#------------------------------------------------------------------------------ #$Date: 2016-04-03 05:03:21 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181216 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/22/95/2229516.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2229516_Fobs loop_ _publ_author_name 'Hu, Qiao-Sheng' 'Deng, Xiao-Yu' 'Sun, Yu-Hui' 'Du, Zi-Yi' _publ_section_title ; Poly[bis[\m~2~-(dimethylazaniumyl)methylenediphosphonato]magnesium] ; _journal_coeditor_code SJ5102 _journal_issue 3 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m362 _journal_page_last m363 _journal_volume 67 _journal_year 2011 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 94.984 _cell_angle_gamma 90.000 _cell_length_a 5.4507 _cell_length_b 11.2166 _cell_length_c 12.5770 _exptl_crystal_F_000 476.00 _reflns_d_resolution_high 0.8108 _cod_data_source_file sj5102Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' [MG(H3L)2] in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 131.06 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 1666.42 1517.61 28.60 o 4 0 0 1.45 2.31 0.58 o 6 0 0 735.27 755.09 17.85 o 1 1 0 5416.84 4820.33 327.50 o 2 1 0 32.23 56.13 2.03 o 3 1 0 713.23 684.31 7.78 o 4 1 0 282.56 292.19 4.48 o 5 1 0 28.10 27.52 1.30 o 6 1 0 67.24 68.57 2.80 o 0 2 0 2402.59 2537.84 32.12 o 1 2 0 4123.30 4233.53 42.36 o 2 2 0 2032.97 2261.68 23.25 o 3 2 0 94.00 122.97 1.69 o 4 2 0 515.65 565.24 8.94 o 5 2 0 166.93 177.06 3.49 o 6 2 0 347.09 343.49 7.12 o 1 3 0 9447.20 8810.77 88.41 o 2 3 0 685.76 848.67 7.85 o 3 3 0 1803.88 1852.30 19.46 o 4 3 0 332.76 350.53 4.81 o 5 3 0 169.72 182.41 3.55 o 6 3 0 152.63 162.11 6.03 o 0 4 0 17176.98 15885.34 398.05 o 1 4 0 5187.63 5255.87 46.41 o 2 4 0 35.85 50.31 1.69 o 3 4 0 2.80 6.67 0.43 o 4 4 0 5.11 6.02 0.87 o 5 4 0 1130.24 1170.62 17.70 o 6 4 0 77.03 68.76 4.30 o 1 5 0 2283.29 2434.74 21.67 o 2 5 0 459.11 428.65 4.54 o 3 5 0 18.20 19.14 0.75 o 4 5 0 801.28 776.84 11.41 o 5 5 0 5.18 6.60 0.99 o 6 5 0 156.45 156.04 6.78 o 0 6 0 61.99 94.86 17.03 o 1 6 0 732.04 711.73 6.27 o 2 6 0 5440.68 5261.67 46.05 o 3 6 0 183.39 164.17 5.05 o 4 6 0 2033.60 1973.44 21.78 o 5 6 0 873.20 873.15 14.55 o 6 6 0 0.10 0.50 0.70 o 1 7 0 1731.54 1767.41 16.36 o 2 7 0 1594.58 1518.53 14.29 o 3 7 0 807.76 781.36 9.22 o 4 7 0 13.31 14.85 1.24 o 5 7 0 5.67 4.37 0.99 o 0 8 0 1.81 0.40 0.40 o 1 8 0 13.91 12.83 0.68 o 2 8 0 95.29 115.75 2.09 o 3 8 0 820.20 792.34 9.54 o 4 8 0 614.23 593.31 9.98 o 5 8 0 237.75 238.44 4.69 o 1 9 0 1638.43 1568.17 15.03 o 2 9 0 1.38 0.56 0.29 o 3 9 0 414.16 405.97 7.51 o 4 9 0 45.44 41.53 2.14 o 5 9 0 440.71 449.91 7.26 o 0 10 0 278.07 298.67 5.83 o 1 10 0 740.25 734.69 8.03 o 2 10 0 160.84 167.81 2.86 o 3 10 0 279.63 284.14 6.05 o 4 10 0 78.36 78.94 2.50 o 1 11 0 578.59 585.41 6.88 o 2 11 0 468.84 460.71 5.82 o 3 11 0 8.07 6.68 1.03 o 4 11 0 0.00 0.00 0.50 o 0 12 0 67.74 62.80 2.56 o 1 12 0 363.44 386.02 5.25 o 2 12 0 350.89 342.64 5.60 o 3 12 0 559.06 574.08 10.47 o 1 13 0 121.08 130.89 2.78 o 2 13 0 166.48 170.23 3.76 o -5 0 1 3562.78 3547.49 66.62 o -3 0 1 370.02 362.93 5.96 o -1 0 1 4.32 16.28 0.58 o 1 0 1 3777.36 3484.68 64.14 o 5 0 1 1535.35 1512.82 30.58 o -6 1 1 246.72 245.13 5.72 o -5 1 1 574.10 548.32 7.67 o -4 1 1 3068.34 3018.13 32.64 o -3 1 1 736.31 823.66 6.49 o -2 1 1 485.55 602.68 4.71 o -1 1 1 2123.49 2137.48 17.25 o 0 1 1 5438.38 5067.52 83.60 o 1 1 1 2074.06 2008.21 24.81 o 2 1 1 2146.99 2117.15 35.70 o 3 1 1 2633.54 2732.61 34.18 o 4 1 1 535.11 539.24 6.70 o 5 1 1 327.69 357.36 6.89 o 6 1 1 125.26 127.84 3.85 o -6 2 1 320.45 324.72 5.62 o -5 2 1 1.48 5.31 1.95 o -4 2 1 153.13 172.09 4.75 o -3 2 1 3185.07 3420.83 26.99 o -2 2 1 2875.10 3317.37 29.16 o -1 2 1 7243.94 6885.35 60.41 o 0 2 1 9.91 2.28 0.18 o 1 2 1 4.79 9.55 0.57 o 2 2 1 107.92 150.26 2.10 o 3 2 1 2.60 0.21 0.31 o 4 2 1 3131.67 3177.59 33.01 o 5 2 1 724.05 733.91 9.63 o 6 2 1 45.26 42.98 3.31 o -6 3 1 23.04 26.26 1.81 o -5 3 1 253.11 254.42 5.10 o -4 3 1 309.30 302.23 3.82 o -3 3 1 1782.82 1912.95 15.49 o -2 3 1 29.99 19.37 0.66 o -1 3 1 397.19 334.88 3.33 o 0 3 1 20.31 31.68 0.51 o 1 3 1 1495.61 1440.80 11.60 o 2 3 1 2133.12 2301.63 20.27 o 3 3 1 1087.13 1070.15 10.00 o 4 3 1 4.22 4.04 2.23 o 5 3 1 259.00 246.13 7.44 o 6 3 1 3.98 4.46 1.49 o -6 4 1 208.79 202.73 5.31 o -5 4 1 699.90 640.93 10.92 o -4 4 1 758.82 748.91 7.88 o -3 4 1 1033.10 991.79 10.87 o -2 4 1 189.17 202.06 2.36 o -1 4 1 1740.38 1759.04 14.11 o 0 4 1 4641.14 4575.00 54.02 o 1 4 1 658.32 678.07 5.85 o 2 4 1 59.68 63.69 0.98 o 3 4 1 141.65 134.55 1.91 o 4 4 1 345.98 293.28 42.65 o 6 4 1 644.08 671.61 17.36 o -6 5 1 226.56 244.40 7.52 o -5 5 1 54.99 44.69 2.16 o -4 5 1 89.30 79.44 2.56 o -3 5 1 92.73 90.97 3.90 o -2 5 1 940.04 933.01 7.96 o -1 5 1 2467.37 2483.30 19.82 o 0 5 1 1146.06 1288.31 10.63 o 1 5 1 820.71 785.24 7.62 o 2 5 1 18.19 28.50 0.64 o 3 5 1 146.66 172.45 2.45 o 4 5 1 768.43 746.38 9.31 o 6 5 1 48.79 44.63 3.64 o -6 6 1 78.26 84.80 4.96 o -5 6 1 2.79 2.81 0.82 o -4 6 1 893.67 863.37 12.86 o -3 6 1 742.07 723.96 7.46 o -2 6 1 284.60 292.00 3.03 o -1 6 1 1381.22 1443.94 14.67 o 0 6 1 2608.49 2663.47 21.32 o 1 6 1 617.30 636.09 10.74 o 2 6 1 165.60 146.47 2.17 o 3 6 1 603.96 596.14 6.36 o 4 6 1 192.48 205.66 3.71 o 5 6 1 123.91 115.70 3.41 o -5 7 1 43.87 42.51 2.38 o -4 7 1 1090.80 1041.53 11.03 o -3 7 1 3.33 6.62 1.64 o -2 7 1 4180.65 4147.56 36.69 o -1 7 1 1.34 0.71 0.21 o 0 7 1 2086.66 2043.74 16.71 o 1 7 1 770.74 744.55 8.68 o 2 7 1 142.60 141.96 2.24 o 3 7 1 1072.49 1048.43 10.42 o 4 7 1 835.74 821.72 15.12 o 5 7 1 76.87 79.29 2.89 o -5 8 1 724.20 710.84 12.62 o -4 8 1 0.23 0.57 0.55 o -3 8 1 0.10 0.69 0.36 o -2 8 1 5.82 7.98 0.59 o -1 8 1 521.06 559.42 6.15 o 0 8 1 595.92 658.56 7.61 o 1 8 1 1477.29 1426.84 16.68 o 2 8 1 1858.45 1847.24 17.30 o 3 8 1 701.71 667.01 8.97 o 4 8 1 402.30 401.62 7.60 o 5 8 1 41.39 41.14 2.40 o -5 9 1 40.17 46.12 2.51 o -4 9 1 215.71 231.91 3.78 o -3 9 1 2.62 3.35 0.53 o -2 9 1 40.70 35.73 1.16 o -1 9 1 44.89 65.28 1.54 o 0 9 1 14.24 16.27 0.82 o 1 9 1 0.19 3.08 0.63 o 2 9 1 435.06 417.59 5.10 o 3 9 1 46.31 49.05 1.62 o 4 9 1 371.10 379.99 7.44 o 5 9 1 174.78 178.07 4.84 o -4 10 1 152.29 144.67 3.42 o -3 10 1 324.51 326.17 4.66 o -2 10 1 9.71 7.90 0.84 o -1 10 1 44.26 44.06 1.35 o 0 10 1 19.79 33.21 1.17 o 1 10 1 763.41 779.43 8.42 o 2 10 1 727.75 690.92 8.86 o 3 10 1 28.16 26.77 1.26 o 4 10 1 163.18 155.30 4.42 o -4 11 1 37.42 43.46 1.87 o -3 11 1 9.78 12.75 1.06 o -2 11 1 56.74 56.98 1.62 o -1 11 1 1.85 1.69 1.32 o 0 11 1 13.40 16.95 0.90 o 1 11 1 228.41 214.54 3.44 o 2 11 1 61.93 59.64 1.95 o 3 11 1 969.19 956.60 15.06 o 4 11 1 251.62 248.43 6.02 o -3 12 1 2.29 3.89 0.95 o -2 12 1 16.79 19.90 1.11 o -1 12 1 84.45 84.17 2.09 o 0 12 1 87.41 93.61 2.20 o 1 12 1 78.62 77.34 2.84 o 2 12 1 443.84 459.42 6.90 o 3 12 1 57.66 54.20 2.61 o -2 13 1 1091.14 1105.04 13.59 o -1 13 1 164.54 171.45 3.27 o 0 13 1 83.58 90.75 2.27 o 1 13 1 86.69 90.47 2.60 o 2 13 1 244.02 246.82 4.71 o -6 0 2 783.06 758.72 18.02 o -4 0 2 7163.60 6861.31 88.42 o -2 0 2 5719.46 5661.36 73.09 o 0 0 2 1322.17 1248.01 22.81 o 6 0 2 187.37 178.36 6.61 o -6 1 2 58.78 68.34 2.29 o -5 1 2 591.43 581.03 8.08 o -4 1 2 88.14 104.07 2.02 o -3 1 2 4.96 1.65 0.35 o -2 1 2 1153.82 1126.62 9.43 o -1 1 2 3689.32 3531.19 31.69 o 0 1 2 620.49 713.02 6.43 o 1 1 2 1669.60 1758.22 14.16 o 2 1 2 1.18 4.89 0.35 o 3 1 2 409.55 418.37 6.23 o 4 1 2 3667.42 3604.02 61.00 o 5 1 2 424.64 447.13 11.24 o 6 1 2 265.32 277.01 6.25 o -6 2 2 294.15 301.56 5.37 o -5 2 2 141.02 138.16 3.01 o -4 2 2 72.46 74.95 1.90 o -3 2 2 5.31 9.28 0.35 o -2 2 2 295.47 299.31 3.29 o -1 2 2 2221.11 2417.00 21.59 o 0 2 2 1740.25 1799.72 13.12 o 1 2 2 1389.53 1368.54 10.97 o 2 2 2 240.40 225.20 4.03 o 3 2 2 12.78 9.09 0.63 o 4 2 2 1423.86 1519.84 19.97 o 5 2 2 2600.30 2585.94 49.09 o 6 2 2 8.18 6.94 1.65 o -6 3 2 14.89 17.67 1.57 o -5 3 2 1168.28 1129.82 13.80 o -4 3 2 124.01 128.31 4.88 o -3 3 2 206.99 167.49 1.91 o -1 3 2 3006.16 2895.64 22.84 o 0 3 2 1178.90 1119.00 8.33 o 1 3 2 15.67 30.76 0.59 o 2 3 2 2659.16 2714.61 30.41 o 3 3 2 4.27 2.82 0.39 o 4 3 2 2974.12 2913.46 30.40 o 6 3 2 7.97 6.28 1.65 o -6 4 2 199.96 197.51 5.95 o -5 4 2 1300.37 1311.88 19.64 o -4 4 2 135.19 109.13 1.97 o -3 4 2 249.45 291.54 4.88 o -2 4 2 261.87 309.42 3.02 o -1 4 2 3911.07 3993.62 31.56 o 0 4 2 166.11 182.88 1.95 o 1 4 2 132.22 114.65 1.44 o 2 4 2 2635.41 2719.03 21.68 o 3 4 2 379.33 388.44 3.86 o 4 4 2 40.31 43.35 2.09 o 6 4 2 8.63 10.41 1.98 o -6 5 2 763.82 812.69 13.90 o -5 5 2 581.88 537.60 9.70 o -4 5 2 183.19 190.91 3.37 o -3 5 2 32.42 29.03 0.87 o -2 5 2 343.72 352.77 3.46 o -1 5 2 146.63 168.12 1.75 o 0 5 2 1594.14 1588.33 11.85 o 1 5 2 227.08 269.50 2.80 o 2 5 2 353.01 297.24 3.50 o 3 5 2 335.40 323.34 4.58 o 4 5 2 20.04 20.50 1.01 o 5 5 2 23.33 26.12 2.48 o 6 5 2 217.91 221.17 5.96 o -6 6 2 1007.68 1050.90 22.15 o -5 6 2 207.94 214.75 5.26 o -4 6 2 494.28 498.80 8.76 o -3 6 2 31.82 26.06 1.07 o -2 6 2 172.06 152.49 1.77 o -1 6 2 58.96 55.12 0.99 o 0 6 2 2963.89 2985.79 27.74 o 1 6 2 1346.66 1349.02 11.31 o 2 6 2 780.63 771.12 8.21 o 3 6 2 584.94 597.18 8.35 o 4 6 2 303.52 297.47 5.86 o 5 6 2 47.52 41.63 2.02 o -5 7 2 203.33 196.51 5.08 o -4 7 2 319.43 310.05 4.36 o -3 7 2 9.42 7.23 0.59 o -2 7 2 1782.39 1664.76 16.61 o -1 7 2 786.65 783.67 6.41 o 0 7 2 42.48 59.22 1.24 o 1 7 2 343.18 341.71 3.64 o 2 7 2 326.54 341.68 4.32 o 3 7 2 2075.13 2061.32 21.90 o 4 7 2 0.47 1.61 0.63 o 5 7 2 14.89 13.14 1.27 o -5 8 2 197.34 208.49 4.45 o -4 8 2 7.58 9.19 0.74 o -3 8 2 1453.56 1359.89 13.69 o -2 8 2 443.85 465.26 5.34 o -1 8 2 258.48 254.86 2.98 o 0 8 2 1572.58 1577.22 14.76 o 1 8 2 99.51 112.60 2.01 o 2 8 2 92.51 97.26 1.88 o 3 8 2 699.69 683.81 8.57 o 4 8 2 22.81 27.45 1.90 o 5 8 2 208.88 214.13 5.32 o -5 9 2 524.13 551.88 10.75 o -4 9 2 7.08 5.89 0.67 o -3 9 2 2233.37 2161.12 20.86 o -2 9 2 5.57 4.95 0.49 o -1 9 2 19.90 19.00 1.41 o 0 9 2 0.35 1.65 0.39 o 1 9 2 1071.13 1035.96 10.90 o 2 9 2 7.65 3.93 0.60 o 3 9 2 621.16 619.41 8.13 o 4 9 2 24.61 22.49 1.62 o -4 10 2 342.13 351.00 5.14 o -3 10 2 48.96 44.91 1.48 o -2 10 2 6.92 7.67 0.65 o -1 10 2 829.96 791.69 8.52 o 0 10 2 512.75 491.01 5.87 o 1 10 2 53.46 40.72 1.31 o 2 10 2 178.00 175.48 3.48 o 3 10 2 38.03 48.94 5.03 o 4 10 2 11.39 11.60 1.31 o -4 11 2 439.87 442.74 8.71 o -3 11 2 349.35 347.32 8.50 o -2 11 2 922.29 904.09 9.79 o -1 11 2 35.96 34.81 1.27 o 0 11 2 205.80 199.29 3.30 o 1 11 2 44.57 46.10 1.68 o 2 11 2 29.33 23.21 1.30 o 3 11 2 144.55 138.57 3.20 o -3 12 2 428.25 426.89 7.89 o -2 12 2 621.12 623.10 7.44 o -1 12 2 554.40 552.41 6.79 o 0 12 2 138.24 154.60 3.36 o 1 12 2 98.53 91.07 2.53 o 2 12 2 43.60 47.55 1.86 o 3 12 2 18.49 20.45 1.82 o -2 13 2 376.18 379.02 6.41 o -1 13 2 2.91 2.50 0.60 o 0 13 2 224.89 216.43 4.32 o 1 13 2 97.72 100.72 2.78 o 2 13 2 88.67 87.48 2.65 o -5 0 3 0.62 0.50 0.47 o -3 0 3 1290.59 1424.05 19.64 o -1 0 3 214.65 289.41 3.37 o 1 0 3 7581.99 6855.51 96.45 o -6 1 3 0.32 0.48 0.50 o -5 1 3 38.95 42.01 1.40 o -4 1 3 738.42 677.19 7.54 o -3 1 3 359.02 365.06 3.68 o -2 1 3 172.04 150.13 1.73 o -1 1 3 4381.52 4412.45 35.83 o 0 1 3 431.63 466.27 5.21 o 1 1 3 6647.56 6170.84 59.60 o 2 1 3 1693.76 1883.70 24.30 o 3 1 3 1163.59 1178.09 21.32 o 4 1 3 832.68 813.60 15.70 o 6 1 3 334.92 361.95 7.53 o -6 2 3 587.65 589.91 8.68 o -5 2 3 892.75 858.38 11.03 o -4 2 3 79.44 71.72 1.90 o -3 2 3 104.16 118.96 1.65 o -2 2 3 639.04 763.55 6.69 o -1 2 3 125.08 140.42 1.91 o 0 2 3 6683.75 6406.32 59.81 o 1 2 3 1207.33 1106.16 9.06 o 2 2 3 659.48 689.42 6.78 o 3 2 3 12.52 15.44 0.99 o 4 2 3 2059.52 2047.23 35.87 o 5 2 3 127.76 138.69 5.12 o -6 3 3 66.85 68.74 3.14 o -5 3 3 428.84 407.67 6.23 o -4 3 3 75.01 81.48 2.06 o -3 3 3 619.43 701.76 7.19 o -2 3 3 2989.88 3263.50 38.45 o -1 3 3 45.61 31.61 1.10 o 0 3 3 98.79 137.72 1.99 o 1 3 3 246.42 266.02 2.54 o 2 3 3 15.25 9.61 0.40 o 3 3 3 377.64 398.00 5.13 o 4 3 3 1289.77 1305.37 23.80 o -6 4 3 68.36 67.26 2.92 o -5 4 3 960.29 925.34 11.79 o -4 4 3 723.19 719.46 10.35 o -3 4 3 410.59 451.92 5.05 o -2 4 3 814.32 824.27 16.27 o -1 4 3 795.06 798.28 14.14 o 0 4 3 135.44 124.25 1.36 o 1 4 3 41.65 48.14 0.94 o 2 4 3 1379.47 1386.48 12.77 o 3 4 3 5.47 6.97 0.67 o 4 4 3 245.78 247.57 6.20 o 5 4 3 5.38 9.92 1.65 o 6 4 3 24.03 24.13 2.64 o -6 5 3 0.41 0.50 0.70 o -5 5 3 413.31 410.29 8.06 o -4 5 3 102.03 84.42 2.11 o -3 5 3 619.03 614.54 7.78 o -2 5 3 970.45 988.00 8.42 o -1 5 3 0.07 1.04 0.17 o 0 5 3 245.83 231.69 2.22 o 1 5 3 1093.70 1099.58 9.31 o 2 5 3 2758.27 2803.68 30.82 o 3 5 3 5878.70 5755.27 57.51 o 4 5 3 162.19 157.65 2.97 o 5 5 3 38.62 44.80 3.14 o -6 6 3 0.41 0.00 0.75 o -5 6 3 0.09 0.41 0.58 o -4 6 3 525.56 524.81 7.11 o -3 6 3 44.38 41.90 1.38 o -2 6 3 1.11 4.09 0.73 o -1 6 3 1026.02 1008.58 7.93 o 0 6 3 391.53 459.07 3.97 o 1 6 3 3.85 3.10 0.32 o 2 6 3 1069.22 1048.50 9.19 o 3 6 3 212.00 207.18 3.48 o 4 6 3 1001.33 950.58 11.24 o 5 6 3 583.87 571.27 14.88 o -5 7 3 83.63 85.40 4.05 o -4 7 3 81.01 86.00 2.24 o -3 7 3 162.91 157.53 2.67 o -2 7 3 249.62 238.74 3.19 o -1 7 3 2859.05 2801.48 20.67 o 0 7 3 407.09 429.22 4.30 o 1 7 3 514.15 492.86 4.85 o 2 7 3 486.51 482.77 6.30 o 3 7 3 97.09 97.13 8.48 o 4 7 3 868.68 820.18 12.80 o 5 7 3 90.10 101.84 4.63 o -5 8 3 402.18 409.28 6.93 o -4 8 3 78.41 78.05 1.95 o -3 8 3 1249.22 1217.83 12.42 o -2 8 3 2468.30 2371.50 19.56 o -1 8 3 354.88 369.99 4.46 o 0 8 3 1890.48 1834.68 15.34 o 1 8 3 6.41 5.40 0.44 o 2 8 3 883.55 859.61 10.23 o 3 8 3 188.90 190.19 3.50 o 4 8 3 159.05 165.71 4.35 o 5 8 3 50.25 47.60 2.38 o -5 9 3 13.29 13.35 1.21 o -4 9 3 106.78 110.39 2.65 o -3 9 3 27.46 29.17 1.15 o 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