#------------------------------------------------------------------------------ #$Date: 2016-04-03 04:30:04 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181172 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/51/2225104.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2225104_Fobs loop_ _publ_author_name 'Liu, Lin' _publ_section_title ; {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II) ; _journal_coeditor_code RZ2410 _journal_issue 2 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m195 _journal_volume 66 _journal_year 2010 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 111.716 _cell_angle_gamma 90.000 _cell_length_a 9.2983 _cell_length_b 19.6789 _cell_length_c 8.4609 _exptl_crystal_F_000 704.00 _reflns_d_resolution_high 0.8390 _cod_data_source_file rz2410Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' P21c in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 163.51 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 60.38 94.65 9.52 o 2 0 0 1726.09 1674.58 77.91 o 3 0 0 6447.78 6473.15 192.03 o 4 0 0 3604.74 3302.98 105.50 o 5 0 0 2738.42 2706.74 92.02 o 6 0 0 4344.08 4182.85 137.08 o 7 0 0 128.08 89.01 30.81 o 8 0 0 9.24 -54.83 70.41 o 9 0 0 454.08 429.11 100.71 o 10 0 0 100.93 10.68 93.50 o 1 1 0 1568.64 1451.22 64.64 o 2 1 0 6.27 7.74 7.52 o 3 1 0 273.41 286.25 12.78 o 4 1 0 25.92 32.22 10.17 o 5 1 0 0.45 -0.95 11.35 o 6 1 0 1.22 40.03 20.39 o 7 1 0 255.64 226.81 25.80 o 8 1 0 119.14 82.25 32.92 o 9 1 0 0.22 45.35 57.01 o 10 1 0 36.99 36.37 65.83 o 1 2 0 3511.87 3537.02 150.06 o 2 2 0 6514.68 6537.34 194.41 o 3 2 0 6044.81 6348.95 141.03 o 4 2 0 1037.50 987.21 28.44 o 5 2 0 826.52 846.19 28.06 o 6 2 0 3607.12 3605.34 85.62 o 7 2 0 26.11 -25.44 26.46 o 8 2 0 7.20 -46.24 30.83 o 9 2 0 560.42 513.72 73.95 o 10 2 0 38.71 32.90 96.09 o 1 3 0 2415.86 2296.16 100.42 o 2 3 0 484.35 412.36 23.53 o 3 3 0 11.69 7.53 5.24 o 4 3 0 230.50 222.44 13.29 o 5 3 0 2183.18 2207.08 47.83 o 6 3 0 249.27 315.43 24.93 o 7 3 0 308.02 371.47 40.07 o 8 3 0 27.96 18.04 34.45 o 9 3 0 40.28 29.01 61.07 o 10 3 0 119.54 -39.82 91.19 o 0 4 0 694.81 787.51 34.92 o 1 4 0 13.33 12.86 4.72 o 2 4 0 1493.52 1353.02 72.01 o 3 4 0 3349.07 3649.10 91.59 o 4 4 0 1977.25 1985.94 51.16 o 5 4 0 522.03 501.66 18.81 o 6 4 0 850.74 914.55 32.55 o 7 4 0 553.44 561.11 37.93 o 8 4 0 153.29 197.13 42.63 o 9 4 0 130.10 191.31 53.63 o 10 4 0 14.81 -4.04 97.25 o 1 5 0 421.38 462.59 21.56 o 2 5 0 224.53 265.75 14.55 o 3 5 0 64.45 48.70 16.75 o 4 5 0 3478.44 3496.85 81.18 o 5 5 0 3350.07 3413.06 62.19 o 6 5 0 1.10 8.87 16.73 o 7 5 0 780.89 747.29 42.05 o 8 5 0 716.87 669.39 57.19 o 9 5 0 14.33 10.03 48.90 o 0 6 0 6342.55 6010.07 228.55 o 1 6 0 158.04 139.96 9.73 o 2 6 0 27.64 29.77 7.61 o 3 6 0 627.86 683.99 23.62 o 4 6 0 719.49 731.15 31.99 o 5 6 0 51.01 97.86 28.71 o 6 6 0 153.12 143.24 21.45 o 7 6 0 9.05 29.83 39.71 o 8 6 0 82.61 126.65 71.13 o 9 6 0 85.91 137.11 55.65 o 1 7 0 4008.23 4282.80 99.58 o 2 7 0 3931.23 4004.15 94.70 o 3 7 0 231.89 239.95 15.59 o 4 7 0 3242.87 3375.79 129.55 o 5 7 0 3735.20 3687.00 92.82 o 6 7 0 37.39 10.01 15.02 o 7 7 0 1104.67 1113.16 65.19 o 8 7 0 869.01 882.97 64.29 o 9 7 0 0.03 -11.35 54.20 o 0 8 0 757.78 777.12 41.27 o 1 8 0 1130.00 1122.84 31.99 o 2 8 0 39.69 47.44 10.38 o 3 8 0 13.05 1.57 10.41 o 4 8 0 34.11 44.32 13.53 o 5 8 0 1.90 15.04 14.91 o 6 8 0 7.19 -3.56 14.81 o 7 8 0 61.57 110.26 55.69 o 8 8 0 24.64 63.51 50.04 o 9 8 0 10.51 -58.36 52.32 o 1 9 0 4262.46 4563.50 107.41 o 2 9 0 5224.55 5377.90 126.14 o 3 9 0 39.00 23.59 12.49 o 4 9 0 1708.95 1864.78 52.92 o 5 9 0 2614.93 2803.19 78.76 o 6 9 0 74.63 55.38 17.76 o 7 9 0 1007.82 1030.78 65.40 o 8 9 0 260.70 298.45 61.32 o 9 9 0 6.54 -75.27 52.97 o 0 10 0 2941.56 2972.57 124.09 o 1 10 0 52.46 61.83 11.52 o 2 10 0 4.19 3.04 11.04 o 3 10 0 2.05 -10.98 12.02 o 4 10 0 250.09 274.25 29.83 o 5 10 0 455.05 468.81 38.25 o 6 10 0 188.44 204.82 32.03 o 7 10 0 0.19 2.81 44.44 o 8 10 0 9.13 25.06 49.50 o 9 10 0 33.53 -75.34 52.33 o 1 11 0 3217.36 3252.39 96.39 o 2 11 0 1816.24 1862.86 57.99 o 3 11 0 157.70 164.52 18.35 o 4 11 0 547.14 579.65 28.18 o 5 11 0 623.37 609.02 30.72 o 6 11 0 20.60 -0.64 21.82 o 7 11 0 109.37 166.31 52.19 o 8 11 0 71.88 -11.77 52.06 o 9 11 0 9.72 -13.85 70.70 o 0 12 0 1249.83 1292.22 67.81 o 1 12 0 745.22 769.40 55.98 o 2 12 0 1048.90 1028.66 48.79 o 3 12 0 404.53 427.03 23.76 o 4 12 0 4.32 -25.13 16.75 o 5 12 0 919.44 885.75 37.31 o 6 12 0 475.78 455.11 48.96 o 7 12 0 46.38 12.14 46.79 o 8 12 0 69.16 14.51 54.18 o 1 13 0 777.29 753.65 37.95 o 2 13 0 213.50 274.90 26.69 o 3 13 0 97.81 114.33 19.12 o 4 13 0 64.32 45.42 24.72 o 5 13 0 22.03 -5.74 19.21 o 6 13 0 71.48 76.61 24.60 o 7 13 0 19.24 -32.55 46.51 o 8 13 0 1.76 -78.33 52.22 o 0 14 0 3312.52 3022.21 132.74 o 1 14 0 1052.31 1053.71 45.17 o 2 14 0 572.76 554.53 40.50 o 3 14 0 2299.11 2407.11 130.42 o 4 14 0 46.28 28.00 19.75 o 5 14 0 269.81 319.88 42.75 o 6 14 0 585.73 645.88 78.75 o 7 14 0 52.56 1.12 48.34 o 8 14 0 122.94 41.80 56.29 o 1 15 0 22.08 4.86 20.17 o 2 15 0 109.14 91.16 22.52 o 3 15 0 105.31 117.04 22.29 o 4 15 0 56.50 30.50 23.13 o 5 15 0 111.34 136.58 35.05 o 6 15 0 1.28 13.30 25.71 o 7 15 0 11.78 -54.07 44.64 o 0 16 0 2078.91 2020.00 101.58 o 1 16 0 418.53 409.64 35.30 o 2 16 0 440.95 394.95 35.83 o 3 16 0 792.67 795.42 44.29 o 4 16 0 404.65 448.69 38.57 o 5 16 0 442.21 469.90 45.82 o 6 16 0 590.56 644.68 73.52 o 7 16 0 165.75 55.93 42.61 o 1 17 0 339.27 333.72 35.01 o 2 17 0 2.04 18.83 25.91 o 3 17 0 264.43 320.56 36.82 o 4 17 0 17.88 49.19 28.88 o 5 17 0 117.79 90.97 50.79 o 6 17 0 31.09 12.28 28.88 o 7 17 0 1.09 7.21 61.18 o 0 18 0 93.66 81.09 38.38 o 1 18 0 52.32 13.34 25.83 o 2 18 0 421.16 398.36 38.13 o 3 18 0 182.55 196.26 35.13 o 4 18 0 606.98 570.43 75.17 o 5 18 0 137.05 155.78 34.54 o 6 18 0 206.77 148.89 71.85 o 1 19 0 155.00 163.13 33.51 o 2 19 0 39.37 6.22 29.91 o 3 19 0 3.48 -18.04 31.32 o 4 19 0 22.67 19.65 32.37 o 5 19 0 286.38 294.09 44.00 o 0 20 0 41.14 2.02 43.00 o 1 20 0 66.26 52.38 31.30 o 2 20 0 0.84 -40.06 30.44 o 3 20 0 39.00 -20.61 32.49 o 4 20 0 66.66 69.45 35.77 o 5 20 0 8.79 -44.42 62.33 o 1 21 0 152.58 156.78 35.91 o 2 21 0 175.31 113.13 35.91 o 3 21 0 1.52 -35.42 35.64 o 4 21 0 130.68 140.32 40.76 o 0 22 0 105.87 38.38 49.92 o 1 22 0 30.91 14.72 34.55 o 2 22 0 11.74 -14.24 89.60 o 3 22 0 14.05 -37.62 35.49 o 1 23 0 142.59 91.52 38.26 o -10 1 1 247.72 231.62 67.74 o -9 1 1 393.54 397.56 65.58 o -8 1 1 41.50 64.53 49.00 o -7 1 1 212.79 227.59 40.11 o -6 1 1 2234.04 2405.56 60.81 o -5 1 1 1367.40 1434.74 45.50 o -4 1 1 321.69 378.47 27.02 o -3 1 1 21.94 12.29 12.34 o -2 1 1 417.92 449.15 21.79 o -1 1 1 3718.12 3753.75 130.87 o 0 1 1 24856.98 22071.11 962.67 o 1 1 1 2943.08 2329.26 50.29 o 2 1 1 4041.71 3646.25 78.53 o 3 1 1 4895.84 4780.30 122.71 o 4 1 1 28.46 -1.56 13.37 o 5 1 1 1655.03 1590.09 44.29 o 6 1 1 942.49 925.43 34.48 o 7 1 1 264.81 254.75 27.98 o 8 1 1 35.82 36.34 34.98 o 9 1 1 276.70 199.71 69.78 o -10 2 1 108.76 44.76 60.91 o -9 2 1 5.29 20.15 54.89 o -8 2 1 178.70 162.56 36.07 o -7 2 1 675.21 600.73 36.33 o -6 2 1 391.38 457.56 22.80 o -5 2 1 1044.53 1173.04 39.18 o -4 2 1 13.65 34.42 9.99 o -3 2 1 4671.12 4919.56 123.38 o -2 2 1 17051.07 18254.71 657.65 o -1 2 1 652.92 726.93 112.54 o 0 2 1 1408.54 1178.31 80.80 o 1 2 1 4669.05 3741.70 184.33 o 2 2 1 4805.87 4009.55 128.04 o 3 2 1 192.14 184.09 13.91 o 4 2 1 1103.14 1123.53 32.80 o 5 2 1 321.84 346.81 32.11 o 6 2 1 690.11 638.73 29.60 o 7 2 1 378.42 385.66 29.66 o 8 2 1 26.34 6.74 35.31 o 9 2 1 2.07 19.11 62.67 o -10 3 1 153.27 47.90 92.92 o -9 3 1 64.22 69.14 54.43 o -8 3 1 60.60 105.23 34.89 o -7 3 1 951.60 974.33 44.95 o -6 3 1 2307.82 2423.30 91.65 o -5 3 1 496.98 551.53 24.15 o -4 3 1 170.38 176.91 15.49 o -3 3 1 5216.59 5737.48 137.09 o -2 3 1 10819.57 10662.05 471.71 o -1 3 1 5667.67 5598.83 127.66 o 0 3 1 1424.66 1624.94 71.85 o 1 3 1 1009.43 925.96 94.22 o 2 3 1 3569.71 3291.60 71.58 o 3 3 1 5278.36 5067.58 151.83 o 4 3 1 25.68 11.10 8.35 o 5 3 1 2485.88 2486.48 62.36 o 6 3 1 1304.00 1242.84 40.72 o 7 3 1 0.84 -13.75 27.37 o 8 3 1 126.78 134.20 39.68 o 9 3 1 419.90 354.19 59.63 o -10 4 1 55.71 -25.11 89.46 o -9 4 1 50.42 15.09 41.11 o -8 4 1 1223.44 1207.53 54.73 o -7 4 1 557.09 584.06 29.85 o -6 4 1 188.01 201.85 28.40 o -5 4 1 5254.99 5744.13 142.09 o -4 4 1 12.94 23.70 9.27 o -3 4 1 990.22 1021.58 30.82 o -2 4 1 26734.67 27397.15 920.63 o -1 4 1 3933.89 4133.81 140.52 o 0 4 1 30.76 38.94 5.06 o 1 4 1 86.60 96.76 11.16 o 2 4 1 1800.72 1582.99 69.59 o 3 4 1 262.35 287.31 13.66 o 4 4 1 2982.93 3039.96 96.17 o 5 4 1 2214.32 2190.89 56.77 o 6 4 1 22.00 45.19 20.08 o 7 4 1 427.34 470.85 41.56 o 8 4 1 481.48 502.40 61.32 o 9 4 1 20.42 18.42 47.95 o -10 5 1 84.41 2.89 91.19 o -9 5 1 11.57 -46.35 45.80 o -8 5 1 59.22 137.03 39.60 o -7 5 1 769.71 785.98 36.97 o -6 5 1 758.76 739.18 34.26 o -5 5 1 115.18 135.65 15.98 o -4 5 1 619.50 590.19 23.02 o -3 5 1 5836.52 6108.35 151.43 o -2 5 1 1751.41 1845.05 75.65 o -1 5 1 2603.65 2502.99 59.88 o 0 5 1 13195.13 13046.92 890.53 o 1 5 1 2855.18 2598.53 102.46 o 2 5 1 52.51 53.75 7.14 o 3 5 1 5934.24 5741.51 151.24 o 4 5 1 0.58 33.59 9.24 o 5 5 1 302.48 280.77 30.15 o 6 5 1 983.54 934.02 42.81 o 7 5 1 61.87 96.98 46.18 o 8 5 1 183.28 237.02 55.39 o 9 5 1 210.38 152.97 53.70 o -10 6 1 79.48 3.17 96.96 o -9 6 1 19.61 -60.36 48.48 o -8 6 1 927.77 931.62 113.70 o -7 6 1 790.19 849.02 39.74 o -6 6 1 176.36 180.52 19.31 o -5 6 1 2340.81 2689.05 71.54 o -4 6 1 1668.92 1765.33 109.20 o -3 6 1 1414.94 1480.51 62.00 o -2 6 1 4372.82 4544.58 119.19 o -1 6 1 4626.89 4740.55 109.35 o 0 6 1 30.27 34.32 7.21 o 1 6 1 1888.81 1977.92 49.37 o 2 6 1 7.08 13.90 6.97 o 3 6 1 198.22 220.13 22.12 o 4 6 1 4496.87 4443.20 94.31 o 5 6 1 802.23 735.65 41.78 o 6 6 1 169.30 267.77 45.23 o 7 6 1 856.20 816.98 59.47 o 8 6 1 330.70 385.89 62.76 o 9 6 1 55.58 55.73 52.49 o -10 7 1 5.50 -84.02 56.02 o -9 7 1 18.44 -69.21 49.44 o -8 7 1 4.74 -4.11 44.68 o -7 7 1 28.18 69.97 32.03 o -6 7 1 0.25 -23.69 15.79 o -5 7 1 121.35 170.02 19.86 o -4 7 1 1603.76 1586.91 104.19 o -3 7 1 1013.33 1000.73 54.15 o -2 7 1 26.51 41.33 9.37 o -1 7 1 49.44 39.79 7.87 o 0 7 1 353.84 309.43 14.64 o 1 7 1 972.39 929.30 30.45 o 2 7 1 356.33 369.13 16.51 o 3 7 1 0.31 -12.71 8.47 o 4 7 1 338.20 394.48 87.33 o 5 7 1 35.53 53.02 22.09 o 6 7 1 98.17 132.02 40.83 o 7 7 1 38.70 86.97 49.63 o 8 7 1 4.26 21.43 50.24 o 9 7 1 42.73 89.48 57.06 o -10 8 1 161.56 71.57 74.16 o -9 8 1 83.09 -48.03 51.24 o -8 8 1 371.71 401.61 62.74 o -7 8 1 1207.08 1215.58 46.46 o -6 8 1 109.37 119.54 21.00 o -5 8 1 2230.41 2583.79 165.43 o -4 8 1 14.82 18.58 14.33 o -3 8 1 78.24 93.04 13.80 o -2 8 1 3541.61 3875.11 105.93 o -1 8 1 3381.97 3606.25 114.34 o 0 8 1 2.24 0.14 7.21 o 1 8 1 174.63 200.64 13.56 o 2 8 1 16.69 20.51 9.53 o 3 8 1 566.01 483.19 25.24 o 4 8 1 2166.78 2182.86 52.73 o 5 8 1 845.96 788.97 56.11 o 6 8 1 248.36 281.47 48.88 o 7 8 1 782.86 670.86 57.03 o 8 8 1 89.81 76.47 53.94 o 9 8 1 93.59 113.44 63.71 o -9 9 1 37.04 7.46 53.45 o -8 9 1 56.64 -6.32 47.91 o -7 9 1 9.23 -2.66 36.34 o -6 9 1 691.19 719.14 44.95 o -5 9 1 83.57 146.85 20.05 o -4 9 1 227.39 283.22 25.27 o -3 9 1 789.03 783.27 36.37 o -2 9 1 589.27 561.72 22.53 o -1 9 1 130.25 142.20 15.77 o 0 9 1 3941.40 4329.90 101.96 o 1 9 1 202.51 227.22 15.38 o 2 9 1 763.92 764.34 29.54 o 3 9 1 744.34 875.43 30.03 o 4 9 1 65.37 89.86 31.52 o 5 9 1 353.85 384.87 65.93 o 6 9 1 139.44 160.42 46.30 o 7 9 1 84.26 104.68 48.77 o 8 9 1 15.01 -36.56 52.18 o 9 9 1 41.94 43.86 78.78 o -9 10 1 17.56 -52.26 52.48 o -8 10 1 224.72 227.93 55.51 o -7 10 1 838.24 847.80 40.36 o -6 10 1 25.77 8.56 19.86 o -5 10 1 1446.37 1574.44 75.09 o -4 10 1 1246.51 1281.44 70.29 o -3 10 1 20.12 40.35 13.79 o -2 10 1 220.64 233.27 16.69 o -1 10 1 1376.27 1456.13 49.82 o 0 10 1 2028.03 2165.22 67.48 o 1 10 1 1693.75 1800.84 48.94 o 2 10 1 222.49 231.43 16.22 o 3 10 1 213.46 218.43 18.27 o 4 10 1 2099.59 2091.65 64.70 o 5 10 1 455.68 426.45 24.00 o 6 10 1 89.88 158.70 45.77 o 7 10 1 256.46 305.30 58.96 o 8 10 1 147.25 64.87 58.77 o -9 11 1 25.56 2.68 53.94 o -8 11 1 16.59 1.98 47.13 o -7 11 1 318.82 320.88 32.23 o -6 11 1 922.97 951.22 44.73 o -5 11 1 488.68 524.57 33.72 o -4 11 1 404.00 437.61 30.91 o -3 11 1 1274.63 1351.20 63.30 o -2 11 1 1013.50 1033.44 35.66 o -1 11 1 552.34 528.16 27.27 o 0 11 1 7249.83 7199.65 198.03 o 1 11 1 117.44 116.42 14.97 o 2 11 1 443.80 441.88 22.15 o 3 11 1 2165.20 2358.89 96.22 o 4 11 1 21.16 3.69 14.60 o 5 11 1 802.14 803.23 31.17 o 6 11 1 446.71 547.94 61.97 o 7 11 1 24.62 -16.70 48.30 o 8 11 1 51.68 -55.72 55.93 o -9 12 1 17.40 -21.20 54.60 o -8 12 1 212.38 208.20 59.57 o -7 12 1 257.20 299.53 34.62 o -6 12 1 0.19 -7.53 20.48 o -5 12 1 420.35 422.96 28.83 o -4 12 1 141.60 184.12 22.06 o -3 12 1 45.04 51.22 19.90 o -2 12 1 1688.60 1700.59 64.40 o -1 12 1 1206.04 1265.67 47.18 o 0 12 1 1378.68 1352.46 65.65 o 1 12 1 1467.54 1568.34 45.55 o 2 12 1 1699.76 1816.11 55.94 o 3 12 1 133.13 161.47 19.92 o 4 12 1 745.84 717.86 29.09 o 5 12 1 580.83 598.04 34.54 o 6 12 1 29.34 42.16 48.19 o 7 12 1 2.54 -69.38 46.25 o 8 12 1 69.09 -13.89 57.07 o -8 13 1 58.99 77.63 85.13 o -7 13 1 160.91 200.84 32.93 o -6 13 1 739.80 795.35 40.23 o -5 13 1 105.99 97.71 28.88 o -4 13 1 206.01 264.67 25.79 o -3 13 1 2036.99 2088.89 155.78 o -2 13 1 436.19 403.90 27.32 o -1 13 1 4091.62 3974.70 147.03 o 0 13 1 2062.14 1976.37 117.88 o 1 13 1 333.84 330.70 26.12 o 2 13 1 953.06 983.44 35.33 o 3 13 1 2087.36 2262.68 69.92 o 4 13 1 123.70 109.22 41.18 o 5 13 1 566.14 527.69 38.52 o 6 13 1 100.63 22.96 45.22 o 7 13 1 41.39 -8.63 63.77 o 8 13 1 46.82 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226.49 231.15 68.97 o -6 7 9 13.98 -22.87 35.10 o -5 7 9 1.83 -47.94 31.96 o -4 7 9 26.37 44.49 46.41 o -3 7 9 53.41 38.53 48.75 o -2 7 9 118.99 96.34 51.16 o -1 7 9 0.79 92.97 52.41 o -6 8 9 148.45 58.74 40.44 o -5 8 9 37.93 15.20 34.35 o -4 8 9 195.28 156.10 63.20 o -3 8 9 241.37 219.19 54.43 o -2 8 9 54.03 14.97 60.31 o -1 8 9 263.50 246.44 73.59 o -5 9 9 156.06 97.15 36.85 o -4 9 9 45.69 64.85 49.48 o -3 9 9 0.12 -44.22 46.93 o -2 9 9 1.15 77.63 72.43 o