#------------------------------------------------------------------------------ #$Date: 2012-09-11 12:26:43 +0300 (Tue, 11 Sep 2012) $ #$Revision: 66590 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/23/54/2235429.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2235429_Fobs loop_ _publ_author_name 'Qi, Chen' 'He, Xiang' 'Shao, Min' 'Li, Ming-Xing' _publ_section_title ; Tetraaquabis[5-(pyridin-3-yl)tetrazolido-\kN^5^]manganese(II) tetrahydrate ; _journal_coeditor_code GK2497 _journal_issue 7 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m890 _journal_volume 68 _journal_year 2012 _space_group_IT_number 2 _symmetry_space_group_name_Hall '-P 1' _symmetry_space_group_name_H-M 'P -1' _cell_angle_alpha 84.878 _cell_angle_beta 65.347 _cell_angle_gamma 72.571 _cell_length_a 8.1370 _cell_length_b 8.6290 _cell_length_c 8.7610 _exptl_crystal_F_000 255.00 _reflns_d_resolution_high 0.8395 _[local]_cod_data_source_file gk2497Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' 1 in P1 New: P-1' _shelx_refln_list_code 4 _shelx_f_calc_maximum 132.77 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 2391.28 2463.28 44.23 o 2 0 0 7.28 9.13 0.55 o 3 0 0 2651.13 2818.40 50.91 o 4 0 0 163.29 187.07 4.78 o 5 0 0 0.74 1.70 0.37 o 6 0 0 0.33 0.86 0.46 o 7 0 0 25.52 28.02 3.02 o 8 0 0 32.91 30.22 3.48 o -8 1 0 2.71 4.03 1.65 o -7 1 0 39.13 41.29 2.35 o -6 1 0 22.93 24.53 1.74 o -5 1 0 45.38 43.66 1.55 o -4 1 0 174.38 168.43 3.79 o -3 1 0 372.50 371.99 7.29 o -2 1 0 13.56 14.46 0.58 o -1 1 0 1787.25 1785.50 32.11 o 0 1 0 851.07 747.81 24.31 o 1 1 0 750.35 715.30 15.73 o 2 1 0 1652.66 1611.95 35.26 o 3 1 0 281.92 263.13 4.68 o 4 1 0 964.39 975.13 20.06 o 5 1 0 19.64 19.13 1.29 o 6 1 0 175.32 187.73 5.36 o 7 1 0 618.26 626.10 21.28 o 8 1 0 41.13 40.30 3.94 o -7 2 0 140.04 134.38 4.77 o -6 2 0 282.54 283.82 6.37 o -5 2 0 8.61 9.49 0.83 o -4 2 0 0.39 0.68 0.29 o -3 2 0 813.76 782.18 14.76 o -2 2 0 191.17 215.31 4.41 o -1 2 0 4422.99 3634.89 117.39 o 0 2 0 142.07 172.20 6.28 o 1 2 0 2142.71 2126.82 46.33 o 2 2 0 66.82 63.64 2.11 o 3 2 0 745.10 733.21 16.50 o 4 2 0 807.40 795.90 15.64 o 5 2 0 55.02 60.53 1.57 o 6 2 0 287.37 282.27 10.50 o 7 2 0 25.51 27.47 2.84 o 8 2 0 3.85 3.39 1.28 o -7 3 0 104.81 118.35 6.51 o -6 3 0 23.92 25.17 3.11 o -5 3 0 0.45 0.33 0.40 o -4 3 0 225.65 216.69 11.31 o -3 3 0 0.66 1.14 0.39 o -2 3 0 131.49 126.09 5.42 o -1 3 0 296.23 309.20 11.20 o 0 3 0 910.70 903.29 30.07 o 1 3 0 692.81 747.74 16.84 o 2 3 0 185.38 198.53 4.92 o 3 3 0 375.93 338.61 8.05 o 4 3 0 113.45 127.47 3.60 o 5 3 0 28.21 34.44 2.29 o 6 3 0 248.25 254.07 9.66 o 7 3 0 0.73 1.65 1.01 o 8 3 0 63.81 60.28 4.21 o -6 4 0 41.66 42.13 3.48 o -5 4 0 96.47 90.49 5.23 o -4 4 0 48.40 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152.18 6.52 o 6 6 0 360.13 346.45 12.71 o 7 6 0 17.34 17.30 2.38 o 8 6 0 54.57 55.60 4.12 o -4 7 0 78.45 73.03 5.04 o -3 7 0 84.27 81.02 5.22 o -2 7 0 302.34 323.05 13.34 o -1 7 0 60.69 56.90 3.94 o 0 7 0 10.74 11.72 1.29 o 1 7 0 57.87 64.42 2.67 o 2 7 0 25.10 23.61 4.53 o 3 7 0 32.26 32.80 1.78 o 4 7 0 16.21 18.77 2.20 o 5 7 0 1.58 2.47 1.01 o 6 7 0 102.41 97.73 5.23 o 7 7 0 230.22 232.31 9.74 o -3 8 0 88.78 95.59 6.14 o -2 8 0 60.50 55.61 4.31 o -1 8 0 43.73 49.55 3.94 o 0 8 0 191.00 185.31 8.82 o 1 8 0 18.75 17.52 1.60 o 2 8 0 6.30 9.72 2.06 o 3 8 0 216.11 210.16 6.22 o 4 8 0 6.73 6.77 1.46 o 5 8 0 11.73 10.53 1.83 o 6 8 0 49.78 58.71 3.94 o 7 8 0 37.38 40.75 3.94 o -1 9 0 38.75 35.72 3.94 o 0 9 0 41.33 36.73 3.94 o 1 9 0 63.44 75.95 5.13 o 2 9 0 55.69 48.83 3.85 o 3 9 0 10.04 11.99 2.01 o 4 9 0 123.99 120.50 6.05 o 5 9 0 9.86 13.18 2.20 o 6 9 0 2.79 3.30 1.46 o 1 10 0 17.86 13.09 2.38 o 2 10 0 2.43 4.12 1.56 o -2 -10 1 12.56 13.55 2.56 o -1 -10 1 3.44 2.65 1.28 o -5 -9 1 31.22 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o 3 -6 1 323.29 336.41 13.72 o 4 -6 1 98.76 95.53 5.68 o 5 -6 1 7.73 3.66 1.46 o -8 -5 1 1.17 3.66 1.46 o -7 -5 1 134.65 137.31 6.70 o -6 -5 1 12.70 10.34 1.83 o -5 -5 1 357.87 353.78 12.54 o -4 -5 1 167.61 160.01 5.47 o -3 -5 1 318.44 326.02 8.22 o -2 -5 1 201.50 193.32 5.21 o -1 -5 1 81.10 81.04 3.30 o 0 -5 1 223.04 227.45 6.00 o 1 -5 1 127.01 138.40 4.10 o 2 -5 1 9.84 8.79 1.56 o 3 -5 1 1.00 1.37 0.82 o 4 -5 1 7.65 9.25 1.83 o 5 -5 1 6.56 16.66 2.56 o 6 -5 1 0.92 0.82 0.92 o -8 -4 1 4.12 5.13 1.56 o -7 -4 1 5.46 5.40 1.46 o -6 -4 1 0.74 0.37 0.73 o -5 -4 1 103.72 104.65 3.50 o -4 -4 1 112.10 115.20 3.57 o -3 -4 1 962.77 967.70 21.95 o -2 -4 1 449.00 431.28 10.22 o -1 -4 1 44.16 41.69 1.56 o 0 -4 1 3323.95 3188.19 69.69 o 1 -4 1 5.12 5.77 1.10 o 2 -4 1 1011.44 1024.40 34.86 o 3 -4 1 76.64 65.46 4.45 o 4 -4 1 125.93 115.11 4.82 o 5 -4 1 30.23 32.24 2.24 o 6 -4 1 0.55 0.87 0.65 o 7 -4 1 84.85 81.93 5.22 o -8 -3 1 3.98 4.94 1.65 o -7 -3 1 199.33 179.17 8.08 o -6 -3 1 585.86 587.96 19.81 o -5 -3 1 33.31 30.78 1.69 o -4 -3 1 10.58 11.16 1.00 o -3 -3 1 333.07 317.12 10.68 o -2 -3 1 157.70 174.18 4.53 o -1 -3 1 985.39 964.96 21.49 o 0 -3 1 1146.67 1170.00 27.76 o 1 -3 1 144.73 150.55 11.41 o 2 -3 1 1574.38 1535.03 50.81 o 3 -3 1 429.99 431.50 10.93 o 4 -3 1 413.35 432.79 11.13 o 5 -3 1 75.88 72.28 2.30 o 6 -3 1 19.07 22.50 1.81 o 7 -3 1 34.01 34.52 2.20 o -8 -2 1 178.55 179.51 8.54 o -7 -2 1 90.59 89.56 5.13 o -6 -2 1 107.56 120.61 5.78 o -5 -2 1 0.34 0.37 0.28 o -4 -2 1 7.13 5.09 0.50 o -3 -2 1 945.69 993.18 22.36 o -2 -2 1 525.88 542.59 14.74 o -1 -2 1 395.23 380.69 8.78 o 0 -2 1 2597.88 2444.38 53.30 o 1 -2 1 17626.92 13861.21 1732.56 o 2 -2 1 74.46 67.65 4.54 o 3 -2 1 120.93 112.82 2.68 o 4 -2 1 1091.34 1097.75 20.54 o 5 -2 1 27.45 32.05 1.37 o 6 -2 1 54.18 57.19 2.06 o 7 -2 1 18.58 22.35 1.81 o -8 -1 1 2.10 1.28 1.28 o -7 -1 1 40.27 55.23 3.94 o -6 -1 1 82.49 94.39 3.40 o -5 -1 1 11.25 9.55 0.99 o -4 -1 1 948.12 922.36 15.61 o -3 -1 1 1026.53 1025.67 18.96 o -2 -1 1 666.60 633.74 11.76 o -1 -1 1 746.19 753.54 17.26 o 0 -1 1 2224.89 2233.26 40.28 o 1 -1 1 398.42 366.33 8.70 o 2 -1 1 58.35 59.52 1.98 o 3 -1 1 417.68 417.69 8.07 o 4 -1 1 62.68 63.08 1.81 o 5 -1 1 100.67 100.89 2.73 o 6 -1 1 30.10 30.00 1.38 o 7 -1 1 177.51 194.44 8.26 o 8 -1 1 243.72 262.75 10.84 o -8 0 1 7.56 8.06 2.11 o -7 0 1 190.08 193.72 8.81 o -6 0 1 132.75 143.59 4.82 o -5 0 1 225.68 233.20 8.74 o -4 0 1 36.52 45.21 1.65 o -3 0 1 35.16 23.91 1.38 o -2 0 1 1545.20 1496.18 24.63 o -1 0 1 368.41 371.26 15.59 o 0 0 1 259.13 266.15 9.12 o 1 0 1 39.15 35.90 1.07 o 2 0 1 1941.14 1944.16 44.53 o 3 0 1 883.13 894.26 16.45 o 4 0 1 152.91 168.58 3.68 o 5 0 1 146.37 150.09 3.50 o 6 0 1 27.22 27.77 1.68 o 7 0 1 95.34 99.93 5.13 o 8 0 1 3.50 5.49 1.56 o -7 1 1 108.13 106.18 7.70 o -6 1 1 103.23 109.14 3.95 o -5 1 1 1.47 2.03 0.59 o -4 1 1 7.65 9.56 0.71 o -3 1 1 114.73 85.43 2.16 o -2 1 1 661.12 681.10 17.10 o -1 1 1 111.79 101.59 2.73 o 0 1 1 673.48 688.34 22.58 o 1 1 1 728.32 757.75 22.69 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22.71 2.66 o 9 3 1 4.66 5.77 1.74 o -6 4 1 21.08 24.72 3.02 o -5 4 1 32.36 28.48 3.02 o -4 4 1 0.64 0.37 0.64 o -3 4 1 393.79 392.35 14.68 o -2 4 1 425.61 381.39 14.06 o -1 4 1 5.27 7.96 1.19 o 0 4 1 2168.19 2061.27 67.50 o 1 4 1 331.81 336.11 13.65 o 2 4 1 144.89 142.37 3.90 o 3 4 1 2214.04 2338.70 51.37 o 4 4 1 316.69 316.17 7.67 o 5 4 1 0.65 2.11 0.73 o 6 4 1 258.58 245.59 9.20 o 7 4 1 357.05 356.51 12.90 o 8 4 1 0.26 1.83 1.01 o 9 4 1 31.80 30.13 3.30 o -5 5 1 1.68 1.37 1.10 o -4 5 1 47.90 40.76 3.30 o -3 5 1 162.20 167.19 7.71 o -2 5 1 38.79 38.93 2.84 o -1 5 1 602.55 549.68 19.68 o 0 5 1 147.68 151.51 6.52 o 1 5 1 31.14 28.48 1.46 o 2 5 1 293.24 288.23 11.72 o 3 5 1 4.05 2.83 0.48 o 4 5 1 440.25 421.00 14.15 o 5 5 1 57.86 53.24 3.12 o 6 5 1 6.74 9.70 1.56 o 7 5 1 309.17 276.35 10.58 o 8 5 1 114.07 116.18 6.05 o -4 6 1 69.62 69.09 4.86 o -3 6 1 65.23 59.28 4.21 o -2 6 1 56.93 55.71 3.85 o -1 6 1 76.62 78.74 4.49 o 0 6 1 130.58 138.48 4.41 o 1 6 1 99.78 101.64 3.47 o 2 6 1 348.98 375.51 9.48 o 3 6 1 85.66 81.33 2.82 o 4 6 1 640.84 653.21 21.25 o 5 6 1 0.87 1.65 0.82 o 6 6 1 66.04 70.56 4.03 o 7 6 1 157.96 159.31 7.16 o 8 6 1 50.26 52.94 3.85 o -4 7 1 76.51 68.45 4.95 o -3 7 1 36.42 31.59 3.48 o -2 7 1 49.63 47.27 3.66 o -1 7 1 150.75 163.27 7.71 o 0 7 1 132.03 153.12 4.92 o 1 7 1 77.37 83.82 3.24 o 2 7 1 23.39 25.51 1.78 o 3 7 1 54.39 54.99 2.40 o 4 7 1 0.91 0.18 0.64 o 5 7 1 30.28 30.22 2.84 o 6 7 1 15.89 15.47 2.11 o 7 7 1 37.97 40.57 3.66 o 8 7 1 27.84 23.99 2.93 o -2 8 1 9.31 10.71 2.11 o -1 8 1 1.02 2.01 1.10 o 0 8 1 248.85 255.85 7.51 o 1 8 1 173.09 169.20 6.75 o 2 8 1 50.53 55.91 2.62 o 3 8 1 5.19 4.76 1.28 o 4 8 1 11.09 9.61 1.74 o 5 8 1 54.84 61.10 3.94 o 6 8 1 1.35 1.37 0.92 o 7 8 1 21.52 25.09 3.02 o -1 9 1 13.14 13.37 2.47 o 0 9 1 67.77 60.56 4.49 o 1 9 1 20.49 23.17 2.24 o 2 9 1 28.76 29.88 5.77 o 3 9 1 60.45 60.83 3.94 o 4 9 1 152.17 152.12 7.06 o 5 9 1 1.14 1.37 1.19 o 6 9 1 0.53 -0.64 0.92 o 1 10 1 10.36 13.00 2.38 o 3 10 1 60.64 60.37 4.21 o 4 10 1 7.83 8.79 1.92 o -3 -9 2 323.06 320.76 13.98 o -2 -9 2 100.73 101.39 6.33 o -1 -9 2 7.84 4.49 1.65 o 0 -9 2 65.25 66.15 4.95 o 1 -9 2 19.96 17.76 2.84 o -6 -8 2 1.27 3.66 1.56 o -5 -8 2 22.32 23.80 2.84 o -4 -8 2 35.93 38.83 3.39 o -3 -8 2 70.52 76.51 5.04 o -2 -8 2 31.12 31.59 3.57 o -1 -8 2 4.73 3.20 1.19 o 0 -8 2 141.35 131.66 7.16 o 1 -8 2 26.40 25.27 3.30 o 2 -8 2 2.92 4.12 1.46 o 3 -8 2 47.53 36.54 4.12 o -6 -7 2 64.35 71.74 4.58 o -5 -7 2 108.30 100.49 5.23 o -4 -7 2 237.59 247.28 8.00 o -3 -7 2 81.51 82.27 3.17 o -2 -7 2 9.28 12.43 1.23 o -1 -7 2 86.30 80.77 4.95 o 0 -7 2 186.64 188.94 8.82 o 1 -7 2 66.24 66.35 4.58 o 2 -7 2 120.23 129.05 6.97 o 3 -7 2 58.79 47.82 3.94 o 4 -7 2 8.12 9.70 2.20 o -7 -6 2 26.18 27.93 3.20 o -6 -6 2 11.69 12.08 2.01 o -5 -6 2 0.63 1.10 0.92 o -4 -6 2 82.59 77.23 3.03 o -3 -6 2 83.26 83.31 3.08 o -2 -6 2 116.93 118.09 3.77 o -1 -6 2 11.45 10.56 1.03 o 0 -6 2 2.13 3.94 1.19 o 1 -6 2 503.79 513.22 19.33 o 2 -6 2 67.77 62.32 4.22 o 3 -6 2 113.03 113.36 6.24 o 4 -6 2 94.77 90.21 5.59 o 5 -6 2 15.48 14.01 2.38 o -7 -5 2 20.79 28.29 3.39 o -6 -5 2 324.95 315.48 12.06 o -5 -5 2 325.66 344.29 12.52 o -4 -5 2 220.38 224.64 6.28 o -3 -5 2 189.24 186.54 5.30 o -2 -5 2 57.91 54.94 2.14 o -1 -5 2 2.58 4.08 0.87 o 0 -5 2 422.12 425.77 10.23 o 1 -5 2 64.53 67.56 4.03 o 2 -5 2 11.11 12.08 1.83 o 3 -5 2 251.66 262.56 11.04 o 4 -5 2 71.09 68.83 3.04 o 5 -5 2 50.62 49.78 7.56 o 6 -5 2 20.73 26.46 3.39 o -7 -4 2 215.89 223.63 9.73 o -6 -4 2 29.20 24.27 2.75 o -5 -4 2 43.49 49.10 2.30 o -4 -4 2 10.68 9.72 1.07 o -3 -4 2 95.47 88.10 2.97 o -2 -4 2 1119.92 1159.87 26.13 o -1 -4 2 531.97 532.61 12.44 o 0 -4 2 342.22 368.58 8.81 o 1 -4 2 1805.16 1738.03 40.62 o 2 -4 2 2692.46 2473.38 72.51 o 3 -4 2 109.28 109.53 4.36 o 4 -4 2 35.33 30.86 4.49 o 5 -4 2 71.45 72.38 3.07 o 6 -4 2 1.54 1.83 0.71 o 7 -4 2 19.24 24.75 2.16 o -7 -3 2 26.89 27.10 3.11 o -6 -3 2 38.96 41.21 3.57 o -5 -3 2 3.56 2.92 0.70 o -4 -3 2 0.78 8.05 1.28 o -3 -3 2 861.74 831.42 19.13 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