#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/19/2221922.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2221922_Fobs loop_ _publ_author_name 'Gowda, B. Thimme' 'Foro, Sabine' 'Nirmala, P. G.' 'Terao, Hiromitsu' 'Fuess, Hartmut' _publ_section_title ; 4-Methyl-N-phenylbenzenesulfonamide ; _journal_coeditor_code BQ2138 _journal_issue 6 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1219 _journal_volume 65 _journal_year 2009 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 113.200 _cell_angle_gamma 90.000 _cell_length_a 8.7700 _cell_length_b 9.7680 _cell_length_c 16.2340 _exptl_crystal_F_000 520.00 _reflns_d_resolution_high 0.8381 _[local]_cod_data_source_file bq2138Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' GA18 P21/C' _shelx_refln_list_code 4 _shelx_f_calc_maximum 114.72 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 3994.20 3831.59 708.25 o 2 0 0 1714.29 1694.45 252.33 o 3 0 0 1013.01 913.81 47.23 o 4 0 0 803.80 800.16 4.36 o 5 0 0 608.39 517.48 3.44 o 6 0 0 579.33 460.41 3.58 o 7 0 0 315.16 266.77 2.81 o 8 0 0 0.82 1.95 0.19 o 9 0 0 1.59 1.17 0.12 o 1 1 0 4461.84 5037.13 261.22 o 2 1 0 11681.07 11948.38 1632.31 o 3 1 0 3830.04 4408.55 17.04 o 4 1 0 11.19 13.12 0.43 o 5 1 0 14.40 10.38 0.30 o 6 1 0 16.42 16.95 0.49 o 7 1 0 11.36 12.58 0.43 o 8 1 0 29.69 29.74 0.81 o 9 1 0 6.42 7.63 0.22 o 0 2 0 296.15 370.78 2.01 o 1 2 0 8910.82 9192.35 422.59 o 2 2 0 5917.90 6773.83 639.50 o 3 2 0 97.40 132.98 1.53 o 4 2 0 2333.21 2096.63 9.39 o 5 2 0 850.50 847.34 5.30 o 6 2 0 67.54 73.04 1.38 o 7 2 0 0.47 0.13 0.18 o 8 2 0 7.12 6.16 0.22 o 9 2 0 0.01 0.10 0.13 o 1 3 0 687.09 741.26 37.46 o 2 3 0 1616.75 1663.27 136.54 o 3 3 0 1451.14 1836.59 8.69 o 4 3 0 1638.76 2033.06 10.13 o 5 3 0 41.27 45.20 1.14 o 6 3 0 297.12 303.70 3.27 o 7 3 0 19.46 23.77 0.67 o 8 3 0 0.07 -0.05 0.32 o 9 3 0 0.55 1.18 0.13 o 0 4 0 371.98 427.13 2.94 o 1 4 0 3.95 0.71 0.07 o 2 4 0 50.87 57.65 5.22 o 3 4 0 64.06 80.45 1.43 o 4 4 0 0.46 2.84 0.20 o 5 4 0 0.95 2.29 0.21 o 6 4 0 0.50 1.36 0.21 o 7 4 0 0.79 0.14 0.38 o 8 4 0 17.72 15.80 0.49 o 9 4 0 4.30 4.86 0.16 o 1 5 0 356.16 497.39 13.93 o 2 5 0 101.35 122.38 12.64 o 3 5 0 10.12 40.17 1.11 o 4 5 0 16.00 16.67 0.52 o 5 5 0 35.75 40.44 1.12 o 6 5 0 56.43 62.68 1.44 o 7 5 0 19.06 18.57 0.59 o 8 5 0 2.28 3.18 0.19 o 0 6 0 208.88 215.18 2.56 o 1 6 0 8.82 8.24 0.17 o 2 6 0 231.59 230.81 21.44 o 3 6 0 1.05 2.77 0.22 o 4 6 0 0.11 2.88 0.24 o 5 6 0 41.91 51.70 1.43 o 6 6 0 8.58 9.17 0.34 o 7 6 0 17.49 19.83 0.60 o 8 6 0 0.65 1.45 0.15 o 1 7 0 115.02 102.89 4.99 o 2 7 0 205.39 191.14 7.83 o 3 7 0 57.59 52.64 1.46 o 4 7 0 34.90 43.82 1.31 o 5 7 0 58.53 67.04 1.60 o 6 7 0 2.23 4.30 0.23 o 7 7 0 0.04 0.20 0.14 o 0 8 0 89.94 73.96 1.73 o 1 8 0 36.56 29.30 0.64 o 2 8 0 0.29 0.59 0.13 o 3 8 0 0.01 -0.13 0.43 o 4 8 0 15.49 15.99 0.49 o 5 8 0 5.98 6.75 0.26 o 6 8 0 4.46 6.62 0.23 o 1 9 0 16.98 14.38 0.34 o 2 9 0 21.16 20.94 2.04 o 3 9 0 51.00 47.82 1.32 o 4 9 0 13.07 15.91 0.47 o 5 9 0 1.58 3.69 0.19 o 6 9 0 2.63 2.90 0.14 o 0 10 0 4.19 2.62 0.22 o 1 10 0 1.28 1.45 0.13 o 2 10 0 2.27 2.55 0.20 o 3 10 0 4.13 4.34 0.23 o 4 10 0 0.23 0.14 0.31 o 1 11 0 4.26 3.86 1.11 o 2 11 0 0.02 -0.06 0.23 o 3 11 0 0.92 0.33 0.12 o -9 1 1 4.70 4.44 0.19 o -8 1 1 44.51 38.82 1.06 o -7 1 1 69.48 55.65 1.20 o -6 1 1 16.20 12.56 0.40 o -5 1 1 0.37 1.65 0.12 o -4 1 1 1719.67 1416.30 6.44 o -3 1 1 396.78 377.70 2.36 o -2 1 1 8295.31 5352.92 3035.04 o -1 1 1 160.06 176.63 4.02 o 0 1 1 191.81 211.87 6.92 o 1 1 1 530.25 509.07 106.03 o 2 1 1 2632.84 3324.87 553.95 o 3 1 1 1.14 2.05 0.14 o 4 1 1 6.15 6.51 0.21 o 5 1 1 262.41 251.15 2.42 o 6 1 1 23.15 20.21 0.63 o 7 1 1 76.56 81.00 1.57 o 8 1 1 0.55 -0.12 0.33 o 9 1 1 0.01 -0.05 0.21 o -9 2 1 0.27 0.04 0.13 o -8 2 1 1.17 1.08 0.16 o -7 2 1 22.02 18.48 0.55 o -6 2 1 85.30 64.90 1.23 o -5 2 1 141.82 121.82 1.57 o -4 2 1 687.26 485.02 3.12 o -3 2 1 39.57 39.92 0.75 o -2 2 1 1419.80 1694.71 238.93 o -1 2 1 21.44 39.80 4.12 o 0 2 1 8938.36 9305.49 52.31 o 1 2 1 83.64 109.48 9.55 o 2 2 1 224.72 307.30 65.65 o 3 2 1 15.28 23.47 0.66 o 4 2 1 4.45 1.87 0.20 o 5 2 1 6.91 18.55 0.57 o 6 2 1 5.62 4.75 0.22 o 7 2 1 50.21 43.76 1.13 o 8 2 1 7.50 7.39 0.23 o 9 2 1 10.29 11.38 0.34 o -9 3 1 8.04 10.97 0.32 o -8 3 1 43.14 47.22 1.14 o -7 3 1 84.30 83.83 1.54 o -6 3 1 704.15 665.04 4.96 o -5 3 1 164.56 143.25 1.85 o -4 3 1 281.22 316.64 2.86 o -3 3 1 1450.59 1547.78 7.35 o -2 3 1 738.49 753.12 70.58 o -1 3 1 1764.45 1921.61 127.66 o 0 3 1 630.32 630.07 12.86 o 1 3 1 1761.11 1985.85 36.17 o 2 3 1 81.09 77.83 15.31 o 3 3 1 17.79 22.71 0.70 o 4 3 1 2.45 1.63 0.16 o 5 3 1 270.40 279.04 2.94 o 6 3 1 285.86 305.09 3.29 o 7 3 1 97.24 89.19 1.57 o 8 3 1 3.77 4.83 0.20 o 9 3 1 1.72 1.59 0.12 o -9 4 1 14.30 18.52 0.52 o -8 4 1 9.46 7.38 0.27 o -7 4 1 10.47 14.10 0.41 o -6 4 1 95.55 98.26 1.83 o -5 4 1 692.18 669.26 4.80 o -4 4 1 569.43 586.16 4.45 o -3 4 1 306.44 290.30 2.65 o -2 4 1 47.43 56.82 3.16 o -1 4 1 164.64 178.52 5.34 o 0 4 1 708.62 734.29 10.10 o 1 4 1 6.52 4.29 0.11 o 2 4 1 811.26 877.52 111.95 o 3 4 1 172.17 188.91 2.32 o 4 4 1 94.08 101.05 1.84 o 5 4 1 29.57 26.51 0.81 o 6 4 1 0.51 0.78 0.20 o 7 4 1 9.06 10.71 0.31 o 8 4 1 41.86 47.89 1.07 o -8 5 1 46.31 52.32 1.16 o -7 5 1 45.34 47.50 1.26 o -6 5 1 42.94 41.12 1.22 o -5 5 1 76.88 95.92 1.96 o -4 5 1 39.20 41.99 1.22 o -3 5 1 72.33 81.45 1.48 o -2 5 1 1222.33 1263.09 84.40 o -1 5 1 48.36 39.35 0.74 o 0 5 1 11.98 10.10 0.36 o 1 5 1 56.60 63.99 3.04 o 2 5 1 17.24 19.70 2.48 o 3 5 1 2.17 1.59 0.18 o 4 5 1 23.93 35.93 0.99 o 5 5 1 229.68 287.28 3.38 o 6 5 1 3.09 4.20 0.25 o 7 5 1 36.42 38.44 1.06 o 8 5 1 4.22 5.52 0.21 o -8 6 1 2.05 2.79 0.18 o -7 6 1 6.86 8.80 0.27 o -6 6 1 63.64 77.22 1.75 o -5 6 1 46.00 58.78 1.57 o -4 6 1 168.60 212.63 2.88 o -3 6 1 61.21 65.94 1.50 o -2 6 1 67.19 63.28 5.78 o -1 6 1 12.80 8.44 0.20 o 0 6 1 51.07 61.83 4.48 o 1 6 1 154.82 129.44 7.97 o 2 6 1 61.47 57.84 6.17 o 3 6 1 94.27 110.05 1.95 o 4 6 1 45.64 57.98 1.45 o 5 6 1 75.59 84.74 1.82 o 6 6 1 4.13 6.51 0.26 o 7 6 1 16.22 19.83 0.58 o 8 6 1 5.84 8.52 0.24 o -7 7 1 7.54 10.08 0.27 o -6 7 1 5.46 6.14 0.27 o -5 7 1 1.61 3.32 0.26 o -4 7 1 63.89 82.78 1.83 o -3 7 1 72.26 71.44 1.68 o -2 7 1 62.15 61.91 7.07 o -1 7 1 8.10 9.89 0.21 o 0 7 1 9.90 7.91 0.42 o 1 7 1 29.42 27.87 0.65 o 2 7 1 3.67 5.65 2.06 o 3 7 1 0.67 1.17 0.20 o 4 7 1 0.40 0.74 0.20 o 5 7 1 32.27 34.46 1.02 o 6 7 1 33.36 41.09 1.13 o 7 7 1 0.73 0.62 0.15 o -7 8 1 0.19 0.24 0.25 o -6 8 1 2.00 2.51 0.19 o -5 8 1 0.43 0.78 0.16 o -4 8 1 0.15 0.13 0.35 o -3 8 1 16.75 15.35 0.44 o -2 8 1 24.59 22.84 2.66 o -1 8 1 8.07 6.16 0.35 o 0 8 1 35.31 27.50 3.08 o 1 8 1 9.37 7.85 0.80 o 2 8 1 17.01 15.46 0.69 o 3 8 1 2.73 4.21 0.25 o 4 8 1 0.16 0.03 0.38 o 5 8 1 0.40 0.54 0.14 o 6 8 1 0.01 0.02 0.31 o -6 9 1 4.58 5.02 0.19 o -5 9 1 0.01 0.35 0.16 o -4 9 1 0.32 -0.21 0.38 o -3 9 1 2.97 2.63 0.24 o -2 9 1 0.95 1.11 0.13 o -1 9 1 72.14 65.08 6.57 o 0 9 1 33.98 20.73 2.72 o 1 9 1 1.25 1.81 0.35 o 2 9 1 15.79 14.40 1.15 o 3 9 1 2.92 3.32 0.22 o 4 9 1 2.33 2.28 0.19 o 5 9 1 5.74 6.14 0.22 o -5 10 1 3.59 5.29 0.19 o -4 10 1 39.56 46.50 1.07 o -3 10 1 31.39 27.60 0.81 o -2 10 1 0.89 0.35 0.10 o -1 10 1 10.61 8.48 1.10 o 0 10 1 15.72 9.86 0.84 o 1 10 1 12.38 9.81 1.77 o 2 10 1 37.99 30.60 0.59 o 3 10 1 39.55 31.52 0.94 o 4 10 1 2.00 1.91 0.16 o -3 11 1 9.39 9.86 0.30 o -2 11 1 22.76 20.44 0.90 o -1 11 1 2.94 2.33 0.73 o 0 11 1 4.54 1.64 0.17 o 1 11 1 5.84 4.11 1.29 o 2 11 1 4.26 3.03 0.47 o -9 0 2 18.61 18.48 0.56 o -8 0 2 151.62 113.73 1.68 o -7 0 2 59.09 39.26 0.98 o -6 0 2 32.61 30.90 0.76 o -5 0 2 110.52 77.09 1.03 o -4 0 2 12.10 15.71 0.41 o -3 0 2 419.97 297.71 43.55 o -2 0 2 577.84 191.07 233.01 o -1 0 2 13161.12 9741.74 621.11 o 0 0 2 1930.33 1598.28 38.52 o 1 0 2 6938.06 6867.33 31.05 o 2 0 2 1923.50 2292.42 219.51 o 3 0 2 4528.01 4493.18 952.19 o 4 0 2 2.97 10.67 0.31 o 5 0 2 427.24 389.48 3.23 o 6 0 2 191.12 180.31 2.28 o 7 0 2 4.84 7.35 0.27 o 8 0 2 14.27 13.97 0.44 o 9 0 2 17.14 21.70 0.64 o -9 1 2 3.74 4.04 0.18 o -8 1 2 51.79 44.78 1.09 o -7 1 2 128.79 94.85 1.51 o -6 1 2 520.72 349.23 2.83 o -5 1 2 89.33 73.91 1.09 o -4 1 2 186.35 149.49 1.35 o -3 1 2 272.17 228.34 1.58 o -2 1 2 35.85 28.64 6.46 o -1 1 2 1.94 5.17 0.29 o 0 1 2 8441.45 9349.41 132.37 o 1 1 2 6111.88 7535.78 195.27 o 2 1 2 1053.37 1239.46 182.53 o 3 1 2 1.23 2.17 0.12 o 4 1 2 30.44 37.40 0.93 o 5 1 2 542.22 535.58 3.90 o 6 1 2 186.19 192.03 2.34 o 7 1 2 127.07 126.43 1.89 o 8 1 2 5.40 6.04 0.21 o 9 1 2 0.04 -0.03 0.24 o -9 2 2 11.66 12.87 0.37 o -8 2 2 12.39 10.41 0.30 o -7 2 2 16.43 13.48 0.41 o -6 2 2 1.19 4.96 0.19 o -5 2 2 4.88 5.56 0.18 o -4 2 2 507.80 514.00 3.30 o -3 2 2 564.70 505.64 2.89 o -2 2 2 944.21 926.70 80.01 o -1 2 2 2376.12 2545.64 162.87 o 0 2 2 256.29 273.82 14.61 o 1 2 2 34.83 29.58 4.81 o 2 2 2 5.34 4.48 1.26 o 3 2 2 296.13 419.73 3.38 o 4 2 2 2078.23 2424.08 11.15 o 5 2 2 174.48 195.78 2.43 o 6 2 2 2.38 6.60 0.24 o 7 2 2 32.47 31.64 0.84 o 8 2 2 3.12 3.84 0.18 o -9 3 2 0.00 0.16 0.30 o -8 3 2 0.74 -0.27 0.37 o -7 3 2 4.73 3.68 0.19 o -6 3 2 5.73 7.05 0.26 o -5 3 2 81.30 69.59 1.18 o -4 3 2 234.46 236.48 2.27 o -3 3 2 1075.23 1146.64 5.60 o -2 3 2 650.90 669.07 41.57 o -1 3 2 757.98 805.76 25.89 o 0 3 2 1090.44 1179.59 46.36 o 1 3 2 124.67 164.42 12.05 o 2 3 2 1123.69 1197.01 184.06 o 3 3 2 397.04 525.72 3.98 o 4 3 2 1.12 0.62 0.15 o 5 3 2 97.30 102.79 1.77 o 6 3 2 10.78 14.81 0.49 o 7 3 2 1.71 2.09 0.18 o 8 3 2 2.20 4.48 0.20 o -9 4 2 1.11 1.68 0.15 o -8 4 2 16.79 15.81 0.47 o -7 4 2 61.66 64.62 1.49 o -6 4 2 6.48 6.34 0.27 o -5 4 2 42.34 45.05 1.22 o -4 4 2 152.98 175.74 2.10 o -3 4 2 12.62 18.47 0.55 o -2 4 2 5.13 11.54 1.79 o -1 4 2 199.89 204.17 11.02 o 0 4 2 147.42 159.59 5.17 o 1 4 2 574.04 657.55 31.73 o 2 4 2 956.19 1017.43 113.05 o 3 4 2 109.47 161.62 2.16 o 4 4 2 60.12 70.91 1.53 o 5 4 2 1.60 1.24 0.20 o 6 4 2 22.08 25.05 0.79 o 7 4 2 0.65 0.89 0.16 o 8 4 2 4.88 5.04 0.21 o -9 5 2 0.35 0.22 0.25 o -8 5 2 6.01 6.45 0.27 o -7 5 2 0.06 0.05 0.36 o -6 5 2 100.39 100.60 1.86 o -5 5 2 49.45 51.39 1.40 o -4 5 2 26.89 34.84 1.06 o -3 5 2 0.98 0.80 0.14 o -2 5 2 796.47 750.16 83.25 o -1 5 2 64.29 70.55 0.88 o 0 5 2 174.61 213.87 1.55 o 1 5 2 0.49 0.84 0.42 o 2 5 2 154.00 143.15 13.66 o 3 5 2 42.68 43.96 1.17 o 4 5 2 9.98 14.41 0.44 o 5 5 2 135.36 130.07 2.07 o 6 5 2 6.49 7.78 0.26 o 7 5 2 5.96 6.70 0.23 o 8 5 2 0.02 -0.21 0.23 o -8 6 2 4.13 5.11 0.22 o -7 6 2 1.25 1.14 0.20 o -6 6 2 161.63 200.57 2.91 o -5 6 2 17.11 19.95 0.58 o -4 6 2 196.48 223.50 2.95 o -3 6 2 138.97 161.14 2.30 o -2 6 2 5.18 6.51 2.30 o -1 6 2 48.22 40.27 2.53 o 0 6 2 75.56 72.66 10.57 o 1 6 2 269.09 290.19 16.03 o 2 6 2 123.61 115.80 4.89 o 3 6 2 51.58 55.95 1.43 o 4 6 2 66.44 79.55 1.74 o 5 6 2 148.61 172.70 2.58 o 6 6 2 0.21 -0.11 0.41 o 7 6 2 0.00 0.13 0.33 o -8 7 2 0.65 0.91 0.12 o -7 7 2 7.72 13.08 0.41 o -6 7 2 51.93 60.71 1.52 o -5 7 2 18.46 18.32 0.59 o -4 7 2 96.20 109.36 2.14 o -3 7 2 91.07 99.65 1.98 o -2 7 2 7.65 5.87 0.71 o -1 7 2 9.61 9.84 0.21 o 0 7 2 89.88 74.20 9.76 o 1 7 2 187.21 177.82 2.91 o 2 7 2 130.48 117.66 1.69 o 3 7 2 72.93 70.95 1.60 o 4 7 2 4.29 8.21 0.32 o 5 7 2 18.47 21.06 0.65 o 6 7 2 0.32 0.77 0.16 o 7 7 2 12.87 18.60 0.50 o -7 8 2 6.72 7.27 0.21 o -6 8 2 39.33 43.12 1.11 o -5 8 2 0.40 0.88 0.18 o -4 8 2 5.48 8.67 0.30 o -3 8 2 47.77 52.15 1.51 o -2 8 2 116.47 100.73 17.80 o -1 8 2 259.48 271.01 4.73 o 0 8 2 0.10 2.22 1.40 o 1 8 2 31.80 31.06 2.93 o 2 8 2 38.71 32.76 0.74 o 3 8 2 112.58 102.78 1.95 o 4 8 2 30.93 35.81 0.98 o 5 8 2 3.46 4.92 0.22 o 6 8 2 8.26 11.97 0.35 o -6 9 2 3.99 6.54 0.21 o -5 9 2 5.84 7.97 0.26 o -4 9 2 11.41 13.06 0.35 o -3 9 2 15.54 18.85 0.58 o -2 9 2 35.90 31.11 2.46 o -1 9 2 0.12 0.49 0.14 o 0 9 2 125.00 89.31 18.18 o 1 9 2 73.77 57.73 10.85 o 2 9 2 25.49 22.80 0.72 o 3 9 2 4.67 5.36 0.26 o 4 9 2 0.15 0.44 0.16 o 5 9 2 0.91 0.26 0.27 o -5 10 2 0.08 -0.25 0.25 o -4 10 2 2.87 4.19 0.22 o -3 10 2 4.02 4.78 0.23 o -2 10 2 12.99 11.73 0.80 o -1 10 2 3.17 3.69 0.41 o 0 10 2 18.01 9.12 1.73 o 1 10 2 0.03 0.01 0.15 o 2 10 2 5.06 5.52 0.52 o 3 10 2 8.01 8.27 0.26 o 4 10 2 1.11 1.74 0.13 o -3 11 2 0.75 1.07 0.14 o -2 11 2 1.64 2.41 0.12 o -1 11 2 3.35 2.90 0.63 o 0 11 2 3.59 1.74 0.28 o 1 11 2 2.94 2.94 1.10 o 2 11 2 1.96 2.14 0.44 o -10 1 3 1.96 2.18 0.14 o -9 1 3 1.07 0.96 0.12 o -8 1 3 35.22 23.70 0.70 o -7 1 3 4.53 3.59 0.19 o -6 1 3 1.81 8.01 0.23 o -5 1 3 4.70 4.83 0.14 o -4 1 3 50.54 41.21 0.66 o -3 1 3 64.78 64.06 0.73 o -2 1 3 454.88 391.71 18.92 o -1 1 3 8996.10 7957.83 1090.25 o 0 1 3 4521.63 4847.94 143.41 o 1 1 3 212.36 188.31 58.55 o 2 1 3 180.57 203.39 32.30 o 3 1 3 22.04 30.05 0.79 o 4 1 3 4.97 1.84 0.18 o 5 1 3 83.50 79.38 1.39 o 6 1 3 2.44 1.69 0.20 o 7 1 3 9.76 8.07 0.25 o 8 1 3 0.79 0.91 0.13 o -9 2 3 5.27 6.59 0.20 o -8 2 3 106.72 84.75 1.51 o -7 2 3 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