#------------------------------------------------------------------------------ #$Date: 2009-05-13 10:52:48 +0300 (Wed, 13 May 2009) $ #$Revision: 717 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2221409.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2221409_Fobs loop_ _publ_author_name 'Fujita, Kyoko' 'MacFarlane, Douglas R.' 'Noguchi, Keiichi' 'Ohno, Hiroyuki' _publ_section_title ; Tetramethylammonium dihydrogen phosphate hemihydrate ; _journal_coeditor_code IS2395 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o797 _journal_volume 65 _journal_year 2009 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 103.614 _cell_angle_gamma 90.000 _cell_length_a 14.3213 _cell_length_b 9.2607 _cell_length_c 13.1990 _exptl_crystal_F_000 776.00 _reflns_d_resolution_high 0.8302 _[local]_cod_data_source_file is2395Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' OhnoNakamuraLab_080710_' _shelx_refln_list_code 4 _shelx_F_calc_maximum 229.23 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 391.20 545.06 10.10 o 4 0 0 42272.17 39382.06 1382.37 o 6 0 0 5238.97 6307.51 67.76 o 8 0 0 18958.74 18641.53 309.80 o 10 0 0 1100.30 879.16 15.09 o 12 0 0 1533.55 1338.18 22.93 o 14 0 0 292.23 253.43 7.82 o 16 0 0 1534.77 1605.55 57.24 o 1 1 0 5321.09 5232.49 49.62 o 3 1 0 5.44 19.30 0.89 o 5 1 0 1322.38 1339.42 9.66 o 7 1 0 4390.00 4607.69 38.91 o 9 1 0 1035.51 1085.77 10.30 o 11 1 0 698.42 703.19 9.27 o 13 1 0 134.36 120.56 3.34 o 15 1 0 140.10 145.01 4.91 o 0 2 0 4275.86 3771.18 37.17 o 2 2 0 3.67 41.65 2.20 o 4 2 0 1155.53 1370.77 9.21 o 6 2 0 3694.03 4013.92 31.64 o 8 2 0 3236.63 3397.56 30.41 o 10 2 0 28.56 54.46 2.10 o 12 2 0 857.02 851.59 12.06 o 14 2 0 11.73 11.47 2.10 o 16 2 0 280.00 296.28 7.35 o 1 3 0 5.35 9.73 1.93 o 3 3 0 89.42 96.71 1.28 o 5 3 0 110.74 83.19 0.98 o 7 3 0 2.61 24.23 0.89 o 9 3 0 232.38 255.32 4.85 o 11 3 0 1614.07 1432.58 21.10 o 13 3 0 176.28 193.43 4.23 o 15 3 0 496.77 463.47 8.68 o 0 4 0 3689.05 3666.75 40.08 o 2 4 0 2465.11 2407.28 18.67 o 4 4 0 314.49 207.01 1.88 o 6 4 0 61.43 72.53 1.38 o 8 4 0 479.52 413.69 4.93 o 10 4 0 2285.68 2155.25 35.07 o 12 4 0 605.66 632.70 11.23 o 14 4 0 308.68 324.32 8.51 o 1 5 0 6434.59 6636.92 60.90 o 3 5 0 2118.11 2263.37 20.19 o 5 5 0 473.33 540.79 5.38 o 7 5 0 591.57 594.23 8.38 o 9 5 0 403.37 370.28 5.98 o 11 5 0 1640.82 1514.07 25.03 o 13 5 0 0.72 0.63 1.42 o 0 6 0 201.54 221.86 4.70 o 2 6 0 0.55 5.37 0.94 o 4 6 0 2756.86 2742.42 35.14 o 6 6 0 427.28 444.40 8.06 o 8 6 0 208.48 179.83 3.81 o 10 6 0 10.49 12.82 2.25 o 12 6 0 91.92 92.21 3.71 o 14 6 0 30.66 22.29 4.66 o 1 7 0 1062.56 1074.23 16.63 o 3 7 0 83.48 63.98 3.02 o 5 7 0 806.33 803.38 12.80 o 7 7 0 1070.57 1011.42 16.34 o 9 7 0 466.36 483.83 8.90 o 11 7 0 270.01 263.08 7.28 o 13 7 0 611.72 647.73 17.35 o 0 8 0 1678.27 1574.85 82.68 o 2 8 0 121.27 150.37 12.27 o 4 8 0 1256.49 1189.77 21.61 o 6 8 0 11.78 15.22 4.82 o 8 8 0 461.60 431.58 7.56 o 10 8 0 47.21 45.34 2.26 o 1 9 0 295.12 299.10 9.19 o 3 9 0 408.12 433.95 13.02 o 5 9 0 206.11 217.34 6.36 o 7 9 0 41.64 57.36 4.42 o 9 9 0 22.72 26.15 2.32 o 0 10 0 6.21 1.01 2.28 o 2 10 0 3.44 3.27 1.79 o 4 10 0 122.31 101.35 6.61 o 6 10 0 22.65 39.15 11.92 o 1 11 0 269.83 291.32 11.41 o -15 1 1 296.56 302.48 6.25 o -13 1 1 2237.35 2202.02 32.84 o -11 1 1 478.33 501.06 7.16 o -9 1 1 173.89 142.51 2.07 o -7 1 1 122.87 116.65 1.29 o -5 1 1 5273.82 4847.45 39.49 o -3 1 1 265.62 278.92 2.61 o -1 1 1 6059.39 6165.52 54.42 o 1 1 1 2026.27 2279.82 15.85 o 3 1 1 19434.47 19893.76 289.68 o 5 1 1 2372.30 2562.71 17.38 o 7 1 1 5893.70 6287.71 57.07 o 9 1 1 1244.76 1298.16 13.31 o 11 1 1 218.92 210.89 3.55 o 13 1 1 554.75 517.41 7.80 o 15 1 1 150.09 157.86 4.14 o -16 2 1 3.37 4.03 1.88 o -14 2 1 782.46 792.70 13.14 o -12 2 1 1477.43 1339.47 20.26 o -10 2 1 4954.01 5039.98 69.90 o -8 2 1 221.93 301.32 3.09 o -6 2 1 442.16 401.52 3.47 o -4 2 1 385.93 426.27 3.25 o -2 2 1 52548.44 48131.59 1017.67 o 0 2 1 11926.13 11964.92 136.19 o 2 2 1 14598.22 14319.97 157.06 o 4 2 1 1196.50 1277.16 8.35 o 6 2 1 3903.81 3870.18 27.73 o 8 2 1 3.53 11.00 1.03 o 10 2 1 136.26 140.04 3.66 o 12 2 1 749.05 713.19 10.80 o 14 2 1 356.70 355.84 5.78 o 16 2 1 115.10 121.90 6.00 o -15 3 1 7.13 10.32 1.98 o -13 3 1 206.42 185.42 4.72 o -11 3 1 95.30 97.29 2.86 o -9 3 1 67.53 48.07 1.50 o -7 3 1 305.14 307.65 2.59 o -5 3 1 3922.12 4400.06 33.40 o -3 3 1 3715.90 3537.60 26.66 o -1 3 1 5619.09 5672.17 45.89 o 1 3 1 7405.86 7510.17 62.66 o 3 3 1 26.44 47.24 1.20 o 5 3 1 207.79 289.97 2.16 o 7 3 1 1950.29 2040.42 17.08 o 9 3 1 152.52 124.83 4.94 o 11 3 1 618.71 595.82 9.06 o 13 3 1 465.61 439.76 7.01 o 15 3 1 8.04 4.12 1.53 o -14 4 1 156.43 183.19 6.24 o -12 4 1 14.73 23.07 2.74 o -10 4 1 30.65 35.93 2.00 o -8 4 1 1655.81 1714.01 17.17 o -6 4 1 289.93 317.59 2.98 o -4 4 1 6.76 7.62 0.58 o -2 4 1 207.92 256.12 2.23 o 0 4 1 9.46 9.48 1.10 o 2 4 1 2340.25 2574.70 18.69 o 4 4 1 952.39 1032.75 7.51 o 6 4 1 89.60 110.65 1.94 o 8 4 1 736.78 706.82 10.02 o 10 4 1 105.20 89.74 3.48 o 12 4 1 277.15 224.58 5.09 o 14 4 1 143.08 147.80 3.50 o -15 5 1 370.36 370.17 9.63 o -13 5 1 427.45 404.20 8.55 o -11 5 1 398.50 368.20 7.79 o -9 5 1 165.71 146.49 3.24 o -7 5 1 340.79 327.41 4.73 o -5 5 1 128.18 178.86 2.76 o -3 5 1 521.07 526.00 6.13 o -1 5 1 378.34 456.89 4.02 o 1 5 1 76.01 48.04 1.32 o 3 5 1 358.12 309.38 3.08 o 5 5 1 3592.33 3512.53 32.19 o 7 5 1 547.01 498.93 6.71 o 9 5 1 1054.90 1070.43 14.22 o 11 5 1 368.05 362.40 7.25 o 13 5 1 1193.47 1172.59 17.23 o -14 6 1 1958.15 2258.43 60.70 o -12 6 1 477.14 449.53 10.63 o -10 6 1 2590.01 2564.24 47.39 o -8 6 1 184.62 201.49 6.33 o -6 6 1 2420.61 2473.52 35.36 o -4 6 1 3.83 3.65 0.97 o -2 6 1 3695.65 3862.08 46.90 o 0 6 1 1787.56 1681.41 16.53 o 2 6 1 7866.85 7673.24 84.49 o 4 6 1 80.43 104.54 2.18 o 6 6 1 3296.66 3184.87 46.67 o 8 6 1 390.63 386.17 7.81 o 10 6 1 1864.65 1824.65 30.61 o 12 6 1 188.28 202.05 6.54 o -13 7 1 838.24 874.82 22.98 o -11 7 1 0.16 2.83 2.10 o -9 7 1 875.47 887.82 13.93 o -7 7 1 88.91 112.25 3.69 o -5 7 1 5.94 6.78 2.13 o -3 7 1 443.95 450.52 13.56 o -1 7 1 39.46 45.39 2.83 o 1 7 1 4120.10 4233.66 64.85 o 3 7 1 44.34 43.07 1.76 o 5 7 1 402.08 418.60 6.67 o 7 7 1 143.56 131.09 3.87 o 9 7 1 526.51 490.72 8.67 o 11 7 1 0.66 0.07 1.39 o -10 8 1 256.59 239.95 4.94 o -8 8 1 144.36 146.57 5.75 o -6 8 1 3485.90 3534.56 70.72 o -4 8 1 278.16 255.92 7.40 o -2 8 1 1675.56 1576.22 37.26 o 0 8 1 367.17 335.91 8.23 o 2 8 1 2166.45 1977.74 30.15 o 4 8 1 39.55 52.49 3.24 o 6 8 1 564.72 504.51 8.06 o 8 8 1 222.86 219.12 4.96 o 10 8 1 126.67 136.17 3.49 o -9 9 1 138.40 149.20 4.44 o -7 9 1 273.78 298.53 8.19 o -5 9 1 603.44 563.33 12.68 o -3 9 1 626.53 570.98 16.44 o -1 9 1 280.57 257.62 7.90 o 1 9 1 22.11 35.26 4.68 o 3 9 1 1164.48 1121.02 25.67 o 5 9 1 295.68 269.57 8.17 o 7 9 1 45.00 44.56 2.36 o 9 9 1 48.52 49.92 3.40 o -6 10 1 165.28 168.11 9.97 o -4 10 1 161.01 156.05 6.38 o -2 10 1 433.99 450.63 13.79 o 0 10 1 33.12 31.96 2.92 o 2 10 1 450.40 473.07 7.80 o 4 10 1 9.36 9.06 1.79 o 6 10 1 368.16 409.75 9.26 o -1 11 1 199.18 228.90 6.29 o 1 11 1 328.50 336.00 14.39 o -16 0 2 1230.38 1308.41 28.71 o -14 0 2 0.41 2.80 2.47 o -12 0 2 8820.74 8224.77 368.87 o -10 0 2 12.98 6.84 1.34 o -8 0 2 9608.69 9154.98 127.29 o -6 0 2 5685.54 5254.22 63.22 o -4 0 2 23835.46 23142.08 464.24 o -2 0 2 12798.22 13225.71 180.12 o 0 0 2 24288.48 26181.01 1031.63 o 2 0 2 16775.91 17139.26 384.85 o 4 0 2 16163.95 15977.31 246.53 o 6 0 2 816.63 915.44 9.13 o 8 0 2 1007.51 1117.52 13.94 o 10 0 2 529.31 486.27 9.71 o 12 0 2 603.65 641.80 11.58 o 14 0 2 456.63 429.21 9.66 o 16 0 2 1066.46 1184.01 36.10 o -17 1 2 186.61 200.17 6.25 o -15 1 2 12.64 8.82 1.90 o -13 1 2 304.14 312.06 6.58 o -11 1 2 657.71 571.51 9.14 o -9 1 2 1179.79 1210.62 10.56 o -7 1 2 115.36 117.21 1.27 o -5 1 2 51.94 15.50 1.51 o -3 1 2 7341.81 7000.61 54.45 o -1 1 2 4126.32 4315.78 30.96 o 1 1 2 13719.24 13385.34 197.65 o 3 1 2 12.79 13.22 0.88 o 5 1 2 4368.49 4555.10 35.81 o 7 1 2 9.21 33.34 1.51 o 9 1 2 110.18 138.43 2.98 o 11 1 2 487.04 420.93 6.63 o 13 1 2 516.79 483.12 7.35 o 15 1 2 394.79 412.70 6.61 o -16 2 2 343.37 364.67 7.74 o -14 2 2 2.05 1.08 1.21 o -12 2 2 306.91 297.52 5.75 o -10 2 2 632.12 582.01 9.79 o -8 2 2 264.75 310.02 3.11 o -6 2 2 5.02 9.35 0.58 o -4 2 2 3174.36 3279.64 25.50 o -2 2 2 135.41 133.00 1.74 o 0 2 2 416.47 442.83 5.44 o 2 2 2 1417.31 1388.03 9.66 o 4 2 2 9322.84 9136.19 74.37 o 6 2 2 871.27 997.97 7.26 o 8 2 2 163.16 123.98 2.01 o 10 2 2 81.44 61.69 2.32 o 12 2 2 1177.61 1060.83 16.62 o 14 2 2 16.25 12.87 1.57 o -15 3 2 278.15 311.95 6.15 o -13 3 2 143.99 130.84 3.97 o -11 3 2 10.73 21.56 1.93 o -9 3 2 817.82 845.48 8.55 o -7 3 2 36.36 18.52 0.71 o -5 3 2 1988.28 2256.68 16.66 o -3 3 2 9801.49 10088.37 88.35 o -1 3 2 112.06 90.90 2.33 o 1 3 2 1316.04 1428.28 10.72 o 3 3 2 3952.72 3455.40 25.31 o 5 3 2 3.82 12.09 0.75 o 7 3 2 1826.10 2056.39 16.81 o 9 3 2 85.71 113.27 3.15 o 11 3 2 887.37 853.01 12.77 o 13 3 2 32.41 16.57 1.99 o 15 3 2 520.63 581.36 10.69 o -16 4 2 1037.99 1162.20 31.16 o -14 4 2 135.35 109.26 3.91 o -12 4 2 3323.92 3206.48 53.21 o -10 4 2 107.20 80.12 2.73 o -8 4 2 2436.83 2437.33 20.10 o -6 4 2 53.01 48.19 1.77 o -4 4 2 675.46 579.67 4.43 o -2 4 2 6397.46 6159.96 55.37 o 0 4 2 11082.82 11167.42 104.68 o 2 4 2 2182.96 2488.09 18.99 o 4 4 2 3497.45 3593.18 27.94 o 6 4 2 30.21 36.06 1.89 o 8 4 2 2500.87 2406.09 31.57 o 10 4 2 39.90 38.28 2.87 o 12 4 2 301.23 282.94 5.87 o 14 4 2 111.51 111.41 2.93 o -15 5 2 526.15 585.21 13.78 o -13 5 2 261.45 234.98 6.59 o -11 5 2 3663.21 3643.13 77.79 o -9 5 2 847.66 777.58 11.53 o -7 5 2 54.01 51.64 1.70 o -5 5 2 251.59 249.60 3.18 o -3 5 2 1343.81 1461.52 11.27 o -1 5 2 7730.18 8025.70 78.01 o 1 5 2 2.09 11.84 1.23 o 3 5 2 4918.22 5023.65 42.30 o 5 5 2 3180.97 3170.55 38.47 o 7 5 2 852.63 819.60 11.23 o 9 5 2 757.25 718.64 10.05 o 11 5 2 712.60 735.39 12.82 o 13 5 2 43.73 46.87 2.09 o -14 6 2 155.95 194.13 8.92 o -12 6 2 133.83 121.41 5.61 o -10 6 2 261.53 223.76 6.23 o -8 6 2 1390.37 1405.62 21.54 o -6 6 2 274.78 271.50 4.98 o -4 6 2 1571.68 1516.08 28.11 o -2 6 2 1806.29 1818.07 18.10 o 0 6 2 9.85 2.74 1.07 o 2 6 2 244.69 223.98 3.33 o 4 6 2 84.30 87.90 2.13 o 6 6 2 748.97 785.30 12.16 o 8 6 2 177.71 160.89 4.92 o 10 6 2 272.81 270.53 6.21 o 12 6 2 229.29 229.96 6.54 o -13 7 2 1129.00 1212.24 45.63 o -11 7 2 723.74 741.28 24.48 o -9 7 2 113.32 110.58 3.46 o -7 7 2 2655.18 2575.09 43.12 o -5 7 2 2105.19 1973.99 29.30 o -3 7 2 2544.21 2476.98 32.54 o -1 7 2 425.79 431.85 7.30 o 1 7 2 4284.73 4103.74 58.35 o 3 7 2 2976.23 2986.21 39.03 o 5 7 2 3022.44 2984.60 45.45 o 7 7 2 1021.45 1061.06 18.92 o 9 7 2 657.59 620.46 11.32 o 11 7 2 721.67 801.36 15.04 o -12 8 2 716.12 800.66 30.11 o -10 8 2 77.29 72.90 2.87 o -8 8 2 359.33 366.81 13.90 o -6 8 2 1.02 0.22 1.18 o -4 8 2 347.04 346.14 7.26 o -2 8 2 388.07 368.46 12.78 o 0 8 2 546.64 548.24 9.18 o 2 8 2 204.48 189.86 4.54 o 4 8 2 1571.69 1467.40 22.46 o 6 8 2 54.77 43.35 2.22 o 8 8 2 284.48 280.63 5.54 o 10 8 2 38.86 39.59 2.12 o -9 9 2 37.84 45.85 4.79 o -7 9 2 22.19 24.62 3.04 o -5 9 2 0.58 6.86 2.12 o -3 9 2 364.09 330.51 10.92 o -1 9 2 1008.10 1035.14 16.67 o 1 9 2 94.32 77.60 3.27 o 3 9 2 299.81 314.82 7.68 o 5 9 2 4.57 8.22 2.62 o 7 9 2 109.24 100.19 3.35 o 9 9 2 0.15 0.38 1.48 o -6 10 2 54.46 48.90 2.93 o -4 10 2 235.21 221.55 8.49 o -2 10 2 29.90 45.98 9.66 o 0 10 2 1.07 2.03 1.70 o 2 10 2 3.65 1.21 1.27 o 4 10 2 0.72 1.76 2.20 o 6 10 2 98.78 97.50 4.94 o -1 11 2 337.17 359.64 11.05 o 1 11 2 229.18 227.96 8.46 o -17 1 3 78.69 85.17 3.39 o -15 1 3 442.28 420.96 8.29 o -13 1 3 653.96 585.85 10.89 o -11 1 3 1648.49 1453.69 21.98 o -9 1 3 5623.91 5847.83 63.68 o -7 1 3 557.13 500.84 3.71 o -5 1 3 1598.89 1682.33 12.10 o -3 1 3 2711.66 2611.59 17.72 o -1 1 3 25530.20 25827.51 434.25 o 1 1 3 19873.88 20148.18 325.31 o 3 1 3 387.93 414.03 3.40 o 5 1 3 5155.16 5102.01 41.71 o 7 1 3 5949.23 6350.00 57.24 o 9 1 3 2486.65 2570.66 33.54 o 11 1 3 18.71 12.62 1.62 o 13 1 3 321.77 320.40 5.81 o 15 1 3 32.49 45.20 3.10 o -16 2 3 445.72 490.67 9.72 o -14 2 3 2024.61 2055.40 32.89 o -12 2 3 115.89 120.86 3.51 o -10 2 3 9263.33 8680.63 137.51 o -8 2 3 2217.82 2490.84 21.32 o -6 2 3 1114.73 1008.65 7.66 o -4 2 3 189.68 119.41 1.41 o -2 2 3 5229.65 4601.87 34.69 o 0 2 3 18798.86 19551.57 227.90 o 2 2 3 2856.73 2602.12 19.61 o 4 2 3 539.93 497.52 3.82 o 6 2 3 3518.50 3345.34 26.33 o 8 2 3 53.83 27.42 1.18 o 10 2 3 1398.41 1319.12 18.31 o 12 2 3 507.28 459.95 7.65 o 14 2 3 296.70 321.93 5.34 o -15 3 3 131.93 126.94 3.34 o -13 3 3 517.09 480.40 8.05 o -11 3 3 945.15 890.15 14.49 o -9 3 3 135.20 105.33 2.09 o -7 3 3 145.48 104.38 1.27 o -5 3 3 1296.45 1255.97 9.27 o -3 3 3 341.81 428.78 3.18 o -1 3 3 354.11 426.84 3.68 o 1 3 3 5251.14 5485.18 46.28 o 3 3 3 142.27 204.38 2.02 o 5 3 3 40.30 77.28 1.32 o 7 3 3 264.04 250.64 2.97 o 9 3 3 1289.12 1191.63 16.68 o 11 3 3 589.55 540.01 10.71 o 13 3 3 14.77 14.42 2.10 o 15 3 3 24.52 21.31 3.32 o -16 4 3 27.29 35.64 6.17 o -14 4 3 77.73 68.35 2.70 o -12 4 3 157.24 140.61 3.84 o -10 4 3 113.02 101.20 2.46 o -8 4 3 1001.70 1009.78 9.78 o -6 4 3 262.76 276.88 2.51 o -4 4 3 8248.47 8145.21 68.86 o -2 4 3 1816.99 1891.36 15.10 o 0 4 3 1714.47 1884.93 14.74 o 2 4 3 1210.48 1160.70 9.19 o 4 4 3 876.95 1036.65 8.11 o 6 4 3 63.69 55.75 1.84 o 8 4 3 8.30 9.93 1.70 o 10 4 3 321.91 324.32 6.64 o 12 4 3 5.96 5.58 1.67 o 14 4 3 80.73 72.21 2.96 o -15 5 3 249.17 340.58 37.75 o -13 5 3 275.78 307.66 10.19 o -11 5 3 133.16 115.60 6.72 o -9 5 3 1208.87 1168.38 62.28 o -7 5 3 2.80 7.16 1.00 o -5 5 3 456.81 449.45 4.50 o -3 5 3 137.63 154.04 2.11 o -1 5 3 15.66 3.32 0.93 o 1 5 3 4013.15 4219.25 36.93 o 3 5 3 480.12 487.02 4.22 o 5 5 3 3368.10 3258.78 42.00 o 7 5 3 34.76 36.46 2.55 o 9 5 3 921.82 833.85 12.17 o 11 5 3 0.34 2.10 1.95 o 13 5 3 264.57 320.99 6.44 o -14 6 3 1585.36 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