#------------------------------------------------------------------------------ #$Date: 2009-10-12 18:56:40 +0300 (Mon, 12 Oct 2009) $ #$Revision: 830 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2223226.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2223226_Fobs loop_ _publ_author_name 'Hua, Jia' 'Gao, Lu' _publ_section_title ; 4,4'-(Propane-1,3-diyl)dibenzoic acid ; _journal_coeditor_code XU2559 _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2233 _journal_volume 65 _journal_year 2009 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 102.722 _cell_angle_gamma 90.000 _cell_length_a 14.5686 _cell_length_b 4.7337 _cell_length_c 21.4634 _exptl_crystal_F_000 600.00 _reflns_d_resolution_high 0.8403 _[local]_cod_data_source_file xu2559Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' sad in C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 235.67 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 1387.38 1444.64 17.53 o 4 0 0 2119.28 2141.12 29.29 o 6 0 0 1112.65 1094.81 26.06 o 8 0 0 2510.04 2762.28 106.97 o 10 0 0 12.09 -4.70 7.63 o 12 0 0 115.39 115.78 17.35 o 14 0 0 194.17 206.48 38.07 o 16 0 0 180.14 174.30 24.66 o 1 1 0 3607.04 3520.21 71.84 o 3 1 0 908.98 722.19 11.88 o 5 1 0 1610.26 1742.45 26.98 o 7 1 0 2988.83 3131.64 48.82 o 9 1 0 370.80 405.48 14.69 o 11 1 0 22.68 12.60 7.48 o 13 1 0 0.19 -0.71 9.87 o 15 1 0 36.17 29.95 13.19 o 0 2 0 2921.57 2851.36 52.71 o 2 2 0 1695.24 1612.59 31.11 o 4 2 0 305.24 305.94 11.66 o 6 2 0 297.50 282.47 16.14 o 8 2 0 5.89 -0.49 5.31 o 10 2 0 269.43 292.91 17.92 o 12 2 0 253.75 262.70 20.42 o 14 2 0 1.22 6.15 15.59 o 1 3 0 6.95 1.09 5.36 o 3 3 0 165.29 170.92 10.21 o 5 3 0 151.14 170.76 10.99 o 7 3 0 90.22 100.43 12.55 o 9 3 0 125.70 119.22 19.80 o 11 3 0 72.14 89.60 20.15 o 13 3 0 185.42 212.37 28.76 o 0 4 0 13.27 15.19 9.38 o 2 4 0 79.13 74.70 8.37 o 4 4 0 0.44 2.49 6.95 o 6 4 0 327.28 334.78 21.96 o 8 4 0 44.35 49.51 13.66 o 10 4 0 32.12 10.09 16.80 o 1 5 0 6.72 -4.83 8.93 o 3 5 0 8.02 -3.56 10.56 o 5 5 0 2.70 -1.54 10.78 o 7 5 0 14.13 19.82 14.71 o -15 1 1 1.43 -8.06 11.32 o -13 1 1 52.40 51.53 10.62 o -11 1 1 4.22 -6.22 6.22 o -9 1 1 82.55 79.79 10.26 o -7 1 1 233.23 271.76 10.78 o -5 1 1 1.76 -2.06 3.37 o -3 1 1 2060.75 2060.85 49.63 o -1 1 1 4628.98 4519.87 110.36 o 1 1 1 851.07 785.95 11.86 o 3 1 1 2406.15 2395.20 32.93 o 5 1 1 321.29 311.56 11.51 o 7 1 1 40.92 77.66 11.49 o 9 1 1 17.03 22.52 6.57 o 11 1 1 208.06 174.17 13.39 o 13 1 1 39.86 35.92 11.81 o 15 1 1 4.17 -4.01 11.63 o -14 2 1 17.40 3.86 21.08 o -12 2 1 6.81 0.54 9.78 o -10 2 1 168.06 186.77 15.76 o -8 2 1 331.94 352.19 12.83 o -6 2 1 0.04 -1.79 4.13 o -4 2 1 33.70 34.75 5.89 o -2 2 1 644.77 570.11 16.44 o 0 2 1 0.00 -0.79 3.89 o 2 2 1 2.23 -2.24 4.14 o 4 2 1 853.07 887.63 21.84 o 6 2 1 556.22 568.28 20.67 o 8 2 1 148.11 173.89 14.51 o 10 2 1 81.27 78.60 12.83 o 12 2 1 561.09 588.57 27.12 o 14 2 1 17.38 33.45 17.96 o -13 3 1 0.18 -7.64 15.92 o -11 3 1 415.38 382.48 30.12 o -9 3 1 197.49 211.29 25.23 o -7 3 1 0.34 -6.82 6.82 o -5 3 1 128.31 139.57 9.84 o -3 3 1 247.49 286.49 11.59 o -1 3 1 185.48 189.91 10.64 o 1 3 1 2160.91 2008.62 51.49 o 3 3 1 33.11 27.51 5.46 o 5 3 1 352.37 401.60 15.95 o 7 3 1 182.12 214.83 16.74 o 9 3 1 18.40 18.74 10.16 o 11 3 1 3.70 -5.99 12.85 o 13 3 1 7.32 7.72 16.73 o -12 4 1 17.76 34.24 21.56 o -10 4 1 14.69 20.63 13.45 o -8 4 1 0.01 -0.94 11.95 o -6 4 1 385.40 416.93 28.33 o -4 4 1 3.57 -4.81 6.96 o -2 4 1 7.64 5.67 6.62 o 0 4 1 216.49 210.55 11.23 o 2 4 1 79.00 70.84 9.59 o 4 4 1 2.34 -2.28 7.08 o 6 4 1 368.89 392.77 23.13 o 8 4 1 377.56 368.27 24.58 o 10 4 1 13.12 3.79 16.13 o -7 5 1 0.00 4.11 16.72 o -5 5 1 1.95 14.64 11.49 o -3 5 1 1.48 -0.08 10.53 o -1 5 1 53.35 58.99 11.97 o 1 5 1 31.02 22.41 9.89 o 3 5 1 16.66 15.07 11.31 o 5 5 1 17.47 13.91 13.79 o 7 5 1 8.11 -7.82 14.12 o -16 0 2 68.91 59.27 18.67 o -14 0 2 544.66 515.02 30.15 o -12 0 2 34.40 19.54 11.51 o -10 0 2 774.61 837.78 45.74 o -8 0 2 133.63 121.71 13.10 o -6 0 2 5511.83 5801.42 58.01 o -4 0 2 194.97 171.70 12.73 o -2 0 2 2958.25 2555.34 32.16 o 0 0 2 4798.69 4704.99 33.17 o 2 0 2 55542.51 48792.41 230.44 o 4 0 2 4006.86 3982.83 42.08 o 6 0 2 451.91 414.48 17.29 o 8 0 2 399.52 434.31 20.43 o 10 0 2 37.25 34.78 11.39 o 12 0 2 121.25 115.06 17.35 o 14 0 2 49.47 33.12 15.21 o 16 0 2 8.81 -20.45 22.26 o -15 1 2 15.00 17.27 12.77 o -13 1 2 93.99 78.76 11.33 o -11 1 2 283.79 269.64 14.02 o -9 1 2 178.28 169.23 10.76 o -7 1 2 537.73 518.81 15.65 o -5 1 2 0.99 2.37 3.40 o -3 1 2 14285.99 12913.80 322.95 o -1 1 2 202.47 199.46 5.61 o 1 1 2 1813.32 1692.06 55.23 o 3 1 2 415.11 367.03 14.77 o 5 1 2 477.90 493.86 12.20 o 7 1 2 1225.45 1317.35 60.96 o 9 1 2 13.20 13.96 6.33 o 11 1 2 3.56 5.05 7.25 o 13 1 2 207.38 202.20 27.03 o 15 1 2 2.91 10.57 12.76 o -16 2 2 16.67 15.58 39.72 o -14 2 2 8.77 10.34 15.60 o -12 2 2 1.66 -7.55 12.26 o -10 2 2 62.20 78.31 9.58 o -8 2 2 75.74 81.18 8.46 o -6 2 2 35.28 37.86 6.11 o -4 2 2 353.66 378.06 10.62 o -2 2 2 1353.46 1398.20 24.53 o 0 2 2 1622.89 1524.27 39.71 o 2 2 2 7.15 2.29 3.39 o 4 2 2 91.54 106.58 12.57 o 6 2 2 5.62 2.09 6.28 o 8 2 2 7.13 3.20 7.68 o 10 2 2 3.33 -4.45 8.33 o 12 2 2 687.81 681.83 29.46 o 14 2 2 77.20 79.98 16.47 o -13 3 2 137.49 203.94 28.38 o -11 3 2 13.70 23.75 15.01 o -9 3 2 1330.59 1306.40 48.03 o -7 3 2 510.70 548.28 23.05 o -5 3 2 32.31 38.38 7.50 o -3 3 2 270.27 284.13 11.55 o -1 3 2 993.36 937.85 26.22 o 1 3 2 175.92 184.67 9.49 o 3 3 2 15.06 7.98 4.95 o 5 3 2 74.27 75.84 9.90 o 7 3 2 112.60 127.79 14.76 o 9 3 2 21.06 9.76 11.93 o 11 3 2 13.00 23.75 14.35 o 13 3 2 19.75 7.12 15.96 o -12 4 2 14.03 11.95 17.94 o -10 4 2 15.42 31.28 17.46 o -8 4 2 240.05 247.90 21.64 o -6 4 2 23.72 23.68 9.60 o -4 4 2 2.17 -3.77 7.97 o -2 4 2 4.45 6.64 6.36 o 0 4 2 370.82 347.66 14.48 o 2 4 2 0.84 -0.82 7.49 o 4 4 2 113.29 128.60 11.82 o 6 4 2 6.53 17.81 9.44 o 8 4 2 334.78 343.74 23.32 o 10 4 2 15.08 18.00 16.47 o -7 5 2 0.16 -3.04 20.82 o -5 5 2 2.30 8.73 11.41 o -3 5 2 25.66 21.98 10.95 o -1 5 2 10.49 0.80 11.68 o 1 5 2 137.65 152.11 14.58 o 3 5 2 9.84 10.88 11.18 o 5 5 2 10.98 6.65 13.69 o 7 5 2 6.84 6.82 14.29 o -15 1 3 31.28 27.23 13.25 o -13 1 3 5.08 -7.37 7.37 o -11 1 3 0.33 -5.94 5.94 o -9 1 3 4.82 0.24 5.30 o -7 1 3 726.87 713.37 16.00 o -5 1 3 1.96 -2.08 3.35 o -3 1 3 6037.60 5587.46 513.47 o -1 1 3 9994.21 9442.33 103.50 o 1 1 3 5398.83 5371.49 65.49 o 3 1 3 1030.36 992.43 24.05 o 5 1 3 2882.03 2866.77 133.25 o 7 1 3 41.78 43.31 6.35 o 9 1 3 379.52 365.45 14.31 o 11 1 3 21.16 14.23 7.42 o 13 1 3 191.94 172.45 21.80 o 15 1 3 17.86 8.07 13.65 o -16 2 3 9.27 -3.28 17.05 o -14 2 3 39.41 46.30 18.26 o -12 2 3 0.11 13.06 13.30 o -10 2 3 728.72 659.12 19.11 o -8 2 3 16.08 29.43 6.58 o -6 2 3 519.71 493.93 13.57 o -4 2 3 178.33 148.01 8.86 o -2 2 3 2670.48 2690.10 66.19 o 0 2 3 828.01 820.12 28.85 o 2 2 3 457.56 434.18 11.04 o 4 2 3 342.18 407.32 19.46 o 6 2 3 1034.05 1038.26 32.46 o 8 2 3 79.55 82.68 11.86 o 10 2 3 75.69 96.56 14.34 o 12 2 3 33.75 35.38 12.37 o 14 2 3 140.22 143.80 20.02 o -13 3 3 86.03 59.17 21.99 o -11 3 3 7.26 3.25 13.00 o -9 3 3 1390.34 1433.53 50.55 o -7 3 3 283.91 278.69 16.66 o -5 3 3 113.94 121.89 9.29 o -3 3 3 33.49 28.95 5.90 o -1 3 3 27.11 31.79 6.15 o 1 3 3 50.75 66.03 7.24 o 3 3 3 4.50 16.87 6.68 o 5 3 3 246.08 248.21 16.31 o 7 3 3 109.57 132.98 14.72 o 9 3 3 7.67 5.16 9.99 o 11 3 3 0.16 -0.12 11.01 o 13 3 3 22.76 30.17 18.46 o -12 4 3 0.97 6.53 22.68 o -10 4 3 5.17 21.85 17.15 o -8 4 3 83.20 83.51 15.27 o -6 4 3 3.80 4.68 8.58 o -4 4 3 12.64 14.84 8.99 o -2 4 3 268.02 257.87 12.99 o 0 4 3 1.86 3.50 6.61 o 2 4 3 24.26 17.79 8.18 o 4 4 3 0.76 5.39 8.51 o 6 4 3 12.68 3.03 9.01 o 8 4 3 120.88 118.41 17.91 o 10 4 3 4.00 -3.06 12.98 o -7 5 3 11.70 16.11 14.41 o -5 5 3 30.44 20.83 13.84 o -3 5 3 8.12 4.96 11.09 o -1 5 3 15.68 7.35 11.55 o 1 5 3 0.23 -1.57 9.30 o 3 5 3 515.68 613.98 25.29 o 5 5 3 14.18 14.95 13.77 o 7 5 3 11.24 24.22 20.11 o -16 0 4 175.61 180.29 24.48 o -14 0 4 31.59 16.70 18.69 o -12 0 4 3.62 -2.02 9.48 o -10 0 4 724.48 755.28 28.45 o -8 0 4 3108.76 3344.04 84.02 o -6 0 4 45.68 24.06 7.11 o -4 0 4 151.88 111.86 12.25 o -2 0 4 70.42 76.76 4.99 o 0 0 4 567.31 586.23 13.40 o 2 0 4 1264.07 1314.17 34.50 o 4 0 4 3209.23 3223.71 64.43 o 6 0 4 2748.58 2717.38 50.16 o 8 0 4 97.47 83.13 12.40 o 10 0 4 9.99 4.04 9.95 o 12 0 4 16.68 0.32 12.11 o 14 0 4 25.21 28.13 14.98 o 16 0 4 17.84 23.21 26.09 o -17 1 4 82.42 29.92 28.54 o -15 1 4 7.84 -1.21 14.50 o -13 1 4 38.51 41.14 10.35 o -11 1 4 30.91 39.19 8.55 o -9 1 4 1920.87 2032.86 30.04 o -7 1 4 0.89 3.20 4.24 o -5 1 4 15.36 6.28 3.26 o -3 1 4 16349.52 16144.93 483.99 o -1 1 4 33847.53 32798.45 699.53 o 1 1 4 822.28 885.67 41.09 o 3 1 4 730.55 797.30 22.59 o 5 1 4 453.00 444.92 12.16 o 7 1 4 63.64 74.61 7.72 o 9 1 4 603.64 516.08 16.88 o 11 1 4 668.55 686.41 27.50 o 13 1 4 22.92 13.16 11.96 o 15 1 4 58.92 35.21 14.52 o -16 2 4 0.14 1.29 18.05 o -14 2 4 6.12 1.18 14.02 o -12 2 4 196.48 225.68 25.45 o -10 2 4 78.43 92.82 12.71 o -8 2 4 15.06 13.60 5.81 o -6 2 4 97.33 105.76 7.28 o -4 2 4 3.04 1.14 3.30 o -2 2 4 4388.87 4474.98 85.16 o 0 2 4 219.23 221.30 8.87 o 2 2 4 77.78 81.59 6.33 o 4 2 4 3186.94 3357.57 54.05 o 6 2 4 41.06 40.65 11.29 o 8 2 4 7.98 17.21 8.47 o 10 2 4 210.79 196.31 18.43 o 12 2 4 1.51 0.11 10.73 o 14 2 4 111.82 91.24 18.34 o -13 3 4 137.42 179.70 26.99 o -11 3 4 25.20 35.13 15.92 o -9 3 4 149.99 170.86 22.10 o -7 3 4 1163.42 1103.48 29.05 o -5 3 4 556.18 577.85 18.82 o -3 3 4 0.03 -2.76 4.67 o -1 3 4 654.10 658.76 32.58 o 1 3 4 148.98 136.77 9.14 o 3 3 4 51.78 60.00 10.33 o 5 3 4 1.84 1.73 7.86 o 7 3 4 2.12 -2.71 8.19 o 9 3 4 34.89 59.12 21.39 o 11 3 4 0.01 17.59 12.71 o 13 3 4 19.95 -10.41 17.49 o -12 4 4 0.30 17.25 17.59 o -10 4 4 18.86 17.07 15.12 o -8 4 4 15.79 15.96 14.93 o -6 4 4 84.88 95.45 13.01 o -4 4 4 2.87 -7.09 7.54 o -2 4 4 2.24 0.68 6.64 o 0 4 4 1.57 0.08 6.49 o 2 4 4 453.42 450.78 19.02 o 4 4 4 3.81 -1.70 8.97 o 6 4 4 230.02 255.50 18.56 o 8 4 4 6.15 8.52 10.95 o 10 4 4 26.71 31.10 15.55 o -7 5 4 0.39 0.89 13.60 o -5 5 4 17.50 21.20 14.09 o -3 5 4 14.32 7.55 12.41 o -1 5 4 0.82 1.80 11.73 o 1 5 4 12.28 20.70 11.09 o 3 5 4 217.67 273.67 21.04 o 5 5 4 100.08 136.70 20.72 o -17 1 5 27.03 33.94 20.34 o -15 1 5 0.83 10.31 11.58 o -13 1 5 11.59 2.34 8.16 o -11 1 5 36.75 36.15 8.25 o -9 1 5 166.86 177.97 11.25 o -7 1 5 62.60 60.06 6.69 o -5 1 5 710.45 719.12 11.72 o -3 1 5 452.61 399.16 11.35 o -1 1 5 10525.71 10047.74 392.41 o 1 1 5 906.76 820.12 23.06 o 3 1 5 3147.63 3181.64 69.91 o 5 1 5 109.24 115.24 8.17 o 7 1 5 1111.51 1070.36 58.62 o 9 1 5 239.37 254.58 14.13 o 11 1 5 363.71 372.36 24.42 o 13 1 5 0.93 6.85 10.91 o 15 1 5 0.05 -6.40 12.20 o -16 2 5 1.60 25.36 18.48 o -14 2 5 0.03 5.26 14.82 o -12 2 5 220.22 241.85 26.84 o -10 2 5 246.27 248.68 17.20 o -8 2 5 1333.26 1374.84 31.23 o -6 2 5 485.43 474.98 11.22 o -4 2 5 708.08 854.40 19.87 o -2 2 5 18.90 17.98 4.14 o 0 2 5 180.72 191.61 8.90 o 2 2 5 743.04 680.52 13.85 o 4 2 5 794.72 860.60 58.67 o 6 2 5 411.84 433.23 23.46 o 8 2 5 2.84 1.20 8.50 o 10 2 5 47.78 46.28 12.50 o 12 2 5 3.36 -10.44 10.44 o 14 2 5 12.11 16.72 14.29 o -13 3 5 15.67 30.56 17.66 o -11 3 5 31.88 31.40 14.90 o -9 3 5 20.19 0.14 12.32 o -7 3 5 446.22 413.84 24.56 o -5 3 5 55.68 77.41 13.33 o -3 3 5 61.72 64.63 7.12 o -1 3 5 55.13 54.99 7.02 o 1 3 5 2.80 4.51 5.24 o 3 3 5 183.13 176.01 14.99 o 5 3 5 153.91 210.57 17.65 o 7 3 5 36.98 36.97 13.35 o 9 3 5 11.54 15.62 10.84 o 11 3 5 7.89 5.42 12.07 o 13 3 5 12.46 8.54 17.87 o -12 4 5 33.10 46.73 31.25 o -10 4 5 0.00 13.67 15.62 o -8 4 5 73.37 61.34 15.30 o -6 4 5 128.90 142.43 17.58 o -4 4 5 31.78 34.97 9.65 o -2 4 5 131.35 129.14 11.09 o 0 4 5 3.87 -2.04 7.35 o 2 4 5 14.98 9.90 9.76 o 4 4 5 3.61 -5.39 9.39 o 6 4 5 0.05 6.89 9.97 o 8 4 5 0.31 -7.82 13.08 o 10 4 5 9.70 12.94 13.81 o -7 5 5 9.52 9.60 14.30 o -5 5 5 9.59 15.60 13.54 o -3 5 5 108.30 98.59 22.20 o -1 5 5 34.73 10.35 15.81 o 1 5 5 1.74 4.42 12.69 o 3 5 5 17.19 17.89 12.21 o 5 5 5 643.94 725.46 34.28 o -16 0 6 0.01 12.39 16.37 o -14 0 6 349.65 346.82 25.61 o -12 0 6 165.31 192.48 20.32 o -10 0 6 691.01 656.56 26.74 o -8 0 6 565.42 566.60 22.42 o -6 0 6 56.23 43.07 8.34 o -4 0 6 2009.37 1906.76 75.93 o -2 0 6 304.40 285.48 9.00 o 0 0 6 107.94 142.74 9.66 o 2 0 6 1920.10 1736.39 45.15 o 4 0 6 4501.74 4621.15 83.81 o 6 0 6 3.43 12.99 12.14 o 8 0 6 3.76 -5.18 7.59 o 10 0 6 221.23 234.87 21.79 o 12 0 6 2.02 9.01 12.99 o 14 0 6 26.84 52.82 28.96 o -17 1 6 92.43 112.00 25.51 o -15 1 6 113.45 123.93 17.28 o -13 1 6 31.70 36.19 12.38 o -11 1 6 0.35 -6.55 6.55 o -9 1 6 0.00 -3.28 5.30 o -7 1 6 1523.10 1603.93 22.96 o -5 1 6 4610.29 4973.19 115.12 o -3 1 6 32.09 30.03 5.12 o -1 1 6 9804.69 9934.42 198.77 o 1 1 6 145.93 154.48 8.20 o 3 1 6 592.12 660.22 22.74 o 5 1 6 248.27 249.28 17.05 o 7 1 6 15.93 8.35 6.32 o 9 1 6 6.83 2.75 6.27 o 11 1 6 1041.35 1005.80 57.21 o 13 1 6 127.41 129.57 18.00 o 15 1 6 9.20 8.21 13.40 o -16 2 6 35.58 34.90 20.18 o -14 2 6 3.06 22.62 16.42 o -12 2 6 712.69 730.81 28.03 o -10 2 6 823.97 756.90 26.26 o -8 2 6 262.54 267.36 15.56 o -6 2 6 147.44 153.16 10.94 o -4 2 6 6280.32 6186.21 119.43 o -2 2 6 144.35 127.86 6.93 o 0 2 6 361.53 390.20 12.00 o 2 2 6 4.34 -0.24 3.84 o 4 2 6 31.46 29.39 10.70 o 6 2 6 1032.56 1034.66 35.38 o 8 2 6 26.22 28.35 11.75 o 10 2 6 15.23 -0.69 10.83 o 12 2 6 139.27 88.96 16.46 o 14 2 6 0.89 24.71 14.44 o -13 3 6 0.03 6.90 17.01 o -11 3 6 0.34 -14.54 14.54 o -9 3 6 0.83 -2.52 8.59 o -7 3 6 2.12 -0.93 6.39 o -5 3 6 1.39 5.89 6.52 o -3 3 6 202.68 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