#------------------------------------------------------------------------------ #$Date: 2012-02-14 12:59:18 +0200 (Tue, 14 Feb 2012) $ #$Revision: 34292 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/31/2233136.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2233136_Fobs loop_ _publ_author_name 'Liu, Biao' 'Zhang, Xin' 'Wen, Lei' 'Sun, Wei' 'Huang, Ya-Xi' _publ_section_title ; An ammonium iron(II) pyrophosphate, (NH~4~)~2~[Fe~3~(P~2~O~7~)~2~(H~2~O)~2~], with a layered structure ; _journal_coeditor_code FI2119 _journal_issue 1 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first i5 _journal_page_last i6 _journal_volume 68 _journal_year 2012 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 99.651 _cell_angle_gamma 90.000 _cell_length_a 9.4131 _cell_length_b 8.1940 _cell_length_c 9.3987 _exptl_crystal_F_000 584.00 _reflns_d_resolution_high 0.7505 _[local]_cod_data_source_file fi2119Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' test in P 21/a New: P21/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 164.86 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 27178.53 26336.97 315.75 o 2 0 0 184.67 191.40 11.45 o 3 0 0 16.79 25.23 8.38 o 4 0 0 363.08 460.83 29.70 o 5 0 0 4316.13 4297.68 146.45 o 6 0 0 186.12 148.90 25.30 o 7 0 0 16984.36 16632.21 375.35 o 8 0 0 2661.48 2384.51 90.57 o 9 0 0 2191.68 2113.10 91.12 o 10 0 0 1205.53 1270.07 114.19 o 11 0 0 453.61 436.27 83.09 o 12 0 0 533.66 538.88 93.48 o 1 1 0 1295.37 1411.17 21.68 o 2 1 0 46.03 42.55 8.00 o 3 1 0 2375.64 2591.65 39.70 o 4 1 0 350.96 387.41 24.01 o 5 1 0 4957.28 5138.56 72.22 o 6 1 0 1659.07 1531.62 41.18 o 7 1 0 432.33 468.43 43.88 o 8 1 0 2092.27 2049.58 68.35 o 9 1 0 287.81 344.68 37.65 o 10 1 0 250.65 321.00 38.34 o 11 1 0 285.06 333.72 41.52 o 12 1 0 558.67 774.13 104.85 o 0 2 0 1255.18 1356.92 53.64 o 1 2 0 334.13 385.08 13.97 o 2 2 0 802.63 716.19 20.84 o 3 2 0 5798.48 5860.25 66.45 o 4 2 0 7556.33 7844.39 87.15 o 5 2 0 811.20 824.54 34.70 o 6 2 0 1176.08 1115.68 39.69 o 7 2 0 1972.27 1861.66 60.97 o 8 2 0 31.94 38.63 16.83 o 9 2 0 242.05 280.39 34.07 o 10 2 0 67.09 86.87 23.54 o 11 2 0 38.28 81.63 33.06 o 1 3 0 7826.52 7838.39 95.88 o 2 3 0 49.52 44.52 6.50 o 3 3 0 576.40 582.81 22.22 o 4 3 0 2.25 14.20 7.13 o 5 3 0 280.09 302.87 22.37 o 6 3 0 5319.50 5363.17 86.38 o 7 3 0 2.43 13.16 13.62 o 8 3 0 0.20 -0.94 14.57 o 9 3 0 848.65 1132.56 136.38 o 10 3 0 13.34 46.15 31.68 o 11 3 0 462.13 431.79 62.71 o 0 4 0 1850.83 2017.17 113.73 o 1 4 0 1486.61 1598.71 41.32 o 2 4 0 6304.46 6658.15 100.76 o 3 4 0 9516.69 9856.62 110.59 o 4 4 0 8322.78 8655.13 118.38 o 5 4 0 2204.86 2139.55 60.81 o 6 4 0 0.67 -0.55 12.68 o 7 4 0 58.67 123.52 31.06 o 8 4 0 457.17 528.32 79.30 o 9 4 0 218.80 267.12 46.38 o 10 4 0 986.08 1058.36 85.82 o 11 4 0 3172.30 3313.31 206.71 o 1 5 0 116.82 124.48 16.05 o 2 5 0 5076.88 5000.99 129.02 o 3 5 0 2470.31 2526.57 88.82 o 4 5 0 397.08 422.29 40.02 o 5 5 0 2230.95 2197.62 72.18 o 6 5 0 22.57 48.75 18.31 o 7 5 0 56.19 76.54 27.31 o 8 5 0 28.50 25.63 23.77 o 9 5 0 901.61 968.17 82.25 o 10 5 0 657.34 877.39 102.57 o 0 6 0 3589.18 3302.39 148.99 o 1 6 0 2258.21 2153.51 84.74 o 2 6 0 120.34 156.48 20.45 o 3 6 0 30.32 34.37 15.43 o 4 6 0 38.57 47.93 16.58 o 5 6 0 1.60 8.90 11.85 o 6 6 0 175.35 217.94 38.56 o 7 6 0 1150.43 1187.37 77.75 o 8 6 0 2536.92 2380.89 144.69 o 9 6 0 720.09 758.21 76.95 o 10 6 0 69.45 107.75 56.04 o 1 7 0 146.02 176.49 33.29 o 2 7 0 1335.39 1381.35 77.58 o 3 7 0 325.93 357.38 79.10 o 4 7 0 60.87 56.66 24.93 o 5 7 0 444.17 433.85 52.26 o 6 7 0 326.63 354.44 42.33 o 7 7 0 173.30 279.47 40.37 o 8 7 0 393.87 490.33 63.48 o 9 7 0 28.97 43.74 36.93 o 0 8 0 1043.45 988.62 107.08 o 1 8 0 882.78 901.10 73.67 o 2 8 0 8.32 26.12 18.15 o 3 8 0 861.76 937.85 80.07 o 4 8 0 46.99 42.37 25.38 o 5 8 0 789.13 831.10 79.88 o 6 8 0 623.27 603.23 72.33 o 7 8 0 934.42 1041.88 100.24 o 1 9 0 1584.18 1344.72 89.86 o 2 9 0 2009.29 1825.57 99.41 o 3 9 0 1738.19 1831.66 112.91 o 4 9 0 159.65 169.68 43.04 o 5 9 0 193.54 219.81 48.09 o 6 9 0 997.34 931.21 94.71 o 0 10 0 72.14 49.63 38.15 o 1 10 0 819.88 793.62 82.38 o 2 10 0 2001.09 1679.95 361.39 o 3 10 0 568.62 451.28 65.96 o -12 1 1 1003.13 1029.84 84.62 o -11 1 1 2944.35 2854.56 112.92 o -10 1 1 676.88 788.70 54.91 o -9 1 1 22.46 39.89 25.24 o -8 1 1 0.21 -0.22 12.89 o -7 1 1 662.14 606.43 38.25 o -6 1 1 64.10 69.77 15.21 o -5 1 1 11740.68 12028.75 118.25 o -4 1 1 7393.87 7139.80 77.40 o -3 1 1 1536.83 1428.60 27.40 o -2 1 1 1308.35 1309.61 29.15 o -1 1 1 4753.31 5079.62 54.88 o 0 1 1 260.12 255.75 16.41 o 1 1 1 5766.06 6209.92 55.50 o 2 1 1 6455.99 7059.75 68.56 o 3 1 1 1733.37 1569.50 49.67 o 4 1 1 1775.96 1781.75 38.88 o 5 1 1 1399.76 1297.98 36.39 o 6 1 1 3099.06 3050.06 66.47 o 7 1 1 733.99 608.65 35.96 o 8 1 1 295.17 279.90 37.59 o 9 1 1 2047.54 1837.55 79.15 o 10 1 1 1080.89 1201.36 66.45 o 11 1 1 452.95 527.08 66.72 o 12 1 1 747.48 758.93 107.06 o -11 2 1 17.74 41.84 24.98 o -10 2 1 2370.32 2426.20 85.32 o -9 2 1 715.10 639.47 47.48 o -8 2 1 160.56 144.41 23.29 o -7 2 1 2.03 1.00 12.55 o -6 2 1 3124.69 2847.79 101.01 o -5 2 1 6636.43 6958.64 95.41 o -4 2 1 487.68 538.27 28.31 o -3 2 1 967.66 831.87 27.40 o -2 2 1 249.68 222.29 14.70 o -1 2 1 290.68 290.93 13.25 o 0 2 1 289.67 346.94 11.55 o 1 2 1 12613.00 13321.44 106.77 o 2 2 1 10843.79 11251.66 97.52 o 3 2 1 3355.53 3616.81 51.80 o 4 2 1 106.10 168.20 18.80 o 5 2 1 1568.44 1530.28 82.56 o 6 2 1 12570.54 12780.68 167.47 o 7 2 1 4387.79 4224.33 110.50 o 8 2 1 1913.04 1838.02 66.08 o 9 2 1 2841.69 2727.38 85.55 o 10 2 1 557.41 604.74 51.30 o 11 2 1 340.70 489.70 64.46 o -11 3 1 30.58 54.25 43.84 o -10 3 1 603.05 734.41 72.61 o -9 3 1 1216.06 1241.02 79.39 o -8 3 1 4292.25 4282.71 146.56 o -7 3 1 7389.79 6930.32 123.96 o -6 3 1 350.04 317.80 27.65 o -5 3 1 1415.24 1426.66 37.01 o -4 3 1 2761.22 2816.76 79.35 o -3 3 1 354.57 458.84 21.54 o -2 3 1 29.13 32.42 7.70 o -1 3 1 787.75 665.20 24.24 o 0 3 1 7676.90 7606.07 72.22 o 1 3 1 13224.00 13286.35 141.79 o 2 3 1 2844.17 2812.35 68.20 o 3 3 1 346.63 395.59 17.62 o 4 3 1 74.82 72.62 11.32 o 5 3 1 0.75 6.41 10.17 o 6 3 1 1421.69 1510.75 51.38 o 7 3 1 480.93 508.56 45.70 o 8 3 1 1035.36 1038.37 69.64 o 9 3 1 596.85 579.37 62.34 o 10 3 1 22.75 33.29 26.25 o 11 3 1 362.52 443.19 64.01 o -11 4 1 308.93 345.08 77.44 o -10 4 1 341.48 345.74 54.75 o -9 4 1 12.42 28.84 22.01 o -8 4 1 938.48 953.98 72.98 o -7 4 1 17.42 52.04 23.70 o -6 4 1 13.70 45.84 20.02 o -5 4 1 1430.60 1411.28 65.20 o -4 4 1 46.92 70.51 22.24 o -3 4 1 94.25 103.91 12.30 o -2 4 1 227.94 231.13 22.87 o -1 4 1 580.92 656.00 23.51 o 0 4 1 5774.63 6027.92 82.08 o 1 4 1 1536.83 1505.86 42.17 o 2 4 1 230.53 274.05 23.22 o 3 4 1 942.84 1028.82 47.71 o 4 4 1 49.42 55.35 14.16 o 5 4 1 1741.68 1695.85 56.56 o 6 4 1 1304.00 1257.52 66.23 o 7 4 1 726.53 786.07 63.77 o 8 4 1 6.18 30.58 21.13 o 9 4 1 950.38 941.78 98.88 o 10 4 1 2358.34 2275.33 113.00 o 11 4 1 890.02 756.69 112.86 o -10 5 1 27.91 23.50 28.30 o -9 5 1 142.58 195.87 42.33 o -8 5 1 14.72 11.41 37.69 o -7 5 1 433.20 496.75 54.70 o -6 5 1 398.27 393.03 47.24 o -5 5 1 465.17 455.91 33.59 o -4 5 1 1364.01 1364.09 62.44 o -3 5 1 8061.15 8345.23 178.18 o -2 5 1 7870.57 7929.38 277.65 o -1 5 1 912.73 940.81 28.28 o 0 5 1 2531.58 2511.34 67.02 o 1 5 1 2899.32 2862.31 64.67 o 2 5 1 959.95 992.77 42.67 o 3 5 1 356.19 391.96 36.55 o 4 5 1 405.61 243.54 29.79 o 5 5 1 1475.94 1409.68 76.70 o 6 5 1 2235.30 2352.17 137.76 o 7 5 1 3541.16 3545.37 142.25 o 8 5 1 3630.42 3595.44 131.56 o 9 5 1 1700.76 1717.74 117.68 o 10 5 1 2.80 39.96 32.28 o -10 6 1 1850.75 1553.19 147.90 o -9 6 1 1384.34 1414.55 191.88 o -8 6 1 533.14 565.27 65.60 o -7 6 1 2138.66 2321.90 104.63 o -6 6 1 2597.69 2661.90 105.84 o -5 6 1 1318.38 1352.12 71.15 o -4 6 1 415.06 409.58 38.18 o -3 6 1 372.34 427.85 63.68 o -2 6 1 6498.63 6224.04 155.13 o -1 6 1 8978.35 8283.66 225.22 o 0 6 1 265.45 204.85 30.68 o 1 6 1 293.79 255.11 44.92 o 2 6 1 379.41 464.99 38.51 o 3 6 1 2703.93 2609.23 96.82 o 4 6 1 2242.55 2234.16 72.63 o 5 6 1 1142.68 1141.53 64.11 o 6 6 1 1808.37 1793.33 68.14 o 7 6 1 35.57 59.34 30.17 o 8 6 1 55.94 86.57 33.55 o 9 6 1 37.01 22.24 27.47 o 10 6 1 65.57 52.24 48.51 o -9 7 1 319.32 418.75 65.56 o -8 7 1 134.94 175.13 44.09 o -7 7 1 443.17 524.25 52.18 o -6 7 1 1026.23 1087.97 68.08 o -5 7 1 1307.60 1394.57 90.65 o -4 7 1 139.92 150.00 32.66 o -3 7 1 442.28 480.94 55.88 o -2 7 1 318.73 364.67 48.91 o -1 7 1 197.70 270.69 41.92 o 0 7 1 595.78 610.28 57.09 o 1 7 1 1410.67 1283.81 195.10 o 2 7 1 2517.04 2576.66 103.18 o 3 7 1 4690.42 4866.83 148.97 o 4 7 1 6040.63 6097.83 172.69 o 5 7 1 2169.59 2172.53 67.40 o 6 7 1 224.99 281.96 53.08 o 7 7 1 1006.87 1028.66 69.10 o 8 7 1 154.27 173.60 35.06 o 9 7 1 173.64 217.01 52.53 o -7 8 1 6.00 28.62 28.59 o -6 8 1 539.63 624.43 75.54 o -5 8 1 1695.31 1676.73 101.69 o -4 8 1 25.75 56.32 23.84 o -3 8 1 522.78 502.87 72.79 o -2 8 1 2676.12 2533.06 109.96 o -1 8 1 1773.26 1805.92 91.24 o 0 8 1 1471.10 1445.67 131.67 o 1 8 1 281.49 355.17 94.80 o 2 8 1 546.49 569.91 63.67 o 3 8 1 29.54 68.38 26.55 o 4 8 1 178.01 177.40 38.22 o 5 8 1 7.83 25.85 18.77 o 6 8 1 171.64 224.92 52.81 o 7 8 1 444.46 400.36 67.07 o -6 9 1 1952.98 1560.84 248.19 o -5 9 1 368.00 296.15 53.82 o -4 9 1 1.16 30.04 25.11 o -3 9 1 764.55 818.64 141.15 o -2 9 1 1855.11 1625.05 99.44 o -1 9 1 24.68 18.90 19.70 o 0 9 1 783.63 816.01 76.10 o 1 9 1 1355.51 1356.05 90.85 o 2 9 1 1.67 4.97 21.25 o 3 9 1 33.61 68.26 28.25 o 4 9 1 1020.14 893.50 85.22 o 5 9 1 804.83 840.61 85.04 o 6 9 1 1.43 -5.62 38.45 o -3 10 1 80.09 132.93 38.84 o -2 10 1 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45.53 o -8 1 2 76.20 148.78 25.57 o -7 1 2 1380.16 1223.58 76.27 o -6 1 2 199.77 131.30 19.45 o -5 1 2 953.04 794.11 44.80 o -4 1 2 3237.55 3481.49 66.42 o -3 1 2 9373.12 9686.45 111.89 o -2 1 2 20259.56 19659.90 174.90 o -1 1 2 1520.99 1618.61 31.14 o 0 1 2 1043.01 1087.59 17.92 o 1 1 2 9960.40 10804.02 80.87 o 2 1 2 14478.39 14521.14 121.20 o 3 1 2 28.08 78.62 10.91 o 4 1 2 548.91 553.33 24.08 o 5 1 2 3286.32 3228.41 60.70 o 6 1 2 2771.96 2611.41 58.63 o 7 1 2 5484.04 5033.64 88.15 o 8 1 2 367.67 363.35 31.70 o 9 1 2 546.85 569.74 45.92 o 10 1 2 340.70 380.12 42.44 o 11 1 2 49.35 43.95 31.59 o -11 2 2 729.58 743.80 57.91 o -10 2 2 297.57 360.20 39.89 o -9 2 2 271.81 325.55 36.64 o -8 2 2 1020.40 884.27 48.31 o -7 2 2 1689.25 1652.80 57.51 o -6 2 2 279.32 245.09 25.63 o -5 2 2 2919.61 2809.39 46.05 o -4 2 2 420.03 406.28 21.59 o -3 2 2 881.05 898.23 30.65 o -2 2 2 4080.83 3709.86 79.17 o -1 2 2 26187.33 26258.49 218.49 o 0 2 2 500.18 519.81 22.79 o 1 2 2 4303.40 4547.13 48.13 o 2 2 2 4808.00 4793.89 58.41 o 3 2 2 1850.33 1940.06 39.01 o 4 2 2 11.29 20.14 9.12 o 5 2 2 959.39 978.70 45.16 o 6 2 2 1878.60 1875.79 49.98 o 7 2 2 64.76 83.22 20.08 o 8 2 2 1844.74 1715.83 55.01 o 9 2 2 1499.39 1568.55 66.01 o 10 2 2 1514.01 1495.25 86.61 o 11 2 2 512.61 614.28 102.05 o -11 3 2 214.28 166.52 40.63 o -10 3 2 927.24 895.96 141.30 o -9 3 2 2033.21 2174.45 76.38 o -8 3 2 11.37 14.06 14.60 o -7 3 2 964.32 894.54 59.30 o -6 3 2 234.70 218.64 24.64 o -5 3 2 3105.07 3231.44 59.83 o -4 3 2 5229.62 5494.73 89.03 o -3 3 2 88.88 100.88 14.19 o -2 3 2 289.70 263.50 17.65 o -1 3 2 861.40 1013.47 25.74 o 0 3 2 4001.55 4695.85 56.12 o 1 3 2 736.34 920.42 21.60 o 2 3 2 2695.04 3016.96 41.53 o 3 3 2 247.24 241.92 17.57 o 4 3 2 707.94 687.73 26.22 o 5 3 2 1.47 15.26 10.31 o 6 3 2 435.90 460.54 29.08 o 7 3 2 0.48 8.36 20.16 o 8 3 2 0.32 21.04 20.42 o 9 3 2 1697.02 1651.56 88.71 o 10 3 2 296.85 303.73 52.01 o -11 4 2 1251.21 1039.07 90.94 o -10 4 2 429.65 468.64 61.56 o -9 4 2 475.23 494.22 59.31 o -8 4 2 153.87 168.32 35.95 o -7 4 2 482.57 558.96 55.62 o -6 4 2 352.68 324.76 29.22 o -5 4 2 7137.85 7530.32 143.12 o -4 4 2 14137.68 14826.97 195.16 o -3 4 2 4755.01 4855.33 89.91 o -2 4 2 434.56 409.98 20.02 o -1 4 2 169.21 169.07 13.31 o 0 4 2 1541.96 1478.01 29.74 o 1 4 2 2283.88 2343.05 55.70 o 2 4 2 1859.00 1716.81 49.24 o 3 4 2 5122.66 4983.12 134.11 o 4 4 2 4161.51 4153.42 106.96 o 5 4 2 2522.00 2308.37 80.72 o 6 4 2 1343.12 1396.44 58.42 o 7 4 2 54.10 54.33 19.88 o 8 4 2 433.45 478.51 57.25 o 9 4 2 78.23 102.05 33.04 o 10 4 2 21.74 48.41 30.35 o -10 5 2 660.11 625.19 72.27 o -9 5 2 175.11 245.77 45.89 o -8 5 2 200.70 254.80 45.63 o -7 5 2 1.99 15.25 18.71 o -6 5 2 6496.09 6682.17 165.08 o -5 5 2 862.16 856.68 55.79 o -4 5 2 528.71 447.16 107.67 o -3 5 2 1927.90 1956.61 110.61 o -2 5 2 921.78 824.40 29.83 o -1 5 2 6157.07 6309.46 79.07 o 0 5 2 183.09 209.43 21.45 o 1 5 2 11529.02 11248.54 177.03 o 2 5 2 994.80 1029.39 42.08 o 3 5 2 138.22 134.24 23.60 o 4 5 2 187.86 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