#------------------------------------------------------------------------------ #$Date: 2016-04-03 01:50:10 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181104 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/84/2218484.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2218484_Fobs loop_ _publ_author_name 'Steyn, Maryke' 'Roodt, Andreas' 'Steyl, Gideon' _publ_section_title ; Tetrakis(1,1,1-trifluoroacetylacetonato-\k^2^O,O')zirconium(IV) toluene solvate ; _journal_coeditor_code NG2456 _journal_issue 6 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m827 _journal_volume 64 _journal_year 2008 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 118.383 _cell_angle_gamma 90.000 _cell_length_a 22.5370 _cell_length_b 8.0540 _cell_length_c 22.7860 _exptl_crystal_F_000 1792.00 _reflns_d_resolution_high 0.7828 _cod_data_source_file ng2456Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 7fmast1_0m in Cc' _shelx_refln_list_code 4 _shelx_f_calc_maximum 517.18 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 67964.98 69697.66 1317.59 o 4 0 0 74003.57 74869.32 930.18 o 6 0 0 267475.47 269586.72 3843.21 o 8 0 0 22845.75 23222.92 1024.21 o 10 0 0 11788.57 11771.15 251.52 o 12 0 0 84920.72 83360.95 1924.97 o 14 0 0 121.91 84.48 31.51 o 16 0 0 3497.01 3610.54 127.41 o 18 0 0 12541.89 12256.16 297.25 o 20 0 0 1718.52 1851.29 156.45 o 22 0 0 1089.40 1014.59 135.83 o 24 0 0 1700.35 1505.11 169.37 o 1 1 0 26013.29 28048.78 319.90 o 3 1 0 3741.60 3845.08 45.21 o 5 1 0 117811.91 121907.63 1349.66 o 7 1 0 4105.30 4147.89 76.23 o 9 1 0 779.54 763.04 28.17 o 11 1 0 18063.63 19606.64 277.09 o 13 1 0 92.21 166.89 23.39 o 15 1 0 1314.30 1282.64 60.83 o 17 1 0 2968.61 3114.82 83.60 o 19 1 0 225.02 324.74 45.75 o 21 1 0 300.26 297.34 65.53 o 23 1 0 883.72 799.84 90.50 o 25 1 0 105.51 98.36 64.05 o 0 2 0 1902.86 1941.52 35.40 o 2 2 0 53960.61 57146.64 548.26 o 4 2 0 6455.62 6434.96 71.61 o 6 2 0 12914.04 13133.78 163.77 o 8 2 0 2637.47 2730.85 44.74 o 10 2 0 381.97 504.93 21.42 o 12 2 0 1536.44 1637.99 51.82 o 14 2 0 4626.58 4478.90 100.38 o 16 2 0 375.06 350.47 35.73 o 18 2 0 2635.46 2786.60 86.59 o 20 2 0 3702.17 3736.79 107.72 o 22 2 0 608.14 800.93 109.30 o 24 2 0 2402.28 2377.98 177.35 o 1 3 0 13.94 11.13 5.96 o 3 3 0 8703.75 8480.85 82.22 o 5 3 0 2139.33 2206.95 34.53 o 7 3 0 19097.81 19650.87 217.21 o 9 3 0 1682.88 1517.70 37.98 o 11 3 0 5828.00 5848.58 88.47 o 13 3 0 3532.86 3766.30 78.50 o 15 3 0 6539.03 6170.42 128.75 o 17 3 0 3242.84 3163.93 91.81 o 19 3 0 5657.81 5655.04 158.08 o 21 3 0 1853.62 1999.73 105.50 o 23 3 0 2239.27 2599.86 143.24 o 0 4 0 27644.76 28422.30 453.54 o 2 4 0 305.45 438.22 15.67 o 4 4 0 2802.46 3231.39 43.79 o 6 4 0 78.26 151.15 16.14 o 8 4 0 2207.70 2194.48 42.44 o 10 4 0 59.60 65.48 14.25 o 12 4 0 9202.15 9460.46 144.00 o 14 4 0 960.14 938.06 41.48 o 16 4 0 994.51 1176.14 49.61 o 18 4 0 277.81 289.66 37.71 o 20 4 0 1165.97 1084.01 81.87 o 22 4 0 416.42 368.68 57.41 o 1 5 0 13136.08 13380.98 136.05 o 3 5 0 4284.04 4324.41 57.38 o 5 5 0 747.00 753.00 33.88 o 7 5 0 616.99 668.35 27.32 o 9 5 0 515.34 626.60 24.63 o 11 5 0 450.35 407.31 26.55 o 13 5 0 3239.77 3339.50 75.17 o 15 5 0 1711.05 1665.01 61.37 o 17 5 0 20.83 15.12 25.42 o 19 5 0 2.43 3.04 25.95 o 21 5 0 4.40 11.38 30.59 o 0 6 0 3840.89 4174.67 115.10 o 2 6 0 1149.56 1128.17 29.95 o 4 6 0 2121.77 2155.20 39.73 o 6 6 0 4885.68 4979.83 83.89 o 8 6 0 1392.73 1448.69 46.67 o 10 6 0 328.89 351.69 57.55 o 12 6 0 470.25 436.40 29.11 o 14 6 0 2241.49 2323.59 70.00 o 16 6 0 87.65 108.59 35.16 o 18 6 0 326.03 414.52 40.78 o 20 6 0 813.49 903.54 75.34 o 1 7 0 433.89 506.59 36.19 o 3 7 0 5412.75 5550.76 116.26 o 5 7 0 1219.13 1062.22 54.49 o 7 7 0 5198.08 5032.50 163.91 o 9 7 0 1992.32 1943.95 73.15 o 11 7 0 390.08 427.46 42.55 o 13 7 0 799.36 793.94 120.02 o 15 7 0 3322.50 3218.51 161.26 o 17 7 0 104.09 21.09 45.81 o 0 8 0 2317.84 2363.26 143.80 o 2 8 0 260.30 281.78 46.50 o 4 8 0 349.65 424.91 49.24 o 6 8 0 2349.30 2091.13 134.18 o 8 8 0 302.11 310.36 46.59 o 10 8 0 1394.64 1669.02 88.86 o 12 8 0 81.58 68.62 40.51 o 14 8 0 115.49 226.69 114.66 o 1 9 0 8276.92 7873.22 218.16 o 3 9 0 3425.04 3469.51 131.73 o 5 9 0 5429.83 5165.90 255.71 o 7 9 0 2097.92 2032.07 99.80 o 9 9 0 4181.45 4016.89 238.66 o 11 9 0 1371.44 1408.80 89.97 o 0 10 0 0.64 126.21 68.46 o 2 10 0 10.71 40.16 44.92 o 4 10 0 350.75 268.84 53.95 o -25 1 1 1313.80 1352.89 150.95 o -23 1 1 22.33 -55.10 39.13 o -21 1 1 1991.79 2040.40 116.79 o -19 1 1 11955.68 11941.89 245.95 o -17 1 1 36.50 55.96 22.89 o -15 1 1 5465.99 5244.21 106.76 o -13 1 1 6579.39 6555.29 119.23 o -11 1 1 754.38 577.77 29.99 o -9 1 1 2198.03 1947.41 87.51 o -7 1 1 6007.75 6240.11 105.92 o -5 1 1 17945.75 19104.59 203.16 o -3 1 1 1790.91 1898.35 37.04 o -1 1 1 91027.43 99350.95 1104.18 o 1 1 1 48661.52 51200.58 368.38 o 3 1 1 40799.51 41630.09 419.03 o 5 1 1 46850.31 46242.35 474.81 o 7 1 1 13275.58 13043.18 172.13 o 9 1 1 5204.16 4825.82 89.68 o 11 1 1 29955.73 30223.86 409.89 o 13 1 1 4331.79 4462.62 95.06 o 15 1 1 2167.89 2043.75 65.61 o 17 1 1 2908.96 2908.64 101.13 o 19 1 1 4536.11 4518.39 173.49 o 21 1 1 21.17 20.07 46.49 o 23 1 1 2741.35 2765.71 147.75 o -24 2 1 820.75 957.70 170.20 o -22 2 1 242.97 309.08 78.09 o -20 2 1 6316.35 6251.24 141.74 o -18 2 1 1146.65 1032.56 93.56 o -16 2 1 448.58 512.97 45.53 o -14 2 1 2071.64 1994.01 55.35 o -12 2 1 1519.00 1448.63 38.92 o -10 2 1 508.49 572.05 29.23 o -8 2 1 15973.84 16686.73 230.71 o -6 2 1 1281.42 1532.04 31.26 o -4 2 1 7541.30 7406.08 98.70 o -2 2 1 296.73 326.34 12.28 o 0 2 1 1210.17 1180.19 18.00 o 2 2 1 184.21 179.37 8.10 o 4 2 1 4969.02 5013.79 59.98 o 6 2 1 18432.89 18620.65 188.43 o 8 2 1 46959.13 45776.03 538.20 o 10 2 1 7876.58 7735.92 117.29 o 12 2 1 3895.70 3822.61 87.61 o 14 2 1 3438.54 3259.38 84.45 o 16 2 1 1423.16 1406.23 59.59 o 18 2 1 2746.01 2772.79 87.31 o 20 2 1 8510.48 8960.85 181.60 o 22 2 1 2305.74 2531.57 140.73 o 24 2 1 714.87 676.92 95.66 o -23 3 1 286.45 280.79 69.81 o -21 3 1 11.04 -10.38 34.88 o -19 3 1 1786.04 1822.54 87.59 o -17 3 1 1260.19 1135.50 56.95 o -15 3 1 258.11 229.68 30.40 o -13 3 1 2349.62 2422.21 59.90 o -11 3 1 2520.12 2977.96 62.87 o -9 3 1 2969.77 3136.15 52.49 o -7 3 1 228.26 467.53 16.75 o -5 3 1 17372.85 18760.18 254.34 o -3 3 1 897.36 1016.55 30.98 o -1 3 1 37.95 45.99 7.10 o 1 3 1 188.98 184.45 13.22 o 3 3 1 8046.06 8728.33 80.64 o 5 3 1 58876.72 62756.81 593.96 o 7 3 1 14867.21 15724.93 180.37 o 9 3 1 5133.01 5028.24 93.64 o 11 3 1 129.28 187.24 19.92 o 13 3 1 474.02 507.74 31.52 o 15 3 1 73.67 93.26 22.66 o 17 3 1 1285.34 1305.84 61.91 o 19 3 1 1673.74 1655.99 64.04 o 21 3 1 2564.44 2736.84 97.43 o 23 3 1 73.10 49.13 60.83 o -22 4 1 1947.36 1940.32 87.96 o -20 4 1 395.80 490.49 46.51 o -18 4 1 4907.90 4858.84 116.85 o -16 4 1 5778.67 5834.34 111.70 o -14 4 1 11860.06 11721.66 173.82 o -12 4 1 7903.78 7790.50 109.56 o -10 4 1 8813.91 8974.38 116.42 o -8 4 1 18018.14 18248.84 205.02 o -6 4 1 22265.24 22571.73 305.92 o -4 4 1 12603.08 12784.97 120.32 o -2 4 1 28934.51 32514.65 279.81 o 0 4 1 42705.45 45536.71 383.85 o 2 4 1 9387.84 9873.48 97.67 o 4 4 1 36083.77 38444.27 348.99 o 6 4 1 13720.06 14360.41 155.69 o 8 4 1 4042.36 4218.86 78.41 o 10 4 1 2598.99 2862.48 56.06 o 12 4 1 4976.42 5014.90 94.53 o 14 4 1 958.04 1032.46 44.42 o 16 4 1 8488.39 8270.26 159.02 o 18 4 1 651.41 536.85 46.16 o 20 4 1 10.21 -31.26 46.51 o 22 4 1 1633.23 1583.19 96.86 o -21 5 1 860.78 922.59 58.87 o -19 5 1 887.39 768.11 54.97 o -17 5 1 2269.68 2371.46 76.07 o -15 5 1 439.56 588.96 38.29 o -13 5 1 7225.62 7718.08 126.09 o -11 5 1 2477.58 2695.98 59.45 o -9 5 1 2230.51 2229.69 49.14 o -7 5 1 8013.74 8400.57 119.08 o -5 5 1 26486.65 27112.44 275.38 o -3 5 1 1881.80 1935.68 34.76 o -1 5 1 10212.79 10559.36 120.26 o 1 5 1 5750.96 5708.34 72.85 o 3 5 1 3611.31 3590.48 51.58 o 5 5 1 5248.41 5245.50 67.18 o 7 5 1 1996.28 1915.35 40.82 o 9 5 1 141.17 129.17 16.10 o 11 5 1 4473.42 4374.44 88.06 o 13 5 1 5590.29 5517.72 104.60 o 15 5 1 140.22 140.88 29.20 o 17 5 1 1692.81 1702.00 68.72 o 19 5 1 54.75 106.34 33.78 o 21 5 1 826.90 929.72 78.32 o -20 6 1 915.67 823.85 70.80 o -18 6 1 278.41 287.54 33.52 o -16 6 1 4.22 -2.61 21.53 o -14 6 1 1495.81 1666.44 55.74 o -12 6 1 7.15 20.33 24.94 o -10 6 1 677.98 769.14 41.57 o -8 6 1 591.94 574.13 31.91 o -6 6 1 34.99 62.65 14.98 o -4 6 1 1638.17 1560.22 33.13 o -2 6 1 4347.47 4485.84 64.84 o 0 6 1 1652.40 1621.87 43.49 o 2 6 1 4982.76 5057.98 66.42 o 4 6 1 429.77 447.36 21.67 o 6 6 1 170.67 190.84 19.82 o 8 6 1 3955.17 3957.21 81.87 o 10 6 1 4457.69 4360.62 98.97 o 12 6 1 287.86 303.34 27.38 o 14 6 1 1333.10 1387.55 51.31 o 16 6 1 6.05 -16.44 23.85 o 18 6 1 90.82 146.50 31.97 o 20 6 1 59.42 59.31 47.78 o -19 7 1 1267.82 1412.65 123.32 o -17 7 1 269.59 311.37 78.78 o -15 7 1 701.60 673.42 66.71 o -13 7 1 990.23 961.09 77.95 o -11 7 1 228.85 276.60 38.49 o -9 7 1 206.99 214.48 31.46 o -7 7 1 6202.61 6192.47 141.57 o -5 7 1 2022.90 2222.76 75.13 o -3 7 1 670.93 677.35 45.24 o -1 7 1 1806.48 1877.12 83.42 o 1 7 1 1305.26 1167.03 73.22 o 3 7 1 421.13 410.37 34.47 o 5 7 1 10728.90 10748.62 208.69 o 7 7 1 7469.28 7270.48 159.51 o 9 7 1 8319.98 8298.55 177.93 o 11 7 1 1373.83 1467.94 83.55 o 13 7 1 2396.31 2307.43 109.32 o 15 7 1 3619.45 3659.42 300.39 o 17 7 1 594.50 473.82 68.70 o -16 8 1 1378.49 1323.92 165.25 o -14 8 1 2751.91 2837.35 121.30 o -12 8 1 1028.61 991.99 105.72 o -10 8 1 2111.40 2240.53 97.68 o -8 8 1 1114.20 1254.06 73.69 o -6 8 1 6732.48 6364.28 178.16 o -4 8 1 3118.95 2731.04 105.94 o -2 8 1 5638.81 5570.36 181.20 o 0 8 1 3605.82 3759.49 262.58 o 2 8 1 3910.22 3955.15 134.43 o 4 8 1 3289.74 3123.60 149.99 o 6 8 1 3450.61 3470.09 125.97 o 8 8 1 376.00 325.87 76.99 o 10 8 1 3203.73 3007.40 122.72 o 12 8 1 1158.44 1281.29 88.40 o 14 8 1 6246.78 6355.00 203.72 o -11 9 1 71.10 172.12 84.41 o -9 9 1 9.83 19.52 36.66 o -7 9 1 97.43 76.42 66.95 o -5 9 1 1604.54 1799.74 95.35 o -3 9 1 0.52 -0.38 34.37 o -1 9 1 40.43 -37.59 56.92 o 1 9 1 1.69 -61.62 30.81 o 3 9 1 12.50 -23.16 30.74 o 5 9 1 696.75 814.19 69.02 o 7 9 1 0.44 -24.71 45.51 o 9 9 1 7.83 16.36 37.76 o 11 9 1 108.49 64.47 43.35 o -6 10 1 519.32 483.78 63.95 o -4 10 1 1354.66 1399.82 91.66 o -2 10 1 4038.01 3956.42 153.05 o 0 10 1 176.71 116.86 47.04 o 2 10 1 4398.38 4516.15 164.49 o 4 10 1 603.82 666.60 70.20 o -26 0 2 1922.41 1603.27 173.50 o -24 0 2 2.24 -92.66 63.52 o -22 0 2 2814.05 3355.30 215.57 o -20 0 2 16567.88 15978.85 541.39 o -18 0 2 2254.72 2437.67 103.79 o -16 0 2 15618.40 16310.27 353.05 o -14 0 2 18485.87 17905.92 371.00 o -12 0 2 4.84 31.03 21.95 o -10 0 2 44977.93 44240.15 806.91 o -8 0 2 63993.86 63678.86 2156.47 o -6 0 2 29426.51 32342.06 558.72 o -4 0 2 2415.89 2966.60 47.56 o -2 0 2 14123.09 14308.13 419.45 o 2 0 2 903.65 1158.43 28.34 o 4 0 2 57347.02 55808.80 873.80 o 6 0 2 135.49 328.95 40.56 o 8 0 2 55287.68 56441.74 1021.09 o 10 0 2 9602.96 9734.79 580.30 o 12 0 2 21537.77 20127.93 416.70 o 14 0 2 10638.26 10942.93 445.57 o 16 0 2 10143.34 10429.86 262.06 o 18 0 2 933.85 995.18 75.95 o 20 0 2 2412.35 2351.71 180.37 o 22 0 2 289.00 236.19 92.39 o 24 0 2 436.47 420.41 117.68 o -25 1 2 106.26 37.73 95.41 o -23 1 2 42.56 75.75 52.31 o -21 1 2 2118.42 2135.61 144.21 o -19 1 2 449.42 480.83 49.00 o -17 1 2 3169.11 3415.95 84.71 o -15 1 2 3180.32 3121.02 76.04 o -13 1 2 2951.63 3179.28 72.85 o -11 1 2 4687.40 4834.93 80.24 o -9 1 2 25451.17 26871.56 373.05 o -7 1 2 4967.98 4805.56 68.31 o -5 1 2 47234.03 46996.98 530.71 o -3 1 2 11150.66 11703.70 180.81 o -1 1 2 16521.77 17431.98 144.31 o 1 1 2 4891.53 5026.14 40.01 o 3 1 2 46494.20 45943.63 458.46 o 5 1 2 950.38 963.01 24.14 o 7 1 2 29298.11 29138.12 327.25 o 9 1 2 26507.23 26094.72 355.68 o 11 1 2 7772.77 8151.10 140.64 o 13 1 2 495.20 421.26 33.16 o 15 1 2 146.14 110.33 31.17 o 17 1 2 25.22 78.88 26.63 o 19 1 2 3728.81 3586.89 138.99 o 21 1 2 2256.73 2331.09 133.13 o 23 1 2 2.58 -21.04 54.03 o -24 2 2 771.50 823.64 91.01 o -22 2 2 510.79 342.68 56.95 o -20 2 2 466.59 440.09 60.83 o -18 2 2 834.68 831.04 77.09 o -16 2 2 2600.03 2512.26 110.69 o -14 2 2 3487.31 3837.24 108.98 o -12 2 2 11476.08 11788.04 182.91 o -10 2 2 395.02 578.77 50.80 o -8 2 2 6950.78 7215.08 164.48 o -6 2 2 5128.12 5577.53 109.68 o -4 2 2 1.11 18.88 11.37 o -2 2 2 305.52 255.73 15.94 o 0 2 2 6892.24 7129.21 88.20 o 2 2 2 10394.64 10464.50 117.53 o 4 2 2 5364.13 5523.44 73.05 o 6 2 2 26748.99 26768.37 287.87 o 8 2 2 6647.50 6220.06 96.94 o 10 2 2 14572.59 14551.58 192.53 o 12 2 2 6643.71 6727.76 110.06 o 14 2 2 6992.56 6617.12 121.70 o 16 2 2 978.21 882.16 49.97 o 18 2 2 1277.93 1366.62 63.78 o 20 2 2 841.49 954.10 73.12 o 22 2 2 1277.61 1135.13 104.47 o -25 3 2 996.46 1069.47 188.62 o -23 3 2 1516.40 1478.13 88.93 o -21 3 2 2396.89 2324.77 102.69 o -19 3 2 1081.79 1303.55 78.48 o -17 3 2 758.27 998.70 69.05 o -15 3 2 4214.15 4253.63 99.91 o -13 3 2 5905.64 6119.45 119.61 o -11 3 2 8129.87 8055.97 119.89 o -9 3 2 9308.83 9646.49 131.23 o -7 3 2 14154.92 13926.07 199.33 o -5 3 2 940.05 883.70 40.22 o -3 3 2 37794.91 40679.66 423.46 o -1 3 2 817.36 647.75 17.33 o 1 3 2 4444.61 4230.78 44.39 o 3 3 2 18322.35 18803.98 167.16 o 5 3 2 3889.33 4127.36 57.31 o 7 3 2 21610.80 21716.82 242.19 o 9 3 2 15822.72 16046.15 191.16 o 11 3 2 5009.01 5300.98 95.87 o 13 3 2 2350.57 2523.27 65.47 o 15 3 2 6798.82 7035.85 127.23 o 17 3 2 1896.35 1860.24 92.04 o 19 3 2 5045.37 5171.78 131.34 o 21 3 2 3437.61 3198.70 126.74 o 23 3 2 1508.34 1668.25 146.69 o -24 4 2 271.19 203.33 55.25 o -22 4 2 437.91 568.66 50.55 o -20 4 2 3923.13 3859.57 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53.08 o -11 3 26 2653.33 2710.99 150.79 o -9 3 26 1010.34 985.59 76.64 o -7 3 26 2326.58 2621.56 121.54 o -5 3 26 2115.26 2290.88 112.17 o -16 4 26 2116.54 2191.39 104.09 o -14 4 26 110.53 143.56 53.73 o -12 4 26 348.93 262.67 51.47 o -10 4 26 113.95 47.98 41.67 o -8 4 26 6.15 -28.47 38.35 o -21 1 27 92.01 104.44 53.10 o -19 1 27 1108.61 1185.44 96.51 o -17 1 27 1540.13 1730.99 108.97 o -15 1 27 661.78 677.68 76.41 o -13 1 27 564.16 597.46 74.45 o -11 1 27 416.02 383.38 67.41 o -9 1 27 120.96 72.29 45.95 o -7 1 27 964.17 1089.13 74.13 o -5 1 27 1008.84 969.45 123.34 o -20 2 27 2539.36 2815.29 139.59 o -18 2 27 1837.54 1877.64 114.55 o -16 2 27 686.55 590.50 159.48 o -14 2 27 644.95 707.21 78.35 o -12 2 27 1357.79 1418.30 87.12 o -10 2 27 1677.59 1360.98 87.68 o -8 2 27 2711.06 3105.98 111.62 o -6 2 27 1632.53 1918.85 104.69 o -17 3 27 1700.19 2065.91 204.84 o -15 3 27 1584.94 1577.10 91.71 o -13 3 27 143.37 121.96 45.54 o -11 3 27 11.89 14.57 41.18 o -9 3 27 27.93 6.69 41.74 o -7 3 27 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