#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/41/2224154.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2224154_Fobs loop_ _publ_author_name 'He, Jun' 'Yang, Jin-cheng' _publ_section_title ; 1-(4-Hydroxy-3,5-dimethoxyphenyl)ethanone ; _journal_coeditor_code CI2962 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3030 _journal_volume 65 _journal_year 2009 _space_group_IT_number 110 _symmetry_space_group_name_Hall 'I 4bw -2c' _symmetry_space_group_name_H-M 'I 41 c d' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 14.9775 _cell_length_b 14.9775 _cell_length_c 17.1423 _exptl_crystal_F_000 1664.00 _reflns_d_resolution_high 0.7603 _[local]_cod_data_source_file ci2962Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' R90714F in I4(1)cd' _shelx_refln_list_code 4 _shelx_f_calc_maximum 214.03 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y+1/2, z+1/2' '-y, x+1/2, z+1/4' 'y+1/2, -x, z+3/4' 'x, -y, z+1/2' '-x+1/2, y+1/2, z' '-y, -x+1/2, z+3/4' 'y+1/2, x, z+1/4' 'x+1/2, y+1/2, z+1/2' '-x+1, -y+1, z+1' '-y+1/2, x+1, z+3/4' 'y+1, -x+1/2, z+5/4' 'x+1/2, -y+1/2, z+1' '-x+1, y+1, z+1/2' '-y+1/2, -x+1, z+5/4' 'y+1, x+1/2, z+3/4' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 2 0 14092.63 13668.12 152.29 o 4 4 0 5820.21 5970.84 46.39 o 1 5 0 31657.08 33436.39 293.13 o 3 5 0 14368.32 14263.13 78.17 o 0 6 0 4502.84 4291.36 39.08 o 2 6 0 125.94 132.93 2.48 o 4 6 0 476.88 459.26 6.53 o 6 6 0 865.88 821.74 13.12 o 1 7 0 8600.89 8594.56 49.87 o 3 7 0 867.86 818.56 7.10 o 5 7 0 32.58 50.37 6.45 o 0 8 0 876.62 955.75 10.78 o 2 8 0 14539.62 14284.99 107.41 o 4 8 0 9283.03 9310.59 54.23 o 6 8 0 57.94 53.47 6.03 o 8 8 0 1305.09 1400.29 24.36 o 1 9 0 1495.32 1637.55 13.78 o 3 9 0 7261.37 7254.56 61.39 o 5 9 0 2042.40 2216.62 20.37 o 7 9 0 35.03 37.24 4.81 o 0 10 0 955.30 1136.14 25.42 o 2 10 0 100.11 95.82 7.60 o 4 10 0 637.13 668.80 8.87 o 6 10 0 1449.14 1491.49 13.25 o 8 10 0 31.49 30.57 5.46 o 10 10 0 622.71 682.73 21.97 o 1 11 0 1021.97 1095.90 15.63 o 3 11 0 176.53 180.15 7.41 o 5 11 0 415.34 406.23 7.96 o 7 11 0 684.29 737.83 15.51 o 9 11 0 145.92 146.09 9.79 o 0 12 0 1629.02 1641.57 34.76 o 2 12 0 216.94 221.23 7.88 o 4 12 0 4551.12 4687.51 44.60 o 6 12 0 1014.67 1039.12 15.76 o 8 12 0 595.84 585.77 21.30 o 10 12 0 0.52 6.83 5.39 o 12 12 0 23.87 16.17 11.79 o 1 13 0 36.61 45.42 6.86 o 3 13 0 385.77 368.90 10.72 o 5 13 0 2537.85 2464.91 28.78 o 7 13 0 1938.53 1981.91 21.98 o 9 13 0 0.59 6.22 5.11 o 11 13 0 269.09 233.05 49.82 o 0 14 0 17.62 13.59 9.50 o 2 14 0 4.67 6.07 3.97 o 4 14 0 1300.14 1324.57 16.68 o 6 14 0 757.00 824.89 14.89 o 8 14 0 467.68 483.33 18.79 o 10 14 0 306.66 290.75 25.97 o 12 14 0 554.81 616.67 44.25 o 1 15 0 145.77 150.15 14.26 o 3 15 0 28.86 31.44 5.36 o 5 15 0 212.41 197.09 15.01 o 7 15 0 210.76 216.88 18.68 o 9 15 0 46.05 40.12 13.87 o 11 15 0 35.92 31.47 15.50 o 0 16 0 246.34 259.69 34.31 o 2 16 0 757.63 704.72 34.36 o 4 16 0 421.37 417.32 14.92 o 6 16 0 3144.14 3271.62 37.08 o 8 16 0 31.92 33.92 12.16 o 10 16 0 62.93 42.95 13.10 o 1 17 0 186.41 158.85 15.83 o 3 17 0 6.68 9.51 6.53 o 5 17 0 802.64 800.35 20.48 o 7 17 0 1313.97 1296.46 32.64 o 9 17 0 333.72 299.32 31.31 o 0 18 0 225.83 238.48 74.65 o 2 18 0 132.64 68.36 18.86 o 4 18 0 51.11 44.28 12.41 o 6 18 0 324.31 313.72 25.30 o 8 18 0 570.13 619.60 24.70 o 1 19 0 907.83 986.27 26.81 o 3 19 0 1.99 5.09 9.11 o 5 19 0 66.95 73.31 20.72 o 1 2 1 5524.64 5089.85 14.92 o 2 3 1 5518.95 5245.21 18.32 o 1 4 1 45807.04 51077.07 676.82 o 3 4 1 9822.86 9351.95 34.02 o 2 5 1 19413.16 19211.59 64.96 o 4 5 1 5631.80 5540.86 26.18 o 1 6 1 196.61 194.52 2.11 o 3 6 1 3034.12 2984.43 16.16 o 5 6 1 4000.80 4049.30 31.40 o 2 7 1 10751.25 10639.90 44.41 o 4 7 1 1445.92 1520.33 8.74 o 6 7 1 1251.37 1318.48 8.39 o 1 8 1 2047.07 2085.13 9.50 o 3 8 1 10593.12 10377.36 57.14 o 5 8 1 3417.24 3747.11 18.54 o 7 8 1 1259.21 1313.06 9.60 o 2 9 1 6147.14 6432.84 40.67 o 4 9 1 19126.73 19398.64 91.60 o 6 9 1 546.10 588.99 6.21 o 8 9 1 1631.06 1624.96 12.08 o 1 10 1 949.91 956.13 7.26 o 3 10 1 368.79 387.68 5.30 o 5 10 1 2808.48 2902.89 15.49 o 7 10 1 103.23 101.66 3.66 o 9 10 1 1027.90 961.09 10.91 o 2 11 1 835.26 824.80 8.77 o 4 11 1 1796.09 1852.18 13.09 o 6 11 1 38.68 37.30 3.78 o 8 11 1 90.85 109.13 6.07 o 10 11 1 465.63 490.89 9.11 o 1 12 1 186.26 185.94 6.46 o 3 12 1 2454.67 2555.35 21.25 o 5 12 1 3483.46 3642.09 27.23 o 7 12 1 1542.20 1536.65 14.13 o 9 12 1 372.74 345.33 7.54 o 11 12 1 0.84 7.33 5.59 o 2 13 1 1910.36 1877.06 16.51 o 4 13 1 4260.36 4244.68 30.98 o 6 13 1 605.78 651.12 9.28 o 8 13 1 237.08 254.95 9.17 o 10 13 1 83.22 76.78 11.85 o 12 13 1 628.65 686.49 23.03 o 1 14 1 253.69 222.54 7.04 o 3 14 1 674.23 619.13 8.71 o 5 14 1 144.35 146.84 8.89 o 7 14 1 283.01 256.25 11.31 o 9 14 1 93.01 87.49 13.44 o 11 14 1 161.20 141.00 22.83 o 13 14 1 19.18 14.38 8.84 o 2 15 1 230.17 207.12 6.70 o 4 15 1 704.14 702.11 10.23 o 6 15 1 254.08 249.59 10.76 o 8 15 1 184.65 176.67 21.47 o 10 15 1 36.94 31.03 8.82 o 12 15 1 61.48 53.90 11.68 o 1 16 1 255.69 253.78 11.33 o 3 16 1 280.64 268.63 10.61 o 5 16 1 360.22 297.82 12.02 o 7 16 1 88.65 81.50 11.66 o 9 16 1 195.42 215.32 22.01 o 11 16 1 16.22 17.57 6.88 o 2 17 1 21.69 17.91 4.62 o 4 17 1 206.21 208.13 14.32 o 6 17 1 1702.20 1699.68 23.33 o 8 17 1 370.71 347.99 14.20 o 1 18 1 37.75 36.24 8.60 o 3 18 1 120.61 100.79 16.56 o 5 18 1 174.49 148.92 16.07 o 7 18 1 260.54 252.42 20.78 o 2 19 1 182.86 144.25 30.44 o 4 19 1 13.04 11.38 6.57 o 1 1 2 12703.88 12374.38 74.50 o 0 2 2 3989.69 3384.75 22.78 o 1 3 2 10433.25 9613.30 33.35 o 3 3 2 16174.59 15408.58 74.68 o 0 4 2 4368.17 4320.39 21.89 o 2 4 2 1339.37 1353.12 6.75 o 1 5 2 597.78 614.39 3.47 o 3 5 2 3933.73 3771.56 13.25 o 5 5 2 17208.20 17098.93 132.51 o 0 6 2 15215.33 15288.53 69.23 o 2 6 2 1978.29 2036.50 7.36 o 4 6 2 9815.78 9905.17 39.12 o 1 7 2 9109.54 9059.45 40.64 o 3 7 2 2984.64 2900.87 14.28 o 5 7 2 438.96 456.34 4.50 o 7 7 2 237.67 284.35 4.99 o 0 8 2 6776.01 7012.84 59.38 o 2 8 2 958.39 973.98 5.78 o 4 8 2 6233.02 6082.32 45.92 o 6 8 2 1977.40 2080.67 13.67 o 1 9 2 5314.12 5396.25 33.16 o 3 9 2 611.19 607.99 5.92 o 5 9 2 905.16 993.56 7.72 o 7 9 2 116.51 118.21 4.58 o 9 9 2 826.37 866.49 14.98 o 0 10 2 2233.12 2312.76 20.57 o 2 10 2 277.75 313.80 4.92 o 4 10 2 1074.25 1112.78 9.40 o 6 10 2 106.42 101.60 3.02 o 8 10 2 1598.76 1521.35 14.08 o 1 11 2 1862.39 1837.08 14.39 o 3 11 2 215.32 230.74 4.80 o 5 11 2 1747.22 1778.63 14.88 o 7 11 2 1718.92 1674.52 14.77 o 9 11 2 262.91 274.97 7.80 o 11 11 2 2234.88 2055.25 30.09 o 0 12 2 14.97 21.02 5.29 o 2 12 2 358.08 371.72 6.01 o 4 12 2 542.07 542.97 8.01 o 6 12 2 254.30 240.97 6.74 o 8 12 2 1423.69 1374.17 15.29 o 10 12 2 452.35 437.55 11.89 o 1 13 2 475.83 475.51 8.06 o 3 13 2 2075.50 2014.16 18.43 o 5 13 2 1365.18 1334.96 18.58 o 7 13 2 424.05 394.38 9.16 o 9 13 2 263.95 211.61 12.40 o 11 13 2 406.14 363.77 12.63 o 13 13 2 518.65 475.42 27.69 o 0 14 2 1236.04 1236.06 21.65 o 2 14 2 1209.57 1190.88 15.55 o 4 14 2 4.63 12.91 3.64 o 6 14 2 5.94 5.38 3.21 o 8 14 2 187.98 178.70 12.12 o 10 14 2 227.56 208.54 25.50 o 12 14 2 30.50 20.59 6.81 o 1 15 2 698.50 659.88 8.92 o 3 15 2 29.29 33.23 4.66 o 5 15 2 796.30 769.48 11.08 o 7 15 2 138.90 127.37 17.08 o 9 15 2 270.58 244.96 20.37 o 11 15 2 96.29 85.35 13.95 o 0 16 2 1276.02 1232.12 25.40 o 2 16 2 72.84 71.46 8.15 o 4 16 2 79.75 58.12 7.35 o 6 16 2 315.12 319.21 11.83 o 8 16 2 111.81 102.35 17.18 o 10 16 2 255.94 281.79 22.00 o 1 17 2 419.65 361.77 11.54 o 3 17 2 113.98 114.60 11.83 o 5 17 2 444.03 417.32 16.93 o 7 17 2 48.53 35.26 7.78 o 9 17 2 465.31 478.58 20.27 o 0 18 2 30.03 17.23 8.33 o 2 18 2 166.16 147.96 16.92 o 4 18 2 266.43 267.15 13.82 o 6 18 2 43.27 30.76 8.94 o 1 19 2 253.51 227.59 19.33 o 3 19 2 37.61 38.91 11.77 o 1 2 3 17467.19 16711.72 68.15 o 2 3 3 8872.56 8071.24 24.21 o 1 4 3 584.56 574.41 2.61 o 3 4 3 6583.68 6082.61 27.65 o 2 5 3 9572.41 8789.85 34.18 o 4 5 3 161.94 184.98 2.58 o 1 6 3 9451.92 8892.49 30.17 o 3 6 3 719.09 658.04 4.08 o 5 6 3 838.29 943.36 8.56 o 2 7 3 419.17 491.17 3.60 o 4 7 3 92.99 109.82 3.35 o 6 7 3 713.26 719.82 8.40 o 1 8 3 565.33 617.64 4.87 o 3 8 3 769.83 886.78 6.20 o 5 8 3 1822.52 1693.19 11.25 o 7 8 3 225.64 238.41 4.79 o 2 9 3 2728.06 2620.38 14.91 o 4 9 3 1762.24 1770.19 11.72 o 6 9 3 425.91 407.25 4.82 o 8 9 3 74.36 59.88 5.48 o 1 10 3 119.53 137.40 4.09 o 3 10 3 292.28 322.80 4.90 o 5 10 3 386.93 402.67 6.87 o 7 10 3 230.24 242.18 6.42 o 9 10 3 517.58 487.40 7.30 o 2 11 3 2606.94 2724.48 15.69 o 4 11 3 285.37 259.96 4.65 o 6 11 3 499.60 543.76 6.78 o 8 11 3 162.49 148.57 7.99 o 10 11 3 947.23 910.16 12.91 o 1 12 3 449.75 464.73 6.99 o 3 12 3 602.66 623.27 8.75 o 5 12 3 109.39 85.49 6.18 o 7 12 3 374.26 328.07 6.84 o 9 12 3 27.17 38.96 6.75 o 11 12 3 126.30 112.85 15.69 o 2 13 3 321.28 364.41 7.62 o 4 13 3 1100.19 1097.36 13.30 o 6 13 3 170.40 181.85 9.06 o 8 13 3 360.43 314.19 8.30 o 10 13 3 512.32 472.14 12.51 o 12 13 3 104.53 75.19 11.66 o 1 14 3 411.82 395.40 7.68 o 3 14 3 188.79 197.80 12.42 o 5 14 3 381.82 343.65 8.30 o 7 14 3 561.77 612.39 10.19 o 9 14 3 142.15 150.67 12.74 o 11 14 3 710.93 735.48 18.86 o 13 14 3 242.54 169.81 38.27 o 2 15 3 924.40 859.41 11.24 o 4 15 3 373.71 368.21 9.58 o 6 15 3 218.74 244.39 13.11 o 8 15 3 4.09 10.64 4.51 o 10 15 3 6.50 13.12 5.97 o 12 15 3 5.16 12.46 6.38 o 1 16 3 309.23 295.86 8.52 o 3 16 3 138.97 115.66 13.06 o 5 16 3 266.69 234.21 17.24 o 7 16 3 476.24 515.46 14.79 o 9 16 3 367.13 407.59 17.23 o 11 16 3 22.29 41.73 11.20 o 2 17 3 46.00 34.34 6.75 o 4 17 3 69.13 61.99 11.07 o 6 17 3 1550.14 1716.09 37.39 o 8 17 3 125.51 110.69 19.84 o 1 18 3 256.63 253.08 13.13 o 3 18 3 247.99 261.14 15.89 o 5 18 3 118.70 119.67 21.45 o 7 18 3 121.99 110.63 21.73 o 2 19 3 444.56 472.59 16.33 o 4 19 3 82.06 75.82 16.00 o 0 2 4 32121.79 33570.18 255.37 o 2 2 4 13880.62 13223.82 73.11 o 1 3 4 1173.71 1151.78 5.09 o 0 4 4 10146.95 9381.91 42.70 o 2 4 4 943.29 976.81 5.24 o 4 4 4 12203.47 11801.72 68.58 o 1 5 4 6437.32 6351.08 27.59 o 3 5 4 833.10 867.73 5.29 o 0 6 4 11061.09 10630.36 70.93 o 2 6 4 3635.34 3696.71 27.69 o 4 6 4 2929.38 2934.35 17.56 o 6 6 4 3656.86 3586.10 37.01 o 1 7 4 2459.82 2239.95 15.99 o 3 7 4 2730.61 2646.65 13.89 o 5 7 4 1839.98 1819.66 12.47 o 0 8 4 1661.71 1648.87 12.17 o 2 8 4 3816.57 3939.66 26.50 o 4 8 4 1154.61 1124.10 9.00 o 6 8 4 436.98 394.96 6.08 o 8 8 4 216.12 193.96 5.37 o 1 9 4 945.48 948.57 6.50 o 3 9 4 884.26 826.91 7.27 o 5 9 4 44.06 41.96 4.28 o 7 9 4 1304.00 1315.02 11.33 o 0 10 4 826.80 898.36 10.18 o 2 10 4 1276.95 1351.86 11.39 o 4 10 4 406.64 393.89 5.35 o 6 10 4 934.39 967.84 11.87 o 8 10 4 3951.23 4064.55 30.09 o 10 10 4 1512.20 1605.39 21.80 o 1 11 4 1226.62 1199.79 8.96 o 3 11 4 827.85 836.91 8.97 o 5 11 4 1580.30 1566.65 16.02 o 7 11 4 901.76 904.54 10.80 o 9 11 4 638.76 620.11 11.57 o 0 12 4 5322.26 5444.06 55.80 o 2 12 4 402.65 353.94 6.45 o 4 12 4 1197.46 1084.86 13.69 o 6 12 4 200.29 198.81 10.78 o 8 12 4 38.75 37.22 5.27 o 10 12 4 177.19 147.90 18.63 o 12 12 4 680.92 661.71 19.66 o 1 13 4 692.88 682.07 8.98 o 3 13 4 1888.68 1854.60 18.77 o 5 13 4 472.65 448.20 9.20 o 7 13 4 1561.90 1590.25 14.93 o 9 13 4 527.55 524.15 11.84 o 11 13 4 20.45 13.91 6.36 o 0 14 4 3353.86 3274.63 37.27 o 2 14 4 671.57 686.08 10.48 o 4 14 4 1042.29 1056.62 12.41 o 6 14 4 636.48 627.28 11.95 o 8 14 4 815.97 838.69 18.80 o 10 14 4 26.24 25.36 6.49 o 12 14 4 65.14 47.33 11.80 o 1 15 4 713.16 674.86 10.72 o 3 15 4 463.26 455.27 9.82 o 5 15 4 826.93 799.36 11.46 o 7 15 4 740.57 745.90 13.54 o 9 15 4 256.36 244.73 24.55 o 11 15 4 87.77 72.99 15.28 o 0 16 4 612.11 621.57 15.12 o 2 16 4 17.00 15.09 3.95 o 4 16 4 29.01 31.66 5.91 o 6 16 4 101.64 82.05 10.23 o 8 16 4 747.13 756.51 15.88 o 10 16 4 819.08 877.05 17.79 o 1 17 4 161.55 129.32 16.63 o 3 17 4 209.87 198.01 21.16 o 5 17 4 423.15 460.23 14.82 o 7 17 4 308.85 353.21 18.91 o 9 17 4 109.88 91.85 19.68 o 0 18 4 39.24 28.85 9.09 o 2 18 4 105.68 88.31 15.75 o 4 18 4 644.80 708.43 20.03 o 6 18 4 346.24 372.64 17.55 o 1 19 4 173.66 201.39 18.09 o 3 19 4 166.12 189.45 22.96 o 1 2 5 1991.31 1838.87 9.01 o 2 3 5 1765.02 1750.62 8.79 o 1 4 5 2310.04 2249.73 9.18 o 3 4 5 385.89 330.54 2.62 o 2 5 5 6893.15 6631.55 28.07 o 4 5 5 4444.50 4335.23 35.66 o 1 6 5 2127.94 1952.60 8.36 o 3 6 5 1472.81 1440.62 8.90 o 5 6 5 893.83 942.44 10.22 o 2 7 5 371.55 433.49 4.14 o 4 7 5 7001.23 6686.03 58.04 o 6 7 5 3214.59 3254.70 24.39 o 1 8 5 130.53 143.90 2.77 o 3 8 5 3954.15 4037.20 22.43 o 5 8 5 6.35 8.43 2.91 o 7 8 5 1419.90 1377.08 11.65 o 2 9 5 2852.43 2726.88 16.39 o 4 9 5 482.86 465.74 6.83 o 6 9 5 1555.89 1553.87 13.22 o 8 9 5 4884.72 4885.64 40.87 o 1 10 5 301.90 288.14 4.30 o 3 10 5 369.55 341.88 7.26 o 5 10 5 3629.22 3741.10 29.60 o 7 10 5 1195.04 1268.54 14.27 o 9 10 5 1259.34 1147.20 16.12 o 2 11 5 554.63 574.65 6.59 o 4 11 5 1812.28 1751.26 16.91 o 6 11 5 638.88 664.63 12.20 o 8 11 5 2190.66 2236.94 23.77 o 10 11 5 784.83 857.14 12.97 o 1 12 5 3628.41 3741.16 33.55 o 3 12 5 1771.62 1818.47 18.67 o 5 12 5 790.90 798.15 10.84 o 7 12 5 1114.15 1158.94 12.91 o 9 12 5 1411.60 1355.19 15.71 o 11 12 5 484.80 482.48 10.89 o 2 13 5 2119.08 2175.66 18.88 o 4 13 5 492.22 518.18 11.51 o 6 13 5 116.48 101.92 11.32 o 8 13 5 398.03 410.44 9.79 o 10 13 5 141.71 126.16 16.54 o 12 13 5 38.86 38.61 8.20 o 1 14 5 301.95 300.76 7.67 o 3 14 5 1222.24 1252.02 14.30 o 5 14 5 813.90 840.78 15.58 o 7 14 5 1343.79 1359.33 15.83 o 9 14 5 209.97 247.22 18.99 o 11 14 5 43.10 28.04 8.76 o 13 14 5 115.91 108.41 20.94 o 2 15 5 625.71 661.46 11.52 o 4 15 5 766.37 794.52 12.70 o 6 15 5 627.77 666.01 14.01 o 8 15 5 2234.54 2507.81 23.58 o 10 15 5 82.77 70.11 10.54 o 12 15 5 332.31 325.00 26.56 o 1 16 5 83.45 69.35 10.16 o 3 16 5 238.44 223.76 15.53 o 5 16 5 401.53 399.21 11.61 o 7 16 5 164.70 157.77 23.24 o 9 16 5 640.84 672.21 17.95 o 2 17 5 136.84 107.84 14.53 o 4 17 5 337.43 357.88 11.69 o 6 17 5 714.27 752.57 18.94 o 8 17 5 759.05 819.68 22.44 o 1 18 5 114.61 97.19 15.04 o 3 18 5 20.54 20.65 6.67 o 5 18 5 83.44 62.32 14.03 o 2 19 5 133.54 102.07 22.45 o 1 1 6 29212.65 29817.12 120.01 o 0 2 6 527.84 593.46 5.72 o 1 3 6 1520.51 1523.58 8.08 o 3 3 6 26901.12 27197.12 203.60 o 0 4 6 10589.19 11087.21 73.96 o 2 4 6 1020.45 1075.08 5.55 o 1 5 6 10879.61 10861.72 49.57 o 3 5 6 5428.46 5791.29 35.61 o 5 5 6 3129.75 3420.59 45.50 o 0 6 6 3264.20 3469.02 28.58 o 2 6 6 135.71 131.81 2.67 o 4 6 6 1649.99 1781.88 12.15 o 1 7 6 1903.59 2202.17 11.75 o 3 7 6 1058.12 1061.78 8.58 o 5 7 6 1682.60 1668.82 14.40 o 7 7 6 277.66 274.83 13.54 o 0 8 6 2165.70 2284.29 16.34 o 2 8 6 2271.04 2296.71 13.10 o 4 8 6 1502.11 1522.21 12.66 o 6 8 6 362.94 414.79 6.05 o 1 9 6 552.28 645.92 6.27 o 3 9 6 71.05 73.62 4.85 o 5 9 6 408.49 379.01 5.65 o 7 9 6 129.66 123.65 7.27 o 9 9 6 5245.95 5675.42 78.33 o 0 10 6 1443.96 1427.90 12.19 o 2 10 6 763.16 851.38 7.37 o 4 10 6 1260.62 1206.19 12.98 o 6 10 6 1087.79 1113.01 13.40 o 8 10 6 539.86 547.82 11.74 o 1 11 6 861.91 844.68 8.23 o 3 11 6 63.84 49.62 5.78 o 5 11 6 6919.51 7197.29 54.89 o 7 11 6 60.41 52.68 6.63 o 9 11 6 841.72 829.91 12.77 o 11 11 6 531.17 485.91 15.48 o 0 12 6 6009.36 6452.83 60.28 o 2 12 6 1986.51 2068.62 17.39 o 4 12 6 326.46 313.91 7.89 o 6 12 6 391.51 369.67 11.40 o 8 12 6 1105.32 1106.16 13.11 o 10 12 6 101.31 99.28 12.55 o 1 13 6 3561.40 3777.01 29.79 o 3 13 6 2991.76 3173.04 30.24 o 5 13 6 333.43 356.16 11.02 o 7 13 6 247.79 263.91 11.19 o 9 13 6 434.35 425.46 11.51 o 11 13 6 182.72 200.46 18.53 o 13 13 6 145.01 120.77 28.30 o 0 14 6 28.36 28.69 9.03 o 2 14 6 434.15 441.87 9.96 o 4 14 6 1482.16 1606.99 16.32 o 6 14 6 341.48 324.65 11.87 o 8 14 6 1356.35 1411.54 17.03 o 10 14 6 169.37 181.92 18.14 o 12 14 6 18.62 17.16 6.80 o 1 15 6 648.07 709.43 11.93 o 3 15 6 99.37 85.73 10.44 o 5 15 6 58.66 63.18 9.90 o 7 15 6 654.17 673.16 13.76 o 9 15 6 188.09 176.80 16.12 o 11 15 6 52.36 35.93 10.12 o 0 16 6 1043.37 1038.55 22.15 o 2 16 6 172.25 146.81 20.08 o 4 16 6 255.23 268.29 14.46 o 6 16 6 961.52 1002.15 19.94 o 8 16 6 344.91 348.23 21.79 o 10 16 6 104.55 91.33 16.07 o 1 17 6 130.49 114.14 19.11 o 3 17 6 22.55 21.87 6.89 o 5 17 6 81.31 70.00 12.47 o 7 17 6 273.92 269.77 21.10 o 0 18 6 260.84 271.30 18.56 o 2 18 6 270.64 287.22 15.11 o 4 18 6 86.57 82.75 16.25 o 6 18 6 361.73 418.58 27.24 o 1 2 7 11579.73 11386.48 56.10 o 2 3 7 11672.58 11205.13 44.34 o 1 4 7 4490.59 4365.81 28.68 o 3 4 7 3945.69 4291.75 28.80 o 2 5 7 269.19 334.68 3.80 o 4 5 7 247.32 201.54 3.06 o 1 6 7 2247.32 2430.28 12.85 o 3 6 7 249.31 305.93 5.44 o 5 6 7 3604.74 3636.86 24.37 o 2 7 7 743.23 890.53 6.73 o 4 7 7 3514.32 3710.59 25.04 o 6 7 7 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13.58 o 4 14 8 376.43 384.67 10.29 o 6 14 8 142.86 126.91 15.55 o 8 14 8 179.04 143.31 18.27 o 10 14 8 647.50 658.83 17.43 o 1 15 8 37.69 30.92 5.94 o 3 15 8 517.46 529.54 12.26 o 5 15 8 631.91 661.85 13.12 o 7 15 8 142.16 113.41 17.02 o 9 15 8 507.66 577.62 16.90 o 0 16 8 700.08 722.69 17.45 o 2 16 8 110.99 89.86 12.46 o 4 16 8 185.87 155.17 25.63 o 6 16 8 441.60 461.28 13.42 o 8 16 8 30.44 18.10 6.39 o 1 17 8 136.90 110.40 17.15 o 3 17 8 304.35 279.53 23.01 o 5 17 8 67.35 54.97 8.70 o 7 17 8 23.64 19.14 6.41 o 0 18 8 11.45 14.95 6.89 o 2 18 8 108.56 93.73 16.52 o 1 2 9 4316.18 4467.56 39.23 o 2 3 9 234.09 243.55 4.50 o 1 4 9 943.99 928.23 7.11 o 3 4 9 1700.97 1724.40 13.98 o 2 5 9 1778.16 1661.75 9.95 o 4 5 9 2625.93 2664.65 17.36 o 1 6 9 958.69 930.86 7.61 o 3 6 9 71.90 75.20 4.94 o 5 6 9 513.53 486.66 5.78 o 2 7 9 77.76 95.74 3.09 o 4 7 9 568.96 627.10 6.60 o 6 7 9 1743.16 1657.16 13.81 o 1 8 9 3305.83 3254.23 20.42 o 3 8 9 2935.72 2785.86 16.81 o 5 8 9 2629.93 2726.61 21.34 o 7 8 9 5589.15 5807.82 48.88 o 2 9 9 5514.68 5665.88 45.17 o 4 9 9 734.69 646.70 7.44 o 6 9 9 133.11 138.03 7.55 o 8 9 9 474.58 445.03 13.26 o 1 10 9 2725.56 2756.19 25.05 o 3 10 9 3634.34 3712.30 29.75 o 5 10 9 439.78 472.76 10.86 o 7 10 9 1247.97 1220.86 18.24 o 9 10 9 3.15 7.00 4.85 o 2 11 9 2909.93 3013.60 26.06 o 4 11 9 436.47 418.33 9.24 o 6 11 9 3420.22 3559.37 28.81 o 8 11 9 244.19 245.38 16.38 o 10 11 9 54.82 52.31 8.08 o 1 12 9 776.49 788.44 11.62 o 3 12 9 865.28 850.04 13.00 o 5 12 9 1915.82 1930.90 27.54 o 7 12 9 205.06 180.78 20.85 o 9 12 9 514.17 562.38 11.32 o 11 12 9 33.78 26.13 6.62 o 2 13 9 66.14 78.78 10.17 o 4 13 9 566.88 568.86 11.11 o 6 13 9 1182.71 1182.82 15.55 o 8 13 9 1159.68 1186.66 17.41 o 10 13 9 174.68 142.18 17.02 o 12 13 9 173.59 134.66 25.39 o 1 14 9 73.04 61.42 9.67 o 3 14 9 126.87 111.97 14.78 o 5 14 9 15.21 21.24 5.01 o 7 14 9 41.24 34.51 6.64 o 9 14 9 488.20 511.71 13.79 o 11 14 9 304.97 329.97 19.88 o 2 15 9 164.99 155.80 21.84 o 4 15 9 1457.35 1578.96 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11.67 o 7 9 10 350.94 327.64 12.27 o 9 9 10 296.36 275.65 20.18 o 0 10 10 4035.16 4044.36 44.67 o 2 10 10 777.53 760.90 10.95 o 4 10 10 1171.54 1145.22 16.08 o 6 10 10 720.89 693.75 12.03 o 8 10 10 425.64 462.95 12.72 o 1 11 10 1861.68 1816.01 19.26 o 3 11 10 491.33 454.76 9.75 o 5 11 10 2252.02 2361.14 22.30 o 7 11 10 361.33 343.38 13.08 o 9 11 10 210.59 221.95 20.81 o 11 11 10 27.17 16.18 8.00 o 0 12 10 155.43 153.79 11.15 o 2 12 10 364.44 358.99 10.47 o 4 12 10 393.12 367.43 9.57 o 6 12 10 526.15 553.47 13.25 o 8 12 10 47.21 48.87 7.50 o 10 12 10 558.42 625.77 14.41 o 1 13 10 85.83 97.22 13.32 o 3 13 10 47.62 46.40 7.24 o 5 13 10 1684.56 1759.28 20.84 o 7 13 10 87.26 82.08 12.81 o 9 13 10 724.63 785.76 19.03 o 11 13 10 148.98 114.63 19.48 o 0 14 10 92.47 80.49 14.94 o 2 14 10 15.17 17.80 5.03 o 4 14 10 714.19 766.61 14.67 o 6 14 10 1323.15 1403.31 20.10 o 8 14 10 255.62 245.97 18.93 o 10 14 10 1176.80 1335.67 20.92 o 1 15 10 213.93 205.27 17.66 o 3 15 10 492.18 534.59 14.36 o 5 15 10 62.56 71.81 13.79 o 7 15 10 4.60 7.32 7.66 o 9 15 10 326.63 391.10 20.98 o 0 16 10 90.55 85.06 21.35 o 2 16 10 145.15 129.01 22.97 o 4 16 10 254.50 201.31 32.52 o 6 16 10 294.65 341.49 16.27 o 1 17 10 395.47 462.71 15.59 o 3 17 10 86.04 76.12 15.93 o 1 2 11 407.36 451.61 7.23 o 2 3 11 879.93 979.50 11.26 o 1 4 11 1452.65 1456.33 12.43 o 3 4 11 113.74 112.81 4.35 o 2 5 11 767.08 776.26 8.42 o 4 5 11 2210.65 2125.16 12.55 o 1 6 11 577.23 503.76 6.84 o 3 6 11 57.60 52.68 4.59 o 5 6 11 873.48 812.71 7.74 o 2 7 11 2.56 8.79 2.11 o 4 7 11 437.02 401.02 6.08 o 6 7 11 1190.88 1147.16 15.81 o 1 8 11 530.21 466.82 7.42 o 3 8 11 572.42 502.45 8.95 o 5 8 11 24.96 21.51 4.29 o 7 8 11 885.88 864.48 14.70 o 2 9 11 610.00 610.51 10.63 o 4 9 11 2773.54 2608.49 25.33 o 6 9 11 610.23 625.04 14.53 o 8 9 11 51.10 34.10 6.87 o 1 10 11 243.96 283.41 8.73 o 3 10 11 255.35 215.63 9.65 o 5 10 11 140.24 164.38 20.21 o 7 10 11 815.34 798.33 17.74 o 9 10 11 327.51 325.80 11.49 o 2 11 11 46.16 58.92 7.67 o 4 11 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4 4 12 526.05 461.98 9.42 o 1 5 12 58.28 58.94 6.08 o 3 5 12 378.13 336.09 5.94 o 0 6 12 4373.25 4434.70 48.63 o 2 6 12 560.91 490.22 7.14 o 4 6 12 744.59 657.40 9.76 o 6 6 12 3516.09 3275.12 33.05 o 1 7 12 144.55 155.97 6.35 o 3 7 12 728.99 651.35 8.01 o 5 7 12 35.51 26.64 4.82 o 0 8 12 1656.91 1558.10 21.50 o 2 8 12 106.77 89.16 6.82 o 4 8 12 788.39 712.58 10.41 o 6 8 12 4.18 8.73 5.25 o 8 8 12 5843.01 5917.94 59.63 o 1 9 12 331.58 281.77 8.81 o 3 9 12 887.59 885.81 11.86 o 5 9 12 359.96 331.05 11.01 o 7 9 12 256.32 249.26 25.00 o 0 10 12 2178.60 1887.52 27.73 o 2 10 12 123.04 119.99 10.32 o 4 10 12 1502.88 1463.02 17.07 o 6 10 12 873.24 833.26 14.17 o 8 10 12 41.80 34.95 7.40 o 10 10 12 169.66 158.63 32.21 o 1 11 12 1671.72 1647.44 17.32 o 3 11 12 49.72 31.78 6.65 o 5 11 12 152.42 125.75 15.24 o 7 11 12 26.25 22.08 6.27 o 9 11 12 34.05 36.26 7.44 o 0 12 12 986.25 1037.67 18.65 o 2 12 12 230.40 206.38 11.91 o 4 12 12 290.22 237.39 17.48 o 6 12 12 564.37 536.95 13.54 o 8 12 12 267.30 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732.31 15.32 o 2 9 13 481.46 503.22 8.77 o 4 9 13 565.16 532.09 11.07 o 6 9 13 465.41 399.50 12.12 o 8 9 13 47.87 62.28 9.89 o 1 10 13 750.42 713.39 10.77 o 3 10 13 975.98 909.82 12.72 o 5 10 13 144.11 141.95 17.62 o 7 10 13 868.37 930.63 15.25 o 9 10 13 131.30 115.42 17.17 o 2 11 13 339.91 307.15 12.36 o 4 11 13 626.36 633.85 13.12 o 6 11 13 363.36 366.83 17.70 o 8 11 13 554.47 560.26 12.50 o 10 11 13 148.96 126.72 19.69 o 1 12 13 1521.21 1534.22 19.82 o 3 12 13 388.09 405.92 14.54 o 5 12 13 1132.55 1078.02 18.16 o 7 12 13 979.77 936.92 15.37 o 9 12 13 18.98 27.13 5.70 o 2 13 13 194.88 163.44 24.63 o 4 13 13 110.98 97.28 12.85 o 6 13 13 1041.54 1055.59 18.62 o 8 13 13 13.25 16.29 6.91 o 1 14 13 206.23 200.50 32.03 o 3 14 13 168.70 177.39 23.95 o 5 14 13 271.37 272.88 20.46 o 7 14 13 41.96 37.39 8.14 o 2 15 13 638.70 656.90 16.17 o 4 15 13 599.00 643.32 19.69 o 1 16 13 3.25 9.29 5.11 o 1 1 14 8676.67 8485.86 119.60 o 0 2 14 7815.94 8027.86 71.42 o 1 3 14 569.23 566.84 8.71 o 3 3 14 5677.75 5854.99 51.65 o 0 4 14 9983.30 10095.61 84.51 o 2 4 14 4209.55 4316.65 33.93 o 1 5 14 2395.80 2464.83 22.30 o 3 5 14 1544.67 1474.13 14.15 o 5 5 14 4263.65 4491.44 31.66 o 0 6 14 6584.89 6753.95 73.60 o 2 6 14 887.66 879.24 11.42 o 4 6 14 1055.10 1054.54 14.39 o 1 7 14 3384.21 3615.36 27.29 o 3 7 14 72.67 64.93 7.31 o 5 7 14 1577.67 1571.71 14.02 o 7 7 14 2207.36 2229.38 38.90 o 0 8 14 4267.04 4268.34 58.24 o 2 8 14 1087.30 1080.49 12.11 o 4 8 14 163.76 165.77 18.37 o 6 8 14 512.88 469.63 11.33 o 1 9 14 927.60 1034.39 15.15 o 3 9 14 510.26 479.75 11.12 o 5 9 14 675.66 731.20 15.16 o 7 9 14 405.40 430.04 11.56 o 9 9 14 88.17 64.75 16.53 o 0 10 14 5949.35 6082.45 72.37 o 2 10 14 682.15 678.60 13.39 o 4 10 14 44.47 47.60 9.27 o 6 10 14 1448.55 1468.71 17.62 o 8 10 14 152.27 122.69 18.93 o 1 11 14 958.43 1089.35 16.74 o 3 11 14 614.38 598.84 13.90 o 5 11 14 628.16 629.26 16.71 o 7 11 14 1272.02 1332.23 17.34 o 9 11 14 143.76 119.05 16.64 o 0 12 14 470.94 502.75 20.67 o 2 12 14 370.87 373.07 19.51 o 4 12 14 249.55 220.59 21.91 o 6 12 14 423.22 508.25 25.23 o 8 12 14 170.77 157.17 26.93 o 1 13 14 811.10 817.10 16.57 o 3 13 14 848.73 879.59 19.42 o 5 13 14 104.50 81.75 11.94 o 7 13 14 436.78 439.65 18.35 o 0 14 14 557.76 567.41 32.83 o 2 14 14 867.74 930.50 19.54 o 4 14 14 47.77 37.27 8.67 o 6 14 14 265.55 249.05 21.22 o 1 15 14 351.46 348.15 17.11 o 3 15 14 291.15 274.78 28.89 o 1 2 15 1564.11 1602.56 14.87 o 2 3 15 4663.12 4661.94 31.39 o 1 4 15 3198.64 3177.41 23.21 o 3 4 15 9.66 19.49 4.19 o 2 5 15 2155.29 1923.11 20.31 o 4 5 15 3296.86 3264.69 20.97 o 1 6 15 163.09 174.10 8.78 o 3 6 15 1497.24 1297.62 12.64 o 5 6 15 388.86 375.01 11.19 o 2 7 15 56.70 41.44 5.94 o 4 7 15 42.02 36.61 5.85 o 6 7 15 686.79 684.91 12.02 o 1 8 15 72.08 77.87 9.23 o 3 8 15 328.09 315.54 9.32 o 5 8 15 1128.95 1106.69 17.15 o 7 8 15 369.75 349.96 12.39 o 2 9 15 2437.85 2413.48 23.55 o 4 9 15 202.37 204.81 17.59 o 6 9 15 278.55 276.63 19.14 o 8 9 15 137.00 108.87 16.20 o 1 10 15 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296.58 13.93 o 4 8 18 386.83 418.93 11.92 o 6 8 18 277.55 279.71 13.76 o 1 9 18 162.41 145.86 19.97 o 3 9 18 119.53 102.26 15.34 o 5 9 18 104.31 102.85 15.26 o 7 9 18 14.24 9.97 6.03 o 0 10 18 28.40 20.31 12.59 o 2 10 18 450.14 450.06 15.81 o 4 10 18 35.90 44.37 8.64 o 6 10 18 146.13 134.67 21.86 o 1 11 18 13.22 19.88 5.67 o 3 11 18 392.46 467.10 18.10 o 1 2 19 337.70 327.97 8.45 o 2 3 19 350.28 328.12 12.85 o 1 4 19 147.86 144.72 10.85 o 3 4 19 28.21 23.58 5.08 o 2 5 19 130.16 110.91 13.84 o 4 5 19 109.86 102.74 12.36 o 1 6 19 497.17 550.75 12.05 o 3 6 19 615.99 645.01 12.69 o 5 6 19 76.66 82.64 12.98 o 2 7 19 627.73 669.11 14.87 o 4 7 19 26.03 27.37 7.21 o 6 7 19 185.94 166.94 16.53 o 1 8 19 147.70 131.58 21.13 o 3 8 19 74.48 68.10 10.46 o 5 8 19 144.26 109.86 17.58 o 2 9 19 660.50 729.40 16.30 o 4 9 19 122.87 112.22 18.89 o 1 10 19 177.07 161.23 34.29 o 3 10 19 15.55 20.29 6.40 o 0 0 20 5655.13 6702.27 73.83 o 0 2 20 122.88 124.72 16.02 o 2 2 20 479.05 515.88 12.71 o 1 3 20 636.86 685.89 9.79 o 0 4 20 32.16 46.53 9.66 o 2 4 20 904.62 978.99 12.72 o 4 4 20 313.59 290.56 21.02 o 1 5 20 365.54 388.21 11.24 o 3 5 20 47.48 34.22 5.43 o 0 6 20 297.58 268.98 16.85 o 2 6 20 278.98 308.63 15.47 o 4 6 20 46.38 49.48 9.86 o 6 6 20 1032.26 1175.09 23.31 o 1 7 20 428.95 455.79 13.15 o 3 7 20 341.62 357.87 13.82 o 5 7 20 255.61 279.58 22.08 o 0 8 20 123.73 150.29 36.34 o 2 8 20 348.96 367.91 16.92 o 4 8 20 156.42 162.89 19.74 o 1 9 20 171.25 157.01 38.23 o 1 2 21 26.86 21.35 4.12 o 2 3 21 538.98 617.69 10.42 o 1 4 21 5.57 13.79 4.78 o 3 4 21 6.12 12.48 4.32 o 2 5 21 224.31 220.35 18.65 o 4 5 21 93.34 83.50 14.15 o 1 6 21 169.82 152.50 22.37 o 3 6 21 3.04 8.95 4.90 o 1 1 22 1550.21 1970.17 23.85 o 0 2 22 677.49 747.61 18.03 o 1 3 22 38.02 38.40 7.92 o 3 3 22 1054.30 1105.50 21.64 o 0 4 22 1979.25 2182.76 39.29 o