#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/01/2230113.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2230113_Fobs loop_ _publ_author_name 'Qian, Xiao-Min' 'Luo, Yang-Hui' 'Li, Jin-Feng' 'Mao, Shu-Lin' 'Gao, Ge' _publ_section_title ; Dichlorido[bis(2-ethyl-5-methyl-1H-imidazol-4-yl-\kN^3^)methane]cobalt(II) monohydrate ; _journal_coeditor_code PV2382 _journal_issue 5 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m575 _journal_volume 67 _journal_year 2011 _space_group_IT_number 11 _symmetry_space_group_name_Hall '-P 2yb' _symmetry_space_group_name_H-M 'P 1 21/m 1' _cell_angle_alpha 90.000 _cell_angle_beta 97.045 _cell_angle_gamma 90.000 _cell_length_a 8.3927 _cell_length_b 12.1388 _cell_length_c 8.5860 _exptl_crystal_F_000 394.00 _reflns_d_resolution_high 0.8403 _[local]_cod_data_source_file pv2382Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 101029h in P2(1)/m' _shelx_refln_list_code 4 _shelx_f_calc_maximum 121.50 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z' '-x, -y, -z' 'x, -y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 2328.30 2518.92 65.54 o 2 0 0 2311.10 2509.51 54.59 o 3 0 0 25.58 23.47 3.01 o 4 0 0 2.26 12.11 2.09 o 5 0 0 97.42 102.77 4.64 o 6 0 0 2503.09 2534.55 51.59 o 7 0 0 12.78 6.48 5.39 o 8 0 0 131.88 158.70 17.62 o 9 0 0 2.23 -6.49 8.58 o 1 1 0 4268.17 4776.81 60.88 o 2 1 0 1861.71 2079.93 27.97 o 3 1 0 39.62 42.39 2.15 o 4 1 0 482.48 468.68 7.99 o 5 1 0 1004.69 963.86 14.34 o 6 1 0 22.31 19.51 3.40 o 7 1 0 538.49 532.23 15.01 o 8 1 0 41.75 48.98 6.80 o 9 1 0 53.64 52.09 9.81 o 0 2 0 776.75 852.99 17.70 o 1 2 0 3757.70 3950.57 45.94 o 2 2 0 166.44 164.43 5.46 o 3 2 0 426.81 488.60 9.13 o 4 2 0 136.28 143.91 5.05 o 5 2 0 511.87 505.81 10.72 o 6 2 0 1021.49 1080.99 22.30 o 7 2 0 123.43 148.02 8.87 o 8 2 0 118.80 126.07 9.29 o 9 2 0 16.05 10.82 6.14 o 1 3 0 11933.74 12320.82 140.34 o 2 3 0 2773.12 2916.57 35.15 o 3 3 0 1368.44 1388.07 20.94 o 4 3 0 1246.24 1372.02 29.04 o 5 3 0 722.88 704.33 13.81 o 6 3 0 0.74 1.70 2.94 o 7 3 0 225.72 238.35 14.79 o 8 3 0 165.14 175.71 11.14 o 9 3 0 183.97 208.01 17.94 o 0 4 0 14761.66 14778.45 386.09 o 1 4 0 1260.81 1294.04 15.20 o 2 4 0 1352.00 1429.19 26.92 o 3 4 0 61.18 75.75 3.25 o 4 4 0 269.01 253.28 7.20 o 5 4 0 144.46 135.71 5.86 o 6 4 0 406.22 383.70 10.49 o 7 4 0 290.18 289.95 17.20 o 8 4 0 182.93 189.59 11.61 o 9 4 0 1.06 -3.41 6.44 o 1 5 0 1489.20 1442.70 17.24 o 2 5 0 454.02 477.20 8.15 o 3 5 0 60.44 63.02 3.32 o 4 5 0 86.64 62.16 4.57 o 5 5 0 1389.93 1422.72 24.09 o 6 5 0 95.37 96.77 6.52 o 7 5 0 110.83 136.76 13.35 o 8 5 0 55.48 70.30 8.71 o 9 5 0 25.33 13.87 7.62 o 0 6 0 2828.18 2470.77 39.94 o 1 6 0 940.87 983.13 14.97 o 2 6 0 859.03 816.91 11.29 o 3 6 0 212.70 204.96 5.69 o 4 6 0 84.96 77.26 5.65 o 5 6 0 188.90 175.93 7.22 o 6 6 0 345.14 378.43 11.17 o 7 6 0 206.98 208.03 12.98 o 8 6 0 170.94 186.48 11.76 o 9 6 0 1.86 7.70 7.77 o 1 7 0 2796.83 2736.80 43.19 o 2 7 0 474.77 439.91 7.70 o 3 7 0 259.35 238.33 7.84 o 4 7 0 202.93 195.26 7.38 o 5 7 0 247.53 268.67 9.13 o 6 7 0 40.25 45.63 7.18 o 7 7 0 157.76 185.48 11.98 o 8 7 0 20.71 32.23 8.08 o 0 8 0 3765.16 3874.38 61.65 o 1 8 0 3.87 -1.02 2.25 o 2 8 0 35.74 29.57 4.89 o 3 8 0 7.41 0.95 2.94 o 4 8 0 27.59 30.17 4.78 o 5 8 0 3.42 1.71 3.86 o 6 8 0 587.30 598.11 15.28 o 7 8 0 0.26 5.13 5.57 o 8 8 0 13.22 11.13 7.74 o 1 9 0 536.75 511.80 14.92 o 2 9 0 9.27 5.75 3.29 o 3 9 0 33.55 29.23 4.04 o 4 9 0 33.79 38.98 5.34 o 5 9 0 254.16 264.83 9.98 o 6 9 0 3.56 -2.44 5.39 o 7 9 0 109.46 125.81 9.59 o 0 10 0 1795.13 1835.00 65.45 o 1 10 0 3.62 -2.52 3.35 o 2 10 0 141.24 155.36 8.58 o 3 10 0 20.62 13.49 4.66 o 4 10 0 24.38 21.38 5.41 o 5 10 0 2.99 -0.59 6.43 o 6 10 0 172.72 205.03 13.53 o 7 10 0 19.65 23.85 8.77 o 1 11 0 188.77 179.31 9.63 o 2 11 0 363.16 372.74 14.11 o 3 11 0 222.11 194.87 21.03 o 4 11 0 97.40 109.36 13.35 o 5 11 0 50.38 38.63 10.32 o 6 11 0 5.06 2.36 8.98 o 0 12 0 95.18 89.01 16.30 o 1 12 0 80.04 72.82 11.48 o 2 12 0 21.49 27.37 9.30 o 3 12 0 0.03 -7.46 7.45 o 4 12 0 32.01 36.78 10.58 o 5 12 0 16.56 14.22 10.07 o 1 13 0 150.13 134.77 14.54 o 2 13 0 0.60 -9.49 9.89 o 3 13 0 0.21 -3.29 8.23 o 4 13 0 9.46 1.18 9.02 o 0 14 0 158.52 240.96 24.23 o 1 14 0 10.12 1.87 9.44 o 2 14 0 28.27 25.06 14.98 o -9 0 1 3.11 11.34 10.82 o -8 0 1 5.43 10.10 8.56 o -7 0 1 3796.46 3963.84 115.12 o -6 0 1 123.78 133.87 14.10 o -5 0 1 2892.37 3005.54 60.11 o -4 0 1 40.78 36.32 3.86 o -3 0 1 1964.18 2212.37 61.71 o -2 0 1 1374.58 1510.77 41.98 o -1 0 1 867.95 946.41 26.03 o 0 0 1 3994.91 4086.93 99.31 o 1 0 1 4216.72 4629.66 81.60 o 2 0 1 24.82 26.16 2.60 o 3 0 1 3593.91 4015.82 92.98 o 4 0 1 90.57 77.81 8.35 o 5 0 1 139.24 146.26 7.77 o 6 0 1 643.09 679.30 19.09 o 7 0 1 1425.38 1427.97 56.19 o 8 0 1 220.59 186.09 17.14 o 9 0 1 218.29 234.77 21.10 o -9 1 1 13.10 5.69 7.08 o -8 1 1 263.03 261.85 13.98 o -7 1 1 41.19 32.46 5.18 o -6 1 1 2065.81 2193.79 38.18 o -5 1 1 330.72 296.78 6.34 o -4 1 1 108.25 129.37 4.47 o -3 1 1 5.84 2.87 1.56 o -2 1 1 637.97 697.34 12.33 o -1 1 1 744.55 777.10 34.73 o 0 1 1 4636.26 4696.94 113.73 o 1 1 1 34.93 25.84 2.24 o 2 1 1 66.17 62.70 2.13 o 3 1 1 1471.81 1474.61 18.77 o 4 1 1 340.48 323.22 6.42 o 5 1 1 2042.86 2131.05 27.40 o 6 1 1 166.12 160.93 6.23 o 7 1 1 1.58 -0.16 3.95 o 8 1 1 328.49 329.35 12.28 o 9 1 1 44.11 60.63 14.16 o -9 2 1 44.64 35.23 9.13 o -8 2 1 145.52 159.99 9.98 o -7 2 1 269.00 283.29 10.53 o -6 2 1 1185.67 1260.08 21.53 o -5 2 1 368.02 361.22 9.01 o -4 2 1 151.28 139.03 4.83 o -3 2 1 9.78 10.41 1.79 o -2 2 1 875.84 908.29 17.16 o -1 2 1 1604.88 1706.71 22.33 o 0 2 1 714.84 698.11 12.30 o 1 2 1 850.22 919.19 20.06 o 2 2 1 1475.93 1505.33 21.39 o 3 2 1 909.91 980.89 13.37 o 4 2 1 2265.79 2374.28 29.60 o 5 2 1 56.03 58.74 3.62 o 6 2 1 137.29 130.01 7.49 o 7 2 1 34.59 26.34 5.21 o 8 2 1 92.05 93.42 8.55 o 9 2 1 353.57 347.70 27.38 o -9 3 1 20.23 6.67 6.74 o -8 3 1 581.76 564.74 16.84 o -7 3 1 13.20 9.98 4.95 o -6 3 1 1593.88 1652.12 32.05 o -5 3 1 1133.03 1140.24 19.48 o -4 3 1 1263.81 1419.76 23.82 o -3 3 1 299.20 316.22 7.16 o -2 3 1 3008.82 3168.03 62.09 o -1 3 1 492.51 500.96 8.32 o 0 3 1 515.79 443.34 7.59 o 1 3 1 551.39 578.26 14.84 o 2 3 1 705.00 692.90 14.25 o 3 3 1 1396.73 1443.36 21.80 o 4 3 1 2941.23 3112.73 37.87 o 5 3 1 209.39 185.55 6.41 o 6 3 1 134.51 131.49 6.42 o 7 3 1 25.18 13.70 4.94 o 8 3 1 282.22 285.77 11.95 o 9 3 1 76.91 102.60 10.19 o -9 4 1 8.46 1.57 6.56 o -8 4 1 14.76 17.53 6.43 o -7 4 1 1670.89 1764.48 34.29 o -6 4 1 117.46 116.15 6.73 o -5 4 1 682.15 660.72 31.58 o -4 4 1 341.32 321.96 8.21 o -3 4 1 422.71 414.48 7.83 o -2 4 1 44.04 44.01 2.11 o -1 4 1 937.43 1037.07 12.76 o 0 4 1 740.06 762.08 26.61 o 1 4 1 23.37 17.54 1.75 o 2 4 1 1057.01 1171.97 16.11 o 3 4 1 1817.35 1788.95 23.53 o 4 4 1 556.60 547.06 11.41 o 5 4 1 401.72 379.28 9.77 o 6 4 1 69.39 64.15 5.31 o 7 4 1 180.11 175.59 9.15 o 8 4 1 2.41 -3.06 5.46 o 9 4 1 304.07 297.32 13.58 o -9 5 1 2.74 0.38 9.12 o -8 5 1 361.79 352.97 34.46 o -7 5 1 47.92 52.16 6.01 o -6 5 1 144.04 157.35 7.17 o -5 5 1 896.71 887.08 17.06 o -4 5 1 5.04 4.30 1.94 o -3 5 1 63.91 80.69 4.67 o -2 5 1 2239.60 2478.01 28.00 o -1 5 1 396.19 444.24 6.97 o 0 5 1 306.96 316.78 5.58 o 1 5 1 729.84 721.66 14.16 o 2 5 1 892.02 924.33 23.95 o 3 5 1 144.78 122.00 5.98 o 4 5 1 49.57 44.30 4.70 o 5 5 1 994.02 1012.14 23.60 o 6 5 1 8.02 7.17 3.81 o 7 5 1 55.63 62.40 7.62 o 8 5 1 244.23 260.14 12.04 o 9 5 1 3.83 5.48 7.01 o -9 6 1 7.61 3.42 7.60 o -8 6 1 14.69 14.98 6.81 o -7 6 1 414.79 457.27 13.07 o -6 6 1 386.25 370.37 10.98 o -5 6 1 575.52 586.90 13.38 o -4 6 1 5.07 5.02 2.92 o -3 6 1 47.70 53.99 6.02 o -2 6 1 175.22 158.40 5.07 o -1 6 1 858.57 727.11 13.52 o 0 6 1 246.25 235.12 7.07 o 1 6 1 171.84 131.89 4.27 o 2 6 1 588.55 565.46 9.99 o 3 6 1 840.17 829.45 14.68 o 4 6 1 865.30 849.70 16.38 o 5 6 1 349.15 335.48 11.71 o 6 6 1 3.02 -2.53 3.46 o 7 6 1 3.39 -3.56 3.96 o 8 6 1 20.49 18.85 6.91 o -8 7 1 181.89 214.14 16.01 o -7 7 1 4.18 0.78 4.84 o -6 7 1 975.12 1037.26 20.91 o -5 7 1 300.60 306.08 11.51 o -4 7 1 363.93 382.89 18.82 o -3 7 1 62.18 61.94 4.08 o -2 7 1 331.36 314.47 6.48 o -1 7 1 158.20 146.70 5.09 o 0 7 1 563.60 565.01 9.14 o 1 7 1 98.19 133.68 7.86 o 2 7 1 126.50 105.35 5.96 o 3 7 1 376.75 360.50 8.27 o 4 7 1 861.55 832.15 18.16 o 5 7 1 185.57 168.39 11.25 o 6 7 1 154.40 170.05 8.70 o 7 7 1 10.49 10.87 5.20 o 8 7 1 166.36 222.16 13.12 o -8 8 1 1.98 -0.56 8.35 o -7 8 1 419.07 439.87 13.69 o -6 8 1 98.40 123.07 8.63 o -5 8 1 175.61 189.75 8.48 o -4 8 1 49.61 61.21 5.97 o -3 8 1 49.09 59.71 4.50 o -2 8 1 0.77 -1.81 2.35 o -1 8 1 445.29 454.40 9.76 o 0 8 1 357.42 386.64 16.39 o 1 8 1 428.74 451.48 9.60 o 2 8 1 2.08 -1.51 2.63 o 3 8 1 173.35 148.57 7.79 o 4 8 1 148.16 150.57 7.36 o 5 8 1 0.57 -1.83 3.93 o 6 8 1 261.25 236.72 9.82 o 7 8 1 121.01 136.18 9.41 o 8 8 1 2.30 -4.52 10.19 o -7 9 1 24.98 13.72 6.39 o -6 9 1 307.83 338.63 12.04 o -5 9 1 2.23 -4.29 4.37 o -4 9 1 69.53 49.01 6.50 o -3 9 1 0.13 -2.07 2.90 o -2 9 1 194.97 182.50 8.48 o -1 9 1 59.84 59.77 6.33 o 0 9 1 480.30 490.81 10.30 o 1 9 1 19.03 14.74 4.11 o 2 9 1 81.91 82.23 6.20 o 3 9 1 75.58 73.20 7.41 o 4 9 1 15.28 7.30 5.20 o 5 9 1 578.65 605.66 18.44 o 6 9 1 33.07 28.80 7.40 o 7 9 1 0.14 -2.60 6.45 o -7 10 1 209.35 288.24 15.53 o -6 10 1 70.75 67.93 9.19 o -5 10 1 200.74 204.47 11.51 o -4 10 1 2.55 2.90 6.06 o -3 10 1 143.04 147.28 8.61 o -2 10 1 93.66 73.70 6.61 o -1 10 1 81.29 82.49 7.99 o 0 10 1 201.23 172.88 7.97 o 1 10 1 91.58 88.80 6.61 o 2 10 1 85.65 93.68 6.94 o 3 10 1 366.49 381.44 24.15 o 4 10 1 55.37 53.09 8.08 o 5 10 1 66.13 74.54 8.82 o 6 10 1 24.02 21.54 7.76 o -6 11 1 109.69 141.85 15.33 o -5 11 1 119.61 139.80 11.44 o -4 11 1 60.82 74.07 12.24 o -3 11 1 3.48 -8.74 5.83 o -2 11 1 198.30 192.94 9.12 o -1 11 1 27.11 17.30 5.60 o 0 11 1 113.21 154.49 9.93 o 1 11 1 1.52 2.79 4.31 o 2 11 1 0.44 0.43 4.41 o 3 11 1 106.12 129.76 14.99 o 4 11 1 247.19 249.30 12.45 o 5 11 1 16.41 13.62 7.15 o 6 11 1 8.85 5.20 7.66 o -5 12 1 4.92 15.55 12.43 o -4 12 1 22.48 9.24 8.38 o -3 12 1 31.07 26.84 11.08 o -2 12 1 8.38 3.36 7.34 o -1 12 1 67.65 89.00 12.10 o 0 12 1 28.05 18.18 7.96 o 1 12 1 2.68 0.83 6.66 o 2 12 1 42.13 35.96 7.39 o 3 12 1 85.98 94.85 12.34 o 4 12 1 40.46 30.03 10.83 o 5 12 1 7.84 9.19 9.34 o -4 13 1 5.03 -1.55 9.51 o -3 13 1 3.56 4.98 8.93 o -2 13 1 104.31 121.06 16.50 o -1 13 1 9.69 -2.70 7.32 o 0 13 1 3.22 -3.37 6.86 o 1 13 1 60.69 49.33 17.36 o 2 13 1 62.12 82.76 19.29 o 3 13 1 8.15 11.75 8.80 o 4 13 1 41.51 30.69 11.94 o -2 14 1 2.68 -1.37 13.21 o -1 14 1 47.46 48.70 11.84 o 0 14 1 20.25 14.65 9.81 o 1 14 1 6.49 8.47 9.00 o 2 14 1 3.21 -4.79 12.79 o -9 0 2 0.33 -5.28 8.99 o -8 0 2 56.05 59.13 12.47 o -7 0 2 583.48 604.38 28.64 o -6 0 2 541.42 568.07 26.08 o -5 0 2 4.37 0.06 4.43 o -4 0 2 503.83 443.70 18.72 o -3 0 2 1658.91 1760.41 50.51 o -2 0 2 9.06 0.96 3.42 o -1 0 2 2323.23 2768.49 73.05 o 0 0 2 10978.37 11771.25 335.17 o 1 0 2 9534.15 10452.81 182.11 o 2 0 2 4206.56 4517.88 81.17 o 3 0 2 2918.61 2877.15 54.16 o 4 0 2 4.27 6.28 3.38 o 5 0 2 1342.18 1335.15 29.84 o 6 0 2 5.70 7.46 4.62 o 7 0 2 69.62 67.90 8.63 o 8 0 2 223.51 201.00 18.48 o 9 0 2 136.70 132.45 18.45 o -9 1 2 65.56 74.69 11.04 o -8 1 2 98.81 110.40 10.75 o -7 1 2 113.07 114.11 11.80 o -6 1 2 301.35 305.89 16.90 o -5 1 2 875.33 889.83 23.09 o -4 1 2 245.92 212.32 8.55 o -3 1 2 212.24 182.44 9.62 o -2 1 2 7555.93 8217.83 326.53 o -1 1 2 1236.90 1508.69 29.47 o 0 1 2 3115.24 3043.00 184.48 o 1 1 2 7624.55 8304.75 120.13 o 2 1 2 92.50 66.80 2.79 o 3 1 2 1674.14 1745.83 24.51 o 4 1 2 2016.52 2018.45 28.71 o 5 1 2 387.79 380.14 13.24 o 6 1 2 200.00 192.48 7.01 o 7 1 2 216.34 192.98 9.38 o 8 1 2 82.13 87.63 10.57 o 9 1 2 24.24 32.97 9.91 o -9 2 2 15.33 3.81 7.33 o -8 2 2 218.21 207.02 12.95 o -7 2 2 29.02 26.32 6.48 o -6 2 2 63.78 66.90 8.39 o -5 2 2 367.31 367.91 10.63 o -4 2 2 1457.60 1438.68 31.56 o -3 2 2 5550.36 6057.91 111.83 o -2 2 2 529.48 505.26 19.67 o -1 2 2 1009.99 1079.21 57.66 o 0 2 2 3494.30 3690.65 266.16 o 1 2 2 1260.45 1298.89 17.83 o 2 2 2 3724.86 3801.21 48.80 o 3 2 2 2644.00 2653.99 35.63 o 4 2 2 71.63 94.43 6.14 o 5 2 2 169.12 150.68 6.68 o 6 2 2 44.81 44.92 5.57 o 7 2 2 0.89 -6.17 4.11 o 8 2 2 46.73 49.15 7.30 o 9 2 2 327.35 331.11 25.87 o -9 3 2 166.05 167.94 20.46 o -8 3 2 38.85 42.38 8.51 o -7 3 2 151.57 140.77 10.56 o -6 3 2 21.91 18.74 3.71 o -5 3 2 44.82 37.33 3.96 o -4 3 2 1444.35 1548.76 27.24 o -3 3 2 2038.91 2141.90 34.65 o -2 3 2 2554.90 2691.29 41.10 o -1 3 2 171.10 174.44 6.55 o 0 3 2 744.90 745.55 20.76 o 1 3 2 2127.66 2030.90 28.05 o 2 3 2 529.36 445.62 10.56 o 3 3 2 2498.31 2589.68 31.72 o 4 3 2 1643.41 1540.56 20.71 o 5 3 2 148.74 141.59 5.87 o 6 3 2 31.21 29.91 4.21 o 7 3 2 18.38 15.43 6.03 o 8 3 2 228.96 216.47 10.82 o 9 3 2 64.51 74.49 9.43 o -9 4 2 10.66 5.77 14.49 o -8 4 2 176.06 194.75 19.00 o -7 4 2 61.97 67.26 7.11 o -6 4 2 3.94 -0.08 3.30 o -5 4 2 360.00 331.61 11.09 o -4 4 2 701.93 691.27 13.34 o -3 4 2 1726.74 1594.61 24.88 o -2 4 2 308.93 307.64 6.46 o -1 4 2 989.51 910.88 20.71 o 0 4 2 893.42 925.21 17.60 o 1 4 2 185.54 191.61 6.58 o 2 4 2 3278.20 3359.11 45.60 o 3 4 2 2763.88 2713.67 38.36 o 4 4 2 195.77 179.55 6.75 o 5 4 2 574.25 540.31 17.17 o 6 4 2 0.37 -4.10 3.10 o 7 4 2 18.41 14.91 5.64 o 8 4 2 75.39 91.78 9.13 o 9 4 2 182.58 214.41 12.66 o -9 5 2 26.72 31.02 13.54 o -8 5 2 128.08 150.68 10.82 o -7 5 2 284.46 253.48 9.44 o -6 5 2 25.28 25.30 6.17 o -5 5 2 428.49 405.51 10.49 o -4 5 2 99.55 89.89 4.21 o -3 5 2 31.95 25.72 5.47 o -2 5 2 5070.32 5105.72 59.70 o -1 5 2 5.95 2.96 1.39 o 0 5 2 19.20 15.30 2.82 o 1 5 2 292.69 250.79 6.01 o 2 5 2 559.91 612.09 11.47 o 3 5 2 682.27 652.57 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