#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/88/2218824.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2218824_Fobs loop_ _publ_author_name 'Singh, Udai P.' 'Aggarwal, Vaibhave' _publ_section_title ; Hydrogen-bonding and \p--\p stacking interactions in tris(1,10-phenanthroline-\k^2^N,N')nickel(II) bis{[1-tert-butylimidazole-2(3H)-thione-\kS]trichloridonickelate(II)} acetonitrile disolvate ; _journal_coeditor_code SU2050 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m935 _journal_page_last m936 _journal_volume 64 _journal_year 2008 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 123.543 _cell_angle_gamma 90.000 _cell_length_a 22.8953 _cell_length_b 15.2934 _cell_length_c 19.9417 _exptl_crystal_F_000 2720.00 _reflns_d_resolution_high 0.8713 _[local]_cod_data_source_file su2050Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' newone in C2/c' _shelx_refln_list_code 4 _shelx_F_calc_maximum 801.00 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 73026.50 64493.28 3714.60 o 4 0 0 58544.36 54918.28 1370.28 o 6 0 0 40930.34 36737.58 1080.10 o 8 0 0 27.20 -82.20 82.20 o 10 0 0 115.65 168.31 124.60 o 12 0 0 10373.88 11145.75 558.13 o 14 0 0 8925.23 9024.44 383.85 o 16 0 0 140.86 8.60 155.55 o 18 0 0 825.29 1182.69 238.80 o 20 0 0 1639.37 1679.02 278.72 o 1 1 0 5214.60 2993.20 340.47 o 3 1 0 89755.56 86682.84 1827.14 o 5 1 0 58285.84 56776.30 1473.28 o 7 1 0 235959.28 220525.06 5026.27 o 9 1 0 19966.26 18840.63 473.00 o 11 1 0 116.43 30.80 76.18 o 13 1 0 845.74 1047.69 106.80 o 15 1 0 3850.87 4318.90 180.25 o 17 1 0 12055.33 11836.06 407.42 o 19 1 0 2349.02 2647.19 218.88 o 21 1 0 360.74 482.60 215.45 o 0 2 0 250387.56 238980.67 5224.86 o 2 2 0 4944.68 4826.40 130.61 o 4 2 0 72831.78 67453.34 1170.79 o 6 2 0 7079.58 6890.54 166.84 o 8 2 0 1294.19 1530.13 92.72 o 10 2 0 27502.02 23418.84 567.99 o 12 2 0 1065.03 1122.98 107.31 o 14 2 0 3681.05 3485.13 160.05 o 16 2 0 2899.59 3358.45 163.85 o 18 2 0 757.42 820.68 170.92 o 20 2 0 3957.99 3975.01 430.82 o 1 3 0 11327.06 10278.42 213.50 o 3 3 0 36588.69 34497.64 610.58 o 5 3 0 4028.27 3837.06 119.39 o 7 3 0 18056.23 15630.06 340.06 o 9 3 0 1412.14 1085.68 99.87 o 11 3 0 751.83 548.02 93.43 o 13 3 0 18352.16 18174.20 468.00 o 15 3 0 113.14 0.23 96.06 o 17 3 0 9535.81 10527.29 356.87 o 19 3 0 1883.37 2202.64 254.78 o 21 3 0 28.99 137.29 213.28 o 0 4 0 10839.53 9875.97 253.48 o 2 4 0 30698.56 29652.20 562.87 o 4 4 0 29576.10 30472.87 566.94 o 6 4 0 14180.56 13498.60 287.80 o 8 4 0 5088.82 5488.60 164.85 o 10 4 0 18316.99 18207.45 459.76 o 12 4 0 5940.82 5704.02 209.25 o 14 4 0 735.28 627.94 117.03 o 16 4 0 17104.39 18935.50 627.11 o 18 4 0 3460.35 4176.93 432.05 o 20 4 0 6162.46 6710.18 574.04 o 1 5 0 34050.36 30766.29 512.99 o 3 5 0 4907.87 4412.19 122.21 o 5 5 0 4933.45 4952.18 147.20 o 7 5 0 7282.65 6685.83 199.94 o 9 5 0 13795.65 12712.64 302.42 o 11 5 0 1114.61 1132.86 112.47 o 13 5 0 22600.08 22812.40 575.49 o 15 5 0 278.84 333.09 121.55 o 17 5 0 297.34 720.54 158.95 o 19 5 0 194.92 86.86 208.20 o 0 6 0 1824.81 1461.85 133.33 o 2 6 0 953.10 1057.88 70.21 o 4 6 0 8001.04 6951.23 173.39 o 6 6 0 28089.58 28709.55 623.28 o 8 6 0 7048.27 7288.61 200.31 o 10 6 0 2000.11 2039.27 114.13 o 12 6 0 3688.70 3379.81 169.27 o 14 6 0 1325.80 1482.68 157.14 o 16 6 0 6325.96 6612.84 326.22 o 18 6 0 217.94 59.96 211.42 o 20 6 0 2868.96 3235.61 310.36 o 1 7 0 9259.49 7932.85 184.15 o 3 7 0 5186.61 4915.48 143.13 o 5 7 0 3101.35 2981.22 114.33 o 7 7 0 1976.99 2044.46 106.79 o 9 7 0 1224.73 1200.31 95.12 o 11 7 0 8989.15 8472.36 242.59 o 13 7 0 2522.80 2668.19 158.71 o 15 7 0 657.49 683.97 150.77 o 17 7 0 253.27 208.38 249.47 o 19 7 0 950.48 1140.75 320.88 o 0 8 0 34714.55 33914.67 797.66 o 2 8 0 876.49 912.01 77.56 o 4 8 0 22124.24 20713.88 382.07 o 6 8 0 438.00 378.86 80.40 o 8 8 0 7471.23 6897.87 215.95 o 10 8 0 1467.33 1259.37 104.47 o 12 8 0 5.78 58.22 103.50 o 14 8 0 1516.87 1424.86 139.71 o 16 8 0 2987.91 3227.97 498.82 o 18 8 0 6917.79 8291.13 652.68 o 1 9 0 866.16 762.18 81.75 o 3 9 0 4456.33 4051.99 135.91 o 5 9 0 1308.93 1349.11 97.43 o 7 9 0 5834.93 5519.54 172.20 o 9 9 0 181.49 73.10 93.77 o 11 9 0 12708.43 12576.85 331.62 o 13 9 0 27.61 22.74 105.80 o 15 9 0 4793.93 6113.24 311.90 o 17 9 0 8.96 125.70 403.27 o 0 10 0 16994.39 17106.77 510.53 o 2 10 0 2493.35 2403.01 107.17 o 4 10 0 12041.30 12220.59 254.23 o 6 10 0 1142.32 1120.90 111.62 o 8 10 0 1954.55 1730.46 127.23 o 10 10 0 1350.87 1259.14 122.28 o 12 10 0 25.74 25.25 95.41 o 14 10 0 1695.10 3032.13 600.13 o 16 10 0 58.00 719.87 441.66 o 18 10 0 3467.85 3432.52 536.50 o 1 11 0 11561.32 11132.21 254.91 o 3 11 0 1169.97 1306.34 100.47 o 5 11 0 2811.57 2864.95 128.38 o 7 11 0 306.15 175.41 92.50 o 9 11 0 10.76 -43.45 105.36 o 11 11 0 2277.20 2304.50 144.36 o 13 11 0 490.03 624.54 168.87 o 15 11 0 3146.79 3919.78 300.92 o 0 12 0 235.96 22.03 134.88 o 2 12 0 14639.63 14911.68 311.93 o 4 12 0 898.06 954.85 103.18 o 6 12 0 387.63 411.17 106.67 o 8 12 0 197.29 264.85 109.35 o 10 12 0 452.83 572.27 125.37 o 12 12 0 1216.89 1328.57 150.31 o 14 12 0 198.78 613.38 362.06 o 1 13 0 1628.05 1812.19 125.12 o 3 13 0 145.05 118.90 108.11 o 5 13 0 11979.87 12563.53 338.34 o 7 13 0 3385.50 3775.64 193.96 o 9 13 0 2484.64 2627.05 168.65 o 11 13 0 289.73 244.60 132.81 o 13 13 0 1341.25 1413.51 199.10 o 0 14 0 7160.88 7723.67 338.33 o 2 14 0 6927.62 7032.22 229.90 o 4 14 0 485.24 613.09 127.48 o 6 14 0 1196.48 1341.12 144.14 o 8 14 0 1684.87 1981.49 159.10 o 10 14 0 293.12 324.17 149.80 o 12 14 0 5117.08 5322.15 264.88 o 1 15 0 1974.42 1864.14 194.75 o 3 15 0 101.71 -57.90 127.92 o 5 15 0 6440.60 7068.64 262.59 o 7 15 0 73.45 225.64 132.14 o 9 15 0 2116.92 2504.85 238.66 o 11 15 0 16.64 -49.78 184.96 o 0 16 0 39.35 -183.09 183.09 o 2 16 0 3120.66 3297.02 219.63 o 4 16 0 0.90 45.50 136.55 o 6 16 0 107.34 152.07 145.25 o 8 16 0 1774.23 1932.27 219.51 o 1 17 0 204.56 523.08 160.91 o 3 17 0 286.53 358.41 152.64 o 5 17 0 3640.60 4488.36 394.79 o -21 1 1 126.27 118.01 196.75 o -19 1 1 305.90 324.00 129.99 o -17 1 1 9.58 -95.40 95.40 o -15 1 1 35.84 -31.56 92.39 o -13 1 1 416.64 351.07 93.57 o -11 1 1 1358.10 1179.64 113.23 o -9 1 1 10012.44 9151.41 278.07 o -7 1 1 2870.18 2524.30 96.30 o -5 1 1 3917.73 3981.81 151.07 o -3 1 1 4350.99 3912.02 166.28 o -1 1 1 2258.11 2194.65 90.90 o 1 1 1 2427.12 2194.21 70.73 o 3 1 1 835.69 733.22 60.03 o 5 1 1 3975.47 3605.65 125.89 o 7 1 1 4.29 9.56 59.11 o 9 1 1 104.25 11.93 68.06 o 11 1 1 731.83 753.84 89.40 o 13 1 1 3.36 -10.82 81.96 o 15 1 1 17.03 -32.09 92.08 o 17 1 1 1573.68 1544.06 191.02 o 19 1 1 113.38 -37.90 160.94 o 21 1 1 0.57 149.82 287.54 o -22 2 1 447.62 -45.00 269.23 o -20 2 1 39.68 -157.90 192.87 o -18 2 1 598.32 320.73 115.04 o -16 2 1 426.99 322.14 101.20 o -14 2 1 15.34 -88.88 88.88 o -12 2 1 6761.33 5805.56 225.28 o -10 2 1 901.75 841.51 89.45 o -8 2 1 12668.86 11396.12 275.41 o -6 2 1 64.05 87.54 67.83 o -4 2 1 25335.53 23593.83 484.71 o -2 2 1 9726.13 9179.14 207.94 o 0 2 1 1003.36 1055.36 96.22 o 2 2 1 328.56 235.94 43.03 o 4 2 1 8903.33 8847.51 185.69 o 6 2 1 2880.80 2577.17 112.16 o 8 2 1 1063.84 1037.27 79.70 o 10 2 1 456.06 495.20 85.38 o 12 2 1 3.57 -76.41 76.41 o 14 2 1 2.22 -83.62 83.62 o 16 2 1 2178.21 2050.92 164.22 o 18 2 1 388.61 52.58 166.16 o 20 2 1 351.36 393.05 215.91 o -21 3 1 285.04 4.74 202.63 o -19 3 1 4468.18 4609.67 268.13 o -17 3 1 207.17 96.04 138.35 o -15 3 1 1044.05 1336.50 136.70 o -13 3 1 145.61 -14.02 96.55 o -11 3 1 216.37 -23.18 79.16 o -9 3 1 17375.94 16807.77 378.04 o -7 3 1 3234.05 2999.82 107.19 o -5 3 1 1.07 -10.17 53.12 o -3 3 1 76.38 -13.45 61.30 o -1 3 1 134676.33 129235.15 2188.27 o 1 3 1 10694.83 11455.56 214.20 o 3 3 1 5560.47 5481.63 134.57 o 5 3 1 21530.26 20205.79 417.21 o 7 3 1 980.04 1145.61 95.24 o 9 3 1 4302.29 3126.44 137.38 o 11 3 1 55.37 28.85 84.98 o 13 3 1 179.37 21.34 90.30 o 15 3 1 1529.48 1493.58 139.51 o 17 3 1 3956.26 4253.46 252.60 o 19 3 1 972.21 1200.54 229.68 o -20 4 1 420.71 795.67 223.37 o -18 4 1 201.66 230.31 148.66 o -16 4 1 710.42 680.64 130.30 o -14 4 1 2352.82 2324.76 165.91 o -12 4 1 7379.26 6711.81 340.40 o -10 4 1 69.95 12.54 73.42 o -8 4 1 680.64 480.04 77.46 o -6 4 1 2269.46 2416.41 86.58 o -4 4 1 57.53 50.49 58.68 o -2 4 1 33812.77 32981.53 567.89 o 0 4 1 16899.64 15278.25 275.08 o 2 4 1 147336.84 143789.20 2485.24 o 4 4 1 19520.83 19515.41 391.14 o 6 4 1 25429.60 23691.57 516.09 o 8 4 1 18741.28 16956.99 389.91 o 10 4 1 1777.57 1720.37 117.98 o 12 4 1 196.41 -78.44 137.95 o 14 4 1 1902.04 2066.26 133.47 o 16 4 1 2565.82 2747.10 221.42 o 18 4 1 186.56 265.61 190.44 o 20 4 1 101.60 -64.75 216.61 o -21 5 1 1073.91 1204.97 252.10 o -19 5 1 10973.47 12994.04 445.41 o -17 5 1 394.98 397.84 133.86 o -15 5 1 254.71 149.24 114.85 o -13 5 1 2322.32 2212.51 192.18 o -11 5 1 1067.10 885.43 98.24 o -9 5 1 6409.04 5743.05 182.52 o -7 5 1 2734.55 2559.57 99.42 o -5 5 1 7047.28 6311.94 164.78 o -3 5 1 327.74 270.46 63.73 o -1 5 1 36108.34 34463.39 532.41 o 1 5 1 34339.49 32820.06 550.29 o 3 5 1 44335.69 42875.53 770.08 o 5 5 1 532.41 837.90 86.48 o 7 5 1 8054.46 7151.42 232.88 o 9 5 1 12558.73 12268.20 308.86 o 11 5 1 1491.42 1220.21 114.22 o 13 5 1 481.57 600.25 111.84 o 15 5 1 2526.57 2624.26 194.03 o 17 5 1 2062.35 2654.32 239.58 o 19 5 1 1938.73 1820.77 268.82 o -20 6 1 1378.26 1557.28 265.49 o -18 6 1 2004.51 3026.30 341.64 o -16 6 1 2051.97 2081.29 170.73 o -14 6 1 1401.42 1341.92 141.17 o -12 6 1 4606.36 4266.85 173.49 o -10 6 1 1.13 -79.25 79.25 o -8 6 1 1022.16 596.01 80.00 o -6 6 1 12839.61 12794.72 267.14 o -4 6 1 1246.20 1094.55 76.87 o -2 6 1 11852.74 10499.07 212.42 o 0 6 1 1324.03 1316.29 71.65 o 2 6 1 13752.47 13078.97 271.30 o 4 6 1 7582.15 6392.89 172.03 o 6 6 1 36777.11 34817.54 699.11 o 8 6 1 23405.79 21698.57 464.98 o 10 6 1 463.09 276.41 87.59 o 12 6 1 563.94 479.53 109.20 o 14 6 1 558.05 746.39 123.38 o 16 6 1 2895.97 2955.20 207.99 o 18 6 1 851.56 743.35 233.30 o -19 7 1 1132.97 1412.31 239.12 o -17 7 1 4868.58 6127.72 571.58 o -15 7 1 206.71 228.91 122.49 o -13 7 1 8.19 -95.69 95.69 o -11 7 1 4300.57 3729.30 157.30 o -9 7 1 6545.35 6383.36 187.07 o -7 7 1 1242.76 1241.99 93.97 o -5 7 1 1058.01 1163.46 82.56 o -3 7 1 9868.48 9048.63 200.67 o -1 7 1 50161.82 47473.02 808.62 o 1 7 1 36727.38 33429.37 565.18 o 3 7 1 6781.04 5645.93 154.35 o 5 7 1 18305.51 18428.13 372.88 o 7 7 1 1475.18 1312.88 104.08 o 9 7 1 6523.06 6320.88 198.59 o 11 7 1 2628.38 2606.88 145.52 o 13 7 1 2709.05 2900.32 163.14 o 15 7 1 195.22 176.30 180.73 o 17 7 1 87.50 254.50 262.42 o 19 7 1 1436.33 1826.03 361.04 o -20 8 1 68.31 401.93 377.70 o -18 8 1 144.64 480.29 199.32 o -16 8 1 2791.69 3136.36 272.85 o -14 8 1 818.57 956.21 204.03 o -12 8 1 2265.89 2395.07 136.22 o -10 8 1 50.73 -80.25 80.25 o -8 8 1 5841.68 5463.97 222.42 o -6 8 1 12437.07 11490.40 254.17 o -4 8 1 44197.81 43799.52 744.29 o -2 8 1 4490.39 3896.88 122.85 o 0 8 1 541.12 515.51 69.43 o 2 8 1 5789.98 5889.67 159.88 o 4 8 1 18219.35 18099.43 348.15 o 6 8 1 8663.00 7923.38 206.83 o 8 8 1 9742.80 9532.42 266.04 o 10 8 1 6324.44 6161.51 204.36 o 12 8 1 79.65 123.31 104.39 o 14 8 1 405.43 419.22 179.95 o 16 8 1 1020.31 1013.39 180.28 o 18 8 1 186.67 286.30 267.05 o -19 9 1 571.20 403.46 272.35 o -17 9 1 659.47 1116.58 214.61 o -15 9 1 67.78 625.05 255.67 o -13 9 1 557.03 617.00 115.08 o -11 9 1 4393.51 4584.57 178.79 o -9 9 1 3562.01 3550.44 136.32 o -7 9 1 220.53 255.66 83.30 o -5 9 1 66.75 44.91 69.54 o -3 9 1 27917.33 26607.20 482.46 o -1 9 1 10933.59 10642.67 231.84 o 1 9 1 31467.03 29235.55 551.91 o 3 9 1 32925.87 32899.00 573.66 o 5 9 1 2290.17 2331.58 110.45 o 7 9 1 39.61 -68.75 86.65 o 9 9 1 1389.33 1501.05 117.07 o 11 9 1 1057.37 996.14 120.33 o 13 9 1 418.14 425.52 144.23 o 15 9 1 114.48 600.14 160.63 o 17 9 1 217.06 576.92 312.66 o -18 10 1 41.34 520.64 208.64 o -16 10 1 927.64 1088.37 255.49 o -14 10 1 1290.15 1406.28 147.17 o -12 10 1 312.42 472.97 107.72 o -10 10 1 119.20 133.07 91.01 o -8 10 1 2135.04 2143.39 125.85 o -6 10 1 8989.26 8956.34 207.82 o -4 10 1 13498.45 14034.74 287.90 o -2 10 1 554.60 479.47 82.05 o 0 10 1 790.53 708.45 81.72 o 2 10 1 38.96 7.40 79.93 o 4 10 1 13880.26 13585.99 281.67 o 6 10 1 8919.01 8588.48 232.99 o 8 10 1 3025.11 3015.66 150.05 o 10 10 1 2597.14 2635.76 197.88 o 12 10 1 77.91 266.33 134.23 o 14 10 1 614.10 832.01 225.29 o 16 10 1 119.13 268.55 251.38 o -17 11 1 677.97 1001.92 294.52 o -15 11 1 545.16 969.16 347.49 o -13 11 1 1159.54 1308.51 195.86 o -11 11 1 236.86 298.86 107.18 o -9 11 1 11.37 -99.64 99.64 o -7 11 1 1518.10 1596.49 109.06 o -5 11 1 409.13 396.00 82.83 o -3 11 1 5722.20 5542.49 162.92 o -1 11 1 6154.37 6266.37 177.38 o 1 11 1 5418.45 5037.98 160.49 o 3 11 1 11810.71 12313.96 271.41 o 5 11 1 15.43 -85.16 85.16 o 7 11 1 193.37 114.65 96.05 o 9 11 1 41.39 -57.57 101.74 o 11 11 1 1197.26 1197.83 157.36 o 13 11 1 294.66 349.94 162.11 o 15 11 1 203.27 406.50 179.01 o -16 12 1 6.22 102.05 203.48 o -14 12 1 4954.74 4920.59 410.96 o -12 12 1 8.45 -59.12 113.79 o -10 12 1 241.71 160.53 117.07 o -8 12 1 63.75 -0.53 101.40 o -6 12 1 613.37 647.70 104.28 o -4 12 1 1249.52 1178.48 105.53 o -2 12 1 1741.01 1656.47 113.69 o 0 12 1 2881.51 2854.09 143.46 o 2 12 1 154.20 48.09 92.02 o 4 12 1 2727.34 2746.25 135.74 o 6 12 1 657.94 593.27 109.58 o 8 12 1 281.99 248.37 115.40 o 10 12 1 345.01 277.82 116.29 o 12 12 1 558.82 655.34 152.61 o 14 12 1 1497.95 1925.07 219.44 o -15 13 1 868.38 969.42 231.22 o -13 13 1 112.80 206.67 214.03 o -11 13 1 82.34 102.01 122.52 o -9 13 1 21.54 -33.25 121.58 o -7 13 1 2661.84 2765.56 166.29 o -5 13 1 2811.94 2727.24 149.84 o -3 13 1 127.44 174.05 107.09 o -1 13 1 259.44 298.89 110.26 o 1 13 1 361.22 372.72 112.95 o 3 13 1 516.80 609.17 116.16 o 5 13 1 34.25 8.07 108.50 o 7 13 1 4857.61 5027.95 212.58 o 9 13 1 40.08 -115.40 115.40 o 11 13 1 186.66 313.92 147.89 o 13 13 1 266.82 259.59 157.42 o -12 14 1 117.60 110.02 155.87 o -10 14 1 2.84 116.18 151.83 o -8 14 1 1614.22 1785.91 167.05 o -6 14 1 31.49 35.61 123.71 o -4 14 1 469.92 673.67 159.08 o -2 14 1 1396.24 1521.37 138.80 o 0 14 1 112.76 -107.11 124.06 o 2 14 1 1247.96 1410.06 146.02 o 4 14 1 1655.63 1586.02 145.38 o 6 14 1 321.60 348.72 150.42 o 8 14 1 249.03 182.04 141.05 o 10 14 1 16.77 -38.35 153.87 o 12 14 1 88.78 70.00 156.40 o -11 15 1 129.85 86.20 164.09 o -9 15 1 347.24 386.88 148.78 o -7 15 1 5.41 -82.99 133.79 o -5 15 1 95.82 55.55 135.47 o -3 15 1 36.07 -58.38 132.52 o -1 15 1 464.19 392.84 125.44 o 1 15 1 126.33 173.73 121.73 o 3 15 1 121.53 133.50 129.56 o 5 15 1 185.54 231.14 131.99 o 7 15 1 846.27 980.43 162.94 o 9 15 1 0.55 -111.59 148.28 o -8 16 1 6.80 97.67 142.68 o -6 16 1 578.95 588.27 154.86 o -4 16 1 119.55 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