#------------------------------------------------------------------------------ #$Date: 2016-04-03 06:31:57 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181248 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/26/2232618.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2232618_Fobs loop_ _publ_author_name 'Liang, Yan-Shu' 'Liu, Bing-Ni' 'Liu, Mo' 'Liu, Deng-Ke' _publ_section_title ; Methyl 5-chloro-2-nitrobenzoate ; _journal_coeditor_code CV5162 _journal_issue 12 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o3139 _journal_volume 67 _journal_year 2011 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 90.644 _cell_angle_gamma 90.000 _cell_length_a 4.2616 _cell_length_b 22.4699 _cell_length_c 9.3894 _exptl_crystal_F_000 440.00 _reflns_d_resolution_high 0.8405 _cod_data_source_file cv5162Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' R80511E in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 76.66 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 475.95 527.89 14.13 o 4 0 0 225.12 250.46 15.98 o 1 1 0 137.82 127.08 1.69 o 2 1 0 56.24 45.54 2.11 o 3 1 0 703.08 749.34 23.07 o 4 1 0 57.96 52.65 8.86 o 5 1 0 105.55 88.93 14.40 o 1 2 0 7.64 6.29 0.71 o 2 2 0 38.85 44.29 1.41 o 3 2 0 1.92 2.07 0.79 o 4 2 0 40.55 32.79 6.62 o 5 2 0 325.92 327.92 9.59 o 1 3 0 768.64 709.48 10.36 o 2 3 0 401.30 390.28 6.48 o 3 3 0 104.48 118.57 4.23 o 4 3 0 652.35 666.90 28.03 o 5 3 0 6.84 4.06 1.96 o 0 4 0 2603.63 2351.46 57.70 o 1 4 0 3035.97 2955.42 51.57 o 2 4 0 931.38 954.81 19.37 o 3 4 0 4.04 3.94 0.94 o 4 4 0 21.30 19.88 3.18 o 5 4 0 197.95 209.45 8.18 o 1 5 0 492.48 425.69 12.18 o 2 5 0 795.29 851.88 13.53 o 3 5 0 547.45 589.64 11.61 o 4 5 0 5.44 3.03 1.18 o 1 6 0 3611.25 3495.00 86.48 o 2 6 0 162.15 160.52 4.46 o 3 6 0 21.39 19.82 2.51 o 4 6 0 116.96 131.86 11.93 o 1 7 0 3820.78 3840.11 54.45 o 2 7 0 527.90 505.81 8.43 o 3 7 0 69.31 75.85 4.05 o 4 7 0 262.92 241.15 10.41 o 0 8 0 28.06 28.35 1.50 o 1 8 0 199.20 190.43 3.00 o 2 8 0 41.62 48.37 1.93 o 3 8 0 29.79 29.54 2.94 o 4 8 0 178.28 170.94 8.16 o 1 9 0 2458.86 2635.34 45.54 o 2 9 0 13.04 22.34 1.59 o 3 9 0 22.57 22.09 3.46 o 4 9 0 395.72 433.17 13.84 o 0 10 0 1130.81 1074.19 19.38 o 1 10 0 224.97 247.38 4.30 o 2 10 0 326.22 384.36 6.52 o 3 10 0 0.18 1.47 0.72 o 4 10 0 83.60 85.48 8.11 o 1 11 0 171.14 155.73 3.22 o 2 11 0 23.91 25.49 2.16 o 3 11 0 112.84 121.29 4.90 o 4 11 0 70.42 72.62 5.40 o 0 12 0 10.83 26.58 2.22 o 1 12 0 1823.62 1815.67 23.21 o 2 12 0 54.68 60.01 2.00 o 3 12 0 0.00 0.91 0.57 o 4 12 0 19.04 11.95 2.30 o 1 13 0 736.35 790.60 11.43 o 2 13 0 159.55 154.39 3.31 o 3 13 0 3.12 2.43 1.18 o 4 13 0 174.64 187.61 11.67 o 0 14 0 236.65 291.29 6.37 o 1 14 0 260.04 231.00 15.31 o 2 14 0 23.21 26.51 2.58 o 3 14 0 202.34 196.18 5.24 o 4 14 0 1.75 2.07 1.25 o 1 15 0 141.21 148.08 4.41 o 2 15 0 158.75 162.82 4.01 o 3 15 0 0.14 0.47 0.95 o 4 15 0 63.69 57.07 6.36 o 0 16 0 3566.58 3819.92 84.78 o 1 16 0 20.45 23.24 2.99 o 2 16 0 17.08 17.34 1.82 o 3 16 0 32.33 35.80 3.39 o 4 16 0 22.75 24.45 4.85 o 1 17 0 47.86 43.37 2.19 o 2 17 0 0.01 0.78 0.96 o 3 17 0 45.89 43.39 5.34 o 0 18 0 89.43 92.85 3.32 o 1 18 0 0.08 0.10 0.55 o 2 18 0 35.30 43.15 3.10 o 3 18 0 3.95 3.61 1.52 o 1 19 0 44.95 34.23 4.69 o 2 19 0 116.09 136.38 5.06 o 3 19 0 12.56 8.52 2.24 o 0 20 0 556.22 597.12 13.43 o 1 20 0 350.67 387.70 7.60 o 2 20 0 14.30 14.05 2.36 o 3 20 0 45.57 44.24 5.24 o 1 21 0 0.03 0.05 0.88 o 2 21 0 85.74 83.05 5.12 o 3 21 0 55.43 54.53 6.36 o 0 22 0 2074.01 2190.49 107.74 o 1 22 0 93.06 95.46 4.38 o 2 22 0 0.03 0.52 1.38 o 1 23 0 1.07 1.18 0.79 o 2 23 0 14.12 13.30 2.32 o 0 24 0 14.00 10.60 3.85 o 1 24 0 51.62 53.03 7.64 o 2 24 0 8.22 4.65 1.46 o 1 25 0 22.97 20.12 4.61 o 0 26 0 149.93 162.70 13.67 o 1 26 0 193.05 214.76 6.27 o -5 0 1 23.02 16.71 6.06 o -3 0 1 195.54 228.74 11.46 o 1 0 1 292.05 232.22 6.51 o 3 0 1 53.29 65.46 9.10 o 5 0 1 54.67 32.23 11.14 o -5 1 1 19.08 11.22 2.45 o -4 1 1 0.00 1.40 1.60 o -3 1 1 20.73 29.78 3.86 o -2 1 1 156.25 134.99 2.28 o -1 1 1 892.01 923.53 9.96 o 0 1 1 48.30 49.98 0.68 o 3 1 1 268.09 262.28 8.40 o 4 1 1 310.88 315.46 13.73 o 5 1 1 31.32 19.24 4.62 o -5 2 1 0.10 -0.81 1.60 o -4 2 1 84.98 84.09 5.89 o -3 2 1 131.99 127.64 5.18 o -2 2 1 285.00 284.61 3.66 o -1 2 1 25.44 23.17 1.64 o 0 2 1 2116.65 2018.38 28.68 o 1 2 1 31.76 28.18 1.43 o 2 2 1 1346.01 1220.96 19.10 o 3 2 1 173.05 176.21 6.61 o 4 2 1 64.41 59.37 6.82 o 5 2 1 32.65 23.56 5.06 o -5 3 1 4.33 3.26 1.53 o -4 3 1 31.98 32.00 6.29 o -3 3 1 126.47 125.27 3.76 o -2 3 1 6.92 8.92 1.17 o 0 3 1 53.78 54.39 1.13 o 1 3 1 2074.62 1986.66 28.38 o 2 3 1 769.81 757.85 10.48 o 3 3 1 1200.20 1230.24 22.45 o 4 3 1 18.12 16.72 3.68 o 5 3 1 9.91 5.48 2.06 o -4 4 1 117.54 117.53 6.77 o -3 4 1 116.59 108.14 3.63 o -2 4 1 31.77 27.69 1.24 o -1 4 1 4048.70 4215.89 104.47 o 0 4 1 369.28 372.48 4.97 o 1 4 1 913.67 854.34 12.47 o 2 4 1 130.65 138.57 3.04 o 3 4 1 512.99 494.91 9.56 o 4 4 1 53.26 58.99 9.49 o -4 5 1 268.02 264.55 9.46 o -3 5 1 21.80 24.22 3.15 o -2 5 1 171.56 165.80 2.84 o -1 5 1 4106.79 4228.02 188.64 o 0 5 1 362.82 368.16 4.53 o 1 5 1 4590.72 4312.95 130.73 o 2 5 1 21.24 21.23 1.91 o 3 5 1 473.30 490.29 9.46 o 4 5 1 279.51 282.55 12.74 o -4 6 1 1.42 1.15 1.07 o -3 6 1 4.03 10.19 1.46 o -2 6 1 62.78 85.38 3.70 o -1 6 1 470.33 454.62 5.42 o 0 6 1 528.50 496.79 7.32 o 1 6 1 20.85 12.47 0.83 o 2 6 1 1459.92 1373.62 21.81 o 3 6 1 337.01 310.97 6.09 o 4 6 1 340.35 358.14 16.12 o -4 7 1 41.54 39.55 4.83 o -3 7 1 91.81 97.66 3.58 o -2 7 1 1571.47 1605.94 24.93 o -1 7 1 4.91 2.49 0.45 o 0 7 1 163.90 158.37 5.12 o 1 7 1 1503.85 1472.48 23.60 o 2 7 1 150.39 166.48 4.07 o 3 7 1 275.09 269.62 5.53 o 4 7 1 111.64 120.02 7.15 o -4 8 1 190.27 202.14 8.62 o -3 8 1 114.80 126.83 3.42 o -2 8 1 334.72 326.92 5.44 o -1 8 1 135.98 163.30 3.64 o 0 8 1 852.88 841.70 10.78 o 1 8 1 205.88 223.61 3.72 o 2 8 1 2314.41 2207.39 36.25 o 3 8 1 0.25 1.19 1.06 o 4 8 1 9.09 8.02 2.47 o -4 9 1 20.68 18.10 2.99 o -3 9 1 0.04 0.86 0.46 o -2 9 1 495.12 483.26 13.87 o -1 9 1 1529.11 1508.83 19.02 o 0 9 1 91.47 86.00 2.68 o 1 9 1 3034.45 3237.58 60.38 o 2 9 1 614.05 600.59 11.00 o 3 9 1 210.57 209.42 6.84 o 4 9 1 153.63 168.49 7.86 o -4 10 1 67.74 66.36 5.20 o -3 10 1 333.61 341.99 7.71 o -2 10 1 632.22 670.94 10.48 o -1 10 1 15.80 7.41 1.17 o 0 10 1 2238.68 2223.63 33.03 o 1 10 1 354.61 317.81 5.81 o 2 10 1 12.43 10.17 1.43 o 3 10 1 207.63 199.73 7.57 o 4 10 1 24.41 17.03 2.56 o -4 11 1 299.81 310.34 15.46 o -3 11 1 200.83 196.31 6.53 o -2 11 1 2134.35 2274.62 39.72 o -1 11 1 505.24 543.90 7.83 o 0 11 1 1695.71 1566.01 23.54 o 1 11 1 0.86 2.76 0.70 o 2 11 1 26.75 24.45 3.43 o 3 11 1 3.57 3.12 1.14 o 4 11 1 167.04 159.86 8.91 o -4 12 1 0.72 0.97 1.36 o -3 12 1 186.05 176.91 3.94 o -2 12 1 4.63 2.99 0.72 o -1 12 1 78.51 79.31 3.34 o 0 12 1 866.96 921.76 13.81 o 1 12 1 961.50 973.98 13.97 o 2 12 1 192.02 202.82 4.24 o 3 12 1 810.40 832.98 14.86 o 4 12 1 41.97 40.35 6.25 o -4 13 1 46.64 40.54 7.70 o -3 13 1 207.45 206.27 4.98 o -2 13 1 0.32 -0.07 0.57 o -1 13 1 1273.62 1230.36 16.25 o 0 13 1 150.40 139.31 2.98 o 1 13 1 233.31 271.35 12.74 o 2 13 1 20.30 26.89 3.79 o 3 13 1 261.31 238.65 14.98 o 4 13 1 38.19 29.90 5.30 o -4 14 1 353.83 409.01 19.16 o -3 14 1 8.02 4.54 0.96 o -2 14 1 312.27 346.31 6.25 o -1 14 1 23.84 15.37 2.51 o 0 14 1 36.52 39.27 4.41 o 1 14 1 60.64 58.36 3.73 o 2 14 1 694.53 736.24 11.00 o 3 14 1 29.29 24.74 2.45 o 4 14 1 3.33 1.16 0.99 o -4 15 1 11.43 4.54 1.51 o -3 15 1 20.27 18.27 3.44 o -2 15 1 195.13 188.90 6.55 o -1 15 1 261.21 268.95 6.36 o 0 15 1 358.23 334.04 7.64 o 1 15 1 971.04 1056.91 23.03 o 2 15 1 0.46 -0.04 1.12 o 3 15 1 2.04 1.44 0.67 o 4 15 1 271.23 304.57 13.41 o -4 16 1 0.03 -0.45 1.38 o -3 16 1 101.69 106.09 5.77 o -2 16 1 157.58 138.56 8.34 o -1 16 1 264.00 256.63 5.71 o 0 16 1 197.22 168.69 16.26 o 1 16 1 386.83 410.72 9.34 o 2 16 1 0.09 0.45 0.67 o 3 16 1 486.73 489.98 13.52 o 4 16 1 28.34 17.78 4.02 o -3 17 1 11.92 5.91 2.01 o -2 17 1 1038.89 1069.58 20.73 o -1 17 1 391.35 377.55 6.84 o 0 17 1 1137.09 1132.55 17.63 o 1 17 1 252.88 244.45 5.02 o 2 17 1 47.21 37.72 3.83 o 3 17 1 86.38 69.83 4.82 o -3 18 1 197.57 218.09 9.97 o -2 18 1 30.76 17.27 3.39 o -1 18 1 203.42 177.37 8.12 o 0 18 1 32.38 28.58 3.50 o 1 18 1 419.96 430.25 14.06 o 2 18 1 93.47 113.34 3.85 o 3 18 1 185.00 178.96 9.17 o -3 19 1 20.38 15.84 4.05 o -2 19 1 37.74 34.19 2.23 o -1 19 1 1899.51 1979.40 28.93 o 0 19 1 20.70 14.80 2.01 o 1 19 1 2.34 2.29 0.81 o 2 19 1 4.51 4.50 1.22 o 3 19 1 72.80 73.85 4.21 o -3 20 1 94.53 96.15 8.47 o -2 20 1 5.79 5.93 2.22 o -1 20 1 252.74 226.24 6.69 o 0 20 1 209.89 202.21 4.36 o 1 20 1 99.57 94.13 3.86 o 2 20 1 104.63 106.59 5.37 o 3 20 1 89.05 88.23 7.66 o -3 21 1 21.90 16.69 2.97 o -2 21 1 27.84 28.33 3.43 o -1 21 1 105.02 107.33 4.68 o 0 21 1 331.00 338.21 7.87 o 1 21 1 34.42 40.36 4.70 o 2 21 1 1.98 1.32 0.83 o 3 21 1 104.55 110.53 5.22 o -2 22 1 135.71 150.09 7.85 o -1 22 1 168.62 177.08 9.23 o 0 22 1 86.93 79.38 4.40 o 1 22 1 146.48 170.51 5.90 o 2 22 1 0.72 1.07 0.71 o -2 23 1 270.83 275.49 12.36 o -1 23 1 430.17 434.20 17.72 o 0 23 1 146.17 146.22 5.81 o 1 23 1 139.55 139.50 5.94 o 2 23 1 10.98 9.38 2.61 o -2 24 1 26.17 24.88 3.79 o -1 24 1 35.54 20.93 7.15 o 0 24 1 33.58 25.48 2.19 o 1 24 1 5.04 2.43 1.07 o 2 24 1 157.38 166.45 6.41 o -1 25 1 442.85 469.80 17.86 o 0 25 1 0.98 0.23 0.68 o 1 25 1 29.07 34.91 5.00 o -1 26 1 16.26 8.75 1.99 o 0 26 1 18.41 23.65 3.87 o 1 26 1 3.00 3.35 1.70 o -4 0 2 10.53 8.80 3.00 o -2 0 2 1986.78 1875.73 29.33 o 0 0 2 1.73 0.96 0.61 o 2 0 2 620.23 570.52 17.19 o 4 0 2 508.35 528.32 29.66 o -4 1 2 154.69 174.61 7.13 o -3 1 2 150.52 158.22 4.13 o -2 1 2 2167.69 2375.37 27.76 o -1 1 2 1391.26 1476.57 18.13 o 0 1 2 1031.70 997.15 17.49 o 1 1 2 2890.23 2506.90 43.80 o 2 1 2 285.59 273.54 13.04 o 3 1 2 264.71 289.05 9.59 o 4 1 2 1.98 2.24 1.73 o -4 2 2 8.26 3.57 1.31 o -3 2 2 1113.49 1194.32 23.01 o -2 2 2 2657.06 2925.45 34.75 o 0 2 2 2917.14 2781.49 68.40 o 1 2 2 88.41 82.96 2.04 o 2 2 2 3613.14 3278.21 61.32 o 3 2 2 18.21 20.62 4.46 o 4 2 2 4.83 4.69 1.36 o -4 3 2 17.51 18.21 2.75 o -3 3 2 357.14 358.23 7.70 o -2 3 2 41.81 50.13 1.73 o -1 3 2 50.28 49.07 1.09 o 0 3 2 27.33 21.91 0.83 o 1 3 2 210.19 202.51 3.51 o 2 3 2 502.97 523.04 8.98 o 3 3 2 11.96 15.91 2.93 o 4 3 2 404.52 417.09 23.65 o -4 4 2 50.81 46.88 4.88 o -3 4 2 53.07 52.25 2.85 o -2 4 2 13.21 7.19 0.96 o -1 4 2 60.78 69.64 1.21 o 0 4 2 5323.61 5098.44 134.07 o 1 4 2 111.84 85.75 1.87 o 2 4 2 1467.07 1418.60 22.23 o 3 4 2 91.83 86.27 3.12 o 4 4 2 376.87 414.19 18.77 o -4 5 2 2.84 2.49 0.65 o -3 5 2 107.64 116.14 2.75 o -2 5 2 1017.91 1036.18 12.73 o -1 5 2 163.16 154.22 3.83 o 0 5 2 281.66 267.39 3.43 o 1 5 2 4647.03 4294.17 74.70 o 2 5 2 494.66 473.67 14.02 o 3 5 2 67.44 60.13 3.41 o 4 5 2 7.44 4.09 2.89 o -4 6 2 2.36 1.03 1.04 o -3 6 2 14.33 13.37 1.81 o -2 6 2 1959.08 2031.75 35.31 o -1 6 2 1852.15 1945.09 24.36 o 0 6 2 2378.97 2294.02 25.47 o 1 6 2 175.89 201.16 5.53 o 2 6 2 591.16 568.55 9.07 o 3 6 2 118.95 122.35 4.23 o 4 6 2 228.16 244.06 12.98 o -4 7 2 171.38 197.85 7.91 o -3 7 2 6.75 7.42 1.39 o -2 7 2 547.68 565.79 7.85 o -1 7 2 6.99 6.43 1.73 o 0 7 2 2789.15 2714.36 30.13 o 1 7 2 68.53 50.49 1.32 o 2 7 2 583.74 569.16 10.30 o 3 7 2 335.17 357.48 10.32 o 4 7 2 47.40 38.65 7.30 o -4 8 2 38.13 33.49 4.85 o -3 8 2 1313.65 1416.68 19.63 o -2 8 2 206.37 219.40 4.31 o -1 8 2 984.48 943.92 29.75 o 0 8 2 174.21 173.96 8.89 o 1 8 2 149.71 142.46 3.01 o 2 8 2 743.89 710.44 17.82 o 3 8 2 688.74 768.66 21.85 o 4 8 2 20.86 21.06 3.14 o -4 9 2 26.56 33.72 6.16 o -3 9 2 145.29 142.20 3.74 o -2 9 2 79.93 81.76 2.70 o -1 9 2 72.76 55.48 3.49 o 0 9 2 2800.53 2837.74 31.66 o 1 9 2 776.78 847.78 14.90 o 2 9 2 56.36 49.55 2.31 o 3 9 2 172.17 167.25 6.29 o 4 9 2 0.01 0.90 0.64 o -4 10 2 133.99 139.20 7.54 o -3 10 2 15.49 12.12 1.88 o -2 10 2 18.73 11.24 1.08 o -1 10 2 50.49 54.48 1.92 o 0 10 2 687.32 760.27 15.08 o 1 10 2 153.95 142.65 4.33 o 2 10 2 319.20 285.98 7.77 o 3 10 2 42.82 43.78 5.72 o 4 10 2 46.62 37.92 5.76 o -4 11 2 33.47 26.74 5.44 o -3 11 2 126.63 142.97 4.23 o -2 11 2 121.78 134.94 3.53 o -1 11 2 544.99 498.77 7.17 o 0 11 2 479.32 483.05 8.38 o 1 11 2 855.77 791.43 21.23 o 2 11 2 27.86 23.92 2.63 o 3 11 2 314.41 309.29 8.66 o 4 11 2 0.05 -0.18 1.72 o -4 12 2 4.36 2.58 1.23 o -3 12 2 3.08 2.55 0.85 o -2 12 2 75.98 79.17 2.25 o -1 12 2 605.98 570.21 9.66 o 0 12 2 943.97 1022.20 16.89 o 1 12 2 0.00 0.06 0.79 o 2 12 2 777.62 777.22 14.25 o 3 12 2 349.84 363.39 9.87 o 4 12 2 406.57 484.93 19.07 o -4 13 2 32.75 37.15 8.06 o -3 13 2 269.37 283.57 6.31 o -2 13 2 61.09 61.79 1.80 o -1 13 2 418.03 444.76 6.53 o 0 13 2 1522.33 1508.07 32.11 o 1 13 2 6.65 7.68 1.48 o 2 13 2 310.00 286.74 13.89 o 3 13 2 0.12 1.13 0.70 o 4 13 2 70.32 54.25 10.69 o -4 14 2 8.30 5.86 3.21 o -3 14 2 1049.30 1120.52 28.02 o -2 14 2 514.79 545.88 8.20 o -1 14 2 259.59 231.00 5.64 o 0 14 2 195.84 203.99 14.36 o 1 14 2 539.35 516.93 11.54 o 2 14 2 66.22 66.92 3.49 o 3 14 2 233.75 257.18 10.36 o 4 14 2 62.11 49.90 8.70 o -4 15 2 15.76 14.09 2.50 o -3 15 2 3.27 0.89 1.40 o -2 15 2 585.31 600.30 9.85 o -1 15 2 39.00 26.58 4.86 o 0 15 2 762.76 766.11 16.77 o 1 15 2 5.87 4.65 1.27 o 2 15 2 87.77 82.03 3.56 o 3 15 2 43.17 39.33 5.61 o 4 15 2 33.50 24.68 7.04 o -3 16 2 1.79 1.62 0.99 o -2 16 2 39.18 31.29 5.00 o -1 16 2 755.16 811.69 12.84 o 0 16 2 53.01 43.36 2.33 o 1 16 2 17.52 17.01 2.12 o 2 16 2 441.59 434.44 11.38 o 3 16 2 0.01 0.89 0.78 o -3 17 2 19.13 15.17 3.14 o -2 17 2 367.44 374.13 15.30 o -1 17 2 6.05 1.94 0.70 o 0 17 2 144.68 149.24 3.13 o 1 17 2 314.02 343.35 5.85 o 2 17 2 13.82 7.54 1.53 o 3 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