#------------------------------------------------------------------------------ #$Date: 2016-04-03 04:57:59 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181207 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/86/2228692.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2228692_Fobs loop_ _publ_author_name 'Cui, Yue' 'Gao, Qian' 'Wang, Huan-Huan' 'Wang, Lin' 'Xie, Ya-Bo' _publ_section_title ; Diaquabis(2-oxo-2H-chromene-3-carboxylato)zinc(II) ; _journal_coeditor_code DN2633 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m69 _journal_volume 67 _journal_year 2011 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 85.640 _cell_angle_beta 89.470 _cell_angle_gamma 66.090 _cell_length_a 6.6113 _cell_length_b 6.8404 _cell_length_c 10.3920 _exptl_crystal_F_000 244.00 _reflns_d_resolution_high 0.7800 _cod_data_source_file dn2633Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' I P -1 R = 0.02' _shelx_refln_list_code 4 _shelx_f_calc_maximum 50.26 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 94.05 99.71 2.94 o 2 0 0 562.15 570.31 17.46 o 4 0 0 845.76 831.81 25.62 o 5 0 0 374.26 356.99 11.58 o 6 0 0 514.53 520.36 16.70 o 7 0 0 35.58 38.34 2.28 o -7 1 0 23.56 28.28 1.96 o -6 1 0 38.37 38.23 2.18 o -5 1 0 306.70 292.15 9.71 o -4 1 0 485.60 487.46 15.39 o -3 1 0 220.67 191.85 4.27 o -2 1 0 266.01 270.99 8.01 o -1 1 0 390.79 404.56 8.56 o 3 1 0 736.42 862.54 91.87 o 4 1 0 193.02 180.21 4.02 o 5 1 0 394.42 400.24 12.85 o 6 1 0 434.29 421.60 13.71 o 7 1 0 354.02 367.61 12.26 o 8 1 0 19.11 27.75 2.01 o -6 2 0 13.20 14.62 1.55 o -5 2 0 60.79 67.53 3.01 o -4 2 0 13.62 13.30 1.22 o -3 2 0 285.65 280.34 6.21 o -2 2 0 596.92 614.14 18.04 o -1 2 0 3.01 1.28 0.23 o 2 2 0 9.60 2.96 0.36 o 3 2 0 274.93 250.55 5.46 o 4 2 0 421.41 426.60 9.19 o 5 2 0 57.19 52.66 2.30 o 6 2 0 282.27 277.62 9.33 o 7 2 0 496.92 482.90 15.73 o 8 2 0 12.58 10.06 1.35 o -6 3 0 49.92 46.77 2.68 o -5 3 0 11.94 10.95 1.35 o -4 3 0 123.19 121.05 4.61 o -3 3 0 368.36 388.54 8.56 o -2 3 0 349.35 346.21 8.16 o -1 3 0 271.94 276.44 6.10 o 0 3 0 106.37 108.66 9.42 o 1 3 0 349.83 338.89 7.31 o 2 3 0 861.73 846.33 24.78 o 3 3 0 879.72 869.85 25.41 o 4 3 0 801.36 795.89 16.89 o 5 3 0 204.81 199.91 4.58 o 7 3 0 188.12 186.28 6.79 o 8 3 0 702.07 723.97 23.21 o -5 4 0 303.19 301.25 10.37 o -4 4 0 245.65 247.42 8.56 o -3 4 0 7.00 8.16 1.07 o -2 4 0 591.21 574.61 18.02 o -1 4 0 671.54 664.82 14.28 o 0 4 0 1430.40 1567.86 32.94 o 1 4 0 1018.19 1139.80 24.07 o 2 4 0 1431.43 1495.32 43.61 o 3 4 0 109.35 115.76 3.90 o 4 4 0 792.28 803.56 23.67 o 5 4 0 364.83 362.77 8.03 o 6 4 0 8.07 9.48 1.09 o 7 4 0 189.60 188.81 6.84 o 8 4 0 414.23 408.12 13.71 o -4 5 0 36.44 41.10 2.40 o -3 5 0 34.49 35.35 2.03 o -2 5 0 124.07 125.89 3.24 o -1 5 0 211.84 209.94 4.94 o 0 5 0 241.25 247.04 5.65 o 1 5 0 43.07 40.30 1.30 o 2 5 0 8.22 8.18 0.86 o 3 5 0 28.40 28.61 1.50 o 4 5 0 43.35 43.13 1.90 o 5 5 0 140.00 140.48 4.74 o 6 5 0 24.77 24.45 1.60 o 7 5 0 34.43 37.68 2.25 o 8 5 0 20.09 22.35 1.78 o -3 6 0 148.94 158.02 6.01 o -2 6 0 2.79 3.77 0.86 o -1 6 0 273.88 274.34 6.41 o 1 6 0 1469.28 1448.10 30.68 o 2 6 0 3.49 5.68 0.86 o 3 6 0 89.21 168.31 5.76 o 4 6 0 1.46 1.70 0.58 o 5 6 0 330.99 341.76 10.75 o 6 6 0 119.90 118.71 3.17 o 7 6 0 4.39 4.87 1.02 o -1 7 0 121.98 126.43 3.42 o 0 7 0 211.24 221.52 8.21 o 1 7 0 436.28 403.56 12.82 o 2 7 0 317.09 317.46 10.34 o 3 7 0 188.94 181.99 6.31 o 4 7 0 174.35 173.58 6.06 o 5 7 0 103.64 107.17 4.16 o 6 7 0 198.16 200.61 6.86 o 7 7 0 84.74 88.08 4.00 o 1 8 0 102.50 82.72 2.58 o 2 8 0 765.93 719.51 22.02 o 3 8 0 193.96 187.97 6.66 o 4 8 0 63.46 63.38 2.96 o 5 8 0 4.29 4.89 0.99 o 6 8 0 196.21 190.03 6.74 o -6 -8 1 247.09 247.93 8.41 o -5 -8 1 4.69 6.03 1.04 o -4 -8 1 86.60 77.13 3.39 o -3 -8 1 50.31 46.54 1.78 o -2 -8 1 3.96 2.73 0.91 o -1 -8 1 510.14 469.88 15.01 o -7 -7 1 32.47 27.37 1.93 o -6 -7 1 496.76 498.45 11.19 o -5 -7 1 78.74 78.04 3.24 o -4 -7 1 130.46 133.62 4.89 o -3 -7 1 128.06 124.40 4.74 o -2 -7 1 52.61 49.42 2.48 o -1 -7 1 358.23 335.60 10.93 o 0 -7 1 168.11 170.13 4.32 o 1 -7 1 274.64 274.59 6.55 o -7 -6 1 48.18 52.81 2.81 o -6 -6 1 6.91 9.28 1.17 o -5 -6 1 280.02 277.83 8.87 o -4 -6 1 12.78 13.08 1.19 o -3 -6 1 424.03 422.97 13.15 o -2 -6 1 239.46 239.03 7.88 o -1 -6 1 238.59 242.24 9.82 o 0 -6 1 437.61 437.89 9.76 o 1 -6 1 718.84 717.16 18.27 o 2 -6 1 4.60 6.39 1.02 o 3 -6 1 85.01 87.83 3.83 o -8 -5 1 168.63 169.61 6.52 o -7 -5 1 363.08 371.79 12.44 o -6 -5 1 173.32 180.65 6.52 o -5 -5 1 199.55 211.84 4.98 o -4 -5 1 85.90 86.99 3.19 o -3 -5 1 103.24 109.19 3.90 o -2 -5 1 94.42 94.22 3.49 o -1 -5 1 21.49 26.30 1.21 o 0 -5 1 68.14 68.80 1.94 o 1 -5 1 14.89 14.74 0.84 o 2 -5 1 125.96 131.73 3.38 o 3 -5 1 58.22 57.37 2.73 o 4 -5 1 18.83 21.08 1.68 o -8 -4 1 421.12 402.43 13.48 o -7 -4 1 177.14 180.24 6.57 o -6 -4 1 316.42 323.77 10.77 o -5 -4 1 271.25 264.23 5.96 o -4 -4 1 374.63 378.02 11.42 o -3 -4 1 5.89 5.04 0.63 o -2 -4 1 1448.08 1523.95 44.47 o -1 -4 1 1557.97 1621.52 34.04 o 0 -4 1 392.28 445.74 9.66 o 1 -4 1 97.01 94.18 2.41 o 2 -4 1 907.41 964.23 20.55 o 3 -4 1 16.53 15.81 1.40 o 4 -4 1 152.84 159.82 5.91 o 5 -4 1 88.62 86.94 3.83 o -8 -3 1 59.64 54.23 2.86 o -7 -3 1 188.62 186.43 6.76 o -6 -3 1 2171.36 2171.18 66.09 o -5 -3 1 84.52 79.64 3.16 o -4 -3 1 749.98 732.59 15.57 o -3 -3 1 1034.05 1050.75 30.66 o -2 -3 1 1565.43 1669.47 48.48 o 0 -3 1 435.60 398.68 8.58 o 1 -3 1 624.41 668.16 14.23 o 2 -3 1 149.31 147.59 3.49 o 3 -3 1 330.00 340.98 7.59 o 4 -3 1 302.48 298.81 9.94 o 5 -3 1 109.12 107.80 4.36 o 6 -3 1 61.76 58.08 3.04 o -8 -2 1 2.20 1.70 0.89 o -7 -2 1 363.04 358.82 11.98 o -6 -2 1 46.22 42.47 2.16 o -5 -2 1 516.45 529.84 16.70 o -4 -2 1 1052.66 1010.47 21.27 o -3 -2 1 381.90 369.82 7.93 o -2 -2 1 33.92 44.90 1.63 o 1 -2 1 92.75 67.77 1.66 o 2 -2 1 23.79 20.78 0.77 o 3 -2 1 322.13 356.65 11.60 o 4 -2 1 38.41 44.96 2.16 o 5 -2 1 271.49 261.18 8.87 o 6 -2 1 40.77 39.81 2.28 o -8 -1 1 60.95 57.73 3.01 o -7 -1 1 11.17 13.23 1.42 o -6 -1 1 147.03 148.79 5.45 o -5 -1 1 1473.35 1518.30 46.34 o -4 -1 1 177.71 197.78 6.57 o -3 -1 1 243.66 226.23 4.89 o -2 -1 1 229.12 234.96 5.08 o -1 -1 1 227.79 242.68 7.14 o 1 -1 1 709.86 695.73 14.60 o 2 -1 1 981.43 1048.88 22.00 o 3 -1 1 154.08 135.47 3.14 o 4 -1 1 200.07 201.91 6.81 o 5 -1 1 280.96 267.18 8.95 o 6 -1 1 108.10 105.74 4.28 o 7 -1 1 90.14 85.35 3.80 o -7 0 1 19.60 20.14 1.80 o -6 0 1 417.57 427.16 13.91 o -5 0 1 5.19 4.18 0.76 o -4 0 1 563.33 581.55 18.12 o -2 0 1 937.28 910.51 27.62 o 3 0 1 1252.97 1202.23 36.57 o 4 0 1 393.06 421.85 9.09 o 5 0 1 352.92 348.81 11.32 o 6 0 1 827.86 796.31 24.98 o 7 0 1 274.13 274.03 9.53 o -7 1 1 228.07 224.59 8.11 o -6 1 1 486.66 466.08 15.13 o -5 1 1 236.67 238.83 8.11 o -4 1 1 708.24 695.05 21.59 o -3 1 1 553.53 561.54 16.34 o -2 1 1 552.78 541.90 11.43 o -1 1 1 509.10 536.24 11.63 o 0 1 1 2.11 2.07 0.29 o 4 1 1 548.64 543.61 11.60 o 5 1 1 328.31 343.41 11.12 o 6 1 1 375.95 382.78 12.54 o 7 1 1 186.94 186.94 6.84 o 8 1 1 261.60 282.64 9.96 o -6 2 1 67.58 71.23 3.32 o -5 2 1 352.51 353.49 11.68 o -3 2 1 113.36 106.75 2.57 o -2 2 1 337.69 328.11 7.14 o -1 2 1 3.76 10.62 0.74 o 0 2 1 454.34 469.57 9.95 o 1 2 1 152.25 151.23 4.66 o 3 2 1 1518.07 1543.26 46.77 o 4 2 1 518.55 472.20 10.17 o 5 2 1 1.80 1.75 0.48 o 6 2 1 58.65 63.35 2.83 o 7 2 1 226.41 219.34 7.83 o 8 2 1 98.83 105.06 4.54 o -6 3 1 72.56 64.89 3.27 o -5 3 1 1179.94 1177.48 36.54 o -4 3 1 27.61 30.91 1.88 o -3 3 1 149.57 153.13 5.40 o -2 3 1 297.26 307.73 6.79 o -1 3 1 406.28 406.50 11.35 o 0 3 1 771.12 764.02 16.15 o 1 3 1 2.33 7.18 0.41 o 2 3 1 122.36 110.51 3.57 o 3 3 1 107.95 94.97 3.14 o 4 3 1 346.19 347.93 7.61 o 5 3 1 202.76 194.38 4.49 o 6 3 1 107.39 111.98 4.36 o 7 3 1 132.32 128.55 5.07 o 8 3 1 51.85 47.08 2.66 o -5 4 1 300.89 302.33 10.44 o -4 4 1 764.29 769.29 24.25 o -3 4 1 53.11 56.94 2.63 o -2 4 1 755.87 754.60 16.17 o -1 4 1 611.10 620.10 13.32 o 0 4 1 135.33 123.66 2.97 o 1 4 1 2481.55 2509.09 72.75 o 2 4 1 1009.95 1033.45 30.28 o 4 4 1 977.23 1009.01 29.59 o 5 4 1 610.66 604.25 13.05 o 6 4 1 43.21 38.97 2.13 o 7 4 1 148.51 141.27 5.48 o 8 4 1 89.14 83.55 3.85 o -4 5 1 983.44 1019.13 31.88 o -3 5 1 85.18 89.94 3.75 o -2 5 1 114.08 118.76 3.07 o -1 5 1 205.18 204.54 5.55 o 0 5 1 247.42 237.17 5.43 o 1 5 1 868.94 886.68 18.91 o 2 5 1 157.64 150.90 5.07 o 3 5 1 149.83 146.21 4.92 o 4 5 1 59.86 62.36 2.48 o 5 5 1 92.04 89.45 3.29 o 6 5 1 96.34 99.70 2.68 o 7 5 1 39.47 43.00 2.45 o 8 5 1 33.55 33.24 2.18 o -3 6 1 186.50 193.27 7.07 o -2 6 1 5.73 5.68 0.97 o -1 6 1 330.25 328.62 7.50 o 0 6 1 105.98 101.59 2.72 o 1 6 1 3.95 7.85 3.71 o 2 6 1 665.13 682.91 20.57 o 3 6 1 784.80 799.53 23.90 o 4 6 1 92.01 108.60 4.03 o 5 6 1 205.70 209.91 6.96 o 6 6 1 116.31 122.25 3.25 o 7 6 1 7.47 6.49 1.12 o -1 7 1 100.87 102.83 2.36 o 0 7 1 123.56 122.48 2.67 o 1 7 1 63.95 66.65 2.91 o 2 7 1 483.99 478.21 14.88 o 3 7 1 257.69 264.37 8.69 o 4 7 1 284.16 264.25 8.72 o 5 7 1 168.84 173.79 6.09 o 6 7 1 123.03 129.57 4.82 o 7 7 1 158.67 166.99 6.49 o 0 8 1 240.10 237.23 5.82 o 1 8 1 103.10 96.77 4.00 o 2 8 1 4.53 4.82 0.99 o 3 8 1 132.99 130.95 4.97 o 5 8 1 14.75 19.94 1.75 o 6 8 1 181.06 187.77 6.68 o -5 -8 2 14.77 13.66 1.42 o -4 -8 2 112.08 100.62 3.15 o -3 -8 2 67.83 67.94 3.22 o -2 -8 2 1.42 1.37 0.81 o -1 -8 2 1.19 0.18 0.69 o -7 -7 2 370.89 363.98 12.34 o -6 -7 2 103.48 110.23 4.51 o -5 -7 2 183.68 177.20 6.16 o -4 -7 2 206.47 208.25 7.19 o -3 -7 2 120.48 113.60 4.41 o -2 -7 2 21.06 20.19 1.52 o -1 -7 2 129.90 120.11 4.71 o 0 -7 2 34.14 33.80 2.44 o 1 -7 2 212.80 206.99 5.15 o -7 -6 2 212.68 213.99 7.73 o -6 -6 2 121.22 126.06 4.87 o -5 -6 2 358.02 368.69 11.50 o -4 -6 2 1.44 0.79 0.56 o -3 -6 2 443.18 444.56 13.81 o -2 -6 2 375.98 366.70 11.63 o -1 -6 2 68.98 73.38 3.14 o 0 -6 2 83.75 80.02 5.41 o 1 -6 2 35.01 33.19 1.33 o 2 -6 2 189.91 186.40 6.59 o 3 -6 2 101.45 114.69 4.61 o -8 -5 2 34.01 32.69 2.16 o -7 -5 2 26.93 28.11 1.88 o -6 -5 2 1199.21 1287.98 39.71 o -5 -5 2 3.86 4.79 0.65 o -4 -5 2 46.52 42.95 1.98 o -3 -5 2 244.22 248.10 5.19 o -2 -5 2 332.72 345.90 10.85 o -1 -5 2 39.48 38.41 1.88 o 0 -5 2 152.91 158.34 3.82 o 1 -5 2 6.22 6.89 0.88 o 2 -5 2 75.49 78.98 2.29 o 3 -5 2 21.10 20.75 1.50 o 4 -5 2 53.41 59.27 2.94 o -8 -4 2 201.49 195.55 7.22 o -7 -4 2 30.89 30.69 1.90 o -6 -4 2 293.65 309.76 10.29 o -5 -4 2 480.23 487.56 15.48 o -4 -4 2 650.89 677.79 14.54 o -3 -4 2 2.79 3.22 0.56 o -2 -4 2 755.83 775.31 15.27 o -1 -4 2 443.68 450.06 8.95 o 0 -4 2 182.56 179.20 4.80 o 1 -4 2 755.39 799.68 17.09 o 2 -4 2 2.42 5.58 0.99 o 3 -4 2 50.71 58.00 1.82 o 4 -4 2 214.13 213.34 7.50 o 5 -4 2 79.30 83.29 3.72 o -8 -3 2 156.32 157.82 6.09 o -7 -3 2 174.44 171.98 6.29 o -6 -3 2 8.59 9.22 1.04 o -5 -3 2 2280.63 2195.15 66.62 o -4 -3 2 829.56 858.05 18.16 o -3 -3 2 557.16 563.71 16.70 o -2 -3 2 1022.23 1017.53 19.92 o 0 -3 2 1118.06 1091.40 22.98 o 1 -3 2 2014.67 2062.09 43.16 o 2 -3 2 267.96 245.03 5.54 o 3 -3 2 465.59 482.63 10.55 o 4 -3 2 207.64 207.13 7.17 o 5 -3 2 237.32 245.82 8.51 o -8 -2 2 9.45 11.40 1.40 o -7 -2 2 337.05 338.97 11.35 o -6 -2 2 10.58 10.29 1.12 o -5 -2 2 216.83 217.04 7.27 o -4 -2 2 874.12 823.93 17.36 o -3 -2 2 965.34 984.53 20.68 o -2 -2 2 141.72 136.89 4.26 o 0 -2 2 401.61 390.68 6.48 o 1 -2 2 363.11 365.82 8.77 o 3 -2 2 50.14 37.30 1.18 o 4 -2 2 66.31 69.91 2.89 o 5 -2 2 412.76 414.00 13.46 o 6 -2 2 138.25 145.15 5.55 o -8 -1 2 25.81 24.37 1.93 o -7 -1 2 65.45 64.56 3.06 o -6 -1 2 290.14 287.33 9.63 o -5 -1 2 519.43 519.72 16.42 o -4 -1 2 319.31 308.26 9.89 o -3 -1 2 454.40 445.62 12.94 o -2 -1 2 49.49 51.13 1.24 o -1 -1 2 79.68 82.13 1.72 o 0 -1 2 303.82 301.19 5.95 o 1 -1 2 35.04 33.55 0.92 o 2 -1 2 1545.94 1547.82 46.80 o 3 -1 2 187.07 166.95 3.83 o 4 -1 2 395.74 407.85 8.90 o 5 -1 2 124.30 121.68 4.56 o 6 -1 2 142.63 135.95 5.17 o 7 -1 2 86.89 89.17 3.93 o -7 0 2 77.99 78.48 3.52 o -6 0 2 698.99 720.42 22.71 o -5 0 2 37.15 37.96 1.96 o -2 0 2 189.86 153.66 4.94 o -1 0 2 444.89 405.64 6.67 o 1 0 2 16.20 12.57 0.58 o 2 0 2 2.61 3.69 0.27 o 4 0 2 211.34 185.42 4.23 o 5 0 2 216.87 204.85 6.99 o 6 0 2 498.31 472.29 15.26 o 7 0 2 140.01 143.85 5.58 o -7 1 2 150.12 153.81 5.96 o -6 1 2 162.39 164.99 6.09 o -5 1 2 1667.14 1666.08 50.90 o -4 1 2 4.18 3.47 0.69 o -3 1 2 185.93 163.62 5.50 o 0 1 2 197.88 197.17 3.29 o 2 1 2 38.71 40.53 1.08 o 3 1 2 1245.37 1286.64 39.10 o 4 1 2 283.20 274.08 6.06 o 5 1 2 610.16 630.92 19.77 o 6 1 2 222.92 220.08 7.65 o 7 1 2 181.04 174.64 6.49 o -6 2 2 104.06 106.25 4.41 o -5 2 2 914.66 928.81 28.96 o -4 2 2 2.67 1.63 0.63 o -3 2 2 463.80 475.40 14.98 o -2 2 2 343.00 341.97 6.78 o -1 2 2 29.84 42.64 0.83 o 0 2 2 302.53 298.16 4.96 o 1 2 2 842.12 791.34 23.09 o 2 2 2 52.14 52.10 1.85 o 3 2 2 294.87 392.91 8.47 o 4 2 2 814.61 899.91 35.36 o 5 2 2 3.28 3.96 0.42 o 6 2 2 98.50 96.16 3.88 o 7 2 2 140.79 133.87 5.25 o 8 2 2 1.68 2.35 0.91 o -6 3 2 92.68 86.71 3.95 o -5 3 2 3.53 3.47 0.91 o -4 3 2 1154.16 1174.16 36.24 o -3 3 2 264.16 282.95 9.33 o -2 3 2 32.40 30.90 1.92 o -1 3 2 180.24 167.39 2.90 o 0 3 2 1056.99 1045.57 21.99 o 1 3 2 227.33 236.43 34.08 o 2 3 2 556.43 516.68 15.28 o 3 3 2 1.72 2.94 0.43 o 4 3 2 166.05 171.69 3.99 o 5 3 2 6.52 5.32 0.62 o 6 3 2 147.94 154.09 5.68 o 7 3 2 35.23 36.77 2.18 o 8 3 2 13.64 14.29 1.60 o -5 4 2 83.41 85.22 3.88 o -4 4 2 718.49 748.44 23.67 o -3 4 2 101.29 103.26 4.08 o -2 4 2 1130.36 1143.99 24.25 o -1 4 2 819.28 838.57 14.48 o 0 4 2 171.80 168.34 3.89 o 1 4 2 1475.87 1424.88 29.95 o 2 4 2 1316.18 1294.72 37.80 o 3 4 2 698.37 715.05 21.16 o 4 4 2 200.14 179.07 5.73 o 5 4 2 521.35 510.65 11.15 o 6 4 2 30.61 35.27 2.01 o 7 4 2 252.84 242.53 8.59 o 8 4 2 177.56 162.58 6.34 o -4 5 2 35.39 34.08 2.18 o -3 5 2 404.84 401.79 13.18 o -2 5 2 622.38 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