#------------------------------------------------------------------------------ #$Date: 2009-05-03 21:56:13 +0300 (Sun, 03 May 2009) $ #$Revision: 691 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2220360.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2220360_Fobs loop_ _publ_author_name 'Liu, Jing' 'Pan, Zhi-Quan' 'Zhou, Hong' 'Li, Yi-Zhi' _publ_section_title ; [\m-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.1^8,12^]tetracosa-1(23),2,6,8,10,12(24),13,17,19,21-decaene-23,24-diolato-\k^4^N^3^,N^6^,O^23^,O^24^:\k^4^N^14^,N^17^,O^23^,O^24^]bis(perchlorato-\kO)dimanganese(II) ; _journal_coeditor_code TK2317 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m1506 _journal_volume 64 _journal_year 2008 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 81.484 _cell_angle_beta 68.520 _cell_angle_gamma 78.838 _cell_length_a 8.3129 _cell_length_b 8.3759 _cell_length_c 9.9712 _exptl_crystal_F_000 346.00 _reflns_d_resolution_high 0.8109 _[local]_cod_data_source_file tk2317Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 80630lj_0m P-1' _shelx_refln_list_code 4 _shelx_F_calc_maximum 187.96 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 2591.21 2581.73 29.85 o 2 0 0 89.19 86.46 22.30 o 3 0 0 325.48 284.76 18.53 o 4 0 0 911.73 836.10 3.77 o 5 0 0 401.42 411.02 20.24 o 6 0 0 1.29 6.86 27.79 o 7 0 0 22.06 48.72 28.13 o 8 0 0 197.01 269.67 50.78 o 9 0 0 0.03 0.00 25.73 o -9 1 0 0.94 6.18 18.53 o -8 1 0 88.51 101.55 11.32 o -7 1 0 346.56 310.15 39.11 o -6 1 0 67.10 74.79 16.47 o -5 1 0 416.15 387.69 1.03 o -4 1 0 8.41 7.55 14.99 o -3 1 0 340.61 322.25 5.49 o -2 1 0 30.87 37.83 7.63 o -1 1 0 162.90 184.08 22.32 o 0 1 0 5254.03 4976.82 45.63 o 1 1 0 3834.99 3834.34 47.35 o 2 1 0 2665.20 2466.69 21.61 o 3 1 0 211.51 281.02 30.72 o 4 1 0 791.17 887.76 43.57 o 5 1 0 371.11 317.36 8.23 o 6 1 0 451.26 456.31 30.53 o 7 1 0 128.78 147.53 7.55 o 8 1 0 0.30 4.46 13.04 o 9 1 0 11.14 20.59 15.44 o -8 2 0 62.85 127.97 48.72 o -7 2 0 141.22 176.00 38.08 o -6 2 0 884.31 804.81 13.90 o -5 2 0 439.83 442.64 16.51 o -4 2 0 602.61 649.55 26.34 o -3 2 0 525.13 515.06 19.27 o -2 2 0 1533.50 1463.61 33.88 o -1 2 0 233.90 262.92 16.35 o 0 2 0 2848.95 2737.84 40.83 o 1 2 0 18.02 25.05 40.48 o 2 2 0 640.85 687.10 25.97 o 3 2 0 1266.00 1259.66 36.54 o 4 2 0 1068.57 1230.75 24.70 o 5 2 0 411.69 441.21 23.33 o 6 2 0 379.92 377.05 15.10 o 7 2 0 67.45 85.77 7.55 o 8 2 0 79.06 102.58 30.88 o 9 2 0 184.54 203.79 27.79 o -8 3 0 81.60 128.31 24.36 o -7 3 0 3.06 26.07 28.48 o -6 3 0 15.60 14.41 3.77 o -5 3 0 80.39 76.51 5.83 o -4 3 0 2.53 20.23 11.11 o -3 3 0 23.05 23.55 25.68 o -2 3 0 1389.58 1307.10 10.04 o -1 3 0 587.60 611.10 11.06 o 0 3 0 313.43 309.33 21.55 o 1 3 0 1082.79 1221.73 36.02 o 2 3 0 674.37 825.81 29.85 o 3 3 0 318.06 303.47 4.29 o 4 3 0 880.62 913.66 24.05 o 5 3 0 124.50 219.23 50.78 o 6 3 0 4.50 12.69 2.06 o 7 3 0 18.92 35.68 35.34 o 8 3 0 22.61 33.97 12.35 o 9 3 0 118.97 125.91 44.26 o -8 4 0 63.01 76.51 45.29 o -7 4 0 9.64 21.61 20.59 o -6 4 0 250.31 238.10 20.24 o -5 4 0 578.08 547.57 9.61 o -4 4 0 380.53 370.84 18.53 o -3 4 0 155.01 150.23 6.52 o -2 4 0 130.69 156.88 10.42 o -1 4 0 27.38 51.61 19.38 o 0 4 0 0.04 1.03 7.20 o 1 4 0 0.42 10.64 15.10 o 2 4 0 828.32 785.67 28.82 o 3 4 0 1248.17 1143.17 1.03 o 4 4 0 1484.31 1309.59 114.08 o 5 4 0 58.85 48.54 7.17 o 6 4 0 166.98 206.20 15.10 o 7 4 0 432.69 383.23 0.69 o 8 4 0 119.38 137.23 13.72 o 9 4 0 9.84 16.47 26.76 o -7 5 0 4.20 4.80 3.77 o -6 5 0 2.17 4.12 7.20 o -5 5 0 615.05 564.04 22.64 o -4 5 0 971.95 986.25 102.24 o -3 5 0 413.81 391.72 11.22 o -2 5 0 115.37 133.12 25.84 o -1 5 0 84.61 89.13 1.94 o 0 5 0 93.95 116.31 16.13 o 1 5 0 237.18 227.81 2.06 o 2 5 0 0.71 27.79 46.66 o 3 5 0 309.63 341.03 33.62 o 4 5 0 393.10 388.95 13.47 o 5 5 0 224.21 200.38 11.15 o 6 5 0 3.36 1.72 0.34 o 7 5 0 46.88 65.87 30.53 o 8 5 0 257.05 242.22 24.36 o -6 6 0 0.60 3.43 25.73 o -5 6 0 44.80 59.01 29.16 o -4 6 0 217.10 228.46 13.21 o -3 6 0 292.75 279.60 16.13 o -2 6 0 74.05 92.75 14.69 o -1 6 0 49.95 72.96 28.68 o 0 6 0 502.32 478.95 31.22 o 1 6 0 1915.50 1845.47 48.38 o 2 6 0 2.01 10.98 5.83 o 3 6 0 32.15 49.40 45.97 o 4 6 0 181.68 177.38 25.39 o 5 6 0 24.89 28.15 9.35 o 6 6 0 24.27 22.99 3.77 o 7 6 0 12.63 15.44 9.26 o 8 6 0 37.44 43.23 6.52 o -5 7 0 75.58 78.57 22.64 o -4 7 0 50.27 57.06 6.86 o -3 7 0 0.37 1.37 7.08 o -2 7 0 41.21 49.75 9.95 o -1 7 0 56.01 69.65 13.38 o 0 7 0 191.54 248.40 47.69 o 1 7 0 334.08 317.36 16.47 o 2 7 0 252.18 296.08 30.88 o 3 7 0 271.62 335.88 47.69 o 4 7 0 221.35 256.97 29.85 o 5 7 0 275.83 291.02 8.07 o 6 7 0 53.57 65.53 33.97 o 7 7 0 15.12 11.32 0.34 o -4 8 0 19.68 22.23 7.20 o -3 8 0 68.60 70.52 21.41 o -2 8 0 82.03 72.38 6.79 o -1 8 0 269.23 313.92 42.54 o 0 8 0 31.13 33.62 4.12 o 1 8 0 18.38 29.51 48.03 o 2 8 0 2.96 7.20 45.97 o 3 8 0 31.54 46.32 13.72 o 4 8 0 72.41 123.17 16.81 o 5 8 0 41.95 57.63 22.90 o 6 8 0 129.72 125.91 51.12 o -3 9 0 2.48 2.37 2.54 o -2 9 0 1.18 2.74 14.75 o -1 9 0 535.20 585.65 45.63 o 0 9 0 82.76 87.14 17.50 o 1 9 0 12.05 15.44 10.98 o 2 9 0 14.39 26.42 27.79 o 4 9 0 45.50 43.23 6.18 o 5 9 0 30.60 44.25 34.67 o 0 10 0 49.79 53.86 7.55 o 1 10 0 63.29 74.45 48.38 o 2 10 0 1.34 2.74 3.77 o -2 -10 1 100.83 93.66 22.99 o -1 -10 1 33.87 31.22 0.34 o -5 -9 1 98.13 90.02 6.86 o -4 -9 1 66.07 68.96 31.91 o -3 -9 1 17.47 15.10 25.73 o -2 -9 1 33.49 37.05 20.24 o -1 -9 1 22.59 27.79 34.99 o 0 -9 1 32.12 36.02 35.34 o 1 -9 1 13.50 15.10 31.91 o 2 -9 1 25.27 29.51 27.79 o 3 -9 1 141.56 132.77 6.86 o -6 -8 1 0.79 6.86 5.83 o -5 -8 1 16.47 18.53 30.08 o -4 -8 1 860.04 802.48 29.16 o -3 -8 1 268.92 312.21 40.14 o -2 -8 1 5.77 8.58 13.04 o -1 -8 1 81.18 92.63 23.67 o 0 -8 1 43.34 50.09 7.89 o 1 -8 1 30.67 33.28 7.89 o 2 -8 1 7.25 8.92 24.02 o 3 -8 1 0.36 1.57 1.67 o 4 -8 1 56.87 71.24 16.47 o -7 -7 1 14.15 19.21 17.15 o -6 -7 1 8.85 30.53 48.03 o -5 -7 1 50.89 43.24 5.49 o -4 -7 1 297.58 285.08 4.29 o -3 -7 1 550.62 546.54 12.35 o -2 -7 1 172.26 187.67 17.15 o -1 -7 1 46.25 50.78 26.07 o 0 -7 1 184.47 231.24 30.53 o 1 -7 1 411.92 392.15 6.18 o 2 -7 1 461.81 426.50 10.98 o 3 -7 1 95.96 98.05 32.39 o 4 -7 1 0.05 0.79 1.56 o 5 -7 1 2.79 9.61 45.97 o 6 -7 1 53.62 66.90 50.09 o -8 -6 1 15.19 14.41 0.34 o -7 -6 1 138.14 119.39 10.64 o -6 -6 1 130.18 152.67 19.21 o -5 -6 1 10.91 12.37 3.68 o -4 -6 1 111.91 128.70 16.38 o -3 -6 1 66.09 59.70 50.09 o -2 -6 1 68.99 82.68 13.38 o -1 -6 1 23.76 35.34 42.89 o 0 -6 1 435.46 481.69 49.75 o 1 -6 1 630.80 588.05 4.46 o 2 -6 1 397.23 340.36 27.89 o 3 -6 1 24.03 42.30 25.61 o 4 -6 1 31.53 36.52 7.20 o 5 -6 1 277.61 312.90 29.85 o 6 -6 1 48.69 43.23 26.42 o -8 -5 1 9.37 9.95 49.75 o -7 -5 1 14.54 17.50 7.20 o -6 -5 1 361.06 359.21 26.07 o -5 -5 1 486.80 449.10 21.05 o -4 -5 1 202.90 191.23 28.85 o -3 -5 1 751.08 708.13 19.21 o -2 -5 1 1061.87 1025.83 32.94 o -1 -5 1 318.76 299.17 6.52 o 0 -5 1 1781.92 1813.90 48.38 o 1 -5 1 903.24 868.52 27.29 o 2 -5 1 57.02 85.91 26.82 o 3 -5 1 67.16 63.87 21.74 o 4 -5 1 34.04 48.42 16.32 o 5 -5 1 793.36 769.20 50.09 o 6 -5 1 91.36 99.84 27.45 o 7 -5 1 35.86 36.37 2.74 o -8 -4 1 57.25 83.71 41.17 o -7 -4 1 1.84 2.74 0.34 o -6 -4 1 48.90 56.27 14.41 o -5 -4 1 274.50 286.67 9.78 o -4 -4 1 300.43 297.07 11.75 o -3 -4 1 77.44 91.39 17.14 o -2 -4 1 381.49 374.99 8.23 o -1 -4 1 612.48 573.98 22.64 o 0 -4 1 1968.87 1906.19 47.35 o 1 -4 1 246.59 252.80 23.38 o 2 -4 1 17.46 29.23 14.30 o 3 -4 1 602.43 586.50 12.29 o 4 -4 1 302.32 313.97 9.33 o 5 -4 1 77.13 58.32 6.86 o 6 -4 1 69.13 78.91 7.55 o 7 -4 1 36.06 60.04 33.97 o 8 -4 1 6.24 9.26 18.53 o -9 -3 1 166.87 199.68 23.33 o -8 -3 1 413.62 383.57 29.51 o -7 -3 1 185.81 168.46 37.05 o -6 -3 1 27.80 28.13 40.14 o -5 -3 1 0.07 6.18 25.73 o -4 -3 1 222.62 225.68 27.28 o -3 -3 1 93.31 91.71 20.59 o -2 -3 1 12.09 88.17 33.62 o -1 -3 1 453.01 440.87 1.03 o 0 -3 1 166.85 205.17 43.57 o 1 -3 1 62.81 59.37 8.16 o 2 -3 1 160.93 211.35 15.48 o 3 -3 1 156.71 175.15 7.96 o 4 -3 1 1712.45 1640.71 11.75 o 5 -3 1 416.20 402.23 16.69 o 6 -3 1 51.14 61.41 42.89 o 7 -3 1 5.14 5.83 7.20 o 8 -3 1 11.40 30.19 35.34 o -9 -2 1 2.36 4.46 1.03 o -8 -2 1 141.51 187.33 34.65 o -7 -2 1 346.42 374.65 33.97 o -6 -2 1 102.51 122.14 25.39 o -5 -2 1 68.47 85.77 2.40 o -4 -2 1 238.60 242.44 7.55 o -3 -2 1 4166.54 3917.88 55.58 o -2 -2 1 112.44 128.39 21.44 o -1 -2 1 1308.34 1233.40 3.77 o 1 -2 1 2.76 7.20 4.61 o 2 -2 1 5.81 11.23 6.33 o 3 -2 1 318.84 305.48 25.17 o 4 -2 1 361.83 527.07 40.09 o 5 -2 1 1435.10 1440.88 48.55 o 6 -2 1 45.08 52.50 3.65 o 7 -2 1 89.07 96.61 5.15 o 8 -2 1 193.86 213.06 48.38 o 9 -2 1 49.31 59.70 38.08 o -9 -1 1 8.55 17.15 11.32 o -8 -1 1 25.58 43.92 4.12 o -7 -1 1 11.61 26.76 10.29 o -6 -1 1 357.74 394.89 36.71 o -5 -1 1 523.15 528.35 19.56 o -4 -1 1 799.31 802.42 40.48 o -3 -1 1 2157.03 2127.83 7.76 o -2 -1 1 765.27 969.12 23.84 o -1 -1 1 515.01 517.50 11.87 o 1 -1 1 5081.96 4855.01 17.71 o 2 -1 1 2373.74 2296.02 17.98 o 3 -1 1 839.67 852.87 13.82 o 4 -1 1 249.52 265.51 27.28 o 5 -1 1 4.59 14.41 35.34 o 6 -1 1 12.22 20.93 33.28 o 7 -1 1 46.82 55.24 44.26 o 8 -1 1 328.06 301.43 7.32 o 9 -1 1 176.56 208.60 45.97 o -9 0 1 72.07 64.84 36.37 o -8 0 1 80.34 89.20 34.99 o -7 0 1 53.79 57.98 1.03 o -6 0 1 232.30 295.06 48.03 o -5 0 1 462.80 403.81 7.55 o -4 0 1 1316.05 1211.79 14.01 o -3 0 1 934.40 1051.21 33.84 o -2 0 1 156.82 188.71 8.98 o -1 0 1 7115.57 6626.63 78.40 o 0 0 1 1182.30 1216.65 8.08 o 1 0 1 2332.47 2238.99 2.06 o 2 0 1 4884.39 4723.28 31.91 o 3 0 1 2361.55 2280.84 6.86 o 4 0 1 418.45 370.53 12.69 o 5 0 1 92.75 123.51 47.69 o 6 0 1 271.33 282.02 9.95 o 7 0 1 15.69 35.68 22.64 o 8 0 1 85.69 132.09 25.73 o 9 0 1 95.17 119.05 46.32 o -8 1 1 28.85 49.06 39.11 o -7 1 1 5.43 34.31 43.23 o -6 1 1 105.84 82.34 6.86 o -5 1 1 1565.47 1569.62 48.72 o -4 1 1 1103.58 999.16 36.37 o -3 1 1 251.31 252.35 20.99 o -2 1 1 936.66 902.67 61.76 o -1 1 1 911.59 889.95 8.47 o 0 1 1 1782.16 1697.16 21.44 o 1 1 1 1194.28 1342.16 40.83 o 2 1 1 446.09 478.95 31.22 o 3 1 1 1589.40 1693.14 25.05 o 4 1 1 28.92 38.77 30.19 o 5 1 1 443.32 418.91 20.93 o 6 1 1 1077.43 1121.55 13.04 o 7 1 1 86.84 68.27 24.36 o 8 1 1 21.77 75.48 15.78 o 9 1 1 11.50 14.07 1.72 o -8 2 1 26.09 28.48 11.66 o -7 2 1 21.36 32.59 49.75 o -6 2 1 74.20 75.48 33.28 o -5 2 1 333.12 345.15 28.13 o -4 2 1 800.42 777.76 15.33 o -3 2 1 576.94 589.46 13.12 o -2 2 1 27.08 32.69 9.09 o -1 2 1 2060.08 1949.77 76.01 o 0 2 1 5903.17 5684.79 20.26 o 1 2 1 8522.15 8608.75 50.09 o 2 2 1 1264.90 1237.52 33.62 o 3 2 1 62.58 70.38 13.03 o 4 2 1 189.20 208.22 13.36 o 5 2 1 370.77 315.98 24.36 o 6 2 1 193.98 164.68 12.69 o 7 2 1 132.55 134.83 1.37 o 8 2 1 97.77 111.50 0.69 o 9 2 1 3.47 4.46 9.26 o -8 3 1 58.10 55.92 30.53 o -7 3 1 238.76 209.97 29.85 o -6 3 1 57.10 107.04 22.99 o -5 3 1 22.36 29.85 9.61 o -4 3 1 1.32 5.83 31.85 o -3 3 1 91.49 134.58 14.93 o -2 3 1 221.43 216.76 7.70 o -1 3 1 183.48 205.51 21.27 o 0 3 1 1469.14 1415.99 22.13 o 1 3 1 423.91 418.22 6.52 o 2 3 1 619.72 613.44 6.86 o 3 3 1 838.90 846.40 15.44 o 4 3 1 1362.42 1294.19 17.59 o 5 3 1 346.51 356.47 29.01 o 6 3 1 156.04 214.09 43.23 o 7 3 1 172.58 168.11 37.05 o 8 3 1 12.22 15.78 16.47 o 9 3 1 3.67 7.55 25.73 o -7 4 1 231.12 241.19 13.04 o -6 4 1 334.58 321.13 7.89 o -5 4 1 93.39 96.06 28.13 o -4 4 1 444.60 445.61 20.15 o -3 4 1 591.32 596.84 14.41 o -2 4 1 174.90 243.79 17.53 o -1 4 1 601.81 601.64 20.87 o 0 4 1 229.08 258.89 13.21 o 1 4 1 265.24 276.53 5.49 o 2 4 1 478.20 498.53 20.24 o 3 4 1 156.40 160.91 12.69 o 4 4 1 2919.64 2868.79 17.22 o 5 4 1 923.10 984.84 43.06 o 6 4 1 673.33 706.07 37.05 o 7 4 1 59.15 74.79 35.34 o 8 4 1 47.54 61.07 17.15 o 9 4 1 83.09 90.23 25.05 o -7 5 1 24.43 31.56 24.36 o -6 5 1 14.45 15.44 9.26 o -5 5 1 1.60 9.95 42.54 o -4 5 1 41.17 47.23 10.28 o -3 5 1 578.72 540.99 8.35 o -2 5 1 94.84 121.54 24.36 o -1 5 1 335.48 315.09 8.58 o 0 5 1 254.43 278.91 7.66 o 1 5 1 23.71 33.97 31.22 o 2 5 1 1.30 19.90 18.53 o 3 5 1 21.10 27.10 9.26 o 4 5 1 24.25 29.51 7.20 o 5 5 1 171.96 184.75 11.52 o 6 5 1 77.15 65.53 21.61 o 7 5 1 35.39 41.17 10.98 o 8 5 1 0.11 18.18 39.11 o 9 5 1 99.32 134.83 48.72 o -6 6 1 13.22 15.78 3.77 o -5 6 1 57.34 65.19 22.64 o -4 6 1 38.79 78.47 22.13 o -3 6 1 189.70 209.99 14.34 o -2 6 1 469.49 476.88 16.55 o -1 6 1 120.08 156.39 15.66 o 0 6 1 62.25 63.13 16.47 o 1 6 1 176.73 213.40 17.15 o 2 6 1 217.66 242.22 18.87 o 3 6 1 402.32 420.97 33.97 o 4 6 1 48.89 49.75 7.20 o 5 6 1 3.18 6.66 9.65 o 6 6 1 126.88 150.27 42.20 o 7 6 1 62.25 76.51 20.93 o 8 6 1 0.32 18.87 29.85 o -5 7 1 11.14 15.44 27.79 o -4 7 1 359.06 345.15 7.22 o -3 7 1 29.63 31.29 5.83 o -2 7 1 0.40 1.59 1.70 o -1 7 1 11.07 11.12 6.31 o 0 7 1 39.07 40.48 27.79 o 1 7 1 160.02 178.75 35.68 o 2 7 1 2.18 21.27 32.25 o 3 7 1 189.33 221.63 27.79 o 4 7 1 372.19 362.30 48.38 o 5 7 1 1.43 2.01 3.50 o 6 7 1 83.41 67.25 2.74 o 7 7 1 124.63 126.26 49.40 o 8 7 1 13.05 15.44 16.47 o -4 8 1 174.69 174.64 15.95 o -3 8 1 46.79 47.13 6.03 o -2 8 1 0.89 7.20 22.77 o -1 8 1 106.06 113.90 28.82 o 0 8 1 406.93 393.52 4.12 o 1 8 1 480.31 468.66 20.24 o 2 8 1 106.36 106.70 38.43 o 3 8 1 21.08 29.16 25.73 o 4 8 1 6.99 6.86 34.99 o 5 8 1 3.71 9.95 18.53 o 6 8 1 0.77 4.80 7.20 o 7 8 1 61.92 62.44 13.38 o -3 9 1 14.61 15.10 5.09 o -2 9 1 62.29 72.73 13.38 o -1 9 1 102.28 113.90 49.06 o 0 9 1 102.47 111.16 43.57 o 1 9 1 153.48 165.02 47.69 o 2 9 1 183.47 183.21 45.97 o 3 9 1 5.29 9.95 9.26 o 4 9 1 21.51 21.96 0.34 o 5 9 1 42.77 45.63 18.87 o 6 9 1 32.01 32.25 33.28 o 0 10 1 10.22 8.23 9.26 o 1 10 1 3.92 3.43 3.77 o 2 10 1 30.59 48.72 26.07 o 3 10 1 28.08 31.91 15.10 o -4 -9 2 1.26 1.72 4.37 o -3 -9 2 21.91 47.00 50.09 o -2 -9 2 53.47 57.30 13.38 o -1 -9 2 57.20 63.13 6.18 o 0 -9 2 0.20 2.40 5.49 o 1 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