#------------------------------------------------------------------------------ #$Date: 2016-04-03 04:26:56 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181168 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/47/2224701.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2224701_Fobs loop_ _publ_author_name 'Sun, Jingya' 'Tong, Xiangdi' _publ_section_title ; Aqua(6,6'-oxydipicolinato-\k^2^O,N,N',O')copper(II) ; _journal_coeditor_code LH2964 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m70 _journal_volume 66 _journal_year 2010 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 110.201 _cell_angle_gamma 90.000 _cell_length_a 7.2487 _cell_length_b 21.0550 _cell_length_c 8.2269 _exptl_crystal_F_000 684.00 _reflns_d_resolution_high 0.8406 _cod_data_source_file lh2964Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' woaini in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 245.21 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 2416.23 2590.84 52.74 o 6 0 0 939.44 984.50 36.49 o 8 0 0 76.09 82.93 15.26 o 1 1 0 5221.44 5867.17 66.28 o 2 1 0 12675.64 14023.70 149.12 o 3 1 0 4433.85 4543.19 54.24 o 4 1 0 2109.82 2191.39 31.17 o 5 1 0 93.75 95.24 7.27 o 6 1 0 19.04 10.34 4.99 o 7 1 0 0.69 1.55 4.91 o 8 1 0 1.67 -2.94 6.63 o 0 2 0 3797.45 2225.73 43.78 o 1 2 0 14640.28 16112.05 150.74 o 2 2 0 60129.86 65383.30 597.26 o 3 2 0 2587.84 2929.57 38.67 o 4 2 0 3.90 28.00 10.25 o 5 2 0 266.11 275.99 9.42 o 6 2 0 82.90 76.12 8.26 o 7 2 0 515.93 543.51 19.93 o 8 2 0 0.22 4.64 5.63 o 1 3 0 5992.92 6502.20 58.69 o 2 3 0 28415.89 30381.31 276.13 o 3 3 0 704.56 682.66 12.48 o 4 3 0 6344.50 6445.94 69.53 o 5 3 0 44.20 48.55 9.16 o 6 3 0 521.88 482.33 16.67 o 7 3 0 10.81 7.96 7.30 o 8 3 0 32.58 37.08 7.93 o 0 4 0 511.06 297.87 9.29 o 1 4 0 6.37 3.49 1.48 o 2 4 0 27.10 52.94 6.03 o 3 4 0 1355.59 1509.32 45.89 o 4 4 0 6014.08 6664.87 75.12 o 5 4 0 1262.13 1156.00 26.90 o 6 4 0 1176.89 1216.62 25.72 o 7 4 0 4.24 4.64 7.30 o 1 5 0 9.01 12.12 2.50 o 2 5 0 179.55 168.33 6.13 o 3 5 0 6583.35 6623.70 63.10 o 4 5 0 3271.93 3384.57 37.05 o 5 5 0 153.69 152.99 8.39 o 6 5 0 189.98 203.62 11.52 o 7 5 0 65.74 66.83 16.25 o 0 6 0 1738.41 1633.72 104.51 o 1 6 0 4414.18 4563.04 41.86 o 2 6 0 944.42 1012.04 13.58 o 3 6 0 0.80 -0.71 2.46 o 4 6 0 987.01 1034.09 16.43 o 5 6 0 702.45 723.05 17.24 o 6 6 0 1622.50 1629.83 29.86 o 7 6 0 57.75 84.37 9.31 o 1 7 0 104.28 103.01 5.31 o 2 7 0 936.63 884.54 12.06 o 3 7 0 794.62 824.53 24.72 o 4 7 0 1741.81 1694.53 23.11 o 5 7 0 260.59 265.75 14.67 o 6 7 0 533.47 497.75 17.24 o 7 7 0 77.61 75.59 10.63 o 0 8 0 2358.41 2101.03 31.43 o 1 8 0 1257.91 1277.05 19.24 o 2 8 0 12.60 7.56 2.03 o 3 8 0 356.33 394.29 8.45 o 4 8 0 86.63 90.02 13.69 o 5 8 0 545.09 551.49 17.83 o 6 8 0 80.57 79.97 10.55 o 7 8 0 52.86 62.45 21.51 o 1 9 0 1442.51 1410.12 17.66 o 2 9 0 38.52 37.33 3.36 o 3 9 0 1830.37 1710.90 22.41 o 4 9 0 24.66 17.70 4.36 o 5 9 0 630.40 669.08 23.37 o 6 9 0 16.13 7.90 4.71 o 7 9 0 259.99 255.17 27.07 o 0 10 0 520.15 439.96 14.10 o 1 10 0 1135.84 1091.29 18.00 o 2 10 0 723.36 659.93 12.04 o 3 10 0 12.66 14.77 2.84 o 4 10 0 511.46 474.49 13.37 o 5 10 0 510.32 446.39 43.88 o 6 10 0 441.02 486.17 25.60 o 7 10 0 157.15 189.01 21.56 o 1 11 0 0.92 1.08 2.57 o 2 11 0 2277.25 2228.45 24.94 o 3 11 0 4.12 5.69 2.74 o 4 11 0 1356.63 1345.15 30.23 o 5 11 0 1.17 5.73 6.46 o 6 11 0 47.27 44.56 10.70 o 7 11 0 9.30 -1.30 8.28 o 0 12 0 2634.03 2816.12 38.66 o 1 12 0 1181.50 1059.44 17.02 o 2 12 0 112.77 93.04 5.34 o 3 12 0 4.99 4.43 3.39 o 4 12 0 2.63 4.12 4.16 o 5 12 0 839.99 840.57 42.52 o 6 12 0 91.35 103.90 12.74 o 7 12 0 136.45 167.00 17.42 o 1 13 0 844.54 737.47 14.68 o 2 13 0 299.27 288.86 8.15 o 3 13 0 2310.38 2370.28 36.67 o 4 13 0 227.32 245.69 17.45 o 5 13 0 232.94 260.99 16.19 o 6 13 0 58.29 52.66 13.35 o 0 14 0 770.41 641.31 19.54 o 1 14 0 842.14 846.91 16.99 o 2 14 0 2821.23 2754.88 37.24 o 3 14 0 0.26 1.00 3.91 o 4 14 0 569.14 559.00 22.62 o 5 14 0 116.60 141.58 21.80 o 6 14 0 130.22 118.68 13.98 o 1 15 0 274.55 299.85 10.26 o 2 15 0 1198.50 1139.98 24.17 o 3 15 0 78.95 64.78 10.14 o 4 15 0 291.30 281.14 18.28 o 5 15 0 134.99 160.04 17.37 o 6 15 0 0.25 5.98 8.02 o 0 16 0 202.07 175.70 14.41 o 1 16 0 1560.38 1489.52 22.80 o 2 16 0 226.01 209.06 10.81 o 3 16 0 40.30 35.89 8.57 o 4 16 0 326.74 313.64 17.92 o 5 16 0 958.45 1049.23 47.47 o 6 16 0 32.87 28.49 13.14 o 1 17 0 1144.29 1122.90 20.81 o 2 17 0 227.11 222.01 18.24 o 3 17 0 829.70 770.12 34.11 o 4 17 0 324.94 338.42 21.27 o 5 17 0 435.07 393.36 22.35 o 0 18 0 1340.04 1354.13 62.69 o 1 18 0 59.28 71.43 7.36 o 2 18 0 176.13 174.76 15.21 o 3 18 0 146.10 155.71 12.81 o 4 18 0 92.04 77.11 11.61 o 5 18 0 0.89 2.19 8.93 o 1 19 0 124.64 146.13 10.33 o 2 19 0 298.02 305.25 15.70 o 3 19 0 1313.66 1245.92 39.85 o 4 19 0 269.81 280.99 21.04 o 5 19 0 141.78 142.83 17.13 o 0 20 0 71.18 59.97 18.77 o 1 20 0 2305.86 2400.89 63.02 o 2 20 0 28.29 28.25 8.30 o 3 20 0 73.43 69.34 10.92 o 4 20 0 7.85 -8.64 6.78 o 1 21 0 10.95 14.19 7.83 o 2 21 0 534.23 557.07 24.28 o 3 21 0 213.93 220.00 19.79 o 4 21 0 282.96 293.16 20.46 o 0 22 0 1289.07 1176.28 71.55 o 1 22 0 607.83 661.48 44.49 o 2 22 0 214.96 247.71 19.90 o 3 22 0 0.01 -4.51 7.88 o 1 23 0 574.54 613.49 34.85 o 2 23 0 32.59 31.45 9.55 o 3 23 0 1087.69 1219.37 38.00 o 1 24 0 401.24 440.97 37.61 o 2 24 0 43.89 49.56 24.61 o -7 0 1 325.39 327.06 21.23 o -5 0 1 158.14 163.86 11.94 o -3 0 1 3226.11 3095.45 65.01 o -1 0 1 17597.46 18292.10 333.03 o 1 0 1 581.59 549.81 12.05 o 3 0 1 3483.35 3438.60 50.62 o 5 0 1 1323.79 1285.80 31.79 o 7 0 1 12.43 27.20 9.95 o -8 1 1 71.00 77.32 9.85 o -7 1 1 328.05 342.74 15.24 o -6 1 1 414.45 418.15 15.48 o -5 1 1 241.23 268.12 20.23 o -4 1 1 132.17 109.64 7.30 o -3 1 1 1134.07 1182.78 21.09 o -2 1 1 1449.31 928.77 21.89 o -1 1 1 363.17 414.49 5.76 o 0 1 1 10486.66 11267.44 109.38 o 1 1 1 9948.28 10575.46 92.72 o 2 1 1 6332.95 6709.84 59.62 o 3 1 1 255.96 235.16 6.65 o 4 1 1 34.78 38.81 4.41 o 5 1 1 160.02 150.80 8.91 o 6 1 1 222.59 248.54 14.05 o 7 1 1 171.88 186.46 16.25 o -8 2 1 110.61 142.79 23.88 o -7 2 1 10.23 0.66 4.69 o -6 2 1 2.43 8.89 4.30 o -5 2 1 2.05 7.92 3.49 o -4 2 1 3069.28 3151.03 49.25 o -3 2 1 450.43 469.14 13.96 o -2 2 1 1181.31 1248.97 21.93 o -1 2 1 110.03 84.39 5.35 o 0 2 1 6042.72 6283.33 59.62 o 1 2 1 3684.98 4081.14 35.97 o 2 2 1 10052.62 10509.65 87.60 o 3 2 1 467.71 455.74 9.71 o 4 2 1 1688.72 1631.25 59.66 o 5 2 1 0.97 3.39 3.70 o 6 2 1 81.09 103.16 10.32 o 7 2 1 17.57 14.93 6.10 o -7 3 1 258.10 298.65 19.52 o -6 3 1 134.22 136.11 9.71 o -5 3 1 1173.92 1179.77 25.54 o -4 3 1 485.65 452.84 51.35 o -3 3 1 1065.79 1137.03 21.84 o -2 3 1 26.15 31.99 4.60 o -1 3 1 2957.82 2975.96 35.20 o 0 3 1 316.14 352.07 7.57 o 1 3 1 4187.01 4474.58 47.17 o 2 3 1 55.53 44.60 3.25 o 3 3 1 4739.27 4991.82 49.95 o 4 3 1 810.29 820.09 15.81 o 5 3 1 896.44 899.40 21.83 o 6 3 1 833.79 854.94 23.60 o 7 3 1 97.40 123.84 11.96 o -7 4 1 146.38 162.44 22.81 o -6 4 1 18.18 19.45 4.97 o -5 4 1 118.02 136.44 7.40 o -4 4 1 572.51 592.68 13.52 o -3 4 1 3675.58 3450.53 46.13 o -2 4 1 1245.60 1353.45 16.84 o -1 4 1 1528.25 1590.44 17.36 o 0 4 1 1145.66 1274.46 14.97 o 1 4 1 1909.25 2207.35 25.06 o 2 4 1 607.34 749.85 14.64 o 3 4 1 12439.88 12861.33 133.86 o 4 4 1 1690.15 1720.30 28.80 o 5 4 1 306.79 312.89 12.40 o 6 4 1 48.85 42.00 8.14 o 7 4 1 9.40 10.06 5.85 o -8 5 1 71.35 72.97 15.26 o -7 5 1 95.12 118.84 13.11 o -6 5 1 1128.24 1179.25 34.31 o -5 5 1 15.82 17.35 5.92 o -4 5 1 65.54 67.85 4.70 o -3 5 1 432.40 421.64 8.68 o -2 5 1 72.21 77.14 3.29 o -1 5 1 2542.99 2697.92 48.89 o 0 5 1 3795.12 3939.83 32.11 o 1 5 1 19.78 26.47 3.91 o 2 5 1 759.81 691.77 20.35 o 3 5 1 427.91 422.58 8.06 o 4 5 1 1175.13 1192.20 27.10 o 5 5 1 1178.51 1142.64 24.43 o 6 5 1 1553.50 1556.63 30.14 o 7 5 1 1.00 6.30 5.63 o -8 6 1 114.15 130.69 19.24 o -7 6 1 150.46 153.08 42.79 o -6 6 1 144.66 125.79 12.36 o -5 6 1 0.73 1.86 2.60 o -4 6 1 2042.27 1953.66 27.72 o -3 6 1 617.34 585.09 10.83 o -2 6 1 215.96 168.01 4.30 o -1 6 1 1797.52 1815.93 18.01 o 0 6 1 212.49 188.82 4.85 o 1 6 1 589.39 625.96 12.56 o 2 6 1 1390.75 1323.51 20.04 o 3 6 1 111.98 113.40 6.57 o 4 6 1 5698.77 5924.57 72.88 o 5 6 1 1599.34 1593.78 28.65 o 6 6 1 207.29 187.28 12.35 o 7 6 1 7.37 0.33 10.95 o -8 7 1 31.95 32.51 11.94 o -7 7 1 478.57 476.91 50.75 o -6 7 1 119.08 108.20 8.38 o -5 7 1 1773.86 1702.01 23.77 o -4 7 1 26.68 27.13 3.38 o -3 7 1 75.08 70.20 3.93 o -2 7 1 689.10 822.33 11.55 o -1 7 1 705.85 572.80 10.38 o 0 7 1 1549.09 1634.33 18.81 o 1 7 1 9973.07 10197.45 96.50 o 2 7 1 1692.64 1846.64 20.86 o 3 7 1 334.99 323.33 7.07 o 4 7 1 163.42 174.03 8.86 o 5 7 1 768.21 765.15 19.10 o 6 7 1 1.16 3.17 4.24 o 7 7 1 524.50 535.66 22.92 o -7 8 1 114.38 88.66 14.50 o -6 8 1 36.57 49.86 9.89 o -5 8 1 428.31 466.57 12.95 o -4 8 1 5.50 1.15 2.70 o -3 8 1 3418.82 3326.30 34.51 o -2 8 1 1604.42 1516.81 17.66 o -1 8 1 1188.20 1165.21 15.52 o 0 8 1 1560.39 1819.01 22.50 o 1 8 1 468.59 575.97 12.76 o 2 8 1 4972.98 5254.59 49.03 o 3 8 1 2735.18 2699.19 31.43 o 4 8 1 94.61 89.27 9.86 o 5 8 1 274.91 289.04 11.71 o 6 8 1 300.41 295.77 13.07 o 7 8 1 225.88 212.30 13.82 o -7 9 1 355.10 388.32 19.57 o -6 9 1 1039.64 1021.40 32.18 o -5 9 1 140.06 148.69 26.13 o -4 9 1 1170.67 1163.56 17.39 o -3 9 1 121.07 137.29 5.78 o -2 9 1 1743.38 1850.25 22.81 o -1 9 1 100.49 121.73 5.36 o 0 9 1 5560.17 5477.62 49.98 o 1 9 1 3.42 9.02 2.70 o 2 9 1 4335.39 4305.19 38.91 o 3 9 1 59.41 62.47 5.84 o 4 9 1 24.15 18.25 4.69 o 5 9 1 206.50 208.64 15.13 o 6 9 1 518.67 517.10 21.55 o 7 9 1 94.83 90.51 13.67 o -7 10 1 516.68 504.82 28.62 o -6 10 1 58.12 52.87 10.24 o -5 10 1 73.48 83.66 11.86 o -4 10 1 1035.32 1056.24 19.43 o -3 10 1 2423.26 2392.45 33.32 o -2 10 1 2795.72 2819.12 34.54 o -1 10 1 7634.66 8002.03 61.86 o 0 10 1 5931.96 6491.47 61.36 o 1 10 1 1648.95 1808.88 22.14 o 2 10 1 778.90 742.77 12.97 o 3 10 1 114.80 92.82 7.14 o 4 10 1 221.07 215.02 14.09 o 5 10 1 447.10 493.25 16.41 o 6 10 1 222.19 174.25 15.73 o 7 10 1 3.36 0.88 18.65 o -7 11 1 528.18 606.92 27.33 o -6 11 1 16.80 17.57 8.91 o -5 11 1 2785.32 2878.68 62.91 o -4 11 1 28.85 25.38 4.78 o -3 11 1 142.58 142.21 5.86 o -2 11 1 437.18 524.69 22.51 o -1 11 1 3037.68 3051.82 28.00 o 0 11 1 1619.23 1719.47 23.62 o 1 11 1 4500.63 4281.75 39.83 o 2 11 1 130.88 133.36 6.70 o 3 11 1 40.08 31.55 4.67 o 4 11 1 61.99 55.40 6.54 o 5 11 1 172.07 199.07 17.99 o 6 11 1 23.38 23.16 8.92 o -7 12 1 0.36 14.20 9.10 o -6 12 1 85.71 92.74 13.85 o -5 12 1 927.36 1020.50 28.36 o -4 12 1 1059.62 1059.96 30.68 o -3 12 1 75.62 71.78 6.15 o -2 12 1 10261.63 10709.26 89.04 o -1 12 1 787.66 795.91 11.68 o 0 12 1 25.02 31.90 3.89 o 1 12 1 1053.62 1130.15 16.60 o 2 12 1 140.05 111.45 7.24 o 3 12 1 520.49 460.99 13.23 o 4 12 1 1080.73 1027.99 22.54 o 5 12 1 140.74 138.44 10.42 o 6 12 1 31.90 36.77 9.41 o -7 13 1 194.69 201.26 18.42 o -6 13 1 1087.11 1102.72 36.23 o -5 13 1 1342.22 1329.73 37.93 o -4 13 1 2019.45 2133.79 44.35 o -3 13 1 686.74 740.39 18.54 o -2 13 1 2.86 8.26 5.29 o -1 13 1 291.53 296.62 8.13 o 0 13 1 4080.15 3951.03 43.15 o 1 13 1 629.25 574.40 12.71 o 2 13 1 1237.35 1097.75 22.86 o 3 13 1 0.08 1.35 4.79 o 4 13 1 13.17 14.40 4.54 o 5 13 1 3.67 2.27 7.11 o 6 13 1 157.25 156.47 16.18 o -6 14 1 0.13 6.38 8.05 o -5 14 1 112.19 147.54 16.32 o -4 14 1 4.05 0.66 6.43 o -3 14 1 6257.88 6440.61 64.10 o -2 14 1 318.39 292.06 11.21 o -1 14 1 1358.64 1275.56 18.61 o 0 14 1 30.49 33.52 6.38 o 1 14 1 711.70 712.26 14.08 o 2 14 1 13.19 15.40 4.50 o 3 14 1 891.70 896.41 22.64 o 4 14 1 182.45 163.02 10.82 o 5 14 1 540.57 522.41 45.73 o 6 14 1 79.67 77.87 13.41 o -6 15 1 600.10 672.25 68.23 o -5 15 1 62.83 80.91 11.96 o -4 15 1 1145.00 1231.12 31.27 o -3 15 1 301.29 305.26 12.49 o -2 15 1 15.69 13.38 5.33 o -1 15 1 2880.79 2985.62 38.51 o 0 15 1 817.01 818.40 29.36 o 1 15 1 2342.78 2319.52 28.93 o 2 15 1 311.82 274.87 11.99 o 3 15 1 6.83 4.58 2.91 o 4 15 1 8.80 11.10 10.28 o 5 15 1 146.98 163.39 18.03 o 6 15 1 167.87 173.81 30.02 o -6 16 1 5.69 5.55 8.31 o -5 16 1 241.94 232.07 16.79 o -4 16 1 553.37 545.90 22.57 o -3 16 1 56.44 56.11 10.33 o -2 16 1 3784.12 3758.20 50.02 o -1 16 1 384.28 399.94 15.65 o 0 16 1 46.38 44.69 5.79 o 1 16 1 290.06 276.11 17.43 o 2 16 1 482.88 447.06 41.48 o 3 16 1 1.65 2.66 2.84 o 4 16 1 1305.02 1263.29 36.63 o 5 16 1 190.19 143.22 17.17 o -6 17 1 45.58 51.06 10.87 o -5 17 1 195.63 182.85 16.94 o -4 17 1 45.09 40.88 9.37 o -3 17 1 255.46 259.76 28.39 o -2 17 1 286.42 324.91 13.29 o -1 17 1 1906.66 1805.67 42.05 o 0 17 1 1547.43 1605.45 33.70 o 1 17 1 1426.76 1416.59 36.23 o 2 17 1 319.29 346.64 15.98 o 3 17 1 80.91 91.13 18.35 o 4 17 1 42.88 34.09 8.61 o 5 17 1 394.13 395.75 24.27 o -5 18 1 111.51 102.80 13.77 o -4 18 1 186.22 164.74 14.69 o -3 18 1 329.81 358.12 21.14 o -2 18 1 1.00 2.75 6.22 o -1 18 1 82.86 95.17 10.03 o 0 18 1 368.32 332.15 18.40 o 1 18 1 1022.20 1028.28 23.35 o 2 18 1 179.34 155.82 12.79 o 3 18 1 1855.88 1802.17 45.27 o 4 18 1 9.26 2.66 7.40 o 5 18 1 515.06 532.21 28.22 o -5 19 1 268.40 273.79 20.96 o -4 19 1 212.15 244.35 22.41 o -3 19 1 17.28 14.14 8.53 o -2 19 1 407.61 411.40 20.91 o -1 19 1 3.46 -1.64 5.65 o 0 19 1 722.02 729.29 21.27 o 1 19 1 45.89 44.13 6.23 o 2 19 1 1460.30 1355.99 55.98 o 3 19 1 43.79 16.46 7.99 o 4 19 1 208.28 220.58 16.84 o -5 20 1 7.87 4.06 8.84 o -4 20 1 401.02 429.24 22.50 o -3 20 1 43.54 53.72 11.97 o -2 20 1 444.76 480.84 26.77 o -1 20 1 109.19 101.20 14.49 o 0 20 1 126.08 133.89 10.83 o 1 20 1 405.00 421.70 18.81 o 2 20 1 682.58 715.73 31.72 o 3 20 1 848.98 807.26 47.04 o 4 20 1 662.91 728.45 29.65 o -4 21 1 90.71 81.56 15.18 o -3 21 1 3.29 4.20 6.81 o -2 21 1 119.30 149.03 14.77 o -1 21 1 237.73 273.53 15.84 o 0 21 1 54.49 39.50 10.62 o 1 21 1 759.13 832.61 39.07 o 2 21 1 550.65 556.36 25.84 o 3 21 1 10.10 10.25 7.76 o 4 21 1 22.80 3.92 9.55 o -4 22 1 13.37 0.93 9.03 o -3 22 1 709.58 673.75 42.13 o -2 22 1 133.84 125.51 15.24 o -1 22 1 485.09 527.07 27.76 o 0 22 1 2.92 29.85 20.39 o 1 22 1 117.77 108.99 25.22 o 2 22 1 302.62 313.40 48.46 o 3 22 1 174.62 186.19 16.60 o -3 23 1 75.64 75.19 24.50 o -2 23 1 4.51 6.12 9.24 o -1 23 1 77.18 53.23 11.87 o 0 23 1 1448.33 1377.99 79.38 o 1 23 1 190.39 163.47 38.07 o 2 23 1 192.56 210.19 36.49 o -2 24 1 407.81 448.45 22.51 o 0 24 1 159.72 139.88 41.46 o 1 24 1 16.22 19.74 24.55 o -6 0 2 1869.49 1930.51 52.41 o -2 0 2 3.31 11.94 3.32 o 0 0 2 7440.61 2888.47 58.38 o 2 0 2 275.36 235.22 9.80 o 4 0 2 6.94 5.00 4.69 o 6 0 2 516.52 570.53 29.85 o -8 1 2 125.57 140.64 19.24 o -7 1 2 782.91 802.06 31.84 o -6 1 2 211.77 229.54 15.26 o -5 1 2 26.21 25.87 5.97 o -3 1 2 1188.99 1330.76 23.19 o -2 1 2 3999.18 4092.25 46.82 o -1 1 2 118.28 107.85 3.36 o 0 1 2 40.89 52.87 3.23 o 1 1 2 6317.11 6690.21 54.52 o 2 1 2 397.82 420.70 8.92 o 3 1 2 3305.03 3253.28 36.25 o 4 1 2 370.92 360.19 11.31 o 5 1 2 893.86 872.85 43.12 o 6 1 2 273.02 280.37 20.23 o 7 1 2 4.20 2.65 5.63 o -8 2 2 13.44 22.56 9.29 o -7 2 2 462.29 478.67 17.95 o -6 2 2 40.91 57.26 6.79 o -5 2 2 2023.38 1.33 1.99 o -4 2 2 585.71 604.24 20.23 o -3 2 2 564.70 518.48 13.36 o -2 2 2 761.94 807.20 12.20 o -1 2 2 13344.01 14336.17 135.46 o 0 2 2 766.73 891.39 10.84 o 1 2 2 3332.51 3206.70 29.24 o 2 2 2 132.32 150.86 5.70 o 3 2 2 593.86 583.11 15.97 o 4 2 2 177.76 149.30 8.93 o 5 2 2 566.45 545.61 16.64 o 6 2 2 11.38 7.24 5.10 o 7 2 2 646.64 605.70 51.41 o -8 3 2 422.59 407.33 26.54 o -7 3 2 95.08 108.10 8.09 o -6 3 2 214.58 210.30 18.58 o -5 3 2 435.66 482.43 12.27 o -4 3 2 1837.67 1786.85 26.05 o -3 3 2 2867.27 2907.97 45.74 o -2 3 2 859.56 733.10 19.24 o -1 3 2 7528.42 7743.11 73.76 o 0 3 2 1880.12 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250.23 6.68 o 0 10 2 7022.75 6918.15 114.10 o 1 10 2 627.38 542.97 11.99 o 2 10 2 1241.93 1160.67 22.63 o 3 10 2 102.26 85.34 7.30 o 4 10 2 64.85 68.62 10.07 o 5 10 2 8.80 10.86 5.13 o 6 10 2 39.97 43.21 7.29 o -7 11 2 15.26 26.63 10.61 o -6 11 2 1340.51 1339.43 51.14 o -5 11 2 262.72 296.89 13.02 o -4 11 2 1164.34 1156.57 34.64 o -3 11 2 1237.75 1242.32 28.57 o -2 11 2 6871.47 6975.57 73.90 o -1 11 2 710.08 745.18 12.53 o 0 11 2 1556.32 1555.23 19.37 o 1 11 2 0.65 3.86 2.41 o 2 11 2 4.25 2.87 5.67 o 3 11 2 67.09 60.85 7.37 o 4 11 2 1445.86 1451.39 30.31 o 5 11 2 42.81 38.03 6.42 o 6 11 2 64.04 72.77 11.11 o -7 12 2 22.84 44.46 11.72 o -6 12 2 717.54 802.15 39.58 o -5 12 2 2749.57 2812.73 50.91 o -4 12 2 718.30 728.26 30.16 o -3 12 2 1859.58 1906.81 48.91 o -2 12 2 302.11 305.41 10.77 o -1 12 2 341.29 288.12 7.93 o 0 12 2 669.49 665.63 12.10 o 1 12 2 2379.92 2277.29 31.87 o 2 12 2 95.24 78.05 7.42 o 3 12 2 113.46 104.86 12.34 o 4 12 2 16.07 25.76 7.84 o 5 12 2 13.44 15.11 8.28 o 6 12 2 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16.81 o -8 2 3 472.78 460.02 19.93 o -7 2 3 4.51 1.33 5.10 o -6 2 3 2150.38 2283.15 35.57 o -5 2 3 94.16 104.39 6.89 o -4 2 3 69.37 62.54 6.06 o -3 2 3 479.94 462.41 9.84 o -2 2 3 4609.23 4425.79 51.50 o -1 2 3 1332.28 1528.74 17.97 o 0 2 3 1598.57 1588.81 18.60 o 1 2 3 1156.56 1254.91 13.04 o 2 2 3 277.54 306.09 11.18 o 3 2 3 99.30 97.59 8.62 o 4 2 3 1320.70 1324.11 25.31 o 5 2 3 2.47 8.57 5.38 o 6 2 3 302.83 304.16 16.18 o -8 3 3 33.92 31.06 7.97 o -7 3 3 97.35 112.07 11.02 o -6 3 3 67.22 86.82 10.46 o -5 3 3 2465.29 2547.92 36.27 o -4 3 3 5159.17 5487.39 65.14 o -3 3 3 3978.78 4132.20 49.37 o -2 3 3 7074.46 7953.50 88.13 o -1 3 3 333.27 395.57 7.09 o 0 3 3 147.81 110.69 4.01 o 1 3 3 8266.69 8394.69 76.68 o 2 3 3 4032.85 4115.04 40.93 o 3 3 3 931.27 912.55 36.03 o 4 3 3 203.04 180.99 10.57 o 5 3 3 11.69 10.99 6.63 o 6 3 3 5.05 10.26 6.63 o -8 4 3 246.11 256.74 24.55 o -7 4 3 734.17 764.44 30.18 o -6 4 3 463.15 449.79 17.36 o -5 4 3 335.84 367.56 11.72 o -4 4 3 1970.98 2246.68 31.16 o 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3.79 o 3 6 3 586.26 604.17 34.54 o 4 6 3 1376.85 1401.66 29.97 o 5 6 3 37.84 43.52 7.06 o 6 6 3 71.27 78.89 22.89 o -8 7 3 3.62 -7.30 9.29 o -7 7 3 112.19 116.18 15.26 o -6 7 3 130.48 147.11 11.70 o -5 7 3 644.55 636.79 19.70 o -4 7 3 94.05 121.08 9.38 o -3 7 3 2626.97 2708.90 48.10 o -2 7 3 629.61 818.77 21.39 o -1 7 3 429.56 450.10 9.03 o 0 7 3 324.76 368.67 13.98 o 1 7 3 6261.40 6268.38 73.26 o 2 7 3 503.12 516.28 13.71 o 3 7 3 423.86 406.75 12.65 o 4 7 3 26.42 23.50 6.89 o 5 7 3 127.04 129.77 11.03 o 6 7 3 2.89 6.83 5.57 o -8 8 3 114.73 162.27 18.86 o -7 8 3 270.08 218.92 23.22 o -6 8 3 5.03 4.45 4.91 o -5 8 3 254.94 243.10 19.24 o -4 8 3 943.77 959.26 23.91 o -3 8 3 45.41 38.57 5.85 o -2 8 3 6130.35 6348.94 85.52 o -1 8 3 5655.48 5802.63 152.50 o 0 8 3 7125.24 7648.64 82.54 o 1 8 3 322.59 379.53 12.26 o 2 8 3 475.03 520.46 15.04 o 3 8 3 1056.86 1063.66 22.62 o 4 8 3 188.17 163.32 10.26 o 5 8 3 386.21 392.85 16.42 o 6 8 3 93.06 102.96 13.93 o -8 9 3 111.89 118.08 27.20 o -7 9 3 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