#------------------------------------------------------------------------------ #$Date: 2009-06-07 09:06:07 +0300 (Sun, 07 Jun 2009) $ #$Revision: 754 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2221804.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2221804_Fobs loop_ _publ_author_name 'Tang, Gui Hong' 'Li, Dong Dong' 'Huang, Gang' 'Xu, Xing Yan' 'Zeng, Xiang Chao' _publ_section_title ; 1H-Pyrrole-2-carboxylic acid ; _journal_coeditor_code SJ2604 _journal_issue 5 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1121 _journal_volume 65 _journal_year 2009 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.969 _cell_angle_gamma 90.000 _cell_length_a 14.0802 _cell_length_b 5.0364 _cell_length_c 14.6126 _exptl_crystal_F_000 464.00 _reflns_d_resolution_high 0.8107 _[local]_cod_data_source_file sj2604Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 01082m in C2/c' _shelx_refln_list_code 4 _shelx_F_calc_maximum 240.52 _shelx_F_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 6964.29 7294.75 141.99 o 4 0 0 8464.94 9177.50 176.00 o 6 0 0 2482.30 2688.66 52.51 o 8 0 0 2175.51 2786.36 54.96 o 10 0 0 114.82 76.96 3.79 o 12 0 0 61.94 55.93 3.58 o 14 0 0 0.04 0.51 2.15 o 16 0 0 526.64 601.38 16.65 o 1 1 0 165.75 92.15 1.17 o 5 1 0 828.32 744.12 11.16 o 7 1 0 1297.47 1506.69 21.72 o 9 1 0 608.64 598.69 10.02 o 11 1 0 2825.84 2875.70 40.90 o 13 1 0 570.15 533.71 10.07 o 15 1 0 60.87 64.17 3.14 o 0 2 0 200.73 76.96 1.52 o 2 2 0 1290.10 1069.57 12.15 o 4 2 0 11.35 -0.73 0.49 o 6 2 0 2024.67 1804.99 36.58 o 8 2 0 125.72 224.16 4.81 o 10 2 0 123.04 126.87 3.64 o 12 2 0 3.30 6.25 1.66 o 14 2 0 216.21 217.36 5.76 o 16 2 0 8.84 19.67 6.28 o 1 3 0 1035.43 1370.38 13.30 o 3 3 0 2633.25 3139.40 30.62 o 5 3 0 200.27 204.02 2.93 o 7 3 0 86.69 51.82 1.81 o 9 3 0 459.57 507.02 13.49 o 11 3 0 553.98 470.10 71.88 o 13 3 0 17.20 12.18 3.08 o 15 3 0 0.38 0.17 3.16 o 0 4 0 570.19 253.04 7.38 o 2 4 0 405.62 474.44 6.80 o 4 4 0 51.93 72.42 2.12 o 6 4 0 198.73 195.75 3.82 o 8 4 0 2509.76 2620.86 29.99 o 10 4 0 125.27 108.68 3.61 o 12 4 0 157.60 198.25 8.51 o 1 5 0 22.38 16.21 2.17 o 3 5 0 120.26 116.66 3.67 o 5 5 0 228.78 233.58 5.58 o 7 5 0 23.63 29.31 5.77 o 9 5 0 115.86 131.01 4.38 o 2 6 0 262.21 304.50 9.78 o 4 6 0 39.45 38.31 3.54 o -17 1 1 34.45 57.13 3.31 o -15 1 1 105.31 108.23 3.96 o -13 1 1 29.50 28.83 2.30 o -11 1 1 1611.00 1548.70 32.07 o -9 1 1 227.53 289.44 5.70 o -7 1 1 139.68 91.00 3.50 o -5 1 1 1675.31 1381.44 60.92 o -3 1 1 519.55 1035.91 14.59 o -1 1 1 5283.67 5372.99 59.39 o 1 1 1 941.65 778.07 7.43 o 3 1 1 1779.98 1472.96 20.61 o 5 1 1 5544.03 5944.21 80.33 o 7 1 1 896.53 1112.81 38.02 o 9 1 1 998.21 897.40 14.15 o 11 1 1 257.86 206.82 5.03 o 13 1 1 195.40 225.03 5.71 o 15 1 1 141.24 149.49 5.65 o -16 2 1 43.64 45.80 3.02 o -14 2 1 680.92 616.96 11.51 o -12 2 1 897.70 832.49 13.93 o -10 2 1 26.81 28.13 1.82 o -8 2 1 84.10 73.54 2.51 o -6 2 1 1492.83 1780.57 68.63 o -4 2 1 1194.86 1539.69 17.60 o -2 2 1 978.80 1151.11 11.56 o 0 2 1 203.58 282.56 2.86 o 2 2 1 50.72 89.76 2.30 o 4 2 1 966.36 1204.39 19.71 o 6 2 1 583.70 656.64 10.47 o 8 2 1 24.50 36.21 1.87 o 10 2 1 48.05 42.61 2.25 o 12 2 1 173.70 158.12 4.52 o 14 2 1 24.13 24.38 6.36 o 16 2 1 16.28 34.25 3.46 o -15 3 1 24.76 19.13 4.34 o -13 3 1 3.54 4.43 2.91 o -11 3 1 45.48 42.06 3.50 o -9 3 1 943.08 880.05 11.50 o -7 3 1 501.36 482.97 5.79 o -5 3 1 936.42 907.16 9.50 o -3 3 1 293.83 214.48 2.88 o -1 3 1 585.47 628.45 5.97 o 1 3 1 110.34 42.70 1.34 o 3 3 1 464.46 383.86 4.48 o 5 3 1 1.26 0.29 0.61 o 7 3 1 47.74 26.85 1.32 o 9 3 1 96.72 66.27 2.08 o 11 3 1 0.27 1.72 2.28 o 13 3 1 0.04 0.38 1.74 o -12 4 1 25.25 25.83 2.38 o -10 4 1 1.01 2.25 1.61 o -8 4 1 15.67 7.51 1.74 o -6 4 1 194.94 207.85 3.94 o -4 4 1 460.11 430.22 6.31 o -2 4 1 215.18 183.31 3.42 o 0 4 1 349.27 337.76 4.48 o 2 4 1 592.83 472.27 6.61 o 4 4 1 504.62 562.14 11.65 o 6 4 1 122.25 93.70 3.04 o 8 4 1 365.32 439.60 9.46 o 10 4 1 1.52 2.14 1.88 o 12 4 1 145.71 151.09 7.33 o -9 5 1 1.60 1.10 1.91 o -7 5 1 28.85 25.52 3.48 o -5 5 1 121.67 95.66 3.46 o -3 5 1 1606.30 1845.57 26.63 o -1 5 1 66.82 73.67 3.20 o 1 5 1 190.20 227.85 3.75 o 3 5 1 325.93 387.72 7.67 o 5 5 1 331.30 313.20 7.06 o 7 5 1 5.81 4.43 1.80 o 9 5 1 5.86 0.70 1.99 o -4 6 1 39.88 37.37 2.68 o -2 6 1 87.83 67.57 3.25 o 0 6 1 0.49 -2.49 2.36 o 2 6 1 6.61 1.73 2.57 o 4 6 1 3.58 -0.63 2.53 o -16 0 2 685.70 745.27 19.26 o -14 0 2 248.17 287.39 9.31 o -12 0 2 1354.94 1209.51 26.55 o -10 0 2 5.34 0.67 1.48 o -8 0 2 4.82 2.19 1.22 o -6 0 2 82.03 74.64 2.91 o -4 0 2 147.24 85.72 2.57 o -2 0 2 126.61 119.39 2.02 o 0 0 2 3385.22 3365.05 97.04 o 2 0 2 1777.60 1834.91 35.87 o 4 0 2 9018.92 9276.71 176.76 o 6 0 2 367.54 568.51 12.81 o 8 0 2 132.17 82.02 3.62 o 10 0 2 75.35 67.98 3.75 o 12 0 2 1015.23 1010.91 23.31 o 14 0 2 17.54 21.62 3.54 o 16 0 2 20.61 33.17 3.84 o -17 1 2 13.65 17.98 5.12 o -15 1 2 119.23 105.92 3.80 o -13 1 2 11.13 6.76 1.61 o -11 1 2 0.26 0.28 1.22 o -9 1 2 21.52 29.99 1.62 o -7 1 2 1114.96 1324.15 19.13 o -5 1 2 3800.53 4011.37 66.86 o -3 1 2 30.71 5.78 0.45 o -1 1 2 10432.49 9518.03 102.38 o 1 1 2 2190.60 2338.73 21.98 o 3 1 2 1388.33 1322.41 14.69 o 5 1 2 81.54 98.77 2.49 o 7 1 2 178.01 165.04 3.78 o 9 1 2 226.71 203.23 4.68 o 11 1 2 265.02 305.22 6.52 o 13 1 2 227.19 189.55 5.20 o 15 1 2 254.63 262.61 10.14 o -16 2 2 26.55 20.99 4.13 o -14 2 2 0.35 -0.06 1.76 o -12 2 2 344.90 338.67 7.06 o -10 2 2 293.94 266.27 5.61 o -8 2 2 572.96 425.46 10.92 o -6 2 2 10.94 0.12 0.62 o -4 2 2 44.18 20.81 0.86 o -2 2 2 4199.67 4004.60 50.71 o 0 2 2 723.12 556.82 5.15 o 2 2 2 198.99 153.97 4.37 o 4 2 2 32.61 0.66 0.55 o 6 2 2 2725.95 2638.67 35.12 o 8 2 2 13.31 7.69 1.38 o 10 2 2 696.36 698.45 12.13 o 12 2 2 32.05 19.34 6.45 o 14 2 2 1.64 1.74 1.83 o -15 3 2 0.34 2.60 2.04 o -13 3 2 85.42 71.74 3.65 o -11 3 2 20.72 32.27 2.11 o -9 3 2 393.53 405.24 6.26 o -7 3 2 255.15 316.96 4.91 o -5 3 2 6.20 2.94 0.88 o -3 3 2 42.89 23.88 0.90 o -1 3 2 29.96 14.34 0.70 o 1 3 2 298.07 332.54 3.57 o 3 3 2 40.59 58.62 1.61 o 5 3 2 342.54 441.39 6.17 o 7 3 2 974.47 994.73 12.27 o 9 3 2 60.52 42.49 1.85 o 11 3 2 15.84 11.43 2.04 o 13 3 2 189.94 215.29 5.86 o -12 4 2 6.26 4.60 2.02 o -10 4 2 16.71 10.09 2.04 o -8 4 2 661.51 674.23 17.89 o -6 4 2 151.44 132.97 3.74 o -4 4 2 1058.26 1130.59 16.98 o -2 4 2 1.19 0.58 0.89 o 0 4 2 45.91 43.06 1.37 o 2 4 2 1.88 7.16 1.32 o 4 4 2 178.16 162.93 3.29 o 6 4 2 61.42 67.89 2.16 o 8 4 2 0.42 1.55 1.24 o 10 4 2 0.39 -1.04 1.79 o 12 4 2 242.55 296.07 7.49 o -9 5 2 41.08 13.82 3.88 o -7 5 2 56.21 48.16 2.73 o -5 5 2 173.22 172.93 4.73 o -3 5 2 102.69 94.94 3.39 o -1 5 2 71.03 67.08 2.81 o 1 5 2 175.16 155.67 3.51 o 3 5 2 766.08 757.35 10.32 o 5 5 2 8.48 7.68 1.93 o 7 5 2 315.17 286.43 6.60 o 9 5 2 42.11 43.12 4.55 o -4 6 2 61.07 39.58 2.74 o -2 6 2 108.45 140.04 6.03 o 0 6 2 9.56 19.13 2.76 o -17 1 3 1.03 1.60 2.99 o -15 1 3 57.83 51.65 3.77 o -13 1 3 347.54 337.64 9.38 o -11 1 3 134.66 124.81 3.53 o -9 1 3 434.75 536.30 13.34 o -7 1 3 5978.46 5901.69 137.14 o -5 1 3 507.20 365.27 4.82 o -3 1 3 115.27 90.91 1.30 o -1 1 3 17117.50 15612.96 170.15 o 1 1 3 660.83 1254.13 12.18 o 3 1 3 43.55 93.75 2.50 o 5 1 3 92.12 120.66 3.50 o 7 1 3 347.34 499.42 8.54 o 9 1 3 1570.17 1487.08 31.44 o 11 1 3 358.39 286.96 6.36 o 13 1 3 561.68 542.51 10.52 o 15 1 3 209.54 265.99 6.96 o -16 2 3 28.53 31.44 4.72 o -14 2 3 13.75 9.15 3.20 o -12 2 3 312.78 334.12 6.97 o -10 2 3 71.11 65.02 1.98 o -8 2 3 109.67 115.23 2.47 o -6 2 3 15.81 1.79 0.67 o -4 2 3 127.81 123.65 2.15 o -2 2 3 49.63 59.74 1.10 o 0 2 3 448.42 524.43 9.82 o 2 2 3 2332.92 2856.38 30.04 o 4 2 3 938.27 1156.29 13.32 o 6 2 3 0.18 0.20 0.91 o 8 2 3 451.47 444.57 8.24 o 10 2 3 1824.30 1861.43 27.82 o 12 2 3 688.10 643.35 11.82 o 14 2 3 38.88 37.70 2.63 o -15 3 3 25.73 35.95 3.12 o -13 3 3 31.49 17.64 4.51 o -11 3 3 43.76 28.54 2.42 o -9 3 3 3.44 1.52 1.37 o -7 3 3 1.07 3.96 1.31 o -5 3 3 814.00 680.36 9.47 o -3 3 3 22.12 37.58 1.08 o -1 3 3 145.83 233.77 3.07 o 1 3 3 1142.58 1040.73 9.42 o 3 3 3 916.72 1006.47 10.15 o 5 3 3 2.77 0.00 0.78 o 7 3 3 1606.94 1509.09 17.76 o 9 3 3 9.95 5.38 1.59 o 11 3 3 181.22 151.45 4.68 o 13 3 3 21.75 39.66 4.05 o -12 4 3 6.18 11.83 2.20 o -10 4 3 327.16 368.09 7.64 o -8 4 3 32.87 37.82 2.28 o -6 4 3 458.73 475.33 8.66 o -4 4 3 479.70 419.11 7.83 o -2 4 3 294.07 338.14 6.58 o 0 4 3 87.26 55.31 1.77 o 2 4 3 1205.76 1192.60 12.38 o 4 4 3 257.66 243.95 5.15 o 6 4 3 190.04 167.20 3.49 o 8 4 3 6.93 4.88 1.92 o 10 4 3 173.16 158.26 4.98 o 12 4 3 57.59 69.86 3.56 o -9 5 3 335.64 427.19 8.90 o -7 5 3 319.73 282.95 6.64 o -5 5 3 100.20 134.35 4.20 o -3 5 3 42.48 35.88 2.26 o -1 5 3 185.39 175.48 4.67 o 1 5 3 1769.12 2007.72 28.83 o 3 5 3 30.68 13.41 4.19 o 5 5 3 127.99 146.08 4.26 o 7 5 3 124.22 161.76 5.02 o 9 5 3 65.28 42.15 4.38 o -2 6 3 2.34 3.59 2.89 o 0 6 3 15.00 27.28 4.80 o 2 6 3 22.64 17.28 3.92 o -16 0 4 19.50 28.83 3.29 o -14 0 4 270.36 269.27 8.72 o -12 0 4 2775.98 2592.74 52.43 o -10 0 4 1301.33 1500.35 31.15 o -8 0 4 0.41 -0.21 1.05 o -6 0 4 2009.33 2282.71 31.27 o -4 0 4 125.30 317.61 5.08 o -2 0 4 57851.65 41793.30 555.34 o 0 0 4 4547.87 4967.44 70.91 o 2 0 4 7323.99 7439.11 99.14 o 4 0 4 8394.79 8127.35 154.68 o 6 0 4 3822.79 4875.78 94.15 o 8 0 4 1215.05 1279.26 27.27 o 10 0 4 1383.31 1470.52 31.61 o 12 0 4 70.16 53.57 3.96 o 14 0 4 337.89 357.95 11.51 o 16 0 4 19.08 42.15 4.38 o -17 1 4 249.58 263.08 9.82 o -15 1 4 76.90 61.09 2.95 o -13 1 4 1601.67 1567.63 23.73 o -11 1 4 210.33 214.34 4.88 o -9 1 4 703.65 743.91 9.58 o -7 1 4 16.05 37.48 1.24 o -5 1 4 1383.13 1763.18 19.96 o -3 1 4 3766.36 4277.06 52.35 o -1 1 4 13894.14 13297.11 144.65 o 1 1 4 841.69 819.07 7.69 o 3 1 4 531.54 419.73 5.24 o 5 1 4 392.63 415.62 5.31 o 7 1 4 198.09 138.45 3.56 o 9 1 4 907.41 971.76 15.64 o 11 1 4 488.40 462.39 9.01 o 13 1 4 53.67 41.49 2.59 o 15 1 4 29.38 43.93 3.14 o -16 2 4 113.30 129.69 4.60 o -14 2 4 106.26 94.94 4.66 o -12 2 4 82.64 71.27 2.92 o -10 2 4 0.05 2.23 1.06 o -8 2 4 599.72 604.31 8.02 o -6 2 4 1118.65 1269.85 14.91 o -4 2 4 2.31 64.07 1.19 o -2 2 4 600.68 521.46 7.93 o 0 2 4 1110.88 1313.80 11.43 o 2 2 4 1614.76 1408.66 12.19 o 4 2 4 1049.77 815.83 9.71 o 6 2 4 92.19 123.11 2.39 o 8 2 4 5.56 0.38 1.22 o 10 2 4 344.56 339.24 7.27 o 12 2 4 0.19 0.37 1.56 o 14 2 4 8.32 2.48 2.06 o -15 3 4 58.28 51.57 3.10 o -13 3 4 436.88 445.61 9.20 o -11 3 4 0.14 0.66 1.59 o -9 3 4 1203.01 1142.17 17.68 o -7 3 4 3.71 4.91 1.37 o -5 3 4 1744.22 1909.80 29.46 o -3 3 4 52.96 91.74 1.70 o -1 3 4 1046.26 1241.59 13.15 o 1 3 4 383.27 553.02 6.17 o 3 3 4 24.13 18.24 0.83 o 5 3 4 549.29 588.02 9.40 o 7 3 4 1834.35 1897.61 27.91 o 9 3 4 426.20 423.15 8.48 o 11 3 4 140.24 133.10 4.41 o 13 3 4 11.51 2.78 2.23 o -12 4 4 81.69 64.27 4.93 o -10 4 4 1035.31 1123.96 43.81 o -8 4 4 247.51 229.47 5.53 o -6 4 4 45.72 36.03 3.33 o -4 4 4 1609.99 1806.05 25.80 o -2 4 4 601.11 666.18 11.02 o 0 4 4 17.22 6.95 1.41 o 2 4 4 237.76 259.93 3.77 o 4 4 4 7.72 11.60 1.87 o 6 4 4 1145.38 1142.08 14.20 o 8 4 4 85.86 73.06 4.19 o 10 4 4 278.16 352.14 8.02 o -9 5 4 117.29 106.94 4.04 o -7 5 4 5.43 5.89 3.98 o -5 5 4 52.07 50.84 2.69 o -3 5 4 35.08 31.41 2.16 o -1 5 4 0.48 0.83 1.54 o 1 5 4 8.25 7.92 1.89 o 3 5 4 123.22 127.51 4.10 o 5 5 4 242.39 252.40 5.89 o 7 5 4 0.00 -3.54 2.82 o -2 6 4 38.74 22.35 2.85 o 0 6 4 15.21 2.21 2.05 o -17 1 5 1.30 -1.88 2.74 o -15 1 5 13.18 5.79 2.00 o -13 1 5 423.03 426.44 6.80 o -11 1 5 20.41 21.51 1.44 o -9 1 5 106.69 63.90 1.84 o -7 1 5 1711.40 1502.11 15.06 o -5 1 5 157.80 218.17 3.16 o -3 1 5 129.59 98.63 1.83 o -1 1 5 1639.04 1466.55 14.33 o 1 1 5 609.01 444.61 5.60 o 3 1 5 58.94 69.82 1.45 o 5 1 5 590.66 574.22 9.39 o 7 1 5 492.34 399.94 7.42 o 9 1 5 48.76 26.31 1.88 o 11 1 5 287.78 321.93 7.05 o 13 1 5 152.38 163.05 4.97 o 15 1 5 6.94 3.71 2.21 o -16 2 5 182.66 177.08 5.52 o -14 2 5 219.14 211.44 5.72 o -12 2 5 118.54 118.02 3.87 o -10 2 5 179.27 182.40 4.59 o -8 2 5 258.40 286.52 4.59 o -6 2 5 138.13 171.20 2.47 o -4 2 5 1018.05 1116.55 13.07 o -2 2 5 19.01 34.94 2.00 o 0 2 5 690.18 752.05 6.87 o 2 2 5 1036.78 1123.12 13.29 o 4 2 5 1218.34 1347.97 11.85 o 6 2 5 409.83 435.18 7.89 o 8 2 5 53.33 53.79 2.43 o 10 2 5 346.77 333.62 7.28 o 12 2 5 6.88 0.25 2.49 o 14 2 5 124.80 114.78 6.81 o -15 3 5 55.49 68.83 3.62 o -13 3 5 40.09 47.30 2.80 o -11 3 5 104.68 89.70 3.33 o -9 3 5 768.13 743.24 12.41 o -7 3 5 253.87 208.52 4.73 o -5 3 5 106.59 117.02 3.20 o -3 3 5 411.73 384.24 5.52 o -1 3 5 22.57 1.67 0.76 o 1 3 5 3.93 5.40 0.77 o 3 3 5 119.33 198.26 2.61 o 5 3 5 188.30 153.23 5.37 o 7 3 5 255.42 241.12 5.54 o 9 3 5 1.03 0.93 1.58 o 11 3 5 78.10 85.37 3.62 o 13 3 5 11.48 4.61 2.35 o -12 4 5 13.42 9.06 3.33 o -10 4 5 64.63 85.94 5.27 o -8 4 5 147.37 147.76 4.31 o -6 4 5 19.90 12.90 1.83 o -4 4 5 207.93 222.42 5.18 o -2 4 5 97.10 82.83 2.94 o 0 4 5 389.18 322.83 6.42 o 2 4 5 316.06 291.99 6.02 o 4 4 5 99.88 67.51 2.11 o 6 4 5 171.17 165.53 18.59 o 8 4 5 0.23 0.74 1.87 o 10 4 5 101.31 99.58 4.01 o -9 5 5 1.18 1.72 2.09 o -7 5 5 126.31 99.16 3.82 o -5 5 5 406.84 482.76 11.36 o -3 5 5 1.48 3.19 1.63 o -1 5 5 174.84 239.07 5.79 o 1 5 5 291.17 346.78 7.30 o 3 5 5 222.67 231.44 5.76 o 5 5 5 91.64 119.86 6.11 o 7 5 5 21.19 4.97 3.20 o -16 0 6 0.69 3.46 2.91 o -14 0 6 887.40 841.71 14.17 o -12 0 6 1.37 3.04 1.44 o -10 0 6 20.88 22.38 1.62 o -8 0 6 1884.71 1888.61 34.37 o -6 0 6 879.06 1087.87 15.68 o -4 0 6 91.83 68.18 11.46 o -2 0 6 3904.95 4189.08 56.05 o 0 0 6 32.40 14.41 0.84 o 2 0 6 5002.06 4874.23 65.21 o 4 0 6 0.56 8.89 1.13 o 6 0 6 45.68 46.53 2.99 o 8 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