#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/85/2228510.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_2228510_Fobs loop_ _publ_author_name 'Steyl, Gideon' 'Muller, Theunis J.' 'Roodt, Andreas' _publ_section_title ; Bis[2-(methylamino)troponato]copper(II) ; _journal_coeditor_code PK2271 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m1508 _journal_volume 66 _journal_year 2010 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 92.108 _cell_angle_gamma 90.000 _cell_length_a 6.7541 _cell_length_b 9.1599 _cell_length_c 22.0840 _exptl_crystal_F_000 684.00 _reflns_d_resolution_high 0.7828 _[local]_cod_data_source_file pk2271Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 6Lgs31_0m in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 217.20 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 732.69 628.66 8.88 o 4 0 0 367.06 248.14 6.12 o 6 0 0 4058.23 3950.93 86.14 o 8 0 0 1558.95 1666.19 56.23 o 1 1 0 7518.53 7843.37 62.28 o 2 1 0 2381.16 2452.83 22.27 o 3 1 0 822.00 727.00 8.19 o 4 1 0 46.60 67.03 2.09 o 5 1 0 1847.04 1818.27 32.78 o 6 1 0 14.10 20.18 3.08 o 7 1 0 1940.30 1967.78 34.45 o 8 1 0 88.86 82.22 6.50 o 1 2 0 4.63 1.94 0.78 o 2 2 0 215.39 223.61 3.58 o 3 2 0 274.45 302.18 4.72 o 4 2 0 241.30 233.54 4.46 o 5 2 0 89.93 81.11 3.10 o 6 2 0 267.26 261.05 6.95 o 7 2 0 110.04 104.07 6.45 o 8 2 0 12.63 7.17 4.64 o 1 3 0 4804.01 4904.00 54.15 o 2 3 0 101.33 127.62 2.73 o 3 3 0 2537.19 2494.14 29.48 o 4 3 0 77.55 91.09 2.95 o 5 3 0 819.26 806.96 12.19 o 6 3 0 154.36 141.48 5.01 o 7 3 0 1428.42 1401.65 28.71 o 8 3 0 51.05 52.99 7.61 o 0 4 0 96.04 42.04 6.11 o 1 4 0 1260.06 1398.66 20.42 o 2 4 0 5412.82 5409.65 77.64 o 3 4 0 2299.71 2486.92 34.19 o 4 4 0 1895.59 1828.49 23.01 o 5 4 0 1617.78 1561.37 24.49 o 6 4 0 2422.05 2364.45 39.44 o 7 4 0 161.35 140.63 9.29 o 8 4 0 2802.35 2764.90 58.18 o 1 5 0 6338.00 6585.04 87.30 o 2 5 0 797.92 882.65 17.12 o 3 5 0 2571.71 2599.81 33.38 o 4 5 0 756.98 764.61 14.06 o 5 5 0 2232.04 2124.35 42.79 o 6 5 0 191.95 183.50 9.31 o 7 5 0 1211.04 1172.15 29.11 o 0 6 0 486.39 497.94 26.63 o 1 6 0 20.67 17.29 2.17 o 2 6 0 127.07 122.20 4.10 o 3 6 0 5.28 9.35 1.93 o 4 6 0 21.10 20.08 3.52 o 5 6 0 4.77 4.76 3.58 o 6 6 0 59.09 55.92 6.22 o 7 6 0 94.82 96.12 8.21 o 1 7 0 478.41 449.28 13.79 o 2 7 0 483.22 506.48 11.33 o 3 7 0 816.96 819.46 17.17 o 4 7 0 181.06 186.08 7.55 o 5 7 0 333.66 321.03 11.48 o 6 7 0 8.05 -1.60 4.98 o 0 8 0 1546.30 1473.07 64.80 o 1 8 0 5.54 2.48 3.02 o 2 8 0 3218.41 3131.95 69.79 o 3 8 0 296.93 301.62 8.98 o 4 8 0 4777.33 4601.74 84.33 o 5 8 0 37.32 40.31 5.81 o 6 8 0 549.05 528.40 16.70 o 1 9 0 755.71 764.18 29.64 o 2 9 0 3.52 6.20 4.78 o 3 9 0 1933.01 1899.82 57.26 o 4 9 0 381.90 378.32 15.07 o 5 9 0 944.86 960.71 23.39 o 0 10 0 191.69 177.04 20.90 o 1 10 0 9.28 9.88 7.14 o 2 10 0 301.48 304.40 26.44 o 3 10 0 27.80 28.39 8.30 o 4 10 0 184.89 179.73 20.83 o 1 11 0 63.50 67.38 11.73 o 2 11 0 257.59 304.68 29.44 o -7 0 1 1585.57 1650.44 42.37 o -5 0 1 14208.88 14452.97 290.10 o -3 0 1 588.90 1004.89 16.53 o -1 0 1 41942.65 31636.69 489.51 o 1 0 1 28526.49 24489.72 382.61 o 3 0 1 2008.59 1843.71 24.36 o 5 0 1 1966.40 1910.25 30.85 o 7 0 1 1505.02 1526.50 39.82 o -8 1 1 535.74 575.67 15.33 o -7 1 1 16.72 17.62 4.13 o -6 1 1 1388.55 1394.66 21.51 o -5 1 1 130.33 123.78 3.35 o -4 1 1 368.57 313.52 5.01 o -3 1 1 833.33 886.04 10.96 o -2 1 1 1151.15 1079.84 11.08 o -1 1 1 4.33 5.12 0.46 o 0 1 1 7429.49 7187.95 220.20 o 1 1 1 2460.21 2668.07 21.38 o 2 1 1 11915.22 11883.25 107.12 o 3 1 1 2098.34 2216.73 20.64 o 4 1 1 1641.81 1726.92 18.18 o 5 1 1 1506.19 1511.21 26.26 o 6 1 1 1460.29 1398.01 23.17 o 7 1 1 858.33 856.76 18.59 o 8 1 1 502.32 500.83 14.19 o -8 2 1 123.24 114.45 8.04 o -7 2 1 66.84 66.68 5.60 o -6 2 1 124.64 115.99 4.69 o -5 2 1 27.11 27.48 2.29 o -4 2 1 343.39 334.26 7.03 o -3 2 1 94.26 94.36 2.07 o -2 2 1 1642.85 1695.78 17.59 o -1 2 1 228.00 246.34 3.89 o 0 2 1 66.17 76.72 1.51 o 1 2 1 117.35 123.32 1.94 o 2 2 1 2412.86 2440.44 25.14 o 3 2 1 136.74 150.07 2.91 o 4 2 1 1413.89 1402.28 15.67 o 5 2 1 1064.16 1111.46 14.12 o 6 2 1 1371.60 1371.81 21.17 o 7 2 1 8.20 13.24 4.00 o 8 2 1 203.16 202.10 10.01 o -8 3 1 838.73 807.21 24.98 o -7 3 1 72.26 75.53 6.31 o -6 3 1 1643.68 1603.88 29.02 o -5 3 1 220.65 212.24 4.89 o -4 3 1 4356.34 4352.54 59.54 o -3 3 1 1224.86 1294.25 16.34 o -2 3 1 2033.88 2063.17 23.83 o -1 3 1 2844.40 2924.86 34.71 o 0 3 1 611.15 604.11 10.82 o 1 3 1 1015.88 1020.48 11.91 o 2 3 1 1970.37 2012.49 21.34 o 3 3 1 1339.25 1324.08 16.64 o 4 3 1 2001.53 2085.70 23.60 o 5 3 1 77.07 72.52 3.99 o 6 3 1 464.10 432.03 9.09 o 7 3 1 314.60 330.49 11.60 o 8 3 1 9.89 11.24 5.77 o -8 4 1 504.43 485.16 17.58 o -7 4 1 2881.62 2793.66 57.05 o -6 4 1 364.92 318.65 9.55 o -5 4 1 1074.40 1116.71 18.67 o -4 4 1 12.27 3.18 1.82 o -3 4 1 4561.29 4430.48 48.79 o -2 4 1 189.41 172.46 4.56 o -1 4 1 1726.07 1573.88 25.13 o 0 4 1 85.63 98.14 2.97 o 1 4 1 8791.42 9035.31 99.09 o 2 4 1 524.34 613.80 9.90 o 3 4 1 3939.26 3936.59 57.12 o 4 4 1 239.83 229.56 5.26 o 5 4 1 608.87 594.96 10.91 o 6 4 1 25.39 22.54 3.64 o 7 4 1 2350.35 2270.43 60.92 o 8 4 1 39.61 31.78 6.81 o -7 5 1 168.20 170.33 12.62 o -6 5 1 1889.06 1790.38 38.58 o -5 5 1 1189.51 1161.96 26.29 o -4 5 1 2234.03 2219.22 36.74 o -3 5 1 304.82 346.87 5.89 o -2 5 1 5863.87 6066.47 95.80 o -1 5 1 19.40 21.53 1.91 o 0 5 1 6321.36 6586.46 105.17 o 1 5 1 3802.15 4267.07 49.22 o 2 5 1 2462.12 2522.30 36.20 o 3 5 1 136.87 139.73 3.97 o 4 5 1 99.01 102.86 4.43 o 5 5 1 7.06 3.66 3.39 o 6 5 1 1618.06 1515.49 33.72 o 7 5 1 68.89 65.64 7.17 o -7 6 1 3.82 3.91 5.19 o -6 6 1 47.55 47.11 7.60 o -5 6 1 245.85 221.45 9.41 o -4 6 1 276.80 275.31 8.78 o -3 6 1 331.49 334.47 6.80 o -2 6 1 217.44 218.77 5.25 o -1 6 1 1.41 4.75 1.15 o 0 6 1 2023.40 2128.14 48.44 o 1 6 1 802.15 830.83 17.68 o 2 6 1 1568.65 1572.69 25.45 o 3 6 1 41.20 35.67 2.67 o 4 6 1 178.46 185.68 8.48 o 5 6 1 74.57 63.29 5.68 o 6 6 1 427.50 418.01 14.23 o 7 6 1 235.24 239.43 11.74 o -6 7 1 55.13 41.43 5.86 o -5 7 1 17.30 14.27 4.30 o -4 7 1 242.80 245.64 7.07 o -3 7 1 1.95 1.69 2.20 o -2 7 1 189.08 180.90 7.55 o -1 7 1 349.32 340.68 12.57 o 0 7 1 2233.10 2339.01 59.20 o 1 7 1 598.65 629.07 17.58 o 2 7 1 98.60 102.74 4.02 o 3 7 1 1358.40 1386.56 26.43 o 4 7 1 553.85 546.83 14.63 o 5 7 1 511.68 508.34 15.04 o 6 7 1 207.97 209.40 10.23 o -6 8 1 213.09 203.22 10.27 o -5 8 1 1419.40 1334.84 29.85 o -4 8 1 74.07 69.11 5.31 o -3 8 1 2205.14 2206.37 42.01 o -2 8 1 969.06 986.46 25.64 o -1 8 1 4739.17 4699.82 132.98 o 0 8 1 872.21 873.97 30.92 o 1 8 1 918.36 886.11 23.64 o 2 8 1 294.63 323.17 10.55 o 3 8 1 1494.44 1481.01 29.63 o 4 8 1 0.34 -4.04 3.21 o 5 8 1 1274.62 1286.74 29.08 o 6 8 1 97.07 97.48 9.78 o -5 9 1 10.98 7.72 4.25 o -4 9 1 1334.60 1351.75 35.44 o -3 9 1 478.58 463.03 20.54 o -2 9 1 1973.53 2046.45 81.19 o -1 9 1 6.39 4.54 6.05 o 0 9 1 330.72 314.41 17.55 o 1 9 1 138.31 139.50 10.40 o 2 9 1 683.06 712.28 25.65 o 3 9 1 21.53 15.00 6.31 o 4 9 1 2165.75 2251.82 53.86 o 5 9 1 160.87 152.69 8.33 o -4 10 1 11.94 12.65 7.77 o -3 10 1 152.12 158.09 12.16 o -2 10 1 149.70 111.23 17.61 o -1 10 1 68.38 72.13 20.92 o 0 10 1 220.24 178.06 14.69 o 1 10 1 668.79 704.02 29.59 o 2 10 1 178.41 175.03 21.28 o 3 10 1 319.37 307.88 27.56 o 4 10 1 230.00 247.58 16.70 o -2 11 1 178.40 197.46 24.62 o -1 11 1 47.20 43.78 11.55 o 0 11 1 334.97 343.19 31.40 o 1 11 1 496.40 481.15 29.08 o 2 11 1 60.52 63.85 16.89 o -8 0 2 650.91 705.43 24.51 o -6 0 2 5015.86 5076.88 108.21 o -4 0 2 193.69 108.59 5.30 o -2 0 2 331.00 270.53 5.24 o 2 0 2 6720.01 6699.85 88.89 o 4 0 2 756.93 766.05 12.69 o 6 0 2 739.89 716.32 21.87 o 8 0 2 250.37 251.30 14.28 o -8 1 2 70.02 84.77 6.65 o -7 1 2 242.96 258.27 9.33 o -6 1 2 574.96 548.24 10.83 o -5 1 2 919.28 889.10 11.86 o -4 1 2 190.92 183.13 3.39 o -3 1 2 3282.47 3379.71 34.46 o -2 1 2 2628.26 2723.68 29.47 o -1 1 2 1402.52 1456.00 20.43 o 0 1 2 485.74 478.51 9.50 o 1 1 2 33.61 42.66 1.80 o 2 1 2 7336.30 7376.81 64.79 o 3 1 2 2731.11 2851.25 27.07 o 4 1 2 2406.70 2456.82 24.09 o 5 1 2 2092.22 2141.96 23.58 o 6 1 2 1285.23 1267.75 21.42 o 7 1 2 742.31 733.54 20.48 o 8 1 2 755.34 751.60 18.19 o -8 2 2 52.28 56.30 6.53 o -7 2 2 1101.39 1163.01 22.97 o -6 2 2 98.85 97.65 4.47 o -5 2 2 1492.39 1433.36 19.86 o -4 2 2 111.24 115.77 3.24 o -3 2 2 1333.79 1285.93 15.88 o -2 2 2 31.57 25.92 1.48 o -1 2 2 5305.58 5503.04 75.82 o 0 2 2 494.06 557.18 5.37 o 1 2 2 21508.86 21388.91 197.30 o 2 2 2 166.38 258.28 3.03 o 3 2 2 776.23 613.22 7.25 o 4 2 2 3069.30 3209.00 32.05 o 5 2 2 1580.87 1593.94 18.92 o 6 2 2 2287.48 2315.38 32.74 o 7 2 2 1218.52 1301.42 24.96 o 8 2 2 106.43 122.54 8.33 o -8 3 2 28.58 26.67 6.47 o -7 3 2 1095.43 1058.19 23.44 o -6 3 2 1394.52 1292.24 20.02 o -5 3 2 1721.77 1612.95 21.66 o -4 3 2 3066.98 3077.15 43.10 o -3 3 2 1113.50 1180.39 16.04 o -2 3 2 3976.32 4173.68 59.04 o -1 3 2 6438.99 6624.53 65.51 o 0 3 2 301.44 271.94 3.48 o 1 3 2 126.77 97.08 1.77 o 2 3 2 2531.05 2547.39 26.87 o 3 3 2 130.75 110.49 2.95 o 4 3 2 1423.63 1445.89 18.49 o 5 3 2 298.67 289.80 5.17 o 6 3 2 451.67 443.12 9.31 o 7 3 2 13.27 9.34 6.09 o 8 3 2 539.29 603.76 20.06 o -8 4 2 926.85 869.52 25.01 o -7 4 2 76.73 64.19 8.08 o -6 4 2 565.14 548.02 13.10 o -5 4 2 198.18 207.42 6.21 o -4 4 2 6238.41 6316.49 76.69 o -3 4 2 326.80 318.14 5.87 o -2 4 2 2568.24 2603.57 42.97 o -1 4 2 545.38 546.76 6.79 o 0 4 2 2563.20 2564.78 35.32 o 1 4 2 142.63 201.95 3.26 o 2 4 2 4623.79 4930.84 62.64 o 3 4 2 44.35 46.98 2.10 o 4 4 2 571.23 562.94 9.26 o 5 4 2 122.30 120.92 4.46 o 6 4 2 426.80 402.56 11.63 o 7 4 2 54.06 55.48 6.98 o 8 4 2 381.73 375.31 15.48 o -7 5 2 500.59 532.01 17.88 o -6 5 2 9.98 0.44 3.81 o -5 5 2 855.04 850.38 20.84 o -4 5 2 1661.10 1630.62 28.23 o -3 5 2 3236.87 3459.65 56.29 o -2 5 2 1400.14 1601.11 24.77 o -1 5 2 905.05 944.82 18.78 o 0 5 2 1584.21 1687.81 28.92 o 1 5 2 4467.09 4852.27 53.15 o 2 5 2 1081.52 1057.61 13.73 o 3 5 2 706.16 718.77 13.16 o 4 5 2 4.13 5.63 2.21 o 5 5 2 44.59 44.43 4.39 o 6 5 2 316.58 316.96 15.41 o 7 5 2 40.62 41.54 6.44 o -7 6 2 135.19 131.87 9.24 o -6 6 2 16.18 15.14 4.78 o -5 6 2 817.41 808.42 20.33 o -4 6 2 923.41 891.85 19.16 o -3 6 2 1530.77 1541.26 23.14 o -2 6 2 88.85 102.03 4.22 o -1 6 2 1602.08 1617.87 28.20 o 0 6 2 2.11 7.91 1.60 o 1 6 2 2278.22 2219.24 45.14 o 2 6 2 1881.14 1935.41 30.67 o 3 6 2 3871.02 3869.64 65.91 o 4 6 2 279.12 292.34 11.98 o 5 6 2 2185.28 2039.50 41.64 o 6 6 2 44.22 39.52 5.74 o 7 6 2 839.38 822.41 23.01 o -6 7 2 212.14 201.22 9.98 o -5 7 2 618.62 601.52 18.44 o -4 7 2 73.33 65.87 3.91 o -3 7 2 240.28 234.71 7.35 o -2 7 2 767.31 734.73 17.54 o -1 7 2 726.40 752.24 16.06 o 0 7 2 3348.59 3493.07 72.52 o 1 7 2 862.79 880.96 22.85 o 2 7 2 1760.18 1750.60 31.04 o 3 7 2 105.76 118.39 5.36 o 4 7 2 3324.35 3257.27 61.43 o 5 7 2 142.22 144.05 7.87 o 6 7 2 924.81 882.53 23.07 o -6 8 2 1634.50 1616.97 36.18 o -5 8 2 54.18 61.43 5.98 o -4 8 2 107.99 113.00 6.89 o -3 8 2 16.84 17.11 2.97 o -2 8 2 1636.55 1681.17 38.82 o -1 8 2 593.84 589.30 16.56 o 0 8 2 936.79 944.32 24.23 o 1 8 2 417.31 430.06 14.08 o 2 8 2 344.77 341.84 10.98 o 3 8 2 47.84 47.18 3.85 o 4 8 2 735.43 742.86 18.28 o 5 8 2 159.17 153.35 8.33 o 6 8 2 234.28 218.06 10.58 o -5 9 2 101.96 99.45 6.98 o -4 9 2 0.67 -0.30 4.40 o -3 9 2 518.76 497.82 21.35 o -2 9 2 38.12 36.79 5.93 o -1 9 2 1207.94 1171.04 40.15 o 0 9 2 179.27 191.33 13.93 o 1 9 2 927.88 907.81 28.06 o 2 9 2 173.19 190.13 11.90 o 3 9 2 517.42 531.91 26.91 o 4 9 2 437.30 450.70 16.63 o 5 9 2 226.91 232.25 10.11 o -4 10 2 217.69 222.30 16.49 o -3 10 2 989.42 1016.57 35.30 o -2 10 2 248.95 224.47 23.38 o -1 10 2 753.26 758.24 30.98 o 0 10 2 211.89 220.09 15.96 o 1 10 2 111.97 118.05 12.48 o 2 10 2 21.07 1.38 9.16 o 3 10 2 909.85 888.22 43.40 o 4 10 2 223.21 177.82 14.71 o -2 11 2 299.42 366.24 32.07 o -1 11 2 68.42 71.67 11.71 o 0 11 2 528.40 491.02 36.08 o 1 11 2 77.80 65.24 14.96 o 2 11 2 342.77 396.78 32.21 o -7 0 3 16.91 22.43 5.95 o -5 0 3 811.70 848.55 23.97 o -3 0 3 539.45 508.79 10.39 o -1 0 3 84.32 79.68 2.65 o 1 0 3 12.67 12.96 0.75 o 3 0 3 358.18 358.17 6.01 o 5 0 3 30.75 35.43 3.11 o 7 0 3 110.13 107.19 9.17 o -8 1 3 267.58 289.14 10.71 o -7 1 3 605.33 591.60 14.58 o -6 1 3 669.68 639.34 13.04 o -5 1 3 1228.72 1188.03 15.30 o -4 1 3 485.98 505.34 7.02 o -3 1 3 4265.03 4381.79 43.55 o -2 1 3 1638.01 1784.60 21.11 o -1 1 3 4705.22 4846.09 61.17 o 0 1 3 927.03 1058.82 9.08 o 1 1 3 5718.32 5932.92 50.74 o 2 1 3 1754.80 1788.04 17.49 o 3 1 3 3298.54 3205.59 28.88 o 4 1 3 773.01 766.72 9.39 o 5 1 3 1776.12 1783.10 19.26 o 6 1 3 13.74 16.92 2.53 o 7 1 3 486.35 498.69 16.95 o 8 1 3 12.59 5.98 4.40 o -8 2 3 555.18 586.69 16.89 o -7 2 3 140.18 135.37 8.12 o -6 2 3 4119.97 4082.32 54.26 o -5 2 3 68.37 64.23 3.07 o -4 2 3 5683.13 5475.62 74.69 o -3 2 3 823.60 897.92 10.66 o -2 2 3 105.58 46.45 1.55 o -1 2 3 432.14 457.57 5.90 o 0 2 3 22826.80 22284.36 186.76 o 1 2 3 45138.93 42545.17 471.93 o 2 2 3 15145.30 15030.75 123.79 o 3 2 3 2122.24 2290.10 22.89 o 4 2 3 2834.34 2735.46 26.47 o 5 2 3 45.10 36.96 3.04 o 6 2 3 980.01 1009.23 15.67 o 7 2 3 87.12 72.22 5.75 o 8 2 3 1993.34 2093.44 40.84 o -8 3 3 2.43 3.06 6.06 o -7 3 3 1199.87 1163.42 25.13 o -6 3 3 774.98 743.86 13.19 o -5 3 3 2455.10 2316.35 29.75 o -4 3 3 54.09 43.76 2.88 o -3 3 3 1801.02 1802.30 21.93 o -2 3 3 823.28 866.44 15.43 o -1 3 3 4954.29 4921.46 57.27 o 0 3 3 397.69 419.24 4.73 o 1 3 3 9487.57 9584.64 86.06 o 2 3 3 224.63 275.41 3.67 o 3 3 3 3578.47 3493.31 35.33 o 4 3 3 70.99 70.42 2.15 o 5 3 3 96.95 86.10 2.76 o 6 3 3 59.33 60.52 3.45 o 7 3 3 2423.19 2368.96 43.68 o 8 3 3 20.10 18.54 6.15 o -8 4 3 120.47 91.74 9.00 o -7 4 3 152.36 122.76 9.87 o -6 4 3 314.04 290.80 13.17 o -5 4 3 1557.70 1525.99 24.08 o -4 4 3 322.34 310.33 6.42 o -3 4 3 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