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Information card for entry 2232930
Preview
| Coordinates | 2232930.cif |
|---|---|
| Structure factors | 2232930.hkl |
| Original IUCr paper | HTML |
| Chemical name | Bis[μ~2~-bis(diphenylphosphanyl)methane-κ^2^<i>P</i>:<i>P</i>']bis(μ~4~- diphenylphosphinato-κ^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis(μ~2~- trifluoroacetato-κ^2^<i>O</i>:<i>O</i>')tetrasilver(I) acetonitrile disolvate |
|---|---|
| Formula | C82 H70 Ag4 F6 N2 O8 P6 |
| Calculated formula | C82 H70 Ag4 F6 N2 O8 P6 |
| SMILES | [Ag]123[P](c4ccccc4)(c4ccccc4)C[P](c4ccccc4)(c4ccccc4)[Ag]45[O]=C(O[Ag]67[O]4P(=[O]3[Ag]([O]2=P([O]56)(c2ccccc2)c2ccccc2)([O]=C(O1)C(F)(F)F)[P](C[P]7(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C(F)(F)F.N#CC.N#CC |
| Title of publication | Bis[μ~2~-bis(diphenylphosphanyl)methane-κ^2^<i>P</i>:<i>P</i>']bis(μ~4~-diphenylphosphinato-κ^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis(μ~2~-trifluoroacetato-κ^2^<i>O</i>:<i>O</i>')tetrasilver(I) acetonitrile disolvate |
| Authors of publication | Huang, Li-Li; Jia, Chen; Tang, Li-Ping; Jing, Bai; Deng, Qi-Hua |
| Journal of publication | Acta Crystallographica Section E |
| Year of publication | 2011 |
| Journal volume | 67 |
| Journal issue | 12 |
| Pages of publication | m1677 - m1678 |
| a | 11.724 ± 0.005 Å |
| b | 14.777 ± 0.006 Å |
| c | 24.183 ± 0.01 Å |
| α | 90° |
| β | 102.254 ± 0.005° |
| γ | 90° |
| Cell volume | 4094 ± 3 Å3 |
| Cell temperature | 296 ± 2 K |
| Ambient diffraction temperature | 296 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0571 |
| Residual factor for significantly intense reflections | 0.0455 |
| Weighted residual factors for significantly intense reflections | 0.1096 |
| Weighted residual factors for all reflections included in the refinement | 0.1167 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.014 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 181251 (current) | 2016-04-03 | hkl/2/23/ (antanas@echidna) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/23/29. |
2232930.cif 2232930.hkl |
| 176798 | 2016-02-21 | cif/2/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/23. |
2232930.cif 2232930.hkl |
| 120072 | 2014-07-11 | Adding DOIs to range 2 structures. | 2232930.cif 2232930.hkl |
| 88064 | 2013-08-29 | Adding _cod_database_fobs_code data item to all COD CIFs that have Fobs deposited and did not have this data item yet. | 2232930.cif 2232930.hkl |
| 31968 | 2012-01-03 | hkl/ Adding automatically assigned IUCr Fobs data for the rest of the year 2001 structures. |
2232930.cif 2232930.hkl |
| 31816 | 2012-01-02 | ../uploads/cif-deposit/cod/cif Adding structures of 2232930 via cif-deposit CGI script. |
2232930.cif |
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