#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/33/2223344.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2223344_Fobs loop_ _publ_author_name 'Wang, Bo' _publ_section_title ; (S)-1-Methoxycarbonyl-3-(4-nitrophenyl)propan-2-aminium bromide ; _journal_coeditor_code CV2604 _journal_issue 10 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o2397 _journal_volume 65 _journal_year 2009 _space_group_IT_number 4 _symmetry_space_group_name_Hall 'P 2yb' _symmetry_space_group_name_H-M 'P 1 21 1' _cell_angle_alpha 90.000 _cell_angle_beta 95.772 _cell_angle_gamma 90.000 _cell_length_a 4.9323 _cell_length_b 8.6233 _cell_length_c 15.2261 _exptl_crystal_F_000 308.00 _reflns_d_resolution_high 0.7700 _[local]_cod_data_source_file cv2604Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 2 in P2(1)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 88.10 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 -11 0 5.40 19.94 8.76 o 0 -10 0 218.62 223.46 40.55 o 1 -10 0 92.12 92.93 14.45 o 2 -10 0 79.31 107.58 21.50 o 1 -9 0 3.69 7.51 4.07 o 2 -9 0 1.80 0.25 4.02 o 3 -9 0 3.27 0.57 6.59 o 0 -8 0 448.54 495.98 53.90 o 1 -8 0 332.37 342.86 32.62 o 2 -8 0 174.83 190.41 18.41 o 3 -8 0 180.59 185.01 26.06 o 4 -8 0 52.88 43.23 17.25 o 1 -7 0 35.43 35.88 7.06 o 2 -7 0 5.26 2.88 2.49 o 3 -7 0 22.28 38.39 15.96 o 4 -7 0 3.07 4.94 5.64 o 0 -6 0 1365.69 1335.74 124.01 o 1 -6 0 698.87 707.32 37.64 o 2 -6 0 528.90 522.44 36.45 o 3 -6 0 255.81 255.29 18.45 o 4 -6 0 97.19 100.39 14.40 o 5 -6 0 103.24 100.11 27.67 o 1 -5 0 211.22 207.80 9.95 o 2 -5 0 9.56 13.37 2.76 o 3 -5 0 10.00 16.03 3.15 o 4 -5 0 5.96 4.76 3.27 o 5 -5 0 2.51 4.91 5.15 o 0 -4 0 2640.30 2959.08 150.28 o 1 -4 0 1978.95 1869.09 74.49 o 2 -4 0 751.04 769.01 39.83 o 3 -4 0 603.77 634.23 39.25 o 4 -4 0 211.85 242.14 18.85 o 5 -4 0 145.50 141.63 18.15 o 1 -3 0 333.35 351.28 13.01 o 2 -3 0 49.64 61.14 6.47 o 3 -3 0 53.24 58.12 4.87 o 4 -3 0 1.84 9.70 3.73 o 5 -3 0 2.77 0.99 9.38 o 6 -3 0 2.83 4.41 5.76 o 0 -2 0 599.50 611.27 19.08 o 1 -2 0 6817.87 7422.20 307.35 o 2 -2 0 1635.23 1655.94 129.70 o 3 -2 0 1188.60 1125.00 37.62 o 4 -2 0 365.42 411.99 28.95 o 5 -2 0 232.18 223.76 17.28 o 6 -2 0 43.69 49.86 11.90 o 1 -1 0 462.53 473.25 19.13 o 2 -1 0 56.65 56.01 2.74 o 3 -1 0 79.38 82.11 4.69 o 4 -1 0 1.37 3.95 2.22 o 5 -1 0 4.19 13.42 5.46 o 6 -1 0 11.87 12.74 8.97 o 1 0 0 111.78 118.96 7.76 o 2 0 0 2831.62 2543.97 335.39 o 3 0 0 426.68 387.50 26.20 o 4 0 0 689.00 688.35 36.80 o 5 0 0 261.66 345.38 53.10 o 6 0 0 60.87 54.43 10.80 o 1 1 0 450.86 498.59 13.22 o 2 1 0 51.77 52.80 7.18 o 3 1 0 89.55 93.94 5.41 o 4 1 0 0.66 7.49 3.62 o 5 1 0 2.51 3.77 4.20 o 6 1 0 13.20 15.27 7.30 o 1 2 0 7344.20 7463.12 237.01 o 2 2 0 1506.83 1419.64 67.46 o 3 2 0 1181.86 1148.80 94.54 o 4 2 0 396.04 374.49 39.64 o 5 2 0 223.66 275.79 25.23 o 6 2 0 51.73 77.60 14.34 o 1 3 0 335.07 362.43 8.48 o 2 3 0 56.17 65.47 4.73 o 3 3 0 45.88 53.79 5.26 o 4 3 0 3.62 10.44 4.06 o 5 3 0 2.99 3.83 2.90 o 6 3 0 2.66 1.51 6.16 o 0 4 0 3018.10 3354.34 222.08 o 1 4 0 1664.56 1743.92 57.51 o 2 4 0 921.84 911.89 46.71 o 3 4 0 566.06 584.93 38.77 o 4 4 0 231.89 267.88 21.95 o 5 4 0 153.59 156.07 17.36 o 1 5 0 214.26 224.53 8.12 o 2 5 0 7.41 7.59 2.43 o 3 5 0 10.34 6.09 3.22 o 4 5 0 4.46 8.32 3.81 o 5 5 0 2.24 3.44 11.74 o 0 6 0 1309.05 1308.14 71.84 o 1 6 0 766.27 793.19 31.49 o 2 6 0 479.93 492.95 31.02 o 3 6 0 250.33 230.17 28.76 o 4 6 0 94.49 94.58 12.53 o 5 6 0 106.18 130.66 34.08 o 1 7 0 37.31 33.80 2.72 o 2 7 0 6.68 12.98 3.48 o 3 7 0 20.65 15.21 10.77 o 4 7 0 1.90 2.54 3.88 o 0 8 0 393.76 374.03 27.11 o 1 8 0 389.82 371.40 47.13 o 2 8 0 138.21 136.04 10.95 o 3 8 0 188.19 181.16 19.72 o 4 8 0 49.28 57.12 11.63 o 1 9 0 3.93 -3.00 4.56 o 2 9 0 1.42 0.27 8.11 o 3 9 0 4.09 15.97 6.99 o 0 10 0 256.80 249.06 33.34 o 1 10 0 71.27 72.19 10.70 o 2 10 0 81.32 89.37 18.38 o 1 11 0 5.47 4.50 9.04 o -1 -11 1 30.31 9.53 7.19 o 0 -11 1 10.36 1.40 7.85 o 1 -11 1 24.40 16.88 8.58 o -2 -10 1 84.90 92.92 18.08 o -1 -10 1 64.05 63.06 13.84 o 0 -10 1 146.21 170.20 23.27 o 1 -10 1 30.05 20.05 7.79 o 2 -10 1 127.76 137.07 23.99 o -3 -9 1 4.32 3.70 6.54 o -2 -9 1 26.42 50.34 9.79 o -1 -9 1 30.10 30.65 7.23 o 0 -9 1 52.02 57.03 11.60 o 1 -9 1 9.85 14.28 9.37 o 2 -9 1 11.79 9.78 7.43 o 3 -9 1 8.87 18.29 7.19 o -4 -8 1 43.76 59.66 17.50 o -3 -8 1 104.41 80.25 21.17 o -2 -8 1 162.30 164.61 14.08 o -1 -8 1 380.51 402.63 37.15 o 0 -8 1 253.90 282.74 26.58 o 1 -8 1 235.98 274.98 25.09 o 2 -8 1 175.79 171.33 21.11 o 3 -8 1 164.61 175.55 22.58 o 4 -8 1 36.82 37.77 12.06 o -4 -7 1 13.22 5.72 4.44 o -3 -7 1 97.94 100.24 10.90 o -2 -7 1 54.65 55.33 7.34 o -1 -7 1 142.32 141.91 12.07 o 0 -7 1 40.55 45.47 10.75 o 1 -7 1 55.12 52.53 6.53 o 2 -7 1 55.08 54.19 9.26 o 3 -7 1 4.44 6.61 5.63 o 4 -7 1 20.19 34.70 11.07 o -5 -6 1 62.08 71.15 22.60 o -4 -6 1 72.05 68.13 7.84 o -3 -6 1 410.52 427.59 28.97 o -2 -6 1 327.98 329.99 20.63 o -1 -6 1 1226.89 1248.93 66.96 o 0 -6 1 934.55 996.14 47.83 o 1 -6 1 397.94 381.07 28.73 o 2 -6 1 580.98 623.57 47.28 o 3 -6 1 204.18 209.42 24.76 o 4 -6 1 207.92 224.01 25.83 o 5 -6 1 64.00 83.62 16.80 o -5 -5 1 7.61 11.01 7.48 o -4 -5 1 71.05 68.38 7.67 o -3 -5 1 142.64 148.32 11.23 o -2 -5 1 259.17 282.37 16.54 o -1 -5 1 247.26 265.91 16.06 o 0 -5 1 34.30 35.77 2.47 o 1 -5 1 20.59 28.72 3.71 o 2 -5 1 278.60 277.84 20.97 o 3 -5 1 13.07 15.48 4.66 o 4 -5 1 45.88 46.31 14.34 o 5 -5 1 2.13 1.57 4.85 o -5 -4 1 176.02 185.08 18.95 o -4 -4 1 125.25 128.04 11.62 o -3 -4 1 723.01 712.85 39.59 o -2 -4 1 1093.13 1162.90 57.10 o -1 -4 1 1947.26 1899.53 76.92 o 0 -4 1 2268.39 2546.13 109.54 o 1 -4 1 1851.58 1825.84 79.82 o 2 -4 1 942.40 978.49 48.88 o 3 -4 1 665.43 663.06 36.08 o 4 -4 1 261.09 247.52 25.67 o 5 -4 1 135.97 153.21 25.52 o -6 -3 1 9.34 -6.45 6.89 o -5 -3 1 32.21 34.46 6.70 o -4 -3 1 63.98 68.43 6.53 o -3 -3 1 91.53 91.76 6.34 o -2 -3 1 866.82 856.31 33.49 o -1 -3 1 97.22 98.25 4.32 o 0 -3 1 422.49 421.28 11.98 o 1 -3 1 892.10 936.00 28.93 o 2 -3 1 925.34 947.26 41.51 o 3 -3 1 47.20 48.42 7.98 o 4 -3 1 19.14 18.76 4.88 o 5 -3 1 4.70 17.59 5.77 o 6 -3 1 1.38 -0.98 4.32 o -6 -2 1 78.97 75.81 20.02 o -5 -2 1 110.61 112.52 18.41 o -4 -2 1 284.10 269.34 13.93 o -3 -2 1 850.64 895.30 40.96 o -2 -2 1 556.51 558.92 22.29 o -1 -2 1 4537.16 4391.85 128.37 o 0 -2 1 6613.19 6754.93 202.59 o 1 -2 1 3135.96 2909.96 194.90 o 2 -2 1 1142.00 1101.38 44.44 o 3 -2 1 658.68 673.43 22.75 o 4 -2 1 506.27 520.89 34.00 o 5 -2 1 177.56 157.87 15.48 o 6 -2 1 25.51 31.49 9.06 o -6 -1 1 34.90 38.06 9.49 o -5 -1 1 7.54 12.67 2.52 o -4 -1 1 80.98 84.66 5.80 o -3 -1 1 405.35 417.73 15.72 o -2 -1 1 209.48 226.32 7.49 o -1 -1 1 2512.18 2447.47 61.21 o 1 -1 1 4917.84 5017.34 85.66 o 2 -1 1 17.62 18.21 2.10 o 3 -1 1 254.41 317.82 19.14 o 4 -1 1 46.23 51.03 4.12 o 5 -1 1 0.79 2.42 2.80 o 6 -1 1 0.78 -5.01 5.54 o -6 0 1 41.19 34.29 8.82 o -5 0 1 174.92 185.17 13.45 o -4 0 1 248.99 265.59 15.12 o -3 0 1 371.37 359.35 15.79 o -2 0 1 4976.79 5112.41 204.08 o -1 0 1 2283.54 2296.46 77.77 o 1 0 1 36.21 37.47 2.09 o 2 0 1 2190.84 2472.39 125.22 o 3 0 1 1154.77 1198.07 75.35 o 4 0 1 379.65 458.06 109.29 o 5 0 1 195.02 235.78 20.87 o 6 0 1 39.15 37.01 8.51 o -6 1 1 33.31 35.45 8.89 o -5 1 1 6.59 11.40 6.83 o -4 1 1 79.47 80.00 6.84 o -3 1 1 383.49 411.12 19.73 o -2 1 1 288.52 303.37 20.26 o -1 1 1 2485.88 2496.03 55.68 o 1 1 1 4537.21 4868.32 169.49 o 2 1 1 20.34 20.67 3.26 o 3 1 1 280.58 276.06 17.80 o 4 1 1 44.63 43.04 7.76 o 5 1 1 1.86 4.78 4.28 o 6 1 1 0.86 -0.28 4.57 o -6 2 1 80.17 92.64 13.89 o -5 2 1 98.94 116.64 21.69 o -4 2 1 290.26 278.01 15.80 o -3 2 1 740.42 856.58 41.31 o -2 2 1 654.79 641.69 16.86 o -1 2 1 4592.47 4631.42 140.48 o 0 2 1 6346.41 6452.61 566.90 o 1 2 1 2421.51 2442.74 97.15 o 2 2 1 1124.13 1084.11 45.09 o 3 2 1 690.68 686.51 56.76 o 4 2 1 494.66 567.50 41.04 o 5 2 1 177.49 259.36 82.39 o 6 2 1 24.59 37.40 13.98 o -6 3 1 10.33 12.20 8.25 o -5 3 1 30.19 33.53 7.48 o -4 3 1 61.20 69.59 11.85 o -3 3 1 97.50 97.18 10.29 o -2 3 1 808.74 769.04 37.72 o -1 3 1 137.13 139.97 3.66 o 0 3 1 355.20 401.40 41.13 o 1 3 1 1026.67 1124.03 50.48 o 2 3 1 854.12 873.41 41.36 o 3 3 1 65.03 61.37 6.91 o 4 3 1 14.18 19.91 4.07 o 5 3 1 6.40 12.82 6.00 o 6 3 1 0.69 -4.67 4.67 o -5 4 1 171.11 165.21 21.14 o -4 4 1 136.76 152.38 15.25 o -3 4 1 659.97 617.59 43.32 o -2 4 1 1126.18 1095.06 63.24 o -1 4 1 1788.07 1808.52 97.08 o 0 4 1 2419.21 2954.27 344.81 o 1 4 1 1774.61 1889.26 134.19 o 2 4 1 955.01 999.89 50.83 o 3 4 1 627.59 570.96 35.57 o 4 4 1 274.12 276.80 17.79 o 5 4 1 130.78 199.51 36.20 o -4 5 1 68.37 53.66 9.82 o -3 5 1 147.37 162.25 14.23 o -2 5 1 267.77 267.50 17.08 o -1 5 1 266.25 296.94 11.00 o 0 5 1 12.16 13.01 1.98 o 1 5 1 14.07 22.00 2.38 o 2 5 1 297.15 308.93 16.26 o 3 5 1 11.29 12.45 2.75 o 4 5 1 45.15 47.85 13.98 o 5 5 1 1.54 -1.41 5.19 o -5 6 1 69.17 80.92 14.20 o -4 6 1 61.24 66.14 16.59 o -3 6 1 418.36 398.01 39.40 o -2 6 1 314.49 329.87 22.22 o -1 6 1 1302.15 1416.16 60.32 o 0 6 1 891.17 901.25 40.67 o 1 6 1 448.03 497.34 24.92 o 2 6 1 524.85 531.72 26.52 o 3 6 1 233.31 241.32 19.67 o 4 6 1 205.23 217.58 26.01 o 5 6 1 67.46 78.67 17.44 o -4 7 1 12.20 23.30 8.69 o -3 7 1 98.79 104.43 11.43 o -2 7 1 82.66 85.67 7.79 o -1 7 1 126.30 133.83 8.05 o 0 7 1 26.46 24.35 3.17 o 1 7 1 46.31 39.41 6.55 o 2 7 1 64.90 60.76 4.95 o 3 7 1 5.04 11.30 14.01 o 4 7 1 20.26 25.82 11.65 o -4 8 1 40.87 52.61 13.95 o -3 8 1 106.25 133.36 21.22 o -2 8 1 153.65 161.53 15.36 o -1 8 1 403.83 409.21 22.85 o 0 8 1 270.02 321.04 20.84 o 1 8 1 233.32 283.60 36.20 o 2 8 1 155.09 191.82 30.71 o 3 8 1 163.96 163.92 28.62 o 4 8 1 43.69 66.98 13.60 o -3 9 1 5.47 9.45 4.92 o -2 9 1 27.55 29.13 7.53 o -1 9 1 26.00 31.46 4.96 o 0 9 1 57.70 64.67 6.48 o 1 9 1 4.36 3.57 3.25 o 2 9 1 14.59 25.59 6.51 o 3 9 1 9.38 4.06 11.62 o -2 10 1 84.64 102.81 16.38 o -1 10 1 75.85 78.50 10.32 o 0 10 1 141.65 145.17 17.16 o 1 10 1 18.07 18.13 6.23 o 2 10 1 136.16 133.13 17.36 o 1 11 1 23.97 20.94 11.21 o -1 -11 2 31.84 27.55 14.80 o 0 -11 2 9.66 15.39 7.39 o -2 -10 2 55.45 62.58 13.02 o -1 -10 2 33.28 43.20 10.10 o 0 -10 2 102.70 94.49 15.85 o 1 -10 2 26.45 43.36 14.81 o 2 -10 2 65.92 76.87 16.52 o -3 -9 2 49.62 21.37 7.12 o -2 -9 2 61.79 65.04 10.38 o -1 -9 2 106.82 119.46 16.01 o 0 -9 2 19.32 24.10 6.62 o 1 -9 2 112.69 114.29 18.74 o 2 -9 2 37.62 28.92 9.79 o 3 -9 2 28.82 38.65 12.40 o -4 -8 2 23.85 35.53 8.69 o -3 -8 2 95.75 100.44 12.50 o -2 -8 2 108.29 123.22 12.77 o -1 -8 2 266.00 279.79 18.82 o 0 -8 2 59.99 74.92 9.16 o 1 -8 2 395.00 396.14 34.57 o 2 -8 2 91.85 96.74 14.15 o 3 -8 2 89.76 82.92 15.10 o 4 -8 2 39.16 57.68 29.66 o -4 -7 2 100.31 86.02 13.42 o -3 -7 2 77.33 73.27 9.21 o -2 -7 2 193.51 191.24 14.36 o -1 -7 2 263.01 269.43 15.10 o 0 -7 2 212.85 240.89 14.84 o 1 -7 2 103.97 95.59 9.88 o 2 -7 2 225.30 222.06 23.15 o 3 -7 2 75.75 78.02 12.77 o 4 -7 2 41.58 50.04 11.22 o -5 -6 2 22.16 31.36 8.41 o -4 -6 2 45.40 48.40 15.24 o -3 -6 2 329.09 311.09 21.71 o -2 -6 2 288.59 324.88 19.12 o -1 -6 2 459.49 494.93 27.94 o 0 -6 2 518.34 590.40 33.50 o 1 -6 2 43.22 28.91 5.22 o 2 -6 2 933.06 998.34 78.24 o 3 -6 2 67.86 78.51 12.54 o 4 -6 2 194.55 194.16 25.40 o 5 -6 2 23.00 30.16 11.68 o -5 -5 2 27.81 42.28 8.75 o -4 -5 2 192.31 184.97 15.97 o -3 -5 2 173.77 186.56 13.89 o -2 -5 2 365.47 328.71 17.50 o -1 -5 2 164.39 143.66 6.34 o 0 -5 2 284.48 279.48 16.93 o 1 -5 2 820.97 847.63 34.83 o 2 -5 2 480.38 498.86 34.53 o 3 -5 2 63.07 63.25 10.81 o 4 -5 2 49.84 41.03 8.73 o 5 -5 2 10.81 12.12 7.28 o -5 -4 2 35.20 39.03 7.34 o -4 -4 2 85.12 111.84 9.47 o -3 -4 2 362.04 352.03 18.87 o -2 -4 2 446.38 438.09 26.21 o -1 -4 2 2010.33 2029.88 85.50 o 0 -4 2 537.94 486.13 18.82 o 1 -4 2 705.50 680.37 20.84 o 2 -4 2 405.06 453.84 33.82 o 3 -4 2 618.62 560.31 43.02 o 4 -4 2 221.85 237.99 25.61 o 5 -4 2 55.47 59.92 10.62 o -6 -3 2 22.39 7.02 10.69 o -5 -3 2 60.14 62.49 7.88 o -4 -3 2 279.50 313.74 22.85 o -3 -3 2 396.17 397.13 19.61 o -2 -3 2 680.46 654.35 31.82 o -1 -3 2 1280.90 1228.95 59.36 o 0 -3 2 1920.52 1895.22 68.65 o 1 -3 2 795.63 884.55 25.35 o 2 -3 2 178.16 178.96 12.55 o 3 -3 2 138.95 136.16 12.91 o 4 -3 2 175.96 170.49 21.42 o 5 -3 2 10.67 12.38 5.00 o 6 -3 2 16.95 18.84 6.75 o -6 -2 2 46.02 29.68 12.14 o -5 -2 2 54.95 66.59 7.31 o -4 -2 2 187.60 206.88 13.80 o -3 -2 2 724.11 768.33 35.68 o -2 -2 2 1543.01 1668.97 82.91 o -1 -2 2 1789.45 1893.97 81.44 o 0 -2 2 1128.69 1131.84 33.81 o 1 -2 2 2855.56 3305.97 100.65 o 2 -2 2 2466.92 2298.90 63.24 o 3 -2 2 787.99 754.53 25.32 o 4 -2 2 228.97 240.29 25.64 o 5 -2 2 120.27 117.43 11.40 o 6 -2 2 29.82 17.21 7.61 o -6 -1 2 41.61 35.39 13.69 o -5 -1 2 81.84 90.22 9.25 o -4 -1 2 379.09 400.34 19.66 o -3 -1 2 900.58 913.67 34.77 o -2 -1 2 986.51 929.11 30.74 o -1 -1 2 2293.86 2237.63 53.11 o 1 -1 2 4716.85 4644.03 147.28 o 2 -1 2 1242.54 1169.96 36.80 o 3 -1 2 498.85 481.54 24.00 o 4 -1 2 82.92 76.79 5.79 o 5 -1 2 24.54 28.42 5.23 o 6 -1 2 17.01 10.99 5.84 o -6 0 2 42.53 40.02 8.58 o -5 0 2 56.16 60.10 6.63 o -4 0 2 256.49 285.55 16.22 o -3 0 2 761.44 819.41 35.38 o -2 0 2 2538.14 2826.15 132.81 o -1 0 2 3969.17 3865.25 87.56 o 1 0 2 1827.97 1868.79 63.86 o 2 0 2 2390.31 2474.60 141.46 o 3 0 2 515.07 599.52 79.75 o 4 0 2 576.38 600.42 32.30 o 5 0 2 95.48 108.81 10.67 o 6 0 2 23.26 15.84 11.40 o -6 1 2 32.97 45.96 8.93 o -5 1 2 104.52 114.84 9.17 o -4 1 2 367.03 441.43 55.49 o -3 1 2 963.08 984.88 46.58 o -2 1 2 891.35 822.12 31.71 o -1 1 2 2062.91 2043.54 92.60 o 0 1 2 2.69 2.99 0.26 o 1 1 2 5123.04 4779.01 148.89 o 2 1 2 1264.30 1368.76 158.58 o 3 1 2 526.93 579.23 62.07 o 4 1 2 58.77 91.89 20.83 o 5 1 2 27.76 32.77 5.77 o 6 1 2 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