#------------------------------------------------------------------------------ #$Date: 2012-09-11 12:26:43 +0300 (Tue, 11 Sep 2012) $ #$Revision: 66590 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/41/2234170.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2234170_Fobs loop_ _publ_author_name 'Trush, Victor A.' 'Gubina, Kateryna E.' 'Gumeniuk, Yaroslav O.' 'Sliva, Tetyana Yu.' 'Konovalova, Irina S.' _publ_section_title ; Tetramethyl N,N'-(2,2,3,3,4,4-hexafluoro-1,5-dioxopentane-1,5-diyl)bis(phosphoramidate) ; _journal_coeditor_code FJ2523 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1127 _journal_volume 68 _journal_year 2012 _space_group_IT_number 15 _symmetry_space_group_name_Hall '-C 2yc' _symmetry_space_group_name_H-M 'C 1 2/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 100.427 _cell_angle_gamma 90.000 _cell_length_a 19.7862 _cell_length_b 5.2801 _cell_length_c 16.9943 _exptl_crystal_F_000 920.00 _reflns_d_resolution_high 0.7108 _[local]_cod_data_source_file fj2523Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' kiev49 in C2/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 296.41 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 4 0 0 18080.93 18194.90 393.15 o 6 0 0 56.73 52.09 6.54 o 10 0 0 1616.67 1860.71 25.68 o 12 0 0 2775.38 3152.35 30.27 o 14 0 0 4.35 14.70 12.17 o 16 0 0 195.35 213.71 15.89 o 18 0 0 4242.29 4322.82 147.02 o 20 0 0 157.88 161.71 18.26 o 22 0 0 658.30 712.08 45.81 o 24 0 0 53.56 28.03 35.49 o 26 0 0 495.08 495.68 51.50 o 1 1 0 2469.42 2342.54 79.30 o 3 1 0 14055.02 13985.05 144.25 o 5 1 0 5019.85 5040.10 38.59 o 7 1 0 24.90 28.79 7.02 o 9 1 0 959.80 1082.47 11.34 o 11 1 0 977.36 856.54 11.80 o 13 1 0 3908.68 3866.80 56.43 o 15 1 0 888.61 790.49 17.53 o 17 1 0 1532.54 1501.49 23.27 o 19 1 0 137.57 120.76 14.87 o 21 1 0 1208.17 1263.46 36.71 o 23 1 0 528.96 575.67 43.67 o 25 1 0 12.78 0.00 8.08 o 27 1 0 148.77 161.91 31.36 o 0 2 0 2627.84 2939.48 24.57 o 2 2 0 5954.99 6068.28 28.84 o 4 2 0 1388.24 1607.07 24.29 o 6 2 0 580.17 582.40 12.05 o 8 2 0 1064.92 1180.77 18.37 o 10 2 0 6841.09 6995.70 53.99 o 12 2 0 694.72 577.21 99.76 o 14 2 0 2740.10 2838.00 26.34 o 16 2 0 1135.15 1179.46 41.56 o 18 2 0 63.20 51.42 13.56 o 20 2 0 317.20 272.80 24.11 o 22 2 0 21.46 9.99 14.75 o 24 2 0 161.50 142.45 25.77 o 26 2 0 5.89 19.08 34.36 o 1 3 0 3818.41 3914.10 20.89 o 3 3 0 1521.88 1433.16 20.30 o 5 3 0 50.98 43.93 4.76 o 7 3 0 321.41 283.21 18.35 o 9 3 0 1056.22 1126.41 17.52 o 11 3 0 0.31 0.00 14.52 o 13 3 0 388.18 358.27 23.04 o 15 3 0 119.99 94.82 19.06 o 17 3 0 5.53 0.00 7.88 o 19 3 0 7.20 0.88 3.35 o 21 3 0 14.10 17.94 19.30 o 23 3 0 2.55 0.42 16.78 o 25 3 0 5.21 2.46 26.20 o 0 4 0 3.73 0.00 5.56 o 2 4 0 963.61 990.68 15.29 o 4 4 0 100.31 102.20 8.33 o 6 4 0 1367.44 1375.73 22.32 o 8 4 0 1402.71 1418.94 39.14 o 10 4 0 26.19 33.81 11.35 o 12 4 0 331.15 298.99 16.08 o 14 4 0 251.55 248.32 17.36 o 16 4 0 267.41 291.73 18.62 o 18 4 0 18.82 15.76 15.88 o 20 4 0 222.94 225.65 21.19 o 22 4 0 18.84 6.64 24.85 o 1 5 0 30.49 30.58 9.67 o 3 5 0 83.08 62.84 10.36 o 5 5 0 6.77 0.00 11.95 o 7 5 0 188.56 176.31 13.69 o 9 5 0 275.09 300.80 18.33 o 11 5 0 11.28 6.47 12.25 o 13 5 0 146.20 151.34 13.50 o 15 5 0 57.11 60.18 14.18 o 17 5 0 54.97 37.34 15.33 o 19 5 0 9.73 13.63 20.75 o 0 6 0 1852.95 2370.35 61.52 o 2 6 0 45.96 44.20 14.56 o 4 6 0 261.34 226.01 21.75 o 6 6 0 0.54 0.00 2.33 o 8 6 0 123.90 116.33 15.68 o 10 6 0 37.99 35.38 14.35 o 12 6 0 0.46 0.00 8.12 o 14 6 0 111.58 119.05 17.72 o 16 6 0 68.10 46.65 16.73 o 1 7 0 2.12 0.00 13.18 o 3 7 0 122.02 97.16 32.05 o 5 7 0 56.22 62.40 17.03 o 7 7 0 28.60 18.59 16.53 o 9 7 0 55.22 65.80 17.31 o -27 1 1 0.08 19.06 29.26 o -25 1 1 77.11 58.80 27.35 o -23 1 1 24.60 15.24 15.32 o -21 1 1 462.14 461.15 19.95 o -19 1 1 624.93 556.88 15.84 o -17 1 1 26.38 15.97 10.10 o -15 1 1 451.39 428.26 12.81 o -13 1 1 1883.61 1894.65 31.52 o -11 1 1 382.57 406.26 12.05 o -9 1 1 787.41 710.11 10.99 o -7 1 1 834.08 721.46 133.38 o -5 1 1 3128.77 3163.44 33.30 o -3 1 1 4421.64 4995.20 43.02 o -1 1 1 7166.12 7696.01 70.38 o 1 1 1 3263.91 3659.68 30.41 o 3 1 1 1729.18 1617.26 8.95 o 5 1 1 3969.41 4496.80 25.85 o 7 1 1 1000.04 917.65 14.34 o 9 1 1 5280.84 5947.04 48.32 o 11 1 1 480.80 458.26 9.68 o 13 1 1 77.45 76.96 9.53 o 15 1 1 65.84 63.41 8.75 o 17 1 1 37.69 27.99 12.02 o 19 1 1 1.74 6.56 13.34 o 21 1 1 18.32 14.16 26.29 o 23 1 1 0.14 3.15 17.69 o 25 1 1 154.84 164.27 27.92 o -26 2 1 9.66 25.55 43.71 o -24 2 1 105.97 102.69 18.50 o -22 2 1 84.70 81.90 16.27 o -20 2 1 45.82 40.59 13.88 o -18 2 1 430.50 387.50 17.59 o -16 2 1 1506.15 1567.60 32.10 o -14 2 1 233.58 213.86 15.47 o -12 2 1 2241.28 2318.29 29.10 o -10 2 1 1219.90 1199.67 36.43 o -8 2 1 4400.52 4290.80 63.89 o -6 2 1 1321.23 1342.19 15.56 o -4 2 1 5491.33 5756.25 43.80 o -2 2 1 8110.06 7812.20 46.54 o 0 2 1 13088.08 13810.88 52.27 o 2 2 1 952.26 1113.94 11.01 o 4 2 1 1872.29 2150.30 23.12 o 6 2 1 478.90 478.52 12.67 o 8 2 1 15.58 8.37 6.56 o 10 2 1 2753.95 2815.51 31.45 o 12 2 1 109.64 103.71 12.68 o 14 2 1 3085.90 3315.77 39.29 o 16 2 1 301.41 247.01 13.99 o 18 2 1 48.43 21.80 19.17 o 20 2 1 358.92 352.75 25.11 o 22 2 1 66.72 47.21 14.93 o 24 2 1 173.48 200.70 27.71 o 26 2 1 14.56 17.18 32.38 o -25 3 1 123.99 153.98 27.11 o -23 3 1 6.75 0.00 12.95 o -21 3 1 261.26 278.36 24.85 o -19 3 1 4.60 7.69 31.55 o -17 3 1 168.31 148.66 22.17 o -15 3 1 589.04 624.56 26.56 o -13 3 1 0.05 14.16 27.19 o -11 3 1 13.62 28.83 17.78 o -9 3 1 1255.65 1218.40 23.95 o -7 3 1 5392.22 6008.91 72.50 o -3 3 1 2188.58 2099.64 16.26 o -1 3 1 825.21 766.68 14.67 o 1 3 1 927.29 869.76 11.08 o 3 3 1 1132.12 1206.49 13.87 o 5 3 1 2487.37 2502.67 18.08 o 7 3 1 1583.19 1803.91 17.17 o 9 3 1 4232.97 4396.74 31.64 o 11 3 1 14428.78 15393.46 290.74 o 13 3 1 967.20 1107.02 22.52 o 15 3 1 250.89 170.36 65.00 o 17 3 1 38.71 18.26 17.67 o 19 3 1 96.41 81.10 22.45 o 21 3 1 240.93 226.64 23.81 o 23 3 1 73.81 67.26 21.37 o -22 4 1 37.36 41.76 23.00 o -20 4 1 4.34 1.61 15.50 o -18 4 1 296.02 335.19 20.23 o -16 4 1 264.97 239.68 37.33 o -14 4 1 7.05 2.64 9.37 o -12 4 1 1665.36 1757.79 28.23 o -10 4 1 2883.64 2929.61 28.22 o -8 4 1 323.85 301.76 14.02 o -6 4 1 1173.43 1224.15 21.63 o -4 4 1 945.11 967.55 14.52 o -2 4 1 1891.68 2098.13 17.95 o 0 4 1 0.82 0.35 3.59 o 2 4 1 14.08 14.01 7.55 o 4 4 1 269.99 299.82 10.58 o 6 4 1 1938.49 2058.62 48.71 o 8 4 1 814.57 809.42 19.24 o 10 4 1 148.24 145.69 11.99 o 12 4 1 0.21 0.73 6.23 o 14 4 1 373.37 391.37 18.68 o 16 4 1 243.80 267.24 19.94 o 18 4 1 27.31 31.38 16.77 o 20 4 1 128.67 138.25 20.44 o 22 4 1 26.65 21.57 27.18 o -19 5 1 117.69 106.88 16.65 o -17 5 1 5.60 0.42 5.22 o -15 5 1 78.53 75.92 13.73 o -13 5 1 16.78 18.34 11.69 o -11 5 1 354.80 350.22 15.00 o -9 5 1 0.38 0.00 8.24 o -7 5 1 320.03 313.34 16.03 o -5 5 1 8.87 7.05 11.33 o -3 5 1 149.84 160.17 12.04 o -1 5 1 10.11 7.16 9.11 o 1 5 1 666.60 686.00 13.94 o 3 5 1 126.62 106.22 13.25 o 5 5 1 38.11 18.96 11.58 o 7 5 1 326.16 309.03 15.87 o 9 5 1 104.04 90.49 12.33 o 11 5 1 205.15 205.48 15.62 o 13 5 1 15.18 10.54 13.31 o 17 5 1 14.62 11.28 15.28 o 19 5 1 96.64 112.18 21.36 o -16 6 1 50.96 44.22 16.82 o -14 6 1 9.63 2.71 6.67 o -12 6 1 36.02 19.64 14.40 o -10 6 1 4.73 3.42 9.47 o -8 6 1 0.13 3.10 16.29 o -6 6 1 7.44 2.83 10.12 o -4 6 1 40.93 33.36 13.32 o -2 6 1 23.62 2.48 19.21 o 0 6 1 0.14 0.09 5.59 o 2 6 1 178.79 208.34 16.90 o 4 6 1 53.47 41.29 17.10 o 6 6 1 130.36 119.92 15.36 o 8 6 1 143.35 129.45 16.34 o 10 6 1 20.56 19.54 13.57 o 12 6 1 25.39 24.75 14.51 o 14 6 1 70.76 80.13 17.83 o -9 7 1 22.18 20.66 17.09 o -7 7 1 2.59 5.08 14.28 o -5 7 1 0.10 11.38 18.89 o -3 7 1 2.01 4.01 16.11 o -1 7 1 23.86 17.62 29.21 o 1 7 1 94.60 88.67 23.23 o 3 7 1 115.43 85.44 32.38 o 5 7 1 6.13 12.20 15.18 o 7 7 1 1.49 11.09 19.52 o -26 0 2 23.55 19.29 40.20 o -24 0 2 633.13 629.95 48.82 o -22 0 2 768.95 882.29 29.10 o -20 0 2 117.52 115.81 18.07 o -18 0 2 2315.60 2470.62 35.67 o -16 0 2 1110.40 1202.86 26.05 o -14 0 2 94.08 96.68 14.41 o -12 0 2 369.80 403.30 15.77 o -10 0 2 444.25 392.88 13.68 o -8 0 2 378.31 442.72 12.32 o -6 0 2 411.05 460.25 12.52 o -4 0 2 21806.45 22045.25 188.31 o -2 0 2 9284.17 9648.24 128.34 o 2 0 2 87861.59 81812.05 974.92 o 4 0 2 16976.35 15608.00 72.06 o 6 0 2 2061.91 1954.58 29.99 o 8 0 2 556.38 437.58 14.11 o 10 0 2 136.69 122.99 7.52 o 14 0 2 3879.59 4176.75 50.38 o 16 0 2 2960.19 2945.67 33.83 o 18 0 2 1320.09 1390.80 50.37 o 20 0 2 2635.76 2686.17 66.90 o 22 0 2 2173.16 2481.52 68.35 o 24 0 2 2.35 12.89 38.70 o 26 0 2 108.86 129.84 44.20 o -27 1 2 18.12 24.12 27.56 o -25 1 2 75.52 57.69 26.83 o -23 1 2 372.50 380.27 20.74 o -21 1 2 119.96 107.71 15.93 o -19 1 2 931.64 888.32 18.42 o -17 1 2 1069.66 1039.08 18.14 o -15 1 2 761.18 710.60 15.22 o -13 1 2 13.41 6.60 7.46 o -11 1 2 2010.87 1856.63 17.32 o -9 1 2 430.00 474.81 10.25 o -7 1 2 9711.38 10535.85 197.97 o -5 1 2 18800.81 18709.49 428.70 o -3 1 2 344.01 298.23 8.64 o -1 1 2 36807.25 36399.42 323.64 o 1 1 2 11376.24 11570.94 23.02 o 3 1 2 6494.27 6385.85 22.12 o 5 1 2 638.55 598.32 7.93 o 7 1 2 1613.38 1397.62 19.97 o 9 1 2 3629.62 3710.59 25.31 o 11 1 2 1960.89 2107.78 15.82 o 13 1 2 109.87 85.99 9.55 o 15 1 2 148.93 128.05 9.19 o 17 1 2 1609.73 1534.39 52.60 o 19 1 2 26.37 21.15 12.83 o 21 1 2 642.49 637.85 30.48 o 23 1 2 36.52 41.37 24.60 o 25 1 2 301.98 320.05 42.32 o -26 2 2 104.98 72.12 45.25 o -24 2 2 0.81 0.44 10.94 o -22 2 2 134.52 106.27 16.60 o -20 2 2 109.65 99.39 14.85 o -18 2 2 2225.77 2225.95 87.85 o -16 2 2 52.38 62.22 13.56 o -14 2 2 3600.27 3523.13 63.76 o -12 2 2 832.20 839.70 33.59 o -10 2 2 2092.83 2200.96 141.50 o -8 2 2 1955.40 1988.70 53.38 o -6 2 2 1035.64 1219.56 20.88 o -4 2 2 8.04 2.94 6.23 o -2 2 2 5375.68 6312.60 25.38 o 0 2 2 99.58 116.79 5.40 o 2 2 2 182.43 209.41 6.61 o 4 2 2 6185.59 6344.37 29.91 o 6 2 2 553.63 552.23 9.67 o 8 2 2 2158.16 2254.34 25.73 o 10 2 2 303.75 273.72 11.65 o 12 2 2 1141.70 1287.91 49.39 o 14 2 2 35.29 34.31 11.61 o 16 2 2 74.78 67.59 12.35 o 18 2 2 14.65 0.00 7.37 o 20 2 2 134.48 142.19 15.64 o 22 2 2 39.64 46.01 22.81 o 24 2 2 14.51 22.69 25.97 o -23 3 2 5.28 0.00 28.34 o -21 3 2 4.66 60.93 40.62 o -19 3 2 23.20 1.37 16.31 o -17 3 2 183.85 173.04 21.47 o -15 3 2 903.29 848.43 28.94 o -13 3 2 496.55 499.87 24.04 o -11 3 2 32.22 17.61 15.34 o -9 3 2 525.35 555.72 15.06 o -7 3 2 577.68 618.67 14.84 o -5 3 2 7.49 3.42 4.15 o -3 3 2 441.78 465.17 8.80 o -1 3 2 76.89 57.21 6.03 o 1 3 2 4.01 0.00 3.04 o 3 3 2 573.64 590.52 11.12 o 5 3 2 0.48 0.00 3.05 o 7 3 2 1187.51 1178.97 11.53 o 9 3 2 60.47 76.00 10.80 o 11 3 2 176.79 178.61 13.79 o 13 3 2 41.07 63.45 15.24 o 17 3 2 19.44 12.05 15.57 o 19 3 2 92.36 73.00 24.30 o 21 3 2 19.74 6.12 93.88 o 23 3 2 0.13 8.85 20.22 o -22 4 2 36.89 29.88 23.07 o -20 4 2 14.78 3.12 11.09 o -18 4 2 502.73 614.29 24.86 o -16 4 2 39.25 24.25 13.44 o -14 4 2 161.71 128.31 15.85 o -12 4 2 282.31 245.94 16.11 o -10 4 2 121.92 117.07 11.03 o -8 4 2 31.37 33.87 9.46 o -6 4 2 73.76 51.14 10.00 o -4 4 2 6.39 8.17 11.53 o -2 4 2 649.04 696.80 13.75 o 0 4 2 1.66 0.00 2.65 o 2 4 2 0.06 0.00 3.20 o 4 4 2 434.10 471.87 12.01 o 6 4 2 30.29 24.01 9.57 o 8 4 2 477.27 421.89 15.60 o 10 4 2 1028.26 1121.50 22.01 o 12 4 2 106.33 106.64 12.49 o 14 4 2 106.33 84.16 16.79 o 16 4 2 4.18 5.13 15.60 o 18 4 2 22.43 18.39 16.29 o 20 4 2 17.94 1.57 9.34 o 22 4 2 1.25 18.98 30.17 o -19 5 2 117.37 114.52 21.10 o -17 5 2 19.28 12.51 11.69 o -15 5 2 110.96 104.83 14.14 o -13 5 2 6.72 7.56 11.50 o -11 5 2 59.96 56.03 11.25 o -9 5 2 27.38 25.89 10.56 o -7 5 2 119.44 113.52 12.84 o -5 5 2 427.27 489.52 14.81 o -3 5 2 326.44 310.65 13.66 o -1 5 2 462.00 473.96 14.68 o 1 5 2 71.37 40.91 8.89 o 3 5 2 610.30 625.81 19.45 o 5 5 2 62.63 44.20 11.27 o 7 5 2 245.47 244.80 14.67 o 9 5 2 103.56 97.13 13.19 o 11 5 2 50.43 57.63 12.50 o 13 5 2 3.01 7.28 12.63 o 15 5 2 38.41 29.80 13.27 o 17 5 2 0.59 0.00 9.06 o 19 5 2 7.96 19.56 21.82 o -16 6 2 19.94 19.84 16.17 o -14 6 2 49.61 36.19 15.47 o -12 6 2 1.99 0.91 14.19 o -10 6 2 70.47 92.95 15.68 o -8 6 2 49.94 43.26 12.60 o -6 6 2 0.02 3.06 5.57 o -4 6 2 118.32 137.02 15.59 o -2 6 2 16.51 3.63 7.65 o 0 6 2 12.13 0.00 18.29 o 2 6 2 873.05 1039.88 26.37 o 4 6 2 311.52 350.08 19.48 o 6 6 2 92.82 83.66 15.02 o 8 6 2 155.96 160.06 16.76 o 10 6 2 2.39 0.00 7.48 o 12 6 2 60.57 78.45 14.93 o 14 6 2 88.66 95.71 19.78 o -9 7 2 18.22 10.80 16.91 o -7 7 2 55.66 61.76 17.68 o -5 7 2 121.69 137.31 18.91 o -3 7 2 7.83 21.68 20.16 o -1 7 2 183.70 169.43 32.77 o 1 7 2 75.20 72.92 23.02 o 3 7 2 4.74 0.00 8.97 o 5 7 2 0.49 0.00 12.80 o 7 7 2 24.66 26.38 16.78 o -27 1 3 159.81 135.67 27.86 o -25 1 3 167.07 153.12 19.83 o -23 1 3 65.07 78.39 16.57 o -21 1 3 75.81 72.99 12.38 o -19 1 3 965.84 998.78 24.44 o -17 1 3 25.56 39.72 10.77 o -15 1 3 66.92 67.09 10.64 o -13 1 3 54.86 47.07 9.15 o -11 1 3 1149.98 1088.52 14.57 o -9 1 3 3588.55 3741.70 45.59 o -7 1 3 29983.63 31202.77 367.77 o -5 1 3 1194.81 1175.64 77.76 o -3 1 3 41196.00 41820.27 241.53 o -1 1 3 7852.75 7991.95 25.14 o 1 1 3 3206.01 3289.78 13.61 o 3 1 3 546.38 600.83 8.14 o 5 1 3 3166.39 3625.72 19.27 o 7 1 3 3988.12 4504.59 32.20 o 9 1 3 947.67 1125.21 16.99 o 11 1 3 1767.31 1920.11 22.86 o 13 1 3 10.21 1.99 4.01 o 15 1 3 1622.48 1617.24 35.42 o 17 1 3 5.94 1.31 4.90 o 19 1 3 1050.80 1114.17 27.24 o 21 1 3 770.43 767.46 31.78 o 23 1 3 92.70 107.07 26.48 o 25 1 3 6.17 0.88 22.86 o -26 2 3 303.85 317.05 29.03 o -24 2 3 174.47 151.47 24.42 o -22 2 3 389.85 404.86 25.70 o -20 2 3 448.82 453.82 35.78 o -18 2 3 119.12 89.95 16.74 o -16 2 3 730.41 638.23 23.50 o -14 2 3 893.21 926.66 26.23 o -12 2 3 479.83 481.27 30.88 o -10 2 3 179.96 165.29 31.47 o -8 2 3 7350.30 7665.55 176.65 o -6 2 3 366.83 445.79 63.50 o -4 2 3 5369.07 5330.19 25.12 o -2 2 3 408.48 490.77 7.28 o 0 2 3 652.08 569.28 7.82 o 2 2 3 880.11 876.75 8.89 o 4 2 3 1448.58 1331.59 10.01 o 6 2 3 6259.39 6111.91 19.87 o 8 2 3 76.93 82.90 6.92 o 10 2 3 1707.42 1658.21 19.76 o 12 2 3 232.15 245.37 18.29 o 14 2 3 1060.77 1049.10 20.78 o 16 2 3 0.07 7.91 20.63 o 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