3 7 0 51.96 54.31 0.73 o 4 7 0 0.78 0.44 0.15 o 5 7 0 2.57 1.40 0.21 o 6 7 0 12.63 13.96 0.45 o 7 7 0 18.58 21.81 0.75 o -9 8 0 4.41 6.00 0.44 o -8 8 0 1.20 0.77 0.24 o -7 8 0 0.04 0.17 0.20 o -6 8 0 117.12 109.18 1.80 o -5 8 0 0.17 0.33 0.09 o -4 8 0 18.54 18.72 0.37 o -3 8 0 62.58 64.58 0.74 o -2 8 0 94.35 90.80 1.67 o -1 8 0 77.54 74.95 0.87 o 0 8 0 2.18 1.85 0.14 o 1 8 0 0.23 0.07 0.34 o 2 8 0 123.74 115.94 1.26 o 3 8 0 6.40 5.97 0.30 o 4 8 0 444.40 461.26 4.67 o 5 8 0 50.93 53.11 0.95 o 6 8 0 1.44 3.08 0.26 o -9 9 0 1.81 1.49 0.28 o -8 9 0 0.03 0.20 0.23 o -7 9 0 0.44 0.39 0.21 o -6 9 0 6.45 5.89 0.36 o -5 9 0 2.24 2.61 0.19 o -4 9 0 327.75 342.28 2.71 o -3 9 0 265.54 274.75 2.96 o -2 9 0 6.97 7.75 0.48 o -1 9 0 13.00 12.90 0.29 o 0 9 0 8.62 8.66 0.33 o 1 9 0 59.43 59.22 0.94 o 2 9 0 1.42 0.96 0.18 o 3 9 0 0.03 0.14 0.17 o 4 9 0 55.75 54.48 0.98 o 5 9 0 33.29 29.98 0.71 o -8 10 0 3.60 2.73 0.31 o -7 10 0 0.65 0.38 0.25 o -6 10 0 27.81 31.26 0.84 o -5 10 0 0.66 0.72 0.19 o -4 10 0 13.39 13.36 0.35 o -3 10 0 644.57 674.37 6.48 o -2 10 0 139.19 142.50 1.49 o -1 10 0 0.36 0.24 0.14 o 0 10 0 3.00 3.51 0.62 o 1 10 0 14.78 14.90 0.86 o 2 10 0 15.82 16.52 0.50 o 3 10 0 2.91 2.71 0.51 o 4 10 0 1.03 0.66 0.21 o -4 11 0 69.36 73.96 1.36 o -3 11 0 0.62 1.24 0.20 o -2 11 0 39.03 42.31 1.28 o -1 11 0 3.60 4.07 0.26 o 0 11 0 1.73 1.60 0.37 o 1 11 0 0.19 0.52 0.17 o 2 11 0 13.66 15.40 0.50 o 3 11 0 1.78 2.18 0.28 o -4 12 0 11.57 12.93 0.53 o -3 12 0 0.71 0.74 0.17 o -2 12 0 0.17 -0.09 0.17 o -1 12 0 7.09 8.34 0.37 o 0 12 0 62.08 61.71 1.35 o 1 12 0 2.12 2.19 0.57 o -3 13 0 10.06 12.13 0.78 o -2 13 0 3.37 2.74 0.31 o 1 -13 1 20.49 20.97 0.73 o 2 -13 1 1.96 2.27 0.30 o 3 -13 1 33.85 36.39 0.96 o -2 -12 1 18.77 19.56 1.11 o -1 -12 1 2.89 2.52 0.25 o 0 -12 1 0.79 1.22 0.45 o 1 -12 1 4.10 4.59 0.30 o 2 -12 1 2.72 4.13 0.28 o 3 -12 1 0.06 0.10 0.30 o 4 -12 1 1.32 2.20 0.29 o -3 -11 1 1.08 0.76 0.21 o -2 -11 1 5.07 5.63 0.32 o -1 -11 1 3.51 4.33 0.28 o 0 -11 1 29.70 31.46 1.21 o 1 -11 1 31.89 30.20 0.66 o 2 -11 1 73.33 79.96 1.19 o 3 -11 1 13.36 14.39 0.44 o 4 -11 1 63.75 70.90 3.31 o 7 -11 1 25.57 27.65 1.25 o -5 -10 1 9.48 8.57 0.40 o -4 -10 1 133.66 141.87 1.89 o -3 -10 1 9.15 8.26 0.37 o -2 -10 1 0.40 0.72 0.35 o -1 -10 1 8.91 7.87 0.34 o 0 -10 1 35.49 35.77 0.70 o 1 -10 1 142.36 142.09 1.74 o 2 -10 1 5.91 5.41 0.29 o 3 -10 1 158.56 156.92 1.59 o 4 -10 1 101.57 100.34 1.13 o 5 -10 1 16.92 16.20 0.78 o 6 -10 1 26.33 24.77 0.72 o 7 -10 1 6.96 9.14 0.59 o 8 -10 1 1.91 3.20 0.33 o -6 -9 1 7.25 7.34 0.44 o -5 -9 1 0.31 0.24 0.19 o -4 -9 1 83.45 86.38 1.30 o -3 -9 1 142.28 144.97 1.82 o -2 -9 1 36.20 37.43 1.37 o -1 -9 1 71.57 68.49 1.15 o 0 -9 1 19.77 22.05 0.51 o 1 -9 1 129.68 121.63 1.50 o 2 -9 1 0.43 0.25 0.14 o 3 -9 1 179.67 174.08 1.37 o 4 -9 1 112.59 120.32 1.27 o 5 -9 1 6.65 7.23 0.26 o 6 -9 1 2.25 2.86 0.23 o 7 -9 1 21.52 18.65 0.54 o 8 -9 1 38.10 35.95 1.85 o 9 -9 1 11.73 12.15 0.59 o -6 -8 1 3.02 4.44 0.29 o -5 -8 1 22.74 25.38 0.62 o -4 -8 1 6.87 7.47 0.34 o -3 -8 1 24.89 23.29 1.11 o -2 -8 1 14.21 13.22 0.40 o -1 -8 1 11.76 13.83 0.39 o 0 -8 1 26.31 24.82 0.43 o 1 -8 1 86.38 79.13 0.80 o 2 -8 1 2.18 2.68 0.13 o 3 -8 1 261.60 261.34 2.08 o 4 -8 1 63.37 62.09 0.76 o 5 -8 1 12.03 9.87 0.33 o 6 -8 1 72.33 63.49 1.21 o 7 -8 1 30.12 24.95 0.62 o 8 -8 1 5.31 4.24 0.35 o 9 -8 1 8.58 8.86 0.50 o -7 -7 1 2.41 3.70 0.59 o -6 -7 1 0.00 -0.03 0.16 o -5 -7 1 0.94 1.06 0.23 o -4 -7 1 0.85 1.34 0.18 o -3 -7 1 86.84 83.37 1.12 o -2 -7 1 4.15 4.15 0.19 o -1 -7 1 455.06 458.36 3.84 o 0 -7 1 671.06 675.12 5.52 o 1 -7 1 159.58 163.17 1.23 o 2 -7 1 104.52 100.94 0.83 o 3 -7 1 73.27 77.61 0.84 o 4 -7 1 96.18 95.88 1.07 o 5 -7 1 15.79 16.39 0.41 o 6 -7 1 23.91 23.15 0.54 o 7 -7 1 21.93 21.99 0.57 o 8 -7 1 8.41 8.43 0.47 o 9 -7 1 0.03 -0.20 0.21 o -8 -6 1 22.00 19.59 0.94 o -7 -6 1 3.28 3.02 0.48 o -6 -6 1 3.55 5.04 0.27 o -5 -6 1 33.36 28.81 0.51 o -4 -6 1 175.51 171.81 1.67 o -3 -6 1 0.56 0.27 0.11 o -2 -6 1 15.97 15.64 0.31 o -1 -6 1 304.41 297.47 2.27 o 0 -6 1 39.95 41.76 0.45 o 1 -6 1 18.61 23.93 0.29 o 2 -6 1 43.77 31.78 0.42 o 3 -6 1 6.60 10.20 0.22 o 4 -6 1 4.22 3.81 0.16 o 5 -6 1 9.12 10.28 0.31 o 6 -6 1 16.30 16.21 0.57 o 7 -6 1 175.39 160.28 1.98 o 8 -6 1 0.00 0.15 0.20 o 9 -6 1 36.80 37.56 1.12 o 10 -6 1 9.00 13.55 0.89 o -8 -5 1 13.23 10.68 0.50 o -7 -5 1 17.22 19.71 0.52 o -6 -5 1 0.20 0.27 0.12 o -5 -5 1 1.79 1.24 0.14 o -4 -5 1 1.99 2.62 0.16 o -3 -5 1 2.83 4.02 0.14 o -2 -5 1 29.12 28.36 0.36 o -1 -5 1 205.80 204.39 1.59 o 0 -5 1 140.27 154.53 1.23 o 1 -5 1 106.41 104.43 0.79 o 2 -5 1 438.69 486.75 3.95 o 3 -5 1 1094.13 1233.99 9.73 o 4 -5 1 219.19 239.39 2.43 o 5 -5 1 19.18 23.47 0.46 o 6 -5 1 0.24 0.51 0.14 o 7 -5 1 21.37 20.72 1.32 o 8 -5 1 83.60 81.68 1.60 o 9 -5 1 1.47 1.46 0.27 o 10 -5 1 63.00 63.22 1.46 o -9 -4 1 16.69 20.62 0.72 o -8 -4 1 16.28 16.54 0.67 o -7 -4 1 8.30 8.69 0.34 o -6 -4 1 10.87 14.51 0.34 o -5 -4 1 6.04 7.73 0.21 o -4 -4 1 197.27 198.93 1.61 o -3 -4 1 2.50 1.73 0.19 o -2 -4 1 7.53 4.33 0.13 o -1 -4 1 539.39 556.81 4.00 o 0 -4 1 27.19 26.46 0.31 o 1 -4 1 40.82 37.52 1.01 o 2 -4 1 1226.74 1316.24 10.33 o 3 -4 1 16.15 15.10 0.41 o 4 -4 1 54.76 60.43 0.65 o 5 -4 1 1.43 1.37 0.16 o 6 -4 1 9.68 8.33 0.26 o 7 -4 1 9.15 7.64 0.47 o 8 -4 1 152.08 148.02 2.34 o 9 -4 1 1.18 0.75 0.25 o 10 -4 1 39.45 42.87 1.14 o -9 -3 1 3.64 3.18 0.32 o -8 -3 1 10.83 10.42 0.38 o -7 -3 1 7.02 7.20 0.33 o -6 -3 1 194.63 198.89 2.21 o -5 -3 1 255.90 288.73 2.90 o -4 -3 1 44.36 44.78 0.59 o -3 -3 1 71.73 79.20 0.71 o -2 -3 1 675.61 706.50 5.04 o -1 -3 1 1704.30 1851.20 15.12 o 0 -3 1 471.68 496.84 3.96 o 1 -3 1 494.01 474.04 3.79 o 2 -3 1 49.59 54.16 1.01 o 3 -3 1 23.61 28.03 0.34 o 4 -3 1 48.99 53.36 0.57 o 5 -3 1 2.11 1.94 0.15 o 6 -3 1 325.41 301.03 3.59 o 7 -3 1 0.82 2.83 0.66 o 8 -3 1 82.96 80.69 1.21 o 9 -3 1 0.37 0.40 0.22 o 10 -3 1 49.23 51.79 1.27 o -10 -2 1 29.03 33.53 0.97 o -9 -2 1 0.47 0.94 0.23 o -8 -2 1 72.05 75.26 1.15 o -7 -2 1 10.01 10.47 0.30 o -6 -2 1 490.41 466.99 3.73 o -5 -2 1 31.17 34.46 0.43 o -4 -2 1 19.20 19.03 0.28 o -3 -2 1 186.44 185.60 1.44 o -2 -2 1 232.52 282.99 2.08 o -1 -2 1 654.76 698.16 4.97 o 0 -2 1 1001.52 1051.53 7.63 o 1 -2 1 1074.10 1166.28 8.34 o 2 -2 1 1.51 1.73 0.09 o 3 -2 1 11.76 7.83 0.17 o 4 -2 1 632.10 672.93 4.83 o 5 -2 1 918.64 961.25 7.57 o 6 -2 1 332.39 296.16 2.64 o 7 -2 1 55.03 47.50 0.69 o 8 -2 1 46.26 42.04 0.67 o 9 -2 1 11.19 11.62 0.42 o 10 -2 1 17.21 18.74 0.73 o -10 -1 1 3.14 2.57 0.31 o -9 -1 1 72.82 79.61 1.25 o -8 -1 1 166.52 165.88 2.02 o -7 -1 1 46.91 45.64 1.11 o -6 -1 1 0.17 0.24 0.10 o -5 -1 1 3.24 2.65 0.12 o -4 -1 1 0.76 0.10 0.07 o -3 -1 1 448.16 483.73 3.49 o -2 -1 1 1314.87 1433.68 10.27 o 0 -1 1 486.46 500.28 4.70 o 2 -1 1 20.98 24.03 0.28 o 3 -1 1 1932.68 2163.88 37.55 o 4 -1 1 865.23 992.43 6.45 o 5 -1 1 25.13 21.56 0.61 o 6 -1 1 6.06 8.06 0.24 o 7 -1 1 127.20 126.48 1.65 o 8 -1 1 2.00 2.38 0.40 o 9 -1 1 22.14 22.07 0.58 o 10 -1 1 15.72 17.91 0.55 o -10 0 1 0.57 0.71 0.24 o -9 0 1 49.02 48.82 0.97 o -8 0 1 8.79 9.85 0.69 o -7 0 1 350.01 349.16 6.18 o -6 0 1 601.70 588.61 4.33 o -5 0 1 0.02 0.18 0.07 o -4 0 1 0.65 0.66 0.09 o -3 0 1 1280.83 1350.32 9.65 o -2 0 1 4239.14 4513.56 51.57 o -1 0 1 19.19 14.70 0.29 o 0 0 1 30.67 26.21 0.35 o 1 0 1 2790.10 2933.12 70.31 o 2 0 1 565.84 618.37 12.29 o 3 0 1 1.23 0.86 0.06 o 4 0 1 187.19 205.29 2.71 o 5 0 1 255.47 226.02 2.04 o 6 0 1 15.06 16.53 0.35 o 7 0 1 3.87 2.88 0.20 o 8 0 1 80.91 81.73 1.04 o 9 0 1 0.54 0.73 0.19 o 10 0 1 4.98 5.90 0.41 o -10 1 1 9.08 11.52 0.45 o -9 1 1 16.46 16.37 0.50 o -8 1 1 181.76 182.34 2.17 o -7 1 1 336.43 340.49 3.03 o -6 1 1 29.38 28.38 0.38 o -5 1 1 8.22 9.08 0.40 o -4 1 1 32.62 26.04 0.31 o -3 1 1 14.38 15.68 0.20 o -2 1 1 115.43 83.34 0.74 o -1 1 1 3116.99 3121.85 67.35 o 0 1 1 5.58 6.36 0.17 o 2 1 1 641.25 671.51 4.77 o 3 1 1 48.26 63.44 0.58 o 4 1 1 134.82 144.17 1.18 o 5 1 1 319.50 338.14 2.58 o 6 1 1 4.88 4.38 0.19 o 7 1 1 165.76 172.82 2.07 o 8 1 1 5.32 4.77 0.26 o 9 1 1 9.07 11.02 0.51 o -10 2 1 10.54 11.03 0.61 o -9 2 1 2.76 3.01 0.24 o -8 2 1 5.78 5.96 0.33 o -7 2 1 0.73 0.69 0.41 o -6 2 1 54.39 52.96 0.66 o -5 2 1 123.00 127.87 1.13 o -4 2 1 70.93 70.22 0.84 o -3 2 1 788.24 842.72 6.67 o -2 2 1 59.90 70.74 0.88 o 0 2 1 3030.47 3285.97 43.03 o 1 2 1 330.86 359.93 2.91 o 2 2 1 571.82 579.46 4.11 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