#------------------------------------------------------------------------------ #$Date: 2010-02-13 12:42:52 +0200 (Sat, 13 Feb 2010) $ #$Revision: 986 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2224663.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2224663_Fobs loop_ _publ_author_name 'Zheng, Guangrong' 'Parkin, Sean' 'Dwoskin, Linda P.' 'Crooks, Peter A.' _publ_section_title ; (2S,6S)-1-Methyl-2,6-trans-distyrylpiperidinium chloride ; _journal_coeditor_code HG2599 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o78 _journal_volume 66 _journal_year 2010 _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 9.9360 _cell_length_b 12.3070 _cell_length_c 15.8300 _exptl_crystal_F_000 728.00 _reflns_d_resolution_high .8409 _[local]_cod_data_source_file hg2599Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' k01174 in P212121' _shelx_refln_list_code 4 _shelx_f_calc_maximum 157.57 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' 'x+1/2, -y+1/2, -z' '-x, y+1/2, -z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 24829.26 23966.44 561.85 o 4 0 0 944.61 1035.84 24.36 o 6 0 0 660.67 768.18 28.78 o 8 0 0 100.94 113.94 10.59 o 10 0 0 27.92 45.27 22.52 o 1 1 0 34.93 45.31 1.07 o 2 1 0 658.32 627.03 8.40 o 3 1 0 676.89 643.98 10.49 o 4 1 0 3.57 .25 1.91 o 5 1 0 53.15 61.82 4.00 o 6 1 0 .01 1.96 2.78 o 7 1 0 140.11 143.33 6.77 o 8 1 0 50.01 49.68 6.07 o 9 1 0 71.38 69.68 8.21 o 10 1 0 14.08 47.71 14.26 o 11 1 0 95.52 96.86 18.91 o 0 2 0 3545.33 3197.57 64.10 o 1 2 0 3756.81 3287.68 41.53 o 2 2 0 159.05 159.96 6.35 o 3 2 0 4399.13 4500.05 54.22 o 4 2 0 286.24 294.16 6.41 o 5 2 0 1697.08 1692.54 25.89 o 6 2 0 1038.59 1095.45 30.55 o 7 2 0 2788.55 2958.48 77.57 o 8 2 0 .98 9.03 43.52 o 9 2 0 679.98 738.50 48.23 o 10 2 0 128.34 118.87 15.48 o 11 2 0 99.82 143.33 28.53 o 1 3 0 1058.72 1056.05 12.01 o 2 3 0 133.37 128.09 2.58 o 3 3 0 32.25 37.31 2.52 o 4 3 0 106.94 106.46 2.84 o 5 3 0 436.60 462.76 8.47 o 6 3 0 400.62 407.16 10.03 o 7 3 0 50.49 47.13 3.19 o 8 3 0 1337.12 1327.68 45.93 o 9 3 0 335.12 325.07 22.19 o 10 3 0 7.82 44.46 15.93 o 11 3 0 23.63 43.79 20.08 o 0 4 0 4809.60 4787.82 81.93 o 1 4 0 127.57 129.74 2.75 o 2 4 0 1552.75 1552.47 17.17 o 3 4 0 376.75 372.17 19.53 o 4 4 0 759.34 709.68 9.48 o 5 4 0 23.04 21.90 2.50 o 6 4 0 173.14 163.49 6.43 o 7 4 0 961.06 975.64 38.40 o 8 4 0 53.12 48.36 5.79 o 9 4 0 664.09 677.91 67.71 o 10 4 0 25.44 43.10 14.14 o 11 4 0 3.01 15.95 14.58 o 1 5 0 1469.87 1593.66 17.01 o 2 5 0 339.74 349.43 6.15 o 3 5 0 7.13 13.20 2.92 o 4 5 0 12.04 17.56 3.42 o 5 5 0 313.53 299.25 9.14 o 6 5 0 1.85 3.18 4.75 o 7 5 0 1544.91 1480.96 55.07 o 8 5 0 94.22 95.21 14.39 o 9 5 0 230.69 252.04 28.23 o 10 5 0 54.63 50.57 22.84 o 11 5 0 128.26 120.79 27.33 o 0 6 0 4.55 7.91 3.08 o 1 6 0 2.62 2.03 1.95 o 2 6 0 860.97 894.12 11.31 o 3 6 0 65.53 51.80 3.32 o 4 6 0 566.74 551.37 13.28 o 5 6 0 476.40 468.83 14.95 o 6 6 0 167.50 186.93 12.79 o 7 6 0 1946.44 1945.17 78.39 o 8 6 0 391.01 356.10 26.17 o 9 6 0 143.65 143.13 23.21 o 10 6 0 25.74 40.12 14.84 o 1 7 0 301.42 306.85 5.76 o 2 7 0 497.33 522.64 13.60 o 3 7 0 14.86 11.60 5.27 o 4 7 0 60.65 64.30 5.57 o 5 7 0 474.05 499.53 26.26 o 6 7 0 2.23 9.44 8.42 o 7 7 0 143.74 126.09 13.79 o 8 7 0 28.61 32.26 9.08 o 9 7 0 107.56 82.69 23.16 o 10 7 0 5.18 66.65 30.01 o 0 8 0 1181.33 1150.56 36.28 o 1 8 0 420.89 432.32 12.22 o 2 8 0 547.47 549.58 15.22 o 3 8 0 4.33 9.33 3.91 o 4 8 0 1078.95 1099.94 37.01 o 5 8 0 171.23 190.35 11.71 o 6 8 0 112.25 124.20 11.06 o 7 8 0 2.51 12.63 8.56 o 8 8 0 82.10 89.30 21.53 o 9 8 0 41.42 49.72 19.74 o 1 9 0 43.87 37.23 12.69 o 2 9 0 788.00 796.92 29.81 o 3 9 0 84.04 78.33 6.20 o 4 9 0 135.42 143.07 8.16 o 5 9 0 2.00 7.16 5.47 o 6 9 0 .02 33.35 12.87 o 7 9 0 4.87 10.02 8.23 o 8 9 0 1.33 9.53 8.45 o 9 9 0 1.05 5.80 15.72 o 0 10 0 3.07 11.22 5.01 o 1 10 0 1618.57 1649.43 55.62 o 2 10 0 561.48 552.94 22.24 o 3 10 0 1159.76 1144.71 57.69 o 4 10 0 428.62 454.17 29.44 o 5 10 0 102.09 105.77 13.09 o 6 10 0 2.16 -2.51 7.68 o 7 10 0 108.12 124.66 25.08 o 8 10 0 3.71 22.06 8.85 o 1 11 0 207.46 174.37 12.67 o 2 11 0 50.69 59.26 10.33 o 3 11 0 101.26 94.20 14.75 o 4 11 0 8.40 8.80 6.71 o 5 11 0 4.70 41.51 35.94 o 6 11 0 10.31 6.93 16.78 o 7 11 0 116.65 127.33 19.98 o 0 12 0 32.19 35.86 12.14 o 1 12 0 4.58 6.28 7.92 o 2 12 0 21.88 37.24 14.55 o 3 12 0 394.04 408.21 42.79 o 4 12 0 403.54 390.85 50.22 o 5 12 0 558.58 539.80 74.33 o 6 12 0 341.95 380.65 59.74 o 1 13 0 2.98 6.18 9.78 o 2 13 0 5.72 13.85 9.92 o 3 13 0 27.02 23.60 10.68 o 4 13 0 86.21 79.65 18.51 o 5 13 0 17.88 41.71 19.20 o 0 14 0 124.39 136.66 53.45 o 1 14 0 151.16 185.07 45.56 o 2 14 0 213.74 181.49 46.01 o 3 14 0 123.88 113.14 37.17 o 1 0 1 1993.20 1967.30 21.34 o 2 0 1 60.53 67.32 2.34 o 3 0 1 147.14 150.08 4.30 o 4 0 1 57.24 64.82 2.95 o 5 0 1 3307.96 3594.57 53.03 o 6 0 1 204.76 205.18 11.37 o 7 0 1 184.62 194.41 18.58 o 8 0 1 33.72 33.37 6.64 o 9 0 1 181.79 185.24 13.44 o 10 0 1 21.27 32.99 12.69 o 11 0 1 400.74 342.48 52.58 o -11 1 1 83.33 107.12 27.50 o -10 1 1 88.31 81.89 13.08 o -9 1 1 198.02 178.27 12.06 o -8 1 1 8.16 16.25 12.99 o -7 1 1 26.14 35.77 4.49 o -6 1 1 38.05 32.59 3.30 o -5 1 1 953.12 1012.76 14.65 o -4 1 1 385.87 362.05 6.17 o -3 1 1 1870.18 1932.46 28.05 o -2 1 1 992.38 970.35 11.97 o -1 1 1 198.79 170.82 8.89 o 0 1 1 55.13 46.01 1.15 o 1 1 1 210.61 181.74 9.28 o 2 1 1 998.17 971.43 11.32 o 3 1 1 1874.59 1895.08 25.06 o 4 1 1 396.94 375.94 6.43 o 5 1 1 961.27 1014.53 14.98 o 6 1 1 42.61 35.06 5.57 o 7 1 1 29.82 33.12 4.98 o 8 1 1 8.61 16.05 3.68 o 9 1 1 205.24 206.28 18.94 o 10 1 1 92.36 97.93 24.94 o 11 1 1 84.25 77.19 17.56 o -11 2 1 89.35 72.77 14.88 o -10 2 1 67.31 73.10 23.13 o -9 2 1 43.26 70.93 22.16 o -8 2 1 520.81 496.22 19.32 o -7 2 1 101.23 93.30 8.22 o -6 2 1 694.79 701.26 20.12 o -5 2 1 342.50 389.51 6.96 o -4 2 1 874.13 892.63 11.14 o -3 2 1 297.40 319.12 6.48 o -2 2 1 4567.03 4697.97 52.78 o -1 2 1 15791.63 15374.73 204.47 o 0 2 1 1217.89 1087.37 14.65 o 1 2 1 15806.66 15361.00 212.32 o 2 2 1 4560.44 4686.37 52.11 o 3 2 1 292.34 308.49 5.57 o 4 2 1 860.33 879.70 11.92 o 5 2 1 336.28 353.93 7.74 o 6 2 1 686.66 688.27 19.32 o 7 2 1 101.14 101.47 11.33 o 8 2 1 518.79 508.37 35.84 o 9 2 1 42.59 48.72 9.76 o 10 2 1 65.08 82.28 14.41 o 11 2 1 87.49 100.50 26.96 o -11 3 1 56.64 106.49 27.21 o -10 3 1 52.03 56.55 14.42 o -9 3 1 41.92 37.51 12.85 o -8 3 1 538.03 526.38 67.61 o -7 3 1 83.16 88.14 9.84 o -6 3 1 1064.92 1093.17 29.06 o -5 3 1 432.04 436.55 6.98 o -4 3 1 73.64 69.39 3.61 o -3 3 1 283.58 294.65 5.27 o -2 3 1 2014.26 2026.08 26.02 o -1 3 1 176.57 179.87 5.08 o 0 3 1 5458.82 5464.22 66.91 o 1 3 1 192.91 200.10 6.84 o 2 3 1 2044.63 2073.98 25.52 o 3 3 1 280.32 291.38 8.79 o 4 3 1 68.70 64.62 2.76 o 5 3 1 431.80 425.47 13.38 o 6 3 1 1059.38 1083.74 26.54 o 7 3 1 88.69 84.98 4.06 o 8 3 1 538.62 530.41 22.75 o 9 3 1 38.66 51.15 12.52 o 10 3 1 53.13 81.93 21.37 o 11 3 1 53.67 81.14 22.83 o -11 4 1 57.40 92.11 22.58 o -10 4 1 45.81 64.60 26.54 o -9 4 1 140.71 140.23 22.41 o -8 4 1 342.19 317.34 30.61 o -7 4 1 102.15 97.61 11.28 o -6 4 1 43.50 44.13 5.62 o -5 4 1 619.68 584.13 14.33 o -4 4 1 68.97 72.25 4.84 o -3 4 1 599.37 579.14 8.54 o -2 4 1 9.89 14.27 1.73 o -1 4 1 2162.56 2214.46 25.39 o 0 4 1 187.37 193.44 4.00 o 1 4 1 2203.39 2282.41 26.05 o 2 4 1 10.56 7.33 1.46 o 3 4 1 612.38 610.72 8.18 o 4 4 1 68.98 71.12 3.32 o 5 4 1 606.91 596.81 14.16 o 6 4 1 40.87 31.94 2.75 o 7 4 1 92.13 93.90 12.44 o 8 4 1 349.38 353.38 19.48 o 9 4 1 140.96 155.93 16.50 o 10 4 1 47.23 79.62 33.15 o 11 4 1 57.38 103.83 77.89 o -11 5 1 24.41 26.97 11.79 o -10 5 1 226.74 262.41 42.42 o -9 5 1 1.97 14.75 14.00 o -8 5 1 93.83 98.80 27.43 o -7 5 1 860.99 862.51 34.17 o -6 5 1 53.65 47.66 7.03 o -5 5 1 30.91 30.59 11.82 o -4 5 1 492.75 520.55 11.87 o -3 5 1 1266.33 1330.49 18.23 o -2 5 1 1855.63 1977.84 24.51 o -1 5 1 927.69 965.60 11.72 o 0 5 1 1367.93 1385.43 14.43 o 1 5 1 932.83 982.25 10.86 o 2 5 1 1833.79 1915.16 24.90 o 3 5 1 1271.18 1351.93 16.40 o 4 5 1 506.27 517.50 9.61 o 5 5 1 32.12 26.70 3.91 o 6 5 1 56.27 54.42 4.22 o 7 5 1 844.07 837.67 31.65 o 8 5 1 87.67 110.59 14.90 o 9 5 1 1.52 -3.10 6.06 o 10 5 1 229.09 264.97 42.71 o 11 5 1 26.10 45.02 29.89 o -10 6 1 21.69 48.73 25.68 o -9 6 1 135.53 150.56 27.48 o -8 6 1 9.94 16.80 9.22 o -7 6 1 29.25 38.56 7.02 o -6 6 1 77.51 75.67 6.99 o -5 6 1 75.00 70.68 6.64 o -4 6 1 948.02 993.27 25.51 o -3 6 1 201.23 199.20 8.09 o -2 6 1 1840.80 1800.74 24.16 o -1 6 1 320.34 334.60 7.81 o 0 6 1 1382.59 1372.45 16.38 o 1 6 1 322.83 333.98 5.85 o 2 6 1 1858.23 1807.93 23.69 o 3 6 1 204.36 205.39 4.66 o 4 6 1 949.15 983.48 22.29 o 5 6 1 79.35 75.23 4.43 o 6 6 1 69.95 53.65 5.46 o 7 6 1 27.44 24.50 9.71 o 8 6 1 10.77 21.30 10.11 o 9 6 1 131.99 152.51 25.44 o 10 6 1 24.48 37.32 17.53 o -10 7 1 588.82 586.81 116.24 o -9 7 1 304.46 289.31 43.84 o -8 7 1 9.15 27.66 9.11 o -7 7 1 1327.60 1354.42 83.52 o -6 7 1 239.32 243.61 21.54 o -5 7 1 423.77 395.17 19.57 o -4 7 1 49.80 37.67 5.79 o -3 7 1 309.65 306.54 9.83 o -2 7 1 24.14 24.10 2.69 o -1 7 1 157.43 143.31 5.86 o 0 7 1 144.56 146.08 3.94 o 1 7 1 150.65 133.29 3.61 o 2 7 1 26.57 21.57 3.28 o 3 7 1 327.82 307.87 8.63 o 4 7 1 50.69 47.67 4.39 o 5 7 1 418.79 379.49 26.56 o 6 7 1 245.95 237.89 20.03 o 7 7 1 1335.63 1333.49 86.85 o 8 7 1 9.23 13.64 30.43 o 9 7 1 299.59 310.38 41.94 o 10 7 1 586.39 580.65 113.94 o -9 8 1 200.58 182.73 39.32 o -8 8 1 92.43 99.38 18.73 o -7 8 1 268.55 264.42 27.72 o -6 8 1 587.09 552.58 33.68 o -5 8 1 608.90 619.74 33.18 o -4 8 1 94.40 102.70 7.09 o -3 8 1 219.32 216.26 10.92 o -2 8 1 199.42 198.19 7.11 o -1 8 1 191.97 178.53 6.62 o 0 8 1 1.37 2.25 2.31 o 1 8 1 189.09 176.59 5.85 o 2 8 1 206.03 202.76 10.21 o 3 8 1 213.63 195.37 10.64 o 4 8 1 89.04 90.81 17.67 o 5 8 1 617.31 585.15 23.08 o 6 8 1 584.30 608.08 39.92 o 7 8 1 277.70 280.07 27.14 o 8 8 1 94.92 81.67 14.35 o 9 8 1 199.41 194.43 35.52 o -9 9 1 14.96 32.55 16.88 o -8 9 1 54.73 93.23 16.17 o -7 9 1 12.54 36.08 9.43 o -6 9 1 237.25 239.67 18.48 o -5 9 1 143.20 146.42 13.53 o -4 9 1 260.27 244.80 17.57 o -3 9 1 318.63 301.88 16.63 o -2 9 1 134.74 127.38 12.89 o -1 9 1 599.03 590.33 16.80 o 0 9 1 113.27 117.22 4.74 o 1 9 1 591.68 566.56 20.60 o 2 9 1 128.68 118.96 9.60 o 3 9 1 313.19 312.32 12.56 o 4 9 1 252.61 229.71 23.83 o 5 9 1 142.58 163.93 13.19 o 6 9 1 233.39 220.16 16.42 o 7 9 1 11.98 10.05 8.30 o 8 9 1 53.45 54.49 20.01 o 9 9 1 14.15 53.50 17.90 o -8 10 1 45.63 60.39 18.14 o -7 10 1 26.89 43.16 18.21 o -6 10 1 101.73 109.55 15.00 o -5 10 1 .64 21.87 9.37 o -4 10 1 153.15 138.07 17.37 o -3 10 1 319.28 310.30 20.86 o -2 10 1 1010.87 1032.51 39.44 o -1 10 1 334.34 320.82 14.89 o 0 10 1 4.77 5.44 4.89 o 1 10 1 336.30 298.69 13.24 o 2 10 1 1016.60 1037.03 40.43 o 3 10 1 317.40 302.60 20.00 o 4 10 1 153.17 148.77 11.26 o 5 10 1 .31 12.89 16.27 o 6 10 1 97.00 87.63 12.92 o 7 10 1 27.33 13.50 11.57 o 8 10 1 48.42 66.79 19.34 o -7 11 1 27.45 70.76 18.61 o -6 11 1 92.90 101.83 21.79 o -5 11 1 51.77 81.06 18.02 o -4 11 1 205.93 215.02 22.93 o -3 11 1 48.62 61.53 27.42 o -2 11 1 119.37 93.40 12.11 o -1 11 1 563.52 579.48 33.30 o 0 11 1 423.30 389.56 24.14 o 1 11 1 559.25 538.52 30.96 o 2 11 1 121.10 121.24 14.29 o 3 11 1 44.29 71.43 15.72 o 4 11 1 209.82 194.31 19.53 o 5 11 1 57.65 67.32 28.94 o 6 11 1 96.18 104.29 18.47 o 7 11 1 29.34 32.11 9.79 o -6 12 1 61.58 65.45 18.61 o -5 12 1 171.06 242.98 40.57 o -4 12 1 264.07 243.47 36.04 o -3 12 1 26.17 18.05 8.08 o -2 12 1 344.78 392.14 41.84 o -1 12 1 233.64 277.41 26.75 o 0 12 1 307.41 260.50 22.47 o 1 12 1 232.92 218.04 20.76 o 2 12 1 331.16 368.50 42.38 o 3 12 1 22.86 18.03 9.49 o 4 12 1 261.82 278.94 47.77 o 5 12 1 171.06 300.59 55.20 o 6 12 1 62.77 111.30 31.72 o -5 13 1 155.66 185.62 35.68 o -4 13 1 78.29 96.12 21.69 o -3 13 1 236.03 270.24 40.63 o -2 13 1 144.80 148.86 28.54 o -1 13 1 91.59 140.95 26.59 o 0 13 1 163.56 139.69 22.07 o 1 13 1 92.12 97.00 25.10 o 2 13 1 141.76 146.75 39.58 o 3 13 1 236.39 252.14 51.08 o 4 13 1 77.68 95.30 18.39 o 5 13 1 155.89 150.87 32.26 o -3 14 1 65.19 85.59 24.70 o -2 14 1 127.77 139.93 45.67 o -1 14 1 90.80 66.14 27.98 o 0 14 1 215.46 211.94 49.26 o 1 14 1 95.25 137.28 44.65 o 2 14 1 127.68 108.92 33.83 o 3 14 1 68.79 84.22 28.37 o 0 0 2 5050.37 4703.69 84.85 o 1 0 2 2119.97 2113.23 24.76 o 2 0 2 711.58 748.43 9.59 o 3 0 2 563.99 519.14 7.69 o 4 0 2 280.40 282.06 10.16 o 5 0 2 170.90 189.84 4.78 o 6 0 2 37.82 50.83 5.27 o 7 0 2 70.03 60.43 21.23 o 8 0 2 36.36 38.68 6.15 o 9 0 2 320.51 305.01 17.98 o 10 0 2 1.03 4.72 8.78 o 11 0 2 .48 16.71 15.28 o -11 1 2 39.52 68.62 17.01 o -10 1 2 32.02 35.50 14.12 o -9 1 2 50.62 66.17 17.38 o -8 1 2 55.90 66.14 9.28 o -7 1 2 89.24 81.88 8.20 o -6 1 2 390.47 355.66 13.73 o -5 1 2 560.93 572.64 10.46 o -4 1 2 925.42 960.07 15.71 o -3 1 2 2713.74 2650.31 33.43 o -2 1 2 53.69 60.10 1.67 o -1 1 2 1088.79 1039.55 19.82 o 0 1 2 1444.71 1570.41 17.69 o 1 1 2 1037.12 999.84 11.69 o 2 1 2 65.14 73.25 2.88 o 3 1 2 2731.59 2701.28 32.94 o 4 1 2 936.33 964.12 13.28 o 5 1 2 542.72 534.07 8.52 o 6 1 2 391.19 362.65 9.16 o 7 1 2 87.59 82.09 7.23 o 8 1 2 56.32 54.74 4.46 o 9 1 2 45.31 41.66 12.60 o 10 1 2 29.95 23.79 8.94 o 11 1 2 38.15 73.39 15.80 o -11 2 2 14.72 -2.59 19.64 o -10 2 2 25.01 17.14 8.70 o -9 2 2 221.36 229.67 19.12 o -8 2 2 175.88 163.22 12.11 o -7 2 2 707.05 690.83 20.20 o -6 2 2 215.66 201.73 7.10 o -5 2 2 26.32 32.62 2.11 o -4 2 2 1674.54 1692.04 20.45 o -3 2 2 32.67 36.83 3.41 o -2 2 2 4120.24 4108.52 44.20 o -1 2 2 888.09 838.29 9.95 o 0 2 2 21.52 32.41 3.52 o 1 2 2 890.15 832.47 9.42 o 2 2 2 4117.04 4094.99 51.94 o 3 2 2 31.81 35.08 1.70 o 4 2 2 1665.86 1689.04 22.36 o 5 2 2 27.98 28.97 2.37 o 6 2 2 220.60 210.73 7.23 o 7 2 2 708.97 690.12 19.79 o 8 2 2 168.65 190.73 10.70 o 9 2 2 220.79 240.74 16.98 o 10 2 2 22.59 65.44 91.40 o 11 2 2 15.06 26.32 11.42 o -11 3 2 118.04 121.31 25.06 o -10 3 2 99.72 129.15 24.59 o -9 3 2 215.13 234.38 26.52 o -8 3 2 441.76 443.64 33.60 o -7 3 2 492.80 508.42 19.92 o -6 3 2 594.05 601.86 19.12 o -5 3 2 192.91 182.62 4.13 o -4 3 2 882.74 861.04 11.49 o -3 3 2 199.50 181.35 3.48 o -2 3 2 930.50 917.31 11.90 o -1 3 2 7091.48 7145.71 87.54 o 0 3 2 3024.17 3063.53 36.93 o 1 3 2 7059.25 7038.55 90.38 o 2 3 2 947.21 914.94 12.83 o 3 3 2 191.96 178.11 3.43 o 4 3 2 870.64 870.89 13.31 o 5 3 2 179.80 174.09 4.10 o 6 3 2 607.44 614.50 17.39 o 7 3 2 500.17 503.88 18.77 o 8 3 2 450.41 447.73 18.03 o 9 3 2 211.03 233.09 31.35 o 10 3 2 96.47 127.33 23.63 o 11 3 2 119.10 169.37 32.65 o -11 4 2 149.52 186.90 42.15 o -10 4 2 133.61 119.72 22.80 o -9 4 2 293.14 315.04 34.19 o -8 4 2 313.33 301.33 21.04 o -7 4 2 207.64 189.90 10.33 o -6 4 2 65.81 66.65 4.63 o -5 4 2 70.78 66.05 5.08 o -4 4 2 219.67 219.61 4.88 o -3 4 2 866.09 1008.38 14.08 o -2 4 2 2158.73 2231.24 26.65 o -1 4 2 423.06 435.59 8.04 o 0 4 2 1819.20 1896.54 25.00 o 1 4 2 421.91 414.98 7.05 o 2 4 2 2149.61 2225.13 23.73 o 3 4 2 875.97 1023.27 16.89 o 4 4 2 218.28 209.94 4.34 o 5 4 2 67.12 78.66 5.96 o 6 4 2 66.99 58.54 5.67 o 7 4 2 200.18 173.11 9.63 o 8 4 2 317.08 282.37 19.53 o 9 4 2 291.66 330.19 28.84 o 10 4 2 134.76 158.61 43.46 o 11 4 2 150.94 283.23 68.61 o -11 5 2 50.25 71.41 21.53 o -10 5 2 6.36 99.16 54.13 o -9 5 2 174.99 169.17 26.66 o -8 5 2 1412.49 1456.77 89.62 o -7 5 2 1268.00 1254.31 52.99 o -6 5 2 728.93 706.93 21.40 o -5 5 2 870.07 865.10 24.10 o -4 5 2 272.28 283.26 10.84 o -3 5 2 920.75 922.47 13.64 o -2 5 2 122.99 130.88 3.73 o -1 5 2 2275.15 2283.02 27.54 o 0 5 2 540.03 570.23 7.27 o 1 5 2 2268.57 2255.19 23.93 o 2 5 2 114.09 130.26 2.76 o 3 5 2 913.47 907.62 11.90 o 4 5 2 284.31 284.01 5.62 o 5 5 2 872.81 886.52 22.55 o 6 5 2 729.93 708.44 20.67 o 7 5 2 1243.27 1231.02 45.06 o 8 5 2 1415.31 1473.66 89.03 o 9 5 2 179.08 154.10 21.72 o 10 5 2 6.31 18.43 11.97 o 11 5 2 51.92 82.89 33.24 o -10 6 2 53.87 77.33 38.29 o -9 6 2 5.88 11.77 11.42 o -8 6 2 675.48 641.05 48.18 o -7 6 2 66.93 73.30 16.32 o -6 6 2 499.42 483.65 21.86 o -5 6 2 22.32 15.74 10.06 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519.07 510.72 10.84 o -2 2 3 2004.93 1933.83 43.06 o -1 2 3 7576.91 7507.83 73.94 o 0 2 3 5755.66 5645.86 57.66 o 1 2 3 7564.85 7514.95 83.91 o 2 2 3 1962.74 1894.56 18.50 o 3 2 3 520.75 505.60 9.44 o 4 2 3 5.02 5.50 1.76 o 5 2 3 325.33 341.97 13.88 o 6 2 3 171.86 164.24 10.35 o 7 2 3 25.35 32.74 4.48 o 8 2 3 140.59 132.48 8.14 o 9 2 3 67.68 76.56 13.57 o 10 2 3 68.72 85.69 23.92 o 11 2 3 100.50 117.78 35.35 o -11 3 3 108.08 98.88 23.97 o -10 3 3 321.14 307.38 43.86 o -9 3 3 37.01 33.89 11.74 o -8 3 3 67.51 54.99 15.90 o -7 3 3 170.42 171.65 9.54 o -6 3 3 208.32 209.54 6.50 o -5 3 3 513.05 504.41 9.61 o -4 3 3 59.11 51.09 3.52 o -3 3 3 4056.19 4144.08 42.75 o -2 3 3 326.26 329.37 6.35 o -1 3 3 4366.50 4303.28 53.84 o 0 3 3 24.72 22.73 1.38 o 1 3 3 4389.83 4260.53 43.92 o 2 3 3 323.77 315.28 5.96 o 3 3 3 4002.32 4074.36 42.54 o 4 3 3 53.12 45.89 1.93 o 5 3 3 514.01 508.11 9.63 o 6 3 3 209.16 209.33 7.36 o 7 3 3 178.89 174.48 9.69 o 8 3 3 64.87 51.79 5.73 o 9 3 3 38.83 25.10 7.30 o 10 3 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118.28 93.05 7.81 o 1 5 3 299.33 298.42 8.98 o 2 5 3 369.82 393.63 8.98 o 3 5 3 1215.24 1294.21 20.52 o 4 5 3 163.77 136.69 5.43 o 5 5 3 362.93 373.35 10.24 o 6 5 3 1769.73 1750.14 45.82 o 7 5 3 140.49 133.58 7.32 o 8 5 3 877.64 843.31 52.65 o 9 5 3 290.72 267.76 27.08 o 10 5 3 62.26 102.87 29.17 o -10 6 3 83.11 129.77 33.52 o -9 6 3 293.89 283.86 40.24 o -8 6 3 252.43 260.40 27.84 o -7 6 3 675.44 703.04 44.74 o -6 6 3 71.32 72.43 7.66 o -5 6 3 77.61 82.20 9.49 o -4 6 3 152.40 141.27 6.84 o -3 6 3 1339.49 1521.41 38.72 o -2 6 3 907.06 998.96 17.07 o -1 6 3 338.33 414.47 8.98 o 0 6 3 24.63 27.04 3.22 o 1 6 3 338.95 404.66 6.24 o 2 6 3 898.68 982.74 12.78 o 3 6 3 1351.95 1525.78 34.28 o 4 6 3 147.57 137.50 7.81 o 5 6 3 81.16 79.54 6.45 o 6 6 3 70.98 68.39 5.26 o 7 6 3 666.96 612.86 30.85 o 8 6 3 245.61 245.23 25.40 o 9 6 3 286.13 293.86 38.57 o 10 6 3 83.36 94.40 23.05 o -10 7 3 39.07 68.81 21.80 o -9 7 3 255.45 286.04 55.05 o -8 7 3 .17 27.95 12.71 o -7 7 3 74.84 85.02 9.33 o -6 7 3 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131.44 27.54 o -6 11 3 18.91 54.94 16.55 o -5 11 3 85.67 107.59 17.54 o -4 11 3 104.11 148.00 20.65 o -3 11 3 121.42 127.73 18.13 o -2 11 3 456.23 482.74 31.81 o -1 11 3 943.95 1039.75 72.85 o 0 11 3 .14 11.69 6.51 o 1 11 3 964.14 1067.11 67.96 o 2 11 3 459.57 458.78 25.75 o 3 11 3 125.11 158.28 16.70 o 4 11 3 106.17 110.73 16.38 o 5 11 3 93.48 91.37 15.78 o 6 11 3 19.88 35.73 11.82 o 7 11 3 92.04 96.54 23.35 o -6 12 3 22.79 28.50 11.87 o -5 12 3 43.18 37.88 41.78 o -4 12 3 26.40 44.66 16.74 o -3 12 3 75.86 96.52 17.94 o -2 12 3 425.00 458.50 48.62 o -1 12 3 249.81 261.42 30.15 o 0 12 3 160.87 152.64 17.96 o 1 12 3 245.22 227.77 23.08 o 2 12 3 429.20 476.63 62.43 o 3 12 3 73.94 92.15 16.67 o 4 12 3 26.14 41.43 28.03 o 5 12 3 40.11 69.25 20.95 o 6 12 3 21.63 42.00 15.31 o -5 13 3 81.08 122.22 36.41 o -4 13 3 254.69 283.66 44.66 o -3 13 3 101.87 110.59 23.01 o -2 13 3 322.08 325.11 45.99 o -1 13 3 70.69 99.72 20.93 o 0 13 3 152.71 135.80 30.89 o 1 13 3 70.78 57.35 16.71 o 2 13 3 313.51 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