#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/77/2217793.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2217793_Fobs loop_ _publ_author_name 'Lemoine, Pascale' 'Viossat, Bernard' 'Brion, Jean Daniel' 'Bekaert, Alain' _publ_section_title ; Dichloridobis[(S)-2-hydroxypropionamide-\k^2^O,O']manganese(II) ; _journal_coeditor_code IM2054 _journal_issue 3 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m471 _journal_volume 64 _journal_year 2008 _space_group_IT_number 4 _symmetry_space_group_name_Hall 'P 2yb' _symmetry_space_group_name_H-M 'P 1 21 1' _cell_angle_alpha 90.000 _cell_angle_beta 99.470 _cell_angle_gamma 90.000 _cell_length_a 6.3120 _cell_length_b 11.7180 _cell_length_c 8.2680 _exptl_crystal_F_000 310.00 _reflns_d_resolution_high 0.7106 _[local]_cod_data_source_file im2054Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' ab122b in P 21' _shelx_refln_list_code 4 _shelx_F_calc_maximum 81.41 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 3 0 0 561.55 490.55 3.74 o 4 0 0 19.01 16.81 0.67 o 5 0 0 7.82 7.81 0.32 o 6 0 0 87.01 73.86 3.99 o 7 0 0 513.34 439.90 6.26 o 8 0 0 23.90 25.08 1.46 o 1 1 0 4411.74 3874.18 149.06 o 2 1 0 134.30 137.91 3.39 o 3 1 0 1245.26 1075.96 15.78 o 4 1 0 264.86 231.36 3.72 o 5 1 0 48.89 44.66 3.06 o 6 1 0 634.33 517.57 18.68 o 7 1 0 13.02 11.80 0.48 o 8 1 0 46.03 38.39 1.60 o 0 2 0 4301.39 3713.61 31.60 o 1 2 0 2162.85 2314.18 78.10 o 2 2 0 1712.69 1631.36 93.42 o 3 2 0 1301.13 1231.83 53.41 o 4 2 0 341.58 313.34 7.93 o 5 2 0 287.87 250.16 3.77 o 6 2 0 34.36 31.80 1.24 o 7 2 0 324.33 287.06 10.65 o 8 2 0 12.84 12.45 0.55 o 1 3 0 684.67 687.52 11.22 o 2 3 0 330.19 346.39 22.62 o 3 3 0 1983.07 1863.41 102.03 o 4 3 0 1034.58 968.08 65.10 o 5 3 0 80.19 75.85 4.78 o 6 3 0 55.30 48.31 3.48 o 7 3 0 41.37 38.86 1.61 o 8 3 0 85.90 78.40 5.13 o 0 4 0 207.39 230.19 3.02 o 1 4 0 3684.10 4008.24 50.95 o 2 4 0 316.80 325.82 10.89 o 3 4 0 913.27 885.12 28.52 o 4 4 0 906.43 910.06 53.49 o 5 4 0 200.43 206.12 7.78 o 6 4 0 13.27 14.84 0.64 o 7 4 0 137.37 143.65 11.04 o 8 4 0 85.91 87.19 3.85 o 1 5 0 667.87 666.98 17.41 o 2 5 0 937.70 960.16 34.09 o 3 5 0 533.05 526.48 18.42 o 4 5 0 90.57 95.94 5.01 o 5 5 0 694.20 682.77 32.99 o 6 5 0 129.88 130.08 6.81 o 7 5 0 32.73 33.67 5.89 o 8 5 0 51.83 52.85 2.05 o 0 6 0 2187.45 2239.58 11.43 o 1 6 0 504.22 499.81 3.96 o 2 6 0 25.71 25.41 0.89 o 3 6 0 644.45 652.10 30.06 o 4 6 0 1147.78 1154.92 78.13 o 5 6 0 10.02 9.86 0.44 o 6 6 0 153.66 145.30 3.59 o 7 6 0 155.87 170.16 8.18 o 8 6 0 3.05 3.48 0.54 o 1 7 0 234.14 234.78 5.83 o 2 7 0 828.15 838.68 23.78 o 3 7 0 523.09 516.07 22.25 o 4 7 0 221.45 221.41 15.53 o 5 7 0 464.82 484.60 33.74 o 6 7 0 132.78 139.86 7.95 o 7 7 0 19.44 22.12 1.15 o 0 8 0 18.89 18.19 1.06 o 1 8 0 376.96 387.87 11.80 o 2 8 0 452.94 476.48 22.14 o 3 8 0 616.00 629.52 33.96 o 4 8 0 597.43 579.88 30.04 o 5 8 0 209.59 206.23 8.76 o 6 8 0 28.22 27.41 3.41 o 7 8 0 45.46 52.61 2.08 o 1 9 0 271.18 282.35 3.85 o 2 9 0 282.64 291.22 12.77 o 3 9 0 121.90 129.44 5.46 o 4 9 0 297.94 312.22 11.66 o 5 9 0 6.83 7.02 0.48 o 6 9 0 89.67 89.29 3.32 o 7 9 0 44.47 46.64 2.04 o 0 10 0 759.55 772.04 9.22 o 1 10 0 143.08 143.24 3.06 o 2 10 0 256.39 250.70 4.04 o 3 10 0 223.16 221.79 7.39 o 4 10 0 117.88 119.64 3.29 o 5 10 0 98.10 102.43 4.48 o 6 10 0 10.99 11.25 0.59 o 1 11 0 852.15 816.22 7.26 o 2 11 0 56.60 53.82 1.98 o 3 11 0 124.81 123.67 3.28 o 4 11 0 49.41 52.58 3.58 o 5 11 0 22.61 20.91 0.97 o 6 11 0 207.39 216.66 14.37 o 0 12 0 1305.74 1272.66 13.43 o 1 12 0 35.75 33.81 1.47 o 2 12 0 56.41 53.44 2.32 o 3 12 0 2.08 0.82 1.43 o 4 12 0 49.49 50.37 1.80 o 5 12 0 75.76 76.95 3.25 o 6 12 0 10.47 9.55 0.99 o 1 13 0 336.25 321.87 5.22 o 2 13 0 5.92 6.34 0.48 o 3 13 0 116.66 108.42 3.50 o 4 13 0 75.56 75.96 3.29 o 5 13 0 5.78 6.56 1.28 o 0 14 0 113.24 111.21 4.92 o 1 14 0 28.69 26.51 1.05 o 2 14 0 118.06 119.23 3.78 o 3 14 0 68.94 70.22 4.31 o 4 14 0 20.72 19.77 0.76 o 1 15 0 19.79 20.02 0.99 o 2 15 0 54.24 54.17 2.06 o 3 15 0 84.29 85.46 3.10 o 0 16 0 47.71 50.07 2.90 o 1 16 0 55.05 57.54 2.21 o 2 16 0 44.40 45.70 1.86 o -8 0 1 185.86 170.73 6.23 o -7 0 1 61.02 57.75 2.00 o -6 0 1 420.34 349.55 10.50 o -5 0 1 105.74 97.62 6.27 o -4 0 1 120.67 103.60 2.11 o -3 0 1 2290.70 1947.63 11.87 o -2 0 1 1501.36 1338.31 20.94 o -1 0 1 1636.01 1727.26 17.31 o 0 0 1 339.37 352.52 5.99 o 1 0 1 2123.01 2285.88 51.50 o 2 0 1 240.37 262.54 2.36 o 3 0 1 179.17 172.52 3.36 o 4 0 1 1553.10 1376.61 9.04 o 5 0 1 340.56 304.88 4.21 o 6 0 1 460.62 394.80 9.96 o 7 0 1 0.46 1.05 0.36 o 8 0 1 3.78 3.98 0.45 o -8 1 1 11.72 11.26 0.84 o -7 1 1 405.81 351.73 5.54 o -6 1 1 73.56 61.32 2.89 o -5 1 1 128.99 112.44 2.57 o -4 1 1 738.06 653.91 16.28 o -3 1 1 354.84 330.19 3.11 o -2 1 1 6627.98 5727.25 136.42 o -1 1 1 193.35 193.75 4.69 o 0 1 1 3394.20 2941.86 134.32 o 1 1 1 2703.95 2887.72 151.64 o 2 1 1 2312.80 2685.81 187.16 o 3 1 1 1116.27 1143.11 60.22 o 4 1 1 497.91 472.97 21.55 o 5 1 1 658.19 573.33 12.08 o 6 1 1 173.35 154.14 3.52 o 7 1 1 99.61 87.05 3.16 o 8 1 1 19.47 19.41 0.83 o -8 2 1 40.15 35.63 1.65 o -7 2 1 2.71 0.90 1.28 o -6 2 1 566.96 503.18 5.95 o -5 2 1 92.86 86.61 2.39 o -4 2 1 681.11 620.40 5.06 o -3 2 1 3708.69 3964.75 58.49 o -2 2 1 562.50 561.15 3.42 o -1 2 1 2896.33 3001.08 35.56 o 0 2 1 1147.61 1285.88 33.39 o 1 2 1 1307.96 1324.40 194.25 o 2 2 1 88.11 108.95 10.98 o 3 2 1 802.91 871.71 72.88 o 4 2 1 1340.95 1355.17 135.57 o 5 2 1 76.44 84.24 10.85 o 6 2 1 268.53 253.26 9.66 o 7 2 1 8.56 8.08 0.44 o 8 2 1 96.32 87.65 3.83 o -8 3 1 2.02 1.64 0.66 o -7 3 1 63.06 57.88 2.64 o -6 3 1 88.23 78.47 6.10 o -5 3 1 586.83 530.32 5.48 o -4 3 1 643.82 605.71 31.50 o -3 3 1 397.21 410.29 13.39 o -2 3 1 197.52 206.36 5.68 o -1 3 1 2288.00 2524.53 30.88 o 0 3 1 762.25 771.72 17.88 o 1 3 1 2760.73 3222.42 138.83 o 2 3 1 1512.70 1487.08 116.14 o 3 3 1 2815.63 2775.56 246.65 o 4 3 1 4.35 5.60 1.18 o 5 3 1 357.16 362.87 35.59 o 6 3 1 3.44 3.64 1.71 o 7 3 1 182.28 192.08 20.67 o 8 3 1 6.20 5.48 0.56 o -8 4 1 8.16 7.79 0.57 o -7 4 1 104.73 101.36 3.26 o -6 4 1 279.69 268.60 4.54 o -5 4 1 47.62 45.89 1.46 o -4 4 1 225.72 221.92 3.32 o -3 4 1 1119.28 1120.80 45.77 o -2 4 1 135.39 145.37 2.09 o -1 4 1 16.80 16.45 3.27 o 0 4 1 2700.38 3148.87 70.39 o 1 4 1 4351.95 4763.22 137.04 o 2 4 1 409.22 406.90 17.28 o 3 4 1 179.75 181.29 14.14 o 4 4 1 415.34 426.57 29.12 o 5 4 1 7.97 7.66 0.40 o 6 4 1 58.60 54.15 8.59 o 7 4 1 106.37 110.34 11.15 o 8 4 1 161.80 185.80 18.01 o -8 5 1 16.07 18.47 0.73 o -7 5 1 67.69 71.29 2.12 o -6 5 1 421.32 407.98 24.99 o -5 5 1 41.60 46.88 1.44 o -4 5 1 517.19 543.50 12.15 o -3 5 1 1019.62 1025.84 46.11 o -2 5 1 648.71 736.59 16.08 o -1 5 1 175.69 184.51 2.30 o 0 5 1 2293.76 2325.22 180.52 o 1 5 1 1400.46 1416.72 53.61 o 2 5 1 1345.44 1412.94 42.25 o 3 5 1 167.29 164.11 15.44 o 4 5 1 652.99 700.30 56.22 o 5 5 1 151.61 172.79 22.63 o 6 5 1 38.61 46.29 5.01 o 7 5 1 186.05 190.89 19.99 o 8 5 1 24.26 23.72 3.74 o -8 6 1 33.80 36.33 1.83 o -7 6 1 262.80 279.45 16.81 o -6 6 1 125.78 124.85 7.34 o -5 6 1 256.26 252.62 11.57 o -4 6 1 15.04 19.37 1.63 o -3 6 1 265.78 271.13 3.54 o -2 6 1 1438.31 1465.24 15.43 o -1 6 1 667.87 670.60 4.66 o 0 6 1 887.85 929.82 18.15 o 1 6 1 2215.86 2329.58 55.08 o 2 6 1 62.47 58.92 3.06 o 3 6 1 1149.98 1176.79 60.16 o 4 6 1 57.24 54.72 5.70 o 5 6 1 97.69 104.00 10.02 o 6 6 1 143.83 156.08 15.84 o 7 6 1 179.64 194.72 13.59 o 8 6 1 39.91 50.20 2.95 o -8 7 1 23.10 25.62 1.12 o -7 7 1 18.60 19.79 0.84 o -6 7 1 180.05 185.48 9.51 o -5 7 1 154.16 162.26 4.68 o -4 7 1 249.88 273.74 8.36 o -3 7 1 439.59 467.85 15.21 o -2 7 1 347.92 363.86 4.00 o -1 7 1 694.39 750.54 5.36 o 0 7 1 1089.54 1142.32 26.26 o 1 7 1 467.70 463.92 4.31 o 2 7 1 1033.51 1070.80 45.82 o 3 7 1 205.38 210.99 7.77 o 4 7 1 365.39 378.04 21.06 o 5 7 1 118.95 125.62 17.44 o 6 7 1 92.19 93.41 8.71 o 7 7 1 79.65 81.71 7.82 o -7 8 1 65.76 64.23 2.58 o -6 8 1 127.08 126.95 3.67 o -5 8 1 19.51 20.00 0.91 o -4 8 1 43.24 45.56 1.81 o -3 8 1 770.86 765.60 10.33 o -2 8 1 150.06 150.68 2.89 o -1 8 1 57.90 59.51 1.92 o 0 8 1 826.01 890.72 9.43 o 1 8 1 1101.35 1119.84 20.98 o 2 8 1 178.36 179.39 6.55 o 3 8 1 93.35 103.05 3.37 o 4 8 1 339.46 353.77 19.32 o 5 8 1 8.80 10.92 1.65 o 6 8 1 21.17 25.27 2.78 o 7 8 1 13.70 14.61 1.26 o -7 9 1 41.28 42.51 3.02 o -6 9 1 18.93 19.77 1.60 o -5 9 1 307.34 312.95 5.15 o -4 9 1 471.16 479.34 10.96 o -3 9 1 58.51 56.49 2.18 o -2 9 1 334.50 353.65 4.50 o -1 9 1 89.09 85.59 4.18 o 0 9 1 243.53 248.37 3.65 o 1 9 1 67.58 69.00 6.09 o 2 9 1 760.64 757.60 19.82 o 3 9 1 623.64 661.13 29.16 o 4 9 1 32.05 34.76 3.68 o 5 9 1 101.60 107.28 3.30 o 6 9 1 12.61 13.03 0.60 o 7 9 1 39.09 43.99 7.15 o -7 10 1 22.42 20.81 1.06 o -6 10 1 99.87 100.12 7.05 o -5 10 1 13.28 12.89 1.33 o -4 10 1 153.40 163.81 3.76 o -3 10 1 576.28 590.83 10.74 o -2 10 1 198.08 201.78 3.67 o -1 10 1 570.14 561.48 8.47 o 0 10 1 46.45 45.01 4.15 o 1 10 1 442.39 449.18 10.16 o 2 10 1 208.68 207.41 13.81 o 3 10 1 63.77 61.49 2.45 o 4 10 1 224.14 231.94 13.59 o 5 10 1 23.61 23.45 0.89 o 6 10 1 64.95 68.75 4.15 o -6 11 1 7.57 8.06 0.90 o -5 11 1 43.26 45.66 3.55 o -4 11 1 89.97 91.03 3.12 o -3 11 1 66.27 63.22 4.35 o -2 11 1 840.57 842.01 7.69 o -1 11 1 15.26 14.76 0.58 o 0 11 1 283.16 290.51 12.17 o 1 11 1 24.56 28.65 1.71 o 2 11 1 41.13 40.24 1.48 o 3 11 1 9.22 11.14 0.46 o 4 11 1 166.50 174.90 4.28 o 5 11 1 244.11 246.95 22.63 o 6 11 1 28.28 30.97 3.72 o -6 12 1 70.04 74.67 2.46 o -5 12 1 37.75 40.54 2.24 o -4 12 1 15.88 17.25 0.72 o -3 12 1 358.49 351.42 12.51 o -2 12 1 107.24 106.53 3.18 o -1 12 1 652.24 634.87 8.74 o 0 12 1 109.10 110.51 3.14 o 1 12 1 9.15 8.57 0.45 o 2 12 1 2.86 3.11 0.43 o 3 12 1 2.26 2.11 1.58 o 4 12 1 110.97 114.33 3.62 o 5 12 1 115.61 122.93 12.45 o -5 13 1 54.98 61.66 5.78 o -4 13 1 103.38 102.26 6.78 o -3 13 1 8.45 8.56 0.54 o -2 13 1 182.18 193.46 4.23 o -1 13 1 14.02 14.14 0.64 o 0 13 1 210.58 211.07 4.31 o 1 13 1 17.41 17.84 0.69 o 2 13 1 149.88 148.24 4.86 o 3 13 1 105.75 106.92 10.68 o 4 13 1 18.45 20.37 0.84 o 5 13 1 103.37 107.25 3.91 o -4 14 1 40.15 40.79 1.79 o -3 14 1 143.94 141.68 4.08 o -2 14 1 28.39 27.70 2.45 o -1 14 1 24.66 24.45 0.82 o 0 14 1 3.21 3.26 0.47 o 1 14 1 161.30 147.90 5.72 o 2 14 1 48.22 50.88 1.94 o 3 14 1 6.83 6.35 0.58 o 4 14 1 135.15 133.15 5.51 o -3 15 1 20.33 20.71 1.29 o -2 15 1 13.58 12.10 0.67 o -1 15 1 11.26 11.56 0.61 o 0 15 1 22.56 20.86 0.77 o 1 15 1 51.08 47.04 1.97 o 2 15 1 102.63 91.92 3.57 o 3 15 1 139.06 128.58 4.27 o -2 16 1 25.33 25.19 0.89 o -1 16 1 21.19 20.44 0.83 o 0 16 1 71.30 64.46 2.23 o 1 16 1 98.45 92.43 4.17 o -8 0 2 3.22 4.34 0.86 o -7 0 2 5.32 4.84 0.52 o -6 0 2 947.91 825.19 10.19 o -5 0 2 1.72 2.33 0.58 o -4 0 2 857.32 782.53 9.21 o -3 0 2 188.28 161.66 2.28 o -2 0 2 3572.96 3552.20 32.99 o -1 0 2 93.69 106.96 1.40 o 0 0 2 250.59 281.90 3.96 o 1 0 2 1.94 1.97 0.17 o 2 0 2 654.18 641.53 8.10 o 3 0 2 245.61 225.40 2.87 o 4 0 2 671.34 624.71 5.43 o 5 0 2 347.18 352.27 4.71 o 6 0 2 0.59 1.00 0.44 o 7 0 2 8.26 7.14 0.46 o 8 0 2 10.44 11.01 0.60 o -8 1 2 53.06 51.61 1.86 o -7 1 2 62.67 57.27 2.05 o -6 1 2 326.72 296.38 4.53 o -5 1 2 700.08 600.28 5.67 o -4 1 2 103.25 96.76 2.12 o -3 1 2 4648.39 4574.79 92.11 o -2 1 2 878.62 846.93 11.88 o -1 1 2 1121.09 1032.17 14.30 o 0 1 2 2628.17 2641.50 55.65 o 1 1 2 2133.06 2407.40 51.58 o 2 1 2 183.60 189.70 4.31 o 3 1 2 749.96 739.96 36.88 o 4 1 2 1569.91 1530.19 72.37 o 5 1 2 105.45 105.98 3.08 o 6 1 2 56.86 53.64 5.75 o 7 1 2 53.13 57.98 4.46 o 8 1 2 3.94 2.53 0.66 o -8 2 2 44.12 42.97 1.78 o -7 2 2 48.81 43.06 1.65 o -6 2 2 405.16 351.40 5.06 o -5 2 2 92.28 82.70 2.37 o -4 2 2 614.16 543.11 8.60 o -3 2 2 628.83 588.75 4.31 o -2 2 2 915.04 879.01 4.52 o -1 2 2 746.25 772.75 13.36 o 0 2 2 3209.55 3192.67 89.84 o 1 2 2 3929.35 4026.70 290.36 o 2 2 2 308.05 341.02 17.84 o 3 2 2 988.04 1003.04 78.81 o 4 2 2 206.27 212.96 18.57 o 5 2 2 211.05 218.62 19.60 o 6 2 2 111.53 118.75 7.76 o 7 2 2 334.70 332.39 22.08 o 8 2 2 52.58 51.32 2.04 o -8 3 2 7.00 7.08 0.56 o -7 3 2 12.16 11.53 0.54 o -6 3 2 250.13 237.73 8.71 o -5 3 2 375.80 361.89 4.57 o -4 3 2 97.45 92.23 2.77 o -3 3 2 1084.69 1097.93 13.12 o -2 3 2 636.67 628.47 7.72 o -1 3 2 31.31 32.33 2.55 o 0 3 2 550.12 608.92 21.66 o 1 3 2 1272.46 1351.13 85.50 o 2 3 2 2372.62 2412.31 187.62 o 3 3 2 26.40 24.85 2.20 o 4 3 2 304.00 309.55 32.27 o 5 3 2 186.47 189.26 19.04 o 6 3 2 401.66 415.44 39.38 o 7 3 2 15.37 15.31 1.44 o 8 3 2 115.08 123.37 10.04 o -8 4 2 19.12 19.64 0.74 o -7 4 2 107.16 106.76 3.36 o -6 4 2 191.78 190.05 3.81 o -5 4 2 476.01 457.80 9.20 o -4 4 2 291.12 300.62 7.48 o -3 4 2 157.78 181.74 2.69 o -2 4 2 959.37 968.75 15.03 o -1 4 2 569.46 588.47 11.67 o 0 4 2 3046.11 3289.12 34.02 o 1 4 2 1767.48 1805.19 125.73 o 2 4 2 1030.24 1156.27 74.77 o 3 4 2 801.78 838.94 89.01 o 4 4 2 35.61 37.46 2.78 o 5 4 2 407.66 419.66 44.49 o 6 4 2 110.46 125.38 17.54 o 7 4 2 165.88 180.17 24.41 o 8 4 2 11.56 12.02 0.87 o -8 5 2 77.64 82.51 3.31 o -7 5 2 190.69 197.54 4.36 o -6 5 2 219.25 213.24 4.21 o -5 5 2 43.90 39.85 1.78 o -4 5 2 207.79 201.11 3.33 o -3 5 2 394.34 416.34 4.63 o -2 5 2 289.84 298.49 3.23 o -1 5 2 2209.53 2209.94 33.30 o 0 5 2 1370.79 1396.15 47.41 o 1 5 2 1949.27 2045.29 105.40 o 2 5 2 510.32 553.14 26.85 o 3 5 2 180.54 195.62 19.89 o 4 5 2 421.20 436.53 33.61 o 5 5 2 160.31 169.06 9.58 o 6 5 2 162.48 172.98 18.98 o 7 5 2 5.00 5.20 1.12 o -8 6 2 70.51 81.23 2.83 o -7 6 2 72.43 71.86 2.46 o -6 6 2 88.57 93.17 3.82 o -5 6 2 459.39 467.80 5.60 o -4 6 2 26.59 26.80 1.08 o -3 6 2 34.62 38.87 1.38 o -2 6 2 3130.25 3075.26 37.66 o -1 6 2 1345.43 1398.86 12.16 o 0 6 2 1300.03 1371.02 46.87 o 1 6 2 26.18 33.95 1.77 o 2 6 2 578.54 620.52 34.60 o 3 6 2 130.51 147.02 6.19 o 4 6 2 81.43 73.87 7.71 o 5 6 2 452.13 481.79 45.61 o 6 6 2 84.61 83.52 5.03 o 7 6 2 30.50 32.26 5.86 o -8 7 2 71.52 82.38 2.85 o -7 7 2 108.88 113.01 5.03 o -6 7 2 200.05 194.91 8.96 o -5 7 2 232.97 226.73 4.17 o -4 7 2 108.76 103.48 4.33 o -3 7 2 232.86 238.46 3.59 o -2 7 2 10.62 10.44 0.35 o -1 7 2 1192.59 1209.14 6.92 o 0 7 2 1334.00 1366.74 30.77 o 1 7 2 1488.48 1534.57 13.44 o 2 7 2 177.34 195.67 14.18 o 3 7 2 61.49 58.04 2.25 o 4 7 2 229.78 256.76 16.20 o 5 7 2 53.63 55.45 5.14 o 6 7 2 156.18 153.69 8.82 o 7 7 2 2.99 3.97 0.55 o -7 8 2 43.49 45.88 1.93 o -6 8 2 47.51 48.84 3.61 o -5 8 2 144.58 152.22 3.59 o -4 8 2 176.52 191.81 4.34 o -3 8 2 247.44 243.61 4.96 o -2 8 2 284.92 310.03 4.45 o -1 8 2 310.18 299.57 6.26 o 0 8 2 500.45 505.27 9.22 o 1 8 2 783.25 790.74 31.16 o 2 8 2 275.98 290.72 13.77 o 3 8 2 247.21 255.55 10.89 o 4 8 2 10.16 11.49 0.48 o 5 8 2 127.10 137.56 5.97 o 6 8 2 99.67 106.44 3.53 o 7 8 2 108.86 117.49 13.57 o -7 9 2 9.92 11.18 0.67 o -6 9 2 123.49 131.75 8.57 o -5 9 2 192.37 201.50 4.21 o -4 9 2 66.61 64.42 3.19 o -3 9 2 107.49 108.21 3.05 o -2 9 2 143.50 155.19 3.13 o -1 9 2 68.66 73.55 2.28 o 0 9 2 89.39 91.55 2.42 o 1 9 2 853.92 860.13 38.39 o 2 9 2 1166.25 1166.10 40.62 o 3 9 2 35.53 35.51 3.40 o 4 9 2 81.58 89.36 7.18 o 5 9 2 16.02 17.27 0.72 o 6 9 2 91.07 95.73 7.96 o -7 10 2 30.93 34.85 1.58 o -6 10 2 70.34 68.02 2.24 o -5 10 2 75.10 74.37 3.00 o -4 10 2 305.49 312.46 5.01 o -3 10 2 153.40 149.31 3.55 o -2 10 2 190.38 188.75 3.60 o -1 10 2 73.01 69.60 2.78 o 0 10 2 382.24 381.85 4.85 o 1 10 2 83.16 84.99 2.55 o 2 10 2 137.40 149.08 3.37 o 3 10 2 342.32 359.29 11.53 o 4 10 2 157.62 153.61 7.98 o 5 10 2 212.47 220.26 13.10 o 6 10 2 16.29 18.94 0.90 o -6 11 2 21.67 21.68 1.16 o -5 11 2 58.06 57.18 2.00 o -4 11 2 40.63 41.78 1.68 o -3 11 2 361.66 358.37 5.39 o -2 11 2 55.41 58.32 2.35 o -1 11 2 263.17 257.46 4.26 o 0 11 2 188.56 186.36 3.63 o 1 11 2 80.72 84.81 2.66 o 2 11 2 59.86 60.86 2.71 o 3 11 2 120.56 124.80 3.35 o 4 11 2 130.47 134.11 3.75 o 5 11 2 56.69 60.60 5.62 o 6 11 2 33.98 40.44 6.25 o -6 12 2 44.85 50.51 2.14 o -5 12 2 8.39 8.56 0.59 o -4 12 2 105.24 106.65 4.06 o -3 12 2 108.57 111.33 3.37 o -2 12 2 698.95 677.89 7.39 o -1 12 2 10.19 10.35 0.47 o 0 12 2 11.04 10.88 0.51 o 1 12 2 26.44 26.50 1.20 o 2 12 2 39.90 38.96 2.61 o 3 12 2 73.45 74.05 3.02 o 4 12 2 107.03 112.73 6.94 o 5 12 2 132.64 139.34 8.68 o -5 13 2 156.47 162.64 7.22 o -4 13 2 14.98 13.43 0.71 o -3 13 2 194.11 189.13 4.43 o -2 13 2 23.52 24.83 1.06 o -1 13 2 14.39 15.48 0.76 o 0 13 2 34.74 36.69 1.54 o 1 13 2 81.73 80.03 5.54 o 2 13 2 45.50 42.20 1.71 o 3 13 2 108.99 106.29 9.45 o 4 13 2 161.40 159.15 6.88 o -4 14 2 101.78 105.95 3.75 o -3 14 2 23.44 24.39 2.09 o -2 14 2 34.09 35.86 2.00 o -1 14 2 35.58 35.18 1.45 o 0 14 2 124.82 118.57 3.60 o 1 14 2 105.95 96.97 3.48 o 2 14 2 34.00 33.63 2.59 o 3 14 2 141.84 138.56 4.36 o 4 14 2 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o 1 1 3 1381.15 1351.85 44.76 o 2 1 3 1911.40 1827.71 48.92 o 3 1 3 931.38 945.96 37.53 o 4 1 3 60.71 66.80 2.39 o 5 1 3 59.88 62.61 2.22 o 6 1 3 67.72 67.67 2.63 o 7 1 3 60.24 57.30 3.00 o 8 1 3 56.20 56.19 2.13 o -8 2 3 76.07 79.33 2.59 o -7 2 3 63.98 62.30 3.23 o -6 2 3 31.82 27.84 3.34 o -5 2 3 473.43 441.46 8.54 o -4 2 3 440.04 385.87 4.19 o -3 2 3 158.76 157.86 2.43 o -2 2 3 112.74 119.65 1.94 o -1 2 3 1526.79 1495.56 10.88 o 0 2 3 3094.87 3274.77 65.58 o 1 2 3 960.41 981.48 16.27 o 2 2 3 1583.56 1579.54 45.94 o 3 2 3 261.35 254.80 8.97 o 4 2 3 220.54 215.77 10.00 o 5 2 3 28.31 26.28 2.47 o 6 2 3 139.42 143.09 4.14 o 7 2 3 142.19 137.26 4.26 o 8 2 3 105.53 114.23 10.38 o -8 3 3 6.07 6.45 0.54 o -7 3 3 137.01 127.23 3.58 o -6 3 3 459.81 430.34 5.66 o -5 3 3 218.82 205.50 3.64 o -4 3 3 299.95 298.32 6.24 o -3 3 3 471.51 481.37 4.27 o -2 3 3 1131.65 1085.41 5.83 o -1 3 3 626.32 659.23 4.16 o 0 3 3 2234.54 2207.94 205.42 o 1 3 3 2989.74 3330.74 157.73 o 2 3 3 175.70 180.29 5.85 o 3 3 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o -8 6 3 131.15 135.31 4.34 o -7 6 3 34.50 37.32 2.64 o -6 6 3 38.81 34.67 1.54 o -5 6 3 160.83 155.40 3.45 o -4 6 3 35.08 34.96 1.32 o -3 6 3 1679.35 1659.66 8.83 o -2 6 3 444.44 440.96 4.33 o -1 6 3 717.87 713.38 13.74 o 0 6 3 70.12 79.49 1.88 o 1 6 3 61.76 69.95 4.37 o 2 6 3 18.95 25.69 4.35 o 3 6 3 45.69 44.29 2.42 o 4 6 3 813.32 800.13 59.99 o 5 6 3 58.32 57.99 7.79 o 6 6 3 20.90 22.21 4.23 o 7 6 3 10.36 10.96 1.25 o -7 7 3 26.01 25.21 1.21 o -6 7 3 92.51 92.31 6.60 o -5 7 3 49.04 48.97 1.63 o -4 7 3 402.28 406.60 20.17 o -3 7 3 182.76 186.37 3.30 o -2 7 3 1627.14 1632.00 48.71 o -1 7 3 91.15 99.16 2.32 o 0 7 3 99.39 100.90 2.29 o 1 7 3 581.37 586.32 8.56 o 2 7 3 117.49 114.69 2.66 o 3 7 3 418.43 423.16 22.29 o 4 7 3 66.79 69.74 2.52 o 5 7 3 293.40 294.39 24.84 o 6 7 3 3.55 4.57 0.49 o 7 7 3 111.66 117.02 12.94 o -7 8 3 64.64 67.42 2.85 o -6 8 3 25.16 26.35 1.08 o -5 8 3 342.38 350.22 9.78 o -4 8 3 93.99 97.09 2.80 o -3 8 3 123.83 122.05 2.93 o -2 8 3 166.26 168.06 3.15 o -1 8 3 1196.57 1211.18 45.93 o 0 8 3 229.88 243.02 12.33 o 1 8 3 75.56 76.32 2.28 o 2 8 3 590.49 617.58 22.98 o 3 8 3 235.88 236.78 13.73 o 4 8 3 316.65 309.84 13.11 o 5 8 3 12.42 13.14 0.59 o 6 8 3 125.07 131.52 12.45 o -7 9 3 36.78 36.22 4.10 o -6 9 3 168.40 176.40 4.35 o -5 9 3 20.23 22.70 2.69 o -4 9 3 178.37 170.25 3.77 o -3 9 3 127.01 125.27 4.71 o -2 9 3 112.23 114.54 3.58 o -1 9 3 72.22 74.84 2.29 o 0 9 3 278.93 295.34 7.62 o 1 9 3 448.38 450.45 11.89 o 2 9 3 28.23 26.25 1.44 o 3 9 3 134.46 127.74 8.53 o 4 9 3 49.33 44.89 3.79 o 5 9 3 256.66 266.75 17.07 o 6 9 3 52.02 51.73 2.10 o -6 10 3 8.11 6.87 2.05 o -5 10 3 163.72 164.03 4.11 o -4 10 3 106.00 110.85 3.22 o -3 10 3 179.80 176.91 3.70 o -2 10 3 178.32 180.13 4.16 o -1 10 3 389.78 384.00 4.99 o 0 10 3 306.88 300.97 8.39 o 1 10 3 106.83 108.65 8.33 o 2 10 3 161.13 156.51 7.74 o 3 10 3 87.12 82.97 6.62 o 4 10 3 66.22 65.04 3.00 o 5 10 3 57.94 60.80 4.15 o 6 10 3 84.76 82.94 5.77 o -6 11 3 86.98 99.46 3.66 o -5 11 3 60.16 60.80 2.05 o 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2.71 o 2 14 3 152.09 151.82 4.22 o 3 14 3 10.29 10.74 0.93 o -3 15 3 31.16 32.17 1.37 o -2 15 3 28.25 26.41 2.06 o -1 15 3 4.98 5.40 0.56 o 0 15 3 126.13 123.18 4.78 o 1 15 3 158.32 156.40 7.38 o 2 15 3 0.03 0.93 1.80 o -8 0 4 110.76 111.35 8.29 o -7 0 4 64.81 63.62 2.58 o -6 0 4 37.07 33.62 2.13 o -5 0 4 741.61 667.18 6.30 o -4 0 4 522.31 529.49 5.07 o -3 0 4 25.66 19.84 0.88 o -2 0 4 1120.05 1162.94 6.10 o -1 0 4 446.09 398.85 5.58 o 0 0 4 821.62 758.91 4.67 o 1 0 4 1378.12 1418.17 31.86 o 2 0 4 234.70 268.61 3.31 o 4 0 4 647.90 637.80 6.70 o 5 0 4 31.58 31.47 1.39 o 6 0 4 18.72 16.99 1.05 o 7 0 4 125.39 137.40 4.35 o -8 1 4 21.18 21.58 0.88 o -7 1 4 131.43 121.90 9.48 o -6 1 4 255.18 237.16 7.80 o -5 1 4 269.29 267.29 14.47 o -4 1 4 69.36 75.63 2.14 o -3 1 4 318.17 338.13 14.62 o -2 1 4 2070.69 1993.21 40.25 o -1 1 4 416.38 433.90 3.59 o 0 1 4 294.21 309.94 3.04 o 1 1 4 2017.14 2008.67 15.55 o 2 1 4 185.65 190.46 2.83 o 3 1 4 96.71 97.78 5.37 o 4 1 4 329.37 349.75 7.49 o 5 1 4 255.44 251.12 4.40 o 6 1 4 72.23 75.08 2.97 o 7 1 4 49.11 45.53 2.07 o -8 2 4 97.16 98.41 3.59 o -7 2 4 55.15 49.67 1.74 o -6 2 4 420.05 394.34 5.41 o -5 2 4 33.48 36.95 1.34 o -4 2 4 56.88 56.23 1.98 o -3 2 4 509.11 512.80 7.54 o -2 2 4 1175.51 1128.63 13.05 o -1 2 4 529.48 503.33 9.78 o 0 2 4 686.02 676.27 15.30 o 1 2 4 2360.73 2404.09 69.94 o 2 2 4 625.90 619.21 13.27 o 3 2 4 142.21 155.85 4.20 o 4 2 4 181.96 179.52 3.45 o 5 2 4 336.66 341.58 22.77 o 6 2 4 41.05 43.25 1.71 o 7 2 4 74.23 73.84 4.33 o -8 3 4 27.02 29.60 1.36 o -7 3 4 106.61 108.97 3.38 o -6 3 4 39.94 43.83 1.92 o -5 3 4 236.53 232.91 3.93 o -4 3 4 1.60 1.27 0.50 o -3 3 4 824.03 805.19 7.77 o -2 3 4 562.26 582.20 12.74 o -1 3 4 1761.01 1725.01 7.47 o 0 3 4 3227.91 3045.10 329.11 o 1 3 4 420.33 428.65 10.92 o 2 3 4 574.45 590.15 11.76 o 3 3 4 3.63 5.38 1.02 o 4 3 4 541.51 549.24 22.57 o 5 3 4 20.21 20.80 0.97 o 6 3 4 207.53 211.49 13.67 o 7 3 4 112.97 113.23 3.81 o -8 4 4 38.79 41.95 2.10 o -7 4 4 42.18 39.22 1.74 o -6 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20.69 23.73 2.14 o -5 9 4 109.90 107.01 6.38 o -4 9 4 33.46 32.39 1.46 o -3 9 4 295.22 290.96 4.61 o -2 9 4 183.01 183.37 3.62 o -1 9 4 395.78 388.06 11.75 o 0 9 4 975.08 964.74 23.53 o 1 9 4 210.89 200.65 3.81 o 2 9 4 97.76 95.33 4.46 o 3 9 4 32.24 32.84 1.45 o 4 9 4 120.31 116.49 3.41 o 5 9 4 55.90 58.45 3.28 o 6 9 4 78.05 82.83 2.84 o -6 10 4 68.80 82.21 3.35 o -5 10 4 40.86 41.91 1.77 o -4 10 4 65.84 64.99 2.66 o -3 10 4 138.31 140.65 5.05 o -2 10 4 252.40 245.61 4.37 o -1 10 4 364.80 364.60 5.06 o 0 10 4 167.13 161.66 3.51 o 1 10 4 203.29 204.12 6.54 o 2 10 4 184.26 187.65 4.48 o 3 10 4 62.84 63.15 6.86 o 4 10 4 64.35 61.38 4.84 o 5 10 4 112.19 114.28 9.13 o -6 11 4 53.85 55.83 2.27 o -5 11 4 81.79 82.04 3.24 o -4 11 4 9.76 10.79 0.59 o -3 11 4 62.38 67.33 2.69 o -2 11 4 202.06 207.57 6.82 o -1 11 4 90.39 92.40 2.88 o 0 11 4 62.08 60.46 2.52 o 1 11 4 384.16 379.22 8.49 o 2 11 4 164.75 158.53 8.70 o 3 11 4 20.46 20.72 1.52 o 4 11 4 51.03 48.76 1.95 o 5 11 4 49.30 47.47 2.15 o -5 12 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