#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:31:35 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181247 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/25/2232580.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2232580_Fobs loop_ _publ_author_name 'Balasubramani, V.' 'Vinuchakkaravarthy, T.' 'Gopi, Sreeraj' 'Narasimhan, S.' 'Velmurugan, D.' _publ_section_title ; 3-Bromo-5-tert-butyl-2-hydroxybenzaldehyde ; _journal_coeditor_code BT5688 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3375 _journal_volume 67 _journal_year 2011 _space_group_IT_number 61 _symmetry_space_group_name_Hall '-P 2ac 2ab' _symmetry_space_group_name_H-M 'P b c a' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 9.9727 _cell_length_b 12.1738 _cell_length_c 18.5580 _exptl_crystal_F_000 1040.00 _reflns_d_resolution_high 0.7487 _cod_data_source_file bt5688Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' GREEN in Pbca' _shelx_refln_list_code 4 _shelx_f_calc_maximum 320.19 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x-1/2, y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 906.52 1088.81 74.00 o 4 0 0 226.72 288.63 29.57 o 6 0 0 11142.09 10602.87 705.53 o 8 0 0 3772.69 3406.06 233.31 o 10 0 0 1552.22 1398.57 78.50 o 2 1 0 17094.27 17021.55 650.57 o 4 1 0 13286.57 13128.07 615.80 o 6 1 0 9359.30 9043.14 347.98 o 8 1 0 603.68 531.23 29.58 o 10 1 0 32.93 -0.12 22.32 o 0 2 0 4132.32 3905.52 196.88 o 2 2 0 2499.56 2317.30 90.06 o 4 2 0 8323.88 7200.27 276.95 o 6 2 0 395.73 481.43 27.44 o 8 2 0 198.36 245.31 22.07 o 10 2 0 181.98 173.75 32.85 o 2 3 0 4613.05 5198.12 245.44 o 4 3 0 3046.70 2718.43 107.03 o 6 3 0 2543.78 2385.79 95.77 o 8 3 0 173.38 188.42 22.55 o 10 3 0 28.02 25.54 33.66 o 0 4 0 67866.05 62986.90 2946.05 o 2 4 0 144.75 224.75 11.88 o 4 4 0 12381.30 13425.06 630.44 o 6 4 0 1407.79 1398.94 60.40 o 8 4 0 3172.06 2743.12 160.93 o 10 4 0 1473.24 1511.64 122.46 o 12 4 0 186.66 203.86 58.56 o 2 5 0 9757.84 10294.07 341.35 o 4 5 0 21100.74 19542.57 918.49 o 6 5 0 7639.56 7686.98 364.91 o 8 5 0 543.01 532.88 59.16 o 10 5 0 95.26 73.94 49.29 o 12 5 0 246.25 259.42 63.42 o 0 6 0 21379.43 20159.29 945.87 o 2 6 0 4529.85 4096.20 138.34 o 4 6 0 51.86 29.60 14.18 o 6 6 0 1323.62 1170.63 68.79 o 8 6 0 262.68 259.97 49.35 o 10 6 0 363.33 405.52 63.03 o 12 6 0 53.04 61.60 68.64 o 2 7 0 1147.98 1150.62 43.69 o 4 7 0 255.73 299.49 22.10 o 6 7 0 267.53 308.53 46.50 o 8 7 0 44.72 -45.76 45.76 o 10 7 0 120.15 143.50 59.42 o 0 8 0 18544.39 17850.17 839.19 o 2 8 0 1643.04 1621.50 59.38 o 4 8 0 66.75 25.03 19.32 o 6 8 0 1150.03 980.80 67.15 o 8 8 0 732.31 744.45 78.20 o 10 8 0 304.38 328.68 70.05 o 2 9 0 2247.41 2132.17 76.36 o 4 9 0 5016.78 5176.42 204.14 o 6 9 0 1232.96 1403.67 118.38 o 8 9 0 366.11 275.95 64.80 o 10 9 0 3.48 -66.42 66.42 o 0 10 0 2711.71 2348.32 143.09 o 2 10 0 1945.02 1816.17 67.72 o 4 10 0 537.23 575.93 60.83 o 6 10 0 362.77 323.15 62.60 o 8 10 0 225.82 341.33 72.23 o 10 10 0 321.77 373.62 82.83 o 2 11 0 13.99 13.74 21.59 o 4 11 0 480.86 461.59 58.57 o 6 11 0 188.32 99.52 61.21 o 8 11 0 50.22 -17.16 69.08 o 0 12 0 665.03 692.48 143.78 o 2 12 0 221.06 228.39 27.23 o 4 12 0 15.58 14.72 31.65 o 6 12 0 81.53 126.74 67.33 o 8 12 0 112.08 62.94 76.58 o 2 13 0 238.52 204.87 30.65 o 4 13 0 1253.76 1210.18 83.91 o 6 13 0 321.18 363.95 78.87 o 0 14 0 506.08 467.65 76.97 o 2 14 0 359.14 329.13 39.95 o 4 14 0 90.31 146.92 49.31 o 6 14 0 62.96 58.08 77.88 o 2 15 0 40.05 -17.37 33.20 o 4 15 0 83.56 99.37 52.74 o 0 16 0 91.22 48.14 82.74 o 2 16 0 16.55 -93.70 93.70 o 1 1 1 1520.43 1404.55 69.63 o 2 1 1 2162.85 2375.75 71.03 o 3 1 1 52.53 40.99 5.13 o 4 1 1 5533.71 5511.42 164.31 o 5 1 1 709.36 652.30 23.43 o 6 1 1 6986.36 6591.59 197.07 o 7 1 1 718.49 632.53 25.86 o 8 1 1 1389.60 1234.95 38.94 o 9 1 1 12.30 23.84 12.43 o 10 1 1 44.26 24.88 17.64 o 11 1 1 0.39 12.29 31.56 o 0 2 1 3190.58 3217.11 108.67 o 1 2 1 3975.29 4007.18 119.62 o 2 2 1 102523.73 96475.61 5737.28 o 3 2 1 6713.06 6393.24 190.32 o 4 2 1 428.24 498.31 17.59 o 5 2 1 88.49 62.30 8.38 o 6 2 1 1603.61 1295.82 38.99 o 7 2 1 30.35 -2.57 10.58 o 8 2 1 5310.31 4889.77 135.18 o 9 2 1 0.48 -16.04 16.04 o 10 2 1 1938.21 1791.28 68.24 o 11 2 1 3.83 -28.90 33.41 o 1 3 1 1174.08 1290.66 31.16 o 2 3 1 53299.04 53172.54 1570.27 o 3 3 1 341.13 379.62 16.19 o 4 3 1 26853.48 27764.47 822.16 o 5 3 1 399.11 406.37 19.02 o 6 3 1 5147.52 4766.45 131.11 o 7 3 1 353.47 311.79 15.91 o 8 3 1 389.73 375.95 18.46 o 9 3 1 1.00 5.89 19.72 o 10 3 1 50.38 36.07 25.96 o 11 3 1 37.70 7.07 28.42 o 12 3 1 243.36 297.30 62.98 o 0 4 1 2991.87 2734.62 92.05 o 1 4 1 227.91 253.40 8.85 o 2 4 1 2150.20 2046.76 51.26 o 3 4 1 184.73 122.84 11.36 o 4 4 1 165.21 180.77 12.62 o 5 4 1 501.16 433.87 19.43 o 6 4 1 13.14 -7.02 12.54 o 7 4 1 12.93 -13.74 13.74 o 8 4 1 351.03 352.63 23.73 o 9 4 1 20.90 -7.70 23.15 o 10 4 1 158.91 169.50 29.31 o 11 4 1 6.40 -31.66 34.36 o 12 4 1 78.49 6.60 59.85 o 1 5 1 528.90 412.98 13.50 o 2 5 1 4941.83 5556.14 131.04 o 3 5 1 826.85 844.19 27.64 o 4 5 1 6607.53 7322.70 245.56 o 5 5 1 66.18 62.42 14.27 o 6 5 1 15.51 -15.26 15.26 o 7 5 1 0.13 -16.83 16.83 o 8 5 1 0.18 -27.04 27.04 o 9 5 1 2.50 -30.37 32.66 o 10 5 1 56.62 40.02 35.14 o 11 5 1 0.10 0.33 39.78 o 12 5 1 62.91 70.84 64.24 o 0 6 1 2748.10 2438.09 83.69 o 1 6 1 324.67 334.15 11.84 o 2 6 1 17543.53 19085.23 447.17 o 3 6 1 122.40 101.99 9.06 o 4 6 1 66.11 93.17 9.89 o 5 6 1 1.48 -10.19 17.19 o 6 6 1 294.43 312.83 22.62 o 7 6 1 151.08 147.32 25.38 o 8 6 1 1497.67 1498.51 85.73 o 9 6 1 4.61 -22.87 32.81 o 10 6 1 709.02 800.70 59.61 o 11 6 1 18.91 -15.61 40.13 o 12 6 1 91.38 38.30 46.03 o 1 7 1 839.71 732.11 21.91 o 2 7 1 2460.58 2326.42 57.40 o 3 7 1 7.75 6.56 8.71 o 4 7 1 6768.49 7085.13 194.39 o 5 7 1 57.03 93.25 29.59 o 6 7 1 5654.04 5269.88 180.03 o 7 7 1 322.57 336.06 30.75 o 8 7 1 521.35 591.71 56.71 o 9 7 1 3.79 -23.17 37.46 o 10 7 1 20.30 25.96 39.82 o 11 7 1 5.29 -25.04 42.56 o 0 8 1 5157.08 4518.30 152.89 o 1 8 1 707.80 638.89 21.34 o 2 8 1 4850.35 4486.41 107.70 o 3 8 1 37.58 24.16 10.29 o 4 8 1 209.41 227.00 16.26 o 5 8 1 304.22 269.61 24.08 o 6 8 1 162.92 151.82 28.23 o 7 8 1 56.68 12.81 33.29 o 8 8 1 1267.72 1106.12 74.90 o 9 8 1 2.32 -37.07 40.75 o 10 8 1 217.25 261.32 83.01 o 11 8 1 0.05 -47.28 47.28 o 1 9 1 0.15 -1.36 11.03 o 2 9 1 156.87 160.97 15.83 o 3 9 1 2.68 -0.57 11.72 o 4 9 1 3.35 1.56 16.69 o 5 9 1 19.84 10.22 22.79 o 6 9 1 74.08 72.60 28.52 o 7 9 1 6.40 -26.38 36.54 o 8 9 1 7.56 -3.39 40.26 o 9 9 1 3.89 -43.83 43.83 o 10 9 1 26.59 -5.78 45.73 o 11 9 1 14.43 -36.17 58.07 o 0 10 1 1631.16 1480.17 57.30 o 1 10 1 4.90 -5.63 12.15 o 2 10 1 1612.69 1726.52 46.17 o 3 10 1 244.62 307.90 17.10 o 4 10 1 30.49 30.06 19.02 o 5 10 1 3.47 25.31 28.06 o 6 10 1 398.77 401.33 46.14 o 7 10 1 4.63 -14.34 41.21 o 8 10 1 593.07 546.77 56.01 o 9 10 1 5.97 -48.37 48.37 o 10 10 1 109.85 5.49 51.93 o 1 11 1 27.80 17.23 14.19 o 2 11 1 1603.59 1603.72 46.34 o 3 11 1 29.81 13.64 15.96 o 4 11 1 1451.87 1681.86 55.25 o 5 11 1 7.88 -31.49 31.49 o 6 11 1 1222.75 1201.03 81.91 o 7 11 1 11.24 35.57 45.57 o 8 11 1 39.32 85.18 69.30 o 9 11 1 1.52 38.54 51.67 o 0 12 1 2001.97 1926.29 116.41 o 1 12 1 3.48 -15.46 15.46 o 2 12 1 768.65 797.51 30.30 o 3 12 1 3.50 -17.65 17.65 o 4 12 1 10.48 3.15 23.88 o 5 12 1 84.01 70.53 42.79 o 6 12 1 4.35 -44.64 44.64 o 7 12 1 0.23 -46.63 46.63 o 8 12 1 181.99 232.97 57.44 o 1 13 1 3.01 -18.00 18.00 o 2 13 1 165.94 105.40 19.43 o 3 13 1 15.41 -20.22 20.23 o 4 13 1 65.03 56.07 27.43 o 5 13 1 0.22 -31.67 31.67 o 6 13 1 167.47 173.08 52.45 o 7 13 1 4.06 -50.71 51.98 o 0 14 1 137.48 158.32 29.97 o 1 14 1 3.23 -12.58 19.99 o 2 14 1 1.06 -20.96 20.96 o 3 14 1 1.07 -19.51 28.76 o 4 14 1 4.46 -33.47 33.47 o 5 14 1 3.23 10.18 35.23 o 6 14 1 22.89 31.30 54.74 o 1 15 1 0.07 -22.34 22.34 o 2 15 1 278.68 277.11 26.14 o 3 15 1 6.26 7.81 34.93 o 4 15 1 154.70 171.29 38.38 o 0 16 1 288.93 331.69 39.23 o 1 16 1 1.08 -24.66 24.66 o 2 16 1 131.03 -20.18 57.59 o 0 0 2 88732.59 62337.67 4132.85 o 1 0 2 235.98 308.35 17.62 o 2 0 2 30766.04 32369.47 1516.17 o 3 0 2 1073.02 825.79 33.62 o 4 0 2 3151.94 3375.23 130.71 o 5 0 2 1386.98 1377.68 56.19 o 6 0 2 6932.61 6716.62 258.90 o 7 0 2 69.16 65.02 15.53 o 8 0 2 4654.66 4334.38 169.90 o 9 0 2 46.61 51.89 19.80 o 10 0 2 1894.56 1807.86 139.27 o 11 0 2 9.54 -17.27 33.17 o 1 1 2 195.16 226.12 16.38 o 2 1 2 6698.88 6725.36 199.72 o 3 1 2 6559.93 6251.94 208.01 o 4 1 2 17186.83 16511.66 489.64 o 5 1 2 1744.02 1829.53 56.79 o 6 1 2 5914.28 5712.72 171.16 o 7 1 2 23.30 39.66 11.67 o 8 1 2 799.10 715.59 26.89 o 9 1 2 400.97 377.22 19.15 o 10 1 2 21.36 11.37 20.57 o 11 1 2 52.59 57.51 33.45 o 0 2 2 6274.92 7664.25 226.63 o 1 2 2 3093.60 3602.87 90.59 o 2 2 2 322.64 206.36 8.74 o 3 2 2 761.10 601.51 23.19 o 4 2 2 1714.55 2065.67 70.69 o 5 2 2 329.17 353.23 17.95 o 6 2 2 134.22 111.31 11.37 o 7 2 2 191.12 162.70 12.52 o 8 2 2 90.78 84.74 13.47 o 9 2 2 64.25 45.64 19.37 o 10 2 2 100.09 119.08 22.48 o 11 2 2 6.40 -5.48 34.31 o 12 2 2 5.92 37.39 54.11 o 1 3 2 10.89 27.89 3.28 o 2 3 2 4990.76 5516.42 164.63 o 3 3 2 1179.91 1357.54 47.95 o 4 3 2 1636.73 1746.35 54.57 o 5 3 2 112.52 123.81 12.72 o 6 3 2 3032.69 3088.90 94.29 o 7 3 2 9.72 0.63 12.54 o 8 3 2 69.29 31.14 17.62 o 9 3 2 137.88 116.20 21.17 o 10 3 2 2.00 -11.89 25.21 o 11 3 2 61.19 65.62 36.78 o 12 3 2 105.88 78.97 42.75 o 0 4 2 13883.00 15116.20 500.42 o 1 4 2 507.38 600.53 16.35 o 2 4 2 6032.72 6344.80 148.86 o 3 4 2 246.31 310.84 14.18 o 4 4 2 7948.54 8106.37 241.97 o 5 4 2 3262.31 3025.54 92.68 o 6 4 2 1617.71 1484.96 49.32 o 7 4 2 119.66 120.95 15.00 o 8 4 2 3112.71 3151.35 110.75 o 9 4 2 43.08 45.10 21.63 o 10 4 2 1185.55 1221.02 62.10 o 11 4 2 33.30 55.77 30.48 o 12 4 2 106.05 76.58 56.78 o 1 5 2 3620.99 3436.83 81.89 o 2 5 2 8385.15 8559.85 200.97 o 3 5 2 827.18 1102.43 33.37 o 4 5 2 16527.93 16841.00 499.88 o 5 5 2 1876.46 1927.80 61.91 o 6 5 2 5961.00 5757.79 173.62 o 7 5 2 16.54 -14.31 18.18 o 8 5 2 770.04 695.89 35.12 o 9 5 2 139.97 156.31 27.34 o 10 5 2 119.48 56.82 44.02 o 11 5 2 2.75 2.47 40.40 o 12 5 2 182.02 212.66 64.28 o 0 6 2 10992.68 10396.65 346.22 o 1 6 2 1.99 0.80 6.88 o 2 6 2 4105.60 4085.72 97.57 o 3 6 2 704.37 795.71 24.66 o 4 6 2 18.18 3.15 9.14 o 5 6 2 19.21 3.48 16.32 o 6 6 2 399.89 434.85 25.09 o 7 6 2 377.31 379.53 30.52 o 8 6 2 298.55 275.10 44.90 o 9 6 2 0.10 -9.51 33.58 o 10 6 2 445.30 405.37 45.21 o 11 6 2 0.43 -13.40 41.98 o 12 6 2 25.68 51.03 69.51 o 1 7 2 76.49 121.19 9.50 o 2 7 2 463.22 538.63 18.72 o 3 7 2 0.27 -5.52 8.34 o 4 7 2 143.81 154.97 13.21 o 5 7 2 434.36 430.34 26.50 o 6 7 2 701.76 717.62 43.72 o 7 7 2 10.60 -25.67 25.67 o 8 7 2 186.39 174.16 37.31 o 9 7 2 105.05 58.99 38.10 o 10 7 2 42.62 36.63 42.19 o 11 7 2 0.48 -36.72 42.92 o 0 8 2 8753.33 8811.40 294.46 o 1 8 2 121.05 99.04 10.49 o 2 8 2 2358.16 2282.00 56.94 o 3 8 2 18.37 7.30 11.41 o 4 8 2 185.67 250.80 16.53 o 5 8 2 167.25 194.39 29.56 o 6 8 2 924.08 1098.44 59.01 o 7 8 2 1.88 -2.53 27.77 o 8 8 2 763.91 842.18 65.84 o 9 8 2 5.34 -13.75 40.12 o 10 8 2 296.73 298.37 49.53 o 11 8 2 3.47 -12.65 47.90 o 1 9 2 176.72 184.08 12.54 o 2 9 2 2228.09 2363.16 59.50 o 3 9 2 264.53 268.88 16.56 o 4 9 2 3564.77 3852.25 109.10 o 5 9 2 0.56 -24.46 24.46 o 6 9 2 1217.25 1277.79 65.64 o 7 9 2 14.13 -17.60 36.71 o 8 9 2 445.38 433.30 50.36 o 9 9 2 229.06 241.91 48.73 o 10 9 2 4.39 15.13 48.72 o 11 9 2 25.22 -34.10 51.95 o 0 10 2 2700.96 2530.45 123.76 o 1 10 2 53.77 32.79 12.70 o 2 10 2 1666.44 1574.46 42.91 o 3 10 2 411.84 471.22 19.61 o 4 10 2 261.32 297.09 21.03 o 5 10 2 47.08 69.09 40.96 o 6 10 2 114.97 146.02 34.28 o 7 10 2 217.23 185.45 43.74 o 8 10 2 268.18 291.92 48.13 o 9 10 2 32.00 -48.15 58.29 o 10 10 2 278.22 309.58 56.35 o 1 11 2 198.89 192.67 15.95 o 2 11 2 9.73 -15.26 15.26 o 3 11 2 2.08 -15.72 15.72 o 4 11 2 373.30 293.41 42.83 o 5 11 2 8.93 -30.88 41.66 o 6 11 2 64.77 30.75 36.70 o 7 11 2 2.44 -44.16 44.16 o 8 11 2 78.54 -10.13 49.63 o 9 11 2 4.80 -51.59 51.59 o 0 12 2 384.36 364.33 47.35 o 1 12 2 0.36 -15.56 15.56 o 2 12 2 193.20 185.75 18.66 o 3 12 2 0.37 -19.97 19.97 o 4 12 2 3.12 -9.21 24.44 o 5 12 2 16.14 8.90 30.25 o 6 12 2 88.05 69.34 45.90 o 7 12 2 4.59 3.07 48.95 o 8 12 2 117.73 27.29 53.98 o 1 13 2 74.20 60.68 18.68 o 2 13 2 285.44 284.48 21.51 o 3 13 2 2.31 -21.42 21.42 o 4 13 2 993.17 1020.55 46.33 o 5 13 2 10.86 -19.81 32.12 o 6 13 2 367.94 385.96 57.50 o 7 13 2 20.18 -53.32 53.32 o 0 14 2 501.74 535.95 36.77 o 1 14 2 10.86 -20.18 20.18 o 2 14 2 348.41 390.78 24.76 o 3 14 2 80.60 74.19 28.06 o 4 14 2 40.04 17.85 30.39 o 5 14 2 10.00 -24.25 35.86 o 6 14 2 34.99 -7.27 54.60 o 1 15 2 21.42 -24.09 24.09 o 2 15 2 21.87 -25.76 25.76 o 3 15 2 4.44 -29.71 29.71 o 4 15 2 55.96 -25.29 37.25 o 0 16 2 5.02 -37.36 42.61 o 1 16 2 8.45 -26.85 26.85 o 1 1 3 2783.69 3163.55 94.22 o 2 1 3 873.86 856.70 35.33 o 3 1 3 909.86 813.01 28.40 o 4 1 3 9770.75 9922.78 294.72 o 5 1 3 310.32 336.14 15.08 o 6 1 3 3390.17 3323.10 100.87 o 7 1 3 1534.21 1584.79 51.48 o 8 1 3 508.99 512.80 22.87 o 9 1 3 440.31 449.41 30.81 o 10 1 3 81.81 57.17 26.95 o 11 1 3 3.78 -26.37 28.76 o 12 1 3 15.04 -2.20 48.83 o 0 2 3 72480.02 86609.09 3071.68 o 1 2 3 329.30 417.96 13.08 o 2 2 3 19045.47 18827.50 787.21 o 3 2 3 4455.15 4320.85 186.63 o 4 2 3 660.56 688.07 27.16 o 5 2 3 3655.98 3346.83 113.18 o 6 2 3 1609.11 1517.98 55.02 o 7 2 3 430.15 491.36 24.59 o 8 2 3 4222.86 4001.17 159.05 o 9 2 3 20.68 13.60 19.99 o 10 2 3 1114.34 1030.07 55.96 o 11 2 3 90.99 107.31 36.91 o 12 2 3 224.98 205.03 42.80 o 1 3 3 6924.68 7000.52 154.37 o 2 3 3 8628.02 9101.16 246.70 o 3 3 3 213.84 226.60 11.07 o 4 3 3 15617.06 15250.67 452.07 o 5 3 3 66.19 67.34 9.75 o 6 3 3 6859.58 6460.79 193.40 o 7 3 3 295.19 268.15 16.61 o 8 3 3 676.95 605.02 31.64 o 9 3 3 288.56 318.72 24.97 o 10 3 3 45.91 23.12 23.28 o 11 3 3 135.29 135.10 40.86 o 12 3 3 243.75 250.18 70.03 o 0 4 3 1848.89 1690.71 58.15 o 1 4 3 16.02 20.39 5.09 o 2 4 3 2075.28 2152.41 48.76 o 3 4 3 5.69 30.95 11.38 o 4 4 3 143.26 116.17 10.93 o 5 4 3 793.86 796.76 30.86 o 6 4 3 11.84 15.80 11.99 o 7 4 3 248.30 262.37 21.00 o 8 4 3 143.66 111.95 21.86 o 9 4 3 118.27 112.30 22.38 o 10 4 3 103.23 91.48 29.47 o 11 4 3 73.29 48.73 68.65 o 12 4 3 107.08 101.97 86.93 o 1 5 3 86.36 118.43 7.45 o 2 5 3 1950.18 2003.24 48.83 o 3 5 3 267.29 298.21 15.06 o 4 5 3 2926.66 2934.81 90.49 o 5 5 3 58.86 41.72 12.48 o 6 5 3 102.81 127.34 14.66 o 7 5 3 0.77 -19.76 19.76 o 8 5 3 171.28 237.87 24.16 o 9 5 3 24.72 45.40 23.62 o 10 5 3 163.62 126.50 31.35 o 11 5 3 0.02 33.53 33.64 o 12 5 3 28.20 -40.04 59.39 o 0 6 3 21678.98 21737.67 720.54 o 1 6 3 103.89 80.70 7.65 o 2 6 3 3208.94 3306.19 79.49 o 3 6 3 198.56 253.76 11.86 o 4 6 3 93.23 92.99 11.48 o 5 6 3 956.75 941.31 42.23 o 6 6 3 264.43 198.84 21.76 o 7 6 3 714.10 728.57 37.71 o 8 6 3 1280.56 1337.23 57.45 o 9 6 3 0.08 48.33 36.23 o 10 6 3 508.51 535.88 51.61 o 11 6 3 116.95 87.31 52.16 o 12 6 3 112.35 166.81 68.22 o 1 7 3 2655.37 2706.47 66.17 o 2 7 3 3740.83 3386.44 81.79 o 3 7 3 380.37 399.62 15.73 o 4 7 3 5402.70 5363.32 147.64 o 5 7 3 0.82 -23.43 23.43 o 6 7 3 4276.86 4515.27 180.82 o 7 7 3 848.58 792.51 48.01 o 8 7 3 282.58 269.74 33.55 o 9 7 3 230.93 203.70 40.80 o 10 7 3 7.07 -40.65 42.25 o 11 7 3 17.51 12.88 48.68 o 0 8 3 6313.82 5674.52 191.35 o 1 8 3 235.67 230.35 12.52 o 2 8 3 1911.10 1712.59 44.41 o 3 8 3 1204.49 1287.02 35.24 o 4 8 3 506.43 505.71 23.94 o 5 8 3 805.00 900.44 50.85 o 6 8 3 313.10 236.12 31.52 o 7 8 3 26.31 -29.92 29.92 o 8 8 3 707.96 817.04 58.35 o 9 8 3 24.59 -35.61 41.06 o 10 8 3 124.56 179.39 49.44 o 11 8 3 6.34 -49.87 49.87 o 1 9 3 28.34 29.25 12.43 o 2 9 3 84.85 65.17 12.39 o 3 9 3 68.57 55.65 12.35 o 4 9 3 66.57 73.45 16.07 o 5 9 3 1.79 13.28 45.33 o 6 9 3 90.64 55.39 31.43 o 7 9 3 7.47 0.13 32.48 o 8 9 3 5.47 -45.31 45.31 o 9 9 3 0.34 -46.23 46.23 o 10 9 3 91.62 95.95 51.48 o 0 10 3 1415.18 1446.81 60.61 o 1 10 3 103.84 87.00 13.35 o 2 10 3 1526.53 1511.24 41.47 o 3 10 3 138.73 160.28 15.13 o 4 10 3 8.14 -9.49 18.70 o 5 10 3 44.83 64.18 28.54 o 6 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56.10 o 1 0 20 0.06 25.23 26.51 o 2 0 20 94.19 106.43 40.05 o 3 0 20 21.79 115.28 41.24 o 4 0 20 41.45 118.80 76.56 o 5 0 20 74.19 261.40 90.21 o 6 0 20 25.06 70.83 95.47 o 7 0 20 4.88 95.90 108.21 o 1 1 20 25.99 43.16 19.34 o 2 1 20 104.83 97.77 31.07 o 3 1 20 1.58 49.63 27.72 o 4 1 20 5.45 87.14 49.57 o 5 1 20 10.13 79.69 60.54 o 6 1 20 76.06 137.43 69.85 o 7 1 20 4.90 74.07 76.99 o 0 2 20 95.62 90.53 27.37 o 1 2 20 4.62 30.84 18.35 o 2 2 20 0.88 51.24 27.01 o 3 2 20 2.30 56.93 34.27 o 4 2 20 1.62 49.77 35.43 o 5 2 20 13.62 70.69 42.06 o 6 2 20 1.41 141.76 54.51 o 7 2 20 0.60 182.02 76.50 o 1 3 20 43.06 40.99 21.86 o 2 3 20 9.45 25.83 26.81 o 3 3 20 0.26 68.32 34.75 o 4 3 20 8.87 59.93 32.15 o 5 3 20 2.12 68.47 34.10 o 6 3 20 5.61 66.22 37.02 o 7 3 20 3.04 172.35 99.20 o 0 4 20 9.47 19.15 28.85 o 1 4 20 4.24 11.97 22.68 o 2 4 20 134.43 207.44 38.00 o 3 4 20 15.02 57.02 34.62 o 4 4 20 0.02 81.53 32.54 o 5 4 20 6.22 32.76 33.93 o 6 4 20 41.82 103.27 46.43 o 7 4 20 2.74 42.45 49.77 o 1 5 20 7.29 0.09 24.00 o 2 5 20 53.72 55.48 33.51 o 3 5 20 0.68 46.83 31.64 o 4 5 20 60.85 137.89 34.16 o 5 5 20 36.61 25.05 34.57 o 6 5 20 74.74 142.38 47.85 o 0 6 20 58.57 28.74 32.84 o 1 6 20 1.61 17.57 27.01 o 2 6 20 17.31 43.03 34.16 o 3 6 20 2.29 62.77 32.73 o 4 6 20 2.15 29.57 33.43 o 5 6 20 2.22 28.97 33.88 o 6 6 20 0.44 45.91 54.06 o 1 7 20 20.70 27.92 28.81 o 2 7 20 0.11 58.01 34.61 o 3 7 20 1.83 44.83 35.22 o 4 7 20 12.12 2.49 31.36 o 5 7 20 2.09 55.44 44.56 o 0 8 20 1.06 65.42 57.41 o 1 8 20 3.99 48.81 53.25 o 2 8 20 45.62 78.79 37.51 o 3 8 20 24.72 -6.30 34.28 o 4 8 20 1.91 45.50 39.56 o 1 9 20 7.71 64.74 39.54 o 2 9 20 13.67 47.94 44.83 o 1 1 21 3.93 31.98 22.23 o 2 1 21 60.25 51.58 30.17 o 3 1 21 3.65 10.41 28.74 o 4 1 21 70.84 153.94 45.97 o 5 1 21 3.56 105.13 63.45 o 6 1 21 6.77 248.47 72.77 o 0 2 21 365.43 372.26 55.52 o 1 2 21 0.02 23.77 24.95 o 2 2 21 4.85 -4.52 28.08 o 3 2 21 32.77 90.88 51.50 o 4 2 21 0.51 42.05 45.89 o 5 2 21 35.95 178.02 94.85 o 6 2 21 7.75 148.22 70.76 o 1 3 21 0.04 37.01 22.28 o 2 3 21 3.84 15.26 33.30 o 3 3 21 25.76 9.05 37.11 o 4 3 21 44.69 43.95 48.34 o 5 3 21 0.65 95.33 35.49 o 6 3 21 16.06 100.39 48.00 o 0 4 21 71.02 91.64 30.80 o 1 4 21 28.08 32.98 25.35 o 2 4 21 1.50 36.05 34.55 o 3 4 21 0.20 73.07 37.96 o 4 4 21 5.79 58.39 35.10 o 5 4 21 2.04 66.61 35.71 o 6 4 21 1.21 65.54 41.08 o 1 5 21 19.54 48.17 25.30 o 2 5 21 1.27 -9.26 42.09 o 3 5 21 0.07 42.48 38.41 o 4 5 21 6.71 43.96 35.92 o 5 5 21 18.23 32.57 37.25 o 0 6 21 96.94 159.65 46.84 o 1 6 21 2.80 46.93 27.48 o 2 6 21 3.73 20.96 38.79 o 3 6 21 3.46 90.67 57.74 o 4 6 21 0.27 50.19 35.32 o 5 6 21 0.17 26.36 37.37 o 1 7 21 1.27 45.11 29.93 o 2 7 21 5.72 59.38 42.98 o 3 7 21 10.73 42.18 45.53 o 4 7 21 36.88 35.72 41.49 o 0 8 21 66.79 181.09 57.13 o 1 8 21 20.90 20.34 36.32 o 2 8 21 2.74 51.24 39.42 o 0 0 22 2.38 31.67 48.83 o 1 0 22 0.06 -5.69 38.10 o 2 0 22 70.46 89.02 109.79 o 3 0 22 39.91 99.29 43.54 o 4 0 22 0.13 80.00 50.37 o 5 0 22 94.35 412.37 99.02 o 6 0 22 3.24 126.25 102.93 o 1 1 22 3.05 26.12 30.95 o 2 1 22 11.89 71.26 29.67 o 3 1 22 7.54 65.22 36.32 o 4 1 22 14.65 49.12 34.01 o 5 1 22 0.02 74.10 53.45 o 6 1 22 18.18 121.87 71.64 o 0 2 22 6.94 -2.76 28.57 o 1 2 22 15.80 10.77 32.51 o 2 2 22 44.99 37.66 29.90 o 3 2 22 8.57 41.40 34.54 o 4 2 22 11.30 77.17 53.86 o 5 2 22 6.93 43.23 42.43 o 1 3 22 19.86 27.98 32.07 o 2 3 22 17.43 13.95 32.26 o 3 3 22 82.63 118.50 47.45 o 4 3 22 0.60 69.73 45.77 o 5 3 22 7.11 48.81 44.44 o 0 4 22 37.95 60.03 31.51 o 1 4 22 3.39 -32.62 32.62 o 2 4 22 30.62 29.28 42.36 o 3 4 22 7.79 113.27 40.20 o 4 4 22 1.53 85.97 42.00 o 5 4 22 8.93 117.94 76.18 o 1 5 22 9.96 42.88 30.83 o 2 5 22 11.39 -20.92 35.99 o 3 5 22 1.28 94.11 72.36 o 4 5 22 22.71 74.35 42.90 o 0 6 22 20.46 20.24 78.09 o 1 6 22 3.48 30.39 41.92 o 2 6 22 99.48 122.94 39.00 o 3 6 22 16.00 74.67 48.14 o 1 7 22 16.55 54.91 33.24 o 2 7 22 4.05 28.26 37.65 o 1 1 23 5.56 -8.80 36.08 o 2 1 23 1.04 -33.11 33.11 o 3 1 23 36.93 78.18 32.62 o 4 1 23 37.77 94.18 58.11 o 0 2 23 0.67 27.72 36.12 o 1 2 23 23.04 38.94 45.68 o 2 2 23 19.01 45.68 39.00 o 3 2 23 0.26 61.43 59.81 o 4 2 23 19.45 54.92 39.43 o 1 3 23 0.12 13.09 34.43 o 2 3 23 1.86 4.29 34.61 o 3 3 23 1.88 16.18 38.49 o 4 3 23 21.11 82.72 77.25 o 0 4 23 81.97 158.75 60.51 o 1 4 23 10.59 61.87 35.34 o 2 4 23 22.17 13.33 40.26 o 3 4 23 22.46 31.05 39.36 o 1 5 23 6.95 25.96 35.60 o 2 5 23 0.09 37.95 37.27 o 0 6 23 1.16 -18.04 73.02 o 0 0 24 100.56 66.46 52.81 o 1 0 24 45.28 108.68 55.88 o 2 0 24 1.11 30.79 54.55 o 3 0 24 33.60 16.88 50.15 o 1 1 24 8.23 30.27 38.10 o 2 1 24 13.91 8.86 35.15 o 3 1 24 11.90 94.25 53.72 o 0 2 24 20.90 36.95 55.43 o 1 2 24 1.44 31.69 38.93 o 2 2 24 7.43 67.87 36.67 o 1 3 24 4.44 26.89 34.88 o 2 3 24 17.56 67.91 37.35 o