#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/72/2217292.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2217292_Fobs loop_ _publ_author_name 'Bhyrappa, P.' 'Velkannan, V.' 'Varghese, B.' _publ_section_title ; 5,10,15,20-Tetrakis(3,5-difluorophenyl)porphyrin ; _journal_coeditor_code SI2056 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o190 _journal_volume 64 _journal_year 2008 _space_group_IT_number 122 _symmetry_space_group_name_Hall 'I -4 2bw' _symmetry_space_group_name_H-M 'I -4 2 d' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 15.4260 _cell_length_b 15.4260 _cell_length_c 13.9910 _exptl_crystal_F_000 1544.00 _reflns_d_resolution_high 0.7482 _[local]_cod_data_source_file si2056Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' velkannanI-4 in I-42d' _shelx_refln_list_code 4 _shelx_f_calc_maximum 280.13 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, z' 'x, -y+1/2, -z+1/4' '-x, y+1/2, -z+1/4' 'y, x+1/2, z+1/4' '-y, -x+1/2, z+1/4' '-y, x, -z' 'y, -x, -z' 'x+1/2, y+1/2, z+1/2' '-x+1/2, -y+1/2, z+1/2' 'x+1/2, -y+1, -z+3/4' '-x+1/2, y+1, -z+3/4' 'y+1/2, x+1, z+3/4' '-y+1/2, -x+1, z+3/4' '-y+1/2, x+1/2, -z+1/2' 'y+1/2, -x+1/2, -z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 0 2 0 7460.07 6983.46 54.47 o 2 2 0 10179.84 9808.69 173.49 o 1 3 0 940.82 1103.52 9.82 o 0 4 0 78470.63 74768.51 558.44 o 2 4 0 3132.19 3562.43 28.16 o 4 4 0 901.77 741.08 16.02 o 1 5 0 11.13 22.70 1.63 o 3 5 0 6803.15 7162.78 70.47 o 0 6 0 9885.57 10654.90 77.95 o 2 6 0 3195.41 3513.51 25.11 o 4 6 0 1291.93 1454.42 17.94 o 6 6 0 6146.01 5587.21 86.66 o 1 7 0 3113.55 4034.71 22.70 o 3 7 0 1200.12 1556.43 14.63 o 5 7 0 749.13 805.43 10.70 o 0 8 0 26.64 12.66 2.84 o 2 8 0 1835.81 1895.21 12.45 o 4 8 0 141.63 161.78 3.69 o 6 8 0 13.02 17.41 2.34 o 8 8 0 366.89 390.79 8.63 o 1 9 0 1824.73 1882.94 12.44 o 3 9 0 4646.64 4883.95 39.15 o 5 9 0 148.23 144.31 3.96 o 7 9 0 2332.93 2432.75 26.15 o 0 10 0 4284.24 4315.04 35.75 o 2 10 0 228.54 314.52 5.02 o 4 10 0 2410.39 2583.06 26.21 o 6 10 0 1550.30 1544.00 15.68 o 8 10 0 2017.01 2108.35 34.90 o 10 10 0 2882.60 2647.06 54.18 o 1 11 0 3.01 -2.29 2.42 o 3 11 0 511.61 529.85 8.00 o 5 11 0 322.68 297.31 6.21 o 7 11 0 486.10 540.99 9.48 o 9 11 0 223.16 177.95 6.17 o 0 12 0 2038.57 1900.99 21.79 o 2 12 0 1108.54 1209.57 11.25 o 4 12 0 45.69 41.21 3.93 o 6 12 0 20.42 33.61 4.51 o 8 12 0 2129.78 1958.42 38.17 o 10 12 0 504.52 485.49 11.06 o 12 12 0 448.56 435.50 21.88 o 1 13 0 987.99 906.40 10.37 o 3 13 0 4614.91 4435.09 32.83 o 5 13 0 434.43 422.82 9.58 o 7 13 0 1307.27 1394.82 24.89 o 9 13 0 1242.39 1214.97 31.82 o 11 13 0 68.43 68.36 7.29 o 0 14 0 2252.51 2096.79 25.47 o 2 14 0 118.84 122.04 5.38 o 4 14 0 11.59 2.38 3.91 o 6 14 0 199.79 189.59 8.92 o 8 14 0 4.99 4.46 5.21 o 10 14 0 46.05 43.80 7.73 o 12 14 0 41.25 41.20 8.90 o 1 15 0 57.53 76.10 5.38 o 3 15 0 1.95 -4.60 4.60 o 5 15 0 155.74 139.18 8.37 o 7 15 0 802.47 725.85 18.03 o 9 15 0 402.28 421.49 24.24 o 11 15 0 348.70 315.07 20.78 o 13 15 0 334.32 379.62 43.21 o 0 16 0 0.70 2.23 7.89 o 2 16 0 375.53 415.04 11.61 o 4 16 0 2.28 -0.07 6.18 o 6 16 0 493.72 550.54 15.49 o 8 16 0 12.73 14.17 7.92 o 10 16 0 241.92 229.22 31.07 o 12 16 0 14.60 4.63 23.92 o 1 17 0 626.56 647.80 17.83 o 3 17 0 101.76 98.36 9.48 o 5 17 0 9.39 5.03 7.45 o 7 17 0 60.87 47.32 16.00 o 9 17 0 952.08 1091.88 37.83 o 11 17 0 357.48 331.78 44.75 o 0 18 0 169.71 149.64 20.54 o 2 18 0 200.32 241.88 16.71 o 4 18 0 369.20 330.29 17.51 o 6 18 0 0.40 -10.58 10.58 o 8 18 0 103.24 95.40 22.05 o 10 18 0 344.94 410.48 51.70 o 1 19 0 365.92 484.74 23.19 o 3 19 0 20.27 18.02 12.93 o 5 19 0 246.58 283.20 29.47 o 7 19 0 2.63 -8.24 17.61 o 0 20 0 47.63 15.43 20.83 o 2 20 0 36.24 16.20 21.60 o 4 20 0 145.60 179.78 35.49 o 0 1 1 3504.98 3340.27 50.74 o 1 2 1 6824.95 6756.94 52.00 o 0 3 1 2987.65 3135.86 42.30 o 2 3 1 7588.37 8265.58 60.76 o 1 4 1 36983.43 36315.38 145.49 o 3 4 1 2783.48 2657.90 20.99 o 0 5 1 12775.28 13540.79 70.82 o 2 5 1 11133.71 10895.38 53.48 o 4 5 1 3570.91 3921.77 34.31 o 1 6 1 2253.40 2231.47 9.48 o 3 6 1 4211.70 4166.61 24.51 o 5 6 1 5405.87 5886.82 52.44 o 0 7 1 7215.27 7404.77 39.39 o 2 7 1 2308.76 2476.39 10.85 o 4 7 1 614.86 614.57 5.52 o 6 7 1 876.17 1027.28 9.29 o 1 8 1 5014.14 5334.00 20.89 o 3 8 1 1476.57 1428.04 8.12 o 5 8 1 4795.71 4972.44 35.05 o 7 8 1 178.95 146.19 2.90 o 0 9 1 835.35 978.77 8.18 o 2 9 1 2649.03 2753.14 14.27 o 4 9 1 668.87 572.85 5.11 o 6 9 1 857.93 949.84 8.60 o 8 9 1 1766.77 1751.59 17.24 o 1 10 1 227.89 223.47 2.97 o 3 10 1 3002.61 3032.78 15.74 o 5 10 1 678.25 672.79 6.59 o 7 10 1 82.58 70.18 2.80 o 9 10 1 792.13 711.60 9.56 o 0 11 1 2.10 1.59 2.52 o 2 11 1 2593.74 2633.68 14.73 o 4 11 1 921.27 916.36 7.62 o 6 11 1 1688.40 1706.18 12.59 o 8 11 1 120.24 113.33 4.12 o 10 11 1 368.45 395.63 7.09 o 1 12 1 1898.79 1874.87 10.27 o 3 12 1 5189.49 4765.92 26.25 o 5 12 1 161.97 188.02 4.15 o 7 12 1 571.34 540.23 7.41 o 9 12 1 915.74 828.53 12.74 o 11 12 1 56.28 61.63 4.26 o 0 13 1 464.24 461.51 7.62 o 2 13 1 1231.79 1204.35 8.95 o 4 13 1 5664.95 5398.30 36.74 o 6 13 1 1314.62 1221.39 12.03 o 8 13 1 984.07 879.17 11.26 o 10 13 1 319.43 289.93 8.58 o 12 13 1 243.57 239.87 13.42 o 1 14 1 989.34 899.00 8.00 o 3 14 1 1459.52 1461.50 11.02 o 5 14 1 757.54 756.42 9.20 o 7 14 1 485.55 465.80 9.82 o 9 14 1 422.88 406.16 7.98 o 11 14 1 43.53 65.21 6.53 o 13 14 1 112.52 116.57 9.16 o 0 15 1 423.98 396.80 9.71 o 2 15 1 23.07 15.08 3.60 o 4 15 1 1280.96 1235.43 13.61 o 6 15 1 253.17 248.54 7.39 o 8 15 1 427.86 476.63 10.81 o 10 15 1 190.65 219.66 9.77 o 12 15 1 399.97 381.44 25.36 o 14 15 1 277.22 260.02 40.89 o 1 16 1 138.59 169.59 6.26 o 3 16 1 420.79 361.30 9.16 o 5 16 1 24.62 21.21 4.94 o 7 16 1 121.99 102.11 7.48 o 9 16 1 19.13 30.77 6.57 o 11 16 1 78.28 136.24 21.58 o 0 17 1 26.93 34.35 7.38 o 2 17 1 33.10 31.36 5.44 o 4 17 1 68.79 95.57 6.42 o 6 17 1 42.74 67.69 8.25 o 8 17 1 39.33 57.77 8.28 o 10 17 1 66.41 48.56 13.71 o 1 18 1 13.32 9.80 6.73 o 3 18 1 69.77 61.20 7.92 o 5 18 1 140.27 149.65 10.21 o 7 18 1 35.92 30.05 11.05 o 9 18 1 37.37 50.16 16.69 o 0 19 1 731.57 792.19 34.75 o 2 19 1 153.97 176.76 11.94 o 4 19 1 85.82 86.99 11.65 o 6 19 1 378.55 407.31 22.99 o 1 20 1 51.15 63.58 18.27 o 3 20 1 288.65 324.89 27.68 o 1 1 2 12706.40 12360.10 134.48 o 0 2 2 4766.03 4441.66 38.10 o 1 3 2 33299.58 32563.53 200.32 o 3 3 2 9528.64 10073.55 94.92 o 0 4 2 12387.18 13502.07 90.49 o 2 4 2 19145.29 18142.41 98.18 o 1 5 2 2368.67 2347.38 11.07 o 3 5 2 8338.40 8079.58 54.72 o 5 5 2 13441.65 14068.11 141.20 o 0 6 2 507.41 615.13 5.58 o 2 6 2 8511.44 8244.31 42.89 o 4 6 2 3230.84 3507.22 28.25 o 1 7 2 144.77 160.28 2.26 o 3 7 2 1147.37 1247.39 9.58 o 5 7 2 1142.43 1214.50 8.31 o 7 7 2 4451.33 4582.70 43.79 o 0 8 2 6724.01 7299.84 40.27 o 2 8 2 1474.84 1565.56 7.56 o 4 8 2 987.23 1085.94 7.58 o 6 8 2 1515.34 1487.92 11.67 o 1 9 2 750.55 609.53 4.51 o 3 9 2 551.00 522.76 4.54 o 5 9 2 116.35 98.08 2.53 o 7 9 2 734.54 705.68 7.07 o 9 9 2 6417.43 5801.27 71.88 o 0 10 2 130.34 107.62 3.25 o 2 10 2 3373.98 3630.23 15.81 o 4 10 2 1783.16 1637.30 9.75 o 6 10 2 413.36 450.83 5.03 o 8 10 2 159.50 131.47 3.49 o 1 11 2 823.56 785.21 6.10 o 3 11 2 1698.00 1700.53 9.96 o 5 11 2 838.62 771.80 7.07 o 7 11 2 65.65 64.79 3.02 o 9 11 2 81.06 88.62 4.06 o 11 11 2 157.25 212.11 7.65 o 0 12 2 87.00 103.01 4.15 o 2 12 2 52.29 60.52 2.75 o 4 12 2 1538.45 1438.52 10.05 o 6 12 2 133.57 133.64 3.82 o 8 12 2 279.68 261.89 5.80 o 10 12 2 211.23 251.70 7.73 o 1 13 2 71.03 58.56 2.93 o 3 13 2 116.76 120.42 3.66 o 5 13 2 2258.61 2105.60 16.67 o 7 13 2 57.11 42.73 3.66 o 9 13 2 263.74 266.42 6.70 o 11 13 2 63.84 36.36 4.64 o 13 13 2 140.52 135.41 16.82 o 0 14 2 424.48 458.67 8.60 o 2 14 2 6706.78 6254.24 33.29 o 4 14 2 446.79 427.68 6.54 o 6 14 2 19.41 9.53 3.67 o 8 14 2 769.42 758.31 15.75 o 10 14 2 38.53 30.10 4.81 o 12 14 2 163.89 157.84 11.32 o 1 15 2 305.55 290.64 5.98 o 3 15 2 228.94 273.19 6.75 o 5 15 2 114.07 101.92 5.42 o 7 15 2 174.83 179.14 6.53 o 9 15 2 100.24 163.48 9.24 o 11 15 2 156.05 161.35 9.65 o 13 15 2 206.90 198.72 25.57 o 0 16 2 33.06 32.97 6.68 o 2 16 2 447.22 424.62 9.19 o 4 16 2 2.72 1.41 4.38 o 6 16 2 211.56 199.59 8.06 o 8 16 2 122.52 143.48 8.00 o 10 16 2 121.58 136.65 9.35 o 12 16 2 56.17 84.10 33.18 o 1 17 2 32.35 47.73 5.40 o 3 17 2 127.97 143.28 7.14 o 5 17 2 43.02 44.27 6.48 o 7 17 2 249.35 268.84 10.39 o 9 17 2 258.84 268.28 16.16 o 11 17 2 107.65 99.53 35.49 o 0 18 2 14.10 18.56 8.45 o 2 18 2 26.83 20.95 6.19 o 4 18 2 42.84 45.55 8.17 o 6 18 2 75.20 78.38 9.55 o 8 18 2 569.83 579.69 32.14 o 1 19 2 503.26 574.92 19.10 o 3 19 2 211.87 216.84 14.53 o 5 19 2 186.15 251.01 24.01 o 7 19 2 160.61 156.06 27.01 o 0 20 2 109.43 174.38 34.72 o 2 20 2 48.03 38.46 17.98 o 0 1 3 34740.41 34497.07 264.31 o 1 2 3 7641.23 7606.97 38.80 o 0 3 3 4787.42 5190.35 41.38 o 2 3 3 1041.03 993.48 6.33 o 1 4 3 5557.46 5518.77 43.90 o 3 4 3 246.15 323.23 2.81 o 0 5 3 669.12 683.69 5.40 o 2 5 3 1206.66 1190.73 6.61 o 4 5 3 246.30 285.57 2.86 o 1 6 3 3367.88 3342.78 15.94 o 3 6 3 12940.71 13731.76 77.45 o 5 6 3 3080.79 3169.77 20.02 o 0 7 3 12031.60 12217.01 64.64 o 2 7 3 18628.94 19686.95 98.35 o 4 7 3 165.68 156.18 2.36 o 6 7 3 2131.76 2096.95 17.76 o 1 8 3 7603.80 7518.51 30.43 o 3 8 3 4345.95 4191.47 23.59 o 5 8 3 2017.51 2092.12 15.67 o 7 8 3 557.79 540.49 4.97 o 0 9 3 55.34 81.32 2.77 o 2 9 3 1171.58 1202.14 6.59 o 4 9 3 1481.93 1543.53 9.61 o 6 9 3 318.96 350.01 4.08 o 8 9 3 848.63 830.91 9.54 o 1 10 3 1040.81 1013.42 6.64 o 3 10 3 691.04 804.77 6.03 o 5 10 3 488.68 488.61 5.15 o 7 10 3 1549.04 1504.26 10.62 o 9 10 3 2766.01 2466.87 25.20 o 0 11 3 257.70 268.45 5.38 o 2 11 3 2392.23 2349.56 11.87 o 4 11 3 156.66 167.80 3.49 o 6 11 3 2059.31 1958.44 14.90 o 8 11 3 540.54 508.97 6.49 o 10 11 3 938.18 987.34 13.98 o 1 12 3 6283.64 6327.50 32.34 o 3 12 3 522.50 461.04 5.60 o 5 12 3 109.08 94.97 3.36 o 7 12 3 788.49 743.53 10.87 o 9 12 3 855.10 763.91 9.31 o 11 12 3 275.79 253.73 6.97 o 0 13 3 697.85 649.59 9.34 o 2 13 3 516.89 466.51 5.81 o 4 13 3 610.19 605.54 6.76 o 6 13 3 431.84 388.02 7.10 o 8 13 3 71.94 44.32 4.53 o 10 13 3 505.97 461.28 11.94 o 12 13 3 2.21 0.40 4.69 o 1 14 3 779.82 703.56 7.41 o 3 14 3 666.60 667.85 8.03 o 5 14 3 280.10 222.02 7.15 o 7 14 3 399.77 406.52 8.54 o 9 14 3 37.52 57.14 5.40 o 11 14 3 199.37 221.96 8.62 o 13 14 3 74.86 65.44 11.13 o 0 15 3 6.38 0.50 4.89 o 2 15 3 463.08 400.58 7.65 o 4 15 3 355.43 346.06 7.67 o 6 15 3 69.43 58.07 5.61 o 8 15 3 96.79 106.65 6.41 o 10 15 3 236.24 253.02 12.27 o 12 15 3 79.62 91.80 12.04 o 1 16 3 683.35 691.00 10.97 o 3 16 3 778.29 766.69 11.90 o 5 16 3 121.78 122.36 6.74 o 7 16 3 168.97 179.73 8.03 o 9 16 3 66.11 75.87 8.13 o 11 16 3 30.82 21.43 14.52 o 0 17 3 28.78 39.78 7.58 o 2 17 3 41.68 30.47 5.26 o 4 17 3 303.07 294.83 9.23 o 6 17 3 167.02 172.45 9.10 o 8 17 3 50.28 70.56 8.42 o 10 17 3 227.21 232.41 24.59 o 1 18 3 60.63 70.94 7.51 o 3 18 3 215.71 222.42 12.36 o 5 18 3 43.93 42.53 8.71 o 7 18 3 59.78 45.57 11.16 o 9 18 3 140.39 148.92 33.95 o 0 19 3 138.37 187.38 24.48 o 2 19 3 102.23 119.70 15.53 o 4 19 3 26.69 19.87 10.77 o 6 19 3 454.80 487.37 75.23 o 1 20 3 62.11 74.46 21.28 o 3 20 3 16.16 -2.20 20.58 o 0 2 4 157.79 178.87 2.60 o 2 2 4 975.64 1185.05 9.99 o 1 3 4 6994.37 7282.25 36.50 o 0 4 4 5492.13 5244.81 45.51 o 2 4 4 1759.15 1740.17 12.66 o 4 4 4 542.88 589.25 6.21 o 1 5 4 2744.89 2703.37 20.87 o 3 5 4 1142.10 1289.52 9.80 o 0 6 4 8995.38 9755.71 62.05 o 2 6 4 4260.56 5058.15 31.04 o 4 6 4 166.25 221.70 2.81 o 6 6 4 1961.66 2019.34 18.30 o 1 7 4 915.99 828.53 5.82 o 3 7 4 28.69 19.28 1.34 o 5 7 4 820.78 843.01 7.69 o 0 8 4 1268.08 1326.20 10.75 o 2 8 4 1182.33 1226.43 6.90 o 4 8 4 340.17 350.69 3.48 o 6 8 4 1826.74 1999.02 16.82 o 8 8 4 472.49 447.68 9.54 o 1 9 4 231.45 194.47 2.69 o 3 9 4 30.02 18.57 1.70 o 5 9 4 455.62 446.48 4.38 o 7 9 4 802.37 806.67 7.45 o 0 10 4 536.54 522.41 7.24 o 2 10 4 830.66 911.28 6.37 o 4 10 4 3048.72 3114.61 19.37 o 6 10 4 968.81 984.74 7.93 o 8 10 4 927.25 917.09 9.13 o 10 10 4 3766.44 3516.74 58.96 o 1 11 4 127.05 149.22 3.02 o 3 11 4 2607.33 2649.96 17.01 o 5 11 4 791.69 775.60 8.35 o 7 11 4 68.42 69.21 2.98 o 9 11 4 1559.33 1541.94 20.49 o 0 12 4 0.36 -2.98 2.98 o 2 12 4 1188.87 1145.62 9.10 o 4 12 4 853.33 844.14 7.61 o 6 12 4 114.73 105.48 3.67 o 8 12 4 1852.88 1771.49 24.41 o 10 12 4 164.05 177.79 5.80 o 12 12 4 432.34 519.40 16.91 o 1 13 4 164.59 179.26 3.86 o 3 13 4 8249.23 7986.09 52.71 o 5 13 4 255.57 223.27 5.13 o 7 13 4 2129.49 2079.78 24.22 o 9 13 4 0.25 -3.98 3.98 o 11 13 4 556.35 523.20 15.99 o 0 14 4 35.08 35.11 4.40 o 2 14 4 344.95 336.66 5.64 o 4 14 4 1763.20 1556.92 13.36 o 6 14 4 690.74 654.44 10.15 o 8 14 4 322.12 316.00 8.85 o 10 14 4 31.05 38.53 5.81 o 12 14 4 126.81 115.04 9.13 o 14 14 4 33.30 33.18 28.55 o 1 15 4 59.03 50.34 4.17 o 3 15 4 488.74 556.16 9.18 o 5 15 4 540.48 594.48 11.36 o 7 15 4 42.18 23.23 5.03 o 9 15 4 309.15 363.44 15.39 o 11 15 4 74.73 79.77 8.71 o 13 15 4 395.72 359.56 28.92 o 0 16 4 6.21 10.19 7.51 o 2 16 4 325.89 304.02 7.99 o 4 16 4 209.49 247.38 7.99 o 6 16 4 122.48 145.04 7.86 o 8 16 4 183.23 176.00 9.33 o 10 16 4 10.69 18.00 9.73 o 12 16 4 13.24 19.89 18.33 o 1 17 4 282.96 319.13 9.60 o 3 17 4 45.69 44.15 6.25 o 5 17 4 72.06 81.01 8.05 o 7 17 4 208.15 198.99 10.72 o 9 17 4 119.38 143.07 15.50 o 0 18 4 181.53 223.30 14.96 o 2 18 4 23.06 27.37 7.29 o 4 18 4 11.93 7.31 7.35 o 6 18 4 199.62 200.52 13.06 o 8 18 4 20.35 27.40 16.03 o 1 19 4 20.33 47.05 14.77 o 3 19 4 19.01 16.42 12.65 o 5 19 4 135.50 176.52 28.55 o 2 20 4 87.02 66.03 22.84 o 0 1 5 25454.75 25785.28 127.01 o 1 2 5 1072.12 1013.23 6.94 o 0 3 5 3542.87 3989.33 37.53 o 2 3 5 5.36 2.78 0.99 o 1 4 5 2099.59 2004.08 11.91 o 3 4 5 3992.82 3812.15 31.69 o 0 5 5 12.17 6.99 1.66 o 2 5 5 2045.21 1791.70 11.04 o 4 5 5 293.31 336.49 3.13 o 1 6 5 1343.05 1307.87 8.38 o 3 6 5 1147.38 1204.69 10.02 o 5 6 5 774.27 844.88 5.62 o 0 7 5 199.24 180.64 4.46 o 2 7 5 1519.81 1641.61 10.91 o 4 7 5 4055.84 4048.73 30.58 o 6 7 5 326.02 311.96 3.32 o 1 8 5 3658.80 3946.20 24.86 o 3 8 5 22.10 32.62 1.59 o 5 8 5 2501.09 2608.07 16.28 o 7 8 5 10.14 11.95 1.82 o 0 9 5 2002.12 2045.17 14.13 o 2 9 5 1629.96 1736.26 10.13 o 4 9 5 806.10 807.87 5.92 o 6 9 5 616.79 680.00 6.45 o 8 9 5 1307.49 1174.69 12.50 o 1 10 5 1839.81 1982.14 12.19 o 3 10 5 408.64 436.68 4.68 o 5 10 5 94.91 90.11 2.62 o 7 10 5 1208.69 1213.05 8.57 o 9 10 5 1518.90 1562.02 17.29 o 0 11 5 23.46 17.82 2.88 o 2 11 5 3062.79 3158.48 19.98 o 4 11 5 206.55 200.41 3.60 o 6 11 5 380.84 359.51 4.84 o 8 11 5 495.07 496.06 6.43 o 10 11 5 172.25 169.98 5.89 o 1 12 5 1408.76 1313.57 10.39 o 3 12 5 1568.48 1390.62 10.25 o 5 12 5 848.03 783.23 8.41 o 7 12 5 140.68 143.67 4.53 o 9 12 5 864.57 831.23 13.24 o 11 12 5 168.46 148.62 6.45 o 0 13 5 503.04 523.55 8.05 o 2 13 5 28.74 8.54 2.53 o 4 13 5 627.03 646.10 7.51 o 6 13 5 1381.25 1357.61 14.46 o 8 13 5 760.01 756.52 11.68 o 10 13 5 179.88 188.20 7.08 o 12 13 5 5.48 -0.54 5.77 o 1 14 5 860.22 806.66 9.70 o 3 14 5 979.48 958.92 10.55 o 5 14 5 170.81 135.81 5.65 o 7 14 5 101.34 92.57 6.06 o 9 14 5 136.03 127.29 7.56 o 11 14 5 137.19 156.08 9.37 o 13 14 5 30.91 36.31 12.54 o 0 15 5 9.41 2.16 5.36 o 2 15 5 159.13 170.92 6.17 o 4 15 5 309.44 325.07 7.88 o 6 15 5 286.44 244.60 8.13 o 8 15 5 68.08 93.21 7.60 o 10 15 5 61.78 76.67 8.04 o 12 15 5 44.37 36.68 12.61 o 1 16 5 311.92 297.60 8.28 o 3 16 5 66.67 57.44 5.70 o 5 16 5 9.56 9.72 5.46 o 7 16 5 122.44 131.14 8.62 o 9 16 5 44.51 22.20 8.21 o 11 16 5 236.13 294.54 27.62 o 0 17 5 85.39 89.34 10.18 o 2 17 5 190.09 202.97 9.45 o 4 17 5 421.24 391.15 11.89 o 6 17 5 16.97 26.14 6.60 o 8 17 5 314.24 368.94 37.13 o 10 17 5 103.13 73.00 21.49 o 1 18 5 26.09 39.16 7.42 o 3 18 5 439.33 442.10 13.90 o 5 18 5 51.50 46.94 10.15 o 7 18 5 55.73 39.80 18.45 o 0 19 5 47.33 48.39 20.41 o 2 19 5 10.17 7.64 15.59 o 4 19 5 240.18 327.79 30.25 o 1 1 6 1417.04 1263.35 7.96 o 0 2 6 19813.63 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1596.98 1587.04 15.23 o 0 10 8 190.21 189.36 5.39 o 2 10 8 69.02 78.89 2.67 o 4 10 8 874.80 869.68 7.60 o 6 10 8 200.33 215.83 4.49 o 8 10 8 725.10 699.29 10.94 o 10 10 8 523.79 482.23 17.06 o 1 11 8 511.66 516.84 6.19 o 3 11 8 225.40 205.62 4.08 o 5 11 8 851.87 761.70 9.91 o 7 11 8 556.04 532.93 8.46 o 9 11 8 53.58 75.31 5.58 o 0 12 8 360.95 313.92 8.16 o 2 12 8 1997.73 1840.08 20.93 o 4 12 8 250.26 272.88 5.74 o 6 12 8 619.61 633.70 12.84 o 8 12 8 1025.53 1039.97 19.24 o 10 12 8 250.66 240.62 8.85 o 12 12 8 190.92 229.26 18.12 o 1 13 8 424.54 450.73 8.38 o 3 13 8 1405.56 1393.13 13.74 o 5 13 8 41.33 58.09 4.56 o 7 13 8 719.55 686.22 12.94 o 9 13 8 132.76 141.38 8.03 o 11 13 8 75.91 77.46 7.68 o 0 14 8 314.34 314.35 10.33 o 2 14 8 171.63 182.87 6.01 o 4 14 8 230.05 185.29 7.35 o 6 14 8 316.53 329.82 9.74 o 8 14 8 191.38 197.53 9.90 o 10 14 8 190.38 201.36 10.19 o 12 14 8 69.87 55.43 16.24 o 1 15 8 184.89 187.59 7.60 o 3 15 8 170.82 198.09 8.07 o 5 15 8 5.27 17.63 6.58 o 7 15 8 49.53 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6.55 o 4 9 9 353.37 351.49 5.49 o 6 9 9 349.40 343.63 5.71 o 8 9 9 105.07 99.84 4.57 o 1 10 9 935.68 868.12 10.14 o 3 10 9 723.91 727.57 8.14 o 5 10 9 83.17 90.45 3.84 o 7 10 9 437.82 426.58 7.93 o 9 10 9 317.36 308.96 7.69 o 0 11 9 247.92 206.70 6.02 o 2 11 9 257.19 231.06 5.00 o 4 11 9 326.38 306.48 6.72 o 6 11 9 382.77 393.34 8.41 o 8 11 9 214.31 214.58 7.43 o 10 11 9 112.34 108.71 7.00 o 1 12 9 405.94 376.07 6.45 o 3 12 9 1330.29 1309.46 14.70 o 5 12 9 129.53 106.10 5.16 o 7 12 9 544.83 564.41 13.37 o 9 12 9 95.68 125.41 6.98 o 11 12 9 187.50 181.25 11.93 o 0 13 9 1.33 -5.08 5.08 o 2 13 9 277.82 264.14 7.97 o 4 13 9 507.55 466.74 9.41 o 6 13 9 234.34 225.42 8.25 o 8 13 9 594.68 574.56 13.54 o 10 13 9 5.07 2.73 6.59 o 12 13 9 200.16 236.82 36.26 o 1 14 9 47.47 23.10 4.43 o 3 14 9 269.89 244.37 8.03 o 5 14 9 207.41 203.28 8.29 o 7 14 9 63.96 71.30 8.41 o 9 14 9 172.99 197.82 16.33 o 11 14 9 156.62 145.08 17.96 o 0 15 9 367.89 470.90 32.77 o 2 15 9 186.08 213.82 9.52 o 4 15 9 82.54 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11.08 o 5 13 12 94.57 97.21 8.76 o 7 13 12 56.44 46.30 12.27 o 0 14 12 6.97 0.15 15.02 o 2 14 12 113.64 148.78 18.15 o 4 14 12 353.15 306.13 19.99 o 6 14 12 26.59 53.37 12.74 o 5 15 12 7.48 0.77 15.43 o 0 1 13 155.99 146.51 5.94 o 1 2 13 44.88 55.24 3.22 o 0 3 13 63.05 64.34 5.24 o 2 3 13 497.31 476.90 6.02 o 1 4 13 1333.31 1324.35 11.97 o 3 4 13 532.44 523.75 6.84 o 0 5 13 468.93 528.75 9.95 o 2 5 13 224.79 238.57 4.90 o 4 5 13 395.81 396.74 8.56 o 1 6 13 45.33 49.19 4.38 o 3 6 13 216.70 208.50 6.13 o 5 6 13 46.70 55.67 5.90 o 0 7 13 316.42 332.76 12.49 o 2 7 13 481.28 472.22 8.93 o 4 7 13 372.48 375.91 8.94 o 6 7 13 84.92 86.11 6.82 o 1 8 13 456.72 411.13 9.96 o 3 8 13 363.94 426.96 9.10 o 5 8 13 59.80 61.58 5.94 o 7 8 13 6.30 3.63 6.26 o 0 9 13 2.03 -6.27 6.79 o 2 9 13 34.71 33.26 4.44 o 4 9 13 223.37 230.54 11.39 o 6 9 13 163.57 139.16 7.61 o 8 9 13 938.27 992.30 21.51 o 1 10 13 122.92 136.65 7.45 o 3 10 13 17.77 23.50 5.41 o 5 10 13 136.42 134.36 8.14 o 7 10 13 30.18 26.24 8.10 o 9 10 13 401.96 390.33 38.19 o 0 11 13 203.19 190.15 12.25 o 2 11 13 52.97 47.55 7.01 o 4 11 13 5.83 -3.69 5.67 o 6 11 13 106.47 123.83 8.73 o 8 11 13 144.31 157.52 15.91 o 1 12 13 375.93 396.08 13.03 o 3 12 13 103.88 121.11 9.98 o 5 12 13 10.45 6.00 7.26 o 7 12 13 45.03 21.60 16.20 o 0 13 13 0.54 -5.74 14.25 o 2 13 13 159.01 141.38 13.70 o 4 13 13 32.55 19.29 16.97 o 6 13 13 130.39 157.33 15.25 o 1 14 13 41.89 47.84 22.38 o 3 14 13 65.64 47.07 22.38 o 1 1 14 1096.33 1126.96 16.21 o 0 2 14 774.50 743.40 14.11 o 1 3 14 71.12 70.74 5.06 o 3 3 14 256.66 268.04 10.64 o 0 4 14 228.65 215.73 9.91 o 2 4 14 1034.57 916.24 12.74 o 1 5 14 237.36 258.98 8.67 o 3 5 14 278.75 292.55 10.81 o 5 5 14 648.02 669.67 21.37 o 0 6 14 125.01 147.85 10.79 o 2 6 14 53.87 70.09 5.71 o 4 6 14 160.24 151.99 7.79 o 1 7 14 63.28 58.53 6.35 o 3 7 14 77.88 88.14 5.95 o 5 7 14 54.17 50.02 7.12 o 7 7 14 448.53 477.71 20.28 o 0 8 14 296.79 304.56 14.37 o 2 8 14 13.15 9.93 4.67 o 4 8 14 30.99 36.21 5.74 o 6 8 14 127.28 141.58 9.50 o 1 9 14 124.86 144.44 8.29 o 3 9 14 17.43 16.07 6.24 o 5 9 14 40.25 45.31 6.65 o 7 9 14 33.64 25.60 9.62 o 9 9 14 96.15 97.99 23.92 o 0 10 14 181.68 223.65 14.10 o 2 10 14 489.08 500.34 25.30 o 4 10 14 273.72 279.95 11.56 o 6 10 14 189.61 204.29 17.61 o 8 10 14 60.64 87.06 19.68 o 1 11 14 22.91 34.25 8.21 o 3 11 14 100.81 107.08 12.22 o 5 11 14 130.88 134.57 11.97 o 7 11 14 204.56 191.35 23.92 o 0 12 14 654.45 658.45 35.59 o 2 12 14 219.64 287.47 31.64 o 4 12 14 498.22 502.30 35.49 o 1 13 14 359.30 448.29 39.35 o 3 13 14 58.71 56.33 20.83 o 0 1 15 162.14 165.19 10.67 o 1 2 15 252.28 236.09 7.72 o 0 3 15 242.74 217.16 10.76 o 2 3 15 711.60 692.85 11.33 o 1 4 15 111.22 104.72 6.66 o 3 4 15 51.27 56.05 4.65 o 0 5 15 8.43 -3.15 5.89 o 2 5 15 95.76 103.08 8.24 o 4 5 15 18.62 21.57 5.22 o 1 6 15 157.54 179.06 8.64 o 3 6 15 186.52 175.51 7.03 o 5 6 15 82.66 72.16 7.86 o 0 7 15 28.43 28.93 9.26 o 2 7 15 190.88 199.74 9.21 o 4 7 15 97.80 83.84 8.00 o 6 7 15 59.10 56.72 8.05 o 1 8 15 99.97 88.62 7.97 o 3 8 15 28.31 27.95 9.20 o 5 8 15 31.46 47.80 8.02 o 7 8 15 586.57 647.93 29.09 o 0 9 15 1.97 19.76 10.27 o 2 9 15 226.20 238.00 11.05 o 4 9 15 123.56 161.16 22.71 o 6 9 15 190.81 259.78 19.44 o 8 9 15 139.73 162.80 26.23 o 1 10 15 315.38 362.29 24.61 o 3 10 15 282.97 318.55 21.86 o 7 10 15 77.65 97.99 20.83 o 0 11 15 1.32 7.72 17.75 o 2 11 15 656.00 629.81 30.86 o 1 12 15 2.09 3.86 18.52 o 0 0 16 247.91 229.93 24.69 o 0 2 16 27.81 19.44 10.02 o 2 2 16 373.27 366.31 23.61 o 1 3 16 330.86 341.24 10.35 o 0 4 16 182.45 160.88 11.00 o 2 4 16 42.84 42.50 6.15 o 4 4 16 87.89 111.94 11.72 o 1 5 16 88.82 75.03 8.36 o 3 5 16 4.40 2.49 6.29 o 0 6 16 0.81 -8.47 8.47 o 2 6 16 97.58 85.40 8.30 o 4 6 16 172.76 181.98 9.98 o 6 6 16 22.92 23.30 35.49 o 1 7 16 122.06 116.63 8.98 o 3 7 16 288.68 323.63 15.92 o 5 7 16 14.92 5.34 8.61 o 0 8 16 10.35 -2.83 11.05 o 2 8 16 37.45 34.65 9.88 o 4 8 16 5.11 -1.70 13.60 o 6 8 16 48.49 64.46 13.90 o 1 9 16 38.84 51.22 16.59 o 3 9 16 33.53 27.78 21.60 o 0 10 16 1.02 6.94 19.29 o 2 10 16 157.06 182.09 23.15 o 0 1 17 7.92 13.94 10.56 o 1 2 17 63.01 43.15 6.25 o 0 3 17 177.22 212.99 12.53 o 2 3 17 6.59 4.23 6.17 o 1 4 17 337.27 352.87 13.26 o 3 4 17 0.44 2.97 7.17 o 0 5 17 6.43 1.16 10.18 o 2 5 17 85.74 85.48 10.65 o 4 5 17 187.73 209.18 15.54 o 1 6 17 13.06 3.40 8.32 o 3 6 17 0.07 -2.72 18.90 o 5 6 17 97.24 105.71 23.15 o 0 7 17 15.66 7.72 15.43 o 2 7 17 29.89 28.67 18.90 o 4 7 17 107.04 168.98 27.01 o 1 8 17 142.68 132.52 16.68 o 1 1 18 26.94 25.28 9.11 o 0 2 18 67.41 34.33 9.50 o 1 3 18 27.70 35.71 9.48 o 3 3 18 158.43 209.10 25.46 o 0 4 18 136.12 186.03 18.89 o 2 4 18 158.80 188.72 20.19 o 1 5 18 99.90 81.79 23.92 o