#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/79/2227926.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_2227926_Fobs loop_ _publ_author_name 'Wan, Chong-Qing' 'Xiao, Nai-You' 'Wang, Zi-Jia' _publ_section_title ; Poly[hexa-\m-acetato-bis(dimethyl sulfoxide)trimanganese(II)] ; _journal_coeditor_code PV2332 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m1478 _journal_volume 66 _journal_year 2010 _space_group_IT_number 5 _symmetry_space_group_name_Hall 'C 2y' _symmetry_space_group_name_H-M 'C 1 2 1' _cell_angle_alpha 90.000 _cell_angle_beta 94.906 _cell_angle_gamma 90.000 _cell_length_a 12.8475 _cell_length_b 12.5439 _cell_length_c 8.6095 _exptl_crystal_F_000 690.00 _reflns_d_resolution_high 0.8378 _[local]_cod_data_source_file pv2332Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' I in C2' _shelx_refln_list_code 4 _shelx_f_calc_maximum 221.58 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 5 -7 0 1334.76 1401.91 48.45 o 11 -7 0 710.84 734.54 37.86 o 13 -7 0 188.70 205.04 19.22 o 4 -6 0 2050.52 2125.82 68.88 o 6 -6 0 2188.42 2290.62 80.92 o 8 -6 0 2132.62 1913.59 80.97 o 12 -6 0 1243.52 1392.49 64.71 o 5 -5 0 2353.52 2254.89 57.16 o 7 -5 0 8513.70 8187.66 352.03 o 9 -5 0 746.17 735.07 22.27 o 11 -5 0 237.96 234.51 18.35 o 13 -5 0 308.20 328.73 24.17 o 4 -4 0 5624.99 5748.94 140.25 o 6 -4 0 7967.75 7639.45 187.73 o 8 -4 0 2409.43 2439.57 64.61 o 10 -4 0 227.41 230.08 10.46 o 12 -4 0 1311.59 1214.58 57.96 o 14 -4 0 62.82 82.38 14.13 o 5 -3 0 7559.57 7658.92 190.03 o 7 -3 0 13532.30 13365.47 317.97 o 9 -3 0 787.44 757.23 23.94 o 11 -3 0 462.88 418.11 16.48 o 13 -3 0 490.55 452.95 29.90 o 2 -2 0 1986.72 1995.71 51.16 o 4 -2 0 3312.75 3489.21 81.49 o 6 -2 0 9419.29 9159.69 273.93 o 8 -2 0 6708.87 6835.56 266.47 o 10 -2 0 47.67 53.60 5.20 o 12 -2 0 1355.77 1328.52 46.41 o 14 -2 0 146.88 138.78 15.82 o 3 -1 0 13577.43 14088.31 353.46 o 5 -1 0 12200.68 12634.14 294.96 o 7 -1 0 306.86 317.46 11.74 o 9 -1 0 1553.67 1450.02 57.55 o 11 -1 0 1201.86 1140.90 34.97 o 13 -1 0 1151.64 1159.55 36.58 o 15 -1 0 107.84 115.73 16.02 o 2 0 0 4018.79 4402.11 82.65 o 4 0 0 101.89 80.23 4.49 o 6 0 0 7784.38 8281.81 154.88 o 8 0 0 427.80 399.01 9.93 o 10 0 0 1291.73 1213.95 35.70 o 12 0 0 1803.57 1829.44 52.13 o 14 0 0 1109.22 1128.63 38.64 o 3 1 0 14260.14 14752.20 270.01 o 5 1 0 11507.16 11710.12 224.13 o 7 1 0 357.01 354.29 8.86 o 9 1 0 1478.36 1341.21 28.86 o 11 1 0 1222.44 1204.05 35.66 o 13 1 0 1169.65 1191.90 37.06 o 15 1 0 110.53 116.65 9.60 o 0 2 0 10758.07 10694.07 236.71 o 2 2 0 1778.86 1754.02 33.06 o 4 2 0 2930.22 3103.65 58.53 o 6 2 0 9471.57 9251.08 172.64 o 8 2 0 6819.65 6849.89 129.36 o 10 2 0 57.92 62.07 5.17 o 12 2 0 1342.65 1277.35 53.59 o 14 2 0 168.88 165.24 10.84 o 1 3 0 2755.45 2995.67 47.22 o 3 3 0 184.32 176.90 4.07 o 5 3 0 7719.59 7800.99 121.78 o 7 3 0 13366.33 12722.79 242.13 o 9 3 0 833.71 809.56 18.56 o 11 3 0 477.02 487.18 27.89 o 13 3 0 506.25 485.75 19.75 o 0 4 0 346.00 431.21 65.58 o 2 4 0 959.30 975.05 16.43 o 4 4 0 5586.34 5674.14 89.80 o 6 4 0 7797.32 7611.24 120.12 o 8 4 0 2380.25 2501.73 49.82 o 10 4 0 235.80 234.98 8.39 o 12 4 0 1264.38 1268.38 39.00 o 14 4 0 71.24 77.74 8.53 o 1 5 0 6161.84 6068.01 94.95 o 3 5 0 630.98 604.30 11.10 o 5 5 0 2206.06 2210.24 36.68 o 7 5 0 8646.71 8407.41 157.37 o 9 5 0 723.59 678.03 17.43 o 11 5 0 217.07 200.76 8.27 o 13 5 0 293.69 315.77 23.25 o 0 6 0 7612.71 8818.41 193.61 o 2 6 0 8172.47 7984.51 124.32 o 4 6 0 1969.02 1922.10 36.74 o 6 6 0 2240.44 2333.03 38.79 o 8 6 0 2110.69 2050.13 42.03 o 10 6 0 110.50 97.19 5.72 o 12 6 0 1256.00 1397.17 32.15 o 1 7 0 7079.72 7037.08 110.39 o 3 7 0 441.07 426.73 8.98 o 5 7 0 1321.26 1339.98 23.74 o 7 7 0 995.55 996.92 23.01 o 9 7 0 224.11 223.18 8.57 o 11 7 0 627.20 643.22 19.25 o 13 7 0 174.35 160.35 14.00 o 0 8 0 6449.25 6775.07 150.91 o 2 8 0 812.81 794.91 15.09 o 4 8 0 789.98 784.17 14.99 o 6 8 0 1134.00 1074.80 19.99 o 8 8 0 96.55 98.91 5.67 o 10 8 0 1848.25 1870.64 41.01 o 12 8 0 445.78 466.40 14.89 o 1 9 0 1719.14 1745.79 30.01 o 3 9 0 545.09 551.22 11.59 o 5 9 0 1167.64 1098.91 20.67 o 7 9 0 630.40 628.66 16.76 o 9 9 0 453.46 432.76 17.18 o 11 9 0 880.53 843.15 35.44 o 0 10 0 731.88 672.52 19.66 o 2 10 0 504.68 462.60 10.54 o 4 10 0 48.26 65.43 4.57 o 6 10 0 853.53 792.29 24.12 o 8 10 0 402.47 411.01 15.88 o 10 10 0 155.49 145.64 9.39 o 1 11 0 32.96 31.54 2.89 o 3 11 0 17.59 22.30 3.15 o 5 11 0 1855.69 1819.00 47.20 o 7 11 0 458.24 471.18 30.99 o 9 11 0 231.13 213.80 11.50 o 0 12 0 963.78 1011.90 28.27 o 2 12 0 27.53 26.48 3.74 o 4 12 0 724.83 724.14 17.90 o 6 12 0 373.69 394.52 15.80 o 8 12 0 191.53 192.54 14.95 o 1 13 0 452.99 461.18 13.31 o 3 13 0 491.34 508.04 14.38 o 5 13 0 60.33 62.36 7.21 o 7 13 0 103.05 122.06 9.23 o 0 14 0 105.27 101.94 10.82 o 2 14 0 414.29 451.88 16.22 o 4 14 0 73.05 73.07 7.48 o -5 -9 1 343.41 357.08 17.82 o -6 -8 1 1039.61 1021.28 42.47 o 10 -8 1 632.45 596.05 33.93 o 12 -8 1 36.67 40.48 10.00 o -7 -7 1 350.23 323.24 15.19 o -5 -7 1 4442.29 4239.16 145.04 o 7 -7 1 2463.22 2522.36 93.54 o 9 -7 1 1261.41 1291.71 58.78 o 11 -7 1 658.76 661.59 37.23 o 13 -7 1 126.31 149.80 17.23 o -8 -6 1 369.77 413.24 19.32 o -6 -6 1 5978.71 5933.01 208.39 o -4 -6 1 3368.99 3185.99 109.12 o 6 -6 1 908.76 874.78 35.19 o 8 -6 1 2077.03 2043.83 84.76 o 10 -6 1 307.01 344.80 23.88 o 12 -6 1 200.83 194.17 17.72 o -13 -5 1 101.87 101.02 14.27 o -11 -5 1 2747.00 2654.45 111.70 o -9 -5 1 143.53 133.97 7.45 o -7 -5 1 281.74 273.97 14.22 o -5 -5 1 1939.65 1843.01 69.71 o 3 -5 1 13088.62 13458.78 318.28 o 5 -5 1 1201.24 1194.19 30.30 o 7 -5 1 1166.04 1074.44 29.70 o 9 -5 1 98.49 97.42 11.84 o 11 -5 1 294.94 315.04 21.60 o 13 -5 1 1017.44 946.29 49.51 o -14 -4 1 195.17 224.85 20.68 o -12 -4 1 1091.33 1084.19 33.79 o -10 -4 1 2123.80 2024.49 120.00 o -8 -4 1 3624.30 3655.40 125.17 o -6 -4 1 1560.66 1424.36 38.34 o -4 -4 1 989.32 1084.68 40.92 o 2 -4 1 18417.05 17024.38 616.88 o 4 -4 1 2507.02 2634.30 67.02 o 6 -4 1 1114.03 1131.60 30.83 o 8 -4 1 1228.96 1259.05 32.35 o 10 -4 1 529.25 575.13 30.87 o 12 -4 1 639.69 596.83 33.59 o 14 -4 1 650.79 601.88 36.94 o -15 -3 1 13.56 14.47 8.20 o -13 -3 1 261.31 251.00 12.88 o -11 -3 1 4158.45 4278.54 106.81 o -9 -3 1 1940.63 1951.01 91.21 o -7 -3 1 1751.13 1584.28 44.36 o -5 -3 1 2385.07 2500.66 64.83 o 1 -3 1 28733.67 27377.76 1017.45 o 3 -3 1 390.66 299.40 12.96 o 5 -3 1 3414.76 3540.41 91.44 o 7 -3 1 850.73 794.67 23.98 o 9 -3 1 320.19 300.81 14.51 o 11 -3 1 331.50 317.47 21.26 o 13 -3 1 1717.40 1678.06 75.19 o -14 -2 1 60.24 67.06 7.72 o -12 -2 1 947.40 956.28 34.08 o -10 -2 1 2499.28 2314.53 71.21 o -8 -2 1 782.84 800.27 23.21 o -6 -2 1 9342.09 9929.65 244.73 o -4 -2 1 9364.25 9816.76 250.30 o -2 -2 1 3817.67 4112.27 129.75 o 4 -2 1 4906.70 4848.59 119.64 o 6 -2 1 1873.06 1873.10 51.44 o 8 -2 1 3114.37 3089.94 75.73 o 10 -2 1 82.39 76.88 7.55 o 12 -2 1 721.60 714.98 36.55 o 14 -2 1 277.09 286.89 22.86 o -15 -1 1 490.79 517.43 21.46 o -13 -1 1 348.93 346.49 15.49 o -11 -1 1 324.01 366.78 14.65 o -9 -1 1 1862.68 1839.11 75.12 o -7 -1 1 3166.03 3284.02 87.73 o -5 -1 1 15428.20 15063.36 381.11 o -3 -1 1 14162.57 14540.32 351.50 o -1 -1 1 5062.58 5780.58 196.01 o 1 -1 1 15929.27 15701.45 395.90 o 3 -1 1 1150.80 1173.97 23.92 o 5 -1 1 3790.55 3736.78 92.22 o 7 -1 1 4153.93 4018.33 98.68 o 9 -1 1 3558.95 3474.23 91.68 o 11 -1 1 320.33 305.70 13.21 o 13 -1 1 74.21 68.34 7.08 o 15 -1 1 137.83 134.17 16.80 o -14 0 1 340.83 362.04 16.60 o -12 0 1 609.43 599.14 21.67 o -10 0 1 95.14 88.77 6.73 o -8 0 1 847.04 811.75 21.07 o -6 0 1 7901.64 8135.03 151.85 o -4 0 1 13132.01 13330.63 274.30 o -2 0 1 2760.45 2932.22 55.54 o 0 0 1 911.05 865.75 30.58 o 2 0 1 39.60 38.00 1.54 o 4 0 1 3373.14 3655.73 90.94 o 6 0 1 11817.50 11509.64 214.16 o 8 0 1 1286.39 1417.57 28.78 o 10 0 1 1851.64 1797.09 49.96 o 12 0 1 120.14 144.08 10.44 o 14 0 1 178.55 198.86 11.94 o -15 1 1 501.83 516.27 25.41 o -13 1 1 320.49 340.55 15.68 o -11 1 1 309.22 325.60 14.25 o -9 1 1 1918.89 1871.28 37.99 o -7 1 1 3298.15 3560.40 66.80 o -5 1 1 16010.50 16149.62 352.68 o -3 1 1 14254.83 14343.04 269.46 o -1 1 1 5134.06 5780.27 107.02 o 1 1 1 16122.33 16008.30 278.61 o 3 1 1 1325.06 1344.04 36.65 o 5 1 1 3553.24 3655.36 70.15 o 7 1 1 4058.75 3813.87 74.63 o 9 1 1 3616.98 3638.08 69.36 o 11 1 1 291.91 298.14 13.46 o 13 1 1 56.27 55.24 6.68 o 15 1 1 145.59 166.12 11.48 o -14 2 1 68.90 80.18 8.17 o -12 2 1 918.45 931.83 31.29 o -10 2 1 2456.69 2368.15 47.70 o -8 2 1 674.29 712.97 17.14 o -6 2 1 9598.05 10020.00 186.43 o -4 2 1 9886.15 10580.14 191.09 o -2 2 1 3480.13 3689.29 71.45 o 0 2 1 2256.05 2554.45 40.19 o 2 2 1 1158.50 1322.37 24.02 o 4 2 1 5025.14 4818.62 178.59 o 6 2 1 2071.67 2085.55 39.68 o 8 2 1 2913.51 2827.53 57.26 o 10 2 1 89.19 83.23 6.82 o 12 2 1 671.09 634.91 23.45 o 14 2 1 269.76 304.19 19.37 o -15 3 1 19.42 18.98 5.59 o -13 3 1 268.45 257.84 15.29 o -11 3 1 4049.82 3985.01 80.59 o -9 3 1 1924.92 1855.25 39.11 o -7 3 1 1771.41 1695.13 28.01 o -5 3 1 2413.19 2512.74 40.74 o -3 3 1 84.12 88.51 2.66 o -1 3 1 24530.23 24758.92 352.92 o 1 3 1 29957.68 29142.22 447.28 o 3 3 1 340.30 277.82 7.75 o 5 3 1 3432.86 3776.56 76.82 o 7 3 1 949.96 884.86 21.57 o 9 3 1 269.47 269.92 8.69 o 11 3 1 290.10 282.40 13.34 o 13 3 1 1629.40 1701.40 50.52 o -14 4 1 190.91 212.32 12.93 o -12 4 1 1111.19 1085.30 37.81 o -10 4 1 2161.15 2043.00 69.37 o -8 4 1 3723.66 3689.08 71.77 o -6 4 1 1444.60 1410.98 24.15 o -4 4 1 1082.02 1145.45 19.41 o -2 4 1 7446.99 7545.65 107.18 o 0 4 1 3616.33 3569.79 56.19 o 2 4 1 18712.55 17647.70 269.90 o 4 4 1 2600.29 2713.19 48.26 o 6 4 1 1123.88 1157.24 24.57 o 8 4 1 1106.90 1057.62 31.25 o 10 4 1 552.15 548.38 14.77 o 12 4 1 604.89 572.09 22.12 o 14 4 1 645.09 623.05 24.29 o -13 5 1 92.27 86.04 8.49 o -11 5 1 2851.96 2840.42 57.34 o -9 5 1 117.12 109.26 5.55 o -7 5 1 330.82 311.21 7.10 o -5 5 1 2059.11 2021.14 33.06 o -3 5 1 8054.34 8415.93 119.63 o -1 5 1 5036.08 5439.85 85.31 o 1 5 1 10335.69 10820.65 167.41 o 3 5 1 12716.06 12831.10 257.04 o 5 5 1 1097.24 1094.17 21.97 o 7 5 1 1119.41 1075.54 23.91 o 9 5 1 141.49 135.12 6.07 o 11 5 1 265.93 263.39 12.32 o 13 5 1 1019.06 1007.33 33.53 o -14 6 1 147.86 142.55 10.76 o -12 6 1 229.75 222.26 9.29 o -10 6 1 595.23 573.96 15.84 o -8 6 1 427.77 433.81 12.22 o -6 6 1 6043.94 6164.18 137.87 o -4 6 1 3258.80 3140.58 51.18 o -2 6 1 5765.69 6254.46 97.93 o 0 6 1 5940.61 6299.15 98.85 o 2 6 1 8454.55 8635.30 143.63 o 4 6 1 111.63 89.82 3.75 o 6 6 1 746.08 727.32 14.25 o 8 6 1 2156.45 2160.70 44.25 o 10 6 1 379.37 400.42 12.10 o 12 6 1 171.90 154.30 10.53 o -13 7 1 166.27 171.80 11.77 o -11 7 1 474.08 515.91 15.24 o -9 7 1 142.95 138.50 6.75 o -7 7 1 331.04 291.73 9.51 o -5 7 1 4351.09 4201.64 68.16 o -3 7 1 5312.38 5486.40 79.47 o -1 7 1 660.21 610.29 11.87 o 1 7 1 3477.38 3441.87 55.31 o 3 7 1 1944.15 1954.73 32.47 o 5 7 1 807.27 816.20 17.33 o 7 7 1 2338.38 2323.34 48.62 o 9 7 1 1317.23 1349.13 30.36 o 11 7 1 672.38 696.77 18.79 o 13 7 1 148.71 167.93 11.37 o -12 8 1 105.63 115.80 8.34 o -10 8 1 400.00 398.29 12.86 o -8 8 1 678.97 651.44 18.12 o -6 8 1 1253.50 1173.54 21.10 o -4 8 1 3365.06 3091.59 46.10 o -2 8 1 1040.96 1038.12 18.93 o 0 8 1 278.14 248.03 6.39 o 2 8 1 408.45 366.42 8.22 o 4 8 1 598.97 642.15 14.74 o 6 8 1 3078.89 2922.96 69.81 o 8 8 1 970.84 930.33 22.63 o 10 8 1 658.07 633.80 17.56 o 12 8 1 29.84 31.55 4.57 o -11 9 1 602.15 626.03 21.66 o -9 9 1 1369.35 1351.77 37.18 o -7 9 1 1043.96 1017.69 28.83 o -5 9 1 422.67 405.05 10.72 o -3 9 1 248.68 256.40 6.91 o -1 9 1 601.61 589.22 12.27 o 1 9 1 1053.42 1068.18 19.60 o 3 9 1 831.39 785.88 17.64 o 5 9 1 1227.30 1231.49 25.59 o 7 9 1 395.92 395.07 12.35 o 9 9 1 874.17 854.93 22.05 o 11 9 1 107.78 114.61 7.01 o -10 10 1 1221.85 1203.92 40.29 o -8 10 1 929.63 941.54 28.23 o -6 10 1 468.98 500.10 17.29 o -4 10 1 1149.39 1084.91 20.57 o -2 10 1 315.46 315.20 8.14 o 0 10 1 675.72 661.55 13.72 o 2 10 1 569.49 529.46 13.46 o 4 10 1 1628.42 1675.86 33.76 o 6 10 1 393.49 397.12 14.98 o 8 10 1 245.61 235.45 9.63 o 10 10 1 140.01 148.98 8.85 o -9 11 1 905.42 936.20 29.11 o -7 11 1 191.34 194.05 10.51 o -5 11 1 260.59 284.72 9.40 o -3 11 1 169.11 160.35 5.81 o -1 11 1 959.53 1010.18 19.67 o 1 11 1 1533.79 1593.96 32.57 o 3 11 1 687.69 680.32 16.70 o 5 11 1 188.55 208.31 10.56 o 7 11 1 53.99 56.79 6.21 o 9 11 1 303.80 297.60 13.93 o -8 12 1 309.50 350.00 15.17 o -6 12 1 22.67 20.63 4.41 o -4 12 1 879.57 872.22 20.63 o -2 12 1 280.56 283.34 9.51 o 0 12 1 746.94 743.84 25.94 o 2 12 1 1644.58 1680.55 34.82 o 4 12 1 402.90 418.83 16.21 o 6 12 1 261.76 269.59 12.88 o 8 12 1 236.81 252.38 16.92 o -7 13 1 195.79 213.99 11.76 o -5 13 1 365.53 379.11 24.42 o -3 13 1 531.77 554.84 18.96 o -1 13 1 294.66 300.99 12.22 o 1 13 1 415.18 384.97 11.94 o 3 13 1 578.95 587.66 16.27 o 5 13 1 57.96 59.56 7.33 o 7 13 1 300.01 318.79 16.67 o -4 14 1 423.03 416.06 16.76 o -2 14 1 156.56 165.86 9.22 o 0 14 1 68.23 72.87 6.51 o 2 14 1 101.51 109.72 6.43 o 4 14 1 84.10 99.35 16.46 o -6 -10 2 5.59 1.70 3.35 o -7 -9 2 113.17 122.91 9.71 o -5 -9 2 1480.61 1522.68 59.85 o 11 -9 2 168.33 159.17 16.41 o -8 -8 2 1463.56 1480.45 54.37 o -6 -8 2 831.09 798.81 32.38 o 8 -8 2 520.75 566.44 30.05 o 10 -8 2 283.25 300.77 21.55 o 12 -8 2 325.15 332.22 25.14 o -9 -7 2 787.46 782.70 33.45 o -7 -7 2 1931.09 1898.45 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626.00 30.14 o 2 0 9 296.99 310.43 18.25 o 4 0 9 70.57 61.84 7.77 o -7 1 9 70.85 81.26 11.50 o -5 1 9 599.57 572.80 29.81 o -3 1 9 1538.78 1547.05 61.84 o -1 1 9 488.04 552.07 27.62 o 1 1 9 220.08 226.01 15.10 o 3 1 9 23.22 8.49 4.42 o 5 1 9 143.80 150.97 11.41 o -8 2 9 587.58 615.66 32.57 o -6 2 9 150.36 154.90 14.08 o -4 2 9 1235.72 1277.73 53.79 o -2 2 9 563.13 590.23 29.56 o 0 2 9 3.26 1.84 3.83 o 2 2 9 709.01 663.14 28.30 o 4 2 9 214.60 184.85 9.86 o -7 3 9 635.32 648.19 33.83 o -5 3 9 439.23 451.01 25.24 o -3 3 9 300.43 297.95 18.59 o -1 3 9 80.05 63.74 8.40 o 1 3 9 216.97 208.78 14.03 o 3 3 9 921.16 845.22 28.59 o 5 3 9 500.00 498.54 21.87 o -6 4 9 102.20 90.58 11.41 o -4 4 9 51.58 53.11 8.40 o -2 4 9 486.44 482.51 23.11 o 0 4 9 566.28 563.38 26.50 o 2 4 9 567.10 537.77 19.22 o 4 4 9 1053.15 1007.24 34.85 o -5 5 9 299.44 320.30 13.63 o -3 5 9 305.94 304.56 17.43 o -1 5 9 324.46 363.78 19.27 o 1 5 9 394.80 419.78 16.56 o 3 5 9 1203.54 1177.77 34.25 o -4 6 9 291.40 275.96 16.94 o 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