#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/86/2228677.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2228677_Fobs loop_ _publ_author_name 'Yang, Feng' _publ_section_title ; 2-Iminiumyl-1,3-diazepane-4-carboxylate ; _journal_coeditor_code BX2320 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o10 _journal_volume 67 _journal_year 2011 _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 6.1740 _cell_length_b 8.7979 _cell_length_c 14.2036 _exptl_crystal_F_000 336.00 _reflns_d_resolution_high 0.8364 _[local]_cod_data_source_file bx2320Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' a in P2(1)2(1)2(1)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 80.42 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 349.61 297.24 8.38 o 4 0 0 0.37 -0.09 2.09 o 6 0 0 0.04 -2.46 2.46 o 1 1 0 6468.02 5932.55 32.43 o 2 1 0 1286.00 1324.62 9.41 o 3 1 0 8.67 11.07 0.80 o 4 1 0 6.25 7.84 1.52 o 5 1 0 269.87 290.82 9.01 o 6 1 0 75.45 63.31 10.30 o 7 1 0 0.01 7.47 2.95 o 0 2 0 524.78 509.10 6.31 o 1 2 0 1402.36 1267.69 8.06 o 2 2 0 2.41 0.45 0.64 o 3 2 0 60.94 50.22 1.54 o 4 2 0 340.98 353.23 5.64 o 5 2 0 2.18 4.98 2.23 o 6 2 0 58.62 58.68 9.12 o 7 2 0 1.45 1.98 2.76 o 1 3 0 50.53 62.91 1.45 o 2 3 0 428.16 392.71 3.93 o 3 3 0 18.23 26.98 1.27 o 4 3 0 0.05 5.08 1.31 o 5 3 0 146.57 155.80 6.67 o 6 3 0 1.23 -0.16 2.06 o 7 3 0 0.00 -3.08 3.43 o 0 4 0 789.66 893.91 11.32 o 1 4 0 3.73 5.63 0.83 o 2 4 0 46.66 51.13 1.50 o 3 4 0 18.06 21.66 1.21 o 4 4 0 78.86 90.36 3.54 o 5 4 0 74.28 82.66 8.11 o 6 4 0 10.55 19.46 5.62 o 1 5 0 131.44 156.32 4.01 o 2 5 0 157.18 141.17 2.81 o 3 5 0 9.71 10.91 1.33 o 4 5 0 104.44 99.07 4.77 o 5 5 0 82.60 75.79 7.98 o 6 5 0 1.17 1.67 3.29 o 0 6 0 156.89 186.15 7.67 o 1 6 0 22.18 23.35 2.22 o 2 6 0 5.01 2.46 1.08 o 3 6 0 5.92 7.38 1.48 o 4 6 0 305.01 297.55 17.29 o 5 6 0 32.90 31.67 6.04 o 6 6 0 0.15 0.22 3.76 o 1 7 0 435.34 415.54 9.19 o 2 7 0 107.04 111.69 4.29 o 3 7 0 13.06 14.79 1.96 o 4 7 0 7.53 6.28 2.70 o 5 7 0 0.14 0.07 3.22 o 0 8 0 295.25 292.68 11.57 o 1 8 0 5.54 4.87 1.70 o 2 8 0 73.81 72.10 4.25 o 3 8 0 12.77 17.93 2.70 o 4 8 0 2.83 4.70 2.28 o 1 9 0 0.44 -0.63 1.36 o 2 9 0 5.07 5.02 1.97 o 3 9 0 3.07 5.03 3.24 o 0 10 0 9.89 6.45 3.34 o 1 10 0 7.35 5.55 4.70 o 2 10 0 6.64 7.24 2.49 o 1 0 1 84.81 167.19 4.56 o 2 0 1 50.27 39.96 2.27 o 3 0 1 300.39 268.87 6.57 o 4 0 1 208.70 189.53 8.23 o 5 0 1 0.39 1.06 1.43 o 6 0 1 43.28 43.82 6.67 o 7 0 1 0.54 0.47 2.92 o 0 1 1 23.26 30.44 0.94 o 1 1 1 2193.59 2293.99 9.37 o 2 1 1 1022.03 994.11 5.29 o 3 1 1 57.64 58.93 1.09 o 4 1 1 12.12 10.77 1.34 o 5 1 1 17.17 15.66 1.76 o 6 1 1 21.84 20.94 2.57 o 7 1 1 3.19 3.92 2.05 o 0 2 1 3444.32 3294.47 26.65 o 1 2 1 1970.52 1917.29 8.49 o 2 2 1 90.50 80.70 1.72 o 3 2 1 453.12 491.54 3.49 o 4 2 1 159.77 173.17 2.39 o 5 2 1 117.95 116.09 8.17 o 6 2 1 19.99 22.11 2.60 o 7 2 1 0.59 0.78 1.78 o 0 3 1 89.19 84.90 1.60 o 1 3 1 457.87 463.99 3.15 o 2 3 1 70.20 47.45 0.97 o 3 3 1 2.57 2.63 0.45 o 4 3 1 42.51 39.88 1.45 o 5 3 1 24.37 24.86 2.30 o 6 3 1 56.09 58.92 4.28 o 7 3 1 10.62 9.89 3.61 o 0 4 1 200.49 202.21 3.20 o 1 4 1 180.07 196.57 2.04 o 2 4 1 408.25 411.16 3.33 o 3 4 1 119.07 111.98 1.64 o 4 4 1 17.05 16.15 1.59 o 5 4 1 40.88 33.51 3.07 o 6 4 1 0.78 0.30 2.35 o 0 5 1 51.96 39.36 3.08 o 1 5 1 105.54 113.61 2.07 o 2 5 1 62.52 61.92 1.55 o 3 5 1 65.03 59.49 1.65 o 4 5 1 64.50 63.44 2.81 o 5 5 1 6.97 7.39 2.78 o 6 5 1 9.17 8.98 4.94 o 0 6 1 10.31 11.63 1.80 o 1 6 1 8.71 8.25 0.91 o 2 6 1 140.69 145.89 2.90 o 3 6 1 78.77 72.37 2.94 o 4 6 1 15.72 17.18 1.92 o 5 6 1 9.86 5.10 2.68 o 6 6 1 6.67 4.63 2.99 o 0 7 1 1.60 1.53 1.28 o 1 7 1 47.85 50.50 2.36 o 2 7 1 37.55 42.91 2.53 o 3 7 1 44.79 40.08 2.52 o 4 7 1 18.27 18.82 2.12 o 5 7 1 5.66 5.00 2.84 o 0 8 1 5.08 2.38 1.54 o 1 8 1 102.04 102.88 3.44 o 2 8 1 4.02 1.65 1.09 o 3 8 1 48.61 46.21 2.36 o 4 8 1 13.95 11.01 2.49 o 0 9 1 67.54 85.84 7.05 o 1 9 1 34.70 36.01 2.52 o 2 9 1 37.26 36.60 2.52 o 3 9 1 1.73 0.52 1.20 o 0 10 1 6.60 7.49 2.33 o 1 10 1 11.74 14.47 2.07 o 2 10 1 12.29 16.18 2.21 o 0 0 2 274.72 303.51 4.31 o 1 0 2 62.24 67.09 1.19 o 2 0 2 145.66 155.41 3.47 o 3 0 2 1856.15 1806.38 24.15 o 4 0 2 244.16 219.32 5.61 o 5 0 2 245.22 256.15 6.83 o 6 0 2 7.03 7.97 2.72 o 7 0 2 0.73 3.81 2.71 o 0 1 2 2231.59 2033.07 22.41 o 1 1 2 2650.92 2738.79 12.15 o 2 1 2 2519.00 2543.53 11.27 o 3 1 2 485.74 459.58 3.68 o 4 1 2 31.52 32.79 1.70 o 5 1 2 20.38 26.63 2.12 o 6 1 2 19.24 24.03 2.67 o 7 1 2 21.34 21.36 2.90 o 0 2 2 1008.95 895.36 16.06 o 1 2 2 2768.50 2741.45 13.16 o 2 2 2 4.75 7.09 0.56 o 3 2 2 491.18 510.08 3.55 o 4 2 2 11.20 11.12 1.68 o 5 2 2 55.81 47.63 3.10 o 6 2 2 3.61 1.44 1.69 o 7 2 2 19.39 25.28 3.68 o 0 3 2 1.76 3.42 0.56 o 1 3 2 61.24 60.95 1.16 o 2 3 2 584.38 626.05 3.97 o 3 3 2 45.81 45.24 1.14 o 4 3 2 56.31 48.73 1.74 o 5 3 2 16.32 15.12 2.23 o 6 3 2 8.24 12.56 2.63 o 7 3 2 12.85 15.11 3.11 o 0 4 2 108.73 90.98 2.03 o 1 4 2 399.90 369.31 3.30 o 2 4 2 8.98 10.18 0.62 o 3 4 2 229.31 245.41 3.26 o 4 4 2 38.23 46.87 1.75 o 5 4 2 7.22 1.58 2.41 o 6 4 2 20.86 16.50 3.57 o 0 5 2 60.72 55.68 2.35 o 1 5 2 105.96 106.95 2.04 o 2 5 2 176.46 176.03 2.45 o 3 5 2 2.23 1.47 0.60 o 4 5 2 91.04 83.49 2.74 o 5 5 2 17.91 20.23 3.59 o 6 5 2 6.92 10.70 3.49 o 0 6 2 113.27 100.37 4.08 o 1 6 2 337.37 333.74 4.84 o 2 6 2 45.96 39.22 1.57 o 3 6 2 102.82 101.16 2.59 o 4 6 2 44.01 45.21 2.31 o 5 6 2 5.24 6.21 2.05 o 6 6 2 2.18 3.52 2.79 o 0 7 2 3.14 8.40 1.81 o 1 7 2 31.17 30.81 1.77 o 2 7 2 94.29 101.19 2.94 o 3 7 2 89.85 89.53 2.65 o 4 7 2 60.71 64.77 3.64 o 5 7 2 18.70 18.98 2.86 o 0 8 2 48.21 52.91 3.78 o 1 8 2 7.95 9.22 1.50 o 2 8 2 30.20 35.81 2.38 o 3 8 2 58.32 62.18 2.67 o 4 8 2 0.75 -0.03 1.46 o 0 9 2 2.45 3.09 1.82 o 1 9 2 21.24 21.18 2.11 o 2 9 2 48.81 55.96 3.04 o 3 9 2 3.50 1.18 1.40 o 0 10 2 2.62 3.53 2.04 o 1 10 2 17.85 13.04 1.99 o 2 10 2 4.08 4.43 1.59 o 1 0 3 104.47 92.23 1.61 o 2 0 3 620.18 618.96 8.01 o 3 0 3 175.56 178.59 4.57 o 4 0 3 38.33 49.26 2.96 o 5 0 3 48.98 52.42 3.50 o 6 0 3 19.89 16.49 3.32 o 7 0 3 0.75 0.69 3.18 o 0 1 3 46.42 42.46 1.13 o 1 1 3 1060.94 1037.50 4.98 o 2 1 3 44.50 57.94 1.47 o 3 1 3 31.39 23.14 0.88 o 4 1 3 121.37 118.69 3.95 o 5 1 3 1.65 1.97 1.21 o 6 1 3 19.85 23.12 2.64 o 7 1 3 37.52 45.14 3.79 o 0 2 3 725.83 708.93 5.83 o 1 2 3 766.23 776.38 4.52 o 2 2 3 273.67 302.02 2.56 o 3 2 3 258.84 269.77 2.40 o 4 2 3 232.90 223.54 3.48 o 5 2 3 33.89 36.39 2.37 o 6 2 3 5.77 8.20 1.96 o 7 2 3 0.19 -0.90 2.39 o 0 3 3 115.80 93.69 1.77 o 1 3 3 661.12 672.85 4.73 o 2 3 3 334.34 344.73 2.70 o 3 3 3 423.29 405.63 3.64 o 4 3 3 0.44 0.09 0.68 o 5 3 3 20.45 19.20 2.06 o 6 3 3 21.00 20.74 3.06 o 0 4 3 165.43 166.32 2.95 o 1 4 3 47.22 41.94 1.30 o 2 4 3 193.31 200.38 2.43 o 3 4 3 38.53 37.19 1.52 o 4 4 3 46.68 40.69 1.94 o 5 4 3 51.71 53.39 3.04 o 6 4 3 8.56 5.07 2.20 o 0 5 3 823.77 801.97 12.22 o 1 5 3 121.83 114.53 2.03 o 2 5 3 4.02 4.49 0.73 o 3 5 3 92.48 99.42 2.17 o 4 5 3 4.45 4.91 1.24 o 5 5 3 4.51 6.29 1.98 o 6 5 3 0.72 0.76 2.48 o 0 6 3 14.63 17.20 3.14 o 1 6 3 99.12 93.18 2.57 o 2 6 3 2.87 3.40 0.75 o 3 6 3 19.55 23.05 1.42 o 4 6 3 53.73 64.27 3.11 o 5 6 3 7.10 5.31 1.98 o 0 7 3 2.13 -1.37 1.61 o 1 7 3 55.46 51.70 2.46 o 2 7 3 38.85 38.87 2.03 o 3 7 3 33.14 26.48 2.09 o 4 7 3 5.40 4.03 1.43 o 5 7 3 4.16 7.35 2.29 o 0 8 3 125.76 142.13 8.13 o 1 8 3 8.79 5.34 1.36 o 2 8 3 111.73 112.99 4.57 o 3 8 3 25.84 22.13 2.18 o 4 8 3 1.80 0.44 1.62 o 0 9 3 16.54 15.83 2.77 o 1 9 3 39.38 47.42 2.87 o 2 9 3 30.40 29.71 2.76 o 3 9 3 20.37 20.12 4.01 o 0 10 3 7.32 8.17 3.57 o 1 10 3 0.29 -0.06 1.20 o 0 0 4 23.08 13.75 2.08 o 1 0 4 114.43 129.04 1.97 o 2 0 4 415.30 441.25 4.28 o 3 0 4 571.94 525.13 8.68 o 4 0 4 48.95 48.14 3.06 o 5 0 4 1.47 1.95 2.66 o 6 0 4 0.40 0.01 2.05 o 7 0 4 11.63 7.48 3.27 o 0 1 4 2441.12 2453.41 21.29 o 1 1 4 234.41 213.52 1.65 o 2 1 4 1672.22 1666.98 9.26 o 3 1 4 178.02 184.22 3.36 o 4 1 4 74.23 74.36 2.54 o 5 1 4 12.40 15.93 2.12 o 6 1 4 9.58 10.53 2.14 o 7 1 4 2.83 3.23 1.95 o 0 2 4 231.83 231.28 3.22 o 1 2 4 531.17 537.07 6.70 o 2 2 4 227.85 227.86 2.19 o 3 2 4 22.89 20.14 1.15 o 4 2 4 307.73 298.63 4.16 o 5 2 4 148.37 133.52 4.45 o 6 2 4 11.23 10.66 3.55 o 7 2 4 2.56 3.44 2.40 o 0 3 4 469.96 438.53 4.62 o 1 3 4 648.44 707.31 5.32 o 2 3 4 272.43 239.20 2.54 o 3 3 4 112.13 124.12 2.17 o 4 3 4 233.41 230.77 4.41 o 5 3 4 17.14 14.04 1.90 o 6 3 4 17.63 14.73 6.44 o 0 4 4 2051.07 2067.18 16.33 o 1 4 4 96.21 76.89 1.73 o 2 4 4 305.58 308.59 3.13 o 3 4 4 18.83 18.50 1.21 o 4 4 4 28.51 25.51 2.11 o 5 4 4 72.91 70.85 4.58 o 6 4 4 1.35 1.64 1.97 o 0 5 4 30.79 42.65 2.72 o 1 5 4 53.28 58.91 1.66 o 2 5 4 182.37 184.78 2.84 o 3 5 4 26.26 25.72 1.47 o 4 5 4 73.59 70.11 2.81 o 5 5 4 7.22 7.47 1.79 o 6 5 4 4.48 4.07 2.87 o 0 6 4 76.90 82.44 3.93 o 1 6 4 16.06 21.61 2.00 o 2 6 4 22.50 18.86 1.30 o 3 6 4 80.41 77.55 2.50 o 4 6 4 12.11 15.46 1.94 o 5 6 4 2.61 3.79 1.89 o 0 7 4 9.09 5.89 1.81 o 1 7 4 4.47 1.35 0.99 o 2 7 4 62.86 58.51 2.61 o 3 7 4 7.54 5.70 1.40 o 4 7 4 26.52 27.55 2.82 o 5 7 4 15.47 15.19 3.16 o 0 8 4 44.15 43.91 3.62 o 1 8 4 27.30 31.14 2.83 o 2 8 4 3.06 2.74 1.12 o 3 8 4 43.51 46.39 2.82 o 4 8 4 4.56 2.73 1.83 o 0 9 4 0.33 -0.10 1.43 o 1 9 4 13.58 15.94 1.98 o 2 9 4 33.11 28.89 3.75 o 3 9 4 15.13 21.46 2.36 o 0 10 4 10.44 13.64 2.91 o 1 10 4 13.27 10.59 1.95 o 1 0 5 1986.61 2056.12 13.34 o 2 0 5 461.77 482.85 4.80 o 3 0 5 6.06 4.92 0.97 o 4 0 5 216.14 201.37 8.06 o 5 0 5 51.50 51.54 4.30 o 6 0 5 2.35 -0.30 2.25 o 7 0 5 3.74 2.05 2.78 o 0 1 5 43.98 35.67 1.28 o 1 1 5 1002.54 1003.33 5.31 o 2 1 5 44.33 52.25 1.08 o 3 1 5 322.06 298.51 3.96 o 4 1 5 251.18 253.44 5.45 o 5 1 5 49.66 51.41 3.05 o 6 1 5 83.10 88.24 5.20 o 7 1 5 2.88 0.82 2.19 o 0 2 5 31.09 39.27 1.37 o 1 2 5 210.28 194.81 2.57 o 2 2 5 117.48 115.40 1.97 o 3 2 5 50.70 50.40 1.42 o 4 2 5 63.30 53.75 2.16 o 5 2 5 77.74 79.65 3.01 o 6 2 5 3.16 3.60 1.95 o 0 3 5 26.54 26.38 1.30 o 1 3 5 92.77 93.61 2.93 o 2 3 5 164.30 181.58 2.28 o 3 3 5 16.46 17.54 1.13 o 4 3 5 46.84 54.53 2.22 o 5 3 5 8.64 8.18 1.62 o 6 3 5 76.51 79.76 4.98 o 0 4 5 31.21 39.72 2.20 o 1 4 5 222.79 222.16 3.26 o 2 4 5 4.25 7.90 0.86 o 3 4 5 70.96 76.99 2.12 o 4 4 5 146.45 153.96 5.00 o 5 4 5 47.43 49.22 3.13 o 6 4 5 7.13 6.84 2.44 o 0 5 5 25.22 30.65 2.50 o 1 5 5 153.28 155.35 3.31 o 2 5 5 219.05 202.06 3.24 o 3 5 5 80.70 88.33 2.40 o 4 5 5 72.50 73.74 2.94 o 5 5 5 5.16 5.97 1.70 o 6 5 5 2.61 3.17 3.02 o 0 6 5 19.63 18.40 2.30 o 1 6 5 57.63 57.65 2.47 o 2 6 5 14.87 13.18 1.28 o 3 6 5 117.86 117.09 3.04 o 4 6 5 4.12 4.43 1.43 o 5 6 5 27.47 26.54 3.23 o 0 7 5 81.33 76.63 4.25 o 1 7 5 30.18 25.54 2.00 o 2 7 5 2.28 2.04 1.00 o 3 7 5 30.97 23.90 2.11 o 4 7 5 4.98 7.95 2.02 o 5 7 5 13.91 19.36 3.72 o 0 8 5 3.55 2.41 1.66 o 1 8 5 3.61 -0.40 0.96 o 2 8 5 12.91 13.13 1.58 o 3 8 5 22.73 23.56 2.58 o 4 8 5 1.98 0.92 1.72 o 0 9 5 0.00 0.33 1.57 o 1 9 5 18.67 15.73 2.01 o 2 9 5 19.89 18.96 2.21 o 3 9 5 1.62 1.35 1.42 o 0 10 5 23.28 28.62 6.81 o 0 0 6 2572.98 2807.99 30.88 o 1 0 6 906.75 960.11 8.50 o 2 0 6 5.64 8.43 0.79 o 3 0 6 5.03 2.76 1.12 o 4 0 6 29.76 29.83 3.57 o 5 0 6 19.49 16.23 2.98 o 6 0 6 0.59 3.03 2.34 o 0 1 6 356.37 358.11 4.94 o 1 1 6 722.53 734.23 5.10 o 2 1 6 65.70 65.54 1.32 o 3 1 6 192.11 198.65 3.58 o 4 1 6 9.04 6.80 1.14 o 5 1 6 18.82 18.12 1.88 o 6 1 6 11.57 9.34 2.05 o 0 2 6 85.96 95.17 1.97 o 1 2 6 250.26 248.13 2.51 o 2 2 6 631.77 682.09 4.84 o 3 2 6 45.12 48.89 1.66 o 4 2 6 145.37 135.48 4.14 o 5 2 6 19.10 17.30 2.02 o 6 2 6 5.75 5.54 2.18 o 0 3 6 237.58 274.34 4.53 o 1 3 6 565.36 590.37 5.12 o 2 3 6 471.93 487.48 4.62 o 3 3 6 193.84 203.48 3.28 o 4 3 6 134.26 132.24 3.55 o 5 3 6 86.05 88.94 3.80 o 6 3 6 7.35 7.04 2.46 o 0 4 6 553.26 563.24 8.54 o 1 4 6 29.11 26.25 1.30 o 2 4 6 48.53 43.52 1.74 o 3 4 6 154.74 149.13 2.98 o 4 4 6 35.52 31.99 2.11 o 5 4 6 36.38 38.60 2.63 o 6 4 6 1.76 2.77 2.18 o 0 5 6 26.64 30.15 2.28 o 1 5 6 59.22 58.52 2.47 o 2 5 6 30.61 28.27 1.38 o 3 5 6 135.05 127.91 3.28 o 4 5 6 9.72 10.31 1.74 o 5 5 6 46.46 45.31 2.74 o 0 6 6 22.40 13.11 2.47 o 1 6 6 2.91 2.80 1.03 o 2 6 6 2.55 2.44 0.89 o 3 6 6 26.07 31.82 2.05 o 4 6 6 42.69 42.58 2.62 o 5 6 6 5.87 5.86 2.24 o 0 7 6 0.02 0.27 1.27 o 1 7 6 79.24 73.34 2.97 o 2 7 6 37.25 35.97 1.95 o 3 7 6 14.81 12.19 1.79 o 4 7 6 5.85 6.35 1.97 o 0 8 6 144.03 142.65 11.83 o 1 8 6 2.96 3.68 1.64 o 2 8 6 8.83 9.18 1.61 o 3 8 6 15.90 17.82 2.17 o 4 8 6 0.52 -0.39 1.69 o 0 9 6 37.87 45.01 4.12 o 1 9 6 11.89 7.59 1.65 o 2 9 6 3.05 3.50 1.43 o 1 0 7 802.59 820.55 8.78 o 2 0 7 0.34 0.54 0.57 o 3 0 7 19.04 14.79 1.97 o 4 0 7 53.26 62.57 4.37 o 5 0 7 30.10 32.45 6.94 o 6 0 7 12.95 18.05 3.63 o 0 1 7 376.90 399.66 5.59 o 1 1 7 116.55 127.50 2.04 o 2 1 7 111.52 109.92 1.84 o 3 1 7 175.34 178.68 4.35 o 4 1 7 16.67 18.11 1.71 o 5 1 7 43.22 42.16 2.50 o 6 1 7 10.02 10.16 2.87 o 0 2 7 6.29 11.42 0.99 o 1 2 7 0.61 1.50 0.49 o 2 2 7 10.59 12.21 0.94 o 3 2 7 91.18 96.57 2.49 o 4 2 7 101.16 107.45 4.81 o 5 2 7 30.50 30.67 2.53 o 6 2 7 23.39 21.61 3.42 o 0 3 7 37.94 44.11 1.92 o 1 3 7 104.71 110.60 2.01 o 2 3 7 31.34 34.12 1.93 o 3 3 7 26.99 25.58 1.70 o 4 3 7 6.96 7.84 1.35 o 5 3 7 19.53 19.24 2.26 o 6 3 7 8.32 7.90 2.51 o 0 4 7 115.09 114.50 3.74 o 1 4 7 187.35 203.16 3.36 o 2 4 7 136.78 142.03 2.61 o 3 4 7 32.35 37.08 2.16 o 4 4 7 0.24 1.16 1.04 o 5 4 7 4.83 3.04 1.33 o 6 4 7 8.85 6.82 3.82 o 0 5 7 68.63 70.36 3.44 o 1 5 7 23.80 26.15 1.80 o 2 5 7 7.90 4.90 1.00 o 3 5 7 76.17 78.17 2.59 o 4 5 7 91.24 87.09 3.34 o 5 5 7 61.96 61.68 3.17 o 0 6 7 11.03 17.93 4.28 o 1 6 7 79.75 84.77 3.09 o 2 6 7 115.80 118.22 3.85 o 3 6 7 63.35 57.51 2.68 o 4 6 7 42.64 43.85 3.02 o 5 6 7 35.04 34.76 2.71 o 0 7 7 75.41 72.40 4.50 o 1 7 7 19.47 23.56 2.68 o 2 7 7 83.25 83.09 5.28 o 3 7 7 36.08 28.19 2.61 o 4 7 7 6.82 9.14 2.26 o 0 8 7 9.13 3.78 1.95 o 1 8 7 33.46 34.33 2.57 o 2 8 7 11.10 15.53 2.33 o 3 8 7 9.28 10.44 2.39 o 0 9 7 0.35 -0.69 1.67 o 1 9 7 1.09 2.97 1.46 o 2 9 7 12.08 11.28 2.25 o 0 0 8 329.05 322.81 7.41 o 1 0 8 12.34 12.60 1.30 o 2 0 8 42.82 35.92 1.62 o 3 0 8 0.91 3.13 1.49 o 4 0 8 62.16 68.16 5.08 o 5 0 8 1.17 -1.08 1.80 o 6 0 8 2.47 3.54 2.49 o 0 1 8 168.36 212.19 4.73 o 1 1 8 166.14 171.09 2.40 o 2 1 8 37.97 40.45 1.84 o 3 1 8 190.77 196.22 4.02 o 4 1 8 22.25 23.80 1.92 o 5 1 8 56.94 59.49 3.11 o 6 1 8 1.92 2.53 2.07 o 0 2 8 830.18 826.20 8.06 o 1 2 8 516.01 549.91 5.03 o 2 2 8 23.25 23.39 1.34 o 3 2 8 1.95 1.55 1.40 o 4 2 8 4.39 5.33 1.47 o 5 2 8 0.03 -1.17 1.17 o 6 2 8 1.48 -0.30 1.85 o 0 3 8 55.06 51.32 1.92 o 1 3 8 1.26 5.05 0.75 o 2 3 8 357.39 367.45 4.06 o 3 3 8 71.20 66.55 2.73 o 4 3 8 123.70 130.38 4.31 o 5 3 8 15.90 18.09 2.80 o 6 3 8 29.71 32.49 3.90 o 0 4 8 13.17 6.20 1.41 o 1 4 8 10.47 11.49 1.28 o 2 4 8 55.41 58.53 1.94 o 3 4 8 155.32 172.11 4.78 o 4 4 8 112.01 110.19 3.65 o 5 4 8 97.47 93.31 4.20 o 0 5 8 0.80 0.28 1.23 o 1 5 8 182.29 191.86 4.41 o 2 5 8 105.33 115.00 3.14 o 3 5 8 3.11 5.79 1.37 o 4 5 8 4.28 3.81 1.40 o 5 5 8 1.44 -0.01 1.19 o 0 6 8 76.09 83.43 4.50 o 1 6 8 62.77 52.62 2.68 o 2 6 8 1.39 0.42 1.32 o 3 6 8 6.43 5.39 1.61 o 4 6 8 15.66 13.75 2.22 o 0 7 8 3.28 2.51 1.68 o 1 7 8 24.72 22.27 2.11 o 2 7 8 8.62 7.49 1.65 o 3 7 8 1.35 0.21 1.31 o 4 7 8 1.65 4.01 1.92 o 0 8 8 11.46 9.28 2.52 o 1 8 8 16.99 14.13 2.54 o 2 8 8 10.42 8.03 1.96 o 3 8 8 4.61 3.85 2.41 o 0 9 8 9.87 9.40 2.61 o 1 9 8 19.17 20.82 2.37 o 1 0 9 127.36 128.66 3.49 o 2 0 9 2.73 1.76 1.49 o 3 0 9 297.00 285.71 10.73 o 4 0 9 5.90 3.33 2.11 o 5 0 9 49.11 45.22 7.71 o 6 0 9 1.87 2.43 2.57 o 0 1 9 177.81 183.82 4.67 o 1 1 9 73.65 75.74 1.84 o 2 1 9 42.13 40.21 1.98 o 3 1 9 3.30 3.13 1.32 o 4 1 9 137.05 137.73 3.94 o 5 1 9 2.13 2.02 1.43 o 6 1 9 3.26 6.16 2.36 o 0 2 9 175.72 175.55 3.90 o 1 2 9 197.20 190.79 3.33 o 2 2 9 89.18 82.40 2.43 o 3 2 9 26.30 26.75 2.30 o 4 2 9 27.30 26.15 2.44 o 5 2 9 14.65 20.45 2.39 o 6 2 9 17.02 20.04 6.12 o 0 3 9 16.31 15.54 1.83 o 1 3 9 123.18 124.65 2.46 o 2 3 9 35.04 33.96 1.74 o 3 3 9 51.22 49.93 4.35 o 4 3 9 87.57 83.99 3.78 o 5 3 9 27.67 24.10 2.58 o 0 4 9 27.24 34.72 2.94 o 1 4 9 38.88 41.12 1.87 o 2 4 9 50.45 56.88 2.37 o 3 4 9 43.89 37.34 2.33 o 4 4 9 10.83 11.82 1.73 o 5 4 9 0.46 2.86 1.66 o 0 5 9 25.85 34.24 3.13 o 1 5 9 305.36 298.16 6.08 o 2 5 9 21.08 18.88 1.92 o 3 5 9 9.24 13.60 1.98 o 4 5 9 21.73 24.35 2.28 o 5 5 9 2.83 2.46 1.50 o 0 6 9 279.25 296.98 8.59 o 1 6 9 27.94 24.50 2.55 o 2 6 9 17.72 16.70 2.19 o 3 6 9 1.93 5.67 1.60 o 4 6 9 25.09 30.93 2.92 o 0 7 9 75.83 73.54 4.78 o 1 7 9 5.06 7.24 1.54 o 2 7 9 2.31 2.54 1.40 o 3 7 9 7.23 3.90 1.88 o 0 8 9 2.44 2.76 2.04 o 1 8 9 18.81 14.51 2.09 o 2 8 9 6.35 5.48 1.97 o 0 0 10 104.22 112.51 6.94 o 1 0 10 14.31 12.36 1.80 o 2 0 10 42.92 45.37 4.04 o 3 0 10 202.75 217.70 8.99 o 4 0 10 3.52 3.55 2.14 o 5 0 10 0.37 -1.89 1.89 o 0 1 10 179.19 157.83 4.53 o 1 1 10 105.78 105.50 2.45 o 2 1 10 400.06 386.45 6.72 o 3 1 10 76.60 82.86 3.82 o 4 1 10 4.15 4.12 1.48 o 5 1 10 18.71 18.16 2.96 o 0 2 10 18.26 15.91 1.59 o 1 2 10 36.69 33.63 1.73 o 2 2 10 152.87 165.28 4.13 o 3 2 10 272.68 257.69 6.02 o 4 2 10 68.47 67.51 4.08 o 5 2 10 5.98 4.64 1.76 o 0 3 10 62.23 69.31 2.79 o 1 3 10 264.78 273.04 4.01 o 2 3 10 248.40 227.18 5.99 o 3 3 10 39.92 34.90 3.51 o 4 3 10 15.23 14.69 2.13 o 5 3 10 2.03 2.61 1.51 o 0 4 10 453.87 452.45 26.20 o 1 4 10 175.94 188.98 4.02 o 2 4 10 201.09 183.18 5.37 o 3 4 10 49.39 44.18 2.73 o 4 4 10 4.64 2.15 1.48 o 5 4 10 14.28 15.18 2.49 o 0 5 10 25.49 22.79 2.82 o 1 5 10 75.78 80.76 3.09 o 2 5 10 216.79 229.67 9.14 o 3 5 10 8.15 4.66 1.66 o 4 5 10 4.43 4.15 1.63 o 0 6 10 26.60 26.02 4.03 o 1 6 10 3.04 3.98 1.52 o 2 6 10 3.12 3.30 1.38 o 3 6 10 10.17 8.81 2.18 o 4 6 10 16.50 19.72 3.81 o 0 7 10 18.57 16.97 3.00 o 1 7 10 9.00 8.28 1.70 o 2 7 10 7.54 7.97 1.78 o 3 7 10 1.02 0.07 1.66 o 0 8 10 0.34 -0.63 1.89 o 1 8 10 0.07 1.35 1.38 o 2 8 10 2.79 1.56 1.55 o 1 0 11 9.67 8.48 2.06 o 2 0 11 11.37 11.80 3.77 o 3 0 11 64.08 52.88 6.65 o 4 0 11 16.44 19.58 5.98 o 5 0 11 0.05 1.81 3.34 o 0 1 11 18.96 18.62 2.03 o 1 1 11 34.38 32.72 1.78 o 2 1 11 41.73 47.33 5.00 o 3 1 11 5.92 1.58 4.16 o 4 1 11 36.77 30.71 2.75 o 5 1 11 13.85 15.94 2.40 o 0 2 11 36.75 46.71 2.55 o 1 2 11 4.30 4.18 1.14 o 2 2 11 27.47 25.23 2.60 o 3 2 11 17.70 20.90 2.62 o 4 2 11 29.41 33.88 2.85 o 5 2 11 0.72 1.31 1.61 o 0 3 11 44.35 44.71 4.78 o 1 3 11 268.46 267.15 5.40 o 2 3 11 82.76 79.44 4.00 o 3 3 11 43.02 40.63 3.27 o 4 3 11 1.97 1.10 1.34 o 5 3 11 5.53 3.85 1.82 o 0 4 11 7.42 8.41 2.04 o 1 4 11 167.99 160.95 4.22 o 2 4 11 1.08 0.29 1.07 o 3 4 11 75.22 80.43 5.00 o 4 4 11 14.15 10.90 2.11 o 0 5 11 12.72 12.61 2.49 o 1 5 11 0.44 0.34 1.01 o 2 5 11 8.96 7.15 1.57 o 3 5 11 2.25 1.77 1.75 o 4 5 11 1.19 3.39 2.01 o 0 6 11 27.32 30.44 3.55 o 1 6 11 7.63 6.86 1.55 o 2 6 11 19.12 15.91 2.13 o 3 6 11 2.76 0.85 1.73 o 0 7 11 17.89 17.21 3.03 o 1 7 11 46.38 48.41 3.07 o 2 7 11 20.64 23.65 2.94 o 0 8 11 41.59 42.32 4.49 o 0 0 12 1.17 -0.44 2.46 o 1 0 12 24.61 24.95 2.83 o 2 0 12 0.07 -0.59 2.37 o 3 0 12 110.85 104.87 9.27 o 4 0 12 6.00 5.59 3.75 o 0 1 12 133.51 131.30 4.57 o 1 1 12 20.63 21.67 2.87 o 2 1 12 8.97 8.12 2.00 o 3 1 12 1.60 0.36 1.47 o 4 1 12 28.03 27.82 3.08 o 5 1 12 11.09 6.37 2.00 o 0 2 12 193.60 183.50 8.91 o 1 2 12 153.56 144.22 5.45 o 2 2 12 171.12 167.71 5.68 o 3 2 12 33.08 37.93 3.37 o 4 2 12 15.50 13.86 2.24 o 5 2 12 5.16 9.13 2.16 o 0 3 12 16.87 13.52 3.18 o 1 3 12 279.05 269.42 7.90 o 2 3 12 73.37 65.70 3.91 o 3 3 12 47.03 51.58 3.76 o 4 3 12 20.36 16.31 2.39 o 0 4 12 175.71 188.02 6.86 o 1 4 12 9.60 8.33 2.18 o 2 4 12 60.57 62.13 5.05 o 3 4 12 32.38 45.44 4.69 o 4 4 12 25.86 23.53 3.14 o 0 5 12 70.35 72.95 4.73 o 1 5 12 49.73 45.85 2.76 o 2 5 12 3.97 3.86 2.03 o 3 5 12 80.46 80.84 4.87 o 0 6 12 1.33 -1.01 1.64 o 1 6 12 78.09 91.00 7.53 o 2 6 12 1.83 1.62 1.75 o 3 6 12 2.51 2.74 1.97 o 0 7 12 7.07 4.37 2.22 o 1 7 12 12.56 12.44 2.85 o 1 0 13 28.94 30.34 3.12 o 2 0 13 6.35 7.03 3.80 o 3 0 13 0.98 6.84 3.72 o 4 0 13 3.49 3.00 3.52 o 0 1 13 1.69 3.16 2.16 o 1 1 13 44.62 38.94 2.57 o 2 1 13 11.69 16.40 3.31 o 3 1 13 16.14 16.43 3.80 o 4 1 13 8.76 9.49 2.48 o 0 2 13 96.88 103.34 6.85 o 1 2 13 0.62 0.80 1.26 o 2 2 13 73.67 73.93 4.30 o 3 2 13 5.21 6.84 2.00 o 4 2 13 5.35 4.20 1.98 o 0 3 13 27.10 37.55 4.81 o 1 3 13 27.63 24.30 2.93 o 2 3 13 1.12 0.89 1.80 o 3 3 13 25.25 29.15 3.20 o 4 3 13 32.93 32.39 3.59 o 0 4 13 106.04 99.12 7.32 o 1 4 13 17.37 18.83 2.89 o 2 4 13 30.26 26.85 4.32 o 3 4 13 14.33 16.65 3.54 o 0 5 13 93.87 88.75 5.28 o 1 5 13 71.09 73.61 4.04 o 2 5 13 0.89 0.54 2.02 o 3 5 13 0.91 0.89 2.41 o 0 6 13 84.24 89.42 5.57 o 1 6 13 17.74 20.85 3.47 o 2 6 13 10.68 10.92 2.52 o 0 0 14 106.17 101.50 7.08 o 1 0 14 65.42 69.18 4.50 o 2 0 14 132.12 131.60 10.26 o 3 0 14 38.00 44.64 7.31 o 4 0 14 1.53 0.69 2.79 o 0 1 14 132.09 121.69 5.77 o 1 1 14 10.65 9.00 1.66 o 2 1 14 67.36 57.95 4.15 o 3 1 14 83.65 80.52 4.89 o 4 1 14 6.92 5.84 2.38 o 0 2 14 75.06 91.93 6.75 o 1 2 14 25.77 25.29 3.01 o 2 2 14 74.23 70.94 4.43 o 3 2 14 1.77 6.21 2.13 o 0 3 14 0.13 0.00 2.20 o 1 3 14 3.44 -0.37 1.51 o 2 3 14 9.01 8.13 2.92 o 3 3 14 11.25 11.19 3.15 o 0 4 14 0.23 -1.12 2.34 o 1 4 14 2.11 2.39 2.36 o 2 4 14 29.74 32.74 4.41 o 3 4 14 22.76 23.64 4.01 o 0 5 14 8.15 3.80 2.92 o 1 5 14 5.36 2.68 2.13 o 2 5 14 12.68 15.33 3.54 o 1 0 15 24.00 30.21 3.95 o 2 0 15 1.23 0.92 2.06 o 3 0 15 86.90 77.00 8.58 o 0 1 15 0.01 3.60 2.31 o 1 1 15 9.34 8.50 2.30 o 2 1 15 13.28 16.28 4.91 o 3 1 15 65.91 70.53 4.91 o 0 2 15 2.24 3.01 2.74 o 1 2 15 44.67 49.47 4.81 o 2 2 15 2.89 3.08 1.89 o 3 2 15 28.23 35.74 4.29 o 0 3 15 1.62 0.42 2.63 o 1 3 15 20.99 18.90 4.46 o 2 3 15 9.68 10.22 3.20 o 0 4 15 0.99 -0.76 2.44 o 1 4 15 18.47 20.17 3.20 o 2 4 15 9.42 16.15 3.86 o 0 0 16 22.68 12.37 3.63 o 1 0 16 1.59 0.13 2.91 o 2 0 16 5.74 5.04 2.72 o 0 1 16 64.02 66.69 6.50 o 1 1 16 31.84 32.46 5.98 o 2 1 16 6.21 5.31 2.39 o 0 2 16 11.84 9.60 3.66 o 1 2 16 37.18 38.14 4.62 o 2 2 16 19.85 16.32 3.62 o 0 3 16 14.48 14.65 4.13 o 1 3 16 1.11 -0.58 2.78 o