#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/45/2224536.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2224536_Fobs loop_ _publ_author_name 'Brown, III, Carlton J.' 'Knaust, Jacqueline M.' _publ_section_title ; 2,5-Dimethylpyrazine 1,4-dioxide ; _journal_coeditor_code ZL2251 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3052 _journal_volume 65 _journal_year 2009 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 102.205 _cell_angle_gamma 90.000 _cell_length_a 3.9971 _cell_length_b 8.9176 _cell_length_c 8.9249 _exptl_crystal_F_000 148.00 _reflns_d_resolution_high 0.6801 _[local]_cod_data_source_file zl2251Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 08mz155_0m in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 92.24 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 99.10 94.88 2.86 o 2 0 0 4.74 8.91 2.29 o 3 0 0 289.77 302.13 5.38 o 4 0 0 53.30 52.58 1.77 o 5 0 0 20.42 18.97 1.25 o 1 1 0 310.17 341.04 10.86 o 2 1 0 137.13 156.17 2.37 o 3 1 0 50.63 58.05 1.16 o 4 1 0 30.65 31.36 1.21 o 5 1 0 4.51 4.11 0.50 o 0 2 0 36.46 36.72 0.97 o 1 2 0 158.37 153.18 1.84 o 2 2 0 121.01 141.05 1.94 o 3 2 0 0.47 0.72 0.24 o 4 2 0 64.09 66.25 1.43 o 5 2 0 2.61 3.08 0.54 o 1 3 0 0.57 0.17 0.12 o 2 3 0 52.86 57.93 1.00 o 3 3 0 16.62 16.35 0.61 o 4 3 0 51.78 49.83 1.22 o 5 3 0 39.50 37.13 1.64 o 0 4 0 1714.17 1761.44 26.32 o 1 4 0 16.39 12.56 0.49 o 2 4 0 184.99 186.57 2.42 o 3 4 0 85.21 75.21 1.64 o 4 4 0 17.93 14.49 0.81 o 5 4 0 7.37 5.89 0.67 o 1 5 0 2.12 2.01 0.27 o 2 5 0 108.23 99.89 2.37 o 3 5 0 151.61 136.04 4.25 o 4 5 0 1.89 1.41 0.75 o 5 5 0 3.35 2.66 0.55 o 0 6 0 13.19 15.25 0.59 o 1 6 0 134.46 123.79 2.07 o 2 6 0 62.58 58.04 1.37 o 3 6 0 28.53 25.49 0.98 o 4 6 0 60.51 55.04 1.59 o 1 7 0 199.24 187.28 2.95 o 2 7 0 82.74 76.17 1.66 o 3 7 0 0.29 -0.27 0.27 o 4 7 0 4.31 2.89 0.52 o 0 8 0 28.41 20.08 1.41 o 1 8 0 67.95 56.98 1.74 o 2 8 0 169.46 169.84 3.61 o 3 8 0 0.00 -0.27 0.27 o 4 8 0 5.78 6.21 0.69 o 1 9 0 1.73 1.32 0.44 o 2 9 0 1.99 2.06 0.53 o 3 9 0 0.77 0.75 0.44 o 4 9 0 0.06 -0.09 0.79 o 0 10 0 0.73 0.09 0.53 o 1 10 0 17.48 18.94 1.18 o 2 10 0 1.00 0.31 0.37 o 3 10 0 70.55 81.64 2.62 o 1 11 0 15.97 16.76 1.54 o 2 11 0 1.71 0.13 0.40 o 0 12 0 5.38 8.89 1.41 o 1 12 0 27.61 30.81 2.29 o -5 1 1 5.45 6.16 0.59 o -4 1 1 25.28 23.55 0.82 o -3 1 1 77.51 78.24 1.38 o -2 1 1 44.42 42.11 0.80 o -1 1 1 575.91 599.92 11.31 o 0 1 1 1295.07 1416.99 39.89 o 1 1 1 311.81 374.34 4.79 o 2 1 1 95.63 120.42 1.70 o 3 1 1 27.48 26.42 0.83 o 4 1 1 64.19 65.38 1.42 o 5 1 1 1.45 1.39 0.34 o -5 2 1 189.47 184.39 3.45 o -4 2 1 0.22 0.00 0.25 o -3 2 1 32.06 33.78 0.89 o -2 2 1 374.16 361.55 4.20 o -1 2 1 391.00 389.78 4.30 o 0 2 1 459.86 497.08 8.83 o 1 2 1 918.42 1101.38 16.24 o 2 2 1 96.86 108.57 2.61 o 3 2 1 21.79 22.32 0.70 o 4 2 1 311.22 300.38 4.06 o 5 2 1 4.32 3.33 0.51 o -5 3 1 1.13 0.67 0.34 o -4 3 1 4.82 4.45 0.43 o -3 3 1 34.52 36.45 0.87 o -2 3 1 82.22 85.67 1.29 o -1 3 1 10.21 8.20 0.26 o 0 3 1 43.81 41.39 0.76 o 1 3 1 17.00 20.34 0.48 o 2 3 1 128.33 149.82 2.30 o 3 3 1 8.02 6.74 0.48 o 4 3 1 8.12 6.23 0.50 o 5 3 1 0.43 0.59 0.33 o -5 4 1 4.34 3.52 0.50 o -4 4 1 21.35 20.72 0.91 o -3 4 1 21.14 19.52 0.78 o -2 4 1 0.20 0.15 0.14 o -1 4 1 319.79 310.94 4.17 o 0 4 1 150.20 140.26 1.74 o 1 4 1 19.79 19.71 0.61 o 2 4 1 1.51 2.08 0.28 o 3 4 1 13.18 11.71 0.54 o 4 4 1 14.03 11.36 0.85 o 5 4 1 16.83 16.39 0.96 o -5 5 1 0.04 0.03 0.40 o -4 5 1 11.70 11.69 1.14 o -3 5 1 123.21 113.43 2.19 o -2 5 1 2.23 2.60 0.34 o -1 5 1 116.31 125.26 2.02 o 0 5 1 418.83 426.50 4.80 o 1 5 1 10.80 10.46 0.49 o 2 5 1 72.74 64.74 1.39 o 3 5 1 36.74 35.60 1.12 o 4 5 1 1.01 1.25 0.42 o 5 5 1 1.33 1.97 0.57 o -5 6 1 1.26 -0.70 0.70 o -4 6 1 0.05 -0.11 0.38 o -3 6 1 168.95 161.61 3.58 o -2 6 1 47.50 45.42 1.58 o -1 6 1 55.02 47.29 1.08 o 0 6 1 22.18 17.79 0.44 o 1 6 1 130.99 125.79 2.12 o 2 6 1 311.88 290.79 5.21 o 3 6 1 4.51 3.00 0.56 o 4 6 1 11.44 8.59 0.70 o -4 7 1 5.49 5.69 0.62 o -3 7 1 33.95 31.67 1.12 o -2 7 1 61.31 63.02 1.49 o -1 7 1 3.63 3.43 0.36 o 0 7 1 1.41 2.04 0.37 o 1 7 1 104.88 98.36 1.83 o 2 7 1 126.07 117.29 2.22 o 3 7 1 4.42 4.57 0.51 o 4 7 1 18.83 18.04 1.20 o -4 8 1 4.24 4.89 0.65 o -3 8 1 1.81 1.94 0.40 o -2 8 1 125.49 124.11 2.39 o -1 8 1 0.25 -0.31 0.40 o 0 8 1 0.15 0.10 0.31 o 1 8 1 124.38 114.61 2.71 o 2 8 1 0.13 0.12 0.27 o 3 8 1 3.79 3.20 0.46 o 4 8 1 0.69 0.61 0.35 o -4 9 1 18.48 22.53 2.35 o -3 9 1 5.71 6.21 0.63 o -2 9 1 8.11 7.96 0.84 o -1 9 1 17.62 14.05 1.00 o 0 9 1 3.73 1.14 0.37 o 1 9 1 0.45 0.22 0.37 o 2 9 1 0.00 0.51 0.40 o 3 9 1 46.41 52.33 1.93 o 4 9 1 4.67 2.91 1.23 o -3 10 1 37.68 44.15 1.87 o -2 10 1 0.29 -0.09 0.40 o -1 10 1 26.84 23.48 1.25 o 0 10 1 17.08 14.80 1.03 o 1 10 1 0.11 0.26 0.37 o 2 10 1 60.90 68.94 2.24 o 3 10 1 3.80 3.94 0.70 o -2 11 1 0.20 0.58 0.53 o -1 11 1 7.17 9.55 1.72 o 0 11 1 21.86 22.36 1.28 o 1 11 1 9.72 10.42 1.00 o 2 11 1 7.63 7.37 1.01 o -1 12 1 20.07 25.60 1.94 o 0 12 1 1.23 0.83 0.88 o 1 12 1 123.67 134.56 3.52 o -5 0 2 13.62 13.69 1.06 o -4 0 2 144.45 149.56 3.33 o -3 0 2 15.49 14.55 0.78 o -2 0 2 3.88 3.30 0.37 o -1 0 2 8508.21 8604.47 190.32 o 0 0 2 582.35 645.02 14.44 o 1 0 2 66.26 116.34 2.82 o 2 0 2 373.26 481.74 10.57 o 3 0 2 190.62 214.26 4.19 o 4 0 2 34.89 35.54 1.46 o 5 0 2 0.20 0.42 0.40 o -5 1 2 14.47 14.88 0.79 o -4 1 2 1.17 1.10 0.34 o -3 1 2 78.08 78.01 1.35 o -2 1 2 71.55 79.51 1.35 o -1 1 2 567.27 578.90 6.25 o 0 1 2 80.83 93.34 1.25 o 1 1 2 101.09 126.13 1.62 o 2 1 2 188.09 255.72 3.19 o 3 1 2 48.27 53.23 1.15 o 4 1 2 33.92 35.08 1.03 o 5 1 2 8.85 7.55 0.61 o -5 2 2 21.21 23.07 1.51 o -4 2 2 2.22 2.16 0.36 o -3 2 2 17.85 18.70 0.63 o -2 2 2 24.36 24.04 0.57 o -1 2 2 82.87 76.43 1.04 o 0 2 2 268.36 288.17 4.02 o 1 2 2 404.30 517.73 6.72 o 2 2 2 30.00 41.54 0.87 o 3 2 2 107.39 120.02 1.93 o 4 2 2 14.23 16.31 0.73 o 5 2 2 0.36 0.22 0.28 o -5 3 2 57.17 55.26 1.62 o -4 3 2 14.40 13.58 0.65 o -3 3 2 9.68 10.91 0.60 o -2 3 2 11.44 12.33 0.44 o -1 3 2 98.30 92.93 1.26 o 0 3 2 62.05 53.59 0.81 o 1 3 2 150.30 170.10 2.20 o 2 3 2 4.90 8.06 0.39 o 3 3 2 12.47 10.36 0.54 o 4 3 2 80.93 72.02 1.52 o 5 3 2 4.75 5.52 0.61 o -5 4 2 1.62 2.13 0.42 o -4 4 2 49.80 46.84 1.37 o -3 4 2 51.45 51.69 1.30 o -2 4 2 2.76 2.17 0.22 o -1 4 2 876.37 896.28 11.30 o 0 4 2 11.28 8.49 0.37 o 1 4 2 248.89 262.87 3.17 o 2 4 2 100.69 94.75 1.51 o 3 4 2 59.16 54.42 1.68 o 4 4 2 7.92 7.06 0.60 o 5 4 2 13.18 9.66 1.05 o -5 5 2 0.03 0.00 0.44 o -4 5 2 57.43 51.33 1.84 o -3 5 2 119.19 109.55 2.64 o -2 5 2 0.83 0.73 0.25 o -1 5 2 31.43 31.40 0.96 o 0 5 2 22.67 23.52 0.55 o 1 5 2 38.45 34.49 0.72 o 2 5 2 238.15 214.17 3.31 o 3 5 2 6.98 4.65 0.50 o 4 5 2 0.17 0.79 0.57 o -5 6 2 22.68 24.52 1.28 o -4 6 2 2.53 2.25 0.45 o -3 6 2 10.59 9.53 0.66 o -2 6 2 31.16 28.62 0.93 o -1 6 2 29.81 33.11 0.90 o 0 6 2 207.29 184.99 2.44 o 1 6 2 180.47 165.62 2.75 o 2 6 2 107.51 99.83 1.95 o 3 6 2 82.66 71.31 1.71 o 4 6 2 22.80 21.09 1.01 o -4 7 2 0.07 0.11 0.32 o -3 7 2 20.33 18.24 0.86 o -2 7 2 231.69 217.22 3.47 o -1 7 2 1.52 0.86 0.26 o 0 7 2 43.89 41.85 2.51 o 1 7 2 165.01 152.81 2.54 o 2 7 2 1.67 2.35 0.39 o 3 7 2 3.11 3.94 0.59 o 4 7 2 0.00 0.32 0.31 o -4 8 2 0.01 -0.32 0.32 o -3 8 2 133.59 135.09 3.34 o -2 8 2 7.69 5.93 0.71 o -1 8 2 18.40 14.42 1.28 o 0 8 2 124.85 105.32 2.46 o 1 8 2 117.94 116.60 2.74 o 2 8 2 1.04 1.37 0.34 o 3 8 2 8.88 8.33 0.68 o 4 8 2 0.44 0.85 0.48 o -4 9 2 6.99 7.55 1.26 o -3 9 2 12.67 13.97 0.90 o -2 9 2 0.62 0.35 0.37 o -1 9 2 3.94 3.60 0.59 o 0 9 2 9.19 7.19 0.75 o 1 9 2 0.04 0.00 0.29 o 2 9 2 2.43 2.69 0.53 o 3 9 2 5.79 4.78 0.74 o -3 10 2 0.17 1.25 0.55 o -2 10 2 8.42 9.04 0.93 o -1 10 2 0.12 -0.29 0.29 o 0 10 2 22.49 25.14 1.25 o 1 10 2 2.43 1.60 0.49 o 2 10 2 77.02 83.59 2.52 o 3 10 2 8.65 10.39 1.00 o -2 11 2 30.28 38.77 1.74 o -1 11 2 0.05 -0.04 0.37 o 0 11 2 2.50 4.05 0.69 o 1 11 2 8.88 8.40 0.90 o 2 11 2 6.69 8.90 0.96 o -2 12 2 18.80 21.49 2.03 o -1 12 2 4.34 5.27 2.07 o 0 12 2 24.89 25.26 1.46 o 1 12 2 3.80 4.33 1.76 o -5 1 3 9.02 8.67 0.64 o -4 1 3 39.85 38.65 1.03 o -3 1 3 0.39 0.39 0.19 o -2 1 3 89.11 95.42 1.38 o -1 1 3 1138.54 1135.30 14.59 o 0 1 3 549.78 578.20 7.28 o 1 1 3 56.11 74.62 1.11 o 2 1 3 7.80 7.07 0.38 o 3 1 3 230.37 267.25 3.56 o 4 1 3 1.26 1.04 0.44 o 5 1 3 4.74 5.33 0.49 o -5 2 3 9.16 8.94 1.42 o -4 2 3 11.80 11.43 0.59 o -3 2 3 80.37 72.38 1.30 o -2 2 3 211.68 202.15 2.53 o -1 2 3 164.65 151.06 2.08 o 0 2 3 366.06 410.90 4.53 o 1 2 3 77.67 90.30 1.44 o 2 2 3 57.14 70.34 1.69 o 3 2 3 319.06 342.23 4.36 o 4 2 3 4.64 3.84 0.44 o 5 2 3 11.69 10.59 0.79 o -5 3 3 0.09 0.01 0.34 o -4 3 3 6.54 7.36 0.61 o -3 3 3 89.98 85.54 1.47 o -2 3 3 0.07 -0.02 0.15 o -1 3 3 7.87 8.39 0.33 o 0 3 3 23.65 19.12 0.45 o 1 3 3 234.17 297.99 3.52 o 2 3 3 1.77 1.18 0.36 o 3 3 3 42.03 37.51 1.00 o 4 3 3 7.60 6.11 0.72 o 5 3 3 1.41 0.81 0.53 o -5 4 3 15.81 15.91 0.94 o -4 4 3 53.55 51.13 1.42 o -3 4 3 3.59 3.86 0.44 o -2 4 3 140.53 131.24 1.83 o -1 4 3 2.46 1.97 0.29 o 0 4 3 6.81 6.97 0.31 o 1 4 3 8.00 7.92 0.36 o 2 4 3 5.70 6.57 0.41 o 3 4 3 43.42 37.55 1.17 o 4 4 3 15.96 15.05 1.72 o 5 4 3 67.23 73.89 3.26 o -5 5 3 0.77 0.84 0.50 o -4 5 3 90.18 83.99 1.96 o -3 5 3 0.50 0.18 0.25 o -2 5 3 5.25 7.46 0.67 o -1 5 3 348.77 346.96 4.06 o 0 5 3 19.75 18.89 0.52 o 1 5 3 3.29 3.46 0.36 o 2 5 3 58.36 62.69 1.33 o 3 5 3 17.11 13.30 0.74 o 4 5 3 4.60 4.89 0.57 o -5 6 3 0.13 0.41 0.36 o -4 6 3 55.51 60.51 1.65 o -3 6 3 8.78 7.77 0.60 o -2 6 3 31.71 30.64 0.95 o -1 6 3 0.47 0.76 0.23 o 0 6 3 172.33 158.40 2.46 o 1 6 3 277.94 261.07 3.84 o 2 6 3 26.77 21.62 0.84 o 3 6 3 33.33 27.15 1.13 o 4 6 3 29.28 26.43 1.09 o -4 7 3 5.31 4.55 0.59 o -3 7 3 25.20 27.35 1.03 o -2 7 3 7.55 6.28 0.55 o -1 7 3 0.02 0.10 0.20 o 0 7 3 101.27 91.99 2.12 o 1 7 3 260.92 245.36 3.69 o 2 7 3 0.62 1.02 0.32 o 3 7 3 19.87 17.44 1.00 o 4 7 3 3.62 3.94 0.60 o -4 8 3 7.12 7.19 0.72 o -3 8 3 80.97 82.76 1.96 o -2 8 3 5.74 4.07 0.49 o -1 8 3 0.01 -0.26 0.31 o 0 8 3 84.94 74.90 1.99 o 1 8 3 4.89 5.81 0.65 o 2 8 3 1.02 0.69 0.41 o 3 8 3 1.09 0.51 0.34 o 4 8 3 48.37 51.91 2.07 o -4 9 3 8.49 9.38 1.13 o -3 9 3 14.36 15.08 0.91 o -2 9 3 25.12 25.68 2.60 o -1 9 3 1.15 -0.19 0.31 o 0 9 3 2.91 3.20 0.53 o 1 9 3 12.33 10.48 1.10 o 2 9 3 72.45 77.18 2.30 o 3 9 3 4.06 4.64 0.65 o -3 10 3 0.62 1.12 0.46 o -2 10 3 14.37 17.12 1.18 o -1 10 3 3.24 3.17 0.84 o 0 10 3 3.31 4.58 1.01 o 1 10 3 48.61 52.33 1.87 o 2 10 3 0.02 0.04 0.40 o 3 10 3 0.04 -0.18 0.40 o -2 11 3 0.09 0.44 0.44 o -1 11 3 18.24 18.40 1.21 o 0 11 3 33.17 39.25 1.72 o 1 11 3 28.40 30.33 1.46 o 2 11 3 3.29 3.30 0.62 o -2 12 3 38.94 49.14 2.82 o -1 12 3 3.62 2.33 0.59 o 0 12 3 66.83 78.44 2.86 o 1 12 3 0.14 -0.07 0.44 o -5 0 4 41.86 48.97 1.86 o -4 0 4 47.94 45.16 1.58 o -3 0 4 15.14 14.78 0.78 o -2 0 4 1357.84 1304.96 29.46 o -1 0 4 132.06 146.95 2.52 o 0 0 4 101.93 125.76 3.61 o 1 0 4 150.32 201.11 3.51 o 2 0 4 376.61 457.35 12.95 o 3 0 4 9.00 9.63 0.86 o 4 0 4 7.11 8.42 0.85 o 5 0 4 56.90 69.57 3.17 o -5 1 4 2.29 3.06 0.45 o -4 1 4 14.21 13.96 0.65 o -3 1 4 20.00 21.13 0.65 o -2 1 4 385.74 365.74 4.24 o -1 1 4 2.27 3.05 0.22 o 0 1 4 14.43 16.40 0.43 o 1 1 4 314.82 383.21 4.39 o 2 1 4 30.90 33.92 0.84 o 3 1 4 129.86 148.52 5.24 o 4 1 4 12.04 12.18 0.97 o 5 1 4 1.70 0.72 0.79 o -5 2 4 1.87 1.19 0.51 o -4 2 4 1.31 1.55 0.33 o -3 2 4 0.25 0.36 0.24 o -2 2 4 57.90 54.58 0.95 o -1 2 4 39.68 43.45 0.74 o 0 2 4 502.55 549.49 6.00 o 1 2 4 116.87 147.83 1.94 o 2 2 4 98.45 119.02 1.81 o 3 2 4 26.39 36.12 1.37 o 4 2 4 0.01 0.07 0.25 o 5 2 4 1.41 0.76 1.81 o -5 3 4 8.31 9.09 0.75 o -4 3 4 2.60 2.53 0.41 o -3 3 4 10.40 10.38 0.49 o -2 3 4 128.38 114.50 1.64 o -1 3 4 92.71 85.99 1.25 o 0 3 4 130.53 136.24 1.75 o 1 3 4 3.73 1.82 0.24 o 2 3 4 5.72 10.43 0.50 o 3 3 4 123.52 117.97 2.26 o 4 3 4 16.80 19.13 0.80 o -5 4 4 21.83 24.70 1.15 o -4 4 4 3.92 4.39 0.61 o -3 4 4 0.16 -0.07 0.28 o -2 4 4 207.97 193.46 2.51 o -1 4 4 6.30 6.16 0.32 o 0 4 4 132.64 127.15 1.73 o 1 4 4 44.41 41.42 1.26 o 2 4 4 82.23 71.52 1.47 o 3 4 4 0.80 1.84 0.33 o 4 4 4 18.15 18.09 0.87 o -5 5 4 16.79 16.19 0.98 o -4 5 4 68.43 66.46 1.71 o -3 5 4 0.24 -0.01 0.27 o -2 5 4 29.40 27.15 0.86 o -1 5 4 46.78 45.62 0.87 o 0 5 4 6.55 7.09 0.35 o 1 5 4 236.91 216.71 2.81 o 2 5 4 8.12 5.11 0.39 o 3 5 4 3.65 3.27 0.45 o 4 5 4 1.96 2.23 0.39 o -5 6 4 0.05 -0.06 0.37 o -4 6 4 0.30 0.39 0.30 o -3 6 4 0.08 0.12 0.25 o -2 6 4 32.75 34.93 1.03 o -1 6 4 79.56 76.44 1.51 o 0 6 4 296.35 275.85 3.40 o 1 6 4 202.45 193.04 2.62 o 2 6 4 57.62 50.28 1.41 o 3 6 4 28.43 26.27 1.01 o 4 6 4 10.22 8.40 1.13 o -4 7 4 0.59 0.29 0.33 o -3 7 4 148.75 149.43 2.81 o -2 7 4 1.08 0.69 0.28 o -1 7 4 0.63 0.74 0.27 o 0 7 4 122.55 117.59 4.18 o 1 7 4 19.72 19.57 0.82 o 2 7 4 30.67 31.60 1.06 o 3 7 4 1.09 1.13 0.33 o 4 7 4 18.52 18.77 1.37 o -4 8 4 63.16 74.82 2.01 o -3 8 4 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